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Search results for: hard coatings
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Radionuclides activity and effective doses referred to geological formations
PublicationNaturally occurring radioactive materials (NORM) are present in Earth’s crust and they caused natural background radiation, variable in different regions. Liquid, gas and solid radionuclides emit three types of radiation – alpha, beta and gamma. Fluctuations of natural radioactivity in different geological formations in the world and in Poland were compared in relation to radiological hazard. Also drilling cuttings from boreholes...
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Preparation and characterisation of iron substituted Mn1.7Cu1.3-xFexO4 spinel oxides (x = 0, 0.1, 0.3, 0.5)
PublicationSpinel oxides with the general formula Mn1.7Cu1.3-xFexO4 (x= 0, 0.1, 0.3, 0.5) were prepared and evaluated in this work for their properties at high temperatures. The effect of partially substituting Cu by Fe has not been studied so far for this group of materials and is thus evaluated in this work. Mn1.7Cu1.3-xFexO4 powders were synthesised by a soft chemistry process and studied in terms of crystallographic phase analysis, electrical...
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Transparent thin films of Cu-TiO2 with visible light photocatalytic acitivity
PublicationThin films of Cu–TiO2 with a high level of transparency were prepared by a dip-coating procedure on the glass surface. CuCl2 was used as a copper precursor added during sol – gel synthesis of TiO2. The extension of optical absorption into the visible region of as-prepared thin films was indicated by UV/Vis spectroscopy. Only the anatase phase was detected by X-ray di ffraction analysis (XRD). The presence of copper in the structure...
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Analysis of the regenerative braking process for the urban traffic conditions
PublicationIn a regular drive system, with an internal combustion engine, vehicle braking is connected with the unproductive dissipation of kinetic and potential energy accumulated in the mass of the vehicle into the environment. This energy can constitute up to 70% of the energy used to drive a vehicle under urban conditions. Its recovery and reuse is one of the basic advantages of hybrid and electric vehicles. Modern traffic management...
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Design Equation for Stirring Fluid by a Stream Pump in a Circulating Tank
PublicationA circulating tank is a very useful theoretical scheme for many fluid-flow objects in several branches of engineering. The motion of the fluid in such objects can be induced in different ways. A stream pump provides an especially interesting possibility; however, the quantitative description of such devices shows some shortcomings. Such a device is analogous to a jet pump, thus has similar advantages (simplicity of construction,...
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Retrosynthesis from transforms to predictive sustainable chemistry and nanotechnology: a brief tutorial review
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Synthesis and Physicochemical Characteristics of Chitosan-Based Polyurethane Flexible Foams
PublicationThe use of shrimp waste to obtain chitosan (Ch) is an essential issue, considering a circular economy, waste management, and its application to environmentally friendly materials. In this study, northern prawn shells were utilized to obtain Ch, which could then be used for synthesizing chitosan-based polyurethane (PUR+Ch) foams with different Ch concentration. The chemical structure, morphology, hardness, thermal properties, viscoelastic...
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Different types of solvability conditions for differential operators
PublicationSolvability conditions for linear differential equations are usually formulated in terms of orthogonality of the right-hand side to solutions of the homogeneous adjoint equation. However, if the corresponding operator does not satisfy the Fredholm property such solvability conditions may be not applicable. For this case, we obtain another type of solvability conditions, for ordinary differential equations on the real axis, and...
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HSDPA - szybka transmisja danych w systemie UMTS
PublicationW artykule przedstawiono architekture nowej metody dostepu pakietowego HSDPA w systemie UMTS wraz z jej analiza funkcjonalna. Scharakteryzowano mechanizmy warstwy fizycznej realizujace adaptacje parametrów transmisji do stanu łacza radiokomunikacyjnego poprzezwybór odpowiedniej wartosciowosci modulacji (AMC), szybki protokół retransmisyjny (HARQ) oraz zaplanowanie ruchu pakietowego.
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Segmentation-Based BI-RADS ensemble classification of breast tumours in ultrasound images
PublicationBackground: The development of computer-aided diagnosis systems in breast cancer imaging is exponential. Since 2016, 81 papers have described the automated segmentation of breast lesions in ultrasound images using arti- ficial intelligence. However, only two papers have dealt with complex BI-RADS classifications. Purpose: This study addresses the automatic classification of breast lesions into binary classes (benign vs. ma- lignant)...
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Effect of high loading of titanium dioxide particles on the morphology and selected properties of natural rubber-based composites
PublicationThe aim of this work was to prepare and characterize the natural rubber vulcanizates contained different amounts of titanium dioxide particles. At first rubber mixture was prepared using a laboratory two-roll mill and then samples were vulcanized in a hydraulic press. The formulation of rubber mixture and rubber-processing technique is based on our earlier investigations. Materials were obtained at the different titanium dioxide...
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Od zrównoważonego rozwoju do dewzrostu - paradygmaty krytyczne wobec wzrostu i ich implikacje dla planowania przestrzennego
PublicationPomimo ponad trzech dekad wdrażania koncepcji zrównoważonego rozwoju środowisko Ziemi ulega dalszej degradacji i destabilizacji. Sytuacja ta przekłada się na ożywienie antycypowanej już w latach 70. XX w. krytyki założeń leżących u podstaw koncepcji zrównoważonego rozwoju – spośród których kluczowe wydaje się założenie możliwości rozłączenia (decoupling) wzrostu gospodarczego i negatywnego oddziaływania na środowisko. W niniejszym...
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Waterborne polyesters partially based on renewable resources
PublicationA new experimental approach for preparing biobased, water-soluble polyesters via titanium(IV) n-butoxide-catalyzed bulk polycondensation is presented. In the described method polymers were obtained from isosorbide, maleic anhydride and poly(ethylene glycol). The chemical structure of the synthesized polyesters was confirmed using 2D NMR spectroscopy and by titration methods. Careful analysis of 2D NMR spectra viz. Correlation Spectra...
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New trifunctional acrylic water-based paint with self-cleaning, biocidal and magnetic properties
PublicationIn the present study, we report the synthesis and application of ZnFe2O4/SiO2-TiO2 nanocomposites with nonstoichiometric content of Fe to Zn used for the first time for the preparation of new generation trifunctional paints with self-cleaning, biocidal and magnetic properties. Currently, there are no compositions on the market for obtaining protective coatings in the form of paint, which simultaneously exhibit biocidal, magnetic...
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Synthesis and Characterization of Poly(zwitterionic) Structures for Energy Conversion and Storage
PublicationZwitterions are unique class of molecules that possess two functional groups bearing electric charges, one positive and second negative. This setup results in peculiar properties such as high water retention and anti-fouling capability. Therefore, zwitterionic coatings and gels are commonly applied in e.g. biosensing and bioelectronic devices. Despite those applications, there are other perspectives for zwitterionic materials....
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Clays as Inhibitors of Polyurethane Foams’ Flammability
PublicationPolyurethanes are a very important group of polymers with an extensive range of applications in different branches of industry. In the form of foams, they are mainly used in bedding, furniture, building, construction, and automotive sectors. Due to human safety reasons, these applications require an appropriate level of flame retardance, often required by various law regulations. Nevertheless, without the proper modifications,...
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Solid phase microextraction: state of the art, opportunities and applications
PublicationSolid phase microextraction is one of the most popular green techniques used for sample preparations in analytical chemistry. It is a simple, rapid, sensitive, and solvent-free technique. Since SPME was first introduced in the early 1990s, there has been an intensification of research in order to elaborate new methodical solutions in many research facilities around the world, which could increase the use of this technique. More...
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Growth and Isolation of Large Area Boron‐Doped Nanocrystalline Diamond Sheets: A Route toward Diamond‐on‐Graphene Heterojunction
PublicationMany material device applications would benefit from thin diamond coatings, but current growth techniques, such as chemical vapor deposition (CVD) or atomic layer deposition require high substrate and gas‐phase temperatures that would destroy the device being coated. The development of freestanding, thin boron‐doped diamond nanosheets grown on tantalum foil substrates via microwave plasma‐assisted CVD is reported. These diamond...
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Gesture recognition framework for multimedia content viewer controlling
PublicationIn the paper a system for controlling a multimedia content viewer by hand gestures is presented. First, selected methods used for gesture recognition are described. Two different application cases of the system, i.e. for multimedia presentation purposes and for multimedia content viewing are outlined. Moreover, a proposal of improvement of the system combining these approaches is also given. The system work cycle is reviewed. The...
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Efficiency of pollutant removal by five multistage constructed wetlands in a temperate climate
PublicationIn recent years, an increase in interest in hybrid constructed wetland systems (HCWs) has beenobserved. These systems are composed of two or more filters with different modes of sewage flow.Based on over eight years of monitoring, carried out at five local HCWs located in the PomeraniaRegion of Northern Poland, the effective removal of organic matter (from 74.9 to 95.5% COD) in theloading range 1.5-17.0 g COD·m-2·d-1 was confirmed....
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Fuzzy soft modeling of environmental data. A study of the impact of a Phosphatic Fertilizer Plant on the adjacent environment in Gdańsk
PublicationAnaliza podobieństwa obejmuje nie tylko zastosowanie logiki rozmytej, ale również wiele innych podejść matematycznych. Opracowano wiele algorytmów, których celem jest wyodrębnienie wyraźnych skupień (hard clusters) z danego zbioru danych. Prawdopodobnie najczęściej stosowanymi algorytmami są tzw. algorytmy c-średnie (c-means algorithms). Twarde c-średnie (hard c-means) służy do ostrej klasyfikacji, podczas której obiekt jest przypisany...
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Heat Transfer of the Multicolor-Laser-Sources-Irradiated Nanoparticles in Reference to Thermal Processes
PublicationUnlike the standard materials, metallic nanoparticles offer enhancing the heat convertion rate which implies the maximum and average temperature boost significantly in the considered system. The work’s purpose is to examine heat transfer in the metallic nanoparticles which have been deposited on a glassy substrate, enabling the nanostructures thermoablation. Furthermore, the functionalized substrate is irradiated with multicolor-laser-sources,...
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Down-Sampling of Large LiDAR Dataset in the Context of Off-Road Objects Extraction
PublicationNowadays, LiDAR (Light Detection and Ranging) is used in many fields, such as transportation. Thanks to the recent technological improvements, the current generation of LiDAR mapping instruments available on the market allows to acquire up to millions of three-dimensional (3D) points per second. On the one hand, such improvements allowed the development of LiDAR-based systems with increased productivity, enabling the quick acquisition...
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Knowledge management and knowledge security—Building an integrated framework in the light of COVID‐19
PublicationAbstract. This paper presents a framework of knowledge risk management in the face of the COVID-19 crisis, derived from the literature on knowledge management, knowledge security and COVID-19. So far, both researchers and practitioners have focused on knowledge as an asset and their efforts have been aimed at the implementation of knowledge management in various organizational contexts. However, with increasing threats related...
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Is There any Demand for the Workers Aged 50+ in Poland?
PublicationThe process of ageing affects all the European Union Member States, including Poland. According to forecasts by the Central Statistical Office, in 2035, the population of Poland will decrease in relation to 2010 by more than 2 million, and the share of people aged 50+ in the total population will increase from 34.8% to 46.6% (Prognoza ludności 2009). In the context of current and projected demographic changes, a discussion is taking...
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The passive operating mode of the linear optical gesture sensor
PublicationThe study evaluates the influence of natural light conditions on the effectiveness of the linear optical gesture sensor, working in the presence of ambient light only (passive mode). The orientations of the device in reference to the light source were modified in order to verify the sensitivity of the sensor. A criterion for the differentiation between two states - "possible gesture" and "no gesture" - was proposed. Additionally,...
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Multi-Agent Signal Filtering for Electrical Energy Demand Management
PublicationConsumers participating in electrical energy Demand Response (DR) programs may be exposed to energy-use related decisions at instants of time which are generally hard to predict. This is especially cumbersome to residential consumers who are less capable of investing in special equipment, or devoting significant time to analyze information and take decisions. To ease residential consumer participation, a multi-agent system proposed...
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Roughness evaluation of turned composite surfaces by analysis of the shape of Autocorrelation Function
PublicationIn this paper, the application of an Autocorrelation Function for the characterisation of surface topography was validated. The roughness evaluation of turned composite surfaces was supported by sophisticated studies of the Autocorrelation Function properties, considering especially the shape of the function. Details were measured with the optical method. The selection of the surface roughness evaluation procedures was carried...
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Bio-Based Polyurethane Composites and Hybrid Composites Containing a New Type of Bio-Polyol and Addition of Natural and Synthetic Fibers
PublicationThis article describes how new bio-based polyol during the liquefaction process can be obtained. Selected polyol was tested in the production of polyurethane resins. Moreover, this research describes the process of manufacturing polyurethane materials and the impact of two different types of fibers—synthetic and natural (glass and sisal fibers)—on the properties of composites. The best properties were achieved at a reaction temperature...
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Exploring Impact of Requirements Engineering on Other IT Project Areas – Case Study
PublicationRequirements Engineering (RE) is recognized as one of the most important (yet difficult) areas of software engineering that has a significant impact on other areas of IT projects and their final outcomes. Empirical studies investigating this impact are hard to conduct, mainly due to the great effort required. It is thus difficult for both researchers and industry practitioners to make evidence-based evaluations about how decisions...
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Pursuing Analytically the Influence of Hearing Aid Use on Auditory Perception in Various Acoustic Situations
PublicationThe paper presents the development of a method for assessing auditory perception and the effectiveness of applying hearing aids for hard-of-hearing people during short-term (up to 7 days) and longer-term (up to 3 months) use. The method consists of a survey based on the APHAB questionnaire. Additional criteria such as the degree of hearing loss, technological level of hearing aids used, as well as the user experience are taken...
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Softly Switched Robustly Feasible Model Predictive Control for Nonlinear Network Systems
PublicationIt is common that an efficient constrained plant operation under full range of disturbance inputs require meeting different sets of control objectives. This calls for application of model predictive controllers each of them being best fit into specific operating conditions. It further requires that not only designing robustly feasible model predictive controllers is needed to satisfy the real plant state/output constraints, but...
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Eqiuitable coloring of corona products of cubic graphs is harder than ordinary coloring
PublicationA graph is equitably k-colorable if its vertices can be partitioned into k independent sets in such a way that the number of vertices in any two sets differ by at most one. The smallest k for which such a coloring exists is known as the equitable chromatic number of G. In this paper the problem of determinig the equitable coloring number for coronas of cubic graphs is studied. Although the problem of ordinary coloring of coronas...
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Trigger-based Model to Assess the Readiness of IT Organizations to Agile Transformation
PublicationThe process of change the method of project management from waterfall to agile is called “agile transformation” (AT). The decision to agile transformation is undertaken based on many different factors. Many companies decide to abandon classic, waterfall methodology for agile without prior analysis. This approach makes the processes of agile transformation is hard to control and frequently the implementation of agile fails. The...
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Novel bio-based thermoplastic poly(ether-urethane)s. Correlations between the structure, processing and properties
PublicationThe main purpose of this work was to analyze the effect of the number of unreacted isocyanate groups and the [NCO]/[OH] molar ratio during the chain extension of a prepolymer during the polymerization process on the structure, processing and selected properties of thermoplastic poly(ether-urethane)s. Three series of novel thermoplastic polyurethanes were obtained via a prepolymer route. Three prepolymers were synthesized from diisocyanate...
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Threshold Attendance under Soft-Crash Model: TAG Protocol and Markovian Analysis
PublicationA realistic and systematic network evaluation should subsume an availability model and a failure model. We combine a "hard availability" model we call threshold attendance, whereby a certain minimum number of network elements must be present at any time, with a soft-crash failure model, whereby after experiencing a failure, a network element is still able to function correctly for a while in an emergency mode at a risk of a major...
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Fluorine ions in photocatalysts’ synthesis: an obstacle or an ally? The investigation of photocatalysts in Ti-O-F system
PublicationTitanium(IV) oxide (TiO2) is one of the most promising photocatalysts, which is expected to be applied in the photocatalytic degradation of xenobiotics. For sustainable development and green chemistry approach recently, much effort has been paid to enhance TiO2 photocatalytic activity in UV-vis light by modifying its structure. The photocatalytic process’s complexity cannot be simply described as electron-hole pairs generations...
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Effect of Thermal Shock During Legionella Bacteria Removal on the Corrosion Properties of Zinc-Coated Steel Pipes
PublicationThe purpose of this investigation was to conduct the failure analysis of a water-supply system made from zinc-coated steel. The observed corrosion process had an intense and complex character. The brownish deposits and perforations were present after 2-3 years of exploitation. The electrochemical study based on the Tafel polarization, corrosion potential monitoring, and electrochemical impedance spectroscopy together with microscopic...
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Społeczny wymiar adaptacji do zmian klimatu w środowisku miejskim na przykładzie Gdańska
PublicationKwestie zmian klimatycznych przestały być przedmiotem zainteresowania jedynie wąskich grup specjalistów, a stały się problemem społecznym angażującym szerszą opinię publiczną. Wobec wzrastającego znaczenia problemów środowiskowych w społeczeństwach, głównie na przełomie XX i XXI wieku, władze centralne we współpracy z samorządami miejskimi zaczęły podejmować działania na rzecz wsparcia tzw. środowiskowej (zielonej) polityki. Artykuł...
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Degradacja powłokowych systemów ochronnych w zmiennych temperaturach
PublicationPrzedstawiono wyniki badań wpływu cyklicznych sinusoidalnych zmian temperatury na powłokowe systemy ochronne o skrajnie różnych właściwościach antykorozyjnych. Porównano zachowanie nowej powłoki poliestrowej typu "coil-coating" na ocynkowanej stali i uprzednio eksponowanej w warunkach atmosferycznych alkidowej powłoki malarskiej na podłożu stalowym. Badania przeprowadzono przy zastosowaniu techniki spektroskopii impedancyjnej....
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CLEANING METHODS FOR DUST DEPOSITED ON THE FRONT COVER OF PHOTOVOLTAIC MODULE
PublicationPhotovoltaic modules are one of the renewable energy sources with great potential for application in various regions of the world as well as for different terrain. They are, however, sensitive to external factors, affecting the overall amount of energy generated, such as solar irradiance, shading effects and any form of soil build-up on the front glass cover of solar device. The latter issue happens over a course of weeks, months...
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Microscale diamond protection for a ZnO coated fiber optic sensor
PublicationFiber optic sensors are widely used in environmental, biological and chemical sensing. Due to the demanding environmental conditions in which they can be used, there is a risk of damaging the sensor measurement head placed in the measuring field. Sensors using nanolayers deposited upon the fiber structure are particularly vulnerable to damage. A thin film placed on the surface of the fiber end-face can be prone to mechanical damage...
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Recent Advances in Nanocomposite Membranes for Organic Compound Remediation from Potable Waters
PublicationWater treatment is one of the main approaches for producing drinking water from contaminated water sources which is challenging due to the presence of a variety of substances requiring removal. The fabrication of nanocomposite membranes relies either on filling nanomaterials into polymeric phases before membrane fabrication, or coating of nanomaterials on the fabricated membrane surface. The removal of organic compounds from potable...
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Diamond protection for reusable ZnO coated fiber-optic measurement head in optoelectrochemical investigation of bisphenol A
PublicationDue to the global problem with plastic contaminating the environment, with bisphenol A (BPA) being one of the highest demand, effective monitoring and purification of the pollutants are required. The electrochemical methods constitute a good solution but, due to polymerization of electrochemical oxidation bisphenol A products and their adsorption to the surfaces, measurement head elements are clogged by the formed film. In this...
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Study of nanomechanical properties of (1-y)BST-yMgO thin films
PublicationIn the present study thin films of MgO – modified Ba0.6Sr0.4TiO3 (BST60/40) solid solution were prepared by the sol-gel-type chemical solution deposition method on stainless steel substrates. A multilayer spin-coating approach was utilized for the Ba0.6Sr0.4TiO3-MgO thin film deposition with subsequent thermal annealing at T=650-750C. Dried BST60/40-MgO gel powders were studied with thermogravimetric and differential thermal analysis...
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EXAMINATION OF SOL-GEL DERIVED HYDROXYAPATITE ENHANCED WITH SILVER NANOPARTICLES USING OCT AND RAMAN SPECTROSCOPY
PublicationHydroxyapatite (HAp) has been attracting widespread interest in medical applications. In a form of coating, it enables to create a durable bond between an implant and surrounding bone tissues. With addition of silver nanoparticles HAp should also provide antibacterial activity. The aim of this research was to evaluate the composition of hydroxyapatite with silver nanoparticles in a non-destructive and non-contact way. For control measurements...
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The Influence of the Chemical Composition of Selected Waste Materials from the Production of Copper on the Final Environmental Assessment
PublicationThis article presents qualitative and quantitative analysis of the waste produced by KGHM Polska Miedź. The waste has been analyzed according to its chemical composition and balanced in order to be reused and recycled. Special attention has been paid to mining industries producing the biggest amount of waste and ore enrichment businesses generating waste, which isn’t reused nowadays. Laboratory reseach has been conducted on floatation...
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The Effect of Welding Conditions on Diffusible Hydrogen Content in Deposited Metal
PublicationThe article presents the results of a literature survey and preliminary tests which set out effects of welding conditions on the amount of diffusible hydrogen in deposited metal. Experiments were conducted by using rutile coated electrodes which generate high contents of diffusible hydrogen in deposited metal. The amount of diffusible hydrogen was determined by a glycerin test.Eleven factors were considered: the electrode angle,...
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Nanolayers in Fiber-Optic Biosensing
PublicationIn this chapter, fiber-optic sensors based on nanolayers or thin films and their ability to perform biophotonic measurements is presented. In the last decade, fiber-optic sensors have gained popularity as biosensing devices. This has been made possible because of the design and the integration of new materials in fiber-optic technology. Nanolayers and thin films made from various materials such as nanodiamond (NCD), boron-doped...
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Gas Composition Influence on the Properties of Boron-Doped Diamond Films Deposited on the Fused Silica
PublicationThe main subject of this study are molecular structures and optical properties of boron-doped diamond films with [B]/[C] ppm ratio between 1000 and 10 000, fabricated in two molar ratios of CH 4 -H 2 mixture (1 % and 4 %). Boron-doped diamond (BDD) film on the fused silica was presented as a conductive coating for optical and electronic purposes. The scanning electron microscopy images showed homogenous and polycrystalline surface...