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Search results for: ION EXCHANGING
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Virtual screening for small molecular non-covalent binders of the SARS-CoV-2 main protease
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Application of the Murnaghan model in analysis of non-linear elastic material properties of pvc-coated fabric
PublicationW pracy omówiono proces identyfikacji parametrów materiałowych dla wybranej tkaniny technicznej typu Panama. Zaproponowano metodę identyfikacji nieliniowo sprężystych właściwości tkaniny Panama dla modelu Murnaghan'a. Określono zakres stosowalności nieliniowo sprężystych parametrów, w oparciu o doraźną wytrzymałości tkaniny na rozciąganie, która poddana redukcji określa tzw. wytrzymałość długoterminową. Opisano doświadczenia niezbędne...
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FE analysis of strain localization in concrete in elasto-plasticity and damage mechanics with non-local softening
PublicationW artykule przedstawiono wyniki symulacji numerycznych zjawiska lokalizacji odkształceń w betonie wykonanaych przy zastosowaniu metody elementów skończonych (MES). Do opisu betonu wykorzystano dwa prawa materiałowe zdefiniowane w ramach teorii plastyczności (kryterium Druckera-Pragera w ściskaniu i warunek Rankine'a w rozciąganiu) oraz mechaniki uszkodzeń w sformułowaniu odkształceniowym. Dla poprawnego opisu lokalizacji (regularyzacji...
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Bifurkacje w zagadnieniu von Karmana dla prostokątnej płyty na podłożu nieliniowo-sprężystym
PublicationW pracy przedstawiono problem wyboczenia płyty prostokątnej spoczywającej na nieliniowo sprężystym podłożu. Wykorzystano do tego celu sformułowanie podane przez von Karmana. Wyznaczono krytyczne parametry układu prowadzące do jego bifurkacji oraz zbadano stan pokrytyczny. Podano typy podłoża nieliniowego, dla których mogą wystąpić niestateczne stany równowagi.
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Multiple solutions of indefinite elliptic systems via a Galerkin-type Con- ley index theory
PublicationW pracy wykazano prawdziwość hipotezy Angenenta i van der Vorsta dotyczącąilości rozwiązań pewnego układu eliptycznego. Liczbę rozwiazań szacuje się zdołu przy pomocy niezmiennika topologicznego zwanego uogólnionym indeksemMorse`a. W dowodzie stosuje sie niezmienniczy index Conleya w przestrzeniachHilberta.
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Studies on intercorrelation between ions co-occurring in precipitation in the Gdańsk-Sopot-Gdynia Tricity (Poland)
PublicationPrzedstawiono wyniki badań próbek opadów deszczowych zebranych na terenie Trójmiasta w okresie 12 miesięcy (na 10 stacjach pobierania próbek). Wyniki oznaczeń zawartości jonów SO4-2, F-, Cl-, NO3-, PO4-3, NH4+, Na+, Mg+2, Ca+2K+ poddano analizie statystycznej. Wyniki pomiarów skorelowano z danymi dotyczącymi kierunków wiatrów i temperatury powietrza atmosferycznego.
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A non-quasi-static small-signal model of the four-terminal MOSFET for radio and microwave frequencies.
PublicationW pracy zaprezentowano nowy małosygnałowy model tranzystora MOS, w którymuwzględnia się efekt nasycenia prędkości nośników. Model jest spójny fizycznie i może być stosowany w analizie dowolnej konfiguracji włączenia tranzystora.
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Ionic chromatographic studies on intercorrelation between cooccuring ions in precipitation waters in the area of Tricity (Poland).
PublicationObszar Trójmiasta jest terenem bardzo zurbanizowanym. Duża koncentracja przemysłu na małej powierzchni stanowi poważne zagrożenie dla powietrza atmosferycznego. Analiza emisji zanieczyszczeń wskazuje na zróżnicowanie ich źródeł. Najważniejsze są substancje które tworzą się podczas energetycznego spalania paliw. 80% emisji ditlenku siarki, ditlenku azotu, pyłu, tlenku węgla i sadzy węglowej pochodzi z Gdańska i Gdyni, głównych centrów...
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Nieliniowy model matematyczny transformatora trójfazowego = Non-linear mathematical model of a three-phase transformer
PublicationPrzedstawiono model transformatora trójfazowego o rdzeniu trójkolumnowym, który zawiera układ rów-nań opisujących obwód magnetyczny oraz oddzielnie układ równań obwodu elektrycznego. Wydzielenie re-luktancji elementów rdzenia umożliwia uwzględnienie zmian względnej przenikalności magnetycznej w funkcji bieżącej wartości strumienia w rdzeniu. Re-luktancje odpowiadające strumieniom rozproszenia obliczono wg zasad klasycznych. Funkcję...
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Analytical and experimental determination of parameters for the non-linear viscoelastic model of earthquake-induced structural pounding
PublicationNieliniowy model lepko-sprężysty umożliwia dokładną symulację siły zderzenia w czasie oraz symulację odpowiedzi konstrukcji podatnej na zderzanie podczas trzęsień ziemi. Jednym z celów niniejszego artykułu jest wyprowadzenie wzoru na zależność pomiędzy liczbą tłumienia zderzenia (parametr wspomnianego modelu), a współczynnikiem odbicia. Kolejnym celem jest wyznaczenie zakresu wartości współczynników odbicia oraz współczynników...
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Non-Adaptive Speed and Position Estimation of Doubly-Fed Induction Generator in Grid-Connected Operations
PublicationThe nonadaptive speed and position estimation scheme for a doubly-fed induction generator (DFIG) is presented in this article. The observer structure is based on the extension of the mathematical model of DFIG to the introduced H vector. Based on the defined H vector, the nonadaptive position and speed estimation is proposed. The Lyapunov method is extended to the practical stability theorem to stabilize the structure. The classic...
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Robust asymptotic super twisting sliding mode observer for non-linear uncertain biochemical systems
PublicationThe problem of state estimation (reconstruction of the state vector) for a given class of biochemical systems under uncertain system dynamics has been addressed in this paper. In detail, the bioreactor at a water resource recovery facility represents the considered biochemical systems. The biochemical processes taking place in the bioreactor have been modelled using an activated sludge model. Based on this model, an appropriate...
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The Sonocatalytic Activation of Persulfates on Iron Nanoparticle Decorated Zeolite for the Degradation of 1,4-Dioxane in Aquatic Environments
PublicationIn the chemical industry, 1,4-diethylene dioxide, commonly called dioxane, is widely used as a solvent as well as a stabilizing agent for chlorinated solvents. Due to its high miscibility, dioxane is a ubiquitous water contaminant. This study investigates the effectiveness of catalyst- and ultrasound (US)-assisted persulfate (PS) activation with regard to degrading dioxane. As a first step, a composite catalyst was prepared using...
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Opioid Growth Factor and its Derivatives as Potential Non-toxic Multifunctional Anticancer and Analgesic Compounds
PublicationIn this paper, we review the structure-activity relationship of OGF and its analogues. We highlight also OGF derivatives with analgesic, immunomodulatory activity and the ability to penetrate the blood-brain barrier and may be used as safe agents enhancing chemotherapy efficacy and improving quality of life in cancer patients. The reviewed papers indicate that Met-enkephalin and its analogues are interesting candidates for the...
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Cyclodextrin polymers as efficient adsorbents for removing toxic non-biodegradable pimavanserin from pharmaceutical wastewaters
PublicationPresence of even small amount of active pharmaceutical ingredients in the environment carries risks tohuman and animal health, presenting an important issue. The paper presents issues related to the newdrug - pimavanserin (PMV). Biological treatment efficiency of pimavanserin (PMV) was evaluated usinglab-scale Sequencing Batch Reactor (SBR). It has been shown to have a negative effect on aquatic or-ganisms by classifying it as...
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Adaptive Positioning Systems Based on Multiple Wireless Interfaces for Industrial IoT in Harsh Manufacturing Environments
PublicationAs the industrial sector is becoming ever more flexible in order to improve productivity, legacy interfaces for industrial applications must evolve to enhance efficiency and must adapt to achieve higher elasticity and reliability in harsh manufacturing environments. The localization of machines, sensors and workers inside the industrial premises is one of such interfaces used by many applications. Current localization-based systems...
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Non-toxic fluorine-doped TiO2 nanocrystals from TiOF2 for facet-dependent naproxen degradation
PublicationIn the present study, the photocatalytic degradation of naproxen (NPX), which is a nonsteroidal anti-inflammatory drug (NSAID), frequently detected in drinking water, was investigated. The F-doped TiO2 with defined morphology was successfully obtained from TiOF2 and applied for photocatalytic degradation under UV-vis and visible light. All samples were characterised by X-ray diffraction, scanning electron microscopy, X-ray photoelectron...
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Structural and luminescence properties of B2O3-Bi2O3-AlF3 glass doped with Eu3+, Tb3+ and Tm3+ ions
PublicationThe B2O3-Bi2O3-AlF3 glass system doped with Eu3+, Tb3+, Tm3+ and triply doped with Eu3+/Tm3+/Tb3+ ions in different molar ratios were successfully synthesized. Glass transition and crystallization temperatures were examined by Differential Scanning Calorimetry (DSC) measurements. X-ray Diffraction (XRD) confirmed the amorphous character of the samples. Fourier Transform Infrared Spectroscopy (FTIR) revealed that the glass matrix...
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Syntheses, Structures and Reactivity of Terminal Phosphido Complexes of Iron(II) Supported by a β-Diketiminato Ligand
PublicationWe report the synthesis of the first series of terminal phosphido iron complexes supported by a β‐diketiminato ligand (Dippnacnac) and their catalytic activity in dehydrocoupling of secondary phosphines. Anionic and neutral mono‐ or diphosphido complexes were obtained from the reaction of [(Dippnacnac)FeCl2Li(dme)2] with the R2PLi (R = iPr, tBu, Cy, Ph) phosphides by tuning the stoichiometric ratio, polarity of the solvent, and...
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Study on 19th-century cast iron columns from the former financial office building in Kwidzyn
PublicationThe article presents the results for cast iron columns used as floor supports in the former financial office building in Kwidzyn (Poland).The stocktaking drawings provided the general and detailed data about the 19th century designer’s decisions. During the research, architectural and structural analysis was carried out. The graphics were used as a starting material for preparing 3D calculation models. The FEM-based numerical simulations...
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Machine Learning Applied to Aspirated and Non-Aspirated Allophone Classification—An Approach Based on Audio "Fingerprinting"
PublicationThe purpose of this study is to involve both Convolutional Neural Networks and a typical learning algorithm in the allophone classification process. A list of words including aspirated and non-aspirated allophones pronounced by native and non-native English speakers is recorded and then edited and analyzed. Allophones extracted from English speakers’ recordings are presented in the form of two-dimensional spectrogram images and...
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Evaluation of the use of reindeer droppings for monitoring essential and non-essential elements in the polar terrestrial environment
PublicationExcess or toxic metals, non-metals and metalloids can be eliminated from the organism by deposition in inert tissue (e.g. fur) or excretion with body secretions, urine and faeces. Droppings are one of the main routes for the elimination of multiple elements and they can be collected without direct contact with the animal. Contaminant concentration has been examined in non-lethally collected tissues of several species (especially...
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Odpowiedź na zarzuty Pozwanego w związku z wykonaną opinią (1/IWN/2018)
PublicationDokument zawiera odpowiedzi na pytania strony pozwanej dotyczące wpływu transportu, rozpakowania, sposoby wykonania linii kablowej, diagnozowania linii kablowej, prac naprawczych na poziom uszkodzeń powłoki zewnętrznej.
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Improved Performance of 1-Ethyl-3-Methylimidazolium Tetrafluoroborate at Steel/HCl Interface by Iodide Ions
PublicationThe corrosion and corrosion inhibition of St37 steel in 0.1 M HCl solution by 1-ethyl-3-methylimidazolium tetrafluoroborate (EMITFB) and the effect of addition of KI on the inhibitive performance of EMITFB have been examined by electrochemical [electrochemical impedance spectroscopy, potentiodynamic polarization, and dynamic electrochemical impedance spectroscopy (DEIS)] and surface examination [scanning electron microscope (SEM)...
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Studies on Silver Ions Releasing Processes and Mechanical Properties of Surface-Modified Titanium Alloy Implants
PublicationDispersed silver nanoparticles (AgNPs) on the surface of titanium alloy (Ti6Al4V) and titanium alloy modified by titania nanotube layer (Ti6Al4V/TNT) substrates were produced by the chemical vapor deposition method (CVD) using a novel precursor of the formula [Ag5(O2CC2F5)5(H2O)3]. The structure and volatile properties of this compound were determined using single crystal X-ray diffractometry, variable temperature IR spectrophotometry...
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Fluorine ions in photocatalysts’ synthesis: an obstacle or an ally? The investigation of photocatalysts in Ti-O-F system
PublicationTitanium(IV) oxide (TiO2) is one of the most promising photocatalysts, which is expected to be applied in the photocatalytic degradation of xenobiotics. For sustainable development and green chemistry approach recently, much effort has been paid to enhance TiO2 photocatalytic activity in UV-vis light by modifying its structure. The photocatalytic process’s complexity cannot be simply described as electron-hole pairs generations...
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The non-invasive evaluation of heart function in patients with an acute myocardial infarction: The role of impedance cardiography
PublicationBackground: The purpose of this study was to analyze hemodynamic changes in patients treated with percutaneous coronary intervention (PCI) at an early stage of acute myocardial infarction (AMI) and at one-month follow-up. Methods: Patients with AMI (n = 27) who underwent PCI were analyzed using impedance cardiography (ICG). ICG data were collected continuously (beat by beat) during the whole PCI procedure and thereafter at every...
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Multianalyte Calibration Methods for Potentiometric Integrated Sensors System for Determination of Ions Concentration in a Body Fluids
PublicationIn recent years, integration and miniaturization of ion-selective electrodes (ISEs) have brought many benefits resulting in the possibility of simultaneous determination of the ions concentration in a small sample volume. One of the key problems related to the preparation of integrated sensors systems (ISSs) is a calibration procedure due to the necessity to calibrate each particular sensor separately. The main aim of the research...
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ON ESTIMATION OF OCCUPANT SAFETY IN VEHICULAR CRASHES INTO ROADSIDE OBSTACLES USING NON-LINEAR DYNAMIC ANALYSIS
PublicationThe article describes a comparison of two general methods of occupants safety estimation based on a numerical examples. The so-called direct method is mainly based on the Head Injury Criterion of a crash test dummy in a vehicle with passive safety system while the indirect method uses a European standards approach to estimate impact severity level. Numerical simulations in LS-DYNA have been conducted.
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Effective degradation of sulfide ions and organic sulfides in cavitation-based Advanced Oxidation Processes (AOPs)
PublicationThe paper presents the results of investigations on the effectiveness and reaction rate constants of the oxidation of sulfide ions and organic sulfides in real industrial effluents from the production of bitumens (2000 mg S2- L-1) using hydrodynamic and acoustic cavitation. The content of the effluents was analysed in terms carbon disulfide, dimethyl sulfide, and di-tert-butyl disulfide concentration. A possibility of complete...
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NON-LINEAR MASTIC CHARACTERISTICS BASED ON THE MODIFIED MSCR (MULTIPLE STRESS CREEP RECOVERY) TEST
PublicationMastic containing asphalt in its composition is an example of a viscoelastic material. It is an effective binder in asphalt. It consists of a filler (<0.063 mm) and asphalt mixed in the right proportions. Just like in asphalt, its response depends on the temperature level, the load and stress time. Changing the stress stiffness of the mastic affects the non-linear course of the stress-strain relationship. Modelling of the non-linear...
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An Extended Control of the Input Angle for Matrix Converters Connected with the Non-Unity Power Factor Loads.
PublicationThis paper proposes a novel PWM modulation algorithm for Multiphase Conventional Matrix Converters (MCMC), with 3 inputs and k outputs, using the transfer function of the load angle. The proposed approach extends the range of power angle control at the input during the operation with a maximum voltage transfer ratio. The proposed concept is based on the Direct Analytic Voltage PWM (DAV--PWM) modulation with an elliptical trajectory...
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Collision‐Aware Routing Using Multi‐Objective Seagull Optimization Algorithm for WSN‐Based IoT
PublicationIn recent trends, wireless sensor networks (WSNs) have become popular because of their cost, simple structure, reliability, and developments in the communication field. The Internet of Things (IoT) refers to the interconnection of everyday objects and sharing of information through the Internet. Congestion in networks leads to transmission delays and packet loss and causes wastage of time and energy on recovery. The routing protocols...
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Study of Non-Newtonian biomagnetic blood flow in a stenosed bifurcated artery having elastic walls
PublicationFluid structure interaction (FSI) gained attention of researchers and scientist due to its applications in science felds like biomedical engineering, mechanical engineering etc. One of the major application in FSI is to study elastic wall behavior of stenotic arteries. In this paper we discussed an incompressible Non-Newtonian blood fow analysis in an elastic bifurcated artery. A magnetic feld is applied along x direction. For...
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Influence of plasmon resonance on the luminescence of titanium dioxide thin films doped with rare earth ions
PublicationIn this work the study of the optical properties of europium doped titanium dioxide thin films (TiO2:Eu) enhanced by gold plasmonic nanostructures are presented. Plasmonic platforms were manufactured by thermal annealing of thin film of Au, deposited on a Corning glass substrate. As a result of thermal treatment, gold spherical nanostructures with average dimensions of 50 nm were obtained. Luminescent TiO2:Eu film was deposited...
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From the pills to environment – Prediction and tracking of non-steroidal anti-inflammatory drug concentrations in wastewater
PublicationThe extend of environment pollution by pharmaceuticals is in a stage that required more automatic and integrated solutions. The non-steroidal anti-inflammatory drugs (NSAIDs) are one of the most popular pharmaceutical in the world and emerging pollutants of natural waters. The aim of the paper was to check the correlation of the sales data of selected NSAIDs (ibuprofen, naproxen, diclofenac) and their concentration in the WWTP...
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Non-Linear Analysis of Structures Utilizing Load-Discretization of Stiffness Matrix Method with Coordinate Update
PublicationThis paper proposes a stiffness method based structural analysis algorithm for geometrically non-linear structures. In this study, the applied load on the joints has been discretized to a sequence of a few loadings applied. Each loading step produces incremental external nodal displacements, which are added to the corresponding coordinates to get a new geometrical shape of the structure. This process is iteratively repeated until...
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Tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels for non-enzymatic glucose sensing
PublicationIn this work, tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels were prepared via the sol–gel synthesis method with subsequent ball-milling fragmentation. The prepared samples were evaluated as glucose–sensing catalyst. The reference MnCo2O4 spinel exhibited a sensitivity of 49 µA mM−1 cm−2 and a nonlinearity error of 5.2% in the response range from 0.02 to 1 mM. The partial substitution of cobalt in the reference...
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Load path sensitivity and multiaxial fatigue life prediction of metals under non-proportional loadings
PublicationEngineering components often operate under complex loadings, in which the variable amplitude multiaxial stresses are raised by geometric discontinuities including holes, grooves, fillets and shoulders, etc. Besides, the non-proportional loading will lead to the rotation of maximum principal stress/strain and additional fatigue damage of structural elements in service. Consequently, the multiaxial and non-proportional loading have...
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Bridge Non-Destructive Measurements Using a Laser Scanning during Acceptance Testing: Case Study
PublicationOwing to the recent proliferation of inventory works on roads and railways, bridge acceptance tests have increased exponentially. These tests’ results are often misinterpreted owing to the use of various measuring equipment types, rendering integrated interpretation problematic. It is also problematic that adjusting the measurement method is difficult when the structure’s response to load is uncertain. Therefore, it is important...
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A non-adiabatic wavepacket dynamical study of the low energy chargetransfer process in the S3+ + H collision
PublicationThe collisional system S3+ + H?S2+ + H+ has been studied using a time-dependent wavepacket methodologyin two-dimensions. Using available potential energy surfaces and coupling matrix elementsobtained from multireference ab initio calculations, five non-adiabatically coupled electronic states of1P symmetry have been included in the dynamical simulations. The collision has been studied in thelow energy regime of 1-10 eV. The wavepacket...
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Balance errors generated by numerical diffusion in the solution of non-linear open channel flow equations
PublicationThe paper concerns the untypical aspect of application of the dissipative numerical methods to solve nonlinear hyperbolic partial differential equations used in open channel hydraulics. It is shown that in some cases the numerical diffusion generated by the applied method of solution produces not only inaccurate solution but as well as a balance error. This error may occur even for an equation written in the conservative form not...
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Investigations of shear localization during granular silo flow with non-local hypoplastic Constitutive Model
PublicationW artykule przedstawiono wyniki numerycznej analizy lokalizacji odkształceń w materiałach granulowanych podczas przepływu w silosach. Obliczenia wykonano przy zastosowaniu metody elementów skończonych w podejściu ALE i mikropolarnego modelu hipoplastycznego. Pokazano wpływ szorstkości ścian silosu i zagęszczenia materiału sypkiego na typ lokalizacji.
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Modeling of shear localization during confined granular flow in silos within non-local hypoplasticity.
PublicationW artykule przedstawiono wyniki numerycznej analizy lokalizacji odkształceń w materiałach granulowanych podczas przepływu w silosach. Obliczenia wykonano przy zastosowaniu metody elementów skończonych i mikropolarnego modelu hipoplastycznego. Zastosowano podejście ALE. Pokazano wpływ szorstkości ścian silosu i zagęszczenia materiału sypkiego na typ lokalizacji.
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An elasto-plastic constitutive model with non-local softening and viscosity to describe dynamic concrete behaviour.
PublicationW artykule zaproponowano model do opisu betonu podczas dynamicznego obciążenia. Przyjęto model sprężysto-plastyczny z degradacją sztywności i nielokalnym osłabieniem rozszerzony o lepkość. Obliczenia MES dla elementów betonowych pod obciążeniem dynamicznym o różnej prędkości obciążenia porównano z doświadczeniami.
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Buckling resistance of a metal column in a corrugated sheet silo - experiments and non-linear stability calculations
PublicationThe results of experimental and numerical tests of a single corrugated sheet silo column’s buckling resistance are presented in this study. The experiments were performed in a real silo with and without bulk solid (wheat). A very positive impact of the bulk solid on the column buckling resistance occurred. The experimental results were first compared to the buckling resistance calculated by Eurocode 3 formulae. The comparison revealed that...
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FE-investigations on crack spacing in reinforced concrete beams within non-local continuum mechanics.
PublicationW artykule przedstawiono wyniki numerycznej analizy rozstawu rys w belkach żelbetowych przy zastosowaniu dwóch ciągłych modeli nielokalnych. Zbadano wpływ wielu różnych parametrów na rozstaw rys.
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Comparative FE-studies of shear localizations in granular bodies within a polar and non-local hypoplasticity.
PublicationW artykule przedstawiono wyniki porównawczej numerycznej analizy lokalizacji odkształceń stycznych w materiałach granulownych przeprowadzonej z nielokalnym i mikropolarnym modelem. Obliczenia wykonano dla ściskania w płaskim stanie odkształcenia stosując metodę elementów skończonych i hipoplastyczne prawo konstytutywne. Analizę przeprowdzonao dla piasku zagęszczonego.
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Die rolle von Chats/Diskussionsforen im eLearning an einem praktischen Bespiel, Die rolle von Chats/Diskussionsforen im eLearning an einem praktischen Bespiel. A practical example of the role of chatrooms/discussion forums in e-learning.
Publication.
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Oxidative Dimerisierung von Phosphanen und Hinweise auf das intermediare Auftreten des Phosphinophosphinidens tBu2P-P in Reaktionen von [(eta^5^-C5H5)2TiCl2] und [(eta^5^-C5H5)(eta^5^-C5Me5)TiCl2] mit tBu2P-P(SiMe3)Li und tBu2P-P(Li)-P-tBu2. Bildung von Titan(III)- Fulvalen-Komplexen.
PublicationReakcja dichlorku tytanocenu z tBu2P-P(Li)-P-tBu2 albo tBu2P-P(SiMe3)Li prowadzi do kompleksów Ti(III). Jednocześnie grupy fosfanowe dimeryzują dając (tBu2P)2P-P(P-tBu2)2 lub (tBu2P-PSiMe3)2. Znaleźliśmy produkty, które sugerują przejściowe występowanie tBu2P-P.