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Wyniki wyszukiwania dla: IMPEDANCE MEASUREMENTS
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Linearization in impedance measurements
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Impulse Impedance Measurements of Lightning Protection Earthings
PublikacjaLightning protection earthing systems should be tested at currents with time parameters similar to those of lightnings. A method and definition of a measured value of impulse impedance are introduced. The impulse impedance was determined by a quotient of voltage drop on the tested earthing to a value of current in measure circuit. The usefulness of the impulse method for lightning protection evaluation is tested on radio base stations...
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Impedance measurements of coating properties on bridge structures
PublikacjaPomiary impedancyjne pozwalają na prostą ocenę właściwości ochronnych powłok ochronnych i wykładzin. Pomiary stosuje się w celu porównania powłok, monitorowania ich właściwości i oceny mechanizmu działania. Metodyka jest z powodzeniem stosowana w pomiarach laboratoryjnych. Pomiary terenowe są bardziej skomplikowane ponieważ wymagają w pełni kontrolowanych komputerowo przyrządów, kontroli warunków pogodowych oraz wielu innych parametrów...
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Impedance measurements of skin layered structure for burns determination.
PublikacjaW pracy analizowany jest dwuwarstwowy model skóry. Pokazano, że za pomocą wielokrotnych pomiarów immitancyjnych jest możliwe wyznaczenia zarówno parametrów elektrycznych oparzonej skóry jak i geometrycznych. Przedstawiono algorytm estymacji i procedurę pomiarową wyżej wymienionych parametrów.
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Monitoring of breast tissue thermo-ablation by means of impedance measurements
PublikacjaW pracy przedstawiono rozważania dotyczące monitorowania jakości termoablacji zmian nowotworowych w piersi przy pomocy pomiarów impedancyjnych. Pokazano prototypowe konstrukcje sond do termoablacji jak również zaprezentowano wyniki symulacji i pierwszych eksperymentów. A usefulness of a developed probe combining power delivery to ablated breast tumour and simultaneous impedance measurements is discussed in the paper. It consists...
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Impedancyjne badanie korozji wżerowej. Impedance measurements of pitting corrosion
PublikacjaKryteria zachodzenia korozji wżerowej związane są z badaniami tego zjawiska metodą cyklicznej polaryzacji i opierają się na wartości gęstości prądu lub bezwzględnej wartości prądu płynącego w układzie. Na podstawie przeglądu literaturowego wybrano cztery kryteria stosowane przy badaniu stali stopowych metodą cyklicznej polaryzacji. Dla warunków prądowych odpowiadających kryteriom zachodzenia korozji wżerowej przedstawiono widma...
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Optimization of impedance measurements using ‘chirp’ type perturbation signal
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The application of impedance measurements for the determination of the probability of the course of corrosion processes
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Optimization of impedance measurements using ''chirp'' type perturbation signal
PublikacjaW pracy przedstawiono innowacyjny sposób pomiaru impedancji przy użyciu sygnału niestacjonarnego "chirp". W procesie akwizycji pobudzenia i odpowiedzi prądowej zastosowano zmienną częstotliwość próbkowania. Podejście takie pozwala zarówno na wielokrotne zmniejszenie ilości niezbędnych do otrzymania widma impedancyjnego rejestrowanych danych jak również upraszcza i przyspiesza proces obliczeniowy. Stwierdzono iż dokładność wyników...
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A telemedical and an outpatient thoracic impedance measurements - a validation algorithm of the electrodes placement
PublikacjaThis paper presents the algorithm for validation of electrodes locations for the thoracic impedance measurements. In particular the presented algorithm was designed to perform the telemetric sleep apnea monitoring. One of the problems, during the clinical tests of a developed device, was to preserve the repeatability of measurements. It strongly depended on the appropriate electrodes placement on the examined person’s thorax. It...
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Determination of time delay between ventricles contraction using impedance measurements
PublikacjaThe paper presents a novel approach to assessment of ventricular dyssynchrony basing on multichannel electrical impedance measurements. Using a proper placement of electrodes, the sensitivity approach allows estimating time difference between chambers contraction from over determined nonlinear system of equations. The theoretical considerations which include Finite Element Method simulations were verified using measurements on...
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Galvanostatic impedance measurements for the efficient adsorption isotherm construction in corrosion inhibitor studies
PublikacjaWe present an approach towards an accurate and time-efficient adsorption isotherm determination to evaluate the corrosion inhibitor interaction in electrolytic environments. The approach is based on dynamic impedance spectroscopy measurements in galvanostatic mode (g-DEIS). The studied corrosion inhibitor is continuously injected between the secondary cell and the corrosion cell. The efficiency corresponding to instantaneous inhibitor...
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Implementation and Validation of Multisinusoidal, Fast Impedance Measurements in Atomic Force Microscope Contact Mode.
PublikacjaThis study presents a novel approach to impedance measurements. The methodology discussed is limited to contact in the sample-probe system under ambient conditions without the presence of electrolyte. Comparison with results of direct and alternating current measurements for well-defined metallic surfaces are made. In spite of idealization related to the type of contact examined, the proposed technique provides an improvement of...
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Localized impedance measurements of AA2024 and AA2024-T3 performed by means of AFM in contact mode
PublikacjaPurpose: The purpose of this paper is to present the results of an atomic force microscopy (AFM) based approach to local impedance spectroscopy (LIS) measurement performed on AA2024 and AA2024-T3 aluminium alloys. Design/methodology/approach: AFM-LIS measurements were performed ex-situ without the electrolyte environment, so in fact the electrical not electrochemical impedance was obtained. Findings: Relative local impedance values...
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Dynamic impedance measurements of the Direct Methanol Fuel Cell cathode at various operating temperatures
PublikacjaThis article discusses the application of impedance analysis for diagnosing the cathode of a direct methanol fuel cell at various operating temperatures. The Dynamic Electrochemical Impedance Spectroscopy technique coupled with a linear current scan was applied for this purpose. This technique allowed the observation of changes in the cathode's properties in the fuel cell operating under real working conditions. An equivalent model...
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Localized impedance measurements of AA2024 and AA2024‐T3 performed by means of AFM in contact mode
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Implementation and Validation of Multisinusoidal, Fast Impedance Measurements in Atomic Force Microscope Contact Mode
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Optimization of the Relative Humidity of Reactant Gases in Hydrogen Fuel Cells Using Dynamic Impedance Measurements
PublikacjaWater management is a key factor affecting the efficiency of proton exchange membrane fuel cells (PEMFCs). The currently used monitoring methods of PEMFCs provide limited information about which processes or components that humidity has a significant impact upon. Herein, we propose the use of a novel approach of impedance measurements using a multi-sinusoidal perturbation signal, which enables impedance measurements under dynamic...
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The fixed state in impedance measurements of a two-step electrode reaction proceeding with accompanying adsorption of an intermediate product
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Reassesing whole tooth electrical impedance spectroscopy measurements
PublikacjaW pracy dokonano krytycznej oceny wyników wcześniejszych badań spektorskopowych zębów przeprowadzonych w innych ośrodkach i porównano je z własnymi. Wskazano na trudności występujące podczas pomiarów.
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Monitoring of CRT by means of impedance multiple measurements - simulation studies
PublikacjaCardiac resynchronization therapy (CRT) is a very promising treatment for patients with congestive heart failure. An Impedance Cardiography (ICG) is used for evaluation of heart mechanical activity. A simulation study with the use of a FEM model was performed. The developed realistic model of the thorax, based on CT data obtained from examination of a 68-year-old man, consisted of 212 000 tetrahedral elements. Different configurations...
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Corrosion rate measurements by non-linear electrochemical impedance spectroscopy
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Atomic force microscopy based approach to local impedance measurements of grain interiors and grain boundaries of sensitized AISI 304 stainless steel
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Atomic force microscopy based approach to local impedance measurements of grain interiors and grain boundaries of sensitized AISI 304 stanless steel
PublikacjaPraca prezentuje wyniki badań uzyskane z pomiarów techniką lokalnej spektroskopii impedancyjnej (LIS) wykonanych w trybie kontaktowym mikroskopii sił atomowych (AFM), które zostały przeprowadzone w lokalnych obszarach powierzchni ziarna austenitu i na granicy ziarna austenitu wysokostopowej stali austenitycznej AISI 304 poddanej procesowi uczulania oraz na próbkach odniesienia nie poddanych obróbce cieplnej.Badania LIS-AFM były...
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Dynamic elektrochemical impedance spectroscopy measurements of passive layer cracking under static tensile stresses.
PublikacjaDynamiczna elektrochemiczna spektroskopia impedancyjna umożliwia badanie podatności i odporności korozyjnej różnych materiałów konstrukcyjnych, a w szczególności określenie właściwości elektrochemicznych warstw pasywnych występujących na ich powierzchni. W wielu przypadkach pęknięcie warstwy pasywnej pod wpływem działania naprężeń rozciągających prowadzi do korozji naprężeniowej. Z tego względu badania pękania warstw pasywnych...
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Dynamic electrochemical impedance spectroscopy measurements of passive layer cracking under static tensile stresses.
PublikacjaDynamiczna Elektrochemiczna Spektroskopia Impedancyjna umożliwia badanie podatności i odporności korozyjnej różnych materiałów konstrukcyjnych, a w szczególności określenie właściwości elektrochemicznych warstw pasywnych występujących na ich powierzchni. W wielu przypadkach pęknięcie warstwy pasywnej pod wpływem działania naprężeń rozciągających prowadzi do korozji naprężeniowej. Z tego względu badania pękania warstw pasywnych...
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Dynamic electrochemical impedance spectroscopy measurements of passive layer cracking under static tensile stresses
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Simultaneous impedance and volumetric studies and additionally potentiodynamic polarization measurements of molasses as a carbon steel corrosion inhibitor in 1M hydrochloric acid solution
PublikacjaThe inhibition effect of molasses on the corrosion of low carbon steel in 1M hydrochloric acid solution was investigated by volumetric and electrochemical measurements. Potentiodynamic polarization and dynamic electrochemical impedance spectroscopy (DEIS) results were obtained and compared with to those, obtained with the hydrogen evolution technique. All results indicate that molasses functioned as a good inhibitor in 1M hydrochloric...
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Polynomial analysis as a new way of describing dynamic impedance spectra – Differential and relative impedance spectra
PublikacjaModel measurements of an equivalent electrical system were carried out using the technique of Dynamic Electrochemical Impedance Spectroscopy. The measurement took the form of potentiodynamic changes imposed on the tested system. Using the possibility of continuous impedance measurements, an attempt was made to develop an original and innovative method of analyzing impedance spectrograms, which is termed polynomial analysis. As...
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The Influence of Thin Gold Electrodes on the High-Temperature Impedance of Oxide Glasses
PublikacjaThe influence of thin gold electrodes on the electrical measurements of glasses at high temperatures was studied using impedance spectroscopy. The impedance was measured several times over a wide frequency range from 10 mHz to 1 MHz and the temperature ranged from 213 to 673 K under air and nitrogen atmospheres. The results showed a drop in the conductivity of more than an order of magnitude at a temperature around 603 K during...
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Assessment of organic coating degradation via local impedance imaging
PublikacjaThe paper presents a new approach to organic coating condition evaluation at micrometer scale using localized impedance measurements. It is based on atomic force microscopy (AFM) in contact mode. Impedance is measured between conductive AFM tip and metal substrate covered with organic coating. A single-frequency voltage perturbation signal is applied between the electrodes and current response signal is registered. As the tip is...
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Local electrochemical impedance spectroscopy in dynamic mode of galvanic coupling
PublikacjaA novel method that combines local electrochemical impedance spectroscopy and mapping in dynamicmode is proposed. Method was validated over two galvanic couplings, namely zinc/copper and cad-mium/copper. Impedance spectrum response for all measuring points was obtained by means ofsimultaneous implementation of selected range of frequencies. Proposed method allows the measure-ment in a more time-efficient manner, at the same time...
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Polynomial description of dynamic impedance spectrogram—introduction to a new impedance analysis method
PublikacjaThis paper presents a polynomial description of spectrograms obtained using Dynamic Electrochemical Impedance Spectroscopy. A method to fit the polynomial degree correctly is discussed. A simple electrical system of a diode connected in parallel with a capacitor was used for testing. Dynamic impedance measurements during potentiodynamic polarization were conducted. This paper presents an alternative analysis method that allows...
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Evaluation of the fast impedance spectroscopy method in the laboratory measurement system
PublikacjaIn this paper the method for fast impedancespectroscopy of technical objects with very high impedance(|Zx| ≥ 1 GΩ) is evaluated by means of simulation and practicalexperiment. The method is based on excitation of an object, witha square pulse and measurements of voltage and currentresponses with DAQ card. The object impedance spectrum isobtained with use of continuous Fourier transform. Someimprovements of the method concerned...
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Validation of dynamic electrochemical impedance spectrograms using autocorrelation function
PublikacjaValidation of impedance data is essential for checking the reliability of experimental data. Kramers – Kronig transformation is used to verify data obtained from classical Electrochemical Impedance Spectroscopy (EIS) measurements. Data obtained from Dynamic Electrochemical Impedance Spectroscopy (DEIS) could be validated in the same way, but in this case, there is no information about internal consistency between every single spectrum...
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Impedance of cation-coupled electron transfer reaction: Theoretical description of one pathway process
PublikacjaIt has been assumed that cation electron coupled charge transfer can be conducted in accordance with two mutually coupled reactions. Using a differential method an expression was introduced which describes the impedance of a cation electron coupled transfer reaction. Also, an electrical equivalent circuit has been defined. The total faradaic impedance is the sum of electron transfer impedance and cation transfer impedance. Issues...
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Application of different modes of nanoscale impedance microscopy in materials research
PublikacjaIn recent years, there is noticeable interest in application of various types of scanning probe microscopy in material science research. One of them is contact atomic force microscopy combined with local impedance measurements, known as nanoscale impedance microscopy. Literature references present its application in investigations of new materials, microelectronics diagnostics, or research of protective coatings performance. In...
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Study of Direct Methanol Fuel Cell Process Dynamics Using Dynamic Electrochemical Impedance Spectroscopy
PublikacjaA new technique, which was developed to characterize the direct methanol fuel cell under work conditions, has been presented in this paper. The impedance measurements were made using dynamic electrochemical impedance spectroscopy research technique in the galvanostatic mode, using multiple sinusoidal excitation. Obtained results show, that together with an increase of the temperature and working load, the global impedance...
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Instantaneous impedance monitoring of synergistic effect between cavitation erosion and corrosion processes
PublikacjaThe most common method of determination of cavitation erosion resistance as well as the magnitude of erosion-corrosion synergistic interaction is based on the weight loss measurements. Nondestructive characterization of installations elements is in most cases impossible to perform. Also, such a measurement does not include local types of failure or alteration of operating conditions. There is an urge to elaborate a method for monitoring...
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Nonlinear impedance in oxide glasses containing single and mixed alkali ions
PublikacjaThe aim of the present was to find more clues on the nonlinearities in impedance of oxide glasses. The first family of researched glasses has a composition of FeO-P2O5-Na2O. Oxide glasses containing iron and alkali are well known for a very low alkali ion mobility and may be considered purely polaron conducting. These glasses show no detectable nonlinearities in the impedance spectra. The second was a family of ionic conducting...
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An integral-differential method for impedance determination of the hydrogen oxidation process in the presence of carbon monoxide in the proton exchange membrane fuel cell
PublikacjaThe impedance of a proton exchange membrane fuel cell powered by hydrogen contaminated with carbon monoxide, ranging from 150 to 300 ppb, is measured and discussed. The tested range of CO concentration complied with the fuel standard specified in the ISO standards. Studies of influence of CO contamination on operation of PEMFC are crucial for further development and commercialization of fuel cells for automotive applications. Based...
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Nonlinear Impedance as Possible Result of Ion-Polaron Interaction in Cu2O-Al2O3-SiO2 Glass
PublikacjaNonlinear a.c. impedance measurements were performed in Cu2O-Al2O3-SiO2 glass in wide frequency range. The obtained results shows that a large nonlinearity in the impedance signal is observed at moderate electric fields of an order 1V/mm. The contents of the third harmonics reaches about 10% and strongly depends on temperature and frequency. The investigated glass exhibits mixed electronic-ionic conductivity. Electronic conduction...
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Electrical and mechanical characterization of two-phase alloys by means of scanning probe microscopy in dynamic impedance spectroscopy mode
PublikacjaDynamic impedance spectroscopy, evaluated for measuring non-stationary systems, was used in combination with scanning probe microscope. Using this approach, localized impedance measurements in the AFM contact mode could be carried out. Additionally, impedance–force curves were made at each phase of investigated materials to illustrate the relation between impedance and the force applied to a probe. Therefore, correlation of electrical...
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Impedance evaluation of coatings from biobased material
PublikacjaThe authors propose a modification of sodium caseinate edible coating for foodstuff protection. The aim was to improve the film’s barrier properties. It was achieved by the addition of propolis, which is a natural, environmentally friendly product known from its intrinsic sealing action. In the next step, propolis-admixed sodium caseinate films were exposed to elevated temperature for 10 min. This approach was meant to improve...
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Fault Loop Impedance Measurement in Circuits Fed by UPS and Principle of Safety Protection
PublikacjaThis paper indicates a significant problem of uncertainty of fault loop impedance (FLI) measurement in circuits powered from uninterruptible power supply (UPS) (double-conversion AC-DC-AC). The correctly determined value of this impedance, related to the short-circuit current disconnection time and to the reference value, is one of the most important elements that determines the approval of an electrical installation and its receivers...
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Novel fast non-linear electrochemical impedance method for corrosion investigations
PublikacjaThe paper presents a novel approach to corrosion rate monitoring using non-linear electrochemical impedance spectroscopy. The authors propose a new variant of non-linear impedance measurement using amplitude-modulated multi-frequency ac perturbation signal. It allows shortening of measurement duration so it is possible to monitor corrosion rate of the systems experiencing rapid changes. In this way a limitation resulting from lack...
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Time evolution of Electrochemical Impedance spectra of cathodically protected steel in artificial seawater
PublikacjaUsability of Electrochemical Impedance Spectroscopy data for better cathodic protection control was investigated. Carbon steel – S235JR2 grade specimen were exposed in artificial seawater environment. Samples were polarized and their potentials corresponded to four different cathodic protection degrees. Time evolution of Electrochemical Impedance spectra was investigated. Goodness of fit function (X2) was analysed in terms of proper...
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Application of galvanodynamic impedance spectroscopy for studying passive film cracking under mechanical strain
PublikacjaThe paper reports the results of simultaneous mechanical and electrochemical investigations on austenitic (18/8) stainless steel in a 2 % solution of sulphuric acid. The measurements were performed using Galvanodynamic Electrochemical Impedance Spectroscopy (GDEIS). Electrochemical analysis of mechanical passive layer cracking and repassivation conditions during a tensile test was carried out. Application of this methodology allowed...
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Local impedance imaging of boron-doped polycrystalline diamond thin films
PublikacjaLocal impedance imaging (LII) was used to visualise surficial deviations of AC impedances in polycrystalline boron-doped diamond (BDD). The BDD thin film electrodes were deposited onto the highly doped silicon substrates via microwave plasma-enhanced CVD. The studied boron dopant concentrations, controlled by the [B]/[C] ratio in plasma, ranged from 1 × 1016 to 2 × 1021 atoms cm−3. The BDD films displayed microcrystalline structure,...
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Evaluation of applicability of classic methods of a fault loop impedance measurement to circuits with residual current devices
PublikacjaMeasurement of fault loop impedance in low voltage grids and systems is in most cases performed to verify the effectiveness of protection against electric shock by automatic disconnection of supply. For the sake of measurement accuracy, it is advisable to perform it using large current. Unfortunately, in circuits with residual current devices which are very widely used nowadays, a large measurement current may trigger those devices...
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The influence of dynamic load changes on temporary impedance in hydrogen fuel cells, selection and validation of the electrical equivalent circuit
PublikacjaTo achieve optimal performance of a fuel cell, a reliable monitoring and diagnostic method is required. The currently utilized methods give limited information or they are impossible to use under dynamic working conditions. To obtain comprehensive information about the fuel cell operation we utilized novel dynamic electrochemical impedance spectroscopy. Impedance measurements in dynamic mode were performed on a hydrogen fuel cell,...
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Distribution of relaxation times as a method of separation and identification of complex processes measured by impedance spectroscopy
PublikacjaImpedance spectroscopy is one of the most commonly performed measurements to characterize electronic and electrochemical systems. Impedance spectra have limited resolution and many different processes may overlap what could be the reason of obstructions in its proper later analysis. Up to date, there are three approaches to solve this problem: examining impedance spectra itself, fitting spectra with equivalent circuits, and calculating...
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Comparison of road and laboratory measurements of tyre/road noise
PublikacjaTyre/road noise is one of the major environmental problems related to road traffic. There are several measuring methods of tyre/road noise that may be carried out on the road (for example Coast-down and Close Proximity Method) or in the laboratory (Drum Method). Road measurements are preferred for evaluations of pavement properties while laboratory methods are mostly used to evaluate tyres. One of the biggest problems associated...
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Electrochemical properties of porous Sr0.86Ti0.65Fe0.35O3 oxygen electrodes in solid oxide cells: Impedance study of symmetrical electrodes
PublikacjaThis work evaluates porous Sr0.86Ti0.65Fe0.35O3 (STF35) as a possible oxygen electrode material for Solid Oxide Cells. The powder synthesis was performed by solid state method. Characterization included DC electrical conductivity study of sintered bulk samples and impedance spectroscopy study of symmetrical electrodes deposited on gadolinium doped ceria substrates. Measurements were carried out in atmospheres with different pO2...
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Dynamic Electrochemical Impedance Spectroscopy (DEIS) as a Tool for Analyzing Surface Oxidation Processes on Boron-Doped Diamond Electrodes
PublikacjaSurface oxidation processes play a key role in understanding electrochemical properties of boron-doped diamond (BDD) electrodes. The type of surface termination groups, which create the potential window of electrolytic water stability or hydrophobicity, influences such properties. In this study the kinetics of oxidation process under anodic polarization were studied in situ by means of Dynamic Electrochemical Impedance Spectroscopy...
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Determination of pitting corrosion stage of stainless steel by galvanodynamic impedance spectroscopy
PublikacjaThis paper investigates the methodology for differentiation of multistep process of pitting corrosion of AISI 304 stainless steel in the environment of iron (III) chloride. Measurements were performed using Galvanodynamic Electrochemical Impedance Spectroscopy (GDEIS). Application of this methodology allowed monitoring of natural corrosion process without external current (IDC = 0A) nor potential perturbation of the system. Applied...
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The impedance of hydrogen oxidation reaction in a proton exchange membrane fuel cell in the presence of carbon monoxide in hydrogen stream
PublikacjaEvaluation of performance of a proton exchange membrane fuel cell, which is affected by carbon monoxide that pollutes the hydrogen stream, was presented. This influence was studied for carbon monoxide concentration of 125–325 ppb, which are close to values specified in ISO 14687:2019 standard. Performed studies provided crucial information for further development of fuel cell as an energy source for automotive application. Impedance...
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Implementation of DEIS for reliable fault monitoring and detection in PEMFC single cells and stacks
PublikacjaDynamic Electrochemical Impedance Spectroscopy (DEIS) was presented as novel method for diagnostic and monitoring of PEMFC stack and single cells operation. Impedance characteristics were obtained simultaneously with current - voltage characteristics for stack and each individual cell. Impedance measurements were performed in galvanodynamic mode. It allowed to compare performance of each cell and identification of faulty cell operation...
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In-situ and ex-situ resistance measurements of polypyrrole film using double-band electrode
PublikacjaMany in-situ techniques are performed in order to determine the resistance of conducting polymer film. However, the resistance measured in solution can be the combination of polymer resistance and that of other components, such as resistance of supporting electrolyte. Therefore, in this work, the influence of the solution on the resistance of polypyrrole (PPy) film has been studied. PPy film was electrchemically synthesized onto...
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Nonlinear and linear impedance of bismuth vanadate ceramics and its relation to structural properties
PublikacjaThe nonlinear and linear electrical properties, topography, and microstructure of bismuth-vanadate ceramics, were studied. The structurewas observed with the use of X-ray diffraction (XRD), scanning electronmicroscopy (SEM), atomic force microscopy (AFM) and confocal microscopy methods. The obtained results showed that ceramic is porous. Two phase transitionswere determinedwith the use of DSC measurements. The linear and nonlinear ac...
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Influence of vacuum sublimation deposited metal layer thickness on metrological parameters of the amperometric gas sensor with Nafion membrane
PublikacjaThe paper presents the results of investigation on an influence of vacuum sublimation deposited platinum layer thickness on the signal, sensitivity and response time of a prototype of sulphur dioxide sensor with Nafion membrane. The working electrode was made by vacuum sublimation deposition of platinum on a surface of Nafion membrane. Pt layers deposited changed an initial structure of Nafion membrane and that phenomenon was utilized...
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Local properties of organic coatings close to glass transition temperature
PublikacjaAcrylic coating applied on copper substrate has been investigated at different temperatures starting from the ambient one up to the level above the glass transition temperature. Its local topographic and electric properties have been examined with the atomic force microscopy (AFM) based approach including dc current mapping and local impedance spectroscopy. The local findings have been compared with the information from global...
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Influence of electropolymerization conditions on the morphological and electrical properties of PEDOT film
PublikacjaIn this work the effects of electropolymerization conditions on the morphological properties and conductivity of poly(3,4-ethylenedioxythiophene) (PEDOT) film have been studied. PEDOT films were electrochemically synthesized in a one step process from acetonitrile solution containing 3,4-ethylenedioxythiophene (EDOT) and lithium perchlorate. Based on atomic force microscopy, scanning electron microscopy, cyclic voltammetry and...
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Multifrequency Nanoscale Impedance Microscopy (m-NIM): A novel approach towards detection of selective and subtle modifications on the surface of polycrystalline boron-doped diamond electrodes
PublikacjaIn this paper, we describe the modification of Nanoscale Impedance Microscopy (NIM), namely, a combination of contact-mode atomic force microscopy with local impedance measurements. The postulated approach is based on the application of multifrequency voltage perturbation instead of standard frequency-by-frequency analysis, which among others offers more time-efficient and accurate determination of the resultant impedance spectra...
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Solid State Conductivity of Optimized Polypyrrole Coatings on Iron Obtained from Aqueous Sodium Salicylate Solution Determined by Impedance Spectroscopy
PublikacjaIn this work the optimization procedure for corrosion resistance, surface analysis and electrical properties of PPy-Fe electrodes have been examined. Polypyrrole (PPy) film was electrochemically synthesized in a one step process from an aqueous solution of sodium salicylate and pyrrole with certain concentrations, different parameters and type of polymerization...
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Adaptive estimation of the transformer stray capacitances for DC–DC converter modelling
PublikacjaNew low cost and accurate estimation method of transformer stray capacitances for wide band DC–DC converter modelling and design is proposed. The Wiener filter (WF) method is applied to estimate the transformer impedance – referred to the selected transformer winding configurations. Laboratory tests are used to adapt the filter, that is to find optimal impedance which minimises mean square error between measured, noise perturbed...
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Transient States during Short-circuit in a Line Powered by UPS and its Impact on Earth Fault Loop Impedance Measurement and Power Quality
PublikacjaThe short-circuit in a line powered by Uninterruptible Power Supply (UPS) during different UPS operation modes is presented in the article. The transient state condition related to the short-circuit in a line fed from double conversion On-line UPS is discussed in detail. The results of the measurements of earth fault loop impedance (FLI) in circuits powered by UPS with the instruments of various manufacturers are presented. The...
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Dynamic Nanoimpedance Characterization of the Atomic Force Microscope Tip-Surface Contact
PublikacjaNanoimpedance measurements, using the dynamic impedance spectroscopy technique, were carried out during loading and unloading force of a probe on three kinds of materials of different resistivity. These materials were: gold, boron-doped diamond, and AISI 304 stainless steel. Changes of impedance spectra versus applied force were registered and differences in the tip-to-sample contact character on each material were revealed. To...
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Evaluation of citric acid corrosion inhibition efficiency and passivation kinetics for aluminium alloys in alkaline media by means of dynamic impedance monitoring
PublikacjaA novel approach is proposed for constructing the adsorption isotherm in corrosion studies, based on a well-known interaction between citric acid and aluminium in alkaline electrolytes. Our approach utilizes the instantaneous impedance measurements via Dynamic Electrochemical Impedance Spectroscopy in galvanostatic mode (g-DEIS). Unlike other common tools, g-DEIS delivers exact information about the concentration required for full...
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The electrochemical impedance spectroscopy studies of the anode material based on polymer and starch derived ceramic for lithium ion batteries
PublikacjaThe anode materials derived of preceramic polymer poly(1,2-dimethylsilazane) (PSN) and starch was study. Commercially available polysilazane (poly(1,2-dimethylsilazane (PSN 2M01 Gelest) was mixed with commercially available starch (POCH Gliwice). The ratio polymer/starch (PSN/starch) was 1/1 or 3/7. The polysialazane/starch blend was cross-linked at 230 ºC for 2 h followed by heating to the final temperature (500 ºC, 700 ºC and...
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Termowizja jako narzędzie weryfikacji stanu elementów ochronnych SMD podczas badań udarowych
PublikacjaPrzedstawiono wyniki badań przyrostów temperatury rejestrowanych za pomocą kamery termowizyjnej ochronnych elementów SMD podczas wykonywania badań odporności na udary napięciowe wykonywane wg normy EN61000-4-5 dla różnych poziomów sprzężeń impedancyjnych
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Evaluation of organic coatings condition with AFM-based method
PublikacjaThe paper presents an atomic force microscopy (AFM)-based approach to evaluation of local protective properties of organic coatings. Apart from topography, it provides local ac and dc characteristics of examined coating. The method consists in application of ac voltage perturbation signal between conductive AFM tip and coated metal substrate. The resulting current is used to determine local impedance characteristics. Both impedance...
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Parametry uziemień przy przebiegach udarowych i wysokoczęstotliwościowych
PublikacjaW artykule skupiono się na porównaniu dwóch metod badania impedancji uziemienia odgromowego: udarowej z wysoką częstotliwościową. Zestawiono wyniki pomiarów istniejących uziemień z wynikami komputerowych obliczeń symulacyjnych przeprowadzonych w środowisku programu PSIM. Uzyskane wyniki wskazują na poprawność przyjętego toku modelowania, a uzyskane w ten sposób dane mogą być przydatne w fazie projektowania do szacowania...
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Electrical mapping of AISI 304 stainless steel subjected to intergranular corrosion performed by means of AFM-LIS in the contact mode
PublikacjaThe paper presents results of the AFM-based approach to local impedance spectroscopy (LIS) measurements performed in a 20 20 lm grid within an austenite grain–grain boundary region for sensitized AISI 304 stainless steel (SS). Maps of electrical parameters obtained on the basis of localized impedance spectra were demonstrated, presenting their changes and correlation with the sample topography. Performed research revealed significant...
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INFLUENCE OF BISMUTH CONTENT ON COMPLEX IMMITTANCE CHARACTERISTICS OF PRESSURELESS SINTERED BiNbO4 CERAMICS
PublikacjaGoal of the present research was to study immittance properties of BiNbO4 ceramics fabricated by the solid state reaction route followed by pressureless sintering. Four sets of samples were examined, namely the one fabricated from the stoichiometric mixture of oxides, viz. Bi2O3 and Nb2O5 as well as the ones with an excess of 3%, 5% and 10% by mole of Bi2O3. The immittance properties were studied by impedance spectroscopy. Measurements...
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Electromagnetic interference frequencies prediction model of flyback converter for snubber design
PublikacjaSnubber design for flyback converters usually requires experimental prototype measurements or simulation based on accurate and complex models. In this study simplified circuit modelling of a flyback converter has been described to dimension snubbers in early stage of design process. Simulation based prediction of the transistor and diode ringing frequencies has been validated by measurements in a prototype setup. In that way obtained...
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Development Of Dynamic Method For Evaluation Of Corrosion Rate On The Example Of Organic Corrosion İnhibitor
PublikacjaMeasurements of the corrosion rate belong to the most important aspects of materials science. In order to reduce material loss corrosion inhibitors are used. However selection of proper inhibitor should be based on evaluation of its mechanism and effective concentrations. Mechanism of inhibition usually has dynamic character so physicochemical parameters are changing in time. Most of actually used methods...
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Methodology of Selecting the Optimal Receptor to Create an Electrochemical Immunosensor for Equine Arteritis Virus Protein Detection
PublikacjaThe study reports a methodology of selecting the optimal receptor to create an electrochemical immunosensor for equine arteritis virus (EAV) protein detection. The detection was based on antigen recognition by antibodies immobilized on gold electrodes. Modification steps were controlled by electrochemical impedance spectroscopy and cyclic voltammetry measurements. In order to obtain the impedance immunosensor with the best parameters,...
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Assessment of copper surface coverage with corrosion inhibitor using AFM-based local electrical measurements
PublikacjaThe paper presents a new method of assessment of metal surface coverage with corrosion inhibitor and thus of inhibitor protective performance. It is based on the atomic force microscopy measurement performed in a contact mode. Apart from topography images the proposed approach allows acquisition of local DC maps and local electrical impedance spectra via application of DC bias voltage or AC perturbation signal between the conductive...
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Methodology of Selecting the Optimal Receptor to Create an Electrochemical Immunosensor for Equine Arteritis Virus Protein Detection
PublikacjaThe study reports a methodology of selecting the optimal receptor to create an electrochemical immunosensor for equine arteritis virus (EAV) protein detection. The detection was based on antigen recognition by antibodies immobilized on gold electrodes. Modification steps were controlled by electrochemical impedance spectroscopy and cyclic voltammetry measurements. In order to obtain the impedance immunosensor with the best parameters,...
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Performance of zinc-rich coatings evaluated using AFM-based electrical properties imaging
PublikacjaThe paper presents the results of investigation of polyvinyl zinc-rich coating exposed to 97% relativehumidity atmosphere for 40 days. Condition of the coating and evolution of its protective properties weredetermined with the novel AFM-based approach capable of providing surface profiles, local dc currentmaps as well as local impedance spectra. The proposed technique allowed insight into the local changesof coating topography...
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A novel concept for tissue-metal detection and differentiation using an inductive proximity sensor
PublikacjaIn this paper a novel application of inductive proximity sensors for detection of living tissue by means of measurements of the coil impedance changes at different frequencies is described. The mathematical analyses utilizing Bessel function estimation include detected object size and its distance from a sensor. The main aim of this study is to prove the possibility of distinguishing between metal objects and living tissues. The...
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Low temperature broad band dielectric spectroscopy of multiferroic Bi6Fe2Ti3O18 ceramics
PublikacjaIn the present research the tool of broadband dielectric spectroscopy was utilized to characterize dielectric behavior of Bi6Fe2Ti3O18 (BFTO) Aurivillius-type multiferroic ceramics. Dielectric response of BFTO ceramics was studied in the frequency domain (Δν=0.1Hz – 10MHz) within the temperature range ΔT=-100°C – 200°C. The Kramers-Kronig data validation test was employed to validate the impedance data measurements and it was found...
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Detection of the Plant Pathogen Pseudomonas Syringae pv. Lachrymans on Antibody-Modified Gold Electrodes by Electrochemical Impedance Spectroscopy
PublikacjaThe present work describes an impedimetric immunosensor for Pseudomonas syringae pv. lachrymans (Psl) detection. This pathogen infects many crop species causing considerable yield losses, thus fast and cheap detection method is in high demand. In the assay, the gold disc electrode was modified with 4-aminothiophenol (4-ATP), glutaraldehyde (GA), and anti-Psl antibodies, and free-sites were blocked with bovine serum albumin (BSA)....
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Assessment of protective properties of rubber lining in absorbers of flue gas desulphurization systems.
PublikacjaResults of research on degradation of rubber lining which is the main protection of absorbers in flue gas desulphurization (FGD) systems were presented. The power plant where the system operated is lignite-fired. Owing to measurements using electrochemical impedance spectroscopy and gravimetric determination of water content in the lining, the areas of the system which are most exposed to degradation were shown. The results obtained...
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Effects of V2O5 Additive on Structure and Dielectric Properties of BiNbO4 Ceramics
PublikacjaGoal of the present research was to investigate the influence of V2O5 additive on the structure and dielectric properties of BiNbO4 ceramics. To fabricate BiNbO4 ceramics with V2O5 added the solid state reaction route and pressureless sintering was utilized. Thus obtained ceramics was characterized in terms of its microstructure (SEM), chemical composition (EDS), phase composition and crystalline structure (X-ray phase and structural...
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Effect of cobalt addition on the corrosion behaviorof near equiatomic NiTi shape memory alloy in normal saline solution: electrochemical and XPS studies
PublikacjaThe electrochemical and corrosion (uniform and localized) behavior of a binary Ni52Ti48 shape memory alloy (SMA) and two ternary Ni52Ti48-xCox (x = 1.5 and 4.0 wt.%) SMAs were studied. Measurements were conducted in 0.9% NaCl solution at 37 oC employing various electrochemical methods. These include: linear polarization resistance (LPR), linear sweep voltammetry (LSV), chronoamperometry and dynamic electrochemical impedance spectroscopy...
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Improvement of electrochemical action of zinc-rich paints by addition of nanoparticulate zinc
PublikacjaThe influence of nanosized particles on electrochemical action of standard zinc-rich paints by means of SEM as well as potential and impedance measurements has been investigated. The motivation for doing this was to obtain additional electrical connection between the spherical microparticles themselves and zinc particles and steel substrate. Overall zinc content was at the level of 92% by weight. Samples with different concentration...
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A novel sensor for measuring temperature profile during the thermoablation
PublikacjaAbstract — A novel approach for monitoring a temperature distribution inside a tissue during thermoablation is presented in the paper. A thermal profile is measured using a set of serially connected thermistors each bypassed by a capacitor. This technique allows a two-wire and simultaneous multi- point measurements using a multi-frequency measurement of electrical impedance. It is...
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Analysis of electromagnetic disturbances in DC network of grid connected building-integrated photovoltaic system
PublikacjaThis paper focuses on conducted electromagnetic interference (EMI) emissions and propagation in the DC network of grid connected building integrated photovoltaic (PV) system. The investigated PV system, consists of ten solar panels, cabling and the grid-connected one phase inverter. The EMI simulation model of the real PV system has been developed with the aid of impedance analyzer measurements of solar panels and the DC network...
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Design and Experiments of a Piezoelectric Motor Using Three Rotating Mode Actuators
PublikacjaThis paper represents a numerical and experimental investigation of the multicell piezoelectric motor. The proposed design consists of three individual cells that are integrated into the stator, double rotor, and a preload system combined into a symmetrical structure of the motor. Each of the cells is characterized by a traveling wave and rotating mode motor. A finite element numerical analysis is carried out to obtain optimal...
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Heterogeneous distribution of surface electrochemical activity in polycrystalline highly boron-doped diamond electrodes under deep anodic polarization
PublikacjaThe surface homogeneity of boron-doped diamond electrodes is variable and depends on anodic polarization conditions. The differentiation factor is the gradual and localized change in surface termination. A series of measurements under different polarization conditions was performed in order to investigate the scale of this effect. Nanoscale impedance microscopy (NIM) revealed large variation of surface resistance in individual...
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Assessment of Fuel Cells’ State of Health by Low-Frequency Noise Measurements
PublikacjaWe proposed applying low-frequency (flicker) noise in proton-exchange membrane fuel cells under selected loads to assess their state of health. The measurement set-up comprised a precise data acquisition board and was able to record the DC voltage and its random component at the output. The set-up estimated the voltage noise power spectral density at frequencies up to a few hundred mHz. We observed the evolution of the electrical...
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AFM-assisted investigation of conformal coatings in electronics
PublikacjaPurpose – This paper aims to presents a new method of investigation of local properties of conformal coatings utilized in microelectronics. Design/methodology/approach – It is based on atomic force microscopy (AFM) technique supplemented with the ability of local electrical measurements, which apart from topography acquisition allows recording of local impedance spectra, impedance imaging and dc current mapping. Potentialities...
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Heterogeneous oxidation of highly boron-doped diamond electrodes and its influence on the surface distribution of electrochemical activity
PublikacjaThe electrochemical active surface area (EASA) of polycrystalline boron-doped diamond (BDD) electrodes is heterogeneous and can be affected by numerous factors. There is a strong need for proper consideration of BDD heterogeneity in order to improve this material's range of application in electrochemistry. Localized changes in surface termination due to the influence of oxidation agent result in increased surface resistance. The...
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Mesoscopic impedance analysis of solid materials surface
PublikacjaSeveral techniques have been developed in order to characterize electrical properties of surfaces in micrometer/nanometer scale. Obtaining of the spatial distribution of sample resistance, capacitance or potential requires separate measurements performed in different scanning modes. On the other hand, analysis of the frequency response of investigated system enables determination of several physical quantities in single measurement...
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Magnetic and capacitive couplings influence on power losses in double circuit high voltage overhead transmission line
PublikacjaPurpose – The paper aims to discuss problems of power and energy losses in a double-circuit overhead transmission line. It was observed from energymeters’ readings, that in such a line, active power losses can be measured as “negative”. The “negative” active power losses appear when the active power injected to the circuit is lower than the active power received at the circuit end. The purpose of this paper is to explain this phenomenon. Theoretical...
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Optical glyphs based localization and identification system
PublikacjaThe paper presents a description of functioning of a platform supporting the detection of obstructive diseases in the respiratory system education process. A 16-parameter model of the respiratory system simulated in the MATLAB/Simulink environment was set in the role of the tested patient. It has been linked to the control layer, developed in the LabVIEW environment, using the SIT library (Simulation Interface Toolkit). This layer...
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An application supporting the educational process of the respiratory system obstructive diseases detection
PublikacjaThe paper presents a description of functioning of a platform supporting the detection of obstructive diseases in the respiratory system education process. A 16-parameter model of the respiratory system simulated in the MATLAB/Simulink environment was set in the role of the tested patient. It has been linked to the control layer, developed in the LabVIEW environment, using the SIT library (Simulation Interface Toolkit). This layer...
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Electrochemical investigations on the corrosion behaviour of reinforcing steel in diatomite- and zeolite-containing concrete exposed to sulphuric acid
PublikacjaCorrosion is a major concern for most structural applications. Its detrimental effect significantly reduces the life of metallic components. This paper presents the results of an experimental investigation of corrosion in the steel reinforcement of concrete samples having three different substituents: 20% diatomite, 20% zeolite, and a reference without zeolite or diatomite. All concrete specimens were subjected to a solution of...