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Search results for: CVD DIAMENT
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DYNAMIC MECHANICAL BEHAVIOUR OF GFRP COMPOSITES WITH SiO2 NANO PARTICLES REINFORCED EPOXY MATRIX
PublicationDynamic mechanic (DMA) tests were performed to compare the mechanical behaviour of glass fibre reinforced epoxy laminate composites with SiO2 nanoparticle reinforced matrix. The selection of the most promising nanoparticle concentrations was considered in terms of elastic modulus and glass transition temperature. The reference specimens (0% nanoparticles) did not contain diluent accordingly the results do not allow the exact comparison...
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Three-Dimensional Printing of Bone Models
PublicationThe trabecular bone occurs, for example, in the femoral heads. Understanding the phenomenon of bone tissue degeneration can be the basis for the possibility of looking for alternative methods of surgical treatment of bone loss. The paper presents the results of the trabecular bone model, which was produced in additive manufacturing method with fused filament fabrication technology. The verification of the mechanical behavior of...
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Low-coherence sensors with nanolayers for biomedical sensing
PublicationIn this paper, we describe the fiber optic low-coherence sensors using thin film. We investigated their metrological parameters. Presented sensors were made with the use of standard telecommunication single mode optical fiber (SMF28). Different materials were applied to obtain thick layers, such as boron doped diamond, silver and gold. The thickness of layers used in the experiments ranged from 100 nm to 300 nm. Measurements were...
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Analiza lepko sprężysta wirnika promieniowego
PublicationAnalizie poddano wirnik wentylatora promieniowego z typoszeregu 405/315. Wentylator zaprojektowany jest w sposób poprawny; zgodny ze sztuką rzemieślniczą. W procesie projektowania posłużono się narzędziami inżynierskimi jak i analizą CSD. Wymagania Normowe do których należalo sie odnieść nie przewidują obciążeń od przejścia fali uderzeniowej. Wirnik wentylatora spełnia wymagania dla klasy F400, tzn. w czasie 120 min. pracy w temperaturze...
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Optymalizacja transformacji wyników pomiarów bloków kadłuba statku z uwzględnieniem ograniczeń
PublicationArtykuł przedstawia algorytm optymalizujący transformację wyników pomiarów bloków i sekcji kadłuba statku z uwzględnieniem ograniczeń. Optymalizacji podlega suma odległości pomiędzy mierzonymi punktami, a korespondującymi punktami w modelu CAD, uwzględniając jedno z dwóch możliwych ograniczeń: wspólna płaszczyzna, albo wspólna oś. Transformacja wyników pomiarów wykonywana jest wcelu przeprowadzenia porównania faktycznych wymiarów...
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Studies on treatment of bitumen effluents by means of Advanced Oxidation Processes (AOPs) in basic pH conditions
PublicationThe paper presents the results of studies on chemical treatment of effluents from production of bitumen of petroleum origin. Due to the presence of sulfide ions, the pH of these effluents is strongly alkaline. Several Advanced Oxidation Processes (AOPs) were studied, including the use of hydroxyl and sulfate radicals oxidants, the hydrodynamic cavitation as well as sonocavitation. The best processes allow to obtain 45% reduction...
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Studies on Treatment of Bitumen Effluents by Means of Advanced Oxidation Processes (AOPs) in Basic pH Conditions
PublicationThe paper presents the results of studies on chemical treatment of effluents from production of bitumen of petroleum origin. Due to the presence of sulfide ions, the pH of these effluents is strongly alkaline. Several Advanced Oxidation Processes (AOPs) were studied, including the use of hydroxyl and sulfate radicals oxidants, the hydrodynamic cavitation as well as sonocavitation. The best processes allow to obtain 45% reduction...
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Di-{bis(tri-tert-butoxysilanethiolato-S)(dimethylformamide-O)cadmium(II)}-μ-trans-1,2-di-4-pyridylethene-κ2N:N'
PublicationW przypadku tytułowego związku di-{bis(tri-tert-butoksysilanotiolano-S)(dimetylformamid-O)kadm(II)}-μ-trans-1,2-di-4-pirydyloeten [Cd(C12H27O3SSi)4(C3H7NO)2(C12H10N2)], centralny atom kadmu jest skoordynowany z czterema atomami donorowymi, tworząc rdzeń typu CdNOS2. Jest to pierwszy kompleks Cd(II) o tego typu centrum i ze względu na obecność dwóch reszt tiolanowych, N- i O-donora może on służyć za model centrum katalitycznego...
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Badania spektroskopowe wybranych silanotiolanów metali o budowie polimerycznej
PublicationPodjęto próby otrzymania tri-tert-butoksysilanotiolanowych kompleksów niklu(II), kobaltu(II), cynku(II) i kadmu(II) o budowie polimerycznej mogących pełnić rolę prekursorów w syntezie materiałów funkcjonalnych. W tym celu przeprowadzono syntezy odpowiednich silanotiolanowych metali z grupą diamin alifatycznych. Otrzymano szereg nowych obojętnych polimerów koordynacyjnych o budowie przestrzennej typu 1D. Dla siedmiu z nich zostały...
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INFOGEST inter-laboratory recommendations for assaying gastric and pancreatic lipases activities prior to in vitro digestion studies
PublicationIn vitro digestion studies often use animal digestive enzyme extracts as substitutes of human gastric and pancreatic secretions. Pancreatin from porcine origin is thus commonly used to provide relevant pancreatic enzymes such as proteases, amylase and lipase. Rabbit gastric extracts (RGE) have been recently introduced to provide gastric lipase in addition to pepsin. Before preparing simulated gastric and pancreatic extracts with...
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Particle Swarm Optimization Based Optimal Design of Six-Phase Induction Motor for Electric Propulsion of Submarines
PublicationRecent research reveals that multi-phase motors in electric propulsion systems are highly recommended due to their improved reliability and efficiency over traditional three phase motors. This research presented a comparison of optimal model design of a six phase squirrel cage induction motor (IM) for electric propulsion by using Genetic Algorithm (GA) and Particle Swarm Optimization (PSO). A six phase squirrel cage induction...
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Path integrals formulations leading to propagator evaluation for coupled linear physics in large geometric models
PublicationReformulating linear physics using second kind Fredholm equations is very standard practice. One of the straightforward consequences is that the resulting integrals can be expanded (when the Neumann expansion converges) and probabilized, leading to path statistics and Monte Carlo estimations. An essential feature of these algorithms is that they also allow to estimate propagators for all types of sources, including initial conditions....
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On design and analysis of flow characteristics of the last stage of gas-steam turbine
PublicationResearch regarding blade design and analysis of flow have been conducted for over a century. Meanwhile new concepts and design approaches were created and improved. Advancements in information technologies allowed to introduce computational fluid dynamics (CFD) and computational flow mechanics (CFM). Currently a combination of mentioned methods is used for design of turbine blades. These methods enabled us to improve flow efficiency...
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Particle Swarm Optimization Based Optimal Design of Six-Phase Induction Motor for Electric Propulsion of Submarines
PublicationAbstract: Recent research reveals that multi-phase motors in electric propulsion systems are highly recommended due to their improved reliability and efficiency over traditional three phase motors. This research presented a comparison of optimal model design of a six phase squirrel cage induction motor (IM) for electric propulsion by using Genetic Algorithm (GA) and Particle Swarm Optimization (PSO). A six phase squirrel cage induction...
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Comparative study on total nitrogen prediction in wastewater treatment 1 plant and effect of various feature selection methods on machine learning algorithms performance
PublicationWastewater characteristics prediction in wastewater treatment plants (WWTPs) is valuable and can reduce the number of sampling, energy, and cost. Feature Selection (FS) methods are used in the pre-processing section for enhancing the model performance. This study aims to evaluate the effect of seven different FS methods (filter, wrapper, and embedded methods) on enhancing the prediction accuracy for total nitrogen (TN) in the WWTP...
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Treatment of landfill leachate by constructed wetlands: three case studies
PublicationThe performance of three CW systems treating landfill leachate, two located in northern Poland (Szadółki near Gdańsk and Gatka near Miastko) and one in southern Sweden (Örebro), is discussed. The CWs differ in size, hydraulic regime, type of hydrophytic plants and type of leachate pre-treatment before discharging to the CW. The CW in Szadółki consists of two parallel beds with sub-surface, horizontal flow of leachate (HSSF) planted...
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Molecular geometry and optical activity of helically chiral N-nitrosamines derived from 1,2,3,4-tetrahydro- and 1,2,3,4,7,8,9,10-octahydro-1,10-phenanthroline
PublicationX-ray crystallographic analysis of the title N-nitrosamines revealed that they assume helical conformations in the solid state. Nitrosamines 1b and 2b were resolved by inclusion crystallization with optically active diols (TADDOLs). The absolute configuration of the guest molecules in the complexes 1b·3b and 2b·3b was assigned as M. The optical activity of the resolved compounds is manifested by their solid state CD spectra, which...
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Próba oceny efektów projektowania układów geometrycznych toru z wykorzystaniem komercyjnych programów komputerowych
PublicationW pracy podjęto kwestię dokładności uzyskiwanej w projektowaniu układów geometrycznych toru z wykorzystaniem komercyjnych programów komputerowych typu CAD. Opisano w sposób ogólny funkcjonowanie wybranego programu. Do celów weryfikacji wykorzystano własną, analityczną metodę projektowania układów torowych. W analizie porównawczej rzędnych poziomych rozpatrzono trzy warianty układu geometrycznego zawierającego łuk koszowy z trzema...
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Badanie modułu odkształcenia podłoża gruntowego w nasypie kontrolowanym za pomocą płyty statycznej i lekkiej płyty dynamicznej
PublicationW praktyce inżynierskiej, zarówno projektowej, jak i wykonawczej, niewątpliwie przydatne są korelacje między parametrami geotechnicznymi. Artykuł przedstawia polowe badania porównawcze lekką płytą dynamiczną (LFWD) oraz płytą statyczną (VSS), wraz określeniem zależności korelacyjnych pomiędzy modułem odkształcenia podłoża wyznaczonym za pomocą lekkiej płyty dynamicznej EVd oraz pierwotnym i wtórnym modułem odkształcenia EV1, EV2....
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GENERALISED HERSCHEL MODEL APPLIED TO BLOOD FLOW MODELLING
PublicationThis paper introduces a new rheological model of blood as a certain generalisation of the standard Herschel-Bulkley model. This model is a rheological constitutive equation and belongs to the group of the so-called generalised Newtonian fluids. Experimental data is compared with results, obtained from the new model, to demonstrate that it allows for the best agreement together with Luo-Kuang model. The new model may be easily implemented...
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Pomiary i analiza dźwięku w filmie oraz w reklamach filmowych z wykorzystaniem modelu głośności LKFS .
PublicationCelem niniejszej pracy był pomiar dźwięku filmie, zapowiedziach filmów oraz reklamach poprzedzających projekcję filmu. W referacie w pierwszej kolejności przywołano problemy związane z pomiarem dźwięku, rekomendacje, które wskazują na dopuszczalne poziomy projekcji filmowej oraz przywołano jednostki, które są wykorzystywane w określaniu głośności projekcji. Następnie przedstawiono pomiary, kalibrację sprzętu pomiarowego oraz analizę...
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3D Printing of Metallic Implants
PublicationThe fabrication of various elements, solid and open porous structures of stainless steel and Ti alloy is described. The process was started with the design of 3D models in CAD/CAM system. The 3D models were transformed into *.stl files and then the manufacturing process of the real structures by means of the selective laser melting with the SLM Realizer 100 3D printer was made. The paper shows the porous specimens made for possible...
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Efficiency of pollutant removal by five multistage constructed wetlands in a temperate climate
PublicationIn recent years, an increase in interest in hybrid constructed wetland systems (HCWs) has beenobserved. These systems are composed of two or more filters with different modes of sewage flow.Based on over eight years of monitoring, carried out at five local HCWs located in the PomeraniaRegion of Northern Poland, the effective removal of organic matter (from 74.9 to 95.5% COD) in theloading range 1.5-17.0 g COD·m-2·d-1 was confirmed....
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Effect of Flow Normalization in Micro-Pin-Finned Heat Sink: Numerical Study
PublicationThe micro-pin-fin heat sink (MPFHS) is widely employed for the heat transfer enhancement of microchannel heat sinks. In the current paper, the effect of flow normalization on the thermohydraulic performance of micro-pin-finned heat sinks is studied numerically. Two geometries of MPFHSs, the conventional design micro-pin-fin heat sink (CD-MPFHS) with a uniform-width micro pin fin and the proposed design micro-pin-fin heat sink (PD-MPFHS)...
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Morphology and local chain structure of polyamide 6 modified in the solid state with a semi-aromatic nylon salt
PublicationStructural and conformational differences between the polyamide 6 (PA6) homopolymer and two copolymers of PA6 modified in the solid state with 20 and 30 wt% of the semi-aromatic nylon salt of 1,5-diamino-2-methylpentane (Dytek A) and isophthalic acid (IPA) in the feed were investigated. Room temperature wide-angle X-ray diffraction (WAXD) analysis together with 13C{1H} cross-polarization/magic-angle spinning solid-state (CP/MAS)...
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Tensile failure study of 3D printed PLA using DIC technique and FEM analysis
PublicationThe paper presents the experimental and numerical study of the failure behaviour of Fused Filament Fabricated (FFF) Polylactic Acid (PLA) samples subjected to tensile load. The examined samples are printed in flat orientation with 0◦, 45◦ and 90◦ raster angles. During the experiments the deformation of the specimens is continuously scanned with the 3D Aramis measuring system utilizing the digital imaging correlation technique,...
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Method of Monitoring of the Grinding Process with Lapping Kinematics Using Audible Sound Analysis
PublicationUtilising microphones as audible sound sensors for monitoring a single-side grinding process with lapping kinematics is presented in the paper. The audible sound generated during grinding depended on the cutting properties of electroplated tools with D107 diamond grains and different thicknesses of the nickel bond. The tool wear affected the obtained technological effects such as material removal rate and the surface roughness...
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Emission Profiles of Volatiles during 3D Printing with ABS, ASA, Nylon, and PETG Polymer Filaments
PublicationIn this short communication we characterize the emission of volatile organic compounds (VOCs) from fused filament fabrication (FFF) 3D printing using four polymer materials, namely polyethylene terephthalate glycol-modified (PETG), acrylonitrile styrene acrylate (ASA), Nylon, and acrylonitrile butadiene styrene (ABS). Detailed emission profiles are obtained during thermal degradation of the polymers as a function of temperature...
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Peptide dendrimers as antifungal agents and carriers for potential antifungal agent—N3‐(4‐methoxyfumaroyl)‐(S)‐2,3‐ diaminopropanoic acid—synthesis and antimicrobial activity
PublicationA series of peptide dendrimers and their conjugates with antimicrobial agent FMDP (N3‐(4‐methoxyfumaroyl)‐(S)‐2,3‐diamino‐propanoic acid) were synthesized. The obtained compounds were tested for the antibacterial and antifungal activity. All novel dendrimers displayed much better activity against the tested strains than FMDP itself. Moreover, their conjugates with FMDP also exhibited antimicrobial activity. The most promising molecules...
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Singlet Exciton Diffusion in Vacuum-Evaporated Films of Amine-Based Materials as Studied by Photocurrent and Photoluminescence Quenching Methods
PublicationThe singlet exciton diffusion lengths are determined by the photoconductivity as well as the luminescence surface quenching technique, in vacuum‐evaporated layers of (4,4′,4″‐tris(N‐(3‐methylphenyl)‐N‐phenylylamino) triphenylamine) (m‐MTDATA), 4,4′,4″‐tris[2‐naphthyl(phenyl)amino] triphenylamine (2TNATA), and N,N′‐diphenyl‐N,N′‐bis(3‐methylphenyl)‐[1,1′‐biphenyl]‐4,4′‐diamine (TPD) which are frequently used for fabrication of electroluminescent...
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Regional resting state perfusion variability and delayed cerebrovascular uniform reactivity in subjects with chronic carotid artery stenosis
PublicationThe aim of this study was to assess regional perfusion at baseline and regional cerebrovascular resistance (CVR) to delayed acetazolamide challenge in subjects with chronic carotid artery stenosis.Sixteen patients (ten males) aged 70.94±7.71 with carotid artery stenosis ≥90% on the ipsilateral side and ≤50% on the contralateral side were enrolled into the study. In all patients, two computed tomography perfusion examinations were...
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High prevalence of Escherichia coli belonging to the B2+D phylogenetic group in inflammatory bowel disease
PublicationBACKGROUND: It is not clear which species of bacteria may be involved in inflammatory bowel disease (IBD). One way of determining which bacteria might be likely candidates is to use culture-independent methods to identify microorganisms that are present in diseased tissues but not in controls. AIMS: (1) To assess the diversity of microbial communities of biopsy tissue using culture-independent methods; (2) to culture the bacteria...
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Prospects of Decreasing Power Losses in a Hydrostatic Thrust Bearing
PublicationIn numerous machines, axial load is carried by tilting pad thrust bearings known since the beginning of 20th century. These bearings are commonly bath lubricated, which is simple, does not require any additional pumps, and, due to this, such systems are highly reliable. In a contemporary technology, however, minimization of friction losses became an important goal of machinery improvement. Calculations based on elementary rules...
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Shape Optimisation of Kaplan Turbine Blades Using Genetic Algorithms
PublicationThis monograph is a comprehensive guide to a method of blade profile optimisation for Kaplan-type turbines. This method is based on modelling the interaction between rotor and stator blades. Additionally, the shape of the draft tube is investigated. The influence of the periodic boundary condition vs. full geometry is also discussed. Evolutionary algorithms (EA) are used as an optimisation method together with artificial neural...
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Predicting Value of Binding Constants of Organic Ligands to Beta-Cyclodextrin: Application of MARSplines and Descriptors Encoded in SMILES String
PublicationThe quantitative structure–activity relationship (QSPR) model was formulated to quantify values of the binding constant (lnK) of a series of ligands to beta–cyclodextrin (β-CD). For this purpose, the multivariate adaptive regression splines (MARSplines) methodology was adopted with molecular descriptors derived from the simplified molecular input line entry specification (SMILES) strings. This approach allows discovery of regression...
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Recent Advancements in Cyclodextrin-Based Adsorbents for the Removal of Hazardous Pollutants from Waters
PublicationWater is an essential substance for the survival on Earth of all living organisms. However, population growth has disturbed the natural phenomenon of living, due to industrial growth to meet ever expanding demands, and, hence, an exponential increase in environmental pollution has been reported in the last few decades. Moreover, water pollution has drawn major attention for its adverse effects on human health and the ecosystem....
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Methods of Assessment of Metal Contamination in Bottom Sediments (Case Study: Straszyn Lake, Poland)
PublicationThe concentrations of six metals (Zn, Cu, Pb, Ni, Cr, and Cd) were investigated in bottom sediments of Straszyn Lake (North Poland). This study was designed to determine a total content of metals and to assess their mobility and bioavailability. The sequential extraction was used to fractionate metals into five fractions: exchangeable, bound to carbonates, bound to Fe–Mn oxides, bound to organic matter, and residual. The evaluation...
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Enhanced cellulose extraction from agave plant (Agave americana Species) for synthesis of magnetic/cellulose nanocomposite for defluoridation of water
PublicationResearch on fluoride removal from water is currently focusing on the development of innovative materials for defluoridation water. The current study extracted and used enhanced cellulose from Agave americana species to synthesize a magnetic/cellulose nanocomposite for water defluoridation. Strong and light binary acids (H2SO4 and CH3COOH) were utilized to pretreat raw material to enhance cellulose extraction. Central composite...
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A pilot study to assess an in-process inspection method for small diameter holes produced by Direct Metal Laser Sintering
PublicationPurpose The purpose of this research is to evaluate the geometric quality of small diameter holes in parts printed by DMLS technology. An in-process optical inspection method is proposed and assessed during a pilot study. The influence of the theoretical hole diameter assumed in a CAD system and the sample thickness (hole length) on the hole clearance was analysed. Design/methodology/approach The samples made of two different...
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COOPERATION BETWEEN UNIVERSITY AND EXTERNAL COMPANY IN ARCHITECTURAL INVENTORY USING INNOVATIVE MEASURING TECHNOLOGY
PublicationArchitectural inventories are the main field for using innovative technology ( remote sensing). The main purpose of using ie. Laser scanning or photogrammetry is to capture all of the important details of structure. Regarding the extents of inventory works, it may only apply to external details, such as facades, supporting structures and surroundings, whilst in terms of advanced inventory, the building's interior is also expected...
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Influence of beta-cyclodextrin on coupling reactions of o-nitrobenzenediazonium salt with pyrrole
PublicationW artykule opisano syntezę azobenzopochodnych pirolu oraz wpływ beta-cyklodekstryn (beta-CD) na te reakcje. W bezpośredniej reakcji prowadzonej bez udziału cyklodekstryny, otrzymano przede wszystkim związek będący monopodstawioną azopochodną pirolu. Przy użyciu większych ilości beta cyklodekstryny w reakcji, tzn. 1 i 2 milimole przypadające na 1 milimol pirolu, otrzymano, oprócz niewielkich ilości innych związków, przede wszystkim...
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Structural Variety of Cobalt(II), Nickel(II), Zinc(II), and Cadmium(II) Complexes with 4,4′-Azopyridine: Synthesis, Structure and Luminescence Properties
PublicationSelf-assembled bi- and polymetallic complexes of CoII, NiII, ZnII, and CdII were obtained by the reaction of 4,4′-azopyridine (azpy) with metal tri-tert-butoxysilanethiolates (Co, 1; Cd, 2), acetylacetonates (Ni, 3; Zn, 4), and acetates (Cd, 5). All compounds were characterized by single-crystal X-ray structure analysis, elemental analysis, FTIR spectroscopy, and thermogravimetry. Complexes 1, 2 and 4, 5 exhibit diverse structural...
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Chitin nanowhiskers from shrimp shell waste as green filler in acrylonitrile-butadiene rubber: Processing and performance properties
PublicationIn this work, chitin nanowhiskers with high crystallinity index were obtained from shrimp shells waste using acid hydrolysis method and then comprehensively characterized. Subsequently, the impact of chitin nanowhisker content on processing and performance of acrylonitrile-butadiene rubber based nanocomposites was evaluated. The results showed that the addition of chitin nanowhiskers increased tensile strength and tear strength...
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Heat Transfer During Pool Boiling of Water, Methanol and R141b on Porous Coated Horizontal Tube Bundles
PublicationThis paper presents the results of experimental investigation of water, methanol and R141b refrigerant boiling on horizontal porous coated tube bundles supposed to represent a flooded-type evaporator. Experiments were carried out for a bundle of 19 tubes in triangular layout for two pitch-to-diameter ratio values – 1.7 and 2.0 – in atmospheric and sub-atmospheric pressure conditions. Average heat transfer coefficients – both local,...
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ANALIZA CECH HYDRO-AERODYNAMICZNYCH BEZZAŁOGOWEGO POJAZDU NAWODNO-POWIETRZNEGO Z WYKORZYSTANIEM EFEKTU PRZYPOWIERZCHNIOWEGO
PublicationW artykule przedstawiono problematykę badań dotyczących opracowania demonstratora technologii bezzałogowego pojazdu nawodno-powietrznego z wykorzystaniem efektu przypowierzchniowego. Opisano podstawowe problemy badawcze związane z analizą cech hydro-aerodynamicznych pojazdu. Opisano przedmiot badań, bezzałogowy pojazd nawodno-powietrzny typu USV-UAV-WIG. Opisano metodę badań. Przeprowadzono wstępną analizę osiągów i zachowania...
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Flow Analysis of a Kaplan Turbine
PublicationThis monograph is a guide to a method of experimental and numerical flow investigations for Kaplan - type turbines. The numerical calculations were compared with the test results of the model Kaplan turbine. The tests were carried out on the model test rig in the Gdańsk University of Technology. The turbine has been thoroughly experimentally investigated, resulting in the identification of optimum setting combination of the stator...
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Prosthetic Elements Made of the Ti-13Zr-13Nb Alloy by Selective Laser Melting
PublicationThe fabrication of the prosthetic foundations and bridges from the Ti-13Zr-13Nb alloy is described. The process was started from CAD/CAM design of 3D models of the foundations based on scanning of patient`s mouth. Next, 3D models were transformed into *.stl files for the manufacturing stage and then the manufacturing process by means of the selective laser melting with the SLM Realizer 100 equipment was made. The intrinsic structure...
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Synteza, badania strukturalne i spektroskopowe kompleksów cynku i kadmu z ligandem tris(2,6-diizopropylofenoksy)silanotiolanowym
PublicationW pracy doktorskiej przedstawiono nowy związek krzemo-siarkowy tris(2,6-diizopropylofenoksy)silanotiolanowy (TDST) zastosowany do syntezy modelowych kompleksów cynku i kadmu, które modelują bezpośrednio środowisko jonu metalu w β anhydrazie węglanowej oraz dehydrogenazie alkoholowej. Zastosowanie związku krzemo-siarkowego tris(2,6-diizopropylofenoksy)silanotiolanowy (TDST) jako liganda do syntezy modelowych kompleksów cynku i kadmu...
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The CON−H…+NH2 Blue-Shifting H-Bond Stabilizing Effect on Z Secondary Amides and Cyclic System Conformational Rearrangement through an Alkylamine-Chain Migration Pathway
PublicationThe paper is focusing on the amide linkage exceptional properties and usage of chemistry (conformational rearrangement, geometrical stereoisomers, spectroscopic blue shift phenomenon, protonation and deprotonation reactions, synthetic scope, and mechanistic implications). Hydrogen-bond-stabilized acylation reactions of a diamine with thioamides or nitriles reveal how substituents influence both the outcome of stereoselectivity...
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Design, synthesis and biological evaluation of novel N-phosphorylated and O-phosphorylated tacrine derivatives as potential drugs against Alzheimer’s disease
PublicationIn this work, we designed, synthesised and biologically investigated a novel series of 14N- and O-phosphorylated tacrine derivatives as potential anti-Alzheimer’s disease agents. In the reaction of 9-chlorotacrine and corresponding diamines/aminoalkylalcohol we obtained diamino and aminoalkylhydroxy tacrine derivatives. Next, the compounds were acid to give final products 6–13 and 16–21 that were characterised by 1H, 13 C, 31P...