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Search results for: GAS-PHASE BASICITIES
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Determination of pKa by pH Gradient Reversed-Phase HPLC
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Effective dielectric constant of two phase dielectric systems
PublicationW tym artykule model brick-layer ścianie został rozszerzony na dwufazowe systemy perkolacyjne. Porównano wyniki obliczeń z danymi eksperymentalnymi. Stałe dielektryczne obu faz oraz próg perkolacji pozwala na wyznaczenie efektywnej stałej dielektrycznej systemu dwufazowego.
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Energy Modeling of Single-Family Houses in the Conceptual Phase
PublicationThe aim of the article is to identify the potential impact of the latest commercial digital tools for building energy analysis on the everyday architectural practice in Poland in the context of typology and energy optimization of single –family houses. The reason for this survey is that “architect friendly” interfaces simulation results’ visualization and energy analysis tools are not given deserved attention in the architectural...
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On iterates of strong Feller operators on ordered phase spaces.
PublicationPraca dotyczy asymptotycznych własności iteracji operatorów Markowa. Udowodniono, że operatory Lasoty i ich wielowymiarowe uogólnienia są asymptotycznie stabilne. Wyniki mają zastosowanie w modelowaniu rozwoju komórki.
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Optimized Space Vector Modulation strategy for five phase voltage source inverter with third harmonic injection
PublicationThis paper presents a simple and an effective SVM algorithm for five-phase Voltage-Source Inverters with the possibility to control independently the voltage vectors for fundamental and auxiliary orthogonal subspaces. The essential benefit is that output voltage is generated using only four active voltage vectors with limited numbers of switching. In the proposed solution, four active vectors are arbitrary chosen, independent of...
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Frequency and phase analysis of daily reprocessed solutions from selected EPN stations relating to geological phenomena,
PublicationThe main assumption of this research was to check and verify the behaviour of a few EPN (European Permanent Network) stations on both sides of the Teisseyre-Tornquist zone (T-T zone), which is located on Polish territory and crosses Poland almost in half. The selected EPN stations’ time series were a subject of frequency and phase analysis. The main purpose of the research was to verify if there is any correspondence between stations...
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Optimized Space-Vector Modulation Schemes for Five-Phase Precision Low-Speed Drives with Minimizing the Stator Current Ripple
PublicationOne of the main ways to improve the quality of a precision electric drive is minimization of the stator current pulsations generated by the voltage inverter. The solution of this problem can be achieved by using of multiphase inverters, as well as improving control algorithms. This paper considers the influence of the space-vector modulation algorithm with different switching sequences of basic vectors on the stator current pulsations...
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Activated Tungsten Inert Gas Weld Characteristics of P91 Joint for Advanced Ultra Supercritical Power Plant Applications
PublicationActivated Tungsten Inert Gas (A-TIG) welding, a variant of tungsten inert gas (TIG) welding, was used for welding P91. In Generation IV power plants, P91 welds are prone to premature failure due to the presence and formation of brittle phases and creep at high temperatures. When performing A-TIG welding, the flux composition plays a role in the reversal of the Marangoni flow in the weld pool, which ultimately determines the level...
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Rovibrational excitation of rare-gas dimers by electron impact
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Approximate Solutions for Non-stationary Gas Permeability Tests
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Anti‐corrosion protection of chimneys and flue gas ducts
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The inflence of TiO2 structure on the complete decomposition of acetaldehyde gas
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Integration of adsorption chillers with combined cycle gas turbine
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The role of hydrogen in microwave plasma valorization of producer gas
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Identification of acrylate copolymers using pyrolysis and gas chromatography
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Hazardous gases detection by fluctuation-enhanced gas sensing
PublicationW pracy przedstawiono układ pomiarowy oraz metodę za pomocą której można jednym rezystancyjnym czujnikiem gazów wykrywać dwa gazy: amoniak i siarkowodór. Podano wskaźnik jaki pozwala dokonać detekcji tych gazów już przy stężeniach rzędu pojedynczych ppm. Przebadano także powtarzalność wyników pomiarów w kilku egzemplarzach czujników.
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Non-aqueous Fracturing Technologies for Shale Gas Recovery
PublicationTechnologie szczelinowania wykorzystywane podczas wydobycia gazu z łupków zostały rozwinięte głównie w USA i są obecnie przystosowywane do warunków geologicznych i wymagań ekologicznych w innych państwach. Praca przedstawia literaturę na temat teoretycznych i praktycznych aspektów wydobycia gazu z łupków z naciskiem na technologie alternatywne do szczelinowania hydraulicznego. Rozpatrzono również techniczne i środowiskowe aspekty...
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Application of gas-steam mixture for wood drying purposes
PublicationW artykule przedstawiono wyniki suszenia drewna przy zastosowaniu mieszaniny parowo-gazowej. Badania dotyczyły suszenia drewna dębowego, sosnowego i świerkowego. We wszystkich eksperymentach skrócono czas suszenia w porównaniu z suszeniem konwencjonalnym.
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Investigation of electrocatalytic gas sensor properties in presence of chlorine
PublicationProperties of sensor based on Nasicon with two round shaped platinum electrodes are investigated. Influence of different chlorine concentrations on the sensor response is presented. Measurements in different temperatures have been performed in order to determine optimal sensor working temperature.
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Noise measurement setups for fluctuations enhanced gas sensing
PublicationObserwacje zjawisk fluktuacyjnych w sensorach gazów pozwala zwiększyć czułość i selektywność detekcji gazów. Problemem jest budowa prostego i taniego systemu do obserwacji tych zjawisk. W artykule przedstawiono dwa systemy pozwalające na obserwacje szumów w rezystancyjnych sensorach gazów dostępnych na rynku i prototypowych, wykonanych z warstwy nanocząstek o zbliżonych wymiarach.
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TWO-SHAFT GAS TURBINE TEACHING AND TESTING STATION
PublicationThe station was established as part of a project co-financed by the European Union with the funds of the European Regional Development Fund as part of the Infrastructure and Environment Operational Programme titled: “Establishment of state-of-the-art technical infrastructure for the Engineers of the Future learning programme at the Gdańsk University of Technology” executed in 2013-2015.
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Investigation of electrocatalytic gas sensor properties in presence of chlorine
PublicationIn this paper performance of an electrocatalytic sensor in presence of chlorine is investigated. Presented studies concern sensor prepared in ceramic technology based on NASICON as a solid electrolyte with two round shaped platinum electrodes. Measurements in different temperatures have been performed in order to determine optimal sensor working temperature.
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Generation of the vorticity mode by sound in a vibrationally relaxing gas
PublicationW badaniu została przedstawiona procedura wyprowadzenia nowego równania dla modu wirowego generowanego przez ultradźwięki w gazach z pobudzonymi stopniami swobody. Pokazano, że w pewnych warunkach kierunek linii prądu dla modu wirowego jest przeciwny w porównaniu do płynów ze standardowym tłumieniem. Teoria została zilustrowana na przykładzie generowania modu wirowego przez okresową wiązkę akustyczną ze słabą dyfrakcją poprzeczną.
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Gas sensing by resistance fluctuations in PdxWO3 nanoparticle films.
PublicationPrzedstawiono wyniki badań sensorów gazu wykonanych z nanocząstek WO3 z dodatkiem Pd. Stwierdzono, że badanie fluktuacji rezystancji tych sensorów może istotnie zwiększyć czułość wykrywania gazu w porównaniu z obserwacją wyłącznie rezystancji stałoprądowej.
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Higher-Order Statistics for Fluctuation-Enhanced Gas-Sensing.
PublicationPrzedstawiono wyniki badań eksperymentalnych wykrywania wybranych mieszanin gazów za pomocą analizy fluktuacji rezystancji obserwowanych w sensorach gazu. Do analizy obserwowanych fluktuacji wykorzystano gęstość widmową mocy oraz funkcję bispektrum.
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Operation of gas turbine engines as the index of their reliability and safety.
PublicationW referacie przedstawiono propozycję ilościowej interpretacji działania turbinowego silnika spalinowego, które (podobnie jak przedstawione w fizyce działania Hamiltona i Maupertiusa oraz działanie wynikające ze zmiany pędu ciała) jest rozpatrywane jako wielkość fizyczna z jednostką miary zwaną dżulosekundą [dżulsekunda]. Wykazano też, że taka interpretacja działania może być uznana za wskaźnik niezawodności, a w szczególnych przypadkach...
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Gas detection in semiconductor sensors using fluctuation phenomena
PublicationRozpatrzono problemy pomiaru szumów, kóre należy rozwiązać, gdy szumy traktuje się jako dodatkowe źródło informacji o gazach. Metoda szumowa (spektroskopia szumów rezystancyjnych, widma wyższych rzędów) daje więcej informacji polepszając czułość i seleKtywność czujnika.
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The gas corrosion of the cobalt base layer at elevated temperature
PublicationPrzedstawiono badania odporności na utlenianie i korozję w gorących gazach spalinowych napawanych laserowo warstw wykonanych ze stopu na bazie kobaltu.
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Green capsule phase microextraction employing hydrophobic monolithic sol-gel octadecyl siloxane platforms for the monitoring of organophosphorus pesticides in environmental water samples
PublicationIn this study, a novel, facile and green capsule phase microextraction (CPME) method is presented for the extraction and preconcentration of organophosphorus pesticides (i.e., chlorpyrifos, disulfoton, ethoprophos, fenchlorphos, prothiofos, and parathion-methyl) from environmental water samples. Monolithic sol-gel octadecyl siloxane (sol-gel C18) sorbent encapsulated within porous polypropylene capsules was synthesized, characterized,...
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Application of gas chromatography–tandem mass spectrometry for the determination of amphetamine-type stimulants in blood and urine
PublicationAmphetamine, methamphetamine, phentermine, 3,4-methylenedioxyamphetamine (MDA), 3,4-methylenedioxymethamphetamine (MDMA), and 3,4-methylenedioxy-N-ethylamphetamine (MDEA) are the most popular amphetamine-type stimulants. The use of these substances is a serious societal problem worldwide. In this study, a method based on gas chromatography-tandem mass spectrometry (GC-MS/MS) with simple and rapid liquid-liquid extraction (LLE)...
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Authenticity Assessment of the "Onisiówka" Nalewka Liqueurs Using Two-Dimensional Gas Chromatography and Sensory Evaluation
PublicationThe “Onisiówka” nalewka liqueur is a regional Polish alcoholic beverage, which is inscribed on the list of regional and traditional products of the Ministry of Agriculture and Rural Development in Poland. It is produced from multiflower honey, black elderberry flower syrup, and spirit. Due to fact that the “Onisiówka” nalewka liqueur has never been investigated, these studies are the foundation for further work on this regional...
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Application of dynamic headspace and gas chromatography coupled to mass spectrometry (DHS-GC-MS) for the determination of oxygenated volatile organic compounds in refinery effluents
PublicationThe paper presents a new procedure for the determination of oxygenated volatile organic compounds (O-VOCs) in postoxidative effluents from the production of petroleum asphalt using dynamic headspace coupled to gas chromatography-mass spectrometry in the selected ion monitoring (SIM) mode (DHSGC-MS). Among the GC capillary columns tested, a polar SLB-IL111 column with the ionic liquid stationary phase was found to be superior due...
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Thermal properties of a cement composite containing phase change materials (PCMs) with post-pyrolytic char obtained from spent tyres as a carrier
PublicationThis work examines the possible use of post-pyrolysis char made from spent vehicle tyres as a carrier for phase change materials (PCM), which could be used as an additive to cement mortar. Because of the ability of PCM to accumulate heat, the cement composite obtained from it, apart from its structural and strength properties, will acquire an additional energy storage function, which can be very important for energy-saving construction. In...
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Investigations on mixture preparation for two phase adiabatic pressure drop of R134a flowing in 5 mm diameter channel
PublicationThe article presents detailed two-phase adiabatic pressure drops data for refrigerant R134a. Study cases have been set for a mass flux varying from 200 to 400 kg/m2 s, at the saturation temperature of 19.4 ◦C. Obtained experimental data was compared with the available correlations from the literature for the frictional pressure drop during adiabatic flow. Influence of mixture preparation on pressure drop was investigated, for...
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Recent advances of selected passive heat transfer intensification methods for phase change material-based latent heat energy storage units: A review
PublicationThe following article overviews recent studies regarding heat transfer enhancement methods, explicitly focusing on fins and coils utilization, in phase change material-based latent heat thermal energy storage systems. It discusses the influence of various geometrical and material parameters on the melting and solidification processes, as well as the orientation of the heat transfer surface within the storage tank. Additionally,...
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Gas chromatography-olfactometry (GC-O), electronic noses (e-noses) and electronic tongues (e-tongues) for in vivo food flavour measurement
PublicationThe capter revies two types of artificial olfaction instrumentation, i.e. gas-chromatography-olfactometry (GC-O) and chemical sensor technologies (electronic nose and tongue), combined with multivariate data processing methods as promising approaches for rapid analysis of food. The chapter also includes examples of specific applications for the detection of food flavour and volatile components.
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Barium boron aluminum silicate glass system for solid state optical gas sensors
PublicationRecent increasing demand for new eco-friendly materials and for low cost fabrication process for use in optical sensors field, raise concern about alternative materials for this application. We have designed two glass-ceramics compositions from the quaternary ROAl2O3- SiO2-B2O3(R=Ba) alkali-earth aluminum silicate system, labeled B72 and B69, with high refractive index (>1.6), large values of Abbe number (94.0 and 53.0, respectively),...
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Electrical and mechanical characterization of two-phase alloys by means of scanning probe microscopy in dynamic impedance spectroscopy mode
PublicationDynamic impedance spectroscopy, evaluated for measuring non-stationary systems, was used in combination with scanning probe microscope. Using this approach, localized impedance measurements in the AFM contact mode could be carried out. Additionally, impedance–force curves were made at each phase of investigated materials to illustrate the relation between impedance and the force applied to a probe. Therefore, correlation of electrical...
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Deposition and characterization of organic polymer thin films using a dielectric barrier discharge with different C2Hm/N2 (m = 2, 4, 6) gas mixtures
PublicationOrganic polymer thin films have been deposited on Si(100) and aluminum coated glass substrates by a dielectric barrier discharge (DBD) operated at medium pressure using different C2Hm/N2 (m = 2, 4, 6) gas mixtures. The deposited films were characterized by various spectroscopic techniques. Fourier transform infrared reflection absorption spectroscopy (FT-IRRAS) revealed the chemical functional groups present in the films. The surface...
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Quantitative structure—retention relationships of some steroid and phenanthrene derivatives on cyano-, reversed-phase, and normal-phase thin-layer chromatography stationary phases
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Low-Cost Unattended Design of Miniaturized 4 × 4 Butler Matrices with Nonstandard Phase Differences
PublicationDesign of Butler matrices dedicated to Internet of Things and 5th generation (5G) mobile systems—where small size and high performance are of primary concern—is a challenging task that often exceeds capabilities of conventional techniques. Lack of appropriate, unified design approaches is a serious bottleneck for the development of Butler structures for contemporary applications. In this work, a low-cost bottom-up procedure for...
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Physical properties of homogeneous TiO2 films prepared by high power impulse magnetron sputtering as a function of crystallographic phase and nanostructure
PublicationOptical, photo-electrochemical, crystallographic and morphological properties of TiO2 thin films prepared by high power impulse magnetron sputtering at low substrate temperatures (<65 ◦C) without post-deposition thermal annealing are studied. The film composition-anatase, rutile or amorphous TiO2-is adjusted by the pressure (p ∼ 0.75-15 Pa) in the deposition chamber. The different crystallographic phases were determined with grazing...
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Quantification of unconjugated and total ibuprofen and its metabolites in equine urine samples by gas chromatography–tandem mass spectrometry: Application to the excretion study
PublicationIbuprofen (IBU) is a widely used nonsteroidal anti-inflammatory drug (NSAID) in human and also veterinary medicine. NSAIDs are usually highly metabolized compounds in horses; they are often present in equine urine, mostly in their conjugated forms (glucuronides). Thus, hydrolysis to cleave the glucuronide linkage prior to anti-doping analysis is often necessary for improving detection. In this study, unconjugated and total IBU...
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A Comparison of Ammonia Emission Factors from Light-Duty Vehicles Operating on Gasoline, Liquefied Petroleum Gas (LPG) and Compressed Natural Gas (CNG)
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Nitrogen oxides removal from hydrogen flue gas using corona discharge in marine boilers: Application perspective
PublicationThis paper focuses on the combustion of hydrogen in boilers, as it appears to be a more effective method than using fuel cells for heating purposes due to higher boiler efficiency. One of the main disadvantages of hydrogen combustion in air is NOx formation. Therefore, the authors decided to introduce corona discharge as an inno- vative technique to clean hydrogen flue gas by effectively reducing NOx levels. The method involves...
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Experimental study on single phase operation of microjet augmented heat exchanger with enhanced heat transfer surface
PublicationThe article presents experimental investigations on a prototype heat exchanger. Presented research is focused on combined active and passive enhancement techniques of surface modification and microjet impingement. The results were compared to reference plate heat exchanger without microjet impingement. The Wilson plot method was applied to determine the heat transfer coefficients in the single phase operation. The heat exchanger...
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Impacts of Using Exhaust Gas Recirculation and Various Amount of Dimethyl Ether Premixed Ratios on Combustion and Emissions on a Dual-Fuel Compression Ignition Engine
PublicationIn the presented research, the authors dealt with the specific properties of the combustion process of dimethyl ether (DME) in a combustion car (Volkswagen Golf IV) engine AJM 1.9 TDI PDE made by Volkswagen factory. Dimethyl ether is an alternative fuel produced most often from natural gas, which can be used in compression ignition engines as a single fuel or co-burned with diesel oil. This work describes the impacts of using exhaust...
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Sensitive simultaneous determination of 19 fluorobenzoic acids in saline waters by solid-phase extraction and liquid chromatography–tandem mass spectrometry
PublicationA solid-phase extraction (SPE) procedure using C18 stationary phase was optimized for the preconcentration of 19 fluorinated derivatives of benzoic acid (FBA): mono-, di-, tri-, and tetrafluorosubstituted in the ring, trifluoromethylbenzoic acid and 3,5-bistrifluoromethyl benzoic acid from undiluted salt-rich (>20%) reservoir waters. Quantitative (>90%) retention/elution of 16 out of 19 analyte compounds was achieved allowing a...
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Two-phase optimizing approach to design assessments of long distance heat transportation for CHP systems
PublicationCogeneration or Combined Heat and Power (CHP) for power plants is a method of putting to use waste heat which would be otherwise released to the environment. This allows the increase in thermodynamic efficiency of the plant and can be a source of environmental friendly heat for District Heating (DH). In the paper CHP for Nuclear Power Plant (NPP) is analyzed with the focus on heat transportation. A method for effectivity and feasibility...
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Preparation and evaluation of 1,3-alternate 25,27-bis-(pentafluorobenzyloxy)-26,28-bis-(3-propyloxy)-calix[4]arene-bonded silics gel high performance liquid chromatography stationary phase
PublicationA 1,3-alternate 25,27-bis-(pentafluorobenzyloxy)-26,28-bis-(3-propyloxy)-calix[4]arene-bonded silica gel stationary phase (CalixBzF10) was synthesized, structurally characterized, and used as a selector in liquid chromatography. The selectivity study of this phase was done by using fluorine-containing compounds (fluorobenzenes, fluoro-pyrimidine bases), as well as non-fluorinated analytes (non-steroidal anti-inflammatory drugs,...