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Search results for: PROMIENIE X
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Coordination polymers and molecular structures among complexes of mercury(II) halides with selected 1-benzoylthioureas
PublicationSix new 1-benzoyl-3-phenylthiourea and 1-benzoyl-3-(2-methylphenyl)thiourea complexes of mercury( II) were obtained in the reactions of the ligands with HgX2 in methanol (X = Cl, Br, I). Their structures, determined by single-crystal X-ray diffraction analysis, exhibit different stoichiometries and molecular organization. Coordination centers adopt more or less distorted tetrahedral geometry (five structures) or distorted trigonal...
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Cancer-selective, single agent chemoradiosensitising gold nanoparticles
PublicationTwo nanometre gold nanoparticles (AuNPs), bearing sugar moieties and/or thiol-polyethylene glycol-amine (PEG-amine), were synthesised and evaluated for their in vitro toxicity and ability to radiosensitise cells with 220 kV and 6 MV X-rays, using four cell lines representing normal and cancerous skin and breast tissues. Acute 3 h exposure of cells to AuNPs, bearing PEG-amine only or a 50:50 ratio of alpha-galactose derivative and...
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Effect of cobalt addition on the corrosion behaviorof near equiatomic NiTi shape memory alloy in normal saline solution: electrochemical and XPS studies
PublicationThe electrochemical and corrosion (uniform and localized) behavior of a binary Ni52Ti48 shape memory alloy (SMA) and two ternary Ni52Ti48-xCox (x = 1.5 and 4.0 wt.%) SMAs were studied. Measurements were conducted in 0.9% NaCl solution at 37 oC employing various electrochemical methods. These include: linear polarization resistance (LPR), linear sweep voltammetry (LSV), chronoamperometry and dynamic electrochemical impedance spectroscopy...
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Reactive deposition of TiNx layers in a DC-magnetron discharge
PublicationTiNx layers have been deposited in 'balanced mode' and 'unbalanced mode' of a reactive DC-magnetron plasma (carrier gas argon, reactive gas nitrogen) under different conditions. Discharge power and reactive gas flow have been varied. The layers have been examined by X-ray photoelectron spectroscopy (XPS), X-ray reflectometry (XR), and spectroscopic ellipsometry (SE). The results of the layer analyses were combined with plasma investigations...
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Parity vertex colouring of graphs
PublicationA parity path in a vertex colouring of a graph is a path along which each colour is used an even number of times. Let Xp(G) be the least number of colours in a proper vertex colouring of G having no parity path. It is proved that for any graph G we have the following tight bounds X(G) <= Xp(G) <=|V(G)|− a(G)+1, where X(G) and a(G) are the chromatic number and the independence number of G, respectively. The bounds are improved for...
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Modernization of large music studio at Polish Radio Szczecin
PublicationStudio Muzyczne S-1 w Polskim Radiu Szczecin należy do największych studiów nagrań w Polsce. Wymiary studia wynoszą 15.3 x 17 x 8.6 m, powierzchnia 261 m2, kubatura 2244 m3. W wyniku licznych korekt akustycznych dokonanych w ciągu ostatnich lat, warunki akustyczne studia są akceptowane przez szeroki krąg realizatorów i wykonawców, co uznano to za cenny i trudno odtwarzalny walor techniczny. W związku z tym, modernizację Studia...
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OPTIMIZATION OF NASICON PREPARATION METHOD
PublicationNasicon is a solid conductor which has an ability to conduct Na+ ions and it is used in solid gas sensors. In this article a method of Nasicon preparation appropriate for gas sensing application by solgel technique is presented. Influence of the fabrication process parameters on properties of obtained samples was determined. Results of X-Ray diffraction, density, porosity, conductivity, and activation energies measurement are presented.
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Porównanie procesu wytwarzania na obrabiarkach konwencjonalnych i CNC na przykładzie korpusu
PublicationPrzedstawiono cztery wersje procesu obróbki korpusu.Pierwsza z nich bazuje na obrabiarkach konwencjonalnych, ostatnia zaś na 9.osiowej tokarce z dwiema głowicami rewolwerowymi posiadającymi osie X,V oraz Z. Opisano też sposób osiagniecia 10-krotnego skrócenia czasu wykonania korpusu poprzez wdrożenie sterowania poprzecznego.
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Porównanie procesu wytwarzania na obrabiarkach konwencjonalnych i CNC na przykładzie korpusu
PublicationPrzedstawiono cztery wersje procesu obróbki korpusu. Pierwsza z nich bazuje na obrabiarkach konwencjonalnych, ostatnia zaś na 9. osiowej tokarce z dwiema głowicami rewolwerowymi posiadajacymi osie X,Y oraz Z. Opisano też sposób osiągniecia 10-krotnego skrócenia czasu wykonania korpusu poprzez wdrożenie sterowania poprzecznego.
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Boron Difluoride Complexes of Carbamoyl Meldrum's Acids
Publication5-[Hydroxy(aryl/alkylamino)methylene]-2,2-dimethyl-1,3-dioxane-4,6-diones react with BF3•Et2O in mild conditions leading to the formation of boron difluoride complexes of carbamoyl Meldrum's acids. The X-ray structure has been obtained for one representative complex. The obtained new compounds are fairly stable at standard ambient conditions and easily isolable.
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EXAFS study of glasses of the CaO-Ga2O3-GeO2 system.
PublicationPrzedstawiono wyniki pomiaru i analizy widm absorpcji promieniowania X na krawędziach K germanu i galu uzyskane dla szkieł Ca3Ga2Ge3O12 i Ca3Ga2Ge4O14.Opisano szczegółowo lokalne otoczenie wokół jonów Ga i Ge (analiza EXAFS) i porównano uzyskane dane strukturalne z danymi opisującymi stechiometryczne odpowiedniki krystaliczne.
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Karol Grębowski dr inż.
PeopleKarol Grębowski (M.Sc.) works as an assistant at the Department of Technical Fundamentals of Architecture Design of the Faculty of Architecture at Gdansk University of Technology. His scientific research deals with dynamic phenomena occurring during the vibration of structures, bridges, and studies the design methodology of the elements forming passive protection system of the vehicles degraded by struck or explosion in the context...
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Dariusz Kowalski dr inż.
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Diaminophosphinoboranes: effective reagents for phosphinoboration of CO2
PublicationThe monomeric diaminophosphinoboranes readily react with CO2 under mild conditions to cleanly form products of the general formula R2P-C(=O)-O-B(NR2)2 in the absence of a catalyst. The isolated products from the CO2-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The mechanism of CO2 phosphinoboration with diaminophosphinoboranes was elucidated by DFT calculations.
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Evaluation of cathode materials for electrochemical photocatalyst deposition
PublicationElectrochemical deposition of photocatalyst, especially TiO2, onto several cathode materials was investigated and evaluated. The deposited films were characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectrometer (EDX) and electrochemical measurements. Photocatalytic activity was determined by the decomposition of cyclohexane in air by irradiation with ultraviolet light emitting diodes. It was found that...
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Eliminacja strat pracy maszyn w procesach aparaturowych
PublicationW niniejszym artykule zostały przedstawione wyniki badań w zakresie eliminacji strat maszyn występujące na linii produkcyjnej w procesach aparaturowych u producenta farb proszkowych przedsiębiorstwa X. Dodatkowo autorzy zaproponowali własne metody organizacyjne , które zasadniczo zmniejszą straty maszyn na linii produkcyjnej i spowodują większą niezawodność parku maszynowego.
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Isostructural zinc and cadmium silanethiolates with bridging biimidazole co-ligands – Enhanced luminescence of zinc complex
PublicationTwo dinuclear complexes of zinc and cadmium with silanethiolate and bridging biimidazole ligands are characterized by X-ray diffraction, FT-IR, UV–Vis and emission spectroscopies. The complexes 1 (Zn) and 2 (Cd) are isostructural but exhibit different electronic structures and different character of frontier HOMO orbitals as indicated by DFT calculations. Lluminescence studies prove strong emission properties of zinc complex.
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Halogen bonded polypseudorotaxanes based on a pillar[5]arene host
PublicationTwo crystalline supramolecular polypseudorotaxanes were obtained by combining permethylated pillar[5]arene as a macrocyclic wheel with 1,4-bis(1-imidazolyl)butane and 1,4-bis(iodoethynyl)benzene or 1,4-diiodo-1,3-butadiyne linked by C–I⋯N halogen bonds and creating a polyrotaxane axis. The resulting highly ordered supramolecular arrays were characterized by X-ray crystallography.
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Intramolecular interactions in crystals of tris(2,6-diisopropylphenoxy)silanethiol and its sodium salts
PublicationHydrolytically stable tris(2,6-diisopropylphenoxy)silanethiol has been obtained and reacted with sodium. Solid state interactions within and between the molecules of tris(2,6-diisopropylphenoxy)silanethiol including S-H---π-interactions between the S-H unit and the π-system of the arene have been analyzed. The interactions are documented by X-ray diffraction and FT-IR spectroscopy.
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Akcelerator predykcji wewnątrzramkowej H.264 do kompresji obrazu w sensorach wizyjnych
PublicationW komunikacie przedstawiono konfigurowalny cyfrowy akcelerator predykcji wewnątrzramkowej przeznaczony dla enkodera wideo standardu H.264. Akcelerator realizuje predykcję typu „intra” dla makrobloków luminancji o wymiarach 4x4 i 16x16. Akcelerator wstępnie zaimplementowano w układzie FPGA, gdzie został on pomyślnie zweryfikowany, a następnie zaimplementowano go w układzie ASIC w technologii UMC 90 nm. Szczegółowe wyniki testów...
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Akcelerator predykcji wewnątrzramkowej H.264 do kompresji obrazu w sensorach wizyjnych
PublicationW artykule przedstawiono konfigurowalny cyfrowy akcelerator predykcji wewnątrzramkowej przeznaczony dla enkodera wideo standardu H.264. Akcelerator realizuje predykcję typu „intra” dla makrobloków luminancji o wymiarach 4x4 i 16x16. Akcelerator wstępnie zaimplementowano w układzie FPGA, gdzie został on pomyślnie zweryfikowany, a następnie zaimplementowano go w układzie ASIC w technologii UMC 90 nm. Szczegółowe wyniki testów akceleratora...
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The Effect of Titanium Oxyfluoride Morphology on Photocatalytic Activity of Fluorine-Doped Titanium(IV) Oxide
PublicationTitanium oxyfluoride (TiOF2) is a metastable product that can be obtained in a fluorine-rich environment. This material can also be a valuable precursor in the synthesis of titanium(IV) oxide (TiO2). However, the effect of TiOF2 morphology on the physicochemical properties of TiO2 has not been studied so far. In this work, single-phase TiOF2 was prepared by a solvothermal method. The as-synthesized samples exhibited a variety of...
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Fabrication of La-Doped Bi4Ti3O12 Ceramics
PublicationLa-modified Bi4Ti3O12 is a typical ferroelectric, piezoelectric and electro-optic material, having relatively low coercive field, low dielectric constant, high Curie temperature and high breakdown strength. Goal of the present research was to apply mixed oxide method for fabrication of BiTLax ceramics, study its chemical composition, crystalline structure and microstructure. The compound BiTLax for x=0, 0.25, 0.5, 0.75 ceramic...
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MnxCo3-xO4 spinel oxides as efficient oxygen evolution reaction catalysts in alkaline media
PublicationThe design of efficient electrocatalysts for oxygen evolution reaction (OER) is an essential task in developing sustainable water splitting technology for the production of hydrogen. In this work, manganese cobalt spinel oxides with a general formula of MnxCo3-xO4 (x=0, 0.5, 1, 1.5, 2) were synthesised via a soft chemistry method. Non-equilibrium mixed powder compositions were produced, resulting in high electrocatalytic activity....
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Effects of Bromine Doping on the Structural Properties and Band Gap of CH3NH3Pb(I1–xBrx)3 Perovskite
PublicationAn experimental and theoretical study is reported to investigate the influence of bromine doping on CH3NH3Pb(I1−xBrx)3 perovskite for Br compositions ranging from x = 0 to x = 0.1, in which the material remains in the tetragonal phase. The experimental band gap is deduced from UV−vis absorption spectroscopy and displays a linear behavior as a function of bromine concentration. Density functional theory calculations are performed...
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The influence of nanostructures size on V2O5 electrochemical properties as cathode materials for lithium ion battery
PublicationIn this paper, V2O5 nanostructures with a size depending on the annealing temperature are successfully synthesized by a sol-gel method. The crystal structure and morphology of samples are characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), selected area electron diffraction (SEAD) and scanning electron microscopy (SEM), respectively. Electrochemical testing such...
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Local Structure and Stability of SEI in Graphite and ZFO Electrodes Probed by As K-edge Absorption Spectroscopy
PublicationThe evolution of the solid electrolyte interphase (SEI) during the first Li uptake in advanced Li-ion electrodes is studied by X-ray absorption spectroscopy (XAS). The As atoms present in the electrolyte solution were used as a local probe for monitoring the SEI growth on different electrodes. High-quality As K-edge spectra were collected in fluorescence mode for a set of graphite and carbon-coated ZnFe2O4 electrodes. XAS measurements...
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Synthesis and properties of AxV2Al20 (A = Th, U, Np, Pu) ternary actinide aluminides
PublicationPolycrystalline samples of AxV2Al20 (A = Ce, Th, U, Np, Pu; 0.7 ≤ x ≤ 1.0) actinide intermetallics were synthesized using the arc-melting method. Crystal structure studies were performed by means of powder x-ray diffraction and the Rietveld refinement method. All studied compounds crystallize in the CeCr2Al20-type structure (space group Fd-3m, no. 227) with the actinoid and Ce atom located in the oversized icosahedral cage formed...
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Visible light photocatalytic activity of ionic liquid-TiO2 spheres: effect of the ionic liquid's anion structure
PublicationThe effect of the ionic liquid’s (IL) anion type ([BIMIM][X], where X= [Br], [PF6] or [OctSO4]) and content on the morphology, surface properties and photoactivity of TiO2 obtained by solvothermal method has been systematically investigated. Our results revealed that the presence of [Br], [OctSO4] anions favors formation of anatase phase, while presence of [PF6] anion causes formation of mixture of anatase and Ti(OH)PO4 phases....
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A CMOS Pixel With Embedded ADC, Digital CDS and Gain Correction Capability for Massively Parallel Imaging Array
PublicationIn the paper, a CMOS pixel has been proposed for imaging arrays with massively parallel image acquisition and simultaneous compensation of dark signal nonuniformity (DSNU) as well as photoresponse nonuniformity (PRNU). In our solution the pixel contains all necessary functional blocks: a photosensor and an analog-to-digital converter (ADC) with built-in correlated double sampling (CDS) integrated together. It is implemented in...
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Enhanced visible light photocatalytic activity of Pt/I-TiO2 in a slurry system and supported on glass packing
PublicationHighly photoactive I/TiO2, Pt/I-TiO2 nanocomposites were obtained using a hydrothermal and wet impregnation method. The incorporation of iodine and modification with 0.05 mol% of platinum leads to enhanced photocatalytic activity as compared to singly doped TiO2 due to the presence of impurity energy level in the structure of TiO2. X-ray diffraction, TEM microscopy, UV–Vis spectroscopy, X-ray photoelectron spectroscopy and BET...
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Oxidation step in the preparation of benzocamalexin: The crystallographic evidence
PublicationThe study of oxidation step in the preparation of benzocamalexin by the α-amidoalkylation–oxidation sequence revealed the formation of perchloro-1,2-phenylene dibenzoate as the product of transformation of tetrachloro- 1,2-benzoquinone applied as the oxidant. The structures of benzocamalexin and perchloro-1,2-phenylene dibenzoate were confirmed by X-ray diffraction analysis. The extraction step in the final isolation of benzocamalexin...
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Physicochemical aspects of the application of surfactants and biosurfactants in soil remediation
PublicationZaprezentowano właściwości zwilżające, emulgujące oraz solubilizujące surfaktantów niejonowych Rokanolu L10, Tritonu X-100 oraz biosurfaktantu JBR 425. Jako modelowe zanieczyszczenia wybrano tetrachloroetylen (PCE) oraz o-dichlorobenzen (o-DCB). Stabilność emulsji rosła wraz ze stężeniem surfaktantu. Rozpuszczalnośc PCE i o-DCB była największa w roztworach micelarnych biosurfaktantu JBR.
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Solution conformational study of Scyliorhinin I analogues with conformational constraints by two-dimensional NMR and theoretical conformational analysis
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Infrared response of multiwalled boron nitride nanotubes
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Kobieta ciężarna i alkohol-toksyczny związek. Smółka noworodków jako materiał w diagnostyce spożywania alkoholu w czasie ciąży
PublicationKażda ilość alkoholu spożyta przez ciężarną kobietę może spowodować poronienie, przedwczesny poród, patologię łożyska, zahamowanie wzrostu wewnątrzmacicznego płodu i wystąpienie licznych wad wrodzonych wywołanych alkoholem, określanych wspólnie mianem spektrum płodowych zaburzeń alkoholowych - FASD. Mogą one objawiać się zaburzeniami psychicznymi i/lub fizycznymi. Współczesna diagnostyka u noworodków zespołu FASD opiera się najczęściej...
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Analiza układów kinematycznych docierania powierzchni płaskich w aspekcie równomierności zużycia tarczy docierającej
PublicationPrzedmiotem rozprawy doktorskiej jest analiza układów kinematycznych docierania jednotarczowego w aspekcie równomierności zużycia tarczy docierającej. W pierwszej części pracy szczegółowo opisano mechanizm docierania powierzchni płaskich oraz określono wpływ poszczególnych parametrów procesu na dokładność obróbki. Przeanalizowano dotychczas opracowane modele zużycia docieraka oraz opisano istniejące rozwiązania konstrukcyjne układów...
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The synthesis and structure of a potential immunosuppressant: N-mycophenoyl malonic acid dimethyl ester
PublicationThe synthesis of a potential immunosuppressant, i.e. dimethyl ester of N-mycophenoyl malonic acid was optimized in the reaction of mycophenolic acid (MPA) with amino malonic dimethyl ester in the presence of propanephosphonic anhydride (T3P) as a coupling reagent. The structural properties of the obtained MPA derivative were investigated by NMR, MS and single crystal X-ray diffraction methods. Theoretical considerations of conformational...
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Determination of the chemical structure of potential organic impurities occurring in drug substance opipramol
PublicationThe tricyclic antipsychotic and antidepressant drug opipramol (opipramole) was examined with regard to the chemical structure of its organic impurities. Impurities were isolated from the technical product by chromatographic methods and their chemical structures were established by 1H NMR, MS and FTIR and further confirmed by comparison with commercially available products or with products obtained by independent synthesis, and...
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Structure and morphology of hydrogen reduced surface of bismuth germanateand bismuth silicate glasses.
PublicationOtrzymano nanostruktury krystalicznego bizmutu w matrycy XO2(X=Si,Ge) oraz warstwę nanostruktur krystalicznego bizmutu na powierzchni redukowanych w atmosferze wodoru szkieł Bi0.33Ge0.67O1. i Bi0.57Si0.43O1.72. Zaproponowano prosty model budowy zredukowanych szkieł bizmutowo-germanowych potwierdzony wynikami badań AFM i XRD. Obserwowane zmiany przewodnictwa elektrycznego redukowanych szkieł wyjaśniono na podstawie modelu.
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The Effect of Fly Ash Microspheres on the Pore Structure of Concrete
PublicationThe fly ash microspheres (FAMs) formed during the mineral transformation stage in coal combustion are hollow spherical particles with a density less than water. This paper presents the results of X‐ray micro‐computed tomography and an automatic image analysis system of the porosity in the structure of hardened concrete with microspheres. Concrete mixtures with ordinary Portland cement and two substitution rates of cement by microspheres—5%...
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Shales Leaching Modelling for Prediction of Flowback Fluid Composition
PublicationThe object of the paper is the prediction of flowback fluid composition at a laboratory scale, for which a new approach is described. The authors define leaching as a flowback fluid generation related to the shale processing. In the first step shale rock was characterized using X-ray fluorescence spectroscopy, X-ray diractometry and laboratory analysis. It was proven that shale rock samples taken from the selected sections of horizontal...
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DFT study of low-energy electron interaction with pyridine, pyrazine and their halo derivatives
PublicationIn this work, the density functional theory with B3LYP hybrid functional was employed to calculate quantities useful for estimating the behavior of pyridine, pyrazine and their derivatives monosubstituted with Cl or Br atom, when exposed to low-energy electron impact. Vertical electron affinities obtained in several Pople basis sets and in aug-cc-pVTZ basis set are reported. Although some of the investigated molecules do not form...
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Structure and transport properties of triple-conducting BaxSr1−xTi1−yFeyO3−δ oxides
PublicationIn this work, BaxSr1−xTi1−yFeyO3−δ perovskite-based mixed conducting ceramics (for x = 0, 0.2, 0.5 and y = 0.1, 0.8) were synthesized and studied. The structural analysis based on the X-ray diffraction results showed significant changes in the unit cell volume and Fe(Ti)–O distance as a function of Ba content. The morphology of the synthesized samples studied by means of scanning electron microscopy has shown different microstructures...
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Lipopeptides - synthesis and their properties
PublicationZaprezentowano syntezę nowych pochodnych tripeptydu Gly-Hyp-Lys o potencjalnie lepszych właściwościach lipofilowych. Modyfikacje polegały na acylowaniu N-końca glicyny kwasami tłuszczowymi (np. palmitynowym i stearynowym). Syntezę lipopeptydów zawierających fragment Gly-X-Y (gdzie: X= Met,Hyp,Hyp-Met,Gly-Hyp; Y=Lys,D-Lys) przeprowadzono na fazie stałej z zastosowaniem procedury Fmoc. Do wydłużanie łańcucha peptydowego zastosowano...
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Experimental tuning of AuAg nanoalloy plasmon resonances assisted by machine learning method
PublicationPlasmonic nanostructures based on AuAg nanoalloys were fabricated by thermal annealing of metallic films in an argon atmosphere. The nanoalloys were chosen because they can extend the wavelength range in which plasmon resonance occurs and thus allow the design of plasmonic platforms with the desired parameters. The influence of initial fabrication parameters and experimental conditions on the formation of nanostructures was investigated....
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Preparation and characterization of Pt–N/TiO2 photocatalysts and their efficiency in degradation of recalcitrant chemicals
PublicationSeries of Pt–N/TiO2 photocatalysts were synthesized using the sol–gel method. The photocatalysts’ characteristics by X-ray diffractometry (XRD), scanning transmission electron microscopy (STEM), diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) showed that sample with the molar ratio Ti:N equal 1:4 and platinum nanoparticles size of about 3 nm had anatase structure, about 94 m2/g specific surface area...
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Enhanced photocatalytic properties of lanthanide-TiO2 nanotubes: An experimental and theoretical study
PublicationA series of Er-, Yb-, Ho-, Tb-, Gd-, Pr-TiO2 nanotubes (RE-NTs) was prepared via an electrochemical method. The as-prepared photocatalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV–vis absorption, scanning electron microscopy (SEM) and luminescent spectroscopy. The experiments demonstrated that toluene in the gas phase was successfully degraded under visible light (LEDs λmax = 465...
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Novel complexes possessing Hg–(Cl, Br, I)⋯O=C halogen bonding and unusual Hg₂S₂(Br/I)₄ kernel. The usefulness of τ₄′ structural parameter
PublicationOne mononuclear and two binuclear Hg(II) complexes have been synthesized and characterized by X-ray diffraction, ATR IR and Hirshfeld surface analysis. Single-crystal X-ray diffraction showed that binuclear compounds are centrosymmetric and isostructural. All complexes form bifurcated intermolecular N–H···O hydrogen bonds that contribute to a formation of the centrosymmetric dimers. In binuclear complexes, sulfur atoms of thiourea...
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Structural and electrical properties of Cr-doped SrTiO 3 porous materials
PublicationSeries of single-phase materials with assumed formula SrTi1−xCrxO3 (where x = 0, 1, 4, 6 mol.%) were obtained by sol-gel method. The structure and microstructure of materials were characterised by X-ray diffraction and scanning electron microscopy methods. Moreover, the study of electrical properties and evaluation of chemical stability in CO2/H2O atmosphere was performed by electrochemical impedance spectroscopy and thermogravimery...