Filters
total: 2707
filtered: 2035
displaying 1000 best results Help
Search results for: SIZE-EXCLUSION CHROMATOGRAPHY
-
Highly crystalline colloidal nickel oxide hole transport layer for low-temperature processable perovskite solar cell
PublicationHighly crystalline NiOX usually requires high annealing temperature (>300 °C) which is incompatible with flexible substrate and might consume high amount of energy. Herein, we demonstrate a facile emulsion process to synthesize highly crystalline, low temperature deposition (<150 °C) and solution processable NiOx nanoparticles (NPs) as a hole transport layer for the perovskite solar cells (PVSCs). A novel surfactant of tetramethylammonium...
-
Investigation of MIEX® resin sedimentation in the aspect of particle sizes remaining in the supernatant
PublicationThe aim of the study was to evaluate the effectiveness of the MIEX® resin sedimentation process, both new and repeatedly used in hybrid water treatment MIEX®DOC + microfiltration (MF) or ultrafiltration (UF) processes (repeatedly regenerated). The tests consisted of performing 1 h sedimentation of the suspension resin in nonflow conditions and analysis of supernatant water at different process durations. The suspension weight analysis...
-
Transcriptomic landscape of blood platelets in healthy donors
PublicationBACKGROUND Blood platelet RNA-sequencing is increasingly used among the scientific community. Aberrant platelet transcriptome is common in cancer or cardiovascular disease, but reference data on platelet RNA content in healthy individuals are scarce and merit complex investigation. METHODS We sought to explore the dynamics of platelet transcriptome. Datasets from 204 healthy donors were used for the analysis of splice variants,...
-
Sharp bounds for the complexity of semi-equitable coloring of cubic and subcubic graphs
PublicationIn this paper we consider the complexity of semi-equitable k-coloring of the vertices of a cubic or subcubic graph. We show that, given n-vertex subcubic graph G, a semi-equitable k-coloring of G is NP-hard if s >= 7n/20 and polynomially solvable if s <= 7n/21, where s is the size of maximum color class of the coloring.
-
A STUDY OF THE ORIGINAL AND CONTEMPORARY LAYOUT OF NAZAR GARDEN WITHIN THE CITY OF SHIRAZ, IRAN
PublicationShiraz city was famous for its beautiful gardens that shaped its landscape. Nazar Garden,with its buildings was designed by Karim Khan in the 18th c. The aim of the research wasto compare the size and layout of the Garden during the Zand Period with its contemporary shape. The research was based on literature sources, available plans and an on-sitesurvey.
-
Human UDP-Glucuronosyltransferases: Effects of altered expression in breast and pancreatic cancer cell lines.
PublicationIncreased aerobic glycolysis and de novo lipid biosynthesis are common characteristics of invasive cancers. UDP-glucuronosyltransferases (UGTs) are phase II drug metabolizing enzymes that in normal cells possess the ability to glucuronidate these lipids and speed their excretion; however, de-regulation of these enzymes in cancer cells can lead to an accumulation of bioactive lipids, which further fuels cancer progression. We hypothesize...
-
Technological vs. Non-Technological Mindsets: Learning From Mistakes, and Organizational Change Adaptability to Remote Work
PublicationThe permanent implementation of the change in working methods, e.g., working in the virtual space, is problematic for some employees and, as a result, for management leaders. To explore this issue deeper, this study assumes that mindset type: technological vs. non-technological, may influence the organizational adaptability to change. Moreover, the key interest of this research is how non-technological mindsets...
-
STRUKTURA SZKŁO-CERAMIKI ZAWIERAJĄCEJ FERROELEKTRYCZNĄ FAZĘ BiV
PublicationLiteratura opiusuje próby wytworzenia nanokompozytów, w których skład wchodzą matryca szkła i rozproszone w niej nanokrystality fazy ferroelektrycznej. Najczęstsza metoda wykorzystywana do otrzymywania takiej szkło - ceramiki polega na wytopie szkła, a następnie jego krystalizacji. W literaturze można znaleźć dużo przykładów wytwarzania tego typu materiałów dwu lub więcej składnikowych. Najwięcej badań dotyczy ferroelektrycznych...
-
Wskaźnik przedsiębiorczości w jednostkach terytorialnych Polski – zróżnicowanie w czasie i przestrzeni
PublicationPrzedmiotem artykułu jest analiza zjawiska prowadzenia działalności gospodarczej przez osoby fizyczne, mierzonego poprzez wskaźnik liczby tych osób na 100 osób w wieku produkcyjnym. Wskaźnik ten nazywany jest nieraz wskaźnikiem przedsiębiorczości, mimo, że mierzy tylko jeden z jej przejawów. Badania prowadzono w układzie podregionów, powiatów i gmin (według ich rodzaju, z wyodrębnieniem miast w gminach miejsko-wiejskich). Celem...
-
Determination of terpene profiles in potential superfruits
PublicationThe aim of this work was to characterize and compare the profiles of volatile terpenes in four potential superfruits. These profiles were determined using headspace solid-phase microextraction coupled with comprehensive two-dimensional gas chromatography linked to time-of-flight mass spectrometry. The proposed technique allowed the separation and identification of 79 terpenes present in cape gooseberry, crabapple, cherry silver...
-
Determination of Terpene Profile in Cape gooseberry (Physalis peruviana L.) with Use of HS-SPME/GCxGC-TOFMS Method
PublicationFresh fruits and products made of them, especially fruit juice, provide the basic energetic substances (simple and complex sugars) and are a source of health beneficial vitamins, macro and microelements, antioxidants and compounds which are classified together with essential oils (for example terpenes), which positively affect human s health. The terpenes profile of cape gooseberry was determined by headspace solid--phase microextraction...
-
Pesticide residues levels in honey from apiaries located of Northern Poland
PublicationConcentration levels of 30 pesticide residues were measured in honey samples collected from apiaries in northern part of Poland (Pomerania) using method based on the QuEChERS extraction followed by liquid chromatography-tandem mass spectrometry with electron spray ionization (LC-ESI-MS/MS). In 29% of the samples were found positive for at least some of the target compounds. Concentration of bifenthrin, fenpyroximate, methidathion,...
-
Modern trends in solid phase extraction: New sorbent media
PublicationBased on the recently published literature, this review provides an update of the most important features and application of formats and devices employed in solid phase extraction (SPE). Special attention was paid on new trapping media proposed in SPE prior the chromatography analysis, based on the use of nanostructured materials, including carbon nanomaterials, electrospun nanofibers, dendrimes and magnetic nanoparticles, molecular...
-
Determination of pharmaceuticals in fish: method optimization and occurrence in different species from Mediterranean rivers
PublicationThe multi-residue analytical method developed, based on accelerated solvent extraction, gel permeation chromatography purification and UPLC-MS/MS analysis allowed the simultaneous determination of 21 pharmaceuticals. Recoveries obtained for most of the target compounds were higher than 50%. The application of UPLC-MS/MS operating in the MRM mode, with two transitions monitored for each compound, provided good sensitivity and selectivity....
-
Quechers sample preparation method variants for analysis of pesticide residues in fruits and vegetables
PublicationThis article describes the comparison of different versions of an easy, rapid and low-cost sample preparation approach for the determination of pesticide residues in fruits and vegetables by concurrent use of gas and liquid chromatography coupled to MS or ECD for detection. The sample preparation approach is known as QuEChERS, which stands for quick, easy, cheap, effective, rugged and safe. It is a combination of liquid-liquid...
-
Distillation cleanup preceded gc determination of short-chain monocarboxylic acids in aqueous and solid samples of wastewater origin = Oznaczanie krótkołańcuchowych kwasów monokarboksylowych w próbkach wodnych i stałych pochodzących z oczyszczalni ścieków z wykorzystaniem chromatografii gazowej poprzedzonej destylacją
PublicationShort-chain monocarboxylic acids (SCMAs) (C2-C5) formed in the process of aerobic biodegradation of larger organic molecules should often be monitored to optimize wastewater biological treatment and study the processes of converting organic waste matter into methane, etc. Gas chromatography (GC) seems a method of choice for such a task. Majority of samples require clean up before they can be injected into GC system. In this work...
-
Occurrence and Levels of Biogenic Amines in Beers Produced by Different Methods
PublicationThe concentration of biogenic amines (BAs) in beer depends, among other factors, on the activity of microorganisms, in particular lactic acid bacteria. In this work an analytical method based on derivatization with tosyl chloride and high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) was used to determine 17 BAs in samples of commercially available beers, and to monitor the changes in concentration of...
-
Application of molecularly imprinted polymers in analytical chiral separations and analysis
PublicationOver the last two decades the process of development and application of a new types of molecular imprinted polymer (MIP) sorbents in the field of analytical chemistry have been widely described in the literature. One of the new trends in analytical chemistry practice is the use of new types of MIP sorbents as specific sorption materials constituting the stationary phase in advanced separation techniques. The following review paper...
-
Aminy w środowisku - niebezpieczeństwo czy jego naturalny element?
PublicationA lot of amines and their compounds are used in the industry. First of all they are used for the preparation of medicines, plant protection agents, fertilizers and plastics. Amines are also released into the environment as a result of natural biological processes such as the release of certain species of flowers to lure insects, and also biochemical breakdown of amino acids in the protein during decomposition of organic matter. Unfortunately,...
-
Application of ultrasound-assisted solvent extraction of porous membrane packed liquid samples for polyphenols determination in wine samples
PublicationPolyphenols play a crucial role in a proper human health maintenance as well as their presence very often correspond to the quality assessment of producs like wine. Thus, their monitoring is of high interest. However, as they occur in a complex matrices their extraction is very often necessary prior the analysis. Herein, a new ultrasound-assisted solvent extraction of porous membrane packed liquid sample technique has been optimized...
-
Portable raman spectrometer with two excitation wavelengths
PublicationSelected problems of development of a portable Raman spectrometer having small size, reduced power consumption and robust construction are shown. The device dedicated for semiskilled personnel uses two lasers: 785nm and 355nm. Results of preliminary tests are presented. Also data processing procedures as well as problems referred to Raman signals acquisition through packages and influence of interfering signals are discussed.
-
Selection of main engines for hopper suction dredgers with the use oobability models
PublicationThis paper presents a new original method of selection of main engines for hopper suction dredgers with regard to probabilistic models. It was proposed to use the normal distribution to describe the operational loads of the main receivers. The principles for determination of parameters of load distribution and design power of the main engines were formulated. Lastly, the principles of selection of the size and number of main engines...
-
SOME PROBLEMS OF SUPPORTING OFFSHORE WIND TURBINES
PublicationBasic problems of foundations of sea wind turbines are considered in this paper. This aims to search for solutions to optimize supporting of the offshore turbines with a size greater than 10 MW. The types of foundations, their basic features, including most important dimensions, applications as well as general design considerations are discussed. Numerical model of the offshore turbine and some preliminary computations for a case...
-
Topology recognition and leader election in colored networks
PublicationTopology recognition and leader election are fundamental tasks in distributed computing in networks. The first of them requires each node to find a labeled isomorphic copy of the network, while the result of the second one consists in a single node adopting the label 1 (leader), with all other nodes adopting the label 0 and learning a path to the leader. We consider both these problems in networks whose nodes are equipped with...
-
Constructing a map of an anonymous graph: applications of universal sequences
PublicationWe study the problem of mapping an unknown environmentrepresented as an unlabelled undirected graph. A robot (or automaton)starting at a single vertex of the graph G has to traverse the graph and return to its starting point building a map of the graph in the process. We are interested in the cost of achieving this task (whenever possible) in terms of the number of edge traversal made by the robot. Another optimization criteria...
-
Engineering Au nanoparticle arrays on SiO2 glass by pulsed UV laser irradiation
PublicationWe study semi-regular arrays of Au nanoparticles (NP) obtained via UV laser irradiation of thin Au films on glass substrate. The NP structures are prepared from films of a thickness up to 60 nm produced by discharge sputtering or pulsed laser deposition, and annealed by nanosecond laser pulses at 266 or 308 nm, respectively, at fluencies in the range of 60-410 mJ/cm2. For the rare- and close-packed NP structures, consistent description...
-
Determinants of export diversification: an empirical investigation
PublicationEmpirical findings confirm that relatively high specialisation of economic structures tends to be associated with low levels of income per capita, but countries diversify their export structures along their path of growth. However, usually only per capita income, and eventually, country-specific fixed effects are the sole explanatory variables taken into consideration in the estimation of specialisation curves. We extend the analysis...
-
Optimization of parallel implementation of UNRES package for coarse‐grained simulations to treat large proteins
PublicationWe report major algorithmic improvements of the UNRES package for physics-based coarse-grained simulations of proteins. These include (i) introduction of interaction lists to optimize computations, (ii) transforming the inertia matrix to a pentadiagonal form to reduce computing and memory requirements, (iii) removing explicit angles and dihedral angles from energy expressions and recoding the most time-consuming energy/force terms...
-
Multi-objective optimization of tool wear, surface roughness, and material removal rate in finishing honing processes using adaptive neural fuzzy inference systems
PublicationHoning processes are usually employed to manufacture combustion engine cylinders and hydraulic cylinders. A crosshatch pattern is obtained that favors the oil flow. In this paper, Adaptive Neural Fuzzy Inference System (ANFIS) models were obtained for tool wear, average roughness Ra, cylindricity and material removal rate in finish honing processes. In addition, multi-objective optimization with the desirability function method...
-
Miniaturized Metal-Mountable U-shaped Inductive-Coupling-Fed UHF RFID Tag Antenna with Defected Microstrip Surface
PublicationThis study presents a novel miniature ultra-high frequency (UHF) radio frequency identification (RFID) tag for metallic objects. Its arrangement includes a U-shaped feeder, which is inductively coupled to two E-type connected patches. Size reduction is achieved by means of utilizing the U-shaped feeder, and introducing a defection in the connection between the two E-type patches. The defection in the connection area between the...
-
Corrosion Properties of Dissimilar AA6082/AA6060 Friction Stir Welded Butt Joints in Different NaCl Concentrations
PublicationA solid-state friction stir welding method which is increasingly used in the marine and shipbuilding industry, has been developed to produce welds with high mechanical properties. In seawater, the oxide layer of aluminium is attacked by Cl− ions resulting in its disruption and formation of pitting corrosion. It is particularly important to determine the electrochemical properties of the produced welds and to evaluate the efect...
-
Insights into the Thermo-Mechanical Treatment of Brewers’ Spent Grain as a Potential Filler for Polymer Composites
PublicationThis paper investigated the impact of twin-screw extrusion parameters on the properties of brewers’ spent grain. The chemical structure, antioxidant activity, particle size, and color properties, as well as the emission of volatile organic compounds during extrusion, were investigated. The main compounds detected in the air during modifications were terpenes and terpenoids, such as α-pinene, camphene, 3-carene, limonene, or terpinene....
-
Enhancement of the Magnetic Coupling in Exfoliated CrCl 3 Crystals Observed by Low‐Temperature Magnetic Force Microscopy and X‐ray Magnetic Circular Dichroism
PublicationMagnetic crystals formed by 2D layers interacting by weak van der Waals forces are currently a hot research topic. When these crystals are thinned to nanometric size, they can manifest strikingly different magnetic behavior compared to the bulk form. This can be the result of, for example, quantum electronic confinement effects, the presence of defects, or pinning of the crystallographic structure in metastable phases induced by...
-
The influence of polypropylene-block/graft-polycaprolactone copolymers on melt rheology, morphology, and dielectric properties of polypropylene/polycarbonate blends
PublicationThe paper discusses the relationship between rheology and morphology of immiscible polypropylene (matrix))/polycarbonate (dispersed phase) blends compatibilized with novel polypropylene-polycaprolactone block and graft copolymers. Transmission electron microscopy (TEM) experiments revealed uniform droplet morphologies and a reduction of the average size of the dispersed phase upon addition of the compatibilizer. The results suggested...
-
EM‐driven constrained miniaturization of antennas using adaptive in‐band reflection acceptance threshold
PublicationNumerical optimization of geometry parameters is a critical stage of the design process of compact antennas. It is also challenging because size reduction is constrained by the necessity of fulfilling imposed electrical performance requirements. Furthermore, full‐wave electromagnetic (EM) analysis needs to be used for reliable performance evaluation of the antenna structure, which is computationally expensive. In this paper, an...
-
Tight bounds on the complexity of semi-equitable coloring of cubic and subcubic graphs
PublicationWe consider the complexity of semi-equitable k-coloring, k>3, of the vertices of a cubic or subcubic graph G. In particular, we show that, given a n-vertex subcubic graph G, it is NP-complete to obtain a semi-equitable k-coloring of G whose non-equitable color class is of size s if s>n/3, and it is polynomially solvable if s, n/3.
-
Zastosowanie addytywów w separacji pianowej białek serwatkowych i białek mlecznych
PublicationZaproponowano proces separacji pianowej do wydzielania białek ze strumieni poprodukcyjnych przemysłu mleczarskiego Ponadto zaproponowano zastosowanie w separacji pianowej białek serwatkowych i mlecznych addytywów dopuszczonych ustawą do stosowania w żywności. Jako cel pracy przyjęto uzyskanie wyników uzasadniających wybór takich addytywów, które intensyfikują przebieg i polepszają wynik procesu separacji pianowej białek. W części...
-
Nanoparticles preparation using microemulsion systems
PublicationMetallic nanoparticles become of current interests because they exhibit unique properties compared with those of metal atoms or bulk metal due to the quantum size effect and their large surface area, which make them attractive for applications in optics, electronics, catalysis biology and medicine. TiO2 has been used for environmental remediation purposes such as in the purification of water and air and also solar-to chemical energy...
-
VIBRATION DIAGNOSTICS OF FOOTBRIDGE WITH USE OF ROTATION SENSOR
PublicationThe benefits of the additional measurement of rotational degrees of free-dom on the performance of the vibration diagnosis of bridges are studied in this paper. The common vibrational diagnostics that uses translational degrees of freedom is extended by measurements of rotations. The study is curried out on a footbridge and the presence of damage as well as its location and size is determined with use of FEM updating procedure....
-
Improved selectivity compact band-stop filter with gosper fractal-shaped defected ground structures
PublicationA novel band-stop filter using Gosper fractal-shaped defected ground structures has been designed and manufactured. The improvement in the filter selectivity has been achieved by introducing a multiresonance fractal-shaped defect leading to a higher filter order, simultaneously maintaining its compact size. The experimental results prove the validity of proposed solution and its utility in novel miniaturized and severe requirement...
-
The influence of ammonia and selcted amines on the characteristics of calcium carbonate precipitated from calcium chloride solutions via carbonation
PublicationThe precipitation of calcium carbonate was carried out by passing a gasous mixture of carbon dioxide and air into a calcium chloride solution. The selected compounds enhancing carbon dioxide absorption were used as additives which promote the formation of carbonate ions in the solution. The additives were ammonia, monoethanolamine, triethylamine and triethanolamine. The resulting calcium carbonate particles varied in polymorphic...
-
Review and comparison of smoothing algorithms for one-dimensional data noise reduction
PublicationThe paper considers the choice of parameters of smoothing algorithms for data denoising. The impact of the window size on smoothing accuracy was analyzed. The parameters of denoising filters were selected with respect to the meansquare error between the computed linear regression and the noisy signal. Finally, we have compared mean, median, SavitzkyGolay, Kalman and Gaussian filter algorithms for the data from the digital sensor....
-
Preparation and characterization of monometallic (Au) and bimetallic (Ag/Au) modified-titania photocatalysts activated by visible light
PublicationThe Au-TiO2 and Ag/Au-TiO2 nanoparticles have been prepared using a water-in-oil microemulsion system of water/AOT/cyclohexane and water/Triton X-100/cyclohexane. The obtained photocatalysts were subsequently characterized by a BET method, DRS spectroscopy, X-ray photoelectron emission spectroscopy (XPS), scanning transmission electron microscopy (STEM) and X-ray powder diffraction analysis (XRD). For gold-doped titanium (IV) oxide...
-
Role of nitrogen in evolution of sp2/sp3 bonding and optical band gap in hydrogenated carbon nitride
PublicationDrastic changes in the bonding are found in amorphous hydrogenated carbon nitride (a-CNx:H) film as a function of nitrogen concentration (or N/C ratio). The total C-sp3 fraction and hardness shows a sharp decrease (at N/C = 0.40) whereas optical band gap and resistivity shows a gradual increase as nitrogen concentration increases from 0.07 to 0.58. Raman spectrum of a-CNx:H film is fitted with both Gaussian (integrated intensity...
-
Comprehensive comparison of compact UWB antenna performance by means of multi-objective optimization
PublicationAn optimization-based procedure for comprehensive performance comparison of alternative compact UWB antenna topologies is discussed. The assessment of the antenna performance is conducted with respect to the structure size and its reflection response. More specifically, the best possible tradeoffs between these two figures of merit are identified through multiobjective optimization at the level...
-
Feedline Alterations for Optimization-Based Design of Compact Super-Wideband MIMO Antennas in Parallel Configuration
PublicationThis letter presents a technique for size reduction of wideband multiple-input-multiple-output (MIMO) antennas. Our approach is a two-stage procedure. At the first stage, the antenna structure is modified to improve its impedance matching. This is achieved through incorporation of an n-section tapered feedline, followed by reoptimization of geometry parameters. Reducing the maximum in-band reflection well beyond the acceptance...
-
Guanosine Dianions Hydrated by One to Four Water Molecules
PublicationIntermolecular interactions such as those present in molecule···water complexes may profoundly influence the physicochemical properties of molecules. Here, we carried out an experimental–computational study on doubly deprotonated guanosine monophosphate···water clusters, [dGMP – 2H]2–·nH2O (n = 1–4), using a combination of negative anion photoelectron spectroscopy (NIPES) with molecular dynamics (MD) and quantum chemical (QM) calculations....
-
Wydłużanie krzywej przejściowej w analitycznej metodzie projektowania
PublicationW pracy przedstawiono problematykę wydłużania krzywych przejściowych, wykorzystując do tego celu analityczną metodę projektowania. Podstawę analizy stanowiły obliczenia numeryczne przeprowadzone dla szerokiego zestawu parametrów charakteryzujących standardowy układu geometryczny. Po sformułowaniu odpowiednich zależności teoretycznych rozpatrzono kwestie znaczenia wielkości promienia łuku kołowego i kąta zwrotu trasy na uzyskane...
-
Elimination of excretion of ibuprofen and its metabolites in horses
PublicationAnalytical procedure based on application of gas chromatography-mass spectrometry (GC-MS) at the step of detection, identification and quantitation of ibuprofen (IBU) and detection of its metabolites – 1-hydroxyibuprofen (1-OH IBU) and carboxyibuprofen (CBX IBU) in horse urine by selected ion monitoring mode after sample preparation covering extraction at pH 3-4 and methylation has been used. The ions at m/z 161, 220 (methylated...
-
Analytical procedures for quality control of pharmaceuticals in terms of residual solvents content: Challenges and recent developments
PublicationResidual solvents play an important role in the synthesis of drugs and in product formulations. In addition, they pose a serious problem, that is toxicity, as many of them exhibit toxic or environmentally hazardous properties. Therefore, constant monitoring of quality control is needed. In this study, we present an overview of regulatory and general methods described by various pharmacopoeias. Then, the most commonly used methodologies...