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Search results for: CUSTOMS UNION
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Effectiveness of toluene separation from gas phase using supported ammonium ionic liquid membrane
PublicationAmmonium ionic liquids (ILs) are relatively cheap in synthesis and environmentally benign and despite that they have been very rarely used in gas separation. In this research we used several ammonium ILs as liquid membranes for removal of residual toluene from gas phase. Ionic liquids used in this study were composed of bis(trifluoromethylsulfonyl)imide anion [Tf2N] and trimethylbutylammonium [N1114], trietylbutylammonium [N2224],...
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Synteza, właściwości i zastosowanie cieczy jonowych, pochodnych naturalnych związków organicznych
PublicationW ramach pracy doktorskiej zaprojektowano, zsyntezowano oraz określono właściwości cieczy jonowych zawierających w swojej strukturze cząsteczki pochodzenia naturalnego – głównie aminokwasów w postaci N-acetylowanej. Wybrane ciecze jonowe zostały wykorzystane jako katalizatory przeniesienia fazowego w reakcjach N- oraz C¬-substytucji. Wydajności reakcji zostały porównane ze standardowymi katalizatorami. Innym rodzajem otrzymanych...
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Thermodynamic study of binary mixtures of 2-propanol with ionic liquids, 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexylammonium bis(trifluoromethylsulfonyl)imide
PublicationIn this work, densities, speeds of sound, refractive indices and viscosities of three binary mixtures containing the ionic liquids 1-hexyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexyl-ammonium bis(trifluoromethylsulfonyl)imide, mixed with 2-propanol at wide temperature and composition ranges at atmospheric pressure have been measured. From these...
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Spontaneous electron emission vs dissociation in internally hot silver dimer anions
PublicationReferring to a recent experiment, we theoretically study the process of a two-channel decay of the diatomic silver anion (Ag2-), namely the spontaneous electron ejection giving Ag2 + e- and the dissociation leading to Ag- + Ag. The ground state potential energy curves of the silver molecules of diatomic neutral and negative ion were calculated using proper pseudo-potentials and atomic basis sets. We also estimated the non-adiabatic...
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Assessment of the Bulgarian Wastewater Treatment Plants’ Impact on the Receiving Water Bodies
PublicationDeterioration of water quality is a major problem world widely according to many international non-governmental organizations (NGO). As one of the European Union (EU) countries, Bulgaria is also obliged by EU legislation to maintain best practices in assessing surface water quality and the efficiency of wastewater treatment processes. For these reasons studies were undertaken to utilize ecotoxicological (Microtox®, Phytotoxkit...
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Eco-friendly modification of bitumen: The effects of rubber wastes and castor oil on the microstructure, processability and properties
PublicationThe bitumen industry in the European Union is facing several difficulties, including rising demand, unstable oil supply, rising prices for synthetic polymer modifiers, and a focus on lowering carbon footprint. Bitumen modification with crumb rubber (CR) is one of the most promising solution to these challenges. However, CR-modified bitumen have poor processability and low storage stability. To overcome these flaws we are introducing...
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The Bridge to Knowledge – Open Access to Scientific Research Results on Multidisciplinary Open System Transferring Knowledge Platform
PublicationThe European policy of Open Access to scientific research is now one of the key issues discussed in public debates on the future development of scientific communication. The implementation of Open Access tools has significant impact on scientific and economic growth. On the one hand, Open Access accelerates disseminating new research findings and facilitates recognition of authors on a more global scale. On the other hand, Open...
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Tools for road infrastructure safety management in Poland
PublicationThe objective of road safety infrastructure management is to ensure that when roads are planned, designed, built and used road risks can be systematically identified, assessed, removed and mitigated. There are a number of approaches to road safety management. European Union Directive 2008/96/EC requires EU member states to use four basic tools of road safety infrastructure management. An overview of the methods in these countries...
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Polish FDI in Central Asian Countries
PublicationSince gaining independence, Kazakhstan, Kyrgyzstan, Tajikistan, Turkmenistan and Uzbekistan gradually opened their markets to foreign investors. Before Poland’s accession to the European Union, the activities of Polish investors in Kazakhstan, Kyrgyzstan, Tajikistan, Turkmenistan and Uzbekistan were based on bilateral treaties concluded by Poland with those countries. Later, except Turkmenistan, they were governed by the partnership...
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Resource productivity and environmental degradation in EU-27 countries: context of material footprint
PublicationThis study explores the relationship between the resource productivity and environmental degradation in European Union-27 countries. This study tests this relationship in context of high, moderate, and low material footprint sub-samples; these samples are formed utilizing the expectation–maximization machine learning algorithm. Using the panel data set of EU-27 countries from 2000 to 2020, linear and non-linear autoregressive distributed...
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Liquid chromatography techniques for separation of flavonoids from Droseraceae
PublicationFlavonoids which are presented in insectivorous plants of the Droseraceae family have wide range of advantageous properties i.e. an antioxidant, anti-inflammatory and antimicrobial activities, antitumor activity was reported as well.The purpose of the research was to develop the most favourable conditions for liquid chromatographic separation and identification of myricetin and quercetin in extracts of insectivorous plants. In...
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Technology convergence and digital divides. A country-level evidence for the period 2000–2010
PublicationThe paper, mostly empirical in nature, investigates issues on cross-national new information and communication technologies (ICTs) adoption patterns and growth directions. In the period of 2000–2010, a great number of countries underwent substantial changes on the field of ICTs implementation. Many of them made a great “jump” starting with almost “zero level” of ICTs adoption in the year 2000 and during the ten- year period were...
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Pedestrian protection, speed enforcement and road network structure the key action for implementing Poland's Vision Zero
PublicationSince 1991 Poland's road safety has been systematically improving with a 60% reduction in road deaths. Despite the progress Poland continues to be one of the European Union' worst performing countries. The country's main road safety problems remain unchanged: dangerous behaviour of road users, underdeveloped system of road safety management and low quality of road infrastructure. This is why subsequent road safety programmes (implemented...
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The significance of institutions' potential to increase Youth civic participation – case study of the South Baltic Youth Core Groups Network Project
PublicationYoung people are a very important group of modern societies, they will replace the currently ruling generation and will shape our common future. Due to that, young people have become the relevant target of national and international policy and science researches. Youth civic participation is a key aspect of the development of a society and should be shaped by effective youth policy at the national and international levels. This...
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Post‐Second World War Reconstruction of Polish Cities: The Interplay Between Politics and Paradigms
PublicationBy the end of the Second World War, many of the Polish cities—and especially their historic centres—were in ruins. This was caused by both bombings and sieges conducted by the Nazis and Soviets. The particular group of cities is associated with former German lands—now called the “Recovered Territories”—which were incorporated into the borders of Poland as compensation for its Eastern Borderlands lost to the Soviet Union. These...
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Fiscal decentralization in the European Countries: a cluster analysis approach
PublicationThe scope of public authority depend on many factors. One of them is a declaration, usually expressed in the constitution of a given country (Sferlea, 2014, Libman, 2010, Nehmelman, Vetzo, 2016) of the application of the decentralisation principle in the performance of public tasks. Despite this declaration, the structure of the public sector and the tasks carried out at different levels in particular countries are not identical....
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Reduction of CO2 Emissions from Offshore Combined Cycle Diesel Engine-Steam Turbine Power Plant Powered by Alternative Fuels
PublicationDiverse forms of environmental pollution arise with the introduction of materials or energy that exert adverse effects on human health, climate patterns, ecosystems, and beyond. Rigorous emission regulations for gases resulting from fuel combustion are being enforced by the European Union and the International Maritime Organization (IMO), directed at maritime sectors to mitigate emissions of SOx, NOx, and CO2. The IMO envisions...
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Possibilities for Developing Electromobility by Using Autonomously Powered Trolleybuses Based on the Example of Gdynia
PublicationTrolleybus transport refers to contemporary challenges related to a reduction in emissions of greenhouse gases and CO2 into the atmosphere formulated by international institutions, such as the United Nations, the Organisation for Security and Co-operation in Europe, or the European Union. Departure from fossil fuels in urban transport is one of the key challenges for the coming years. Trolleybuses are an important tool in this...
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Medical Image Dataset Annotation Service (MIDAS)
PublicationMIDAS (Medical Image Dataset Annotation Service) is a custom-tailored tool for creating and managing datasets either for deep learning, as well as machine learning or any form of statistical research. The aim of the project is to provide one-fit-all platform for creating medical image datasets that could easily blend in hospital's workflow. In our work, we focus on the importance of medical data anonimization, discussing the...
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Experimental research on helical coil biomass boiler with oil as a heating fluid
PublicationThis paper presents an experimental research of helical coil biomass boiler with thermal oil heating agent. Heat exchanger consists of two coaxial helical coils swept by the flue gases. The burner is a single vertical retort connected to the fuel tank (wooden pellets). The boiler is a part of micro-power plant in which the heat from the boiler is exchanged with low-boiling HFE7100 to produce steam for a custom steam turbine. The...
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Microfluidically Frequency-Reconfigurable Self-Quadruplexing Antenna Based on Substrate Integrated Square-Cavity
PublicationIn this article, a novel concept of self-quadruplexing tunable antenna (SQTA) enabled by microfluidic channels is investigated. The operating channels are either filled with air or dielectric liquids to enable frequency tunability. The proposed SQTA is implemented on the substrate-integrated square-cavity (SISC). A swastika-shaped slot is milled on the top-surface of the SISC to create four quarter-mode resonators. The resonators...
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Mutual Coupling Reduction in Antenna Arrays Using Artificial Intelligence Approach and Inverse Neural Network Surrogates
PublicationThis paper presents a novel approach to reduce undesirable coupling in antenna arrays using custom-designed resonators and inverse surrogate modeling. To illustrate the concept, two stand-ard patch antenna cells with 0.07λ edge-to-edge distance are designed and fabricated to operate at 2.45 GHz. A stepped-impedance resonator is applied between the antennas to suppress their mutual coupling. For the first time, the optimum values...
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Low-strain sensor based on the flexible boron-doped diamond-polymer structures
PublicationA free-standing high boron-doped diamond nanosheet (BDDNS) has been fabricated for the development of a flexible BDDNS strain senor. High boron-doped diamond was initially grown on a tantalum substrate in a microwave plasma-assisted chemical vapor deposition method, and was then transferred to a Kapton polymer substrate to fabricate the flexible BDDNS/Kapton device. Before performing the transfer process, the thin BDDNS’s morphology...
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WYDATKI INWESTYCYJNE WOJEWÓDZTW SAMORZĄDOWYCH PO WPROWADZENIU INDYWIDUALNEGO WSKAŹNIKA ZADŁUŻENIA
PublicationOkreślenie dopuszczalnego poziomu zadłużenia jest ważną kwestią dla każdej jednostki samorządu terytorialnego w Polsce, a jej ranga jeszcze rośnie, jeśli samorząd odczuwa silną presję na dbanie o rozwój obszaru, na którym funkcjonuje, borykając się równocześnie z niedostatkiem dochodów. Taka sytuacja dotyczy większości województw samorządowych, które spośród wszystkich szczebli struktury samorządowej...
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Thermal performance of a prototype plate heat exchanger with minichannels under boiling conditions
PublicationTo solve the problem and to meet the requirements of customers in the field of high heat fluxes transfer in compact units, a new design of plate heat exchanger with minichannels (minichannels PHE) was proposed. The aim was to construct a compact heat exchanger of high effectiveness for the purpose of household cogeneration ORC system. In this paper the experimental analysis of an assembled prototype of such compact heat exchanger...
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Hybrid Finite Element Method Development for Offshore Structures’ Calculation with the Implementation of Industry Standards
PublicationIn the design process of offshore steel structures, it is typical to employ commercial calculation codes in which simulation and evaluation of results are performed on the basis of the available standards (e.g. API, DNV, Lloyds). The modeling and solution rely on finite element methods and cover the simulation of the structure’s properties along with the influence of the marine environment – sea currents, wave and wind loading,...
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Field Calibration of Low-Cost Particulate Matter Sensors Using Artificial Neural Networks and Affine Response Correction
PublicationDue to detrimental effects of atmospheric particulate matter (PM), its accurate monitoring is of paramount importance, especially in densely populated urban areas. However, precise measurement of PM levels requires expensive and sophisticated equipment. Although low-cost alternatives are gaining popularity, their reliability is questionable, attributed to sensitivity to environmental conditions, inherent instability, and manufacturing...
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Modernization and adaptation of historical interiors
PublicationModernization of the historical building's interior entails the need to take many decisions, often conflicting. Operational requirements, protection of the architectural heritage, fire-safety recommendations, construction regulations, all these aspects involve a whole set of problems that require a rational solution, respecting ambient architectural and historical value, as well as the needs arising from the planned transformation....
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Efficient Simulation-Based Global Antenna Optimization Using Characteristic Point Method and Nature-Inspired Metaheuristics
PublicationAntenna structures are designed nowadays to fulfil rigorous demands, including multi-band operation, where the center frequencies need to be precisely allocated at the assumed targets while improving other features, such as impedance matching. Achieving this requires simultaneous optimization of antenna geometry parameters. When considering multimodal problems or if a reasonable initial design is not at hand, one needs to rely...
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Deep eutectic solvents with solid supports used in microextraction processes applied for endocrine-disrupting chemicals
PublicationThe determination of endocrine-disrupting chemicals (EDCs) has become one of the biggest challenges in Analytical Chemistry. Due to the low concentration of these compounds in different kinds of samples, it becomes necessary to employ efficient sample preparation methods and sensitive measurement techniques to achieve low limits of detection. This issue becomes even more struggling when the principles of the Green Analytical Chemistry...
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Resource constrained neural network training
PublicationModern applications of neural-network-based AI solutions tend to move from datacenter backends to low-power edge devices. Environmental, computational, and power constraints are inevitable consequences of such a shift. Limiting the bit count of neural network parameters proved to be a valid technique for speeding up and increasing efficiency of the inference process. Hence, it is understandable that a similar approach is gaining...
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Lighting conditions in Home Office and occupant’s perception: an international study
PublicationThe global pandemic and physical distancing restrictions are forcing us to rethink how residential buildings are used regarding the visual environment. This paper describes home office lighting conditions within different countries and continents. The aim is to define the current limitations of home offices in providing a resilient visual environment. The work was developed by a team of international experts working together on...
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Static Shunt PE Voltage-Quality Controllers
PublicationThis chapter focuses on power electronics (PE)-based solutions used in distribution networks for reduction of supply-voltage-quality deterioration, from long interruptions to the harmonics. Various PE devices and their combinations are addressed for particular or a range of voltage disturbances. A particular solution is applied taking into account demands for voltage quality and network configuration. In general, there are three...
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(CsX)Cu5O2(PO4)2 (X = Cl, Br, I): A Family of Cu2+ S = 1/2 Compounds with Capped-Kagomé Networks Composed of OCu4 Units
PublicationThree new salt inclusion compounds (CsX)Cu5O2(PO4)2 (X = Cl, Br, I), phosphate analogues of the kagomé mineral averievite, are reported. Their crystal structures are composed of trigonal networks of corner-sharing OCu4 anion-centered tetrahedra, forming capped-kagomé planes, which can also be regarded as two-dimensional slices along the [111] direction of a pyrochlore lattice. Magnetization and heat capacity measurements reveal...
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Fate of Ionic Liquids in Soils and Sediments
PublicationZrozumienie losu cieczy jonowych w glebach i osadach dennych jest istotnym elementem ich implementacji z zachowaniem idei zrównoważonego rozwoju. Niniejsza publikacja zawiera analizę i podsumowanie danych dotyczących oddziaływań cieczy jonowych w roztworach wodnych oraz agregacji na powierzchniach stałych. Zaobserwowano, że silnie lipofilowe ciecze jonowe zawierające długi łańcuch węglowodorowy lub duży organiczny anion wykazują...
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Measurement of activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-hexyl-1,4-diaza[2.2.2]bicyclooctanium bis(trifluoromethylsulfonyl)imide using gas–liquid chromatography
PublicationBased on gas–liquid chromatography (GLC) retention data, activity coefficients at infinite dilution of 39 different solutes in the ionic liquid 1-hexyl-1,4-diaza[2.2.2]bicyclooctanium bis(trifluoromethylsulfonyl)imide ([HDABCO][NTf2]) have been determined. Measurements covered a broad range of types of organic solutes including alkanes, alcohols, ketones, benzene derivatives and McReynold’s compounds. Activity coefficients were...
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Temperature-dependent structure-property modeling of viscosity for ionic liquids
PublicationIn this paper we present the methodology for assessing the ionic liquids' viscosity at six temperature points (25, 35, 45, 50, 60 and 70 [C]), which utilizes only the in silico approach. The main idea of such assessment is based on the "correction equation" describing the correlation between experimentally measured viscosity and theoretically derived density (calculated with use of molecular mechanics), given at 6 different temperature...
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Use of pyridinium and pyrrolidinium ionic liquids for removal of toluene from gas streams
PublicationSeparation of toluene from a toluene/N2 gas mixture using supported liquid membranes based on a series of pyridinium (1-butylpyridinium- bis(trifluoromethylsulfonyl)imide - [C4Py][Tf2N], 1-hexylpyridinium trifluoromethanesulfone [C6Py][Tf2N]) and pyrrolidinium (1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide - [C4Pyrr][Tf2N], 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide - [C6Pyrr][Tf2N], 1-butyl-1-methylpyrrolidinium...
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Preparation of Allyl Alcohol Oligomers Using Dipicolinate Oxovanadium(IV) Coordination Compound
PublicationCurrently, new precatalysts for olefin oligomerization are being sought in the group of vanadium(IV) complexes. Thus, the aim of our research was to examine the catalytic activity of the oxovanadium(IV) dipicolinate complex [VO(dipic)(H2O)2] 2 H2O (dipic = pyridine-2,6-dicarboxylate anion) in 2-propen-1-ol oligomerization as well as to characterize oligomerization products using matrix-assisted laser desorption/ionization–time-of-flight...
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Efecto contagio en el uso del voto electrónico en Estonia: de las elecciones a otros niveles de la administración pública y la sociedad
PublicationEstonia, cuarto país más pequeño de la Unión Europea tras Luxemburgo, Chipre y Malta, con una población que no alcanza el millón y medio de habitantes, ha sido en los últimos años objeto de atención mediática internacional por considerarlo the World’s more digital country (GREENWALD, 2018) , the first “Digital” Country (LUFKIN, 2017) o the Digital Republic (HELLER, 2017); así como uno de los referentes en el mundo académico en...
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Impact of the Alkyl Side Chains of Cations and Anions on the Activity and Renaturation of Lysozyme: A Systematic Study Performed Using Six Amino‐Acid‐Based Ionic Liquids
PublicationThe impact of the structure of ionic liquid on the activity and renaturation of lysozyme from the hen egg white (HEWL) was investigated. A set of six ionic liquids based on morpholinium cation and N-acylated amino acids as anions were exploited. The matrix used was based on two homologous series: one with N-acetyl-L-valinate [Val] as a common anion and morpholinium cation with a different number of carbon atoms in the n-alkyl chain...
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Propagation of Ship-Generated Noise in Shallow Sea
PublicationContamination of sea environment by noise and any energy radiated to water constitutes today a problem to which more and more attention is paid, in view, a.o., of consequences of an impact of these factors onto marine fauna. European Union has introduced a directive by which EU countries are made responsible to undertake efforts aimed at reaching a good envirenmental status of European seas by 2020. A main source of underwater...
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Spatial Distribution of Eucalyptus Plantation and its Impact on the Depletion of Groundwater Resources of Tehsil Swat Ranizai, District Malakand
PublicationNative to the continent of Australia, eucalyptus is a tall, evergreen tree belonging to the Myrtaceae family. Malakand district has the largest eucalyptus plantation in the province, covering an area of 22,071.29 ha. The present study aims to evaluate its impact on the groundwater table (GWT) in three selected union councils (UCs) of the study area, i.e., Agra, Totakan, and Kot. Both primary and secondary data support the study....
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Application of dispersive liquid - liquid microextraction for determination of pesticides from various chemical groups in water samples
PublicationPesticides are a global risk because they move with the wind, rain and sea currents from other regions, which makes getting to places which were never used before. Their presence was detected in all types of water circulating in the ecosystem, which is an easy source of exposure to life and health of all living organisms. Currently, it is considered one of the most dangerous and toxic pollutants, which fate and function is still...
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Tools for road infrastructure safety management – Polish experiences
PublicationThe objective of road safety infrastructure management is to ensure that when roads are planned, designed, built and used road risks can be systematically identified, assessed, removed and mitigated. There are a number of approaches to road safety management. European Union Directive 2008/96/EC requires EU member states to use four basic tools of road safety infrastructure management. An overview of the methods in these countries...
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Comparison of hydrophilic interaction and reversed phase liquid chromatography coupled with tandem mass spectrometry for the determination of eight artificial sweeteners and common steviol glycosides in popular beverages
PublicationHydrophilic interaction liquid chromatography (HILIC) coupled with tandem mass spectrometry (MS/MS) was used to separate artificial and natural sweeteners approved for use in European Union (EU). Among three tested HILIC columns (BlueOrchid PAL-HILIC, Ascentis Express Si and Acclaim™ Trinity™ P2) the last one was selected for the development of HILIC method due to the best results obtained with it. Early eluting and coeluting compounds...
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C2 NIWA Community-Segmentation Criteria and Building Brand Associations on the Example of a Selected Target Group
PublicationEvery organization which offers products or services wishes to communicate with their customers in the most effective way. This kind of communication is based on proper selection of target groups, which are extracted in the process of market segmentation. That is way it is very important to ask the question to whom the message is to be directed and what kind of message we want to give. This article describes the selection criteria...
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Towards solving heterogeneous fleet vehicle routing problem with time windows and additional constraints: real use case study
PublicationIn advanced logistic systems, there is a need for a comprehensive optimization of the transport of goods, which would reduce costs. During past decades, several theoretical and practical approaches to solve vehicle routing problems (VRP) were proposed. The problem of optimal fleet management is often transformed to discrete optimization problem that relies on determining the most economical transport routes for a number of vehicles...
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Agile Commerce in the light of Text Mining
PublicationThe survey conducted for this study reveals that more than 84% of respondents have never encountered the term “agile commerce” and do not understand its meaning. At the same time, they are active participants of this strategy. Using digital channels as customers more often than ever before, they have already been included in the agile philosophy. Based on the above, the purpose of the study is to analyse major text sets containing...
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Economics of credit scoring management
PublicationCredit scoring models constitute an inevitable element of modern risk and profitability management in retail financial lending institutions. Quality,or separation power of a credit scoring model is usually assessed with the Gini coefficient. Generally, the higher Gini coefficient the better, as in this way a bank can increase number of good customers and/or reject more bad applicants. In...