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Promotion of Photocatalytic Hydrogen Evolution under Visible Light with NiO/C Fabricated via a Super Facile and General Strategy
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Thermal and mechanical properties of polyamide 12/modified carbon nanotubes composites prepared via the in situ ring-opening polymerization
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Laser stimulated second and third harmonic optical effects in F: SnO2 nanostructures grown via chemical synthetic route
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Thermal and spectroscopic profiles variation of cold-pressed raspberry seed oil studied by DSC, UV/VIS, and FTIR techniques
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Temperature Coefficient of Electronic Polarizability in Thin Polymer Films Deposited on Si and SiO2 Substrates Determined via Spectroscopic Ellipsometry
PublicationEllipsometry is widely used to determine the thermo-optical properties of thin polymer films. However, if the thermo-optic coefficient (TOC) and the linear thermal expansion coefficient (LTEC) are to be used to determine the temperature coefficient of electronic polarizability (TCEP) in thin polymer films, their values must be determined with the greatest possible accuracy, as both have the opposite effect. In this article,...
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A facile method for Tauc exponent and corresponding electronic transitions determination in semiconductors directly from UV–Vis spectroscopy data
PublicationIn this work, a facile method allowing for estimation of the exponent in the Tauc equation directly from the UV–vis spectra is presented. It is based on the Taylor expansion of the logarithmic version of the Tauc equation. The Tauc exponent is calculated from the tangent slope of the absorption data. Knowledge of this coefficient provides information about the optical transition types and is used as an input for the calculations...
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Cu-Doped Layered Double Hydroxide Constructs the Performance-Enhanced Supercapacitor Via Band Gap Reduction and Defect Triggering
PublicationLayered double hydroxides (LDHs) are regarded as the excellent electrode materials for supercapacitors because of their high theoretical capacitance and abundance. However, the poor conductivity and limited reaction kinetics of LDHs restrict their practical application severely. Herein, Cu is chosen from groups VIII/IB/IIB as dopants for Co-based LDH (CuCo-LDH). The designed metal–organic framework-derived hierarchical CuCo-LDH...
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Non-Coaxially Rotating Motion in Casson Martial along with Temperature and Concentration Gradients via First-Order Chemical Reaction
PublicationThe effect of non-coaxial rotation on the transport of mass subjected to first-order chemical reaction is studied analytically. The effects of thermal radiation, buoyancy, constructive and destructive chemical reactions along with Casson fluid in rotating frame are discussed. Time evolution of primary and secondary velocities, energy and solute particles are analyzed. The behavior of flow under the variation of intensity of magnetic...
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Activation Energy and Inclination Magnetic Dipole Influences on Carreau Nanofluid Flowing via Cylindrical Channel with an Infinite Shearing Rate
PublicationThe infinite shear viscosity model of Carreau fluid characterizes the attitude of fluid flow at a very high/very low shear rate. This model has the capacity for interpretation of fluid at both extreme levels, and an inclined magnetic dipole in fluid mechanics has its valuable applications such as magnetic drug engineering, cold treatments to destroy tumors, drug targeting, bio preservation, cryosurgery, astrophysics, reaction kinetics,...
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Poly-L-Lysine-functionalized fluorescent diamond particles: pH triggered fluorescence enhancement via surface charge modulation
PublicationRecently, the interest in applying fluorescent diamond particles (FDPs) containing nitrogen-vacancy (NV) centers for enhancing the mechanical and chemical properties of some materials, biological imaging, and sensing has been expanding rapidly. The unique properties of NV centers such as intensive, time-stable fluorescence, and an electron spin, which exhibits long coherence time and may be manipulated using external stimuli, such...
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Morphology Regulation Mechanism and Enhancement of Photocatalytic Performance of BiOX (X = Cl, Br, I) via Mannitol-Assisted Synthesis
PublicationBiOX (X = Cl, Br, I) photocatalysts with dominant (110) facets were synthesized via a mannitol-assisted solvothermal method. This is the first report on the exposed (110) facets-, size-, and defects-controlled synthesis of BiOX achieved by solvothermal synthesis with mannitol. This polyol alcohol acted simultaneously as a solvent, capping agent, and/or soft template. The mannitol concentration on the new photocatalysts morphology...
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Rapid development of the photoresponse and oxygen evolution of TiO2 nanotubes sputtered with Cr thin films realized via laser annealing
PublicationRecently, earth abundant transition metal oxides have gained particular attention as potential catalyst candidates due to their availability and low-cost comparing to substrates containing precious Pt or Au species. Herein, we present characterization of morphology, structure and electrochemical properties of pulsed 532 nm laser treated TiO2 nanotubes (NT) sputtered by the thin film of chromium. Scanning electron microscopy enables...
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Influence of Installation Effects on Pile Bearing Capacity in Cohesive Soils – Large Deformation Analysis Via Finite Element Method
PublicationIn this paper, the whole process of pile construction and performance during loading is modelled via large deformation finite element methods such as Coupled Eulerian Lagrangian (CEL) and Updated Lagrangian (UL). Numerical study consists of installation process, consolidation phase and following pile static load test (SLT). The Poznań site is chosen as the reference location for the numerical analysis, where series of pile SLTs...
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TiO2 /SrTiO3 and SrTiO3 microspheres decorated with Rh, Ru or Pt nanoparticles: Highly UV–vis responsible photoactivity and mechanism
PublicationA series of TiO2/SrTiO3 and SrTiO3 microspheres decorated by Rh, Ru or Pt NPs were prepared by facile hydrothermal method. The as-prepared samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM) with energy-dispersive Xray (EDX) spectroscopy, scanning electron microscopy (SEM), photoluminescence spectrometry (PL), Fourier transform infrared (FT-IR) and...
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The early failure of the gamma nail and the dynamic hip screw in femurs with a wide medullary canal. A biomechanical study of intertrochanteric fractures
PublicationBackground: Intertrochanteric fractures may occur in a bone with a wide medullary canal that may lead to significant mobility of a intramedullary nail, contrary to an extramedullary device. This study evaluates the Dynamic Hip Screw and the gamma nail in AO 31.A2.1 fractures in these circumstances. Methods: Synthetic femora with canals drilled to 18 mm were used. Five fixation types were examined: a 2 - hole and a 4 – hole Dynamic...
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Sustainable Strategy for Algae Biomass Waste Management via Development of Novel Bio-Based Thermoplastic Polyurethane Elastomers Composites
PublicationThis work concerns the waste management method of algae biomass wastes (ABW). For this purpose, we prepared bio-based thermoplastic polyurethane elastomer (bio-TPU) composites. Algae biomass wastes are derived from algal oil extraction of Chlorella vulgaris and from biomass of Enteromorpha and Zostera marina. ABWs were used in the bio-TPUs composites as a filler in the quantity of 1, 5, 10, and 15 wt.%. The bio-based composites...
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New LED photoreactor with modulated UV–vis light source for efficient degradation of toluene over WO3/TiO2 photocatalyst
PublicationThe efficiencies of prepared WO3/TiO2 photocatalysts with varying amounts of WO3 were evaluated for gas-phase photocatalytic degradation of toluene. The obtained results revealed that the best photocatalytic properties were characteristic for samples calcined at 500ºC, which can be associated with high crystalline phase content (> 97%) and favourable BET surface area. The photocatalytic degradation tests were performed in two photoreactors...
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The effect of PEDOT morphology on hexavalent chromium reduction over 2D TiO2/PEDOT photocatalyst under UV–vis light
PublicationThe present study represents an approach to apply organic-inorganic hybrid materials for photocatalytic removal of heavy metals from the aqueous environment. The photocatalytic activity of the semiconductor modified with the conjugated polymer may depends on the conjugated polymer type, its amount and morphology. Therefore, in the present study the effect of poly (3, 4-ethylenedioxythiophene) (PEDOT) morphology on adsorption and photoreduction...
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Hydrodynamika reaktora airlift z odwrotną warstwą fluidalną a szybkość wnikania tlenu. VII Ogólnopolska Konferencja Przepływów Wielofazowych.
PublicationGenerowano odwrotną warstwę fluidalną w strefie opadania reaktora airlift z zewnętrzną cyrkulacją. Stwierdzono, że wnikanie tlenu zachodzi wyłącznie w strefie wznoszenia reaktora airlift, a średni dla reaktora współczynnik wnikania tlenu pozostaje niezależny od stężenia ciała stałego w strefie opadania. Stwierdzono, że dla tego samego stężenia ciała stałego stosunek współczynników wnikania tlenu w badanym reaktorze i zawiesinowym...
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Stochastyczne nieizotermiczne smarowanie stawu biodrowego z odkształcalną chrząstką = Stochastic nonisothermic lubrication of hip joint with deformable cartilage
PublicationW niniejszej pracy przedstawiono metodę rozwiązywania problemu nieizotermicznego smarowania naturalnych stawów biodrowych człowieka oraz endoprotez z uwzględnieniem deformacji powierzchni stawowych oraz związanych z tym faktem efektów losowych. Przedstawiono również wyniki pomiarów powierzchni głów kostnych na Aparacie Rank-Taylor Hopson Talyscan 150. Uzyskane wyniki zostały opracowane z użyciem programu komputerowegoTalymap-Expert.
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Realizacja łącza sygnalizacyjnego SS7 w sieci IP QoS
PublicationWykorzystanie technologii IP dla realizacji połączeń między sieciami PSTN/ISDN wymaga obsługi sygnalizacji SS7 ISUP. Jednym z rozwiązań tego problemu jest utworzenie łącza sygnalizacyjnego na platformie IP dla połączenia punktów sygnalizacyjnych łączonych sieci. W niniejszej pracy opisano pojęcie łącza sygnalizacyjnego SS7, jego ekwiwalent w sieci IP oraz propozycję rozwiązania programowego realizującego takie łącze w sieci IP...
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A practical approach to restoration in survivable IP/WDM mesh networks
PublicationW pracy omówiono warstwową architekturę: IP na optycznej sieci transportowej (OTN). Węzły mają zintegrowaną funkcjonalność: rulerów IP i przełącznic optycznych (OXC). Dopuszcza się możliwość konwersji długości fal na ścieżkach optycznych. Autor rozważa zagadnienie znalezienia ścieżek optycznych o możliwie najniższym koszcie przy spełnieniu ograniczeń przepustowości, wymaganych strumieni zapotrzebowań i zabezpieczonych z góry na...
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Katalizatory wanadowe w przemysłowej produkcji kwasu siarkowego (VI)
PublicationSpośród wszystkich chemikaliów wytwarzanych w przemyśle chemicznym, kwas siarkowy (VI) jest produkowany na największą skalę. To powoduje, że zużycie tego kwasu często jest używane do monitorowania stopnia uprzemysłowienia danego kraju. Obecnie produkcja na całym świecie przekracza 160 mln ton rocznie. Europejskie Stowarzyszenie Producentów Kwasu Siarkowego zaleca ciągły rozwój i udoskonalenie procesów technologicznych oraz unowocześnianie...
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Realizacja usługi Fax w sieci z technologią IP
PublicationZastosowanie technologii IP jako platformy usług telekomunikacyjnych wymaga realizacji przez tą sieć usługi Fax. Niestety specyfika tej usługi oraz właściwości sieci z protokołem IP stwarzają szereg problemów przy praktycznej jej realizacji. W niniejszym artykule przedstawiono dwa sposoby realizacji usługi Fax w postaci aplikacji SIP-t31modem oraz Terminal-T.38. Oba rozwiązania poddano testom i omówiono uzyskane wyniki.
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Specyfikacja Systemu IP QoS opartego na architekturze DiffServ
PublicationArtykuł przedstawia ogólną specyfikację systemu IP QoS (ang. Internet Protocol Quality of Service), który to system jest obecnie implementowany w ramach projektu krajowego "Zarządzanie ruchemw sieciach IP". System ten jest zgodny z architekturą DiffServ (ang. Differentiated Services) i architekturą NGN (Next Generation Networks). W szczególności, artykuł pokrótce omawia architekturęsystemu, oferowane klasy usług w systemie oraz...
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Koncepcja modelu do badnia wydajności domeny IP QoS
PublicationCelem artykułu jest przedstawienie koncepcji hierarchicznie rozproszonego brokera MBB (Multiple Bandwidth Broker) realizującego funkcje AC w oparciu o pomiary. Zaproponowane zostały przez autorów modele funkcjonalne brokera centralnego oraz brokera brzegowego. Autorzy zaproponowali także algorytm realizujący MBAC, zaimplementowany w brokerze brzegowym. Prezentowany model koncepcyjny umożliwia zwiększenie skalowalności DS oraz ograniczenie...
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Evaluation of TiO2/UV; O3/UV, and PDS/Vis for improving chlorfenvinphos removal from real municipal treated wastewater effluent
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FTIR Studies of the Surface of TiO2, Fe-TiO2 and Fe-C-TiO2 Photocatalysts in Phenol Oxidation Via the Photo-Fenton Process
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Effect of the carbon coating in Fe–C–TiO2 photocatalyst on phenol decomposition under UV irradiation via photo-Fenton process
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Mo93m isomer depletion via nuclear excitation by electron capture in resonant transfer into highly excited open-shell atomic states
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Effect of multi-walled carbon nanotubes properties on the photocatalytic activity of bismuth-based composites synthesised via an imidazolium ionic liquid
PublicationThe use of various types of multi-walled carbon nanotubes in the synthesis of bismuth oxybromide semiconductors via imidazolium ionic liquid was studied in detail. The effect of the MWCNT shape, specific surface area, and various diameters on the morphology, surface properties and photoactivity of the Bi-based composites has been investigated for the first time. So far, the literature has only shown the enhancement of photocatalytic...
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Value co‐creation (VCC) and value co‐destruction (VCD) via open government data (OGD): Empirical case of Tanzania
PublicationHaving emphasized upon the potential benefits of Open Government Data (OGD) initiatives via value derivation and innovation pursuits of the stakeholders, it falls in place to complement this line of OGD research in the specific case of Tanzania, a developing country, to support the inferences. Specifically, it is important to understand the manner in which OGD VCC-one of the hinges of OGD initiatives- and OGD VCD-a possible fall...
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Pharmaceuticals wastewater treatment via different advanced oxidation processes: Reaction mechanism, operational factors, toxicities, and cost evaluation – A review
PublicationPharmaceuticals comprises different drugs used for treating different infections in human being and animals. The huge quantities of pharmaceuticals used are found to discharge into different water resources and cause different health and environmental problems. The continuous and large-scale discharge of pharmaceuticals increases their persistency which can consequently make them more toxic. The different advanced oxidation processes...
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SU‐E‐T‐103: Three‐Dimensional Measurements of Dose and LET from a Proton Beam via Polymer Gel Dosimetry
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Csk homologous kinase (CHK), unlike Csk, enhances MAPK activation via Ras-mediated signaling in a Src-independent manner
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Promotion of MXene (Ti3C2Tx) as a robust electrocatalyst for oxygen evolution reaction via active sites of ZIF-67 - In situ mechanism investigations
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Investigation of sinonasal anatomy via low-dose multidetector CT examination in chronic rhinosinusitis patients with higher risk for perioperative complications
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Copper(II) complexes with substituted imidazole and chlorido ligands: X-ray, UV-Vis, magnetic and EPR studies and chemotherapeutic potential
PublicationCrystal structures, UV-Vis and EPR spectra and magnetic properties of four copper(II) complexes with chloride anions and 4-methylimidazole, 2-ethylimidazole, 2-isopropylimidazole or 2-ethyl-4-methylimidazole are described. In the solid state three of the complexes are mononuclear and one complex with 2-ethylimidazole is binuclear with bridging chlorido ions. UV-Vis spectra of the methanolic solutions of the complexes show LMCT...
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THE GENE CLONING, OVEREXPRESSION, PURIFICATION AND BIOCHEMICAL CHARACTERISATION OF A NEW COLD-ADAPTED β–GALACTOSIDASE FROM ARTHROBACTER SP. VII-4
PublicationINTRODUCTION. β-Galactosidase [EC 3.2.1.23] is an enzyme that catalyzes the hydrolysis of O-glycosidic linkages in galactosides. It is commercially used in dairy industry for the production of milk with reduced lactose content. Potentially, the best method for lactose removal under cooling conditions should be carried out with a cold-adapted enzyme. AIM. The aim of this study was to determine the taxonomic affiliation of the isolate...
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Orthodontic characteristics of maxillary arch deficiency in 5-year-old patientsundergoing unilateral cleft lip and palate repair with and withoutearly gingivoplasty
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Copper(II) complexes with substituted imidazole and chlorido ligands: X-ray, UV–Vis, magnetic and EPR studies and chemotherapeutic potential
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Application of a novel deep eutectic solvent modified carbon nanotube for pipette-tip micro solid phase extraction of 6-mercaptopurine
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Mono- and bimetallic (Pt/Cu) titanium(IV) oxide core–shell photocatalysts with UV/Vis light activity and magnetic separability
PublicationTitanium(IV) oxide is one of the most widely investigated photocatalysts. However, separation of nano-sized particulate titania might result in profitless technologies for commercial applications. Additionally, bare titania is almost inactive under the Vis range of solar spectrum due to its wide bandgap. Therefore, the present study aims to prepare novel coreinterlayer- shell TiO2 magnetic photocatalysts modified with metal nanoparticles...
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Nitrogen removal via the nitrite pathway during wastewater co-treatment with ammonia-rich landfill leachates in a sequencing batch reactor
PublicationThe biological treatment of ammonia-rich landfill leachates due to an inadequate C to N ratio requires expensive supplementation of carbon from an external carbon source. In an effort to reduce treatment costs, the objective of the study was to determine the feasibility of nitrogen removal via the nitrite pathway during landfill leachate co-treatment with municipal wastewater. Initially, the laboratory-scale sequencing batch reactor...
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Rheological characteristics of oligomeric semiproducts gained via chemical degradation of polyurethane foam using crude glycerin in the presence of different catalysts
PublicationPolyurethane (PU) recycling is a topic of growing interest due to the increasing amount of polyurethane waste. The main purpose of polyurethane chemical recycling is to recover the starting polyol. In this study, a method of polyurethane thermochemical recycling, glycerolysis by means of crude glycerin, is proposed. This work presents a comparative study of commercial catalysts used in order to accelerate the decomposition process,...
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Rare earth ions doped K 2 Ta 2 O 6 photocatalysts with enhanced UV–vis light activity
PublicationNew rare earth-doped K2Ta2O6 photocatalysts were successfully synthesized by hydrothermal method. The effect of dopant type (Y,Yb,Ho,Pr,Er) and amount of rare earth precursor (2,4,8 and 10 mol%) on the physicochemical and photocatalytic properties of RE-K2Ta2O6 have been investigated. All as-prepared materials were characterized by UV–vis diffuse reflectance spectroscopy, Brunauer-Emmett-Teller specific surface area measurement,...
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Rheological properties, oxidative and thermal stability, and potential application of biopolyols prepared via two-step process from crude glycerol
PublicationIn this work, previously synthesized biopolyols were analyzed in terms of their rheological and thermal properties, very important from the technological point of view. For better evaluation of performed synthesis, the influence of its time and temperature on the properties of biopolyols was determined. In the end, obtained materials were used to prepare rigid polyurethane-polyisocyanurate (PUR-PIR) foams, to evaluate their potential...
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Nonlinear harmonic amplitudes in air coils above and below a metal plate as a function of tensile strength via finite element simulation.
PublicationOpisano wyniki obliczeń numerycznych (symulacja metodą MES) wpływu naprężeń na amplitudy nieliniowych harmonicznych napięcia indukowanego w cewkach powietrznych umieszczonych nad i pod płytą.
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Model analityczny budżetu czasu opóźnienia w sieci IP QoS
PublicationPodstawowym celem artykułu jest przedstawienie i przebadanie sposobu podziału opóźnienia end-to-end dla danego strumienia pakietów wzdłuż łączy ścieżki, tak aby wolne zasoby przydzielane były w sposób gwarantujący jakość, a jednocześnie miała miejsce na tej ścieżce maksymalizacja liczby przyjętych do obsługi strumieni pakietów. Proces ten może dotyczyć zarówno łańcucha domen jak i łańcucha łączy. Opisany model LSS oparty jest na...
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Jutro miasta. VI Kongres Urbanistyki Polskiej: Prezentacje – Debaty – Wydarzenia.
PublicationTowarzystwo Urbanistów Polskich, jedno z najstarszych stowarzyszeń urbanistów w Europie, aktywnie działa od 1923 roku jako rzecznik interesu społecznego oraz profesjonalnego w projektowaniu, planowaniu, zagospodarowaniu i użytkowaniu przestrzeni polskich miast, miasteczek i obszarów wiejskich. Od 2003 roku Towarzystwo organizuje co trzy lata Kongresy Urbanistyki Polskiej, które stanowią platformę dyskusji o najważniejszych wyzwaniach,...