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Homoclinic orbits for a class of singular second order Hamiltonian systems in ℝ3
PublikacjaWe consider a conservative second order Hamiltonian system \ddot{q}+ ∇V(q)=0 in R3 with a potential V having a global maximum at the origin and a line l ∩ {0} = ∅ as a set of singular points. Under a certain compactness condition on V at infinity and a strong force condition at singular points we study, by the use of variational methods and geometrical arguments, the existence of homoclinic solutions of the system.
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Kilka spotkań z Andrzejem Staszewskim
PublikacjaKatalog poświęcony twórczości Andrzeja Staszewskiego. Katalog liczy 108 stron i zawiera teksty krytyczne i 86 reprodukcji. Tekst autora na stronach 17 - 20. Reprodukcja pracy malarskiej autora na str. 19. Wydawcą katalogu jest urząd gminy w krzynowłodze małej oraz towarzystwo przyjaciół ziemi przasnyskiej. ISBN: 978-83933044-0-0.
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Fluorine ions in photocatalysts’ synthesis: an obstacle or an ally? The investigation of photocatalysts in Ti-O-F system
PublikacjaTitanium(IV) oxide (TiO2) is one of the most promising photocatalysts, which is expected to be applied in the photocatalytic degradation of xenobiotics. For sustainable development and green chemistry approach recently, much effort has been paid to enhance TiO2 photocatalytic activity in UV-vis light by modifying its structure. The photocatalytic process’s complexity cannot be simply described as electron-hole pairs generations...
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Low-cost multiband four-port phased array antenna for sub-6 GHz 5G applications with enhanced gain methodology in Radio-over-fiber systems using modulation instability
PublikacjaPhased array antenna (PAA) technology is essential for applications requiring high gain and wide bandwidth, such as sensors, medical, and 5G. Achieving such a design, however, is a challenging and intricate process that calls for precise calculations and a combination of findings to alter the phase and amplitude of each unit. Furthermore, coupling effects between these PAA structure elements can only be completed with the use of...
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Spectroscopic and photophysical properties of ZNTPP in a room temperature ionic liquid
PublikacjaThe steady-state absorption and emission spectra and the time-resolved Soret- and Q-band excited fluorescence profiles of the model metalloporphyrin, ZnTPP, have been measured in a highly purified sample of the common room temperature ionic liquid, [bmim][PF(6)]. S(2)-S(0) emission resulting from Soret-band excitation behaves in a manner completely consistent with that of molecular solvents of the same polarizability. The ionic...
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Unequally-Spaced Slot Strategy for Radiation Null Reduction in Single SIW-Embedded Antenna Element
PublikacjaThe incorporation of higher-order modes (HOMs) can substantially augment the antenna gain and bandwidth, but this improvement is typically accompanied by compromised radiation performance including radiation nulls and higher side lobe levels. In this study, an inventive strategy is introduced to reduce the radiation nulls and the side lobe levels of a single antenna element by positioning multiple slots of the radiating element...
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Cross-linking of sodium caseinate-structured emulsion with transglutaminase alters postprandial metabolic and appetite responses in healthy young individuals
PublikacjaThe physico-chemical and interfacial properties of fat emulsions influence lipid digestion and may affect postprandial responses. The aim of the present study was to determine the effects of the modification of the interfacial layer of a fat emulsion by cross-linking on postprandial metabolic and appetite responses. A total of fifteen healthy individuals (26·5 (sem 6·9) years and BMI 21·9 (sem 2·0) kg/m2) participated in a cross-over...
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Novel calix[4]resorcinarenes with side azobenzo-15-crown-5 residues
PublikacjaZsyntezowano nowe kaliks[4]rezorcareny z dwoma lub czteroma resztami azobenzo-15-korony-5 w dowolnym pierścieniu. Związki te otrzymano w reakcji kondensacji rezorcynolu z odpowiednimi aldehydami (acetalami).
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Bis(ammonium) Zoledronate Dihydrate
PublikacjaNeutralization of 2-(1-imidazole)-1-hydroxyl-1,1`-ethylidenediphosphonic acid (zoledronic acid) by an excess of ammonia yielded bis(ammonium) zoledronate dihydrate, {C5H8N2O7P2 2−, 2(H4N+), 2(H2O)}. The product is readily soluble in water and forms monocrystals for which the X-ray structural analysis was carried out. The zoledronic anion is of double negative charge due to deprotonation of three P–OH groups and protonation of the...
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Systems, Environments, and Soliton Rate Equations: Toward Realistic Modeling
PublikacjaIn order to solve a system of nonlinear rate equations one can try to use some soliton methods. The procedure involves three steps: (1) find a ‘Lax representation’ where all the kinetic variables are combined into a single matrix ρ, all the kinetic constants are encoded in a matrix H; (2) find a Darboux–Bäcklund dressing transformation for the Lax representation iρ˙=[H,f(ρ)], where f models a time-dependent environment; (3) find...
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Application of BDD thin film electrode for electrochemical decomposition of heterogeneous aromatic compounds
PublikacjaThe aim of the presented study is to investigate the applicability of electrochemical oxidation of aromatic compounds containing heteroatoms, e.g. waste from production of pesticides or pharmaceutics, at a borondoped diamond (BDD) electrode. The BDD electrodes were synthesized by microwave plasma enhanced chemical vapour deposition (MW PE CVD). Investigation of the electrode surface by optical microscopy and scanning electron microscopy...
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DYNAMIC MECHANICAL BEHAVIOUR OF GFRP COMPOSITES WITH SiO2 NANO PARTICLES REINFORCED EPOXY MATRIX
PublikacjaDynamic mechanic (DMA) tests were performed to compare the mechanical behaviour of glass fibre reinforced epoxy laminate composites with SiO2 nanoparticle reinforced matrix. The selection of the most promising nanoparticle concentrations was considered in terms of elastic modulus and glass transition temperature. The reference specimens (0% nanoparticles) did not contain diluent accordingly the results do not allow the exact comparison...
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Long-term Hindcast Simulation of Currents, Sea Level, Water Temperature and Salinity in the Baltic Sea
PublikacjaThis dataset contains the results of numerical modelling of currents, sea level, water temperature and salinity over a period of 50 years (1958–2007) in the Baltic Sea. A long-term hindcast simulation was performed using a three-dimensional hydrodynamic model (PM3D) based on the Princeton Ocean Model (POM). The spatial resolution was 3 nautical miles, i.e. about 5.5 km. Currents, water temperature, and salinity were recorded...
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obraz olejny pt. 0:0 7/10
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Quasirelativistic potential energy curves and transition dipole moments of NaRb
PublikacjaWe report on extensive calculations of quasi-relativistic potential energy curves and, for the first time, transition dipole moments including spin-orbit and scalar-relativistic effects of the NaRb molecule. The calculated curves of the 0+, 0-, 1, 2 and 3 molecular states correlate for large internuclear separation with the fourteen lowest atomic energies up to the Na(3s ^2S_{1/2}) + Rb(7s ^2S_{1/2}) atomic limit. Several new features...
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Investigation of noises in the EPN weekly time series
PublikacjaThe constantly growing needs of permanent stati ons’ velocities users cause their stability level to increase. To this research we included more than 150 stations located across Europe operating within the EUREF Permanent Network (EPN) w ith weekly changes in the ITRF2005 reference frame. The obvious long-range dependencies in the stochastic part of GPS time series were p roven by Ljung-Box...
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Analiza składu kwasów tłuszczowych frakcji WKT wyizolowanej z produktów przeestryfikowania enzymatycznego wysokotopliwej frakcji tłuszczu mlecznego olejem słonecznikowym
PublikacjaOpracowano metodę ilościowego oznaczania kwasów tłuszczowych występujących w WKT mieszaniny poreakcyjnej. Substratem były frakcje WKT pochodzące z produktów enzymatycznego przeestryfikowania frakcji tłuszczu mlecznego i oleju słonecznikowego, w obecności Lipozyme RM IM. Frakcje te izolowano z produktu metodą preparatywnej CCW i przeprowadzano w estry metylowe, stosują jako katalizator SOCl2. Otrzymane estry analizowano metodą chromatografii...
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Evolution of magnetic and transport properties in (Cr1−xMnx)2AlC MAX-phase synthesized by arc melting technique
PublikacjaHerein we initiate a comeback to the arc melting technique to produce MAX-phase solid solutions. Bulk samples of (Cr1−xMnx)2AlC MAX-phase with X = 0, 0.025, 0.05 and 0.1 were synthesized and studied by means of X-ray diffractometry, scanning electron microscopy in combination with energy-dispersive X-ray spectroscopy. Samples were established to be homogeneous with an incorporation of Cr7C3, AlCr2 and Al2O3 secondary phases which...
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Wpływ dodatku odcieków składowiskowych do oczyszczanych ścieków komunalnych na wielkość frakcji ChZT
PublikacjaManaging landfill leachate is one of the most important problems with maintaining landfills. The aim of this study was to determine the influence on COD fraction of landfill leachate addition from 0,5% to 5% to raw wastewater. The results of this study show that soluble inert COD in wastewater and mixture wastewater with landfill leachate constituted the smallest percentage of total COD. Nonetheless this fraction (soluble inert...
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Steady magnetohydrodynamic flow in a diverging channel with suction or blowing
PublikacjaAn analysis is made of steady two-dimensional divergent flow of an electrically conducting incompressible viscous fluid in a channel formed by two non-parallel walls, the flow being caused by a source of fluid volume at the intersection of the walls. The fluid is permeated by a magnetic field produced by an electric current along the line of intersection of the channel walls. The walls are porous and subjected to either suction...
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Characterization of GM3 Gangliosides in Human Milk throughout Lactation: Insights from the Analysis with the Use of Reversed-Phase Liquid Chromatography Coupled to Quadrupole Time-Of-Flight Mass Spectrometry
PublikacjaGangliosides are complex lipids found in human milk that play important structural and biological functions. In this study, we utilized reversed-phase liquid chromatography coupled to quadrupole time-of-flight mass spectrometry to evaluate the molecular distribution of GM3 in human milk samples collected at distinct lactation stages, ranging from colostrum to advanced lactation samples. Throughout lactation, GM3 d40:1 emerged as...
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Dion desorption from condensed CD4, C2D2, C2D4, C2D6 ans C2D8 moleculesinduced by electron impact. Radiation.
PublikacjaZmierzono wydajność desorpcji jonu D-z deuteryzowanych węglowodorów. Desorpcja jest stymulowana wiązką elektronów w zakresie energii od 0 do 20 eV.
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Environmentally Friendly Fabrication of High-Efficient Fe-ZnO/Citric Acid-Modified Cellulose Composite and the Enhancement of Photocatalytic Activity in the Presence of H2O2
PublikacjaIn the present study, a novel Fe-ZnO/citric acid-modified cellulose composite (x%Fe-ZnOy% CAC) was synthesized using an environmentally friendly hydrothermal method. The obtained samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV−vis diffuse reflectance spectroscopy (DRS), Fourier transform infrared spectroscopy (FTIR), nitrogen physisorption, and electrochemical and photocurrent density...
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Probing the Magnetic Anisotropy of Co(II) Complexes Featuring Redox-Active Ligands
PublikacjaCoordination complexes that possess large magnetic anisotropy (otherwise known as zero-field splitting, ZFS) have possible applications in the field of magnetic materials, including single molecule magnets (SMMs). Previous studies have explored the role of coordination number and geometry in controlling the magnetic anisotropy and SMM behavior of high-spin (S = 3/2) Co(II) complexes. Building upon these efforts, the present work...
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Are Pair Trading Strategies Profitable During COVID-19 Period?
PublikacjaPair trading strategy is a well-known profitable strategy in stock, forex, and commodity markets. As most of the world stock markets declined during COVID-19 period, therefore this study is going to observe whether this strategy is still profitable after COVID-19 pandemic. One of the powerful algorithms of DBSCAN under the umbrella of unsupervised machine learning is applied and three clusters were formed by using market and accounting...
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Odczuwanie przestrzeni, czyli architektura jako lekarstwo
PublikacjaRecenzja książki, Esther M. Sternberg, Healing Spaces: The Science of Place and Well-Being , The Belknap press of Harvard University press, 2010, ISBN 978-0-674-05748-7
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A FPTAS for minimizing total completion time in a single machine time-dependent scheduling problem
PublikacjaIn this paper a single machine time-dependent scheduling problem with total completion time criterion is considered. There are given n jobs J1,…,Jn and the processing time pi of the ith job is given by pi=a+bisi, where si is the starting time of the ith job (i=1,…,n),bi is its deterioration rate and a is the common base processing time. If all jobs have deterioration rates different and not smaller than a certain constant u>0,...
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Correlation between charge density waves and antiferromagnetism in Nd1−xGdxNiC2 solid solutions
PublikacjaWe report a study on the evolution of a charge density wave and antiferromagnetism in the series of the polycrystalline solid solution Nd1−xGdxNiC2 (0 _ x _ 1) by means of magnetic and transport properties measurements. The experimental results reveal the violation of the de Gennes law and a strong correlation between the Peierls, Néel, and Curie-Weiss temperatures, which strongly suggests a cooperative interaction between the...
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Analytical calculations of scattering lengths for a class of long-range potentials of interest for atomic physics
PublikacjaWe derive two equivalent analytical expressions for an $l$th partial-wave scattering length $a_{l}$ for central potentials with long-range tails of the form % \begin{math} \displaystyle V(r)=-\frac{\hbar^{2}}{2m}\frac{Br^{n-4}}{(r^{n-2}+R^{n-2})^{2}} -\frac{\hbar^{2}}{2m}\frac{C}{r^{2}(r^{n-2}+R^{n-2})}, \end{math} % ($r\geqslant r_{s}$, $R>0$). % For $C=0$, this family of potentials reduces to the Lenz potentials discussed in...
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Solvation phenomena in ternary system tetramethylurea-methylacetamide-water: Insights from volumetric, compressibility and FTIR analysis
PublikacjaThe properties of the ternary systems N,N,N’,N’-tetramethylurea - N-methylacetamide - water were investigated using Fourier-transform infrared spectroscopy (FTIR), volumetric and compression measurements. Densities and sound velocities were determined in order to obtain the apparent molar volumes (VΦ) and apparent molar isentropic compressions (ΚS,Φ). These values were then extrapolated to infinite dilution. Additionally, interaction parameters...
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Identification of defected sensors in an array of amperometric gas sensors
PublikacjaPurpose Amperometric gas sensors are commonly used in air quality monitoring in long-term measurements. Baseline shift of sensor responses and power failure may occur over time, which is an obstacle for reliable operation of the entire system. The purpose of this study is to check the possibility of using PCA method to detect defected samples, identify faulty sensor and correct the responses of the sensor identified as faulty. Design/methodology/approach In...
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Water absorption and blistering of glass fibre-reinforced polymer marine laminates with nanoparticle-modified coatings
PublikacjaMacro and microstructural damage was studied in typical glass fibre-reinforced polymer laminates with two types of coating systems – (a) isophtalic gel coat: pure or mixed with SiO2 nanoparticles 5 wt% (5%N) or 10 wt% (10%N) and (b) a two-layer coating system: urethane-modified vinyl ester-based gel coat and additional polyester barrier coat layer. Accelerated tests were performed at 50C for 50 days for specimens with nanoparticle-modified...
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Relationship between vortex structures and shear localization in 3D granular specimens based on combined DEM and Helmholtz-Hodge decomposition.
PublikacjaRelationship between vortex structures and shear localization in 3D granular specimens based on combined DEM and Helmholtz-Hodge decomposition. Granular Matter, doi:10.1007/s10035-018-0815-0, 2018.
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Unusual odd-chain and trans-octadecenoic fatty acids in tissues of feral European beaver (Castor fiber), Eurasian badger (Meles meles) and raccoon dog (Nyctereutes procyonoides).
PublikacjaW lipidach wyizolowanych z różnych partii ciała bobrów, borsuków i jenotów stwierdzono obecność znaczących ilości niezwykłych jak na zwierzęta jednożołądkowe kwasów tłuszczowych - nieparzystowęglowych nasyconych i jednonienasyconych KT (15:0, 17:0, 15:1 i 17:1) oraz (w lipidach tkanek bobra i jenota) oktadecenowych KT konfiguracji trans, w tym kwasu wakcenowego - KT charakterystycznych dla tkanek i mleka przeżuwaczy. Obecność tych...
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On extremal sizes of locally k-tree graphs
PublikacjaA graph G is a locally k-tree graph if for any vertex v the subgraph induced by the neighbours of v is a k-tree, k>=0, where 0-tree is an edgeless graph, 1-tree is a tree. We characterize the minimum-size locally k-trees with n vertices. The minimum-size connected locally k-trees are simply (k + 1)-trees. For k >= 1, we construct locally k-trees which are maximal with respect to the spanning subgraph relation. Consequently, the...
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Wpływ rozwinięcia powierzchni na przenoszenie ciepła podczas wrzenia R 22 wewnątrz rur
PublikacjaPrzedstawiono wyniki badań przejmowania ciepła i spadku ciśnienia podczas wrzenia czynnika chłodniczego R 22 w przepływie wewnątrz rur poziomych. Badanymi rurami były: rura miedziana niskożebrowana typu "micro-fin", rura ze stali nierdzewnej śrubowoformowana, a także miedziana i stalowa rura gładka. Średnica zewnętrzna rur wynosiła 10 mm. Eksperymenty prowadzono przy temperaturze nasycenia 0 stopni C, stopniu suchości na wlocie...
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Badania wrzenia R22 w rurkach z powłoką porowatą. Investigation of R22 flow boiling in porous tubes.
PublikacjaW pracy przedstawiono wyniki pomiarów współczynnika przejmowania ciepła przy wrzeniu w przepływie R22 w poziomej rurce z aluminiową powłoką porowatą. Otrzymane dane odniesiono do wyników uzyskanych dla gładkiej stalowej rurki oraz rurki typu microfin. Rurka gładka i z powłoką porowatą była wykonana ze stali nierdzewnej o grubości ścianki 0.6 mm. Grubość powłoki porowatej wynosiła 0,2 mm. Eksperymenty prowadzono przy stopniu suchości...
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Assessment of the application of CEM III with exposed aggregate as an alternative to CEM I for road pavements
PublikacjaThe article presents a results of study on the impact of replacing CEM I SR3/NA by CEMIII/A LH/HSR/NAon the mechanical properties and durability of pavement concrete with exposed aggregate. Was used granite aggregate and washed sand. Water/cement () ratio in the tested concretes constituted 0.35 and 0.4 and part of the cement was replaced with a 5% addition of natural pozzolana – zeolite. Compressive strength tests were performed...
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Growth and Electric Transport of Ca-doped PrBa2Cu3O7-δSingle Crystals
PublikacjaCrystal growth of Ca-doped PrBa2Cu3O (Pr-123) single crystals by slow cooling of Pr3O11-CaCO3-BaCO3-CuO melts (self-flux technique) in ambient air atmosphere was studied. As the first approach the growth of Ca-free crystals in Al2O3 and ZrO2 crucibles was investigated. The best quality crystals with the average size of 5 x 5 x 0.2mm3 were obtained from Al2O3 crucibles for Ba/Cu = 0.41 and 15 wt.% (2.41 mol.%) of stoichiometric...
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Design and synthesis of TiO2/Ti3C2 composites for highly efficient photocatalytic removal of acetaminophen: The relationships between synthesis parameters, physicochemical properties, and photocatalytic activity
PublikacjaIn this study, we report the potential of TiO2/Ti3C2 composite fabricated by oxidation of MXene for degradation of persistent organic pollutants. The effect of the synthesis conditions (time, temperature, and reaction environment) on the morphology, physicochemical properties, and photocatalytic activity was investigated. It was found that acetaminophen degradation was positively correlated with TiO2 content in the composite structure. Furthermore,...
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Natural convective heat transfer from isothermalconic
PublikacjaTheoretical considerations on convective heat transfer from isothermal upward conicalsurfaces have been presented. The physical model of this phenomenon consists of an isothermalcone of inclination angle (φ) between the cone generating line (X) and the radius (R) of the cone base. The angle is a parameter of conical surface which varied from (φ = 0−circular horizontal plate) to (φ = π/2—vertical cylinder) . Onthe basis of Navier–Stokes...
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COMPOSITION OF BIOACTIVE SECONDARY METABOLITES AND MUTAGENICITY OF SAMBUCUS NIGRA L. FRUIT AT DIFFERENT STAGES OF RIPENESS
PublikacjaThe relationship between the content of bioactive compounds and mutagenic activity of elderberry fruit at different stages of ripeness was investigated. Signifi cant differences in the antioxidant profi les (TLC, HPLC with post-column derivatization) and antioxidant activity (ABTS, DPPH, and FC tests) were observed for studied elderberry extracts. The more ripen the fruit at the time of harvest were, the higher the content of...
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Stability investigation of the PCM nanocomposites
PublikacjaIn present study was showed the results of research the stability of nanoPCMs in terms of types and concentrations of surfactant used. For stearic acid has been added PVP or oleic acid in concentrations of 0%, 5% and 10%. Nanoparticles TiO2 and Al-2O3 in concentration of 1% were chosen to be researched in this test. The mixing of nanocomposites has been done in an ultrasonic scrubber in which the samples were placed for 45 mins....
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Enzymatyczna acydoliza jako metoda otrzymywania niskokalorycznych strukturyzowanych lipidów. Enzymatic acydolysis as a method for obtaining low-calorie structured lipids.
PublikacjaBadano stopień wbudowania się kwasów tłuszczowych krótko- i średniołańcuchowych C6 - C10 oraz kwasu behenowego C22 w TAG oleju rzepakowego, na drodze enzymatycznej acydolizy. Stwierdzono, że przy zachowaniu tych samych stosunków molowych oleju do kwasu 1:5, najmniej wbudowało się kwasu kapronowego C6 (9,9%) a najwięcej kwasu kaprynowego D10 (27,2%). Kwasy te wbudowały sie głównie w pozycje zewnętrzne sn-1,3 TAG a tylko niewielkie...
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Optimisation of conditions for precipitation of collagen from solution using kappa-carrageenan. Studies on collagen from the skin of Baltic cod (Gadus morhua)
PublikacjaZbadano wpływ stężenia kolagenu (0,012-3%) wyekstrahowanego ze skór dorsza bałtyckiego (Gadus morhua) i stężenia kappa-karagenu w obecności NaCl (0-5%) na wydajność strącania włókien kolagenowych z roztworu przy pH 2,2-8. Stwierdzono, że wydajność strącania włókien jest wprost proporcjonalna do masowego stosunku kappa-karagen : kolagen w zakresie niższym od 0,4. Kolagen rozpuszczony w kwasie cytrynowym jest całkowicie strącony,...
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Development of novel (BiO)2OHCl/BiOBr enriched with boron doped-carbon nanowalls for photocatalytic cytostatic drug degradation: Assessing photocatalytic process utilization in environmental condition
PublikacjaIn this work, a series of novel (BiO)2OHCl/BiOBr-x%B:DGNW (x = 0%, 1%, 1.5%, 2%) composites with different content of boron-doped diamond/graphene nanowalls (B:DGNW) were fabricated by simple solvothermal synthesis. A boron-doped diamond/graphene nanowalls (B:DGNW) were prepared by CVD method. A series of analyses: XRD, XPS, SEM, and TEM showed that the photocatalyst (BiO)2OHCl/BiOBr-x%B:DGNW with a “flower-like” morphology was...
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Estimation of a smoothness parameter by spline wavelets
PublikacjaWe consider the smoothness parameter s*(f) of a function f∈L2(R) in terms of Besov spaces. The existing results on estimation of smoothness [K. Dziedziul, M. Kucharska and B. Wolnik, J. Nonparametric Statist. 23 (2011)] employ the Haar basis and are limited to the case 0
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Generic invariant measures for iterated systems of interval homeomorphisms
PublikacjaIt is well known that iterated function systems generated by orientation preserving homeomorphisms of the unit interval with positive Lyapunov exponents at its ends admit a unique invariant measure on (0, 1) provided their action is minimal. With the additional requirement of continuous differentiability of maps on a fixed neighbourhood of {0,1} { 0 , 1 } , we present a metric in the space of such systems which renders it complete....
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Diffusion equations with spatially dependent coefficients and fractal Cauer-type networks
PublikacjaIn this article, we formulate and solve the representation problem for diffusion equations: giving a discretization of the Laplace transform of a diffusion equation under a space discretization over a space scale determined by an increment h > 0, can we construct a continuous in h family of Cauer ladder networks whose constitutive equations match for all h > 0 the discretization. It is proved that for a finite differences discretization...
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Peroxymonosulfate-assisted photocatalytic degradation of artificial sweeteners in water
PublikacjaIn the present study, peroxymonosulfate (PMS) activation was proposed for efficient photocatalytic degradation of aspartame, acesulfame, saccharin, and cyclamate - artificial sweeteners frequently present in wastewaters and surface waters worldwide. The TiO2 nanosheets with exposed {0 0 1} facets were synthesised using the fluorine-free lyophilisation technique as a green concept for the synthesis and used for the photodegradation...