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Search results for: polymer thin films
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THE INFLUENCE OF POLYMER STRIPS IN REDUCTION OF A STEEL GRANDSTAND VIBRATIONS
PublicationGrandstands are types of structures commonly used during sport events or music concerts. Dynamic loads generated by crowd movement may have significant influence on human perception as well as may lead to the destruction of a structure. Lighter and more slender structural steel members are more easily excitable by spectators. If the synchronized movement is tuned with the natural frequency of the affected part of the structure,...
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On Nonlinear Dynamic Theory of Thin Plates with Surface Stresses
PublicationWe discuss the modelling of dynamics of thin plates considering surface stresses according to Gurtin–Murdoch surface elasticity. Taking into account the surface mass density we derive the two-dimensional (2D) equations of motion. For the reduction of the three-dimensional (3D) motion equations to the 2D ones we use the trough-the-thickness integration procedure. As a result, the 2D dynamic parameters of the plate depend not only...
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Experimental and numerical analysis of an aluminum cantilevered beam with polymer adhesive
PublicationIn this paper, experimental and numerical investigation on a composite cantilevered aluminum beam has been conducted. The subject of the study consists of two plain aluminum elements bonded with polymer adhesive of different thickness. It has been proven in the previous study that this kind of material has high damping properties. During an experimental investigation, value of damping ratios have been obtained. The aim of a numerical...
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The Effectiveness of Polymer Damper in Damage Reduction of Temporary Steel Grandstand
PublicationA large number of accidents involving damage of temporary grandstands during different types of events were observed in the past. The aim of the paper is to analyse numerically the effectiveness of a polymer damper in damage reduction of a temporary steel scaffolding grandstand exposed to dynamic load due to jumping. The element has been installed as a diagonal one at the back part of the structure. The method has been compared...
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How Chain Transfer Leads to a Uniform Polymer Particle Morphology and Prevents Reactor Fouling
PublicationABSTRACT: The effect of adding diethyl zinc as a chain transfer agent during the polymerization of propylene in heptane performed at 80 °C was studied. Although it was expected that the chain transfer would stop after precipitation of the polymer, the polymer molecular weight continued to increase throughout the whole of the polymerization. The presence of diethyl zinc had an additional effect that the polymerizations were devoid...
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Distortional buckling of thin-walled columns of closed quadratic cross-section
PublicationThe elastic stability of axially compressed column related to the cross-section distortion is investigated. Two kinds of closed quadratic cross-sections are taken into consideration with internal walls and without it. The governing differential equation is derived with aid of the principle of stationary total potential energy. The critical loads for the simply supported columns are found in an analytical form and compared with...
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Molecular dynamics simulations of the growth of poly (chloro-para-xylylene) films.
PublicationParylene C, poly(chloro-para-xylylene) is the most widely used member of the parylene family due to its excellent chemical and physical properties. In this work we analyzed the formation of the parylene C film using molecular mechanics and molecular dynamics methods. A five unit chain is necessary to create a stable hydrophobic cluster and to adhere to a covered surface. Two scenarios were deemed to take place. The obtained results...
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Growth of polymer brushes by “grafting from” via ATRP – Monte Carlo simulations
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Analysis of magnetic field inside thin-layer ferromagnetic objects
PublicationResults of the numerical analysis of the magnetic field inside an infinitely long, thin-layer ferromagnetic pipe with and without a barrier were presented in this paper. Two wires with current symmetrically placed on two sides of the pipe are the sources of magnetic field. Numerical calculations for the quasi-steady state for chosen frequency band were carried out in the Flux 2D.
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THE ROLE OF THIN FUNCTIONAL LAYERS IN SOLID OXIDE FUEL CELLS
PublicationWidespread commercialization of solid oxide fuel cells requires lowering its cost. It is generally accepted that to lower the cost of solid oxide fuel cells it is necessary to use metal alloys as interconnectors and, consequently, lower its operating temperature to slow down interconnectors degradation. As a result the area specific resistance of the cathodes should be lowered to sustain the performance of the cells. In order to...
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A New Microwave Ceramic – Polymer Composite with 0-3 Connectivity
PublicationGoal of the present research was to fabricate and study two-phase BiNbO4//PVDF composites with 0-3 connectivity. Such composite consists of there-dimensionally connected polymer matrix loaded with dielectric ceramic particles. In the present case BiNbO4 powder acted as an active phase (dispersed phase) whereas polyvinylidene fluoride (PVDF) acted as a non-active (passive) phase (matrix). BiNbO4//PVDF composites with the volume...
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The Synergistic Microbiological Effects of Industrial Produced Packaging Polyethylene Films Incorporated with Zinc Nanoparticles
PublicationZinc compounds in polyolefin films regulate the transmission of UV-VIS radiation, affect mechanical properties and antimicrobial activity. According to hypothesis, the use of zinc- containing masterbatches in polyethylene films (PE) with different chemical nature—hydrophilic zinc oxide (ZO) and hydrophobic zinc stearate (ZS)—can cause a synergistic effect, especially due to their antimicrobial properties. PE films obtained on an...
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GOOD HEALTH PRODUCTS AND POLYMER COMPOSITES OBTAINED WITH THE USE OF NATURAL ORIGIN MICRO- AND NANOFIBERS
PublicationThe aim of this work was focused on good health products and polymer composites obtained with the use of natural origin micro- and nanofibers. Many different type of the natural plants are used in the production of good health products and polymer processing like curcuma, cellulose, microalgae and others. Often are used as a antioxidants and fillers. In this work the effect of algae and cellulose as a microfillers on the chosen...
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Experimental study on the effectiveness of polymer damper in damage reduction of temporary steel grandstand
PublicationA large number of accidents, involving collapses of temporary grandstands during different types of events, were observed in the past. If the synchronized movement of people is tuned with the natural frequency of the affected part of the structure, resonance might occur. It may lead to severe damages of grandstands, their collapse or panic among the spectators. The aim of the paper is to assess, through preliminary experimental...
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The effect of macro polymer fibres length and content on the fibre reinforced concrete
PublicationThe paper presents studies of a ready-mix concrete containing polymer fibres of three different lengths: 24, 38 and 54 mm. The performed tests allowed to determine the effect of fibre volume fraction and length on the concrete strength. The basic parameters of concrete mixture (consistency, air content and bulk density) were identified. Fibre reinforced concrete belongs to a group of composite materials. The polymer fibres are...
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Doped Nanocrystalline Diamond Films as Reflective Layers for Fiber-Optic Sensors of Refractive Index of Liquids
PublicationThis paper reports the application of doped nanocrystalline diamond (NCD) films—nitrogen-doped NCD and boron-doped NCD—as reflective surfaces in an interferometric sensor of refractive index dedicated to the measurements of liquids. The sensor is constructed as a Fabry–Pérot interferometer, working in the reflective mode. The diamond films were deposited on silicon substrates by a microwave plasma enhanced chemical vapor deposition...
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On Von Karman Equations and the Buckling of a Thin Circular Elastic Plate
PublicationWe shall be concerned with the buckling of a thin circular elastic plate simply supported along a boundary, subjected to a radial compressive load uniformly distributed along its boundary. One of the main engineering concerns is to reduce deformations of plate structures. It is well known that von Karman equations provide an established model that describes nonlinear deformations of elastic plates. Our approach to study plate deformations...
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Measurement of temperature at sliding polymer surface by grindable thermocouples
PublicationThis paper is devoted to experimental study of capabilities and limitations of grindable thermocouples as applied to polymer materials sliding on metal. Chromel–alumel and chromel–copel grindable thermocouples have been developed and tested for wide ranges of contact pressure and sliding velocity. The background temperature of the sliding surface can be determined as the lower envelope of the signal from the grindable thermocouple....
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Express Polymer Letters
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IRANIAN POLYMER JOURNAL
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Compliance tests of the polymer layers used as hydrodynamic bearing coatings
PublicationOperational experience and scientific investigations results showed that polymer lined hydrodynamic bearings can withstand more severe operating conditions compared than white metal bearings. PTFE and PEEK-based coatings are the most frequently used as Babbitt alternatives. Both polymers differ significantly from the each other in material properties. According to catalogue data compression modulus of PTFE, it is about an order...
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The Influence of Thin Gold Electrodes on the High-Temperature Impedance of Oxide Glasses
PublicationThe influence of thin gold electrodes on the electrical measurements of glasses at high temperatures was studied using impedance spectroscopy. The impedance was measured several times over a wide frequency range from 10 mHz to 1 MHz and the temperature ranged from 213 to 673 K under air and nitrogen atmospheres. The results showed a drop in the conductivity of more than an order of magnitude at a temperature around 603 K during...
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Numerical investigation into plastic hinge formation in arched corrugated thin-walled profiles
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Dynamic FE simulations of buckling process in thin-walled cylindrical metal silos
PublicationW artykule przedstawiono wyniki dynamicznej analizy wyboczeniowej cienkościennych silosów metalowych o przekroju kołowym. Analizy MES wykonano dla wstępnych imperfekcji geometrycznych o różnym kształcie i amplitudzie. Wyniki analizy dynamicznej porównano z analizami statycznymi.
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Surface quality control of a thin SiN layer by optical measurements
PublicationFiber optic interferometers have a wide range of applications, including biological and chemical measurements. Nevertheless, in the case of a reflective interferometer setup, standard silver mirrors cannot be used in every measurement, due to their chemical activity. This work investigates the surface quality of a thin optical layer of silicon nitride (SiN), which can serve as an alternative material for silver mirrors. We present...
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Shaking table experimental study on the effectiveness of polymer bearings for seismic isolation of structures
PublicationSeismic isolation has been recognised to be a very effective way of protecting structures from damage during earthquakes. It allows us to extend the natural period of the structure and therefore avoid resonance with the ground motion. Moreover, by increasing damping in the isolation devices, more energy can be dissipated and thus the structural response can be further reduced. The aim of this paper is to show the results of the...
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Coffee silverskin as a potential bio-based antioxidant for polymer materials: Brief review
PublicationCoffee silverskin is one of the by-products generated by the coffee industry. Although it is not the most burdensome one, because it stands only for ~4.2 wt % of coffee, it seems like an auspicious raw material for industrial processes. Coffee silverskin is characterized by a relatively low moisture content of ~5–7%, so it often does not require quite energy-consuming drying processes. The chemical composition of coffee silverskin,...
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Potential applications of crude glycerol in polymer technology–Current state and perspectives
PublicationThe increasing use of bio-based fuels and fuel additives, among them biodiesel, causes significant surplus of crude glycerol on the market which creates new challenges in terms of its sustainable utilization. A lot of ways for the incorporation of this by-product into different branches of industry requires purification by expensive and complicated processes. Therefore, researchers are seeking for applications of untreated crude...
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Coffee Wastes as Sustainable Flame Retardants for Polymer Materials
PublicationDevelopment of green flame retardants has become a core part of the attention of material scientists and technologists in a paradigm shift from general purpose to specific sustainable products. This work is the first report on the use of coffee biowastes as sustainable flame retardants for epoxy, as a typical highly flammable polymer. We used spent coffee grounds (SCG) as well as SCG chemically modified with phosphorus (P-SCG)...
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Investigation of solid polymer electrolyte gas sensor with different electrochemical techniques
PublicationIn this work solid polymer electrolyte (SPE) amperometric sulphur dioxide sensor is investigated. Nafion was used as a membrane electrode and 1M sulphuric acid as an internal electrolyte. Sensor response to sulphur dioxide was measured. Besides traditional constant voltage amperometry also different electrochemical techniques were used. Results obtained by these methods are compared.
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Maillard-reaction (glycation) of biopolymeric packaging films; principles, mechanisms, food applications
PublicationBackground The biodegradable, biocompatible, sustainable, and renewable nature of biomaterials has led to increased interest in developing biopolymeric food packaging films (BFPFs) with green ingredients and strategies. To enhance the performance of these films, biopolymer molecules can be modified or combined with additives like nanomaterials, cross-linkers, bioactive compounds, and other polymers, particularly with Maillard-reaction...
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Biophotonic low-coherence sensors with boron-doped diamond thin layer
PublicationLow-coherence sensors using Fabry-Perot interferometers are finding new applications in biophotonic sensing, especially due to the rapid technological advances in the development of new materials. In this paper we discuss the possibility of using boron-doped nanodiamond layers to protect mirror in a Fabry-Perot interferometer. A low-coherence sensor using Fabry-Perot interferometer with a boron-doped nanodiamond (B-NCD) thin protective...
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Influence of reactive oxygen species during deposition of iron oxide films by high power impulse magnetron sputtering.
PublicationIron oxide films were deposited using high power impulse magnetron sputtering (HiPIMS) of an iron cathode in an argon/oxygen gas mixture at different gas pressures (0.5~Pa, 1.5~Pa, and 5.0~Pa). The HiPIMS system was operated at a repetition frequency $f = 100$~Hz with a duty cycle of 1~\%. A main goal is a comparison of film growth during conventional and electron cyclotron wave resonance-assisted HiPIMS. The deposition plasma...
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Effect of low-temperature plasma on chitosan-coated PEEK polymer characteristics
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TESTING CONTRACTION AND THERMAL EXPANSION COEFFICIENT OF CONSTRUCTION AND MOULDING POLYMER COMPOSITES
PublicationThe paper presents results of systematic tests of contraction and thermal expansion coefficients of materials based on polymer composites. The information on the above material properties is essential both at the design stage and during the use of finished products. Components for the samples were selected in such a way as to represent typical materials used for production of construction and moulding elements. The performed tests...
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Optically transparent boron-doped nanocrystalline diamond films for spectroelectrochemical measurements on different substrates
PublicationFabrication process of optically transparent boron nanocrystalline diamond (BNCD) electrode on silicon and quartz substrate was shown. The B-NCD films were deposited on the substrates using Microwave Plasma Assisted Chemical Vapor Deposition (MWPACVD) at glass substrate temperature of 475 ºC. A homogenous, continuous and polycrystalline surface morphology with high sp3 content in B-NCD films and film thickness depending from substrate...
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Gas Composition Influence on the Properties of Boron-Doped Diamond Films Deposited on the Fused Silica
PublicationThe main subject of this study are molecular structures and optical properties of boron-doped diamond films with [B]/[C] ppm ratio between 1000 and 10 000, fabricated in two molar ratios of CH 4 -H 2 mixture (1 % and 4 %). Boron-doped diamond (BDD) film on the fused silica was presented as a conductive coating for optical and electronic purposes. The scanning electron microscopy images showed homogenous and polycrystalline surface...
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Investigation of energy deposition and its optical imaging in polymer gel dosimeters
PublicationThis following chapter describes methods for verifying the absorbed dose during radiotherapy. Special attention is paid to the method using polymer-gel dosimeters, the dose reading of which is performed by means of Laser Computed Tomography. The chapter also includes considerations on alternative solutions for dosimetric measurements and various types of radiotherapy and their pros and cons. In addition, both the methods of structural...
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The influence of temperature on properties of the polymer flexible joint used for strengthening historical masonries
PublicationA new method of repairing damaged structures by filling the cracks with a specially prepared elastomeric polymer mass has been recently proposed. This new and innovative technique, known as the Flexible Joint Method (FJM), is mainly dedicated to masonries and historical objects, where minimum intervention is permitted. The flexible joint bonds the disrupted elements and ensures further safe exploitation of a damaged structure....
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Influence of the Addition of Recycled Aggregates and Polymer Fibers on the Properties of Pervious Concrete
PublicationThe aim of the study was to check the possibility of reusing aggregate from recycled concrete waste and rubber granules from car tires as partial substitution of natural aggregate. The main objective was to investigate the effects of recycled waste aggregate modified with polymer fibers on the compressive and flexural strength, modulus of elasticity and permeability of pervious concrete. Fibers with a multifilament structure and...
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Interferometric Sensor of Wavelength Detuning Using a Liquid Crystalline Polymer Waveplate
PublicationOperation of a polarization interferometer for measurement of the wavelength changes of a tunable semiconductor laser was investigated. A lambda/8 waveplate made from liquid crystalline polymer is placed in one of interferometers’ arms in order to generate two output signals in quadrature. Wavelength was measured with resolution of 2 pm in the wavelength range 628–635 nm. Drift of the interferometer, measured in the period of 500...
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Polymer Chemistry
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Elastic distortional buckling of thin-walled bars of closed quadratic cross-section
PublicationIn this study a thin-walled bar with closed quadratic cross-section is considered. The elastic stability of axially compressed bar related to the cross-section distortion is investigated. The governing differential equation is derived with aid of the principle of stationary total potential energy. The critical load for the simply supported bar is found in analytical form and it is compared with the FEM solution. Sufficient accuracy...
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The Idea of Using Adhesive Bonds in Shaping of Cold-formed Thin-walled Beam-columns
PublicationThe chapter concerns the idea of using adhesive bonds in the shaping of cold-formed thin-walled beam-columns. The idea of adhesive-bonded connections is not new but is unlikely to have been used in the design and shaping of thin-walled beam-columns in civil engineering up to date. Metal bar structures, including (due to economic reasons) thin-walled structures, are the most common and effective means to build engineering superstructures/loadbearing...
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Construction and investigation of SO2 amperometric sensor with a solid polymer electrolyte membrane
Publicationn this paper a sensor for detection of the sulphur dioxide based on three electrode cell configuration with a liquid electrolyte, a mercury sulphate reference electrode and a solid polymer electrolyte working electrode is presented. Working elec- trode was obtained by using Takenaka-Torikai chemical deposi- tion method by precipitation of Au particles into the pores of the Nafion membrane. Sensors characteristics measurements were...
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Polarization interferometer using a Liquid Crystalline Polymer waveplate for wavelength measurement
PublicationA two-beam polarization interferometer for measuring wavelength changes of a tunable semiconductor laser was designed, built and tested. This interferometer uses a λ/8 waveplate made from Liquid Crystalline Polymer in order to generate two output signals in quadrature. The λ/8 waveplate can be manufactured either on a beamsplitter face or on the mirror surface, reducing the cost and complexity of the optomechnical assembly. Experiment...
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Potential applications of by-products from the coffee industry in polymer technology – Current state and perspectives
PublicationCoffee is one of the most popular beverages in the world, and its popularity is continuously growing, which can be expressed by almost doubling production over the last three decades. Cultivation, processing, roasting, and brewing coffee are known for many years. These processes generate significant amounts of by-products since coffee bean stands for around 50% of the coffee cherry. Therefore, considering the current pro-ecological...
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Controlling crystallites orientation and facet exposure for enhanced electrochemical properties of polycrystalline MoO3 films
PublicationThis study focuses on the development and optimization of MoO3 films on commercially available FTO substrates using the pulsed laser deposition (PLD) technique. By carefully selecting deposition conditions and implementing post-treatment procedures, precise control over crystallite orientation relative to the substrate is achieved. Deposition at 450 °C in O2 atmosphere results in random crystallite arrangement, while introducing...
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Investigation of natural frequencies of axially loaded thin-walled columns
PublicationThe paper deals with correlation between natural frequencies of two steel thin-walled columns and the corresponding applied load. The structures are made of cold-formed lipped channel sections. The columns lengths were assumed to follow two buckling patterns – global flexural and flexural-torsional buckling. In the thicker structure two material models were considered – linearly-elastic and elastic-perfectly plastic. Numerical...
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Experimental and numerical study on polymer element used for reduction of temporary steel grandstand vibrations
PublicationThe purpose of the paper is to analyse the effectiveness of a polymer damper in reduction of a temporary steel grandstand vibrations through the experimental and numerical study. The damper considered in the investigation is constructed out of two L-shape steel members bonded with polymer mass of high damping properties. The element has been installed as a diagonal one at the back part of the structure. The method has been compared...