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Search results for: BSC
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Transport properties of microemulsions with ionic liquid apolar domains as a function of ionic liquid content
PublicationThe specific conductivity, dynamic viscosity and apparent diffusion coefficient of each of four aqueous ionic liquid microemulsions (IL-MEs) were measured as a function of ionic liquid (IL) content. The investigated systems were composed of water, hydrophobic ILs (1-butyl-3-methylimidazolium hexafluorophosphate or bis(trifluoromethanesulphonyl)imide) and the nonionic surfactant Triton X-100 or its mixture with cosurfactant (butanol)....
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Highly stable organic–inorganic junction composed of hydrogenated titania nanotubes infiltrated by a conducting polymer
PublicationA poly(3,4-ethylenedioxythiophene) conducting polymer doped with poly(2-styrene sulfonate) (pEDOT:PSS) was efficiently electrodeposited on a layer composed of ordered titania nanotubes. TiO2 nanotubes were formed during an anodization process and, after calcinations, a layer was subjected to hydrogen plasma. Hydrogenation leads to Ti(III) formation, a decrease in resistance, and a huge increase of donor density when compared with...
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Synthetic lipopeptides as potential topical therapeutics in wound and skin care: in vitro studies of permeation and skin cells behaviour
PublicationSeveral Gly-His-Lys analogues were obtained to investigate their antimicrobial properties. Three lipophilic analogues with the structure numbering 1b, 2b, 4b, exhibit significant effect against bacteria and were selected for in vitro evaluation of skin cells behaviour. In the present studies, an in vitro model of wound repair, proliferative cell staining, and tracking of living cells were used. Cell proliferation and cell migration,...
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Convenient and efficient synthesis of functionalized unsymmetrical alkynyl sulfides
PublicationWe developed a simple and efficient method for the synthesis of functionalized unsymmetrical alkynyl sulfides under mild conditions in good yields. The designed method is based on the reaction of 5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-disulfanyl derivatives with lithium acetylides. The developed method allows the preparation of unsymmetrical alkynyl sulfides bearing additional hydroxyl, carboxyl, or amino functionalities.
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Catalytic impact of alloyed Al on the corrosion behavior of Co50Ni23Ga26Al1.0 magnetic shape memory alloy and catalysis applications for efficient electrochemical H2 generation
PublicationThe electrochemical and corrosion behaviour of Co50Ni23Ga27-xAlx (x = 0 and 1.0 wt%) magnetic shape memory alloys (MSMAs) was studied in 0.5 M NaCl solutions using various electrochemical techniques. Results showed remarkable activation of the tested MSMA toward pitting corrosion upon alloying it with Al. XPS examination confirmed the activation influence of alloyed Al. It proved that the presence of Al in the alloy's matrix weakens...
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Microplastics removal from aqueous environment by metal organic frameworks
PublicationThis paper provides an overview of recent research performed on the applications of metal–organic frameworks (MOFs) for microplastics (MPs) removal from aqueous environments. MPs pollution has become a major environmental concern due to its negative impacts on aquatic ecosystems and human health. Therefore, developing effective and sustainable methods for removing them from aqueous environments is crucial. In recent years, MOFs...
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An automated, low-latency environment for studying the neural basis of behavior in freely moving rats
PublicationBackground Behavior consists of the interaction between an organism and its environment, and is controlled by the brain. Brain activity varies at sub-second time scales, but behavioral measures are usually coarse (often consisting of only binary trial outcomes). Results To overcome this mismatch, we developed the Rat Interactive Foraging Facility (RIFF): a programmable interactive arena for freely moving rats with multiple feeding...
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Evaluation of adhesion strength, corrosion, and biological properties of the MWCNT/TiO2 coating intended for medical applications
PublicationMulti-wall carbon nanotube (MWCNT) coatings are gaining increasing interest because of their special properties used in many science fields. The titania coatings are known for their improvement of osteoblast adhesion, thus changing the surface architecture. Bi-layer coatings comprising 0.25 wt% of the MWCNTs and 0.30 wt% of titania (anatase structure) were synthesized in a two-stage procedure using the electrophoretic deposition...
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ZnO-decorated green-synthesized multi-doped carbon dots from Chlorella pyrenoidosa for sustainable photocatalytic carbamazepine degradation
PublicationThe promising green synthesis of carbon dots (CDs) from microalga Chlorella pyrenoidosa was achieved using simple hydrothermal and microwave-assisted methods. Doping of nanomaterials by nonmetals (N, S, and P) was confirmed by X-ray photoelectron spectroscopy (XPS), while the existence of metals in the CDs was confirmed by inductively coupled plasma optical emission spectroscopy (ICP-OES) and transmission electron microscopy (TEM),...
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Photocatalytic activity of layered MoS2 in the reductive degradation of bromophenol blue
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Study on the flammability, thermal stability and diffusivity of polyethylene nanocomposites containing few layered tungsten disulfide (WS2) functionalized with metal oxides
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A facile synthesis method and electrochemical studies of a hierarchical structured MoS2/C-nanocomposite
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Correction: MOF-5 derived carbon as material for CO2 adsorption
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MOF-5 derived carbon as material for CO2 absorption
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Enhancement of photocatalytic hydrogen evolution with catalysts based on carbonized MOF-5 and g-C3N4
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Anticancer and antimicrobial properties of novel η6-p-cymene ruthenium(ii) complexes containing a N,S-type ligand, their structural and theoretical characterization
PublicationRuthenium(II) complexes are lately of great scientific interest due to their chemotherapeutic potential asanticancer and antimicrobial agents. Here we present the synthesis of new pyrazole carbothioamidederivatives and their four arene–ruthenium complexes. The title compounds were characterized with theapplication of IR, NMR, mass spectrometry, elemental analysis and X-ray diffraction. Additionally, for newcomplexes DFT calculations...
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Solvothermal synthesis and structural characterization of three polyoxotitanium-organic acid clusters
PublicationThree new titanium oxo-clusters Ti4O2(OiPr)10(OOCPhMe)2 (I), Ti6O4(OEt)8(OOCPhMe)8 (II) and Ti6O6(OEt)6(OOCCHPh2)6 (III) were obtained by easy one-step solvothermal reactions of titanium(IV) isopropoxide, alcohols and carboxylic acids. The three compounds were characterized by single-crystal and powder X-ray diffraction, TGA/DSC, optical and electron microscopy, and FTIR and NMR spectroscopy. X-ray powder diffraction and spectroscopy...
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Ho2Pd1.3Ge2.7 – a ternary AlB2-type cluster glass system
PublicationWe report a successful synthesis of a ternary AlB2-type intermetallic compound. The phase purity was obtained by fine-tuning the Pd-Ge ratio out of the idealized 1-3. Attempts to synthesize an Er analogue were not successful. We discuss the instability of the Er analogue based on the atomic size ratio and also suggest that the increased stability of Ho2Pd1+xGe3−x in the Pd-rich range likely stems from a combination of atomic size...
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Structure and transport properties of triple-conducting BaxSr1−xTi1−yFeyO3−δ oxides
PublicationIn this work, BaxSr1−xTi1−yFeyO3−δ perovskite-based mixed conducting ceramics (for x = 0, 0.2, 0.5 and y = 0.1, 0.8) were synthesized and studied. The structural analysis based on the X-ray diffraction results showed significant changes in the unit cell volume and Fe(Ti)–O distance as a function of Ba content. The morphology of the synthesized samples studied by means of scanning electron microscopy has shown different microstructures...
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Novel tetrahedral cobalt(II) silanethiolates: structures and magnetism
PublicationThree heteroleptic complexes of Co(II) tri-tert-butoxysilanethiolates have been synthesized with piperidine [Co{SSi(OtBu)3}2(ppd)2] 1, piperazine [Co{SSi(OtBu)3}2(NH3)]2(μ-ppz)·2CH3CN 2, and N-ethylimidazole [Co{SSi(OtBu)3}2(etim)2] 3. The complexes have been characterized by a single-crystal X-ray, revealing their tetrahedral geometry on Co(II) coordinated by two nitrogen and two sulfur atoms. Complexes 1 and 3 are mononuclear,...
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Free-standing TiO2 nanotubes decorated with spherical nickel nanoparticles as a cost-efficient electrocatalyst for oxygen evolution reaction
PublicationHere, we report significant activity towards the oxygen evolution reaction (OER) of spherical nickel nanoparticles (NPs) electrodeposited onto free-standing TiO2 nanotubes (TNT) via cyclic voltammetry. It has been shown that simple manipulation of processing parameters, including scan rate and number of cycles, allows for formation of the NPs in various diameters and amounts. The polarization data with respect to transmission electron...
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Diaminophosphinoboranes: effective reagents for phosphinoboration of CO2
PublicationThe monomeric diaminophosphinoboranes readily react with CO2 under mild conditions to cleanly form products of the general formula R2P-C(=O)-O-B(NR2)2 in the absence of a catalyst. The isolated products from the CO2-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The mechanism of CO2 phosphinoboration with diaminophosphinoboranes was elucidated by DFT calculations.
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Development and validation of a model that includes two ultrasound parameters and the plasma D-dimer level for predicting malignancy in adnexal masses: an observational study
PublicationBackground: Pre-operative discrimination of malignant from benign adnexal masses is crucial for planning additional imaging, preparation, surgery and postoperative care. This study aimed to define key ultrasound and clinical variables and develop a predictive model for calculating preoperative ovarian tumor malignancy risk in a gynecologic oncology referral center. We compared our model to a subjective ultrasound assessment (SUA)...
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Pseudo-superparamagnetic behaviour of bariumhexaferrite particles
PublicationThe effect of hexadecyltrimethylammonium bromide (CTAB) addition on the crystal structure, morphology,and magnetic properties of co-precipitated hexagonal barium ferrite was investigated. For afixed amount ofsurfactant, different Fe3+concentrations and Fe3+/Ba2+ratios were used to optimize the formation ofsingle-phase barium ferrite particles. The results indicated that the obtained ferrite particles exhibitedcoercivity changes...
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Chromium‑based metal organic framework for pipette tip micro‑solid phase extraction: an effective approach for determination of methyl and propyl parabens in wastewater and shampoo samples
PublicationAbstract Background A chromium-based metal organic framework was synthesized and employed as an efficient sorbent for pipette tip micro-solid phase extraction and preconcentration of parabens from wastewater and shampoo samples up to sub-ppb level before their spectrophotometric analysis. Results Factors affecting preconcentration including volume and type of solvent, amount of sorbent, number of extraction, and volume and pH of...
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Activation of the C=P bond in phosphanylphosphaalkenes C=P–P bond system) in the reaction with nucleophilic reagents: MeLi, nBuLi and tBuLi
PublicationThree reactions of phosphanylphosphaalkene (1) with nucleophiles were performed to activate the diphosphorus monomer. We observed similar results in the reactions with MeLi and nBuLi, in which the P–P bond is cleavaged and triphosphorus systems [P(Me)2–CH(biph)–CH(biph)–P–(PtBu 2)]- (1a'') and [P(nBu)2–CH(biph)–CH(biph)–P–(PtBu 2)]- (1b''), respectively, are formed depending on the nucleophilic reagent (biph ¼ biphenyl). In the...
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Effect of cobalt addition on the corrosion behaviorof near equiatomic NiTi shape memory alloy in normal saline solution: electrochemical and XPS studies
PublicationThe electrochemical and corrosion (uniform and localized) behavior of a binary Ni52Ti48 shape memory alloy (SMA) and two ternary Ni52Ti48-xCox (x = 1.5 and 4.0 wt.%) SMAs were studied. Measurements were conducted in 0.9% NaCl solution at 37 oC employing various electrochemical methods. These include: linear polarization resistance (LPR), linear sweep voltammetry (LSV), chronoamperometry and dynamic electrochemical impedance spectroscopy...
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Degradation kinetics and mechanism of pentoxifylline by ultraviolet activated peroxydisulfate
PublicationDegradation of pentoxifylline (PTX) by sodium peroxydisulfate (SPDS) assisted by UV irradiation has been investigated in deionized water. The treatment was more favorable over direct photolysis or peroxydisulfate oxidation alone. The effects of various parameters, including different dosage of oxidant agent, PTX concentration, initial solution pH levels, and the presence of inorganic ions like chloride, nitrate and carbonate have...
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5-Selenocyanato and 5-trifluoromethanesulfonyl derivatives of 2′-deoxyuridine: synthesis, radiation and computational chemistry as well as cytotoxicity
Publication5-Selenocyanato-2′-deoxyuridine (SeCNdU) and 5-trifluoromethanesulfonyl-2′-deoxyuridine (OTfdU) have been synthesized and their structures have been confirmed with NMR and MS methods. Both compounds undergo dissociative electron attachment (DEA) when irradiated with X-rays in an aqueous solution containing a hydroxyl radical scavenger. The DEA yield of SeCNdU significantly exceeds that of 5-bromo-2′-deoxyuridine (BrdU), remaining...
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Reactions of cobalt(ii) chloride and cobalt(ii) acetate with hemisalen-type ligands: ligand transformation, oxidation of cobalt and complex formation. Preliminary study on the cytotoxicity of Co(ii) and Co(iii) hemisalen complexes
PublicationSeveral molecular cobalt(II) complexes, one Co(II) coordination polymer, and one ionic cobalt(III) complex with imine hemisalen ligands were synthesized. The hemisalen ligands were synthesized from o-vanillin (oVP) and diverse aminopyridines (compounds HL1–HL4) or aminophenol (compound HL5). It was observed that cobalt(II) chloride in dry acetonitrile catalyzes a transformation of HL1 and HL3 instead of complex formation. The conversion...
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Exfoliated graphite with spinel oxide as an effective hybrid electrocatalyst for water splitting
PublicationThe aim of the conducted research was to develop hybrid nanostructures formed from MnCo2O4 and exfoliated graphite. Carbon added during the synthesis allowed for obtaining a well-distributed MnCo2O4 particle size with exposed active sites contributing to the increased electric conductivity. The influence of the weight ratios of carbon to a catalyst for hydrogen and oxygen evolution reactions was investigated. The new bifunctional...
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Role of MnO in manganese–borate binary glass systems: a study on structure and thermal properties
PublicationStructural and thermal properties of x MnO−(100−x)B2O3 (where x=40, 50 and 60 mol%) glass samples have been investigated with the employment of various techniques. Fourier transform infrared spectroscopy results revealed the influence of MnO on glass matrix. Decrease of B–O bond-related band intensities has been observed. MnO addition was found to introduce broken [BO2O−]n chains. Differential scanning calorimetry (DSC) measurements...
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Spectroscopic evaluation on pseudopolymorphs of sodium naproxen
PublicationThis paper demonstrates the assessment of vibrational spectroscopy methods such as middle infrared, near infrared and Raman spectroscopy (FTIR, FT-NIR, Raman) for the identification of pseudopolymorphic forms of a model active pharmaceutical ingredient (API) - sodium naproxen (NpxNa). NpxNa, in the form of three different pseudopolymorphs, was investigated by methods dedicated for solid state characterization: DSC (differential...
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Light intensity analysis of photovoltaic parameters for perovskite solar cells
PublicationThe number of publications on perovskite solar cells (PSC) continues to grow exponentially. Although the efficiency of PSC is exceeded 25.5%, not every research laboratory can reproduce this result or even pass the border of 20%. Unfortunately, it is not always clear which dominating mechanism is responsible for the performance drop. Here, we develop a simple method of light intensity analysis of JV parameters allowing the understanding...
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The influence of the UV irradiation on degradation of virgin rapeseed oils
PublicationThis paper presents research which is a continuation of the investigations described earlier. The aim of these studies was to determine the influence of UV irradiation on flavor and the oxidative stability of different rapeseed oils varieties. For the purpose of this study, oil samples underwent accelerated deterioration for 4.5 h under a UV light test. In the obtained sample, characteristic values (peroxide (PV, 1.23–1.62 meq...
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Wave propagation in a sensor/actuator diffusion bond model
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Udział Politechniki Gdańskiej w projekcie RECO
PublicationReco jest projektem opartym na współpracy partnerów z Białorusi, Estonii, Finlandii, Litwy, Łotwy, Niemiec, Polski, Rosji i Szwecji w zakresie gospodarki odpadami i planowania przestrzennego. Liderem projektu jest Urząd Administracji Regionu Sztokholm. Projekt Reco realizowany jest w ramach Programu BSR Interreg III B
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Dywersyfikacja nadawania i jej zastosowanie w systemie UMTS.
PublicationW referacie przedstawiono technikę zwielokrotnionego nadawania przewidzianą do zastosowania w stacjach bazowych systemów DSC DMA, w celu zmniejszenia skutków zaników sygnałów odbieranych przez stacje ruchome. Zamieszczono klasyfikację i przegląd metod dywersyfikacji nadania zarówno z pętlą zamkniętą.Opisano sposób implementacji tych metod w systemie UMTS.
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Impulse Measurements of Tower Earthings of Overhead Transmission Lines
PublicationPrzepisy wymagają okresowego badania uziemień słupów elektroenergetycznych linii przesyłowych. pomiary takie metodami klasycznymi niskiej częstotliwości wymagają odłączania uziomów od konstrukcji słupa, co wiąże się z wyłączaniem linii. wykorzstanie metody udarowej do oceny uziemień nie wymaga odłączania uziomów i może byc przeprowadzane podczas pracy linii.
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Static analysis of thin-walled beams and frames with stiffeners.
PublicationPraca zawiera pełną treść referatu wygłoszonego na Konferencji w Wilnie.Referat przedstawia problem numerycznej analizy belek i ramstalowych zbudowanych z bi-symetrycznych profili cienkościennychze stężeniami. Wyniki analizy przeprowadzonej według koncepcji superelementu jednowymiarowego porównano z wynikami obliczeń przy zastosowaniu gęstej siatki elementów powłokowych QUAD4 programu MSC NASTRAN.
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Komputerowo wspomagana klasyfikacja wybranych sygnałów elektromiografii powierzchniowej
PublicationWykorzystywanie sygnałów elektromiografii powierzchniowej (ang. Surface Electromyography, SEMG) w procesach sterowania systemami rehabilitacyjnymi stanowi obecnie standardową procedurę. Popularność SEMG wynika z nieinwazyjności metody oraz możliwości szybkiej i precyzyjnej identyfikacji funkcji mięśniowej. W przypadku osób małoletnich proces klasyfikacji sygnałów jest utrudniony ze względu na mniejsze rozmiary i wyższą dynamikę...
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Finding the Right Solvent: A Novel Screening Protocol for Identifying Environmentally Friendly and Cost-Effective Options for Benzenesulfonamide
PublicationThis study investigated the solubility of benzenesulfonamide (BSA) as a model compound using experimental and computational methods. New experimental solubility data were collected in the solvents DMSO, DMF, 4FM, and their binary mixtures with water. The predictive model was constructed based on the best-performing regression models trained on available experimental data, and their hyperparameters were optimized using a newly...
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Structure and electric conductivity of reduced lead-germanate, bismuth-germanate and bismuth-silicate glasses modified with potassium
PublicationZbadano szkła germanianowo-ołowiowe i krzemianowo+bizmutowe. Warstwy metalicznych granul wytwarzano w nich poprzez redukcję powierzchni w atmosferze wodoru. Praca dotyczy wpływu potasu na właściwości szkła. Przeprowadzono badania metodami mikroskopii sił atomowych, DSC oraz pomiary przewodności elektrycznej. Stwierdzono, że obecność potasu poprawia mechaniczne i technologiczne właściwości szkła.
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Partial characterization of indigo (Polygonum tinctorium Ait.) plant seeds and leaves
PublicationThe aim of this study was to assess the contents of indigo's bioactive compounds, its antioxidant and anticancer activities in acetone, hexane and DMSO extracts and to compare the overall bioactivity with another more used medicinal plant named prolipid. It was found that the contents of the bioactive compounds in the studied extracts from different parts of indigo plant varied (P < 0.05): the significantly highest content of polyphenols...
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Wpływ syntetycznego polihydroksymaślanu na wybrane właściwosci nowych, otrzymanych z jego udziałem poliuretanów do zastosowań medycznych. cz II. Poliuretany z cykloalifatycznym diizocyjanianem w segmencie sztywnym. Polimery 56(1) 27-34, 2011
Publicationzsyntezowano poliuretany, w ltórych segmenty gietkie SG były zbudowane z telehelicznego, zakończonego obustronnie grupami -OH, ataktycznego polihydroksymaślanu (PHB). Wyniki DSC wskazują, że wprowadzenie PHB zaburza uporządkowanie w obrębie SG i sztywnych, zminejsza sie stopień krystaliczności, zwieksza sie nieco sorpcja wody. Test mikrobiologiczne wytworzonych PUR dowodzą skuteczności sterylizacji plazmą.
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Thermal decomposition of some aromatic azomonoethers. Part II. Non-isothermal study of three liquid crystals in dynamic air atmosphere
PublicationW ramach pracy zweryfikowano stabilność termiczną trzech barwników azowych o właściwościach ciekłokrystalicznych - potencjalnych prekursorów do otrzymywania warstw stosowanych w optyce nieliniowej. Zarejestrowano przebiegi TG, DTG, DTA oraz DSC jak również analizowano skład gazów powstających podczas rozpadu za pomocą przystawki FTIR. Przeprowadzono analizę kinetyki rozkładu, wyznaczając energię aktywacji procesu.
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Gas sensing by thermoelectric voltage fluctuations in SnO2 nanoparticle films
PublicationPrzedstawiono eksperymentalne wyniki wykrywania gazów za pomocą badania fluktuacji napięcia termoelektrycznego w warstwie SnO2 przygotowanej z jednorodnych ziaren o średnicy 20 nm. Obserwowano fluktuacje napięcia bez zewnętrznej polaryzacji warstwy SnO2. Intensywność obserwowanych fluktuacji przekraczała 1000-krotnie intensywność szumów termicznych. Obserwowane zjawisko może byc wykorzystane do zwiększenia czułości wykrywania...
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Synteza i charakterystyka „zielonych” mieszanin polimerowych na bazie biopochodnego termoplastycznego poliuretanu i octanomaślanu celulozy
PublicationOtrzymano mieszaniny polimerowe z biopochodnego termoplastycznego poliuretanu (TPU) i dostępnego handlowo octanomaślanu celulozy (CAB), stosowanego w ilości 0–20%. TPU syntezowano metodą prepolimerową z wykorzystaniem biopoliolu, glikolu 1,3-propylenowego i diizocyjanianu heksametylenu. Materiały poddano analizie pod kątem struktury chemicznej (FTIR), właściwości termicznych (TGA, DSC) i właściwości termomechanicznych (DMTA).
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Selected issues of women's participation in labour market and on boards of family entreprises
PublicationThe chapter presents cultural determinants of roles attributed to women, as well as their situation in the labour market and in family businesses. The main aim of the study is to trace the changes in the social image of women’s roles in the labour market. The observations made are based on the changes in the value of the economic activity rate among women in the Baltic Sea Region (BSR) countries, as well as on the feminisation...
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Fault detection in the marine engine using a support vector data description method
PublicationFast detection and correct diagnosis of any engine condition changes are essential elements of safety andenvironmental protection. Many diagnostic algorithms significantly improve the detection of malfunctions.Studies on diagnostic methods are rarely reported and even less implemented in the marine engine industry.To fill this gap, this paper presents the Support Vector Data Description (SVDD) method as applied to thefault detection...