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Partial inhibition of borohydride hydrolysis using porous activated carbon as an effective method to improve the electrocatalytic activity of the DBFC anode
PublikacjaCarbon materials are commonly used catalyst supports in various types of fuel cells. Due to the possibility of designing their properties, they seem to be attractive and functional additives. In Direct Borohydride Fuel Cells (DBFCs), the electrooxidation reaction of borohydride competes with the undesirable hydrolysis reaction, therefore our work aimed to modify anodes based on a multi-component hydrogen storage alloy with a small...
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Distillery Fusel Oil as an Alternative Carbon Source for Denitrification – from Laboratory Experiments to Full-Scale Applications
PublikacjaIndustrial waste products may be a viable alternative to commercial external carbon sources, such as ethanol. In this study, the properties of fusel oil (distillery waste product) were investigated in terms of temperature dependency of denitrification, acclimation period, and the effects on NO2-N and PO4-P behavior. Furthermore, results obtained during three different full-scale trials were used to verify similarities and differences...
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The influence of feed rate and shear forces on the devulcanization process of ground tire rubber (GTR) conducted in a co-rotating twin screw extruder
PublikacjaThe search for new ways to recycling of rubber waste has been the aim of many studies conducted by research centers and companiesworldwide. The results of our investigations on the process of continuous thermomechanical devulcanization of ground tire rubber using a twin screw extruder are presented.We used a co-rotating twin screw extruder with a special configuration of plasticizing unit, enabling generation of considerable shear...
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A significance of multi slip condition for inclined MHD nano-fluid flow with non linear thermal radiations, Dufuor and Sorrot, and chemically reactive bio-convection effect
PublikacjaThe aim of this research is to discuss the significance of slip conditions for magnetized nanofluid flow with the impact of nonlinear thermal radiations, activation energy, inclined MHD, sorrot and dufour, and gyrotactic micro motile organisms over continuous stretching of a two-dimensional sheet. The governing equations emerge in the form of partial differential equations. Since the resultant governing differential equations...
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Cyclic Behavior of Masonry Shear Walls Retrofitted with Engineered Cementitious Composite and Pseudoelastic Shape Memory Alloy
PublikacjaThe behavior of masonry shear walls reinforced with pseudoelastic Ni–Ti shape memory alloy (SMA) strips and engineered cementitious composite (ECC) sheets is the main focus of this paper. The walls were subjected to quasi-static cyclic in-plane loads and evaluated by using Abaqus. Eight cases of strengthening of masonry walls were investigated. Three masonry walls were strengthened with different thicknesses of ECC sheets using...
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Photolysis for the Removal and Transformation of Pesticide Residues During Food Processing: A State-of-the-Art Minireview
PublikacjaPesticide residues are of great significant issue that exerted adverse effects on humans. There is a need for effective and non-toxic decontamination of pesticide residues during food processing. In this minireview, the recent advances in the degradation of pesticide residues by photolysis have been firstly described during food processing. The mechanisms of pesticide residues destruction by photolysis were discussed accordingly....
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Identification of pollutants at the adjacent areas to the landfill site using two dimensional gas chromatography with mass spectrometry technique
PublikacjaMunicipal landfills are considered one of the main sources of air pollutants. In this article is presented the use of a modern analytical technique: a two dimensional gas chromatography to identify the substances in the atmospheric air near a waste processing plant located in Gdansk. In order to determine the types of substances occurring in different atmospheric conditions, the study was conducted from February to April 2016....
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Mechanical Recycling via Regrinding, Rebonding, Adhesive Pressing, and Molding
PublikacjaIncreasing amount of polyurethane foams waste (e.g. from the building or furniture industry) produced every year resulted in the intensive development of their recycling methods. This chapter covers most important mechanical recycling methods, i.e. regrinding, rebonding, adhesive pressing, and molding. The procedure, required equipment and chemicals (if needed) for each method were described. The possible applications of the products...
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Characteristic and specificity of protease activity of thermophilic bacteria Meiothermus ruber
PublikacjaThe primary purpose of research was to establish the possibility of using thermophilic bacteria Meiothermus ruber as a source of proteolytic enzymes. The main reason of searching new proteases is their commercial value especially in production of detergents, food, pharmaceuticals, leather, diagnostics or waste management. The development of this type processes will be possible by utilization of enzymes which have unique characteristics...
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FATE OF LAS SURFACT ANTS IN WWTPs BASED ON MEASURED CONCENTRATIONS IN WASTEWATER AND SLUDGE
PublikacjaThe fate of the surfactant LAS in the two different types of Waste Water Treatment Plants has been reviewed: the small “Swarzewo” WWTP (45 000 PE), and large WWTP “Wschód” (760 000 PE). The elimination of LAS from the water stream in Swarzewo (98,7%), is better than that found in Gdańsk (97,6%). In the sludge treatment course, the reduction of LAS in Swarzewo is greater than that in Gdańsk due to the greater biodegradation of LAS...
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Screen-printed Sn-doped TiO2 nanoparticles for photocatalytic dye removal from wastewater: A technological perspective
PublikacjaTiO2 is widely used as a photocatalyst with a wide band gap, which limited its application. Ion doping and formulating a high-quality screen-printing paste enhance its features. However, the printability of objects for advanced application seems essential nowadays. In this research, the Sn-doped TiO2 nanoparticles were prepared through a sol-gel method followed by calcination at various temperatures of 450 °C, 550 °C, 650 °C, 750...
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Assessment of the application of CEM III with exposed aggregate as an alternative to CEM I for road pavements
PublikacjaThe article presents a results of study on the impact of replacing CEM I SR3/NA by CEMIII/A LH/HSR/NAon the mechanical properties and durability of pavement concrete with exposed aggregate. Was used granite aggregate and washed sand. Water/cement () ratio in the tested concretes constituted 0.35 and 0.4 and part of the cement was replaced with a 5% addition of natural pozzolana – zeolite. Compressive strength tests were performed...
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Structure and performance properties of environmentally-friendly biocomposites based on poly(ɛ-caprolactone) modified with copper slag and shale drill cuttings wastes
PublikacjaThe potential application of two types of industrial wastes, drill cuttings (DC) and copper slag (CS), as silica-rich modifiers of poly(ɛ-caprolactone) (PCL) was investigated. Chemical structure and physical properties of DC and CS fillers were characterized using X-ray diffractometer, X-ray fluorescence spectroscopy, particle size and density measurements. PCL/DC and PCL/CS composites with a variable content of filler (5 to 50...
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Comparative analysis of thermodynamic cycles of selected nuclear ship power plants with high-temperature helium-cooled nuclear reactor
PublikacjaThis paper presents a comparative analysis of thermodynamic cycles of two ship power plant systems with a high-temperature helium- cooled nuclear reactor. The first of them is a gas system with recuperator , in which classical gas chamber is substituted for a HTGR reactor (High Temperature Gas-cooled Reactor) . The second of the considered cycles is a combined gas-steam system where working medium flux from gas turbine outlet...
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Distillery Fusel Oil as an Alternative Carbon Source for Denitrification – from Laboratory Experiments to Full-Scale Applications
PublikacjaIndustrial waste products may be a viable alternative to commercial external carbon sources. In this study, the properties of fusel oil (distillery waste product) were investigated in terms of temperature dependency of denitrification and acclimation period. Furthermore, results obtained during three different full-scale trials were used to verify similarities and differences with the results obtained under laboratory-scale conditions....
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A new strategy for PET depolymerization: Application of bimetallic MOF-74 as a selective catalyst
PublikacjaLarge-volume production of poly(ethylene terephthalate) (PET), especially in the form of bottles and food packaging containers, causes problems with polymer waste management. Waste PET could be recycled thermally, mechanically or chemically and the last method allows to obtain individual monomers, but most often it is carried out in the presence of homogeneous catalysts, that are difficult to separate and reuse. In view of this,...
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ZRÓŻNICOWANIE STRUKTURY KAPITAŁOWO-MAJĄTKOWEJ W ZALEŻNOŚCI OD WIELKOŚCI PRZEDSIĘBIORSTWA
PublikacjaW artykule przedstawiono różnice w kształtowaniu struktury kapitałowo-majątkowej pomiędzy małymi, średnimi i dużymi przedsiębiorstwami. W trakcie przeprowadzonych badań uwzględniono 97 471 sprawozdań finansowych przedsiębiorstw, prowadzących działalność gospodarczą w 12 różnych działach polskiej gospodarki narodowej. Do potwierdzenia zróżnicowania struktury kapitałowo-majątkowej w zależności od wielkości przedsiębiorstwa wykorzystano...
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Critical review of electronic nose and tongue instruments prospects in pharmaceutical analysis
PublikacjaElectronic nose (enose, EN) and electronic tongue (etongue, ET) have been designed to simulate human senses of smell and taste in the best possible way. The signals acquired from a sensor array, combined with suitable data analysis system, are the basis for holistic analysis of samples. The efficiency of these instruments, regarding classification, discrimination, detection, monitoring and analytics of samples in different types...
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Detection of Denatonium Benzoate (Bitrex) Remnants in Noncommercial Alcoholic Beverages by Raman Spectroscopy
PublikacjaIllegal alcoholic beverages are often introduced into market using cheap technical alcohol, which is contaminated by denatonium benzoate (Bitrex) of very small concentration. Bitrex is the most bitter chemical compound and has to be removed before alcohol consumption. The home-made methods utilize sodium hypochlorite to disintegrate particles of denatonium benzoate in alcohol and to remove bitter taste before trading. In this experimental...
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"Numeryczna symulacja pracy gazowego kotła wodnego raz ocena jego wpływu na środowisko"
PublikacjaIlość dostarczanego powietrza oraz rozkład jego koncentracji w komorze paleniskowej mają istotny wpływ na prawidłowość przebiegu procesu spalania. Uzyskanie jednorodnego rozkładu jest praktycznie niemożliwe, dlatego powietrze dostarczane jest w nadmiarze. Konieczne jest jednak dobranie takiej wartości współczynnika nadmiaru powietrza, która pozwoli ograniczyć stratę wylotową, utrzymując przy tym wartości emisji na możliwie niskim...
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"Numeryczna symulacja pracy gazowego kotła wodnego oraz ocena jego wpływu na środowisko"
PublikacjaIlość dostarczanego powietrza oraz rozkład jego koncentracji w komorze paleniskowej mają istotny wpływ na prawidłowość przebiegu procesu spalania. Uzyskanie jednorodnego rozkładu jest praktycznie niemożliwe, dlatego powietrze dostarczane jest w nadmiarze. Konieczne jest jednak dobranie takiej wartości współczynnika nadmiaru powietrza, która pozwoli ograniczyć stratę wylotową, utrzymując przy tym wartości emisji na możliwie niskim...
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Numeryczna symulacja pracy gazowego kotła wodnego oraz ocena jego wpływu na środowisko
PublikacjaIlość dostarczanego powietrza oraz rozkład jego koncentracji w komorze paleniskowej mają istotny wpływ na prawidłowość przebiegu procesu spalania. Uzyskanie jednorodnego rozkładu jest praktycznie niemożliwe, dlatego powietrze dostarczane jest w nadmiarze. Konieczne jest jednak dobranie takiej wartości współczynnika nadmiaru powietrza, która pozwoli ograniczyć stratę wylotową, utrzymując przy tym wartości emisji na możliwie niskim...
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Kluczowe zagadnienia procesu recyklingu zużytych modułów fotowoltaicznych I i II generacji
PublikacjaW ramach technologii fotowoltaicznych wyróżniamy obecnie trzy generacje ogniw fotowoltaicznych. Pierwsza z nich to ogniwa z mono- i polikrystalicznego krzemu (c-Si), druga obejmuje ogniwa wykonane na bazie technologii cienkowarstwowej, zarówno z krzemu amorficznego (a-Si) jak i diseleneku indowo-miedziowo-galowego (CIGS), tellurku kadmu (CdTe) oraz arsenku galu (GaAs). Trzecia generacja to najnowsze technologie, takie jak: organiczne...
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Analysis of the Factors Affecting Static In Vitro Pepsinolysis of Food Proteins
PublikacjaIn this meta-analysis, we collected 58 publications spanning the last seven decades that reported static in vitro protein gastric digestion results. A number of descriptors of the pepsinolysis process were extracted, including protein type; pepsin activity and concentration; protein concentration; pH; additives; protein form (e.g., ‘native’, ‘emulsion’, ‘gel’, etc.); molecular weight of the protein; treatment; temperature; and...
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Combination of air-dispersion cathode with sacrificial iron anode generating Fe2+Fe3+2O4 nanostructures to degrade paracetamol under ultrasonic irradiation
PublikacjaIn the present study, ultrasound (US) was coupled with an electrochemical process (ECP) consisting of a novel cathode of carbon cloth (CC)-carbon black (CB) as the nano-composite air-dispersion cathode (NADC) for the degradation of paracetamol (APAP) in an aquatic medium. The NADC favored in situ production of H2O2 by the cathodic reduction. The implementation of iron sacrificial anode instead of dimensionally stable anodes resulted...
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Injectable poloxamer/graphene oxide hydrogels with well‐controlled mechanical and rheological properties
PublikacjaAlthough significant progress has been made in the design and application of injectable hydrogels for biomedical applications, concurrent control of rheological and mechanical properties of injectable hydrogels has remained as an open challenge to the researchers. In this work, we introduce and put into practice a photo‐curable poloxamer (also known as Pluronic)/graphene oxide (Plu/GO) injectable hydrogel with well‐controlled rheological...
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Microwave-assisted synthesis of a TiO2-CuO heterojunction with enhanced photocatalytic activity against tetracycline
PublikacjaA microwave method was used for the synthesis of TiO2-CuO oxide systems. A detailed investigation was made of the effect of the molar ratio of components (TiO2:CuO=9:1, 7:3, 5:5, 3:7, 1:9) on the crystalline structure and morphology. Transmission electron microscopy (TEM) confirmed the presence of octahedral and rod-shaped titania particles and sheet copper(II) oxide particles; moreover, HRTEM analysis indicated the presence of...
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Dimeric structure of the N-terminal domain of PriB protein from Thermoanaerobacter tengcongensis solved ab initio
PublikacjaPriB is one of the components of the bacterial primosome, which catalyzes the reactivation of stalled replication forks at sites of DNA damage. The N-terminal domain of the PriB protein from the thermophilic bacterium Thermoanaerobacter tengcongensis (TtePriB) was expressed and its crystal structure was solved at the atomic resolution of 1.09 Å by direct methods. The protein chain, which encompasses the first 104 residues of the...
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Ordered titanium templates functionalized by gold films for biosensing applications – Towards non-enzymatic glucose detection
PublikacjaRecently, metal nanostructures evoke much interest due to application potential in highly sensitive detectors in biochemistry and medical diagnostics. In this work we report on preparation and characteristics of thin (1–100 nm) Au films deposited onto highly ordered structured titanium templates for SERS (Surface Enhanced Raman Spectroscopy) and electrochemical sensing. The Ti templates are formed by selective removal of TiO2 nanotubes...
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Flexible dye-sensitized solar cells based on Ti/TiO2 nanotubes photoanode and Pt-free and TCO-free counter electrode system
PublikacjaFlexible dye-sensitized solar cells (DSSCs) are getting more attention compared to standard glass covered DSSCs due to their unique commercial applications (e.g. tents or sail surfaces) and the possibility of rolling up into a small, portable device. In this work, titania nanotubes (TiO2 NT) modified with titania nanoparticles (TiO2 NP) were photoelectrochemically characterized as an anode for flexible dye-sensitized solar cells....
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A universal NDT method for examination of low energy impact damage in CFRP with the use of TLC film
PublikacjaThe article presents an attempt to use a sheet of laminated thermochromic liquid crystal film (TLC film) for non-destructive testing of the impact damage (energy values: 1J, 2J, 3J and 4J) in carbon fibre-reinforced polymer (CFRP). This is a new, alternative NDT approach based on the thermo-optical effect. The main advantages of this method are a) the low cost of TLC film, b) the low cost of recording devices due to the usage of...
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Experimental research on helical coil biomass boiler with oil as a heating fluid
PublikacjaThis paper presents an experimental research of helical coil biomass boiler with thermal oil heating agent. Heat exchanger consists of two coaxial helical coils swept by the flue gases. The burner is a single vertical retort connected to the fuel tank (wooden pellets). The boiler is a part of micro-power plant in which the heat from the boiler is exchanged with low-boiling HFE7100 to produce steam for a custom steam turbine. The...
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Polymers for burn dressings and skin substitutes
PublikacjaSkin burns belong to the group of the most complex injuries due to convoluted skin structure which includes nerve cells, muscles, sweat and sebaceous glands and blood vessels. Both on the market and at the research stage, there are many different dressing and skin substitutes proposals that utilize various materials and active substances. This chapter focuses on summarizing and describing the most popular polymer-based commercial...
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Modifications to the anaerobic digestion model no. 1 (ADM1) for enhanced understanding and application of the anaerobic treatment processes – A comprehensive review
PublikacjaAnaerobic digestion (AD) is a promising method for the recovery of resources and energy from organic wastes. Correspondingly, AD modelling has also been developed in recent years. The International Water Association (IWA) Anaerobic Digestion Model No. 1 (ADM1) is currently the most commonly used structured AD model. However, as substrates become more complex and our understanding of the AD mechanism grows, both systematic and specific...
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Effect of Chitosan Solution on Low-Cohesive Soil’s Shear Modulus G Determined through Resonant Column and Torsional Shearing Tests
PublikacjaIn this study the effect of using a biopolymer soil stabilizer on soil stiffness characteristics was investigated. Chitosan is a bio-waste material that is obtained by chemical treatment of chitin (a chemical component of fungi or crustaceans’ shells). Using chitosan solution as a soil stabilizer is based on the assumption that the biopolymer forms temporary bonds with soil particles. What is important is that these bonds are biodegradable,...
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Knowledge sharing and knowledge hiding in light of the mistakes acceptance component of learning culture- knowledge culture and human capital implications
PublikacjaPurpose: This study examines the micromechanisms of how knowledge culture fosters human capital development. Method: An empirical model was developed using the structural equation modeling method (SEM) based on a sample of 321 Polish knowledge workers employed in different industries. Findings: This study provides direct empirical evidence that tacit knowledge sharing supports human capital, whereas tacit knowledge hiding does...
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Synthesis and characterization of biopolyols through biomass liquefaction of wood shavings and their application in the preparation of polyurethane wood composites
PublikacjaThe sustainability of production systems in wood processing, wood industry, and wooden waste disposal is an important issue for European industry and society. Proper development of products based on renewable wood resources gives an opportunity to provide materials with long-term environmental, social, and economic sustainability. This study aims to establish a new way of forestry and agricultural waste materials utilization by...
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Influence of Phosphorus Speciation on Its Chemical Removal from Reject Water from Dewatering of Municipal Sewage Sludge
PublikacjaThe aim of the presented research was the assessment of phosphorus speciation impact on the precipitation of phosphorus in reject water using Ca(OH)2. To achieve this, phosphorus speciation (organic and inorganic phosphorus in suspension and in dissolved form) in reject water that is produced during sludge dewatering, after methane digestion in wastewater treatment plants (WWTPs), was determined. This study covered the materials...
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Distillery Wastes as External Carbon Sources for Denitrification in Municipal Wastewater Treatment Plants
PublikacjaIn order to improve efficiency of N removal within the existing capacities, the denitrification process can be enhanced by adding external carbon sources. The studies on utilization of various by-products or waste materials as alternative carbon sources for denitrification have been carried out for over 20 years (Sage et al. 2006). Among several commercially available organic compounds (such as methanol, ethanol, acetic acid, glucose),...
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Thermal utilization of meat and bone meals. Performance analysis in terms of drying process, pyrolysis and kinetics of volatiles combustion
PublikacjaA development of technology of thermal utilization requires a thorough knowledge of the physicochemical properties, as well as kinetics of combustion of volatiles and char. Due to waste management regulations the meat and bone meal (MBM) is regarded as biofuel constituting one of the alternatives to fossil fuels in the energy market. MBM is a heterogeneous material that may consist of several different fractions. The extensive...
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Pyrolysis of Pruning Residues from Various Types of Orchards and Pretreatment for Energetic Use of Biochar
PublikacjaThe routine pruning and cutting of fruit trees provides a considerable amount of biowaste each year. This lignocellulosic biomass, mainly in the form of branches, trunks, rootstocks, and leaves, is a potential high-quality fuel, yet often is treated as waste. The results of a feasibility study on biochar production by pyrolysis of residues from orchard pruning were presented. Three types of biomass waste were selected as raw materials...
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First evaluation of wastewater discharge influence on marine water contamination in the vicinity of Arctowski Station (Maritime Antarctica)
PublikacjaIn Antarctica,waste is generatedmainly during scientific research programmes and related logistics. In this study, the impact ofwastewater on the western shore of Admiralty Baywas investigated during austral summer in 2017 and 2019. A range of physicochemical parameters and the presence of selected trace metals, formaldehyde and different groups of surfactants were determined in wastewater coming from Arctowski Station and in nearby coastal...
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“Shadow” vs. “Phase 3D” method within endoscopic examinations of marine engines
PublikacjaA visual investigation of surfaces creating internal, working spaces of marine combustion engines by means of specialized view-finders so called endoscopes is at present almost a basic method of technical diag-nostics. The surface structure of constructional material is visible during investigations like through the magnifying glass (usually with a precisely determined magnification), which makes possible a detection, recognition...
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Oxygen concentration regulated the efficient liquefaction of vulcanized natural rubber
PublikacjaOxidative liquefaction represents a promising avenue for the homogeneous and high-value utilization of waste tire rubber. Given that truck tires predominantly comprise natural rubber (NR), this study investigated the efficient liquefaction of vulcanized NR regulated by oxygen concentration. Remarkably, the liquefaction of vulcanized NR was realized with an oxygen concentration of 75 % at 200 °C within 3 min. FTIR spectroscopy showed...
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The 12 principles of green analytical chemistry and the SIGNIFICANCE mnemonic of green analytical practices
PublikacjaThe current rapid development of green analytical chemistry (GAC) requires clear, concise guidelines in the form of GAC principles that will be helpful in greening laboratory practices. The existing principles of green chemistry and green engineering need revision for their use in GAC because they do not fully meet the needs of analytical chemistry. In this article we propose a set of 12 principles consisting of known concepts...
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Biodegradable polymer packaging materials - influence on environment
PublikacjaAwareness of the waste problem and its impact on the environment has awakened new interest in the area of biodegradable polymers. Biodegradation of various polymers have been studied under diverse environments like in soil, in sewage sludge, in compost conditions and in sea water by different research groups. The aim of this paper is to present the research methods on the biodegradation of the commercially available biodegradable...
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A Flexible Nafion Coated Enzyme‐free Glucose Sensor Based on Au‐dimpled Ti Structures
PublikacjaThe detection of glucose at low concentrations using electrochemical sensors is of great importance due to the possibility of using different human body fluids than blood, such as e.g. urine, saliva, sweat or tears. The interest behind those biofluids is related to their utility in non-invasive sugar determination. In this work, we present flexible, fully biocompatible electrode material based on Au nanoparticles immobilized onto...
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Material Parameters Identification of Historic Lighthouse Based on Operational Modal Analysis
PublikacjaIn the present paper, the identification of the material parameters of a masonry lighthouse is discussed. A fully non-invasive method was selected, in which the material properties were determined via numerical model validation applied to the first pair of natural frequencies and their related mode shapes, determined experimentally. The exact structural model was built by means of the finite element method. To obtain experimental...
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Badania eksperymentalne i numeryczne zachowania się zbiorników stalowych poddanych wstrząsom górniczym i sejsmicznym
PublikacjaW niniejszej dysertacji opisano wyniki kompleksowych badań zachowania się zbiorników stalowych poddanych wstrząsom górniczym i umiarkowanym trzęsieniom ziemi. Badania prowadzono dla dwóch zbiorników rzeczywistych zlokalizowanych na terenie Polski. W pierwszym etapie badań przeprowadzono badania eksperymentalne na specjalnym stanowisku laboratoryjnym dla modeli doświadczalnych zbiorników. Badania prowadzono dla różnego poziomu wypełnienia...
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Analysing By-Products Interaction as an Industry Resource of Circular Economy in Ukraine and the World
PublikacjaThe paper analyses existing and current scientific developments and literature sources, which show the advantages and disadvantages of many different influences of waste in Ukraine and other countries of Europe and the world. As a research result, stable connections have been established between the factors and criteria in assessing the by-product interaction as an industry resource. In our research, we used programs R.Studio and...