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Search results for: MINIMALLY CONSCIOUS STATE
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Tailoring of SiOC composition as a way to better performing anodes for Li-ion batteries
PublicationPolymer derived silicon oxycarbide (SiOC) ceramics are investigated as potential anodes for lithiumion batteries. Different SiOC ceramics are prepared by pyrolysis (1000 °C and 1400 °C under controlled argon atmosphere) of polysiloxanes ceramic precursors. Preceramic polymers are synthesized using the sol–gel method. Phenyltriethoxysilane (PhTES) and methyltriethoxysilane (MTES) have been used as starting precursors and mixed with...
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Electronic conductivity in the SiO2-PbO-Fe2O3 glass containing magnetic nanostructures
PublicationThe linear impedance spectra of iron–silicate–lead glass samples were measured in the frequency range from 1 MHz to 1 MHz and in the temperature range from 153 K to 423 K. The structure was investigated by means of XRD and atomic force microscopy. Local electrical and magnetic properties of the samples were tested with the aid of electrostatic force microscopy (EFM) and magnetic force microscopy (MFM). The obtained results show...
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Electrical properties and structure of lead-borate glass containing iron ions.
PublicationThe ac and dc conductivity in iron–lead-borate glass samples was investigated in the frequency range from 1 mHz to 1 MHz and in the temperature range from 153 K to 423 K. The structure was investigated by the means of atomic force microscopy (AFM) and the crystalline phases (if present) were identified by the means of X-ray diffractometry. Two types of ac electrical behaviour were observed. The first group of glass samples which...
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Investigation of catalytic layers on anode for solid oxide fuel cells operating with synthetic biogas
PublicationIn this paper solid oxide fuel cells operating with dry synthetic biogas have been examined. In order to increase their stability the layers of CuO-CeO2, Cu1.3Mn1.7O4 and Y0.08Sr0.92Ti0.8Fe0.2O3 -δ have been deposited on the Ni-YSZ anode site. These layers should catalyze the internal biogas reforming and prevent the carbon deposition on the anode site. It has been found that CuO-CeO2 and Cu1.3Mn1.7O4 catalysts led to an increase...
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The Influence of Modelling Material Zones on Strains and Stresses at Weld Toe Notch
PublicationThe latest development in the field of welding technology enabled prefabrication of thin-walled sandwich structures in an industrial scale. Sandwich structures fabricated of steel, or aluminium alloy plates and stiffeners are welded with the use of hi-power CO2 lasers. Strength analysis of such structures with the use of finite element method needs proper material modelling.In this paper the material model of steel sandwich panel...
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Photoelectrochemical properties of BIMEVOX (ME=Cu, Zn, Mn) electrodes in contact with aqueous electrolyte
PublicationLayered oxide Bi4O2O11 and mixed oxides of bismuth, vanadium and a third metal (ME = Cu, Zn, Mn) were synthesized and characterized using XRD, Raman and SEM. The energy band gap (Eg) of samples determined using UV–VIS reflectance spectra equals to 2.46, 2.34, 2.27 and 2.18 eV for Bi4V2O11, BICUVOX (Bi2V1 − xCuxO5.5 − 3x/2), BIZNVOX (Bi2V1 − xZnxO5.5 − 3x/2) and BIMNVOX (Bi2V1 − xMnxO5.5 − x/2) (x = 0.1), respectively. Open circuit...
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Multi Parameter Sliding Test Result Evaluation for The Selection of Material Pair for Wear Resistant Components of a Hydraulic motor Dedicated for Use With Environmentally Friendly Working Fluids
PublicationIn the paper the method and results are presented of the testing of tribological performance of a number of hard materials available commercially. The tests consisted in unidirectional sliding with liquid lubrication. The load and velocity regime chosen were similar to a standard four-ball lubricity test with constant velocity and load increasing over time. The regime was modified in such a way that over the initial part of the...
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Influence of Spatial Structures of 316L Stainless Steel on Its Cavitation Erosion Resistance
PublicationCavitation erosion performance of modified macroscopic internal structure 316L stainless steel was investigated. The samples processed by means of SLM method were subjected to cavitation erosion test. The scanning electron microscope Philips 30/ESEM was used to examine morphology of eroded surface.
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Effect of Some Sulphur Additives on The Degradation of 9Cr-1Mo Steel After Its 10 Years Service in The CCR Platforming Unit
PublicationThe work shows the results of the tests of 9Cr-1Mo steel, which was for 10 years operated in the CCR platforming unit in Group Lotos SA in Gdańsk, and then in the laboratory was sulphidised during 166 h at a temperature of 600 °C. Sulphidation was performed in a mixture of H2-H2S gases at the vapour pressure of sulphur 4.1·10-14 atm, so the order of magnitude of vapour pressure was less than that of the dissociation pressure of...
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Nonlinear and linear impedance of bismuth vanadate ceramics and its relation to structural properties
PublicationThe nonlinear and linear electrical properties, topography, and microstructure of bismuth-vanadate ceramics, were studied. The structurewas observed with the use of X-ray diffraction (XRD), scanning electronmicroscopy (SEM), atomic force microscopy (AFM) and confocal microscopy methods. The obtained results showed that ceramic is porous. Two phase transitionswere determinedwith the use of DSC measurements. The linear and nonlinear ac...
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Fabrication and properties of electrode material composed of ordered titania nanotubes and pEDOT:PSS
PublicationWe report on the two-stage preparation method of electrode material composed of titania nanotubes and poly(3,4-ethylenedioxythiopene):poly(2-styrenesulphonate) conductive polymer (pEDOT:PSS). Initially, titania nanotube arrays were produced by the anodization process of Ti substrate. Next, the polymer was potentiostatically deposited onto the thermally annealed nanotube arrays from the electrolyte containing monomer and counter...
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Properties of Nasicon-based CO2 sensors with Bi8Nb2O17 reference electrode
PublicationPotentiometric CO2 sensors based on Nasicon (Na+ conductor, Na3Zr2Si2PO12) electrolyte, Bi8Nb2O17/Pt reference electrode and different sensing electrodes have been prepared. Besides the sensing electrode material, sensors differ from each other in the reference electrode preparation technique. The main aim of this study is to investigate sensor construction and electrode fabrication process influence on sensor properties. The optimal...
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Cation diffusion coefficients in CuAgI via molecular dynamics simulations
PublicationPraca prezentuje wyniki analizy strukturalnej otrzymane poprzez symulacje dynamiczno-molekularne (zespół NpT, dwuciałowy potencjał Vashisty-Rahmana) superjonowego związku o składzie (1-x)Cu-xAg-I, x = 0.0, 0.25, 0.5, 0.75, 1.0). Wyznaczono wartość współczynnika dyfuzji kationów i energii aktywacji w funkcji składu szkła i temperatury. Otrzymane rezultaty porównano z danymi literaturowymi.
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Transport of alkali metal cations in poly(3,4-ethylenethiophene) films.
PublicationElektrochemicznie otrzymana warstwa kompozytowa złożona z poli(3,4-etyleno-dioksytiofenu) i poli(styrenosulfonianu) podczas polaryzacji ulega odwracalnemu procesowi sorpcji-desorpcji kationów z elektrolitu zewnętrznego. Transportowi jonowemu towarzyszą cząsteczki wody (rozpuszczalnika). Ilość cząsteczek wody przypadająca na jednostkowy kation metali alkalicznych została wyznaczona za pomocą metody elektrochemicznej mikrowagi...
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Mixed ionic polaron transport and rapid crystallization in (Bi, Pb)-Sr-Ca-Cu-O glass.
PublicationPrzedstawiono rezultaty pomiarów zmiennoprądowego przewodnictwa elektrycznego w szkłach (Bi,Pb)-Sr-Ca-Cu-O. Zaobserwowano dwa mechanizmy przewodnictwa.Zaproponowano hopping małych polaronów i dyfuzję jonów Cu(I) jako mechanizmy przewodnictwa.
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Ionic conductivity of bismuth silicate and bismuth germanate glasses.
PublicationPrzedstawiono wyniki badań przewodnictwa d.c i a.c. szkieł BixGe1-xO2-0.5x (gdzie x=0.13, 0.23, 0.33, 0.47) i BixSi1-xO2-0.5x (gdzie x=0.47, 0.57, 0.67). Wyniki sugerują, że przewodnictwo elektryczne jest zdeterminowane ruchem jonów tlenu. Znaczący wzrost przewodnictwa elektrycznego przy x> 0.33 został wytłumaczony na podstawie faz perkolacyjnego modelu ruchu jonów w podsieci BiO5-6.
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Electronic conductivity in Na2O-FeO-P2O5 glasses. oz.
PublicationZbadano przewodnictwo stałe i zmiennoprądowe w szkłach: 50P2O5-(50-x)FeO-xNa2O i 50P2O5-(50-x)FeO-xCaO, gdzie x zmieniano od 7 do 20mol%. Wykazano,że zamiana CaO na Na2O w małym stopniu zmienia przewodnictwo elektryczne szkieł, co sugeruje, że przewodnictwo w szkłach zawierających Na2O ma charakter elektronowy. Do badania procesów migracji elektronów i jonów zastosowano metodę tarcia wewnętrznego. W widmie tarcia wewnętrznego...
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Structural and electrical transport studies of reduced in hydrogen surfaceof bismuth germanate glass
PublicationOtrzymano nanostruktury krystalicznego bizmutu w matrycy szkła germanowegooraz warstwę nanostruktur krystalicznego bizmutu na powierzchni redukowanegow atmosferze wodoru szkła Bi0.33Ge0.67O1.83. Zaproponowano prosty model bu-dowy zredukowanych szkieł bizmutowo-germanowych potwierdzony wynikami badańAFM i XRD. Zbadano wpływ czasu i temperatury redukcji oraz topnienia bizmu-tu na własności elektryczne badanych szkieł. Przeanalizowano...
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Chemical instability of the cobalt oxyhydrate superconductor under ambientconditions.
PublicationPrzedstawiono badania dyfrakcyjne i termograwimetryczne uwodnionego, sodowo-kobaltowego tlenku nadprzewodzącego: NaxCoO2 yH2O (y=1.4). Materiał ten jest niestabilny już w temperaturze pokojowej i przechodzi w nowo odkrytą fazę = 0.6.
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Phase investigations of copper based CuZn38Al2MnFe alloy
PublicationW pracy przedstawiono analizę fazową mosiądzu CuZn38Al2MnFe. Wykazano, że obecność fazy Fe4Mn77Si19 powoduje kruchość stopu w teście zginania próbek.
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Establishing Relationships between Parameters of the controlled Compaction Soil by Using Various In-Situ Tests
PublicationThe aim of research was evaluating reliable correlations between chosen soil parameters describing state of surface layers of soil. The paper presents site comparative tests based on the light falling weight deflectometer (LFWD), the static plate load tester (VSS), the dynamic probing light tester (DPL) and the bearing ratio tester (CBR in-situ) with relationships between soil state parameters. All featured in-situ...
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No-local-broadcasting theorem for multipartite quantum correlations
PublicationWe prove that the correlations present in a multipartite quantum state have an operational quantum character even if the state is unentangled, as long as it does not simply encode a multipartite classical probability distribution. Said quantumness is revealed by the new task of local broadcasting, i.e., of locally sharing preestablished correlations, which is feasible if and only if correlations are stricly classical. Our operational...
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Dual role of oxygen-related defects in the luminescence kinetics of AlNMn2+
Open Research DataThis dataset presents the impact of temperature and pressure on AlN:Mn2+ luminescence kinetics. Unusual behavior of Mn2+ optical properties during UV excitation is observed, where a strong afterglow luminescence of Mn2+ occurs even at low temperatures. When the temperature increases, the contribution of the afterglow luminescence is further enhanced,...
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The XAS spectra of O-K edges, Fe-L edges in pristine, La-, and Nb-doped SFM in 3 states: as-prepared, reduced and reoxidized
Open Research DataThis dataset contains the normalized and exported to *.txt spectra for x-ray absorption spectroscopy. The samples analyzed were strontium ferrite molybdate based, doped with lanthanum and niobium. The powders were measured in as-prepared state (denoted in filename as AP), reduced (red) and reoxidized (reox). The filenames are written accordingly: Edge_(optional:...
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The OpenMolcas Web: A Community-Driven Approach to Advancing Computational Chemistry
Open Research DataThe developments of the open-source OpenMolcas chemistry software environment since spring 2020 are described, with a focus on novel functionalities accessible in the stable branch of the package or via interfaces with other packages. These developments span a wide range of topics in computational chemistry and are presented in thematic sections: electronic...
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The XRD diffraction patterns of (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials after reduction at 900 deg.C in hydrogen
Open Research DataThe (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials were synthesized via the solid state reaction method and examined as a potential anode material. First, the mixed oxide reagents were pressed into pellets and calcined at 1200 °C for 12 hours to decompose most of the organic compounds. The resulting calcined pellet was ground...
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The structure of the Polish banking sector in 2004-2018
Open Research DataDynamic changes in the banking system in the 1990s contributed to the relative stability of the number of banks in all sectors (state-owned, private, cooperative) after 2004. The total number of banks (including credit institutions) has decreased since 2004 from 653 to 612 in 2018 - it should therefore be noted that in the analyzed period the Polish...
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The XRD diffraction patterns of (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials after reduction at 1000 deg.C in hydrogen
Open Research DataThe (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials were synthesized via the solid state reaction method and examined as a potential anode material. First, the mixed oxide reagents were pressed into pellets and calcined at 1200 °C for 12 hours to decompose most of the organic compounds. The resulting calcined pellet was ground...
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The XRD diffraction patterns of (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials after reduction at 1100 deg.C in hydrogen
Open Research DataThe (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials were synthesized via the solid state reaction method and examined as a potential anode material. First, the mixed oxide reagents were pressed into pellets and calcined at 1200 °C for 12 hours to decompose most of the organic compounds. The resulting calcined pellet was ground...
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XPS measurements of the Fe-Pb-Si based glass
Open Research DataGlass samples with nominal compositions of xFe2O3-(50-x)PbO–50SiO2, where x = 12.5, 15, 17.5 (mol%) were prepared. Analytical grade substrates were used: Fe2O3, SiO2, and PbO. The appropriate amounts of reagents were mixed in an agate mortar. The powders obtained were melted in porcelain un-enamelled crucibles in an electric furnace at a temperature...
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Joanna Rymaszewska prof. dr hab. n. med.
PeopleCV Joanna Rymaszewska Wroclaw University of Science and Technology, Wroclaw, Poland +48 601 98 26 24, joanna.rymaszewska@pwr.edu.pl orcid.org/0000-0001-8985-3592 2023 → Professor of Wroclaw University of Science and Technology (WUST), Poland 2011 → 2023 Professor of Wroclaw Medical University (WMU), PL 2016 → 2022 Head of the Department of Psychiatry, Wroclaw Medical University 2016 → 2022 Head of the Clinic of Psychiatry,...
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Ce site dilution effects in the antiferromagnetic heavy fermion CeIn3
PublicationLa-doped intermetallic single crystals of Ce1−xLaxIn3 were synthesized via an In self-flux method throughout the entire range (x = 0–1). The prototypical heavy-fermion compound CeIn3 shows an antiferromagnetic phase transition at 10.1 K and becomes superconducting near a critical pressure where TN is completely suppressed. As the La concentration increases, Ce moments are diluted, and the lattice constant increases linearly, satisfying Vegard’s...
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Dia- and paramagnetic contributions to magnetizabilities of relativistic hydrogenlike atoms in some low-lying discrete energy eigenstates
PublicationIn this paper we present tabulated data for relative diamagnetic and paramagentic contributions to the magnetizability ($\chi$) of the relativistic hydrogenlike atoms with a pointlike, motionless and spinless nucleus of charge $Ze$. Utilizing general analytical formulas for the diamagnetic ($\chi_{d}$) and paramagnetic ($\chi_{p}$) components of $\chi$, recently derived by us [P. Stefa{\'n}ska, 2020] with the aid of the Gordon...
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The symmetric extendibility of quantum states
PublicationStudies on the symmetric extendibility of quantum states have become particularly important in the context of the analysis of one-way quantum measures of entanglement, and the distillability and security of quantum protocols. In this paper we analyze composite systems containing a symmetric extendible part, with particular attention devoted to the one-way security of such systems. Further, we introduce a new one-way entanglement...
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Application of a stochastic compartmental model to approach the spread of environmental events with climatic bias
PublicationWildfires have significant impacts on both environment and economy, so understanding their behaviour is crucial for the planning and allocation of firefighting resources. Since forest fire management is of great concern, there has been an increasing demand for computationally efficient and accurate prediction models. In order to address this challenge, this work proposes applying a parameterised stochastic model to study the propagation...
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An observability and detectability analysis for non-linear uncertain CSTR model of biochemical processes
PublicationThe problem of proving observability/detectability properties for selected non-linear uncertain model of biochemical processes has been addressed in this paper. In particular, the analysis of observability/detectability in the face of parametric and unstructured uncertainty in system dynamics transformed into unknown inputs, and unknown initial conditions has been performed. Various sets of system measured outputs were taken into...
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Design of Intelligent Low-Voltage Load Switch for Remote Control System in Smart Grid
PublicationCurrent low-voltage load switches do not support remote disconnect/connect and real-time monitoring of a disconnect/connect state. Addressing to these issues, this paper presents a low-voltage load switch for a smart remote control system, which uses a one-chip microcontroller board and a DC step motor drive mechanism and provides the feedback on the switch status also. Arrears disconnect and full-pay connect control is implemented...
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Application of electrochemical impedance spectroscopy to monitoring discharging process of nickel/metal hydride battery.
PublicationThis paper presents the possibility of applying impedance analysis to cell diagnostics. In order to obtain characteristic curves of both electrodes of a NiMH battery simultaneously, a reference electrode was added into the circuit. The authors analysed the cell under three cases, i.e. when its properties are determined only by the state of the positive electrode, only by the state of the negative electrode, or when both electrodes...
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Mechanism of Osmolyte Stabilization–Destabilization of Proteins: Experimental Evidence
PublicationIn this work, we investigated the influence of stabilizing (N,N,N-trimethylglycine) and destabilizing (urea) osmolytes on the hydration spheres of biomacromolecules in folded forms (trpzip-1 peptide and hen egg white lysozyme─hewl) and unfolded protein models (glycine─GLY and N-methylglycine─NMG) by means of infrared spectroscopy. GLY and NMG were clearly limited as minimal models for unfolded proteins and should be treated with...
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Ultrafast Intramolecular Relaxation and Wave-Packet Motion in a Ruthenium-Based Supramolecular Photocatalyst
PublicationThe hydrogen-evolving photocatalyst [(tbbpy)2 Ru(tpphz)Pd(Cl)2 ](2+) (tbbpy=4,4'-di-tert-butyl-2,2'-bipyridine, tpphz=tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazine) shows excitation-wavelength-dependent catalytic activity, which has been correlated to the localization of the initial excitation within the coordination sphere. In this contribution the excitation-wavelength dependence of the early excited-state relaxation...
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Photophysics of a Ruthenium 4H-Imidazole Panchromatic Dye in Interaction with Titanium Dioxide
PublicationThe photophysics of bis(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)[2-(4-carboxyphenyl)-4,5-bis(p-tolylimino-κN)imidazolato]ruthenium(II) hexafluorophosphate is investigated, both in solution and attached to a nanocrystalline TiO2 film. The studied substitution pattern of the 4H-imidazole ligand is observed to block a photoinduced structural reorganization pathway within the 4H-imidazole ligand that has been previously investigated....
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Photoelectron and threshold photoelectron valence spectra of pyridine
Publication. The pyridine molecule has been examined by the means of photoelectron and threshold photoelectron spectroscopies. Ionization energies were determined for both outer and inner valence orbitals and new adiabatic values were also resolved. Vibronic structure associated with several states was assigned mainly to be due to C–C stretches and ring bends. Additionally a Rydberg state converging to 7b2 state was ascribed. The data shown...
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Monitoring of the Process of System Information Broadcasting in Time
PublicationOne of the problems of quantum physics is how a measurement turns quantum, noncopyable data, towards copyable classical knowledge. We use the quantum state discrimination in a central system model to show how its evolution leads to the broadcasting of the information, and how orthogonalization and decoherence factors allow us to monitor the distance of the state in question to the one perfectly broadcasting information, in any...
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Broken rotor symptoms in the sensorless control of induction machine
PublicationThe purpose of this paper is to investigate the need for a universal method for sensorless controlled induction motor drive diagnosis. The increasing number of sensorless control systems in industrial applications require a universal method for the drive diagnosis, which provides reliable diagnostic reasoning independent of control system structure and state variables measurement or estimation method.Simulations and experimental...
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PI observer stability and application in an induction motor control system
PublicationThe paper discusses the problem of stability of a proportional-integral Luenberger observer, designated for the state variables reconstruction of a linear, time-invariant dynamical system.
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Targi Pracy GUT International Career Day 2020
EventsBiuro Karier PG oraz Dział Międzynarodowej Współpracy Akademickiej zapraszają na Targi Pracy – GUT International Career Day. Zaproszone firmy przedstawią oferty pracy, praktyk i staży.
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Methodology for implementing power plant efficiency standards for power generation: potential emission reduction
PublicationSome methods of generating power such as power generation through coal, natural gas, oil result in inevitable emissions of greenhouse gases. While power generation is necessary due to its increasing demand, it is important for power companies to generate their power in an efcient manner to reduce its efect on the environment. One of the most efective ways of tackling inefciency issues is through the implementation of efciency standard....
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Chemical and biological characterization of Ocimum basilicum L. phenolic extract and essential oil derived through ultrasound and microwave-assisted extraction techniques
PublicationPlant-derived bioactive molecules are increasingly utilized in food processing as natural additives, driven by a growing interest in healthier lifestyles. This trend has spurred industries to reformulate products to meet the demands of health-conscious consumers. This study investigates the phenolic extract and essential oil of O. basilicum L. obtained via ultrasound-assisted extraction and microwave-assisted extraction, respectively. Characterization...
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Maciej Łuszczek dr hab. inż.
PeopleMaciej Łuszczek born in 1967 in Gdynia. He received the M.Sc. degree in Applied Physics in 1991, the Ph.D. degree in 1999, and the D.Sc. (‘habilitation’) degree in 2015, all from the Gdańsk University of Technology. Since 1991 he has been with the above university, initially at the Faculty of Applied Physics and Mathematics, Department of Solid State Physics, and currently (since 2015) at the Faculty of Electrical and Control Engineering,...
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Two-dimensional hydrogen-like atom in a weak magnetic field
PublicationWe consider a non-relativistic two-dimensional (2D) hydrogen-like atom in a weak, static, uniform magnetic field perpendicular to the atomic plane. Within the framework of the Rayleigh-Schr¨odinger perturbation theory, using the Sturmian expansion of the generalized radial Coulomb Green function, we derive explicit analytical expressions for corrections to an arbitrary planar hydrogenic bound-state energy level, up to the fourth...