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Search results for: PCA ANALYSIS
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Impact of a newly-formed periglacial environment and other factors on fresh water chemistry at the western shore of Admiralty Bay in the summer of 2016 (King George Island, Maritime Antarctica)
PublicationThis study provides a comprehensive analysis of the inorganic chemistry of flowing water at the western shore of Admiralty Bay. In the water samples, ions, and major and trace metals (and B)were detected and quantified. Additionally, the parameters of pH, specific electrolytic conductivity (SEC25) and total organic carbon (TOC) were determined. Moreover, multivariate data set was created and Principal Component Analysis (PCA) was...
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A nontargeted approach to determine the authenticity of Ginkgo biloba L. plant materials and dried leaf extracts by liquid chromatography-high-resolution mass spectrometry (LC-HRMS) and chemometrics
PublicationThe lack of stringent regulations regarding raw materials for herbal supplements used for medicinal purposes has been a constant challenge in the industry. Ginkgo biloba L. leaf extracts attract consumers because of the supposed positive effect on mental performance and memory. Supplements are produced using dried leaf materials and standardized leaf extracts such as EGb 761. Adulteration of Ginkgo biloba L. plants and extracts...
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Analyzing the Effectiveness of the Brain–Computer Interface for Task Discerning Based on Machine Learning
PublicationThe aim of the study is to compare electroencephalographic (EEG) signal feature extraction methods in the context of the effectiveness of the classification of brain activities. For classification, electroencephalographic signals were obtained using an EEG device from 17 subjects in three mental states (relaxation, excitation, and solving logical task). Blind source separation employing independent component analysis (ICA) was...
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Gas mixtures recognition using an array of amperometric gas sensors with drifting or faulty sensors
PublicationIn this study, the possibility of using selected methods for diagnostics of performance of matrix composed with six amperometric electrochemical gas sensors is investigated. Measurements of sensor responses in selected concentrations of single toxic gases or gas mixtures were performed and were repeated over time to show sensor drift. Additionally, the studies on the sensors’ drift were performed. The drift has been recognized...
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The Use of Electronic Nose for Sunflower and Rapeseed Oil Classification
PublicationThe electronic nose is an analytical device often used in food industries to examine the authenticity of their products. The use of the electronic nose allows for a rapid assessment of the quality of food. The oil samples from sunflower and rapeseed were used in this study. Both oil samples were kept inside the thermostat incubator at different ranging from 20oC to 180oC with increment of 40oC. Principal Component Analysis (PCA)...
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The Use of Electronic Nose for Sunflower and Rapeseed Oil Classification
PublicationThe electronic nose is an analytical device often used in food industries to examine the authenticity of their products. The use of the electronic nose allows for a rapid assessment of the quality of food. The oil samples from sunflower and rapeseed were used in this study. Both oil samples were kept inside the thermostat incubator at different ranging from 20oC to 180oC with increment of 40oC. Principal Component Analysis (PCA)...
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Data-driven models for fault detection using kernel pca:a water distribution system case study
PublicationKernel Principal Component Analysis (KPCA), an example of machine learning, can be considered a non-linear extension of the PCA method. While various applications of KPCA are known, this paper explores the possibility to use it for building a data-driven model of a non-linear system-the water distribution system of the Chojnice town (Poland). This model is utilised for fault detection with the emphasis on water leakage detection....
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Computational complexity and length of recorded data for fluctuation enhanced sensing method in resistive gas sensors
PublicationThis paper considers complexity and accuracy of data processing for gas detection using resistance fluctuation data observed in resistance gas sensors. A few selected methods were considered (Principal Component Analysis – PCA, Support Vector Machine – SVM). Functions like power spectral density or histogram were used to create input data vector for these algorithms from the observed resistance fluctuations. The presented considerations...
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Gas Detection Using Resistive Gas Sensors And Radial Basis Function Neural Networks
PublicationWe present a use of Radial Basis Function (RBF) neural networks and Fluctuation Enhanced Sensing (FES) method in gas detection system utilizing a prototype resistive WO3 gas sensing layer with gold nanoparticles. We investigated accuracy of gas detection for three different preprocessing methods: no preprocessing, Principal Component Analysis (PCA) and wavelet transformation. Low frequency noise voltage observed in resistive gas...
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Water chemistry of tundra lakes in the periglacial zone of the Bellsund Fiord (Svalbard) in the summer of 2013
PublicationClimate changes observed in the Arctic (e.g. permafrost degradation, glacier retreat) may have significant influence on sensitive polar wetlands. The main objectives of this paper are defining chemical features of water within six small arctic lakes located in Bellsund (Svalbard) in the area of continuous permafrost occurrence. The unique environmental conditions of the study area offer an opportunity to observe phenomena influencing...
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Differentiation Between Spirits According to Their Botanical Origin
PublicationAgricultural distillates are used for the production of spirit beverages. As more and more products with a specific botanical composition specified on the label are produced (e.g. rye vodkas, wheat vodkas and Polish Vodka, which cannot be produced with the addition of maize distillate), it is necessary to look for quicker and more accurate methods allowing the determination of botanical origin of alcoholic beverages and materials...
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Comparison of the Physical and Sensory Properties of Hybrid Citrus Fruit Jaffa® Sweetie in Relation to the Parent Fruits
PublicationIn the presented study, an overall Jaffa sweetie evaluation was made to find a correlation between Citrus grandis Osbeck × Citrus paradisi Macf. and its parent fruits’ (Citrus grandis Osbeck, Citrus paradisi Macf.) properties. Based on the sensory analysis, it was found that the taste and aroma of the new hybrid fruit are close to pummelo. By the use of chromatographic analysis, the selected monoterpenes present in the fruits were...
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Detection of apple in orange juice using ultra-fast gas chromatography
PublicationThe determination of authenticity is an increasingly important issue for food quality and safety. The use of an electronic nose based on ultra-fast gas chromatography technique ensures rapid analysis of the volatile compounds from food products. Due to the fact that this technique enables chemical profiling of agricultural products, it can be an effective tool for authentication when combined with chemometrics. In this article...
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Application of chemometric techniques in studies of toxicity of selected commercially available products for infants and children
PublicationThe goal of the present study is to assess the impact of the experimental conditions for extraction procedures (time of extraction, thermal treatment and type of extraction media) as applied to several baby and infant products checked for their possible ecotoxicological response when tested by various ecotoxicity tests(Microtox®, Ostracodtoxkit F™and Xenoscreen YES/YAS™). The systems under consideration are multidimensional by...
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Seashore sediment and water chemistry at the Admiralty Bay (King George Island, Maritime Antarctica) – geochemical analysis and correlations between the concentrations of chemical species
PublicationThis study covers water and sediment chemical characteristics by the western shore of Admiralty Bay (King George Island, Antarctica) in 2016. Chemical processes between sediment and water have been described based on the determination of ions, metals, non-metals, and TOC concentrations. Rock weathering is an important source of Fe, Ni, Co, Al in the seashore area. The PCA shows the impact of acidification in the release metals...
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APPLICATION OF ULTRAFAST GAS CHROMATOGRAPHY TO RECOGNIZE ODOR NUISANCE
PublicationPotentialities of ultrafast gas chromatography applied to periodical monitoring of odor nuisance originating from a municipal landfill have been examined. The results of investigation on classification of the atmospheric air samples collected in a vicinity of the landfill during winter and summer season have been presented. The investigation was performed using ultrafast gas chromatography of Fast/Flash GC type HERACLES II by Alpha...
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Typology of towns in the peripheries of Polish coastal regions: conclusions for urban policy
PublicationPeripheries means the land outside metropolitan areas. One of the main problemsin these areas is a lack of growth factors. Some towns can contribute to the developmentof these regions, because there are few such factors, and it is easier to create the newones, especially in urban policy.The subject of this paper is a typology of towns within the Polish peripheral coastalregions, limited to towns with more than 5 thousand inhabitants....
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Performance evaluation and model-based optimization of the mainstream deammonification in an integrated fixed-film activated sludge reactor
PublicationThis study aimed to model and optimize mainstream deammonification in an integrated fixed-film activated sludge (IFAS) pilot plant under natural seasonal temperature variations. The effect of gradually decreasing temperature on the performance was evaluated during a winter season and a transition period to summer conditions, and the correlation of the performance parameters was investigated using principal component analysis (PCA)....
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Music Data Processing and Mining in Large Databases for Active Media
PublicationThe aim of this paper was to investigate the problem of music data processing and mining in large databases. Tests were performed on a large data-base that included approximately 30000 audio files divided into 11 classes cor-responding to music genres with different cardinalities. Every audio file was de-scribed by a 173-element feature vector. To reduce the dimensionality of data the Principal Component Analysis (PCA) with variable...
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Music Mood Visualization Using Self-Organizing Maps
PublicationDue to an increasing amount of music being made available in digital form in the Internet, an automatic organization of music is sought. The paper presents an approach to graphical representation of mood of songs based on Self-Organizing Maps. Parameters describing mood of music are proposed and calculated and then analyzed employing correlation with mood dimensions based on the Multidimensional Scaling. A map is created in which...
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Rapid assessment of the authenticity of limequat fruit using the electronic nose and gas chromatography coupled with mass spectrometry
PublicationCitrus fruits are very popular food products. There are many species and varieties of them. There are also documented cases of some citrus fruits causing a severe allergic reaction. Some species of the citrus fruits, especially hybrid ones show a reduced allergenic effect due to the lack of seeds. There is a need for rapid methods for evaluation of citrus’ botanical origin. During research, the headspace of three citrus fruits...
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Efficiency of gas detection algorithms using fluctuation enhanced sensing
PublicationEfficiency of various gas detection algorithms by applying fluctuation enhanced sensing method was discussed. We have analyzed resistance noise observed in resistive WO3- nanowires gas sensing layers. Power spectral densities of the recorded noise were used as the input data vectors for two algorithms: the principal component analysis (PCA) and the support vector machine (SVM). The data were used to determine gas concentration...
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Water uptake in protective organic coatings and its reflection in measured coating impedance
PublicationWater uptake in commercially available epoxy coating on mild steel using impedance spectroscopy and gravimetry was studied. The water content in the coating was determined using the Brasher-Kingsbury equation and various methods of coating capacitance calculation used in the literature. The obtained results were compared with reference gravimetric data. An overestimation of values obtained from impedance data in relation to gravimetric...
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Assessment of Lipophilicity Indices Derived from Retention Behavior of Antioxidant Compounds in RP-HPLC
PublicationReverse phase high pressure liquid chromatography was employed in order to evaluate the lipophilicity of antioxidant compounds from different classes, such as phenolic acids, flavanones, flavanols, flavones, anthocyanins, stilbenes, xantonoids, and proanthocyanidins. The retention time of each compound was measured using five different HPLC columns: RP18 (LiChroCART, Purosphere RP-18e), C8 (Zorbax, Eclipse XDBC8), C16-Amide (Discovery...
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Study on the Structure-Property Dependences of Rigid PUR-PIR Foams Obtained from Marine Biomass-Based Biopolyol
PublicationThe paper describes the preparation and characterization of rigid polyurethane-polyisocyanurate (PUR-PIR) foams obtained with biopolyol synthesized in the process of liquefaction of biomass from the Baltic Sea. The obtained foams differed in the content of biopolyol in polyol mixture (0–30 wt%) and the isocyanate index (IISO = 200, 250, and 300). The prepared foams were characterized in terms of processing parameters (processing...
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Typology of low developed non-metropolitan sub-regions in the European Union
PublicationThis paper shows a typology of 319 NUTS-3 sub-regions in the European Union. The selected sub-regions are non-metropolitan sub-regions, whose gross domestic product per capita in 2011 was below 75% of the EU average. The objective of this typology was to recognize diversity in the examined sub-regions as a starting point for the selection of areas for future comparative research. The typology takes into account 24 variables related...
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Metabolomic and antioxidant properties of different varieties and origins of Dragon fruit
PublicationDragon fruit has appealed much concern from consumers as a novelty fruit with potent nutritional and medicinal benefits. Dragon fruit quality warrants comprehensive evaluation, based on the contents of pigments and health- promoting natural compounds in different varieties. This study was aimed to evaluate the differences among dragon fruit varieties extracted with methanol–water (CD3OD-D2O) and methanol (CD3OD) by proton nuclear magnetic...
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Multibeam sonar data processing for seafloor characterisation
PublicationThe approach to seafloor characterisation was investigated. It relies on calculation of several descriptors (parameters) related to seabed type using three types of multibeam sonar data obtained during seafloor sensing: 1) the grey-level sonar images of seabed, 2) the 3D model of the seabed surface which consist of (x, y, z) points, 3) the set of time domain echo envelopes corresponding to several beams. The proposed method has...
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Classification of Polish wines by application of ultra-fast gas chromatography
PublicationThe potential of ultra-fast gas chromatography (GC) combined with chemometric analysis for classification of wine originating from Poland according to the variety of grape used for production was investigated. A total of 44 Polish wine samples differing in the type of grape (and grape growth region) used for the production as well as parameters of the fermentation process, alcohol content, sweetness, and others which characterize...
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Monitoring and diagnosis of quality and quantity in drinking water systems.
PublicationArtykuł przedstawia nowe podejście do inteligentnego monitorowania oraz diagnostyki Systemu Wodnego (WS) jako problem statusu, warunków operacyjnych oraz rozpoznawania zdarzeń. Oprogramowanie komputerowego systemu monitorowania i diagnostyki zawiera narzędzia dla identyfikacji modeli dyskretnych statusów oraz określenia parametrów ilości i jakości wody dla każdego statusu. Dla każdego stanu decyzje podejmowane są przy użyciu metody...
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Metoda głównych składowych w analizie wyników otrzymanych za pomocą dynamiki molekularnej
PublicationMetoda głównych składowych (ang. principal component analysis, PCA) jest jednym z najpopularniejszych statystycznych narzędzi do wielowymiarowej analizy dużego zestawu danych. Pozwala ona na przekształcenie danego zbioru wzajemnie skorelowanych cech (zmiennych) w nowy układ cech wzajemnie nieskorelowanych (tzw. głównych składowych), który jest porównywalny z układem pierwotnym - zastosowanie PCA upraszcza więc w znaczny sposób...
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The influence of reactions conditions on aggregation of dyes used in biochemistry
PublicationSelf-association of dyes and related substances is a very important phenomenon in many fields of applied chemistry. It is also fundamental model reaction of many kinds of molecular interactions such as the micelle formation of amphiphilic substances and the binding of small organic molecules to macromolecules. In spite of many studies concerning the dimerization equilibria of dyes and related substances, the mechanism seems not...
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Feasibility study of a Raman spectroscopic route to drug detection
PublicationWe present an surface-enhanced Raman spectroscopy (SERS) approach for detection of drugs of abuse in whole human blood. We utilize a near infrared laser with 830 nm excitation wavelength in order to reduce the influence of fluorescence on the spectra of blood. However, regular plasmon resonance peak of plasmonic nanoparticles, such as silver or gold fall in a much lower wavelength regime about 400 nm. Therefore, we have shifted...
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Emissions and toxic units of solvent, monomer and additive residues released to gaseous phase from latex balloons
PublicationThis study describes the VOCs emissions from commercially available latex balloons. Nine compounds are determined to be emitted from 13 types of balloons of different colors and imprints in 30 and 60°C. The average values of total volatile organic compounds (TVOCs) emitted from studied samples ranged from 0.054 up to 7.18 μg∙g-1 and from 0.27 up to 36.13 μg∙g-1 for 30oC and 60oC, respectively. The dataset is treated with principal...
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Discrimination of selected fungi species based on their odour profile using prototypes of electronic nose instruments
PublicationThe paper presents practical application of an electronic nose technique to fast and efficient discrimination of the samples of different fungi species such as: Penicillium chrysogenum, Cladosporium herbarum, Rhizopus oryzae, Alternaria alternata. Two prototypes of electronic nose instrument were utilized for investigation of discrimination capability with respect to odour profile of these fungi: the first prototype was based on...
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Bass Enhancement Settings in Portable Devices Based on Music Genre Recognition
PublicationThe paper presents a novel approach to the Virtual Bass Synthesis (VBS) applied to mobile devices, called Smart VBS (SVBS). The proposed algorithm uses an intelligent, rule-based setting of bass synthesis parameters adjusted to the particular music genre. Harmonic generation is based on a nonlinear device (NLD) method with the intelligent controlling system adapting to the recognized music genre. To automatically classify music...
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SYNAT_PCA_48
Open Research DataThere is a series of datasets containing feature vectors derived from music tracks. The dataset contains 51582 music tracks (22 music genres) and feature vector after Principal Component Analysis (PCA) performing, so there are 48-element vectors derived from music excerpts. Originally, a feature vector containing 173 elements was conceived in earlier...
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SYNAT_PCA_11
Open Research DataThe dataset contains 51582 music tracks (22 music genres) and feature vector after Principal Component Analysis (PCA) performing, so there are 11-element vectors derived from music excerpts. Originally, a feature vector containing 173 elements was conceived in earlier research studies carried out by the team of authors [1-6]. A collection of more than...
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Preliminary Identification of Quantitative Factors Determining the Duration of Court Proceedings in Commercial Cases
PublicationPurpose: The aim of the article was to identify factors that are linear combinations of the variables under scrutiny that affect the duration of court proceedings. Design/Methodology/Approach: This research was conducted on commercial cases, based on the Principal Components Analysis (PCA). The original variables were grouped into factors that are correlated with each other. The Kaiser Criterion (own value >1) was chosen as the...
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The Distribution of Glucosinolates in Different Phenotypes of Lepidium peruvianum and Their Role as Acetyl- and Butyrylcholinesterase Inhibitors—In Silico and In Vitro Studies
PublicationThe aim of the study was to present the fingerprint of different Lepidium peruvianum tu- ber extracts showing glucosinolates-containing substances possibly playing an important role in preventinting dementia and other memory disorders. Different phenotypes of Lepidium peruvianum (Brassicaceae) tubers were analysed for their glucosinolate profile using a liquid chromatograph coupled with mass spectrometer (HPLC-ESI-QTOF-MS/MS platform)....
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Rainwater chemistry composition in Bellsund: Sources of elements and deposition discrepancies in the coastal area (SW Spitsbergen, Svalbard)
PublicationDiscrepancies in rainfall chemistry in Bellsund were found to be influenced by the orographic barrier and related to the variability in the inflow of air masses as well as to the distance of sampling sites from the sea and thus the extent of sea spray impact. This study covers measurements of rainfall (P) and air temperature (T), physicochemical parameters (pH, specific electrolytic conductivity (SEC), major ions (Cl , NO3 , SO4...
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Selection of Organic Coating Systems for Corrosion Protection of Industrial Equipment
PublicationThe most important element of corrosion protection in industrial conditions is the protective coating system. However, selecting the right coating can often be a real problem due to the sheer number of coating manufacturers and their products on the market. A quantitative approach based on the data mining technique used to analyze the obtained multi-site exposure data has been proposed. This was demonstrated by the example of the...
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Application of the Electronic Nose Technique to Differentiation between Model Mixtures with COPD Markers
PublicationABSTRACT The paper presents the potential of an electronic nose technique in the field of fast diagnostics of patients suspected of Chronic Obstructive Pulmonary Disease (COPD). The investigations were performed using a simple electronic nose prototype equipped with a set of six semiconductor sensors manufactured by FIGARO Co. They were aimed at verification of a possibility of differentiation between model reference mixtures with...
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Concentrations and loads of DOC, phenols and aldehydes in a proglacial arctic river in relation to hydro-meteorological conditions. A case study from the southern margin of the Bellsund Fjord – SW Spitsbergen
PublicationClimate warming accelerates the melting and thawing of cryosphere components. Therefore, it favours the release of contaminants stored in High-Arctic glaciers for many years. The rate of land-based glacier retreat is of particular importance for the hydrological regime of glacial rivers, but also for the chemical composition of their waters. In this study, we examined 84 surface water samples collected during a period of 42 days...
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Authenticity Assessment of the "Onisiówka" Nalewka Liqueurs Using Two-Dimensional Gas Chromatography and Sensory Evaluation
PublicationThe “Onisiówka” nalewka liqueur is a regional Polish alcoholic beverage, which is inscribed on the list of regional and traditional products of the Ministry of Agriculture and Rural Development in Poland. It is produced from multiflower honey, black elderberry flower syrup, and spirit. Due to fact that the “Onisiówka” nalewka liqueur has never been investigated, these studies are the foundation for further work on this regional...
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Glucosinolates from lepidium peruvianum as potential antiamnestic drugs
PublicationLepidium peruvianum (maca) (Brassicaceae) is a naturally occurring plant mainly in the high Andes of Peru. In recent years, it has been intensively researched in terms of its influence on various diseases and towards health improvement. Alzheimer’s disease is an incurable disease that most often affects adults over the age of 60. As since 2003 the US Food and Drug Administration (FDA) did not approve any new drug for Alzheimer’s...
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The assessment of microbiological purity of cosmetic preparations
Open Research DataThe dataset contains the results of a single series of determinations of the microbiological purity of the cosmetic based on the aqueous phase in the test for the total number of bacteria and the total number of yeasts.The tests were performed by preparing a series of decimal dilutions of the cosmetic in peptone water and performing in-depth culture...
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Detekcja obumierania bakterii osadu czynnego
PublicationAnaliza składników głównych (PCA) jest narzędziem służącym wyodrębnieniu podstawowych czynników w rozważanych procesach w oparciu o dostępne pomiary. Zastosowanie PCA w monitorowaniu procesów pozwala na analizę pod kątem diagnostyki nie tylko wielkości mierzonych lecz również wielkości niedostępnych pomiarowo (ograniczenia technologiczne, koszty). Zaleta ta jest szczególnie istotna w przypadku biologicznej oczyszczalni ścieków,...
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Investigation of sweet substances of different molecular structure by potentiometric taste sensor with all solid state electrodes
PublicationA five channel potentiometric taste sensor consisting of an array of All Solid State Electrodes (ASSESs) with different lipid-polymer membranes has been developed. The electrodes are constructed of glassy carbon discs with electrochemically deposited poly(3,4-ethylenedioxythiophene) (PEDOT) acting as ion to electron transducer. The outer layer of the electrode is lipid-polymer membrane. Lipid substances immobilized in PVC membranes...
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Anthropogenic trace metals in Setiu Wetland: Spatial and seasonal distribution and implications for environmental health
PublicationThe growing urban wastewater volume poses a major global environmental challenge, especially in developing nations where inadequate treatment and discharge impact clean water availability. This study focused on Setiu Wetland, aiming to analyze seasonal and spatial variations of trace metals in particulate form from anthropogenic and pathogenic sources. Surface water samples were collected from multiple stations, measuring physical...