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Search results for: GREEN MOF
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Ionic conductivity in bismuth silicate glasses.
PublicationZbadano właściwości elektryczne szkieł krzemianowo- bizmutowych zawierających 55 mol% tlenku bizmutu. Uzyskane wyniki potwierdzają jonowy charakter przewodnictwa, za które odpowiedzialne są jony tlenu.
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The electronic structure of p-xylylene and its reactivity with vinyl molecules
PublicationThe electronic states of p-xylylene molecule were described at the multi-configurational CASSCF/MRMP2 level of theory. The closed-shell singlet state representing the quinoidal p-xylylene molecule was pre-dicted to be the ground electronic state whereas the triplet (benzoidal) and the singlet open-shell states were found to be much higher in energy (by 159 and 423 kJ/mol, respectively, as found at the CASSCF(8,8)/6-31+G(d) level)....
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In Vitro and In Vivo Imaging-Based Evaluation of Doxorubicin Anticancer Treatment in Combination with the Herbal Medicine Black Cohosh
PublicationAs a substitution for hormone replacement therapy, many breast cancer patients use black cohosh (BC) extracts in combination with doxorubicin (DOX)-based chemotherapy. In this study, we evaluated the viability and survival of BC- and DOX-treated MCF-7 cells. A preclinical model of MCF-7 xenografts was used to determine the influence of BC and DOX administration on tumor growth and metabolism. The number of apoptotic cells after...
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Unprecedented Adhesive Performance of Propylene-Based Hydroxyl Functionalized Terpolymers
PublicationThe synthesis of hydroxyl functionalized propylene-based terpolymers and their performance as hot melt adhesives were investigated. The products comprise uniformly distributed butyl and 4-hydroxyl-butyl branches along the polypropylene backbone. Despite the low hydroxyl-functionality level of ≤ 0.5 mol%, hydroxyl functionalized terpolymers show formidable adhesion to aluminum and steel providing an adhesive strength exceeding 16...
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A framework estimating the minimum sample size and margin of error for maritime quantitative risk analysis
PublicationThe average accident frequency is essential for quantitative risk analysis and is conventionally estimated from accident statistics. This paper has systematically synthesised the knowledge on statistical errors and offered the missing instructions, a framework, for determining the minimum sample size and the margin of error (MOE) when calculating the average accident frequency from an accident database at hand. We have applied...
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Influence of the addition of citric acid on the physico-chemical properties of poly(sorbitol sebacate-co- butylene sebacate)
PublicationThe article presents the results of the physicochemical properties of poly(sorbitol sebacate- co-butylene sebacate) (PSBS) obtained with 0.25; 0.5; 0.75; 1 mol of citric acid (KC). It was shown that PSBS obtained with 0.25 and 0.5 mol KC is characterized by the most optimal mechanical and thermal properties. As a result of the study, it was found that the use of sorbitol and citric acid allows obtaining ester materials with...
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High resolution liquid chromatography and time of flight mass spectrometry in perfume analysis
PublicationPerfumes consist of a wide range of natural and synthetic compounds that belongs to different chemical classes. Most of these compounds are generally determined by GC. However, in this study RP-HPLC-Q-TOF-MS and HILIC-Q-TOF-MS technique was applied for the determination of ingredients of original perfumes and their imitations. Antioxidants and compounds specific to fragrances of animal \origin were found in original...
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Wpływ rozwiązań technicznych i rozwiązań technologicznych na efektywność w ciepłownictwie
PublicationPrzedstawiono zagadnienia wpływu rozwiązań technicznych i technologicznych na efektywność w ciepłownictwie. Opisano nowoczesne rozwiązania złącza rur preizolowanych ze szczególnym uwzględnieniem muf termokurczliwych sieciowanych radiacyjnie.
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Multicriteria Decision Analysis and Grouping of Analytical Procedures for Phthalates Determination in Disposable Baby Diapers
PublicationThis study presents the application of one of the tools from the multicriteria decision analysis set (MCDA), the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS). Selected green analytical chemistry metrics were used to rank analytical procedures for the phthalate determination in disposable baby diapers. Nine analytical procedures were assessed in order to find one that has the lowest environmental impact...
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Band engineering of BiOBr based materials for photocatalytic wastewater treatment via advanced oxidation processes (AOPs) – A review
PublicationSemiconductor based photocatalysts have been an efficient technology for water and wastewater remediation, addressing the concepts of green chemistry and sustainable development. Owing to narrow and suitable band structure, BiOBr is a promising candidate for efficient wastewater treatment via photocatalysis. Enhancement of photocatalytic properties can be obtained by various techniques like doping, element rich strategy, facet...
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The innovative exploitation of Brassica vegetables in the production of quality food for health. From lab bench to field and fork.
PublicationThe specific chemical composition of vegetables belonging to Brassicaceace , as regard both nutrients and non-nutrients, renders them particularly suitable for the health food production chain. The ability of these plants to accumulate heavy metals may be utilised for phytoremediation of arable soils, but also as a vehicle to fortify foods in micronutriens such as selenium. The bioactive organosulfur compounds, especially glucosinolates...
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A Visual Method of Measuring Railway-Track Weed Infestation Level
PublicationThis paper concerns the assessment of railway track surface conditions in relation to the degree of weed infestation. The paper conceptually describes the proposed method using a visual system to analyse weed infestation level. The use of image analysis software for weed detection is also proposed. This new measurement method allows for a mobile assessment of the track’s weed infestation status. Validation of the assessment method...
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A quasi-2D small-signal MOSFET model - main results
PublicationMain results stemming from a new quasi 2D non-quasi-static small-signal four-terminal model of the MOSFET are presented in this work. The model is experimentally verified up to 30 GHz.
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Technological solutions for boosting hydrogen role in decarbonization strategies and net-zero goals of world shipping: Challenges and perspectives
PublicationFacing the problems concerning greenhouse gas (GHG) emissions from international ocean shipping has meant that the latest regulations of the International Maritime Organization, issued on 1st January 2023, have come into force, with the aim of reducing GHG emissions from maritime activities. Hydrogen has been suggested as an alternative fuel to achieve decarbonization ambitions in the near future. Although hydrogen has been investigated...
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Greencoin: a Proenvironmental Action-Reward System
PublicationThe massive destruction of the natural environment is rapidly eroding the world’s capacity to provide food and water, threatening the security of billions of people. In order to facilitate green lifestyles – understood in terms of both pro-environmental behaviors and green self-image on the one hand, and to build sustainable local and global communities, on the other, we put forward an idea of a novel action-reward system based...
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The content of biogenic amines in Rondo and Zweigelt wines and correlations between selected wine parameters
PublicationThe purpose of this study was to evaluate the content of biogenic amines (BAs) in wines using dispersive liquid–liquid microextraction–gas chromatography–mass spectrometry (DLLME-GC–MS). An additional objective was to assess the correlations between selected parameters characterizing the samples such as the content of BAs, sugars, and organic acids, pH, and total acidity. Wines produced from the same grape variety in which alcoholic...
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Water uptake and energetics of the formation of barium zirconate based multicomponent oxides
PublicationA group of multi-component oxides based on BaZrO3 have been prepared using a solid-state reaction method and examined in terms of their water uptake and thermodynamics of formation. Depending on the type and amount of acceptor substitution, the synthesized compounds exhibit various proton defect concentrations, reaching up to 0.2 mol/mol for a compound containing 10 different elements in the B-sublattice, where 50% of them are...
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Chapter 31. Preparation of silver doped titanium dioxide nanoparticles in microemulsion system
PublicationNanocząstki TiO2 domieszkowanego srebrem przygotowano w mikroemulsji woda-AOT-cykloheksan. Zbadano wpływ zawartości srebra (od 1,5 do 8,5% mol.) na aktywność fotokatalityczą oraz właściwości bakterio- i grzybobójcze. Stwierdzono, że TiO2 modyfikowany za 6,5% mol. Ag wykazuje najwyższą aktywność w reakcji degradacji fenolu oraz najwyższą aktywność mikrobiologiczną. Aktywność mikrobiologiczną wyznaczano jako minimalne stężenie hamujące...
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Are deep eutectic solvents useful in chromatography? A short review
PublicationA literature update has been done concerning Deep Eutectic Solvents (DES) use in chromatography applications. The literature survey was based on the period from 2010 till 2020 and manuscripts reported in the data bases Web of Science and Scopus. The use of DES as mobile phase and mobile phase additives, stationary phases and solid phase modifiers and the use of DES as reaction solvents for chromatography use, were evaluated. Emphasis...
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Application of deep eutectic solvents (DES) in analytical chemistry
PublicationRecent years have been associated with efforts to reduce the impact on the natural environment. A greener approach has been introduced in various areas of science, including analytical chemistry. One of the basic procedures for preparing a sample for analysis is its extraction. Traditional methods involve the use of large amounts of organic compounds, often toxic, with an unfavorable impact on the environment. A representative...
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Praca farmy wiatrowej w krajowym systemie elektroenergetycznym w świetle wymagań stawianych wymianie międzysystemowej
PublicationW referacie przedstawiono wpływ elektrowni wiatrowych na moc przesyłaną między poszczególnymi systemami elektroenergetycznymi pracującymi synchronicznie. Zamieszczono również wymagania stawiane elektrowniom wiatrowym jako obiektom uczestniczącym w systemowych procesach regulacyjnych.
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Enhanced Spectroscopic Insight into Acceptor-Modified Barium Strontium Titanate Thin Films Deposited via the Sol–Gel Method
PublicationIn the present paper, composite thin films of barium strontium titanate (BaxSr1−xTiO3) with an acceptor modifier (magnesium oxide—MgO) were deposited on metal substrates (stainless steel type) using the sol–gel method. The composite thin films feature BaxSr1−xTiO3 ferroelectric solid solution as the matrix and MgO linear dielectric as the reinforcement, with MgO concentrations ranging from 1 to 5 mol%. Following thermal treatment...
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New LED photoreactor with modulated UV–vis light source for efficient degradation of toluene over WO3/TiO2 photocatalyst
PublicationThe efficiencies of prepared WO3/TiO2 photocatalysts with varying amounts of WO3 were evaluated for gas-phase photocatalytic degradation of toluene. The obtained results revealed that the best photocatalytic properties were characteristic for samples calcined at 500ºC, which can be associated with high crystalline phase content (> 97%) and favourable BET surface area. The photocatalytic degradation tests were performed in two photoreactors...
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Relatively high-Seebeck thermoelectric cells containing ionic liquids supplemented by cobalt redox couple
PublicationMeanwhile no general and reliable equation determining the Seebeck coefficient (S e ) and involving electro-chemical reaction effects was derived for solutions. We reported the database of 15,000 ionic liquids supplemented by three different redox couple systems: 0.01 mol/l Co 3+/2+ (bpy) 3 , 0.01 mol/l I 3-/3I- and 0.2 mol/l 3- /3I- , and the corresponding estimated Seebeck coefficients. We also reported methods for estimating...
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Multi-fidelity aerodynamic design trade-off exploration using point-by-point Pareto set identification
PublicationAerodynamic design is inherently a multi-objective optimization (MOO) problem. Determining the best possible trade-offs between conflicting aerodynamic objectives can be computationally challenging when carried out directly at the level of high-fidelity computational fluid dynamics simulations. This paper presents a computationally cheap methodology for exploration of aerodynamic design trade-offs. In particular, point-by-point...
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The response of human colon cancer cells to C-1748 (4-methyl-1-nitroacridine derivative) treatment
PublicationPrzeprowadzone badania miały na celu określenie wpływu pochodnej 4-metylo-1-nitroakrydyny C-1748 na komórki ludzkiego raka okrężnicy HCT8 oraz HT29. Komórki obu linii, traktowane badanym związkiem, ulegały przede wszystkim apoptozie, przy czym liczba komórek apoptotycznych była znacznie większa w przypadku linii HCT8. Ponadto, proliferacja części komórek HCT8, została zahamowana w wyniku uruchomienia procesu starzenia, czego nie...
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Luminescence properties of MgF2:Yb2+ at high hydrostatic pressure
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An independent relationship between plasma leptin and heart rate in untreated patients with essential hypertension
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Induction of G2/M phase arrest and apoptosis of human leukemia cells by potent antitumor triazoloacridinone C-1305
PublicationWykazaliśmy, że pochodna triazoloakrydonu C-1305 w stężeniach biologicznie istotnych indukuje blok cyklu komórkowego w fazie G2/M i apoptozę w komórkach białaczek ludzkich MOLT4 i HL60. Zjawisko apoptozy zostało określone na podstawie charakterystycznych zmian morfologicznych jak i biochemicznych tj. fragmentacji DNA, aktywacji kaspazy 3, cięcia PARP, spadku potencjału mitochondrialnego i ATP oraz eksternalizacji fosfatydyloseryny.
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Search for the fundamental solution to the vector acoustic wave equations
PublicationCzasowo-przestrzenna funkcja Greena pola swobodnego jest dobrze znanym rozwiązaniem podsta-wowym skalarnego niejednorodnego równania falowego. Wyraża ona odpowiedź ośrodka płynnego na punktowe zaburzenie o symetrii sferycznej. Odpowiedź ośrodka na zaburzenie wektorowe nie jest tak oczywista. Artykuł przedstawia oryginalne podejście do problemu, polegające na systematycznej, szcze-gółowej weryfikacji hipotetycznych rozwiązań skalarnych...
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Analiza montażu stożkowo-planetarnej przekładni zębatej.
PublicationPrzedstawiono budowę i montaż stożkowo-planetarnej przekładni zębatej, przenoszącej moc 400 kW przy przełożeniu 1:22,21. Porównano dwie wersje harmonogramów montażu przekładni, wskazując na możliwości skrócenia cyklu o 22%.
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A non-quasi-static small-signal model of the four-terminal MOSFET for radio and microwave frequencies.
PublicationW pracy zaprezentowano nowy małosygnałowy model tranzystora MOS, w którymuwzględnia się efekt nasycenia prędkości nośników. Model jest spójny fizycznie i może być stosowany w analizie dowolnej konfiguracji włączenia tranzystora.
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WŁAŚCIWOŚCI ELEKTRYCZNE SZKIEŁ TLENKOWYCH ZAWIERAJĄCYCH Fe2O3
PublicationZbadano właściwości elektryczne szkieł krzemianowo – ołowiowo - żelazowych. Szkła tlenkowe zawierające jony żelaza mogą potencjalnie wykazywać przewodnictwo polaronowe. Celem niniejszej pracy było bliższe określenie zachodzącego w nich mechanizmu przewodnictwa. Wytworzono szkła o składzie dobranym na podstawie ich zakresu szklenia: (50 – 0.5x)[SiO2, PbO] - xFe2O3 gdzie x wynosił odpowiednio 2, 5, 10, 15, 20 i 25 (w % mol). Otrzymane...
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Influence of Antimony Substitution on Spontaneous Strain and Thermodynamic Stability of Lanthanum Orthoniobate
PublicationThe analysis of the antimony substitution influence on temperature dependence of unit cell distortion has been done. The values of spontaneous strain and Landau order parameter for three different antimony contents varied had been calculated. The phase transition occurring for antimony substituted lanthanum orthoniobate was found to be second order. The high temperature solution calorimetry method has been used to investigate...
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Automated Reduced Model Order Selection
PublicationThis letter proposes to automate generation of reduced-order models used for accelerated -parameter computation by applying a posteriori model error estimators. So far,a posteriori error estimators were used in Reduced Basis Method (RBM) and Proper Orthogonal Decomposition (POD) to select frequency points at which basis vectors are generated. This letter shows how a posteriori error estimators can be applied to automatically select...
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Zagadnienie obciążeń okrętowych silników głównych o zapłonie samoczynnym
PublicationZaprezentowano pogląd na temat przydatności mocy użytecznej jako wielkości fizycznej, stosowanej do jednoznacznego określenia obciążenia silnika o zapłonie samoczynnym. Scharakteryzowano ją na przykładzie teoretycznych charakterystyk zewnętrznych okrętowych silników głównych. Wykazano, że do jednoznacznej oceny obciążenia silnika powinny być zastosowane inne wielkości fizyczne niż jego moc użyteczna. Moc użyteczna nie może być...
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A study of a reduction of a micro- and nanometric bismuth oxide in hydrogen atmosphere
PublicationA reduction of bismuth oxide in hydrogen atmosphere was investigated. The reaction was performed with a material in various structural forms: powder: with micrometric grains, powder with nanometric grains and powder pressed into pellets. The process was performed in both isothermal and non-isothermal conditions. An activation energy of the reaction calculated with Friedman method was found to be about 85 kJ/mol for the reduction...
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Miniaturized solid-phase extraction techniques
PublicationMore than 80% of analysis time is spent on sample collection and sample preparation, so sample preparation is a critical part of the analytical process. Traditionally, liquid-liquid extraction was developed and employed to screen for general unknowns. However, solid-phase extraction (SPE) is becoming highly popular as an alternative, due to its simplicity and economy in terms of time and solvent. This review summarizes the current...
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MARKAL long-term power generation scenarios for Poland - Concept of the model
PublicationIn this paper we have presented the concept of Polish MARKAL optimization model developed for the needs of power generation scenarios in long-term perspective i.e. by 2040. The depiction of Polish MARKAL with Reference Energy System structure was provided. In addition, basic model assumptions, energy technology database, projections of electricity demand and power plant ageing pathways were presented. Our goal is to test MARKAL...
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Zakłócenia sprzężenia podłożowego w układach scalonych CMOS
PublicationTemat artykułu stanowią zagadnienia modelowania sprzężenia podłożowego w układach scalonych CMOS. Zaprezentowana została metoda modelowania podłoża oparta na funkcji Green´a, która pozwala projektantom wygenerować model podłoża na podstawie danych geometrycznych projektu topografii oraz danych technologicznych procesu. Na podstawie symulacji komputerowej dwóch mieszanych układów scalonych (oscylator pierścieniowy i "analogowy"...
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Assessing the industrialization progress of hydrodynamic cavitation process intensification technology: a review
PublicationHydrodynamic cavitation (HC) is widely acknowledged as a promising green approach for enhancing various production and waste management processes, such as water treatment, sludge pretreatment, lignocellulosic biomass (LCB) pretreatment, emulsification, and food processing. Despite demonstrating superior industrialization potential compared with other emerging technologies such as ultrasound and microwave, the widespread commercial...
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Cellulose Nanomaterials in Biomedical, Food, and Nutraceutical Applications: A Review
PublicationNanotechnology with bionanomaterials have tremendous potential to enhance and utilize for nutrient and bioactive absorption, drug delivery systems, pharmaceutical, and nutraceutical field through various applications. Cellulose nanomaterials are green materials that are obtained from renewable sources and possess exceptional mechanical strength and biocompatibility. The associated unique physical and chemical properties have made...
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Combined extraction and microextraction techniques: Recent trends and future perspectives
PublicationThe latest advancements in the analytical sample preparation indicate a trend of combining different extraction techniques with targeting an improvement in separation, cleanup, detection limits, enrichment factors, and dealing with complex matrices. This manuscript identifies mainly two groups of combined sample preparation techniques. The first group integrates conventional or enhanced extraction techniques with microextraction....
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A quasi-2D small-signal MOSFET model - main results
PublicationDynamic properties of the MOS transistor under small-signal excitation are determined by kinetic parameters of the carriers injected into the channel, i.e., the low-field mobility, velocity saturation, mobility at the quiescent-point (Q-point), longitudinal electric field in the channel, by dynamic properties of the channel, as well as by an electrical coupling between the perturbed carrier concentration in the channel and the...
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The Mechanism of a Retro-Diels–Alder Fragmentation of Luteolin: Theoretical Studies Supported by Electrospray Ionization Tandem Mass Spectrometry Results
PublicationThe mechanisms of retro-Diels–Alder fragmentation of luteolin are studied theoretically using the Density Functional Theory method (B3LYP hybrid functional) together with the 6-311++G(d,p) basis set and supported by electrospray ionization tandem mass spectrometry (ESI-MS) results. The reaction paths leading to the formation of 1,3A and 1,3B fragment ions observed as the main spectral features in the ESI-MS spectrum are described...
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Increasing the conductivity of V2O5-TeO2 glass by crystallization: structure and charge transfer studies
PublicationIn the present paper, V 2 O 5 -TeO 2 glass was prepared by the melt-quenching technique. Crystallization of glass with a vanadium content higher than 35%mol results in an increase in electrical conductivity by a few orders of magnitude and a decrease in activation energy from ~0.40 to ~0.12 eV. In this work, a critical review of existing charge transfer models was presented on the example of V 2 O 5 -TeO 2 glass and glass–ceramics....
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Future of nature, our future. A preregistered report on future time perspective, social value orientation, and pro-environmental outcomes based on data from Poland and Sweden
PublicationIntroduction: The objective of the study was to examine the role of social value orientation and future time perspective to account for individual differences in pro-environmental behaviors, intentions, and opinions about the link between pro-environmental action and pandemic threat (three separate models) in Polish and Swedish samples expected to differ in rate of pro-environmental behaviors (higher in Sweden). We hypothesized...
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Sztokholm : Europejska Zielona Stolica 2010 : tytuł dla miasta przyjaznego środowisku naturalnemu
PublicationTytuł "The European Green Capital Award" (EGCA) jest co roku przyznawana miastu europejskiemu, które przoduje w promocji rozwiązań urbanistycznych przyjaznych środowisku naturalnemu. Tytuł "Zielonej Stolicy Europy 2010" przyznano stolicy Szwecji - Sztokholmowi. W ocenie ekspertów miasto Sztokholm zostało uhonorowane tytułem za długoterminową wizję ochrony środowiska. Eksperci podkreślają fakt, że około 95% populacji tego miasta...
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Extreme weather layer method for implementation of nature-based solutions for climate adaptation: Case study Słupsk
PublicationOne of the most severe climate risks that is expected to affect all regions is related to stormwater. Climate models, constructed based on long-term trends, show that extreme weather events such as storms, cloudbursts and a large rise in sea level will be significant in the coming decades. Moreover, even the frequency and intensity of “normal” rainfall events, such as microbursts, are expected to be remarkably higher than today...
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Pendant Proton-Relays Systematically Tune the Rate and Selectivity of Electrocatalytic Ammonia Generation in a Fe-Porphyrin Based Metal-Organic Framework
PublicationElectrocatalytic nitrite reduction (eNO2RR) is a promising alternative route to produce ammonia (NH3). Until now, several molecular catalysts have shown capability to homogeneously reduce nitrite to NH3, while taking advantage of added secondary-sphere functionalities to direct catalytic performance. Yet, realizing such control over heterogeneous electrocatalytic surfaces remains a challenge. Herein, we demonstrate that heterogenization...