Search results for: THERMOPLASTIC ELASTOMERS
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Recycling of Polyurethanes Containing Flame-Retardants and Polymer Waste Transformed into Flame-Retarded Polyurethanes
PublicationThe growing number of polyurethanes (PUs) produced every year has developed methods for their mechanical and chemical recycling which yield valuable products like substitutes for commercial polyols or flame-retardants. PUs can be produced in different shapes and forms (i.e., elastomers, flexible or rigid foams, coatings, etc.) using several different components (i.e., di- or polyisocyanates, ester- or ether-based polyols, low-molecular...
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Full scattering profile of circular optical phantoms mimicking biological tissue
PublicationHuman tissue is one of the most complex optical media since it is turbid and nonhomogeneous. In our poster, we suggest a new type of skin phantom and an optical method for sensing physiological tissue condition, basing on the collection of the ejected light at all exit angles, to receive the full scattering profile. Conducted experiments were carried out on an unique set-up for noninvasive encircled measurement. Set-up consisted...
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Badania mieszanek mineralno-asfaltowych w niskiej temperaturze
PublicationW artykule przedstawiono metody badań w niskiej temperaturze betonu asfaltowego przeznaczonego do warstwy ścieralnej. Przedstawione zostały wyniki badań dla 4 różnych metod badawczych: zginania, pełzania, pośredniego rozciągania oraz rozciągania termicznego przy ograniczonym odkształceniu (test TSRST). Próbki betonu asfaltowego były przygotowywane w laboratorium z wykorzystaniem 3 rodzajów asfaltów: asfaltu zwykłego, asfaltu modyfikowanego...
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Sztywność i energia rozpraszana polieterouretanowych elementów sprężystych
PublicationPrzedstawiono wyniki badań wytrzymałościowych i energii rozpraszanej materiałów wytworzonych z elastomeru polieterouretanowego w postaci walca i cylindrycznej tulei, różniących się współczynnikiem kształtu i przekrojem poprzecznym. Próbki zsyntetyzowano z 4,4’-diizocyjanianu difenylometanu (MDI), oligo(oksytetra-metyleno)diolu (PTMG), a butano- 1,4-diol (BDO) użyto jako przedłużacz łańcucha prepolimeru. Stosunek molowy grup izocyjanianowych...
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Cavitation erosion degradation of Belzona® coatings
PublicationIn hydrocarbon and maritime industry there is a constant need of materials and coatings withstanding severe conditions. One of adverse phenomena present there is cavitation erosion. The paper presents evaluation of cavitation resistance of three different steel coatings. Belzona 2141 (ACR-Fluid Elastormer), 1321 (Ceramic S-Steal) and 5831 (ST-Barrier) were deployed on P110 steel and subjected to ultrasound cavitation in distilled...
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Fabrication of toughened plastic using styrene butadiene rubber-poly (methyl methacrylate) interpenetrating polymer networks
PublicationA standard set of interpenetrating polymeric networks (IPNs) has been contrived using an elastomerstyrene butadiene rubber and a thermoplastic poly (methyl methacrylate) through sequential polymerization protocol. This low-cost material can be hopefully engaged as a toughened plastic with cocontinuous morphology. Different morphological protocols including Raman imaging are effectively utilized to envisage the effect of blend ratio...
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Mathematical Modelling of a Seismic Isolation System to Protect Structures During Damaging Earthquakes
PublicationThe present study aims to determine the effectiveness of a nonlinear mathematical model in simulating complex mechanical behaviour of a seismic isolation system to protect structures during strong and damaging earthquakes. In order to construct the Polymeric Bearings considered in this research, a specially prepared flexible polyurethane elastomer with increased damping properties has been used. The usefulness of the proposed mathematical...
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Assessment of the devulcanization process of EPDM waste from roofing systems by combined thermomechanical/microwave procedures
PublicationEthylene-propylene-diene rubber (EPDM) is a elastomer widely used in common industrial applications. EPDM can be shaped into sheets and employed as isolating material for roofing systems. In this study, scraps of EPDM from commercial, industrial and residential roofing systems were treated by combined thermo-mechanical and microwave devulcanization processes including peroxide of benzoyl (BPO). The devulcanized EPDM (Dev-EPDM)...
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Glikoliza odpadów poliuretanowych. Cz. II. Oczyszczanie oraz wykorzystanie glikolizatów
PublicationNa podstawie literatury przedstawiono sposoby oczyszczania produktów glikolizy odpadów poliuretanowych w celu ich ponownego wykorzystania w syntezie poliuretanów (PUR). Metody te obejmują ekstrakcję, destylację oraz usuwanie grup aminowych (szkodliwych w dalszymprocesie otrzymywania PUR) za pomocą np. tlenków alkilenowych, eterów glicydolowych lub cyklicznych węglanów. Opisano metody badań glikolizatów i produktów dekompozycji...
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Degradation of polycaprolactone modified with TPS or CaCO3 in biotic/abiotic seawater
PublicationThis paper is an investigation of the polymer degradation process in two types of seawater (with and without microorganisms) sourced from the Baltic Sea. The chosen polymeric materials were polycaprolactone modified with either thermoplastic starch (PCL/TPS>85%) or calcium carbonate (60% PCL/40% CaCO3) compared directly against unmodified polycaprolactone. All samples were incubated for 28 weeks in seawater with and without microorganisms...
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Prediction of the fatigue lifetime of PUR structural elements using a combined experimental-numerical approach
PublicationThis paper presents a method for estimating the fatigue life of polyurethane elastomeric components. A rubber replacement - polyurethane of hardness 80ShA commonly used in vibration damping systems, for example, in motor vehicle suspensions, was used for the study. A metal-rubber bushing component was selected for analysis, and numerical analysis was carried out along with a fatigue model proposal based on a modification of the...
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Justyna Kucińska-Lipka dr hab. inż.
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Sposób otrzymywania elastomerów poliuretanowych
InventionsPrzedmiotem wynalazku są nowe elastomery poliuretanowe wytwarzane z udziałem glikolizatów - komponentów odzyskanych z odpadów polimerowych w procesie recyklingu.
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Modification of thermal and rheological characteristics of bitumen by waste PET/GTR blends
PublicationWaste poly(ethylene terephthalate) (wPET)/ground tire rubber (GTR) blends with variable compositions were applied as low-cost modifiers into bitumen and their performance has been evaluated via morphological, thermal and rheological analyses. Depending on the weight ratio of wPET/GTR, dispersion of single/composite domains of waste polymers in the bitumen has promoted the interaction between bitumen and blend components. Fourier...
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Fabrication and Characterization of Flexible Medical-Grade TPU Filament for Fused Deposition Modeling 3DP Technology
PublicationThe possibility of using additive manufacturing (AM) in the medicine area has created new opportunities in health care. This has contributed to a sharp increase in demand for 3D printers, their systems and materials that are adapted to strict medical requirements. We described herein a medical-grade thermoplastic polyurethane (S-TPU) which was developed and then formed into a filament for Fused Deposition Modeling (FDM) 3D printers...
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Evaluation of Thermal Stresses in Asphalt Layers in Comparison with TSRST Test Results
PublicationThe paper presents the results of calculations and laboratory determination of thermal stresses at low temperatures. The modified Hills and Brien's method was used to calculate the thermal stresses in asphalt layers of pavements and the results were compared against the values obtained at a laboratory with the Thermal Stress Restrained Specimen Test (TSRST) method. The laboratory investigations were conducted using plain grade...
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Grafting and reactive extrusion technologies for compatibilization of ground tyre rubber composites: Compounding, properties, and applications
PublicationChemical modification of ground tyre rubber (GTR) to compatibilize it with the matrix is a well-known approach. Based on our recent review of the surface etching methods used in GTR modification, the purpose of the current work is to take a deeper look into more advanced methods such as grafting and reactive extrusion. While grafting is more efficient in achieving compatibility, however, it usually involves multi-step synthesis...
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Novel Biodegradable Potato Starch-based Compositions as Candidates in Packaging Industry, Safe for Marine Environment
PublicationAbout 70 % of our planet’s surface is covered by seas and oceans to which even 10 million tons of waste go every year. It makes these places the largest global landfills, containing up to 90 % of plastic waste. In this article we present the results of research on novel starch-based compositions expected to be more safe for the marine environment. For these purpose biopolymers such as, thermoplastic starch (TPS), polylactide (PLA)...
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Effect of modified soybeen oil amount on rheological characteriza-tion of polyurethane pre-polymers
PublicationPolyurethanes (Pu’s) are the polymeric materials which have got urethane groups in the structure. The properties of Pu’s depend both on the method of preparation and monomers used. Polyurethanes are produced by two methods known as one step or two step method called as “pre-polymers method”, especially for the case of segmented polyurethanes (SPU’s). These materials are thermoplastic block copolymers of the (AB)n type consisting...
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Influence of Fragment Size on the Time and Temperature of Ethylene Vinyl Acetate Lamination Decomposition in the Photovoltaic Module Recycling Process
PublicationPhotovoltaics is a commercially available and reliable technology with significant potential for long-term growth in nearly all global regions. Several research institutes and companies are working on recycling concepts for thin film modules and modules with crystalline cells. The establishment of recycling and reuse technologies appropriate and applicable to all photovoltaics (PV) modules is a key issue to be addressed as part...
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Cast polyurethanes obtained from reactive recovered polyol intermediates via crude glycerine decomposition process
PublicationIn this work, the possibility of applying intermediates from polyurethane waste recycling in polyurethane synthesis was presented. Polyurethanes were synthesised in a two-step method using a mixture of petrochemical polyol and glycerolysate, used as a reactive component, 4,4-diphenylmethane diisocyanate (MDI) and 1,4-buthanediol (BD). Glycerolysates were produced during decomposition of polyurethane elastomer by crude glycerine...
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Recykling poliuretanów oraz poli(tereftalanu etylenu)
PublicationPoliuretany (PUR) oraz poli(tereftalan etylenu) (PET) stanowią zaraz obok poliolefin główne źródło odpadów z tworzyw sztucznych. Poliuretany są produkowane w formie elastomerów, elastycznych i sztywnych pianek oraz klejów i powłok. Szeroki wachlarz zastosowań poliuretanów, wynikający zarówno z ich unikalnych właściwości, jak i z możliwych form użytkowych, skutkuje rosnącym z roku na rok zapotrzebowaniem na te materiały. Poli(tereftalan...
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The influence of temperature on properties of the polymer flexible joint used for strengthening historical masonries
PublicationA new method of repairing damaged structures by filling the cracks with a specially prepared elastomeric polymer mass has been recently proposed. This new and innovative technique, known as the Flexible Joint Method (FJM), is mainly dedicated to masonries and historical objects, where minimum intervention is permitted. The flexible joint bonds the disrupted elements and ensures further safe exploitation of a damaged structure....
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Curing characteristics, mechanical properties and morphology of butyl rubber filled with ground tire rubber (GTR)
PublicationThe results on testing application of ground tire rubber (GTR), as potential filler for butyl rubber, are pre- sented. The GTR content variation, within the range of 10–90 phr, was studied with respect to the vulcanization process, static mechanical properties (tensile strength, elongation-at-break, hardness and resilience), dynamic mechanical properties and the morphology of the obtained vulcanizates. Butyl rubber was characterized...
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Technological aspects of manufacturing polymer packaging materials degradable in seawater environment
PublicationIn recent years, the number of polymer materials used in the food packaging market was growing extremely fast. This contributed to depletion of non-renewable resources and more intense degradation of the environment due to resistant polymer. Therefore, such a dramatic situation has forced researchers to look for biodegradable materials, decomposable under action of microorganism. Currently, only a small number of researches examine...
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Manufacture and research of TPS/PE biocomposites properties
PublicationIn this paper the process of native starch preparing for modification by extrusion and manufacture of biocomposites is presented. The first aim of this study was to determine the mixing and granulating condition of native starch to obtain granulated native starch. For mixing and granulation of native starch Intensive Mixer manufactured by Maschinenfabrik Gustav Eirich was used. Mixing and granulation in a single process is a new...
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Chitin nanowhiskers from shrimp shell waste as green filler in acrylonitrile-butadiene rubber: Processing and performance properties
PublicationIn this work, chitin nanowhiskers with high crystallinity index were obtained from shrimp shells waste using acid hydrolysis method and then comprehensively characterized. Subsequently, the impact of chitin nanowhisker content on processing and performance of acrylonitrile-butadiene rubber based nanocomposites was evaluated. The results showed that the addition of chitin nanowhiskers increased tensile strength and tear strength...
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Reclaimed Rubber/Poly(ε‐caprolactone) Blends: Structure, Mechanical, and Thermal Properties
PublicationThe amount of elastomeric waste, especially from tires is constantly increasing on a global scale. The recycling of these residua should be considered a priority. Compounding the waste rubbers with other polymers can be an excellent alternative to reuse waste materials. This procedure requires solving the issue of the lack of compatibility between the waste rubber particles and other polymers. Simultaneously, there is a claim for...
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Nonlocalized thermal behavior of rotating micromachined beams under dynamic and thermodynamic loads
PublicationRotating micromachined beams are one of the most practical devices with several applications from power generation to aerospace industries. Moreover, recent advances in micromachining technology have led to huge interests in fabricating miniature turbines, gyroscopes and microsensors thanks to their high quality/reliability performances. To this end, this article is organized to examine the axial dynamic reaction of a rotating...
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Influence of Giant Reed (Arundo Donax L.) Culms Processing Procedure on Physicochemical, Rheological, and Thermomechanical Properties of Polyethylene Composites
PublicationGiant reed (Arundo donax L.) is a plant species with a high growth rate and low requirements, which makes it particularly interesting for the production of different bioproducts, including natural fibers. This work assesses the use of fibers obtained from reed culms as reinforcement for a high-density polyethylene (HDPE) matrix. Two different lignocellulosic materials were used: i) shredded culms and ii) fibers obtained by culms...
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Green TPUs from Prepolymer Mixtures Designed by Controlling the Chemical Structure of Flexible Segments
PublicationThis study concerns green thermoplastic polyurethanes (TPU) obtained by controlling the chemical structure of flexible segments. Two types of bio-based polyether polyols—poly(trimethylene glycol)s—with average molecular weights ca. 1000 and 2700 Da were used (PO3G1000 and PO3G2700, respectively). TPUs were prepared via a two-step method. Hard segments consisted of 4,4?- diphenylmethane diisocyanates and the bio-based 1,4-butanodiol...
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Ground tire rubber thermo-mechanically devulcanized in the presence of waste engine oil as asphalt modifier
PublicationCross-linked elastomers network is main limitation for industrial usage of ground tire rubber (GTR) as asphalts’ and road pavements modifier. GTR was thermo-mechanically devulcanized via extrusion in the presence of waste engine oil (WEO) at temperature ranges from 150 to 280 °C. Combined impact of WEO content and extruder barrel temperature on the change of cross-linked structure of degraded GTR (DTGR) was investigated through...
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Synteza, właściwości i zastosowanie liniowych polioli poliestrowych otrzymanych z wykorzystaniem surowców pochodzenia roślinnego
PublicationCelem rozprawy doktorskiej było opracowanie nowych liniowych polioli poliestrowych z wykorzystaniem surowców pochodzenia roślinnego, dedykowanych do syntez termoplastycznych elastomerów poliuretanowych. Przed przystąpieniem do prac eksperymentalnych wykonałam szczegółowy przegląd literatury, który stanowił aktualne spojrzenie na różne kierunki rozwoju bio-surowców w syntezie poliuretanów. Na podstawie analizy zebranych informacji...
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Zastosowania wybranych technik analizy termicznej w badaniu tworzyw sztucznych
PublicationMetody analityczne oparte na wykorzystaniu technik analizy termicznej były i nadal są bardzo popularne i często wykorzystywane w badaniu tworzyw sztucznych. Techniki te pozwalają na określenie właściwości termicznych materiałów polimerowych takich jak np. temperatura zeszklenia, temperatura i ciepło topnienia, temperatura i ciepło krystalizacji oraz ciepło właściwe. Oddziaływanie wysokiej temperatury na polimery może prowadzić...
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Thermomagnetic behavior of a semiconductor material heated by pulsed excitation based on the fourth-order MGT photothermal model
PublicationThis article proposes a photothermal model to reveal the thermo-magneto-mechanical properties of semiconductor materials, including coupled diffusion equations for thermal conductivity, elasticity, and excess carrier density. The proposed model is developed to account for the optical heating that occurs through the semiconductor medium. The Moore–Gibson–Thompson (MGT) equation of the fourth-order serves as the theoretical framework...
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Preliminary Testing of the Influence of Modified Polycaprolactones on Anabaena Variabilis Growth in Seawater
PublicationSeveral new biodegradable polymer materials have recently come onto the global market. Mostly the results on degradation kinetic studies are presented. This paper suggests using one of the tests to estimate the impact of polymer packaging material on sea life. The microorganism chosen was Anabaena variabilis (identified in many waters, including those of the Baltic Sea, especially in the Gulf of Gdansk and Puck Bay; this cyanobacterium...
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Novel Biomass-Based Polymers: Synthesis, Characterization, and Application
PublicationA wide range of polymers were prepared from biomass-derivatives, using different polymerization mechanisms. Well-defined, fully hydroxy-functional polyesters based on aliphatic diols were synthesized, using either conventional metal-based catalysts or the organic superbase 1,5,7-triazabicyclododecene (TBD). Unsaturated polyesters were also made, offering additional functionality to these biobased resins. Metal-catalyzed or enzymatic...
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POM/EVA Blends with Future Utility in Fused Deposition Modeling
PublicationPolyoxymethylene (POM) is one of the most popular thermoplastic polymers used in the industry. Therefore, the interest in its potential applications in rapid prototyping is understandable. Nevertheless, its low dimensional stability causes the warping of 3D prints, limiting its applications. This research aimed to evaluate the effects of POM modification with ethylene-vinyl acetate (EVA) (2.5, 5.0, and 7.5 wt.%) on its processing...
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Composite Polyurethane-Polylactide (PUR/PLA) Flexible Filaments for 3D Fused Filament Fabrication (FFF) of Antibacterial Wound Dressings for Skin Regeneration
Publicationhis paper addresses the potential application of flexible thermoplastic polyurethane (TPU) and poly(lactic acid) (PLA) compositions as a material for the production of antibacterial wound dressings using the Fused Filament Fabrication (FFF) 3D printing method. On the market, there are medical-grade polyurethane filaments available, but few of them have properties required for the fabrication of wound dressings, such as flexibility...
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Synthesis, structure and properties of novel poly(hydroxyurethane)s obtained by non-isocyanate route
PublicationNon-isocyanate polyurethanes (NIPUs) can be synthesized by polyaddition of five-membered bis(cyclic carbonate)s and primary diamines. NIPUs are an alternative for the commonly used (in the form of foams, elastomers, coatings or fibers) in the industry polyurethanes obtained using toxic and moisture sensitive diisocyanates, polyols and low-molecular weight chain extenders. The main aim of this work was to synthesize non-isocyanate...
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Preparation and characterization of biodegradable and compostable PLA/TPS/ESO compositions
PublicationIn this study, biodegradable and compostable compositions, derived from totally natural feedstock/raw materials, namely polylactide (PLA), potato thermoplastic starch (TPS) and plant glycerin have been made by melt extrusion with epoxydized soybean oil (ESO) as reactive modifier in order to improve PLAs ductility and reduce the products cost without compromising biodegradation. The obtained PLA/mTPS(0,5ESO)[75/25] and PLA/ mTPS(2ESO)[75/25]...
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Preparation, characterization, and manufacturing of new polymeric materials for 3D printing for medical applications
PublicationThis work concerns the synthesis, formation, and characteristics of new filaments for 3D printing in FDM™/FFF technology for medical purposes. Two types of filaments were developed, i.e. degradable polyurethane and biodegradable polylactide-starch. The influence of the 3D printing process on selected filament properties was investigated. A detailed analysis of the filament formation process by the extrusion method was carried out,...
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Ground lemon and stevia leaves as renewable functional fillers with antioxidant activity for high-density polyethylene composites
PublicationThe development of new sustainable material solutions in the processing of thermoplastic polymers concerns both the application of biopolymers and the use of valorized plant derivatives as fillers and modifiers of petrochemical polymers. Herein, the possibility of using unprocessed raw parts of two commonly used in the food industry leaves, i.e., lemon (LL) and stevia (ST), as active and functional fillers for high-density polyethylene...
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Characterization and Filtration Efficiency of Sustainable PLA Fibers Obtained via a Hybrid 3D-Printed/Electrospinning Technique
PublicationThe enormous world demand for personal protective equipment to face the current SARS-CoV-2 epidemic has revealed two main weaknesses. On one hand, centralized production led to an initial shortage of respirators; on the other hand, the world demand for single-use equipment has had a direct and inevitable effect on the environment. Polylactide (PLA) is a biodegradable, biocompatible, and renewable thermoplastic polyester, mainly...
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Mater-Bi/Brewers’ Spent Grain Biocomposites—Novel Approach to Plant-Based Waste Filler Treatment by Highly Efficient Thermomechanical and Chemical Methods
PublicationThermoplastic starch (TPS) is a homogenous material prepared from native starch and water or other plasticizers subjected to mixing at a temperature exceeding starch gelatinization temperature. It shows major drawbacks like high moisture sensitivity, poor mechanical properties, and thermal stability. To overcome these drawbacks without significant cost increase, TPS could be blended with bio-based or biodegradable polymers and...
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Toughness augmentation by fibrillation and yielding in nanostructured blends with recycled polyurethane as a modifier
PublicationIn the present paper, we have carefully investigated the morphology and fracture mechanism of the recycled polyurethane (RPU) /epoxy blend system. The second phase (RPU) added to the epoxy resin has a positive effect on the overall mechanical properties. Interestingly, the recycled polymer has a remarkable effect on the fracture toughness of epoxy resin. The mechanism behind the fracture toughness improvement up on the addition...
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Ocena efektywności modelu matematycznego do opisu nieliniowego zachowania wibroizolacji sejsmicznej w postaci łożysk polimerowych
PublicationW pracy została dokonana ocena efektywności modelu matematycznego, opisującego nieliniowe zachowanie prototypu wibroizolacji sejsmicznej w postaci łożysk polimerowych. Do budowy łożysk polimerowych został wykorzystany elastomer poliuretanowy, który charakteryzuje się dobrymi właściwościami tłumiącymi. Wyniki badań materiałowych przeprowadzonych dla analizowanego polimeru zostały przedstawione we wcześniejszych publikacjach. W zaproponowanym...
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Real-time monitoring of the emission of volatile organic compounds from polylactide 3D printing filaments
PublicationEstablishing the emission profile of volatile organic compounds generated during fused deposition modeling 3D printing using polymer filaments is important in terms of both understanding the processes taking place during thermal degradation of thermoplastics, and assessing the user's exposure to potentially harmful volatiles. However, obtaining detailed, real-time qualitative and quantitative results poses a challenge. In this...
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Synteza i właściwości jonowoprzewodzących materiałów poliuretanowych
PublicationPrzewodzące kompozyty poliuretanowe otrzymywano w syntezie dwuetapowej. W pierwszym etapie syntetyzowano prepolimer uretanowy. W tym celu poddawano reakcji 4,4'-diizocyjanianu difenylometanu (MDI) oraz oligoeterol ( PTMG 1000, PTMG 2000 lub Rokopol D-2002). W drugim etapie jako przedłużacz łańcuchów stosowano 1,4-butanodiol (BDO). Elastomery te były domieszkowane solami LiClO4 lub LiCl oraz modyfikowane montmorylonitem. Domieszkowanie...
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Dewulkanizacja i kompatybilizacja w wytłaczarce dwuślimakowej
PublicationDynamiczny rozwój przemysłu motoryzacyjnego przyczynił się do powstania ogromnej ilości odpadów gumowych, z których aż 80% stanowią zużyte opony samochodowe. Szacunkowe dane wskazują, że na całym świecie rocznie powstaje ponad 17 mln sztuk zużytych opon, z czego w krajach UE wycofywanych z eksploatacji jest prawie 3,3 mln opon samochodowych. W Polsce, wg szacowań Ministerstwa Środowiska, Głównego Urzędu Statycznego oraz Oddziału...