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Rigid polyurethane foams from a polyglycerol-based polyol
PublikacjaRigid polyurethane foams (rPUs) were synthesized by replacing 35 and 70 wt.% of petrochemical polyol with polyglycerol. Two types of polyglycerol with different molecular weights and hydroxyl numbers were used to obtain new ‘‘green’’ polyurethane–polyglycerol foams. The foams were prepared by a single step method for the ratio of NCO/OH groups equal to 2. rPUs synthesized with polyglycerol showed regular cellular structure, with...
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Structure versus hydrolytic and thermal stability of bio-based thermoplastic polyurethane elastomers composed of hard and soft building blocks with high content of green carbon
PublikacjaNowadays, sustainability plays a key role in the design and synthesis of new materials. One of the methods for the preparation of green materials is incorporation into their structure the monomers with a high content of green carbon. Therefore, the aim of this work was to investigate the influence of the type and molecular mass of two bio-based polyester polyols and bio-glycol on the properties of aliphatic partially bio-based...
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New sample preparation strategies for comprehensive lipidomics of human breast milk
PublikacjaGLOBAL PROFILING ANALYSIS OF HUMAN BREAST MILK (HBM) LIPIDS IS HINDERED BY COMPLEX COMPOSITION OF HBM. THIS PROBLEM IS HUGE FROM ANALYTICAL POINT OF VIEW, SINCE DUE TO THAT DETECTION OF ALL HBM LIPIDS DURING ONE ANALYTICAL RUN IS LIMITED. THUS, SAMPLE PREPARATION STEP CONSTITUTES A CRUCIAL STEP IN UNTARGETED LIPIDOMIC ANALYSIS OF HBM, ESPECIALLY WHEN SEMI-QUANTITATIVE ANALYSIS IS ASSUMED. HEREIN, WE PRESENT A COMPARISON OF PUBLISHED...
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Design of three control algorithms for an averaging tank with variable filing
PublikacjaAn averaging tank with variable filling is a nonlinear multidimensional system and can thus be considered a complex control sys-tem. General control objectives of such object include ensuring stability, zero steady state error and achieving simultaneously shortest possible settling time and minimal overshoot. The main purpose of this research work was the modelling and synthesis of three control systems for an averaging tank. In...
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Green TPUs from Prepolymer Mixtures Designed by Controlling the Chemical Structure of Flexible Segments
PublikacjaThis study concerns green thermoplastic polyurethanes (TPU) obtained by controlling the chemical structure of flexible segments. Two types of bio-based polyether polyols—poly(trimethylene glycol)s—with average molecular weights ca. 1000 and 2700 Da were used (PO3G1000 and PO3G2700, respectively). TPUs were prepared via a two-step method. Hard segments consisted of 4,4?- diphenylmethane diisocyanates and the bio-based 1,4-butanodiol...
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Numerical investigation on dynamic response of a steel lattice tower under various seismic events
PublikacjaThe present paper presents the results of the numerical study designed to investigate the soil-structure flexibility effects on modal parameters (i.e. fundamental frequencies) and time-history analysis response (represented by the top relative displacements) of a 46.8 m high steel lattice tower subjected to a number of ground motions including also one mining tremor. In addition to the fixed-base condition, three different soil...
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Borrelia burgdorferi BmpA-BBK32 and BmpA-BBA64: New Recombinant Chimeric Proteins with Potential Diagnostic Value
PublikacjaCurrently, the diagnosis of Lyme disease is based mostly on two-tiered serologic testing. In the new generation of immunoenzymatic assays, antigens comprise whole-cell lysates of members of the Borrelia burgdorferi sensu lato (s.l.) species complex, with the addition of selected recombinant proteins. Due to the high diversity of members of the B. burgdorferi s.l. genospecies and the low degree of conservation among the amino acid...
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XPS measurements of the iron elements covered by chromium
Dane BadawczeAnticorrosive coatings are an important issue in modern materials engineering. One of the most commonly used, for that coating materials, is chrome. Three metal elements were measured, named as Turcja, WB Tech and Nomet. Names were given according to producer of elements. XPS measurements of the Cr 2p region give an ansver concering on surface chemical...
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A compact seven-section rat-race hybrid coupler incorporating pbg cells
PublikacjaA conventional rat-race coupler has been doubly miniaturized: (i) characteristic impedances and electrical lengths of microstrip sections have been adequately modified as the first step of size reduction and (ii) T-shaped PBG cells have been implemented to diminish strip section length as the second step of circuit rat-race couplerminiaturization. The experimental results show good agreement with theoretical characteristics. Furthermore,...
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Chinese Law Research Guide
PublikacjaA journey of a thousand miles begins with a single step. This Research Guide will be the first step in your journey with Chinese law. China grows more important every day from a global perspective. However, studying and conducting research on Chinese law can be extremely challenging, especially if you do not know Mandarin well. This book is intended as a compact but comprehensive research guide that would provide students (especially...
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Conditions of Best Practice Transfer - Results of the Quick IGA Project
PublikacjaThe Quick IGA project supports the development of working and organizational structures in SMEs in order to increase the employment rate of women and elderly and concurrently increases innovation capacities. One of the main project’s tasks was to find best practices from SMEs in Nordic countries in that field (in the first step) and identify (in second step) possibilities and conditions of their implementation in SMEs in other...
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Physico‐Mechanical Properties and Flammability of PUR/PIR Foams Containing Expandable Graphite Core‐Shell Composite Particles
PublikacjaIn this work, polyurethane/polyisocyanurate (PUR/PIR) foams were modified by two types of expandable graphite (EG) core-shell composite particles. The pulverized EG core-shell composite particles were prepared during emulsion polymerization using methyl methacrylate or glycidyl methacrylate for the synthesis of the polymeric shells (poly(methyl methacrylate) (PMMA) and poly (glycidyl methacrylate) (PGMA)), and then the obtained EG_PMMA...
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The Influence of the Co-Dopant Dexamethasone Phosphate on the Electrodeposition Process and Drug-Release Properties of Polypyrrole-Salicylate on Iron
PublikacjaIn this work, the influence of incorporation of two anti-inflammatory drugs dexamethasone phosphate and sodium salicylate on the electrodeposition process of polypyrrole (PPy) film on iron has been studied. The incorporation of the agents into PPy has been carried out in a one-step electropolymerization process on oxidizable iron. The role of each drug agent during the deposition process has been discussed. The morphological and...
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Hybrid analogues of SFTI-1 modified in P1 position by β- and γ-amino acids and N-substituted β-alanines
PublikacjaA series of compounds containing either non-proteinogenic beta-/gamma-amino acids or N-substituted beta-alanine residues (beta-peptoid units) in P-1 specificity position were synthesized based on the structure of sunflower trypsin inhibitor 1 (SFTI-1). The compounds were synthesized on a solid support; the N-substituted beta-alanines (beta Nhlys and beta Nhphe) were introduced into a peptidomimetic chain via a two-step approach...
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Structure-rheology relationship of fully bio-based linear polyester polyols for polyurethanes - Synthesis and investigation
PublikacjaThe synthesis of polyols from renewable substances as an alternative for petrochemical-based polyols play important matter in the polyurethane industry. In this work, the fully bio-based linear polyester polyols with different catalyst amounts were synthesized via two-step polycondensation method. The effect of various catalyst content on the structure and rheological behavior were established. Fourier Transform Infrared Spectroscopy,...
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Structural changes of a simple peptide—Trpzip-1—in aqueous solutions and the corresponding hydration phenomena under the influence of temperature
PublikacjaTrpzip-1, a simple β-hairpin, is a rare example of peptide with stable secondary structure and can be a convenient model to study temperature-related processes that potential prion or amyloid proteins undergo. Although its sequence is simple, the exact processes which the peptide undergoes in aqueous solutions are quite complex and not well understood. The selection of well-established experimental (DSC, FTIR) and theoretical methods...
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A novel calibration method for RSS-based DoA estimation using ESPAR antennas
PublikacjaIn this paper, we introduce a new calibration method that can successfully be used in direction of arrival (DoA) estimation using electronically steerable parasitic array radiator (ESPAR) antennas and employing power-pattern cross-correlation (PPCC) algorithm, which relies on received signal strength (RSS) values recorded at the antenna output port. Instead of the commonly used two-step approach, during which ESPAR antenna calibration...
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“Dilute & Shoot” approach for rapid determination of trace amounts of nicotine in zero-level e-liquids by reversed phase liquid chromatography and hydrophilic interactions liquid chromatography coupled with tandem mass spectrometry-electrospray ionization
PublikacjaTwo analytical procedures are proposed where HILIC and RPLC techniques are coupled with tandem mass spectrometry detection for rapid determination of trace amounts of nicotine in zero-level liquids for electronic cigarettes. Samples are prepared on the basis of the approach “dilute & shoot” which makes this important step quick and not complicated. The chromatographic separation was carried out on a Zorbax XDB column (RPLC method)...
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Elastic polyurethane foams containing graphene nanoplatelets
PublikacjaElastic polyurethane foams were produced from two-component polyurethane systems (SPECFLEX NE 113 izocyjanian/NR 816 poliol system—SPC and Elastic MBMarket company system POLYOL ET MB 500/ISO ET MB 800—ET) by using a one-step method. The foams were a graphene nanoplatelets (GNP) in the amount ranging from 1 to 2 wt.%. The effect of the nanofiller on polyurethane matrix was determined by analyzing the chemical structure, static...
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Analysis of chiral pharmaceutical residues in influent and effluent samples at racemic and enantiomeric level using liquid chromatography-tandem mass spectrometry
PublikacjaIn this work, two different chromatographic methods for seasonal monitoring of pharmaceutical residue in wastewater samples were developed. In the case of enantiomeric separation of selected compounds, LC-MS technique combining with vancomycin based chiral stationary phase was used. The performance of chiral analysis enabled to monitor the pharmaceutical contamination at the enantiomeric level. The d-SPE procedure was developed...
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MgPd2Sb : A Mg-based Heusler-type superconductor
PublikacjaWe report the synthesis and physical properties of a full Heusler compound, MgPd2Sb, which we found toshow superconductivity belowTc=2.2K. MgPd2Sb was obtained by a two-step solid-state reaction methodand its purity and cubic crystal structure [Fm-3m,a=6.4523(1) Å] were confirmed by powder x-ray diffrac-tion. Normal and superconducting states were studied by electrical resistivity, magnetic susceptibility, andheat...
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A new cold-adapted beta-D-galactosidase from the Antarctic Arthrobacter sp. 32c - gene cloning, overexpression, purification and properties
PublikacjaThe development of a new cold-active β-D-galactosidases and microorganisms that efficiently ferment lactose is of high biotechnological interest, particularly for lactose removal in milk and dairy products at low temperatures and for cheese whey bioremediation processes with simultaneous bio-ethanol production. In this article, we present a new β-D-galactosidase as a candidate to be applied in the above mentioned biotechnological...
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Long range molecular dynamics study of regulation of eukaryotic glucosamine-6-phosphate synthase activity by UDP-GlcNAc
PublikacjaGlucosamine-6-phosphate (GlcN-6-P) synthase catalyses the first and practically irreversible step in hexosamine metabolism. The final product of this pathway, uridine 5' diphospho N-acetyl-D-glucosamine (UDPGlcNAc), is an essential substrate for assembly of bacterialand fungal cell walls. Moreover, the enzyme is involved in phenomenon of hexosamine induced insulin resistance in type II diabetes, which makes it a potential target...
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Janusz Kozak prof. dr hab. inż.
OsobyDr hab. inż. Janusz Kozak Dziekan Wydziału Oceanotechniki i Okrętownictwa Politechniki Gdańskiej Urodzony: 04.07.1953 w Pucku Absolwent Technikum Budowy Okrętów „Conradinum” w Gdańsku, 1973. Absolwent Instytutu Okrętowego PG, 1978. Po ukończeniu studiów praca w Stoczni Gdynia, a od roku 1980 w Katedrze Technologii Okrętów Instytutu Okrętowego a później Wydziału Oceanotechniki i Okrętownictwa Politechniki Gdańskiej kolejno na...
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Structure-Property Relationship and Multiple Processing Studies of Novel Bio-Based Thermoplastic Polyurethane Elastomers
PublikacjaCurrently, the growing demand for polymeric materials has led to an increased need to develop effective recycling methods. This study focuses on the multiple processing of bio-based thermoplastic polyurethane elastomers (bio-TPUs) as a sustainable approach for polymeric waste management through mechanical recycling. The main objective is to investigate the influence of two reprocessing cycles on selected properties of bio-TPUs....
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Street Art and Urban Regeneration. Case Study Gdansk and Rome.
PublikacjaStreet art plays an important role in urban planning as a transforming engine to regenerate the public spaces and in the processes of participation. The article analyzes two main topics. The first one focuses on the urban serving as a support for spatial and cultural strategies in urban redevelopment projects. The second one is related to the potential of micro urban interventions as a strategy for a wider involvement of inhabitants...
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Kinetics of cyclohexane removal by Candida subhashii and Fusarium solani
Dane BadawczeDataset presents cyclohexane biodegradation in gas phase using two species of microorganisms: Candida Subhashii and Fusarium solani. Biodegradation was carried out in sealed chambers with a capacity of 1000 ml. In each of them there are two discs inhabited with microorganisms, made of polyurethane foam, 80 mm in diameter and 20 mm thick.
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TOWARDS EXPLAINABLE CLASSIFIERS USING THE COUNTERFACTUAL APPROACH - GLOBAL EXPLANATIONS FOR DISCOVERING BIAS IN DATA
PublikacjaThe paper proposes summarized attribution-based post-hoc explanations for the detection and identification of bias in data. A global explanation is proposed, and a step-by-step framework on how to detect and test bias is introduced. Since removing unwanted bias is often a complicated and tremendous task, it is automatically inserted, instead. Then, the bias is evaluated with the proposed counterfactual approach. The obtained results...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=2.4, b=0.26) and (C=6.2, b=0.38) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=2.0, b=0.11) and (C=7.3, b=0.49) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=2.4, b=0.26) and (C=7.3, b=0.49) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=2.4, b=0.26) and (C=3.3, b=0.40) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=2.0, b=0.11) and (C=6.4, b=0.45) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=5.5, b=0.37) and (C=7.3, b=0.49) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=2.0, b=0.11) and (C=3.3, b=0.40) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=5.5, b=0.37) and (C=6.2, b=0.38) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=2.0, b=0.11) and (C=6.2, b=0.38) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=5.5, b=0.37) and (C=3.3, b=0.40) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=5.5, b=0.37) and (C=6.4, b=0.45) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a serial connection of two pneumatic elements with (C=2.4, b=0.26) and (C=6.4, b=0.45) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of serial connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in-line. Four test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a parallel connection of two pneumatic elements with (C=2.10, b=0.14) and (C=6.40, b=0.45) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of parallel connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in parallel. Three test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a parallel connection of two pneumatic elements with (C=2.80, b=0.25) and (C=6.40, b=0.45) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of parallel connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in parallel. Three test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a parallel connection of two pneumatic elements with (C=2.10, b=0.14) and (C=7.30, b=0.49) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of parallel connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in parallel. Three test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a parallel connection of two pneumatic elements with (C=5.50, b=0.37) and (C=6.40, b=0.45) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of parallel connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in parallel. Three test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a parallel connection of two pneumatic elements with (C=2.80, b=0.25) and (C=3.30, b=0.40) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of parallel connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in parallel. Three test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a parallel connection of two pneumatic elements with (C=2.00, b=0.11) and (C=6.20, b=0.38) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of parallel connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in parallel. Three test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a parallel connection of two pneumatic elements with (C=2.00, b=0.11) and (C=7.30, b=0.49) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of parallel connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in parallel. Three test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a parallel connection of two pneumatic elements with (C=5.50, b=0.37) and (C=6.20, b=0.38) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of parallel connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in parallel. Three test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a parallel connection of two pneumatic elements with (C=2.10, b=0.14) and (C=6.20, b=0.38) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of parallel connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in parallel. Three test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...
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Determination of flow properties of a parallel connection of two pneumatic elements with (C=2.00, b=0.11) and (C=3.30, b=0.40) from changes in air pressure in a tank being emptied
Dane BadawczeThe aim of the study was to determine the flow properties of parallel connection of pneumatic components.The experiments were to measure the pressure changes in a being emptied tank for a directional control valve and a pressure relief valve arranged in parallel. Three test configurations were used: (1) being emptied tank -> DCV -> ambient atmosphere,...