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Wyniki wyszukiwania dla: visible light photocatalysis
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Strategie rozwoju byłych miast wojewódzkich w Polsce Wschodniej
PublikacjaPrzedmiotem opracowania są strategie rozwoju 9 miast należących do najsilniejszych ośrodków poza obecnymi miastami wojewódzkimi w najsłabiej rozwiniętych polskich regionach. Miasta te mogą dawać szansę aktywizacji swojego otoczenia. Przyczynić się do tego mogą dobre strategie zwiększające konkurencyjność miast i pobudzające rozwój. Celem badań było uzyskanie odpowiedzi na pytania, czy i w jakim stopniu badane strategie: (1) zgodne...
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"Raport z wstępnych badań własności stali trudnościeralnej 460HB",. ang "Report on preliminary tests of the properties of wear-resistant steel 460HB"
PublikacjaMikrostrukturę badanej stali trudnościeralnej 460HB stanowi drobnoziarnisty martenzyt odpuszczony, który jest właściwy dla stali konstrukcyjnych niskowęglowych, niskostopowych ulepszonych cieplnie. W przypadku blach grubych, do których zalicza się badana stal, struktura może ulec zaburzeniu, jeżeli w hutniczym procesie wytwórczym wystąpiła niejednorodność odkształcenia plastycznego i w konsekwencji tworzenie się pasm segregacyjnych,...
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The Impact of Long-Time Chemical Bonds in Mineral-Cement-Emulsion Mixtures on Stiffness Modulus
PublikacjaDeep cold in-place recycling is the most popular method of reuse of existing old and deteriorated asphalt layers of road pavements. In Poland, in most cases, the Mineral-Cement-Emulsion mixture technology is used, but there are also applications combining foamed bitumen and cement. Mineral-Cement-Emulsion mixtures contain two different binding agents – cement as well as asphalt from the asphalt emulsion. Asphalt creates asphalt...
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Artificial Intelligence Aided Architectural Design
PublikacjaTools and methods used by architects always had an impact on the way building were designed. With the change in design methods and new approaches towards creation process, they became more than ever before crucial elements of the creation process. The automation of architects work has started with computational functions that were introduced to traditional computer-aided design tools. Nowadays architects tend to use specified tools...
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Thermal Transitions and Structural Characteristics of Poly(3,4-ethylenedioxythiophene/cucurbit[7]uril) Polypseudorotaxane and Polyrotaxane Thin Films
PublikacjaHerein, we report the thermal transitions and structural properties of poly(3,4-ethylenedioxythiophene/cucurbit[7]uril) pseudopolyrotaxane (PEDOT∙CB7-PS) and polyrotaxane (PEDOT∙CB7-PR) thin films compared with those of pristine PEDOT. The structural characteristics were investigated by using variable-temperature spectroscopic ellipsometry (VTSE), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force...
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Optical and electrical properties of boron doped diamond thin conductive films deposited on fused silica glass substrates
PublikacjaThis paper presents boron-doped diamond (BDD) film as a conductive coating for optical and electronic purposes. Seeding and growth processes of thin diamond films on fused silica have been investigated. Growth processes of thin diamond films on fused silica were investigated at various boron doping level and methane admixture. Two step pre-treatment procedure of fused silica substrate was applied to achieve high seeding density....
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Processing, physico-mechanical and thermal properties of reclaimed GTR and NBR/reclaimed GTR blends as function of various additives
PublikacjaIn this work, ground tire rubber (GTR) was mechano-chemically reclaimed in the presence of bitumen and various additives. During studies three types of processing and curing additives: (i) peptizer P300; (ii) vulcanization accelerator tetramethylthiuram disulfide (TMTD) and (iii) organic peroxide di(2-tert-butyl-peroxyisopropyl)benzene (BIB1) were applied to enhance reclaiming of GTR. Reclaiming process was evaluated by oscillating...
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Assessing Roadside Hybrid Energy Absorbers Using the Example of SafeEnd
PublikacjaA combination of crash cushion and end-terminal, hybrid energy absorbing devices have been in use worldwide for a few years already. They include SafeEnd, a system Poland has recently introduced. Some road authorities have raised concerns as regards the operating conditions of the devices and how they work together with safety barriers. The objective of this research is to clarify the concerns and answer the following questions:...
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Exploring multi-step glucose oxidation kinetics at GOx-functionalized nanotextured gold surfaces with differential impedimetric technique
PublikacjaFor a few past years, we can observe the enormous growth of investigations related to ultrasensitive electrochemical sensors capable of reliable determination of important body parameters and analytes. Utilized procedures rely on standard electrochemical methods, demanding electrode polarization, and information about the initial characteristics of the working electrode. More and more complex electrode materials are characterized...
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Improved Empirical Coefficients for Estimating Water Vapor Weighted Mean Temperature over Europe for GNSS Applications
PublikacjaDevelopment of the so-called global navigation satellite system (GNSS) meteorology is based on the possibility of determining a precipitable water vapor (PWV) from a GNSS zenith wet delay (ZWD). Conversion of ZWD to the PWV requires application of water vapor weighted mean temperature (Tm) measurements, which can be done using a surface temperature (Ts) and its linear dependency to the Tm. In this study we analyzed up to 24 years...
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The Proposal to “Snapshot” Raim Method for Gnss Vessel Receivers Working in Poor Space Segment Geometry
PublikacjaNowadays, we can observe an increase in research on the use of small unmanned autonomous vessel (SUAV) to patrol and guiding critical areas including harbours. The proposal to “snapshot” RAIM (Receiver Autonomous Integrity Monitoring) method for GNSS receivers mounted on SUAV operating in poor space segment geometry is presented in the paper. Existing “snapshot” RAIM methods and algorithms which are used in practical applications...
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Tuning of photocatalytic activity by creating a tridentate coordination sphere for palladium
PublikacjaThe synthesis and characterisation of an asymmetric potential bridging ligand bmptpphz (bmptpphz = 2,17-bis(4-methoxyphenyl)tetrapyrido[3,2-a:2’,3’-c:3’’,2’’-h:2’’’,3’’’-j] phenazine) is presented. This ligand contains a 1,10-phenanthroline (phen) and a 2,9-disubstituted phen sphere and possesses a strong absorbance in the visible. Facile coordination of the phen sphere to a Ru(tbbpy)2 core leads to Ru(bmptpphz) ([(tbbpy)2Ru(bmptpphz)](PF6)2;...
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Sensitive method for determination of benzoic acid in beverages and food samples using air–assisted hydrophobic deep eutectic solvent-based dispersive liquid-liquid microextraction
PublikacjaA simple, reliable and rapid air–assisted hydrophobic deep eutectic solvent-based dispersive liquid–liquid microextraction (AA-HDES-DLLME) was developed for analysis of benzoic acid in various beverages and food samples. The final determination stage was performed via UV–visible spectrophotometry. The key parameters (extraction time, HDES type and volume, dispersant volume, pH and sample volume) of the AA-HDES-DLLME method were...
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Correlations of structural, thermal and electrical properties of sodium doped complex borophosphosilicate glass
PublikacjaBorophosphosilicate glasses with varying sodium ion concentrations were investigated for their, structural, thermal, and electrical properties. All the obtained glasses were transparent except the glass with the highest sodium content, which exhibited translucency due to inhomogeneities. Increasing sodium content led to reduced boron and silicon content while maintaining a constant B/Si ratio, indicating progressive depolymerization...
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Structural, optical and electrochemical performance of black phosphorus and black arsenic-phosphorus nanostructures
PublikacjaBlack phosphorus (BP)-based nanostructures have drawn a lot of attention due to their tunable bandgap and extraordinary properties such as: high surface-to-volume ratio, large number of active sites, and prominent edges. However, low dimensional structures of black phosphorus oxidize easily, which hamper their application on a broader scale. One way to overcome these difficulties is to modify the black phosphorus structure by substituting...
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MOF/TiO2 erythrocyte-like heterostructures decorated by noble metals for use in hydrogen photogeneration and pollutant photodegradation
PublikacjaVarious metal–organic framework (MOF)/TiO2 heterostructures can be obtained by the partial hydrolysis or calcination of Ti-based MOFs. By adjusting the hydrolysis and calcination steps of NH2-MIL-125 (Ti), a novel photoactive material composed of a MOF (NH2-MIL-125 (Ti)) and TiO2, with a unique “erythrocyte” shape, was developed. Furthermore, modification of the composition prepared by the partial hydrolysis of NH2- MIL-125 (Ti)...
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Ultrasound-Assisted Dispersive Liquid-Liquid Microextraction Using Deep Eutectic Solvents (DESs) for Neutral Red Dye Spectrophotometric Determination
PublikacjaDeep eutectic solvents (DES), which have low toxicity and are low cost, biodegradable, and easily synthesized, were used for the extraction of neutral red (NR) dye before its spectrophotometric analysis. DES, containing choline chloride as a hydrogen bond acceptor and phenol as a hydrogen bond donor with a molar ratio of 1:2, was used for the extraction of NR dye from aqueous media. The possible interaction of different DESs with...
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Two-photon perimetry utilizing picosecond laser
PublikacjaAge-related impairments are becoming more and more severe for aging societies. The sensory organ diseases are particularly troublesome as they exclude seniors from their everyday activity. Therefore, maintaining good quality eyesight is essential for normal functioning. New medical therapies help restrain age-related changes, but still, monitoring is essential to the treatment process. Humans do not have the natural ability to...
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Sperm segmentation and abnormalities detection during the ICSI procedure using machine learning algorithms
Publikacja(1) About 15-20% of couples struggle with the problem of infertility. 30 to 40% of these cases are caused by abnormalities in the structure and motility of sperm. Sometimes the only possibility for such people is to use the procedure of artificial insemination. CASA systems are used to increase the efficiency of this procedure by selecting the appropriate sperm cell. (2) This paper presents an approach to the sperm classification...
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Separation of toluene from gas phase using supported imidazolium ionic liquid membrane
PublikacjaInvestigation on utilization of supported ionic liquids membranes for hydrocarbon separation from the gas phase was performed. Properties of membrane phase, wettability of supports, swelling effects and solubility of toluene were taken into account. Toluene permeation rates were significantly higher than those of pure nitrogen, the selectivity in a range of 17–341 was satisfying for separation. Despite the increase of viscosity...
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Application of the Optimum Dataset Method in Archeological Studies on Barrows
PublikacjaLight Detection and Ranging (LiDAR) became one of the technologies used in archaeological research. It allows for relatively easy detection of archaeological sites that have their own field form, e.g.: barrows, fortresses, tracts, ancient fields [1]. As a result of the scanning, the so-called point cloud is obtained, often consisting of millions of points. Such large measurement datasets are very time-consuming and labor-intensive...
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Lighting education for architects, the barriers and challenges: a survey of architecture students
PublikacjaCreating a well-lit environment requires the understanding of daylight and electric lighting design principles within the built environment. Recent years have brought a large number of new lighting assessment and design methods. The discovery of new photoreceptor cells in the eye - photosensitive retinal ganglion cells - forced lighting researchers to focus on parametrisation for the image forming (IF) and non-image forming (NIF)...
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Origin of bitumen fractions in the Jurassic-early Cretaceous Vaca Muerta Formation in Argentina: insights from organic petrography and geochemical techniques
PublikacjaThis paper investigates chemical functional groups of the two extracted bitumen fractions in shales of the Jurassic to early Cretaceous Vaca Muerta Formation of the Neuquén Basin in Argentina, South America. The results indicate that Bitumen I is strongly aliphatic and appears to be genetically related to fluorescent amorphous organic matter. In contrast, Bitumen II consists of highly condensed, aromatic hydrocarbons, and has some...
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Comparison of Different Measurement Techniques as Methodology for Surveying and Monitoring Stainless Steel Chimneys
PublikacjaThe measurement of a chimney axis is an engineering geodesy task. These measurements allow to assess the technical condition of chimneys and are usually carried out for reinforced concrete chimneys. When measuring high chimneys, the main problem may be the need to go a long distance to take a measurement. The surface of the chimney can also be problematic because it can absorb so much light from the range finder that total station...
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Reduction of measurement data before Digital Terrain Model generation vs. DTM generalisation
PublikacjaModern data acquisition technologies provide large datasets that are not always necessary in its entirety to properly accomplish the goal of the study. In addition, such datasets are often cumbersome for rational processing, and their processing is time and labour consuming. Therefore, methods that enable to reduce the size of the measurement dataset, such as the generalization of the Digital Terrain Model (DTM) or the reduction...
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Intercultural interactions in multinational subsidiaries
PublikacjaPurpose - Our aim is to show how individuals perceive the quality of intercultural interactions at work in multinational subsidiaries, and to address the question of what actually prevails in their accounts, i.e. ‘the dark side’ or ‘the bright side’. Design/methodology/approach - We report the findings from five subsidiaries located in Poland and interviews with 68 employees of these companies. Findings - The ‘bright side’ dominated...
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Photoplethysmographic Time-Domain Heart Rate Measurement Algorithm for Resource-Constrained Wearable Devices and its Implementation
PublikacjaThis paper presents an algorithm for the measurement of the human heart rate, using photoplethysmography (PPG), i.e., the detection of the light at the skin surface. The signal from the PPG sensor is processed in time-domain; the peaks in the preprocessed and conditioned PPG waveform are detected by using a peak detection algorithm to find the heart rate in real time. Apart from the PPG sensor, the accelerometer is also used to...
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Core-Shell Nanoparticles with Hyperbranched Poly(arylene-oxindole) Interiors
PublikacjaCore-shell type star polymers composed of poly(tert-butyl acrylate) (poly(t-BuA)) arms and 100% hyperbranched poly(arylene-oxindole) interiors were synthesized via the "core-first" method. Atom transfer radical polymerization of t-BuA initiated by 2-bromopropionyl terminal groups of the hyperbranched core was applied for the synthesis of the stars. The resultant star structures were characterized by gel permeation chromatography...
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China and the Chinese in the modern world. An interdisciplinary study
PublikacjaThis monograph is a collection of chapters devoted to modern China on various approaches. There is no future without a past and a modern China is a country that skillfully combines the new with the old and the authors have attempted to present this phenomenon in this book. It brings to light issues such as a honorificativity in Chinese administrative and legal documents, a comparison of Chinese and...
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Zirconia ceramics with additions of Alumina for advanced tribological and biomedical applications
PublikacjaThe results of an investigation on slip cast and sintered Y2O3 (3 wt%)- stabilized ZrO2 with additions of 5, 10, 15 wt% Al2O3 are reported. The surface roughness, porosity and density of the samples were measured. The hardness HRc and Hv, fracture toughness K1C, and friction coefficients were also measured using standard methods. The structural properties of the samples were observed by Scanning Electron Microscopy (SEM). The surface...
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COMBINING FUNCTIONAL AND AESTHETIC ASPECTS OF DAYLIGHTING IN SUSTAINABLE ARCHITECTURE WITH THE USE OF DIGITAL DESIGN METHODS
PublikacjaThe aesthetics of modern architecture should relate to its origins and goals - the environment, function, sustainability and its users. One of the conditions that meet the criteria is the presence of daylight and the use of its potential. The contemporary digital tools that support the design process allow to controlling the use of difficult and capricious materials, such as daylight. They also combine daylighting aspects with...
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Thermal performance of a prototype plate heat exchanger with minichannels under boiling conditions
PublikacjaTo solve the problem and to meet the requirements of customers in the field of high heat fluxes transfer in compact units, a new design of plate heat exchanger with minichannels (minichannels PHE) was proposed. The aim was to construct a compact heat exchanger of high effectiveness for the purpose of household cogeneration ORC system. In this paper the experimental analysis of an assembled prototype of such compact heat exchanger...
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Prediction of Ship Resonant Rolling - Related Dangerous Zones with Regard to the Equivalent Metacentric Height Governing Natural Frequency of Roll
PublikacjaPotentially dangerous zones corresponding to dynamical stability phenomena, possibly encountered by ships sailing in rough sea, are estimated nowadays with the use of the method recommended by IMO in the guidance coded MSC.1/Circ.1228. In this IMO method the parameter governing the natural period of roll is the initial metacentric height. Some earlier studies revealed that the initial metacentric height...
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Mono- and bimetallic (Pt/Cu) titanium(IV) oxide photocatalysts. Physicochemical and photocatalytic data of magnetic nanocomposites’ shell
PublikacjaSurface modification of titania with noble and semi-noble metals resulted in significant enhancement of photocatalytic activity. Presented data, showing the photocatalytic properties of TiO2-M (where M is Pt and/or Cu) photocatalysts were further used as Fe3O4@SiO2/TiO2-M magnetic nanocomposites shells in "Mono- and bimetallic (Pt/Cu) titanium(IV) oxide core-shell photocatalysts with Vis light activity and magnetic separability"...
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Impact of Microphytobenthos Photosynthesis on the Characteristics of the Echo Signal from Baltic Sandy Sediments
PublikacjaThe understanding the influence of biological processes on the characteristics of the signals backscattered by the sea floor is crucial in the development of the hydroacoustical benthic habitat classification techniques. The impact of the microphytobenthos photosynthesis on the acoustical backscattering properties of the Atlantic sandy sediments was previously demonstrated by Holliday et al. (2004) and Wildman and Huettel (2012). To...
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Experimental Testing of Innovative Cold-Formed "GEB" Section / Badania Eksperymentalne Innowacyjnego Kształtownika Giętego Na Zimno Typu „Geb“
PublikacjaOne of the major advantages of light gauge steel structures made of cold-formed steel sections is their low weight, so manufacturers are increasingly using the possibilities of those sections for the production of typical single-storey steel structures systems. Well known profiles, such as Z, C and the so called hat sections that have been studied and described in the literature, are used mainly as purlins or truss components....
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The optimization of CuxO microwires synthesis for improvement in photoelectrochemical performance
PublikacjaOne of the most important challenges in the fabrication of CuxO microstructures via the electrochemical method is formation of long, regular and well-packed microwires with good adhesion on the Cu substrate and to achieve better photoelectrochemical properties, which can be potentially applied in solar-driven water splitting and CO2 conversion to light hydrocarbons. In this paper, Cu2O photoelectrode has been fabricated by direct...
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Sustainable Waste Management for Implementation of a Circular Economy Model in a Port
PublikacjaThe manuscript presents the management of waste from marine vessels and cargo handling companies in a selected European Union port. The main objective of the paper is to analyse and evaluate the existing waste management model in the port of Szczecin in the context of circular economy. The expert research carried out is aimed, inter alia, at identifying which of the solutions currently in use need to be improved from an environmental...
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Organic Vapor Sensing Mechanisms by Large-Area Graphene Back-Gated Field-Effect Transistors under UV Irradiation
PublikacjaThe gas sensing properties of graphene back-gated field-effect transistor (GFET) sensors toward acetonitrile, tetrahydrofuran, and chloroform vapors were investigated with the focus on unfolding possible gas detection mechanisms. The FET configuration of the sensor device enabled gate voltage tuning for enhanced measurements of changes in DC electrical characteristics. Electrical measurements were combined with a fluctuation-enhanced...
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Effect of Laser Treatment on Intrinsic Mechanical Stresses in Titanium and Some of Its Alloys
PublikacjaLaser surface treatment conducted at different power levels is an option to modify titanium bone implants to produce nano- and microtopography. However, such processing can lead to excess mechanical stress within the surface layer. This research aims to calculate the level of such residual stresses after the surface processing of Ti grade IV, Ti15Mo, and Ti6Al7Nb alloys with an Nd:YAG laser. Light and scanning electron microscopies...
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Structural and luminescence properties of B2O3-Bi2O3-AlF3 glass doped with Eu3+, Tb3+ and Tm3+ ions
PublikacjaThe B2O3-Bi2O3-AlF3 glass system doped with Eu3+, Tb3+, Tm3+ and triply doped with Eu3+/Tm3+/Tb3+ ions in different molar ratios were successfully synthesized. Glass transition and crystallization temperatures were examined by Differential Scanning Calorimetry (DSC) measurements. X-ray Diffraction (XRD) confirmed the amorphous character of the samples. Fourier Transform Infrared Spectroscopy (FTIR) revealed that the glass matrix...
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Connected early-career experiences of equality in academia during the pandemic and beyond: Our liminal journey
PublikacjaIn this paper, we draw on our subjective experiences as two female early-career academics during the global COVID-19 pandemic. While we acknowledge that the pandemic had negative implications for many female scholars due to compulsory telework or increased family responsibilities, we also want to shed light on the empowering experiences shaped by collegial support that became an important part of our pandemic story. We build on...
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Badania nośności na zginanie innowacyjnego kształtownika giętego na zimno typu GEB
PublikacjaLekkie konstrukcje metalowe wytwarzane z kształtowników giętych na zimno to jedna z najszybciej rozwijających się dyscyplin w zakresie budownictwa. Do niedawna profile gięte na zimno stosowano wyłącznie jako elementy drugorzędne, czyli płatwie oraz rygle. Nowo opatentowany przekrój typu GEB ma być wykorzystywany jako element nośny konstrukcji ramowych. Jednak jego zaistnienie na rynku budowlanych konstrukcji metalowych jest uwarunkowane...
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Kinetics study of the fully bio-based poly(propylene succinate) synthesis. Functional group approach
PublikacjaCurrently, the increasing importance of the bio-based chemical compounds development is visible in the polymer chemistry, chemical engineering and materials science. It is well-known that the various purity level and different contaminants characterize petrochemical-based compounds compared to their biobased counterparts. Therefore, it is necessary to find out the contaminants impact on the bio-based monomers synthesis. One of...
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Context sensitive privacy management in a distributed environment
PublikacjaArtykuł przedstawia mechanizm zarządzania prywatnością stworzony dla systemu rozproszonego z założeniem, że węzły systemu mają ograniczone zasoby (moc procesora, pamięć). Podstawowy pomysł zakłada, że prywatne dane są filtrowane zgodnie z polityką prywatności użytkowników przed ich ujawnieniem innym użytkownikom. Te decyzje są silnie umiejscowione, co ogranicza narzut związany z zarządzaniem prywatnością na węzłach systemu. Sam...
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Evaluation of the photoprotective effect of β-cyclodextrin on the emission of volatile degradation products of ranitidine
PublikacjaThe process of the photo-excitation of ranitidine hydrochloride (RAN) in a solid state makes visible changes to its colour and generates an unpleasant odour. The purpose of the present study was to observe the protective effects of ˇ-cyclodextrin (CD) complexation as well as the effect of the mixture of two stoichiometries 1:1 and 1:2 (RAN:CD, IC) on the photostability of samples in a solid state. Samples of inclusion complexes...
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Fatigue and Professional Burnout in Police Officers and Firefighters
PublikacjaExcessive demands, work overload and the working time arrangements are an important cause of burnout and fatigue in employees. Specific working time arrangements are characteristic of the internal security services, such as police officers and firefighters. This applies to both the ordering of day and night shifts and the length of shifts. Depletion of personal resources is a common component for acute fatigue and burnout. However,...
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“Shadow” vs. “Phase 3D” method within endoscopic examinations of marine engines
PublikacjaA visual investigation of surfaces creating internal, working spaces of marine combustion engines by means of specialized view-finders so called endoscopes is at present almost a basic method of technical diag-nostics. The surface structure of constructional material is visible during investigations like through the magnifying glass (usually with a precisely determined magnification), which makes possible a detection, recognition...
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Behaviour of asymmetric structures with base isolation made of Polymeric Bearings
PublikacjaEarthquake-induced ground motions are the most severe and unpredictable threats to the structures all around the world. Seismic excitations cause a lot of damage in a wide variety of ways, leaving thousands of casualties in their wake. During the last few years alone, the world has witnessed many major earthquakes, five of which have caused far-reaching consequences of a national scale for Haiti (January 2010), Chile (February...
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Evaluation of the photoprotective effect of ˇ-cyclodextrin on the emission of volatile degradation products of ranitidine
PublikacjaThe process of the photo-excitation of ranitidine hydrochloride (RAN) in a solid state makes visible changes to its colour and generates an unpleasant odour. The purpose of the present study was to observe the protective effects of ˇ-cyclodextrin (CD) complexation as well as the effect of the mixture of two stoichiometries 1:1 and 1:2 (RAN:CD, IC) on the photostability of samples in a solid state. Sam- ples of inclusion complexes...