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Wyniki wyszukiwania dla: EMISSION CHARACTERISTICS
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Tire camber angle influence on tire-pavement noise
PublikacjaTaking into account tire-pavement noise and tires classification with respect to noise emission special measurement methods are usually used. When two of them are applied (the Laboratory Drum Method (DR) and the Close-Proximity Method (CPX)) the investigator has to be sure that the position of the tire is correct. The authors of this paper thought about tire position as tire (wheel) alignment in particular tire camber angle. They...
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New coordination polymers based on a V-shaped ligand and lanthanides: Structural description and symmetry-luminescence correlation using europium as a probe
PublikacjaWe have synthesized new luminescent coordination polymers using 4,4'-sulfonyldibenzoic acid (H2SDA) and several lanthanide ions by open crystallization in DMF. Three different 1-D structures were obtained, as determined by single-crystal X-ray diffraction: [La(η2-NO3)(μ-SDA)(DMF)3]n (1), [Sm(η2-NO3)(μ-SDA)(DMF)2 2DMF]n (3), [Ln(η2-NO3)(μ-SDA)(DMF)2 DMF]n (Ln ¼ Eu (4), Dy (5), Ho (6), Er (7), Tm (8) and Lu(9)). A 2-D structure,...
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Visible light activity of rare earth metal doped (Er3+, Yb3+ or Er3+/Yb3+) titania photocatalysts
PublikacjaA series of Er3+-TiO2, Yb3+-TiO2 and Er3+/Yb3+-TiO2 photocatalysts were obtained via sol-gel method, using rare earth metal (RE) precursor ranging from 0.25 to 10 mol%. The experiments demonstrated that phenol in aqueous solutions was successfully degraded under visible light (> 450 nm) using RE3+-TiO2. The as-prepared samples were characterized by X-ray diffraction (XRD), X-ray photoelectron emission spectroscopy (XPS), UV-Vis...
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Concentration‐Induced Hetero‐Valent Partial‐Inverse Occupation of Infrared Phosphor
PublikacjaInfrared luminescent materials have evoked much attention from chemists and material scientists. Although substantial progress is made in materials design, the luminescent mechanism remains ambiguous in the complex structures, presenting major barriers to developing novel infrared luminescent materials. Herein, this study aims to deliberate a complete discussion on infrared phosphors with concentration-induced hetero-valent partial-inverse...
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Lead(II) coordination polymers with imidazole-4- and pyrazole-3-carboxylate isomeric linkers: Structural diversity and luminescence properties
PublikacjaUsing 1H-imidazole-4-carboxylic acid (4imCOOH) and 1H-pyrazole-3-carboxylic acid (3pyrCOOH) coordination polymers [Pb(4imCOO)2(H2O)]n (1) and [Pb2(3pyrCOO)4]n (2) were constructed. Obtained polymers were characterized via FT-IR, X-ray, PL and TG methods. The coordination polyhedron around Pb(II) in 1 is described as distorted pentagonal pyramid with hemidirected coordination sphere (based on DFT calculations). Compound 2 consists...
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Surface-Plasmon-Coupled Emission of Rhodamine 110 in a Silica Nanolayer
PublikacjaThe first observation of strong directional surface-plasmon-coupled emission (SPCE) of Rhodamine 110 in silica nanofilms deposited on silver nanolayers is reported. The preparation of the material is described in detail. The intensity of SPCE exceeds 10 times that of free space fluorescence and total linear light polarization in the SPCE ring is observed. A new experimental setup and an original data collection method is presented....
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The Role of Molecular Structure in Monte Carlo Simulations of the Secondary Electron Yield and Backscattering Coefficient from Methacrylic Acid
PublikacjaIn this paper, we show the influence of the chemical structure of four different conformers on the secondary electron emission and backscattering of an electron beam from a gel of methacrylic acid. The conformers have different permanent dipole moments, which determines the cross sections for elastic collisions with electrons. The cross sections are used in Monte Carlo simulations of an electron beam, which enters the gel of methacrylic...
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Interactive information and decision support system for urban and industrial air quality management based on multi-agent system
PublikacjaThis article presents conception of interactive information and decision support system for urban and industrial air quality management. The emphasis of the project is on real-time analysis and multi-media information, and the support of distributed and mobile clients through the Internet. The approach integrates meteorological data and forecasts, air quality and emission monitoring, dynamic 3D simulation modelling and forecasting,...
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Monoterpenes emissions from different samples of wood-based materials – laminated chipboards and medium-density fiberboards (MDF)
PublikacjaThe paper presents the results of studies on emission rates of monoterpenes, carried out with the use of a new type of device - Markes’ Micro-Chamber/Thermal Extractor™ (μ-CTE250). Subject of studies were different types of wood-based materials such as: laminated chipboards and medium-density fiberboards (MDF). Based on the results obtained one can conclude that the laminated chipboards may affect the indoor air quality in much...
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Spectroscopic properties of Rhodamine B entrapped in hybrid porous nanolayers at high dye concentration
PublikacjaThe preparation procedure and characterization of Rhodamine B entrapped in zirconia, silica and mixed silica–zirconia nanolayers is described. The nanolayers were produced by the sol–gel spin-coating technique. The pronounced effect of the dye concentration on the absorption and fluorescence spectra as well as on time-resolved fluorescence spectra was found. The results show that the aggregation of Rhodamine B is stronger in silica...
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The forming and emission of high power electromagnetic pulses
PublikacjaAn impulse energy source, a power conditioning system and an electromagnetic field emitter are essential to generate an electromagnetic field pulse (EMFP) with a specific frequency bandwidth. Selected simulation results for a power conditioning system consisting of a fuse opening switch and a paraboloidal electromagnetic emitter have been presented in this article. The synthetic system examined in the simulation is powered by an...
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Price Changes in Wholesale Market of Electrical Energy in Poland
PublikacjaThe article discusses the Price changes on the wholesale electricity market in Poland Moreover, The price levels on the futures electricity markets and the spot transactions market are presented. The impact of emission charges under the EU ETS on the price of electricity in the domestic market has been taken into consideration Furthermore, the basic determinants of the generation structure in Poland that influence the level of...
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Study of microstress state of P91 steel using complementary mechanical Barkhausen, magnetoacoustic emission, and X-ray diffraction techniques
PublikacjaThe paper deals with assessment of microstress state of martensite P91 steel using three complementary techniques: mechanical Barkhausen emission, magnetoacoustic emission (MAE), and X-ray diffraction (XRD) profile analysis. Magnetic coercivity Hc and microstructure were investigated with inductive magnetometry and magnetic force microscopy (MFM), respectively. Internal stress level of P91 steel was modified by heat treatment....
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Spectroscopic study of atmospheric pressure 915 MHz microwave plasma at high argon flow rate
PublikacjaIn this paper results of optical emission spectroscopic (OES) study of atmospheric pressure microwave 915 MHz argon plasma are presented. The plasma was generated in microwave plasma source (MPS) cavity- resonant type. The aim of research was determination of electron excitation temperature Texc gas temperature Tg and electron number density ne. All experimental tests were performed with a gas flow rate of 100 and 200 l/min and...
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Tuning of photocatalytic activity by creating a tridentate coordination sphere for palladium
PublikacjaThe synthesis and characterisation of an asymmetric potential bridging ligand bmptpphz (bmptpphz = 2,17-bis(4-methoxyphenyl)tetrapyrido[3,2-a:2’,3’-c:3’’,2’’-h:2’’’,3’’’-j] phenazine) is presented. This ligand contains a 1,10-phenanthroline (phen) and a 2,9-disubstituted phen sphere and possesses a strong absorbance in the visible. Facile coordination of the phen sphere to a Ru(tbbpy)2 core leads to Ru(bmptpphz) ([(tbbpy)2Ru(bmptpphz)](PF6)2;...
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The emissions of monoaromatic hydrocarbons from small polymeric toys placed in chocolate food products
PublikacjaThe article presents findings on the emissions of selected monoaromatic hydrocarbons from children's toys placed in chocolate food products. The emission test system involved the application of a new type of microscale stationary emission chamber, μ-CTE™ 250. In order to determine the type of the applied polymer in the manufacture of the tested toys, Fourier transform infrared spectroscopy and thermogravimetric analysis coupled...
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Negative impact of constant RPM control strategy on ship NOx emission in waves
PublikacjaIn severe wave conditions, the ship propulsion system is loaded with high fluctuations due to external disturbances. The highly fluctuating loads enforce radical changes in the main engine torque, which in turn demands variation of the fuel rate injected into the cylinders if a constant rotational speed strategy is applied. Therefore, the temperature of gases varies to a large extent during the combustion process in the cylinders....
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Wild oscillations in a nonlinear neuron model with resets: (II) Mixed-mode oscillations
PublikacjaThis work continues the analysis of complex dynamics in a class of bidimensional nonlinear hybrid dynamical systems with resets modeling neuronal voltage dynamics with adaptation and spike emission. We show that these models can generically display a form of mixed-mode oscillations (MMOs), which are trajectories featuring an alternation of small oscillations with spikes or bursts (multiple consecutive spikes). The mechanism by...
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Evaluating the effect of different operational strategies on the carbon footprint of wastewater treatment plants – case studies from northern Poland
PublikacjaNowadays, low greenhouse gas (GHG) emission is expected at wastewater treatment plants (WWTPs). However, emission quantification and evaluation still faces difficulties related to data availability and uncertainty. The objective of this study was to perform carbon footprint (CF) analysis for two municipal WWTPs located in northern Poland. Slupsk WWTP is a large biological nutrient removal (BNR) facility (250,000 PE) which benefits...
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The forming and emission of high power electromagnetic pulses
PublikacjaAn impulse energy source, a power conditioning system and an electromagnetic field emitter are essential to generate an electromagnetic field pulse (EMFP) with a specific frequency bandwidth. Selected simulation results for a power conditioning system consisting of a fuse opening switch and a paraboloidal electromagnetic emitter have been presented in this article. The synthetic system examined in the simulation is powered by...
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Optoelektroniczny system przestrzennego monitoringu wzbudzenia plazmy w procesach syntezy optycznych warstw diamentopodobnych
PublikacjaPrzedmiotem pracy jest optoelektroniczny system do badania wzbudzenia plazmy mikrofalowej w procesie syntezy warstw DLC (ang. Diamond Like-Carbon). W komunikacie zaprezentowano budowę systemu do przestrzennego monitoringu stanu wzbudzenia plazmy podczas procesu CVD. System SR-OES (ang. Spatially Resolved Optical Emission Spectroscopy) umożliwia określanie rozkładu wzbudzenia cząstek w przestrzeni komory i na tej podstawie wybrania...
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Electron impact fragmentation of pyrrole molecules studied by fluorescence emission spectroscopy
PublikacjaThe fluorescence emission spectroscopy using electron impact excitation technique was employed to study fragmentation processes of the gas phase pyrrole molecules. The following excited fragmentation species were observed by detection of their fluorescence decay: the atomic hydrogen H(n), n = 4-7 and the diatomic CH(A2Δ), CN(B2Σ+), NH(A3Π) and C2(d3Πg) fragments. These atomic and molecular products differ from those previously...
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Multi-source-supplied parallel hybrid propulsion of the inland passenger ship STA.H. Research work on energy efficiency of a hybrid propulsion system operating in the electric motor drive mode
PublikacjaIn the Faculty of Ocean Engineering and Ship Technology, Gdansk University of Technology, design has recently been developed of a small inland ship with hybrid propulsion and supply system. The ship will be propelled by a specially designed so called parallel hybrid propulsion system. The work was aimed at carrying out the energy efficiency analysis of a hybrid propulsion system operating in the electric motor drive mode and at...
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Instantaneous impedance monitoring of AA 7075 aluminum alloy corrosion in borate buffer with admixed chloride ions
PublikacjaThe study presents a research capabilities of Dynamic Electrochemical Impedance Spectroscopy (DEIS) as a tool used for instantaneous on-line monitoring of corrosion processes on the example of AA 7075 aluminum alloy. A borate buffer with admixed chloride ions in a quantity ranging from 0.05 to 25 mM was used to represent different types of corrosion attack. The surface of samples specimens was evaluated before and after the tests...
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3D PCB package for GaN inverter leg with low EMC feature
PublikacjaThis paper presents the adaptation of a 3D integration concept previously used with vertical devices to lateral GaN devices. This 3D integration allows to reduce loop inductance, to ensure more symmetrical design with especially limited Common Mode emission, thanks to a low middle point stray capacitance. This reduction has been achieved by both working on the power layout and including a specific shield between the devices and...
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The impact of sediment, fresh and marine water on the concentration of chemical elements in water of the ice-covered lagoon
PublikacjaThe common use of chemical elements by man has been contributing to their extraction for centuries. As a consequence, they have been directly or indirectly introduced into the biogeochemical cycle. In the framework of many conventions, mining and processing of elements are currently subject to many restrictions. However, their large load that has already been deposited in the soil and bottom sediments can be remobilised and...
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Reduction of CO2 Emissions from Offshore Combined Cycle Diesel Engine-Steam Turbine Power Plant Powered by Alternative Fuels
PublikacjaDiverse forms of environmental pollution arise with the introduction of materials or energy that exert adverse effects on human health, climate patterns, ecosystems, and beyond. Rigorous emission regulations for gases resulting from fuel combustion are being enforced by the European Union and the International Maritime Organization (IMO), directed at maritime sectors to mitigate emissions of SOx, NOx, and CO2. The IMO envisions...
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Lanthanide ions (Eu3+, Er3+, Pr3+) as luminescence and charge carrier centers in Sr2TiO4
PublikacjaA series of strontium orthotitanate (Sr2TiO4) samples doped with 2% of a mole of europium, praseodymium, and erbium were obtained using the solid-state synthesis method. The X-ray diffraction (XRD) technique confirms the phase purity of all samples and the lack of the influence of dopants at a given concentration on the structure of materials. The optical properties indicate, in the case of Sr2TiO4:Eu3+, two independent emission...
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Deep Eutectic Solvents: Properties and Applications in CO2 Separation
PublikacjaNowadays, many researchers are focused on finding a solution to the problem of global warming. Carbon dioxide is considered to be responsible for the “greenhouse” effect. The largest global emission of industrial CO2 comes from fossil fuel combustion, which makes power plants the perfect point source targets for immediate CO2 emission reductions. A state-of-the-art method for capturing carbon dioxide is chemical absorption using...
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Recent advances in hydrogen production from biomass waste with a focus on pyrolysis and gasification
PublikacjaThis paper presents the results research on the optimal fuel compositions and the control parameters of the spark ignition engine fueled with syngas-biogas-hydrogen for the purpose of setting up a flexible electronic control unit for the engine working in a solar-biomass hybrid renewable energy system. In syngas-biogas-hydrogen mixture, the optimal content of hydrogen and biogas is 20% and 30%, respectively. Exceeding these thresholds,...
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Thermal efficiency investigations on the self-ignition test engine fed with marine low sulfur diesel fuels
PublikacjaWithin the article an issues of implementing the new kinds of marine diesel fuels into ships’ operation was described taking into ac-count restrictions on the permissible sulphur content introduced by the International Maritime Organization. This is a new situation for ship owners and fuel producers, which forces the necessity to carry out laboratory research tests on especially adapted engine stands. How to elaborate the method...
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Up-conversion white emission and other luminescence properties of a YAG:Yb2O3·Tm2O3·Ho2O3@SiO2 glass-nanocomposite
PublikacjaWe report on a glass-nanocomposite material consisting of yttrium aluminum garnet (Y3Al5O12, YAG) nanocrystals co-doped with Yb3+, Tm3+ and Ho3+ ions as well as entrapped into a SiO2 xerogel. This 94YAG·5Yb2O3·0.8Tm2O3·0.2Ho2O3@SiO2 (abbr. YAG:YbTmHo@SiO2) nanocomposite material has been prepared by sol–gel procedure. Its structure and morphology has been characterized by means of X-ray diffraction (XRD) and scanning electron microscope...
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Emissions and toxic units of solvent, monomer and additive residues released to gaseous phase from latex balloons
PublikacjaThis study describes the VOCs emissions from commercially available latex balloons. Nine compounds are determined to be emitted from 13 types of balloons of different colors and imprints in 30 and 60°C. The average values of total volatile organic compounds (TVOCs) emitted from studied samples ranged from 0.054 up to 7.18 μg∙g-1 and from 0.27 up to 36.13 μg∙g-1 for 30oC and 60oC, respectively. The dataset is treated with principal...
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Biocomposites from recycled resources as candidates for laboratory reference material to validate analytical tools used in organic compounds emissions investigation
PublikacjaA suitably chosen reference material should meet specific criteria like representing one of the compound classes most commonly occurring in indoor materials as well as having optimal long-term stability during storage and transport to its destination point and having a compact size. The described interdisciplinary pilot research was aimed to develop and characterize a polymer-based candidate for the laboratory reference material...
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Flexible syngas-biogas-hydrogen fueling spark-ignition engine behaviors with optimized fuel compositions and control parameters
PublikacjaThis paper presents the results research on the optimal fuel compositions and the control parameters of the spark ignition engine fueled with syngas-biogas-hydrogen for the purpose of setting up a flexible electronic control unit for the engine working in a solar-biomass hybrid renewable energy system. In syngas-biogas-hydrogen mixture, the optimal content of hydrogen and biogas is 20% and 30%, respectively. Exceeding these thresholds,...
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Possibilities for Developing Electromobility by Using Autonomously Powered Trolleybuses Based on the Example of Gdynia
PublikacjaTrolleybus transport refers to contemporary challenges related to a reduction in emissions of greenhouse gases and CO2 into the atmosphere formulated by international institutions, such as the United Nations, the Organisation for Security and Co-operation in Europe, or the European Union. Departure from fossil fuels in urban transport is one of the key challenges for the coming years. Trolleybuses are an important tool in this...
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Rational Use of Primary Energy in Single-Family Residential Houses
PublikacjaThis work presents results of the primary energy use for heating residential single-family house. Analysis includes domestic hot water system (DHW) and heating, ventilation and air condition system (HVAC). During researches the conventional and alternative energy sources (natural gas, biomass, fuel oil, bituminous coal, lignite or electric energy obtained from electric power system – EPS) were used in DHW and HVAC systems. Furthermore...
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Formation of OH Radicals as Evidence of Intramolecular Hydrogen Migration in Cation-Induced Dissociation of Furan Molecules
PublikacjaWe present the experimental results on a hydrogen atom migration preceding fragmentation of the furan molecules induced by the H3+ and C+ impact. The excited OH(A2Σ+) radical has been detected among the furan decomposition products using collision-induced emission spectroscopy. However, the OH moiety is absent in the furan ring skeleton, so detecting the OH(A2Σ+→X2Π) luminescence indicates the intramolecular H atom relocation prior...
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Terminal charging scheduling of battery electric buses based on vehicle routing problem
PublikacjaElectric buses are considered to be a viable solution for reducing emission in dense urban areas. However, the greater charging time is a huge challenge for operators. In this paper, charging scheduling method was elaborated based on vehicle routing problem using mixed-integer linear programming model. The main novelty of the paper is the combination of modelling aspect, namely flexible turn sequence and heterogeneous shared charging...
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Silver complexes stabilized by large silanethiolate ligands – crystal structures and luminescence properties
PublikacjaBulky silanethiolate and disiladithiolate ligands were applied to synthesize one mononuclear and three trinuclear silver complexes including two cyclic “microclusters” and a linear tri-nuclear silanethiolate complex. All obtained compounds are characterized by X-ray diffraction and FT-IR. NMR and emission spectroscopies were used where possible. The first trinuclear anionic silver thiolate is structurally characterized. The influence...
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Marine Fuel Sulphur Limit Impact on Air Pollution
PublikacjaThe article presents calculation of Sulphur oxides percentage drop rate in marine industry recorded after 01.01.2020 when new limits, provided by International Maritime Organizations legislation, became effective. Ships’ SOx global emission was estimated and compared between 4th quarter 2019 and 1st quarter 2020. For more accurate estimation 3 seaside cities with big harbors were selected for statistical analysis. Noticeable...
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A BODIPY‐Based Molecular Rotor in Giant Unilamellar Vesicles: A Case Study by Polarization‐Resolved Time‐Resolved Emission and Transient Absorption Spectroscopy
PublikacjaBODIPY and BODIPY-derived systems are widely applied as fluorophores and as probes for viscosity detection in solvents and biological media. Their orientational and rotational dynamics in biological media are thus of vital mechanistic importance and extensively investigated. In this contribution, polarization-resolved confocal microscopy is used to determine the orientation of an amphiphilic BODIPY-cholesterol derivative in homogeneous...
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Application of mechanistic and data-driven models for nitrogen removal in wastewater treatment systems
PublikacjaIn this dissertation, the application of mechanistic and data-driven models in nitrogen removal systems including nitrification and deammonification processes was evaluated. In particular, the influential parameters on the activity of the Nitrospira activity were assessed using response surface methodology (RSM). Various long-term biomass washout experiments were operated in two parallel sequencing batch reactor (SBR) with a different...
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Laboratory station for research of the innovative dry method of exhaust gas desulfurization for an engine powered with residual fuel
PublikacjaContemporary methods of exhaust gas desulfurization in marine engines are all expensive methods (4-5 million euro). This is, among other reasons, due to the limited market audience, but primarily due to the monop-olized position of manufacturers offering fabrication and assembly of this type of marine ship installations. Proposed as part of a research project financed by the Regional Fund for Environmental Protection and Maritime...
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Atmospheric opacity estimation based on IWV derived from GNSS observations for VLBI applications
PublikacjaThermal emission of atmospheric water vapor has a great influence on the calibration of radio astronomical observations at millimeter wavelengths. The phenomenon of an atmospheric water vapor emits noise signal and attenuates astronomical emission. At 22 GHz, integrated water vapor (IWV) obtained from global navigation satellite systems (GNSS) is strictly related to atmospheric opacity (τ0), which is a crucial parameter for data...
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Neutral Dissociation of Pyridine Evoked by Irradiation of Ionized Atomic and Molecular Hydrogen Beams
PublikacjaThe interactions of ions with molecules and the determination of their dissociation patterns are challenging endeavors of fundamental importance for theoretical and experimental science. In particular, the investigations on bond-breaking and new bond-forming processes triggered by the ionic impact may shed light on the stellar wind interaction with interstellar media, ionic beam irradiations of the living cells, ion-track nanotechnology,...
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Te use of acoustic emission for assessment of the oil lubricity in a four-ball tester
Publikacjain view of the increased dynamic and temperature load in the compression-ignition engine tribological systems, particular attention is drawn to the problem of such lubrication of the friction nodes that after breaking the boundary layer it could be restored without any wear occurring. therefore, an idea has been devised of introducing to friction nodes, with the lubrication oils, of new substances (operational preparations) modifying...
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Optoelectronic system for investigation of cvd diamond/DLC layers growth
PublikacjaDevelopment of the optoelectronic system for non-invasive monitoring of diamond/DLC (Diamond-Like-Carbon) thin films growth during μPA ECR CVD (Microwave Plasma Assisted Electron Cyclotron Resonance Chemical Vapour Deposition) process is described. The system uses multi-point Optical Emission Spectroscopy (OES) and long-working-distance Raman spectroscopy. Dissociation of H2 molecules, excitation and ionization of hydrogen atoms...
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Application of acoustic emission for detection of fatigue microdemage in main and crank bearings for diesel engines
PublikacjaThe article presents reasons for applying the acoustic emission (AE) to detect fatigue microdamage in main bearings and crank bearings of ship main engines. Problem of determination of the fatigue life for slide bearing bushes was characterized in general. There were demonstrated properties of the objects of research, which were bushings made of the MB58 alloy, as well as an overall description of the research. It was shown that...
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Local Dye Concentration and Spectroscopic Properties of Monomer−Aggregate Systems in Hybrid Porous Nanolayers
PublikacjaAnalysis of absorption, fluorescence, and time-resolved emission spectra of rhodamine 6G in hybrid porous nanolayers at high dye concentration allowed identification of two fluorescent species: monomers and fluorescent aggregates. The method of determination of mean local concentration of aggregates in matrices is proposed based on the energy transfer process between monomers and fluorescent aggregates. Evaluation of aggregate...