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Mechanical properties of PVDF-coated fabric under tensile tests
PublikacjaThis article describes the laboratory tests necessary to identify the mechanical properties of the polyvinylidene fluoride (PVDF)-coated fabrics named Precontraint 1202S and Precontraint 1302S. First, a short survey of the literature concerning the description of coated woven fabrics is presented. Second, the material parameters for PVDF-coated fabrics are specified on the basis of biaxial tensile tests. A comparison of the 1:1...
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Curing characteristics, mechanical and thermal properties of reclaimed ground tire rubber cured with various vulcanizing systems
PublikacjaGround tire rubber was thermo-mechanical reclaimed at 120 °C using a co-rotating twin screw extruder. The effect of vulcanizing system type on curing characteristics, static mechanical properties (tensile strength, elongation-at-break, hardness and resilience), dynamic mechanical properties and thermal properties of reclaimed ground tire rubber was investigated. Reclaimed rubber was cured using different types of vulcanization...
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Nonlinear viscoelasticity in Three Dimensional filler reinforced rubber composites and nanocomposites
PublikacjaThis chapter describes the influence of three-dimensional nanofillers used in elastomers on the nonlinear viscoelastic properties. In particular, this part focuses and investigates the most important three-dimensional nanoparticles, which are used to produce rubber nanocomposites. The rheological and the dynamic mechanical properties of elastomeric polymers, reinforced with spherical nanoparticles, like POSS, titanium dioxide and...
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Degradation of polyurethanes in sea water
PublikacjaOceniono degradowalność różnych poliuretanów w wodzie morskiej Bałtyku. Porównano te dane z wynikami stopnia degradacji poliuretanów w wodzie morskiej z dodatkiem azydku sosowego. Ocenę stopnia degradacji przeprowadzano na podstawie pomiarów zmian masy, właściwości mechanicznych i morfologii przed i po procesie degradacji. Wykazano, że różna podatność na degradację poliuretanów w wodzie morskiej związana jest z ich odmiennym stopniem...
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Microwave treatment in waste rubber recycling – recent advances and limitations
PublikacjaEnvironmentally-friendly microwave heating is increasingly used in polymer chemistry and technology. The selectivity and highly efficiency in the heat transfer present a huge advantage in systems based on recycling, improving their productivity and economic competitiveness. In case of the industrial recycling of waste rubbers, especially end-of-life tires, microwave-induced devulcanization and pyrolysis are nowadays considered...
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Clickable polysaccharides for biomedical applications: A comprehensive review
PublikacjaRecent advances in materials science and engineering highlight the importance of designing sophisticated biomaterials with well-defined architectures and tunable properties for emerging biomedical applications. Click chemistry, a powerful method allowing specific and controllable bioorthogonal reactions, has revolutionized our ability to make complex molecular structures with a high level of specificity, selectivity, and yield...
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Thermal degradation of polylactic acid (PLA)/polyhydroxybutyrate (PHB) blends: A systematic review
PublikacjaPolylactic acid (PLA) and polyhydroxybutyrate (PHB) are two biopolyesters obtained from renewable resources like corn or sugar under bacterial fermentation. PLA is the most widely used biopolymer in diverse applications. Addition of PHB to PLA can improves the crystallinity of PLA, and thereby its mechanical strength. However, both PLA and PHB suffer from poor thermal stability, which limits their potential industrial application....
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High-density polyethylene/EPDM rubber blend composites of boron compounds for neutron shielding application
PublikacjaNovel materials with neutron shielding property were fabricated by incorporating boron compounds into highdensity polyethylene (HDPE)/Ethylene propylene diene monomer rubber (EPDM) blends. A detailed investigation on the morphological, thermal, mechanical, and neutron attenuation properties of suitable proportion of HDPE/EPDM blend with boric acid (BA), boron carbide (BC), and nano boron carbide (NBC) were performed. Morphology...
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Charakterystyka bakterii rodzaju Thermus i ich przydatność w biotechnologii
PublikacjaGram ujemne, termofilne bakterie rodzaju Thermus o optymalnych temperaturach wzrostu mieszczących się w zakresie 55-85 C są przydatne jako źródło nukleaz, polimeraz DNA oraz wielu innych termostabilnych enzymów. W przedstawionym artykule wymieniono występowanie i morfologię bakterii rodzaju Thermus, sposoby odżywiania i warunki ich wzrostu, budowę struktur powierzchniowych, sposoby adaptacji do wzrostu w podwyższonej temperaturze...
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Quantum dots in gas sensing a review
PublikacjaAir pollution becomes an increasing problem in the recent years. There is a need to develop more sensitive gas sensors. Much effort has been performed to develop different types of gas sensors, such as electrochemical sensors or polymer sensors. One of the most promising approaches to improve sensors performance is the application of the nanostructures as sensing materials. State of the art of quantum...
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Numerical model of human head phantom to ensure dosimetry of dose components for boron neutron capture therapy
PublikacjaExtremely important aspects of the boron neutron capture therapy are, first of all, administering to the patient a boron compound that selectively reaches the neoplastic cells, and in the second step, the verification of the irradiation process. This paper focuses on the latter aspect, which is the detailed dosimetry of the processes occurring after the reaction of thermal neutrons with the boron-10 isotope. The results of computer...
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Ground lemon and stevia leaves as renewable functional fillers with antioxidant activity for high-density polyethylene composites
PublikacjaThe development of new sustainable material solutions in the processing of thermoplastic polymers concerns both the application of biopolymers and the use of valorized plant derivatives as fillers and modifiers of petrochemical polymers. Herein, the possibility of using unprocessed raw parts of two commonly used in the food industry leaves, i.e., lemon (LL) and stevia (ST), as active and functional fillers for high-density polyethylene...
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Improving performance of large thrust bearings through modeling and experimentation
PublikacjaLarge thrust bearings are highly loaded machine elements and their failures cause serious losses. Start ups and stoppages of the bearing under load are specially critical regimes of operation. Load carrying capacity depends on the profile of the oil gap. In transient states this profile is also changing. In the design of large thrust bearings minimizing thermo-elastic deformations is an important goal, which can be accomplished...
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Influence of selected submicron inorganic particles on mechanical and thermo-mechanical properties of unsaturated polyester/glass composites
PublikacjaIn this paper, the influence of different submicron-scaled particles (zinc oxide, titanium dioxide, or silica) on mechanical and thermo-mechanical properties of unsaturated polyester matrix composites reinforced with glass fabric was investigated. Surface morphology of obtained composites was also examined. At first inorganic particles were mechanically dispersed into unsaturated polyester resin system as per the calculated weight...
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INVESTIGATION OF ACIDIC SOLUTIONS BY POTENTIOMETRIC TASTE SENSOR WITH ALL SOLID STATE ELECTRODES
PublikacjaPotentiometric taste sensors with electrodes containing lipophilic compound / polymer membranes were already used to distinguish commercial liquid products. In this paper a new potentiometric taste sensor consisting of six All Solid State Electrodes (ASSEs) has been presented. Each of the membrane contains a selected lipophilic compound. The set-up consists of a reference electrode and six ASSEs. The inner layer made of a conducting...
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Experimental comparison of hydrodynamic thrust bearings with different pad surface materials
PublikacjaBabbitt is the material most frequently used as the pad surface material for hydrodynamic bearings operating at usual operating conditions. It shows many advantages important for safe bearing operation, as for example: low friction coefficient, corrosion resistance, fair mechanical properties and outstanding conformability. On the other hand, it is not free from disadvantages, such as limited fatigue strength or limited resistance...
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Bitumen-Based Poroelastic Pavements: Successful Improvements and Remaining Issues
PublikacjaThis article presents the development process of designing and testing poroelastic pavement based on highly polymer-modified bitumen. Poroelastic wearing course was composed of mineral and rubber aggregate mixed with highly polymer-modified bitumen, in contrast to previous trials, during which polyurethane resins were mainly used as binder, which led to several serious technological problems concerning difficult production, insufficient...
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The effect of PEDOT morphology on hexavalent chromium reduction over 2D TiO2/PEDOT photocatalyst under UV–vis light
PublikacjaThe present study represents an approach to apply organic-inorganic hybrid materials for photocatalytic removal of heavy metals from the aqueous environment. The photocatalytic activity of the semiconductor modified with the conjugated polymer may depends on the conjugated polymer type, its amount and morphology. Therefore, in the present study the effect of poly (3, 4-ethylenedioxythiophene) (PEDOT) morphology on adsorption and photoreduction...
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Real-time monitoring of the emission of volatile organic compounds from polylactide 3D printing filaments
PublikacjaEstablishing the emission profile of volatile organic compounds generated during fused deposition modeling 3D printing using polymer filaments is important in terms of both understanding the processes taking place during thermal degradation of thermoplastics, and assessing the user's exposure to potentially harmful volatiles. However, obtaining detailed, real-time qualitative and quantitative results poses a challenge. In this...
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Degradation of polyurethanes in Compost Under Natural Conditions
PublikacjaThe estimation of degradibility of different polyurethanes under natural weather depending conditions in compost pile was the subject of the studies. The incubation of polymer samples took place for a period up to 24 months. The characteristic parameters of the compost: temperature, pH, moisture content, and activity of dehydrogenasis were monitored and their influence on degradation of polyuiretahnes was discussed. The compostability...
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Peculiarities associated with testing polyetheretherketone (PEEK) in a model rolling contact
PublikacjaPolyetheretherketone (PEEK) was investigated using a modified version of the four-ball tester in which the upper forth ball was replaced by a cone in such a way that kinematics of the four-ball configuration were fully preserved. Rotation of the cone enforced orbiting and rolling of the ceramic balls around the polymer cup. The results produced some unexpected peculiarities in the wear of ceramic balls which, in principle, should...
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Przemiany termooksydatywne wybranych olejów oliwkowych i oleju rzepakowego, zachodzące w czasie ogrzewania i smażenia
PublikacjaOmówiono przemiany termooksydatywne zachodzące w tłuszczu podczas procesu smażenia oraz wpływ produktów powstających w wyniku tych przemian na zdrowie człowieka. Na przykładzie wybranych olejów oliwkowych (Extra virgin, Pomace i Sansa) oraz oleju rzepakowego pokazano zależność wybranych wskaźników jakości tłuszczów smażalniczych (LK, LOO, L.An, zawartość frakcji polarnej oraz polimerów i dimerów TAG) od czasu smażenia i rodzaju...
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Effects of Xanthan Gum Biopolymer on the Permeability, Odometer, Unconfined Compressive and Triaxial Shear Behavior of a Sand
PublikacjaBiopolymers, which are microbially induced polymers, can be used as an alternative material to improve engineering performance of soils. In this paper, a laboratory study of 0.075-1.0 mm size sand and biopolymer (i.e., xanthan gum) mixtures with various mix ratios (0%, 0.5%, 1.0%, and 1.5%) was performed. The materials, specimen preparation, and test methods are described, as are the results of a suite of permeability, odometer, unconfined...
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Synteza, budowa i właściwości poliestrouretanów sieciowanych metakrylanem metylu
PublikacjaNową grupę poliestrouretanów (PEU) sieciowanych metakrylanem metylu otrzymano z nienasyconych prepolimerów uretanowych zsyntetyzowanych z oligo(alkilenoestro)dioli (OEA) zawierającą wiązania podwójne. Budowę otrzymanych PEU ustalono na podstawie analizy widm FTIR. Wyniki badań statycznych i dynamicznych właściwości mechanicznych oraz właściwości termicznych wykazały, że uzyskane PEU są interesującą grupą polimerów, których właściwości...
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Study of the influence of thermal factors on the welding process of polyethylene gas pipelines,
PublikacjaA one-dimensional calculation scheme is proposed with the help of which it is possible to determine and set the technological parameters with the accuracy to be realized in production conditions: the temperature of the heating element and the heating time, which allows maximum mechanization of the technological operations of polyethylene gas pipelines welding. The numerical value of the coefficient of temperature for polyethylene...
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Experimental investigations on concrete beams reinforced with CFRP lamellas
PublikacjaPaper presents experimental investigation made on two concrete beams reinforced with internal Carbon Fibre Reinforced Polymer (CFRP) lamellas (i.e. strips, bands). The reinforcement geometrical arrangement was similar as in normal concrete beams reinforced with steel bars and stirrups. The beams were destroyed by the shear forces, as intended. Obtained load-carrying capacities were lower as expected: below 40% of a calculated value....
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Electrode materials for electrochemical capacitors based on poly(3,4-ethylenedioxythiophene) and functionalized multi-walled carbon nanotubes characterized in aqueous and aprotic electrolytes
PublikacjaWithin this work, we report a facile one-stage synthesis of nanocomposites based on functionalized carbon nanotubes (CNTs) and electroactive polymer poly(3,4-ethylenedioxythiophene). Three different composites are investigated as potential electrode materials for the electrochemical capacitors. Two of the composites contain carbon nanotubes (ox-CNTs), functionalized by acid oxidation process (65% HNO3, 120 °C). The third composite...
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The Impact of Ground Tire Rubber Oxidation with H2O2 and KMnO4 on the Structure and Performance of Flexible Polyurethane/Ground Tire Rubber Composite Foams
PublikacjaThe use of waste tires is a very critical issue, considering their environmental and economic implications. One of the simplest and the least harmful methods is conversion of tires into ground tire rubber (GTR), which can be introduced into different polymer matrices as a filler. However, these applications often require proper modifications to provide compatibility with the polymer matrix. In this study, we examined the impact...
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Reclaimed rubber in-situ grafted with soybean oil as a novel green reactive plasticizer in SBR/silica compounds
PublikacjaPolymer recycling and biodegradable polymeric materials are two major routes towards the sustainable development of polymer materials which contributes to the management of waste. In this regard, an eco-friendly approach is presented wherein high reclaiming degree of ground tire rubber (GTR) was achieved by low-temperature oxidation under swollen action of soybean oil. In-situ reclaimed GTR with soybean oil was cured into reactive...
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Wstępne badania biokompatybilności poliuretanów otrzymanych z udziałem syntetycznego polihydroksymaślanu
PublikacjaCelem pracy było oznaczenie sorpcji oleju oraz pozostałości po ekstrakcji wodą i heksanem poliuretanów otrzymanych z udziałem poli{[R,S]-3-hydroksymaślanu. Oceniono także jego wpływu na parametry krwi. Wysoka sorpcja oleju roślinnego przez badane próbki oraz przebieg widm FTIR przed i po ekstrakcji heksanem a także analiza parametrów krwi po kontakcie z próbkami PU wskazują na potencjalną przydatność tych polimerów jako biomateriałów...
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Azo group(s) in selected macrocyclic compounds
PublikacjaAzobenzene derivatives due to their photo- and electroactive properties are an important group of compounds finding applications in diverse fields. Due to the possibility of controlling the trans–cis isomerization, azo-bearing structures are ideal building blocks for development of e.g. nanomaterials, smart polymers, molecular containers, photoswitches, and sensors. Important role play also macrocyclic compounds well known for...
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The use of GFRP tubes as load-bearing jackets in concrete-composite columns
PublikacjaThe paper presents the fields of applications of polymer composites in building structures. The use of composite glass fibre tubes is discussed in more detail. The laboratory methods used to test the mechanical properties of these pipes are presented. An original research program is presented, including six concrete-filled glass fibre tubes. The cylinders and columns made in this way were tested for their axial load capacity. Conclusions...
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Small Polymeric Toys Placed in Child-Dedicated Chocolate Food Products—Do They Contain Harmful Chemicals? Examination of Quality by Example of Selected VOCs and SVOCs
PublikacjaThis study was focused on child-dedicated chocolate food products that contain a plastic package with a small toy inside (also known as chocolate eggs). Three types of these products that are commercially available on the Polish market, with different prices, chocolate composition, and main types of polymers used in the toy manufacturing process, were investigated. The polymers were identified using Fourier-transform infrared (FT-IR)...
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Badanie efektywności zastosowania tłumików polimerowych do redukcji drgań tymczasowych trybun metalowych poddanych oddziaływaniom dynamicznym wywołanym zachowaniem widzów
PublikacjaNiegdyś trybuny metalowe wykorzystywane były tylko podczas wydarzeń sportowych. Dziś, wykorzystuje się je podczas koncertów muzycznych, festiwali oraz wydarzeń, w których uczestniczy duża liczba ludzi. Jednocześnie, użycie lekkich i smukłych elementów konstrukcyjnych prowadzi do redukcji wartości częstotliwości drgań własnych konstrukcji, przez co łatwiej wzbudzić ją do drgań. Konsekwencją tej sytuacji może być wystąpienie...
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How to make membrane distillation greener? A review on environmentally friendly and sustainable aspects
PublikacjaThere is an urgent need for the development of new water resources in order to solve the problem of the world’s growing demand for clean water. Membrane distillation (MD) is a promising alternative to conventional seawater desalination. Although MD itself is often defined as sustainable desalination technology, there are many aspects within the membrane manufacture and process operation that make it far from being green. For instance,...
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Water-Lubricated Sintered Bronze Journal Bearings—Theoretical and Experimental Research
PublikacjaWater lubricated bearings are used from many years in shipbuilding, hydro power and other industries because of their advantages such as: extensive serviceable life, low coefficient of friction, longevity of shaft sleeve, good abrasion resistance, low maintenance required, unit simplicity, no danger of pollution and low price. Various types of water lubricated sliding bearings have been tested at the Technical University of Gdansk...
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Research on water lubricated main shaft bearings in conditions of improper lubrication and cooling conducted on high torque real-life scale bush test rig
PublikacjaWater lubricated polymer bushes find increasingly popular use in the sliding bearings of marine propellers, water turbines and pump shafts. Such popularity is partly due to their simple construction which also means relatively affordable price. In addition, properly designed and installed water lubricated bearings may well last for over a decade. However, in practical experience one may also observe cases of rapid wear...
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Effect of kenaf fibre modification on morphology and mechanical properties of thermoplastic polyurethane materials
PublikacjaThe presented study examined the morphology and mechanical properties of biocomposites obtained from kenaf natural fibre and thermoplastic polyurethane. Kenaf was modified using various methods, namely: acetylation, blocked isocyanate, maleic anhydride and permanganate treatment. Those methods and ways of carrying out of surface modifications were not studied before on kenaf/thermoplastic polyurethane composites. Different fibre...
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pH-dependent composite coatings for controlled drug delivery system - Review
PublikacjaNowadays in case of long-term implants, the most common postoperative complications are bacterial infections, which in consequence may provoke loos- ening of the implants in the primary phase of stabilization. Bacterial infections are currently the most frequent cause of revision surgery of the implants such as hip joint endoprosthesis, knee joint endoprosthesis and dental implants. In order to provide the local and long-term antibacterial...
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Whether Carbon Nanotubes Are Capable, Promising, and Safe for Their Application in Nervous System Regeneration. Some Critical Remarks and Research Strategies
PublikacjaCarbon nanotubes are applied in or considered for different fields of medicine. Among them is the regeneration or rebuilding of nervous system components, which still lack substantial progress; this field is supported by carbon nanotubes to a great extent as the principal material. The limited research on this issue has involved PU/silk/MWCNTs, PCL/silk/MWCNTs, PCL/PGS/CNTs, chitin/CNTs, PGF/CNTs, CNTs/PGFs/PLDLA,MWCNTs chitosan,MWCNTs/PPy,...
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Advanced fatigue and rutting characterisation of Polish asphalt mixtures based on the VECD model and viscoplastic shift model
PublikacjaThe advanced asphalt mixture performance-related specifications (AM-PRS) recently developed in USA can allow an optimisation of the design process of asphalt pavements thanks to the possibility to fully take into account the intrinsic material properties. In this study, four typical Polish mixtures, i.e. a Stone Mastic Asphalt (SMA) for wearing course, two mixtures for binder course with neat bitumen or Polymer modified Bitumen...
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Influence of Surface-Modified Montmorillonite Clays on the Properties of Elastomeric Thin Layer Nanocomposites
PublikacjaIn recent years, polyurethane nanocomposites have attracted more attention due to the massive demand for materials with increasingly exceptional mechanical, optical, electrical, and thermal properties. As nanofillers have a high surface area, the interaction between the nanofiller and the polymer matrix is an essential issue for these materials. The main aim of this study is to validate the impact of the montmorillonite nanofiller...
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Biocomposites from recycled resources as candidates for laboratory reference material to validate analytical tools used in organic compounds emissions investigation
PublikacjaA suitably chosen reference material should meet specific criteria like representing one of the compound classes most commonly occurring in indoor materials as well as having optimal long-term stability during storage and transport to its destination point and having a compact size. The described interdisciplinary pilot research was aimed to develop and characterize a polymer-based candidate for the laboratory reference material...
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Wpływ uniepalniaczy na właściwości mechaniaczne sztywnych pianek poliuretanowych
PublikacjaW celu zmniejszenia palności i polepszenia właściwości mechanicznych pianek poliuretanowych stosuje się antypireny. Zastosowanie tych środków podyktowane jest ty iż sztywne pianki poliuretanowe muszą spełniać określone wymagania, których nie posiada pianka bez napełniacza. Wśród modyfikatorów palności można wyróżnić te, które opóźniają palenie, zmniejszają palność oraz ograniczają dymienie [1-3]. Substancje te mogą działać fizycznie,...
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Degradable poly(ester-ether) urethanes of improved surface calcium deposition developed as novel biomaterials
PublikacjaBones, which are considered as hard tissues, work as scaffold for human body. They provide physical support for muscles and protect intestinal organs. Percentage of hard tissues in human body depends on age, weight, and gender. Human skeleton consists of 206 connected bones. Therefore, it is natural that the hard-tissue damage such as fractures, osteoporosis, and congenital lack of bone may appear. The innovative way of bone healing...
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Naturally-derived hydrogels for 3D pancreatic tumor models: A short review
PublikacjaStatistics suggest a high proportion of mortality rate by pancreatic cancer, which is a solid tumor characterized by high heterogeneity and the presence of a complex extracellular matrix. The very low effectiveness of pancreatic cancer treatment roots in the high metastatic potential and drug resistance of this tumor. Therefore, the quest for efficient cellular models enabling precise mimicking in vivo conditions, and anticancer...
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Biopsy needles coated with the antimicrobial coatings
PublikacjaDrug delivery systems are used to achieve higher therapeutic effects of medicaments in a specific diseased site with minimal toxicological effect. The used of biopolymers in drug delivery systems ensure the biocompatibility, biodegradability and low immunogenicity. Drug delivery systems enhance the drug delivery actively and can be used in different diseases. In this study, two types of polymer coatings were prepared and were...
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Kompozytowe materiały poliuretanowo-gumowe otrzymywane z lanych elastomerów uretanowych i recyklatów gumowych
PublikacjaW pracy prezentujemy wyniki badań dotyczących nowej grupy kompozytowych materiałów poliuretanowo-gumowych (KPG), otrzymywanych przy udziale różnej ilości recyklatu gumowego (RG), w których jako osnowę wykorzystano opracowane w Katedrze Technologii Polimerów Politechniki Gdańskiej lane nienasycone poliestrouretany (PEUR), poddawane rodnikowej kopolimeryzacji sieciującej ze styrenem. Zastosowanie PEUR umożliwiło uzyskanie nowej grupy...
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On the Equations of the Surface Elasticity Model Based on the Theory of Polymeric Brushes
PublikacjaMotivating by theory of polymers, in particular, by the models of polymeric brushes we present here the homogenized (continual) two-dimensional (2D) model of surface elasticity. A polymeric brush consists of an system of almost aligned rigid polymeric chains. The interaction between chain links are described through Stockmayer potential, which take into account also dipole-dipole interactions. The presented 2D model can be treated...
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Saccharides
PublikacjaSaccharides are widely distributed in nature as the major component of fruits and vegetables (primarily monosaccharides), milk and malt (mainly disaccharides), and grains (mostly polysaccharides). They are an important source of energy, structural material, as well as flavor and taste factors. Molecules of this class of compounds contain mainly carbon, hydrogen, and oxygen atoms; however, most natural saccha- rides do not have...