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Coffee Wastes as Sustainable Flame Retardants for Polymer Materials
PublikacjaDevelopment of green flame retardants has become a core part of the attention of material scientists and technologists in a paradigm shift from general purpose to specific sustainable products. This work is the first report on the use of coffee biowastes as sustainable flame retardants for epoxy, as a typical highly flammable polymer. We used spent coffee grounds (SCG) as well as SCG chemically modified with phosphorus (P-SCG)...
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Unveiling the Green Mirage: Unearthing Weaknesses in Pro-Environmental Applications
PublikacjaGrowing ecological concerns and a general shift towards tailored digitized solutions in cities lead to an increased popularity of pro ecological applications, especially those associated with transport-oriented functionalities. This research focuses on the results from a testbed of a pro-environmental application deployment among early adopters. Based on quantitative and cartographic analysis enriched with interviews’ results,...
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Advancing Solar Energy: Machine Learning Approaches for Predicting Photovoltaic Power Output
PublikacjaThis research is primarily concentrated on predicting the output of photovoitaic power, an essential field in the study of renewable energy. The paper comprehensively reviews various forecasting methodologies, transitioning from conventional physical and statistical methods to advanced machine learning (ML) techniques. A significant shift has been observed from traditional point forecasting to machine learning-based forecasting...
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Single-Slope ADC With Embedded Convolution Filter for Global-Shutter CMOS Image Sensors
PublikacjaThis brief presents an analog-to-digital converter (ADC) suitable for acquisition and processing of images in the global-shutter mode at the pixel level. The ADC consists of an analog comparator, a multi-directional shift register for the comparator states, and a 16-bit reversible binary counter with programmable step size. It works in the traditional single-slope mode. The novelty is that during each step of the reference ramp,...
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Enhanced Electrochemical Performance of MnCo1.5Fe0.5O4Spinel for Oxygen Evolution Reaction through Heat Treatment
PublikacjaMnCo1.5Fe0.5O4 spinel oxide was synthesized using the sol−gel technique, followed by heat treatment at various temperatures (400, 600, 800, and 1000 °C). The prepared materials were examined as anode electrocatalysts for watersplitting systems in alkaline environments. Solid-state characterization methods, such as powder X-ray diffraction and X-ray absorption spectroscopy (XAS), were used to analyze the materials’ crystallographic...
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Recycled Polyurethane as a Second Phase in Thermoset Blends and Its Effect on Thermal Degradation Kinetics Studies
PublikacjaA new approach is introduced in the modification of thermosetting polymer by using different amount of polyurethane of waste origin. The post consumer polyurethane foam coatings are degraded using glycolysis process and the recycled product is further converted into new polyurethane. The blending of recycled polyurethane with epoxy exhibits transparency and produces nanostructures. The effective interaction between two polymers...
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Fast bubble dynamics and sizing
PublikacjaSingle bubble sizing is usually performed by measuring the resonant bubble response using the Dual Frequency Ultrasound Method. However, in practice, the use of millisecond-duration chirp-like waves yields nonlinear distortions of the bubble oscillations. In comparison with the resonant curve obtained under harmonic excitation, it was observed that the bubble dynamic response shifted by up to 20 percent of the resonant frequency...
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Fiber-optic Fabry-Pérot sensors – modeling versus measurements results
PublikacjaThis paper describes how parameters of investigated substances and the fiber-optic Fabry-Pérot sensing interferometer affect the spectrum of the optical radiation at the output of the sensor. First, the modeling of the operation of the sensing interferometer was conducted. Most important parameters and effects that were taken into account are: dependences of the refractive indices of the core and the cladding, as well the mode...
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High Rise Building: The Mega Sculpture Made Of Steel, Concrete and Glass
PublikacjaHigh rise building has transformed from providing not only the expansion of floor space but functioning as mega sculpture in the city. The shift away from economic efficiency driven need is only expected to grow in the future. Based on literature studies; after analysing planning documents and case studies, it was examined whether the presumption that gaining the maximum amount of usable area is the only driving factor; or if the...
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The CON−H…+NH2 Blue-Shifting H-Bond Stabilizing Effect on Z Secondary Amides and Cyclic System Conformational Rearrangement through an Alkylamine-Chain Migration Pathway
PublikacjaThe paper is focusing on the amide linkage exceptional properties and usage of chemistry (conformational rearrangement, geometrical stereoisomers, spectroscopic blue shift phenomenon, protonation and deprotonation reactions, synthetic scope, and mechanistic implications). Hydrogen-bond-stabilized acylation reactions of a diamine with thioamides or nitriles reveal how substituents influence both the outcome of stereoselectivity...
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Evaluation of excessive noise effects on hearing employing psychoacoustic dosimetry
PublikacjaResearch results regarding the noise impact on hearing applying the concept of the Psychoacoustic Noise Dosimetry (PND) are presented. The general characteristics of the PND algorithm are discussed. Additionally, the results of hearing examinations conducted in the laboratory conditions are shown. The main objective of the research was to determine the time needed for the Temporary Threshold Shift to reverse. The results were used...
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Optical-Fiber Microsphere-Based Temperature Sensors with ZnO ALD Coating—Comparative Study
PublikacjaThis study presents the microsphere-based fiber-optic sensor with the ZnO Atomic Layer Deposition coating thickness of 100 nm and 200 nm for temperature measurements. Metrological properties of the sensor were investigated over the temperature range from 100 °C to 300 °C, with a 10 °C step. The interferometric signal was used to monitor the integrity of the microsphere and its attachment to the connecting fiber. For the sensor...
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Incremental Dynamic Analysis and Fragility Assessment of Buildings with Different Structural Arrangements Experiencing Earthquake-Induced Structural Pounding
PublikacjaStructural pounding is considered as one of the most critical phenomena occurring during earthquakes. This paper presents the incremental dynamic analysis and fragility assessment of buildings experiencing earthquake-induced pounding. Three 3-D buildings with different number of storeys and under different structural arrangements have been considered. Three pounding scenarios have been taken into account, i.e. pounding between...
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One-dimensional chaos in a system with dry friction: analytical approach
PublikacjaWe introduce a new analytical method, which allows to find chaotic regimes in non-smooth dynamical systems. A simple mechanical system consisting of a mass and a dry friction element is considered. The corresponding mathematical model is being studied. We show that the considered dynamical system is a skew product over a piecewise smooth mapping of a segment (the so-called base map). For this base map we demonstrate existence of...
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Designing efficient A-D-A1-D-A type fullerene free acceptor molecules with enhanced power conversion efficiency for solar cell applications
PublikacjaThe achievement of highly efficient power conversion efficiency (PCE) is a big concern for non-fullerene organic solar cells (NF-OSCs) because PCE can depend on numerous variables. Here, new five novel acceptor molecules without fullerenes were developed and investigated using DFT (density functional theory) and TD-DFT (time dependent-density functional theory). Compared to the recently synthesized molecule (PZ-dIDTC6), the developed...
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The bismuth vanadate thin layers modified by cobalt hexacyanocobaltate as visible-light active photoanodes for photoelectrochemical water oxidation
PublikacjaBismuth vanadate thin films deposited using the pulsed laser deposition technique were modified using cobalt hexacyanocobaltate (Cohcc). The 2-step method of Cohcc nanocubes preparation was applied: i) metallic cobalt deposition and ii) cobalt electrooxidation in Co(CN)63− containing electrolyte. The presence of CN stretching vibrations was confirmed by Raman spectroscopy. The energy band gap was equal to 2.5 eV and was estimated...
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Elastic polyurethane foams containing graphene nanoplatelets
PublikacjaElastic polyurethane foams were produced from two-component polyurethane systems (SPECFLEX NE 113 izocyjanian/NR 816 poliol system—SPC and Elastic MBMarket company system POLYOL ET MB 500/ISO ET MB 800—ET) by using a one-step method. The foams were a graphene nanoplatelets (GNP) in the amount ranging from 1 to 2 wt.%. The effect of the nanofiller on polyurethane matrix was determined by analyzing the chemical structure, static...
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Anatomy of noise in quantitative biological Raman spectroscopy
PublikacjaRaman spectroscopy is a fundamental form of molecular spectroscopy that is widely used to investigate structures and properties of molecules using their vibrational transitions. It relies on inelastic scattering of monochromatic laser light irradiating the specimen. After appropriate filtering the scattered light is dispersed onto a detector to determine the shift from the excitation wavelength, which appears in the form of...
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In-situ monitoring of electropolymerization processes at boron-doped diamond electrodes by Mach-Zehnder interferometer
PublikacjaIn this work, the Mach-Zehnder interferometer was designed to monitor the electrochemical processes conducted at boron-doped diamond electrode surface. The diamond electrodes were synthesized via Microwave Plasma-Assisted Chemical Vapor Deposition on optical grade quartz glass. The achieved transmittance in working are of diamond electrodes reached 55 %. A cage system-based Mach-Zehnder interferometer was used which allowed the...
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Multistatyczny, Dopplerowski System określania położenia i prędkości ruchomych celów w wodzie
PublikacjaW omawianym w pracy multistatycznym, dopplerowskim systemie określania położenia i prędkości ruchomych celów w wodzie źródłem sygnału są dwa nadajniki emitujące sinusoidalne, akustyczne fale ciągłe o różnych częstotliwościach, które po odbiciu od ruchomego celu są obierane przez cztery hydrofony. W artykule przedstawiono analize teoretyczna efektu Dopplera, na którym oparte jest działanie systemu oraz metodę rozwiązania głównych...
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Image Segmentation of MRI image for Brain Tumor Detection
Publikacjathis research work presents a new technique for brain tumor detection by the combination of Watershed algorithm with Fuzzy K-means and Fuzzy C-means (KIFCM) clustering. The MATLAB based proposed simulation model is used to improve the computational simplicity, noise sensitivities, and accuracy rate of segmentation, detection and extraction from MR...
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Wykrywanie on-line anomalii w odebranym sygnale PSK za pomocą zespolonej pulsacji chwilowej
PublikacjaJednym z głównych problemów w analizie sygnałów PSK (ang. Phase Shift Keying) jest wykrywanie anomalii występujących w sygnale odebranym. Większość urządzeń stosowanych do analizy sygnałów PSK (np. oscyloskopy cyfrowe, analizatory widma) w celu wykrycia anomalii wykorzystuje algorytm EVM (ang. Error Vector Magnitude) w którym bada się, on-line, różnicę między konstelacją PSK, a skupieniami odebranych symboli zespolonych. W związku...
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T cell Activation Is Driven by an ADP-Dependent Glukosinase Linking Enhanced Glycolysis with Mitochondrial Reactive Oxygen Species Generation
PublikacjaMitochondria-originating reactive oxygen species control T cell receptor (TCR)-induced gene expression. Here, we show that TCR-triggered activation of ADP-dependent glucokinase (ADPGK), an alternative, glycolytic enzyme typical for Archaea, mediates generation of the oxidative signal. We also show that ADPGK is localized in the endoplasmic reticulum and suggest that its active site protrudes toward the cytosol. The ADPGK-driven...
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Multidecadal (1960-2011) shoreline changes in Isbjornhamna (Hornsund, Svalbard)
PublikacjaAsection of a gravel−dominated coast in Isbjørnhamna (Hornsund, Svalbard) was analysed to calculate the rate of shoreline changes and explain processes controlling coastal zone development over last 50 years. Between 1960 and 2011, coastal landscape of Isbjørn− hamna experienced a significant shift from dominated by influence of tide−water glacier and protected by prolonged sea−ice conditions towards storm−affected and rapidly...
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Towards an Understanding of the Stability Assessment of Floating Buildings
PublikacjaOne of the most important aspects of the design of floating facilities such as ships, floating offshore structures or floating houses is stability. Its impact on both general safety and operational aspects renders it a fundamental consideration already in preliminary design stages. Usually, the concept of sufficient stability of floating buildings is associated with the ability to keep an allowed heel angle and residual freeboard,...
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Femtosecond Er-doped fiber laser source tunable from 872 to 1075 nm for two-photon vision studies in humans
PublikacjaWe report the development of a widely-tunable femtosecond fiber laser system and its application for two-photon vision studies. The source is based on an Er-doped fiber laser with spectral shift up to 2150 nm, followed by a second harmonic generation module to generate a frequency-doubled beam tunable from 872 to 1075 nm. The source delivers sub-230 fs pulses with nearly-constant duration over the entire tuning range, with output...
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Model-Based Evaluation of N2O Production Pathways in the Anammox-Enriched Granular Sludge Cultivated in a Sequencing Batch Reactor
PublikacjaA mechanistic model was developed as an extension of the Activated Sludge Model No. 1 to describe three nitrous oxide (N2O) production pathways in a laboratory-scale anammox-enriched granular sequencing batch reactor. Heterotrophic denitrification and two processes mediated by ammonia oxidizing bacteria (AOB), that is, ammonia (NH4+) oxidation via hydroxylamine (NH2OH) and autotrophic denitrification, were considered. A systematic...
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Failure Monitoring and Condition Assessment of Steel-Concrete Adhesive Connection Using Ultrasonic Waves
PublikacjaAdhesive bonding is increasingly being incorporated into civil engineering applications. Recently, the use of structural adhesives in steel-concrete composite systems is of particular interest. The aim of the study is an experimental investigation of the damage assessment of the connection between steel and concrete during mechanical degradation. Nine specimens consisted of a concrete cube and two adhesively bonded steel plates...
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Long-term comparative evaluation of an acoustic climate in selected schools before and after the acoustic treatment
PublikacjaThe results of long-term continuous noise measurements in two selected schools are presented in the paper. Noise characteristics were measured continuously there for approximately 16 months. Measurements started eight months prior to the acoustic treatment of the school corridors of both schools. An evaluation of the acoustic climates in both schools, before and after the acoustic treatment, was performed based on comparison of...
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An Optimized Ka-Band Low Profile Dual-Polarized Transmitarray Antenna With 2D Beam Switching
PublikacjaThis article presents an optimized dual-polarized transmitarray antenna (TA) designed for MIMO applications at the Ka-band, capable of switching beams in two directions. The antenna aperture uses a small unit cell with three layers of Taconic RF-35 dielectric substrates, which can be easily fabricated using PCB technology. The unit cell achieved a 360-degree phase shift and a transmission magnitude exceeding –0.4 dB at 28 GHz....
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Reduction of the Velocity Impact on the Magnetic Flux Leakage Signal
PublikacjaThe velocity effect on the magnetic flux leakage (MFL) signal was investigated in this paper. Experiments were performed for velocity of the MFL tool within the range of 0–2 m/s. The velocity was not constant during each measurement to imitate real operational conditions of the MFL tool. Two components of the leakage were measured, i.e. the tangential to the motion direction (x) and the normal to the investigated surface (z). In...
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Nonlinear finite element modeling of vibration control of plane rod-type structural members with integrated piezoelectric patches
PublikacjaThis paper addresses modeling and finite element analysis of the transient large-amplitude vibration response of thin rod-type structures (e.g., plane curved beams, arches, ring shells) and its control by integrated piezoelectric layers. A geometrically nonlinear finite beam element for the analysis of piezolaminated structures is developed that is based on the Bernoulli hypothesis and the assumptions of small strains and finite...
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Greening Higher Education in Europe. Institutional Transitions to Sustainable Development
PublikacjaThis book provides a comprehensive overview of the advances made in European higher education institutions (HEIs) over the last twenty years in response to the challenges of sustainable development. In recent years, there has been a visible shift toward sustainable development, and universities have been addressing their accountability to the public through corporate social responsibility. Greening Higher Education in Europe explores...
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Spectroscopic and photophysical properties of ZNTPP in a room temperature ionic liquid
PublikacjaThe steady-state absorption and emission spectra and the time-resolved Soret- and Q-band excited fluorescence profiles of the model metalloporphyrin, ZnTPP, have been measured in a highly purified sample of the common room temperature ionic liquid, [bmim][PF(6)]. S(2)-S(0) emission resulting from Soret-band excitation behaves in a manner completely consistent with that of molecular solvents of the same polarizability. The ionic...
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Computer Support of Analysis of Optical Spectra Measurements
PublikacjaThe verification of measurement errors has a big impact on the assessment of the accuracy of conducted measurements and obtained results. In many cases, computer simulation results are compared with measurement results in order to evaluate measurement errors. The purpose of our research was to check the accuracy of measurements made with a Fabry–Perot interferometer working in the transmission mode. In the measurement setup, a...
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A gap waveguide-based mechanically reconfigurable phase shifter for high-power Ku-band applications
PublikacjaThis paper presents a novel design of a low-loss, reconfgurable broadband phase shifter based on groove gap waveguide (GGW) technology. The proposed phase shifter consists of a folded GGW and three bends with a few pins forming the GGW and one bend attached to a movable plate. This movable plate allows for adjustments to the folded waveguide length, consequently altering the phase of electromagnetic waves. The advantage of GGW...
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Tailoring optical constants of few-layer black phosphorus coatings: Spectroscopic ellipsometry approach supported by ab-initio simulation
Publikacja2D black phosphorus (BP) has attracted extensive attention as an anisotropic platform for novel optoelectronic and polarizing optics applications. Insight into the factors that tune the optical and polarizing properties of 2D BP reveals their essential influence on BP-based photonic and optoelectronic devices. In this work, studies of the optical constants of few-layer black phosphorus coatings are studied and discussed, with particular...
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Protective and Suppressing Electromagnetic Interference Properties of Epoxy Coatings Containing Nano-Sized NiZn Ferrites
PublikacjaNano-crystalline ferrites with the chemical formula NixZn(1−x)Fe2O4, where x = 0, 0.2, 0.4, 0.6, 0.8, 1.0, were synthesized using a co-precipitation method. The obtained ferrites were investigated by X-ray diffraction (XRD). The corrosion inhibiting behavior of nano-sized ferrites was tested using carbon steel samples and 10% aqueous ferrite extracts. Results were compared with previous data obtained for micro-sized ceramic ferrites....
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The Undisrupted Growth of the Airbnb Phenomenon between 2014–2020. The Touristification of European Cities before the COVID-19 Outbreak
PublikacjaAs a result of the Airbnb eruption, not only has the character of the short-term rental market been completely transformed, but the decades long growth in tourism has also been further accelerated. Therefore, due to the new demands of the tourism economy, the major shift in the usage of historic city centers occurred–the process of ‘touristification’, that results in the emergence of its new, unsustainable form. Despite the significance...
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Computer support of analysis optical spectra measurements
PublikacjaVerification of measurement errors has a big impact on assessment of accuracy of conducted measurements and obtained results. In many cases computer simulation results are compared with measurement results in order to evaluate measurement errors. The purpose of our research was to check the accuracy of measurements made with Fabry-Perot interferometer working in the transmission mode. In measurement setup, a 1310 nm superluminescent...
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The use and development of e-learning systems in educational projects
PublikacjaThe article introduces the problem of usage and development of e-learning systems among Polish universities. Easily accessible internet and IT development led to changes in education. Through the use of IT tools, e-learning has become an increasingly popular form of education. Presently, majority of Polish universities use an e-learning system of their own choosing designed to support the didactic processes. The goal of the article...
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Influence of Annealing Atmospheres on Photoelectrochemical Activity of TiO2 Nanotubes Modified with AuCu Nanoparticles
PublikacjaIn this article, we studied the annealing process of AuCu layers deposited on TiO2 nanotubes (NTs) conducted in various atmospheres such as air, vacuum, argon, and hydrogen in order to obtain materials active in both visible and UV–vis ranges. The material fabrication route covers the electrochemical anodization of a Ti plate, followed by thin AuCu film magnetron sputtering and further thermal treatment. Scanning electron microscopy...
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The use of fungi in biofiltration to remove hydrophobic volatile organic compounds
PublikacjaThe growing importance placed on air quality by environmental regulations and public opinion necessitate the minimization and removal of volatile organic compound emissions (VOCs), including odours. The removal of hydrophobic VOCs from the air by biological methods remains a major technical challenge (despite its importance in the shift to green engineering). A potential solution to this challenge is the use of fungi in biofiltration....
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Compatibility of Sustainable Mater-Bi/poly(ε-caprolactone)/cellulose Biocomposites as a Function of Filler Modification
PublikacjaDespite their popularity and multiplicity of applications, wood–polymer composites (WPCs) still have to overcome particular issues related to their processing and properties. The main aspect is the compatibility with plant-based materials which affects the overall performance of the material. It can be enhanced by strengthening the interfacial adhesion resulting from physical and/or chemical interactions between the matrix and...
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Elucidating photoluminescent properties of Eu‐doped Ca–Al–Si–O(–N) glasses and the local structures of Eu ions
PublikacjaEuropium (Eu) ion–doped luminescent materials have attracted considerable attention for their numerous optical applications. Eu-doped Ca–Al–Si–O(–N) glasses were synthesized from a mixture of oxynitride glasses and Eu2O3 powder using a standard melt-quenching technique in a radiofrequency furnace. The source Eu trivalent ions primarily changed to Eu2+ during melting, and the ratio of Eu2+ ions increased with an increase in Eu content...
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Overcoming Challenges of Virtual Scrum Teams: Lessons Learned Through an Action Research Study
PublikacjaAfter the COVID-19 breakout, agile teams found themselves in situations that “pure agilists” and textbooks on agile methods had preferred to ignore. Whereas agile mindsets helped them to quickly shift to remote work, mere virtualization of agile practices often proved insufficient, and several challenges emerged. This paper reports on an Action Research project carried out in Lufthansa Systems Poland with the aim of (1) revisiting...
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Synchrotron radiation photoemission spectroscopy of the oxygen modified CrCl3 surface
PublikacjaWe investigate the experimentally challenging CrCl3 surface by photon energy dependent photoemission (PE). The core and valence electrons after cleavage of a single crystal, either in a ultrahigh vacuum (UHV) or in air, are studied by keeping the samples at 150 1C, aiming at confirming the atomic composition with respect to the expected bulk atomic structure. A common spectroscopic denominator revealed by data is the presence of...
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Effect of osmolytes of different type on DNA behavior in aqueous solution. Experimental and theoretical studies
PublikacjaOsmolytes, the small organic molecules accumulated in cells under environmental stress, can modulate the stability of biopolymers such as proteins and DNA. In spite of many years of research, there is no established molecular mechanism of the influence of osmolytes on DNA structure. Here, we used two model osmolytes that denature (urea) or stabilize (trimethylglycine, TMG) proteins to study their effect on DNA in aqueous solutions...
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Curing epoxy with ethylenediaminetetraacetic acid (EDTA) surface-functionalized Co Fe3-O4 magnetic nanoparticles
PublikacjaIn this work, the bulk and surface composition of Fe3O4 supermagnetic nanoparticles were modified for efficient epoxy curing. The bare, ethylenediaminetetraacetic acid (EDTA) capped, and cobalt (Co)-doped EDTA capped Fe3O4 nanoparticles were synthesized electrochemically. The crystalline structure and phase information, surface capping, morphology and magnetization behavior of nanoparticles were studied by X-Ray diffraction (XRD),...
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Assembly of 1D Granular Structures from Sulfonated Polystyrene Microparticles
PublikacjaBeing able to systematically modify the electric properties of nano- and microparticles opens up new possibilities for the bottom-up fabrication of advanced materials such as the fabrication of one-dimensional (1D) colloidal and granular materials. Fabricating 1D structures from individual particles offers plenty of applications ranging from electronic sensors and photovoltaics to artificial flagella for hydrodynamic propulsion....