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Wyniki wyszukiwania dla: primary oxidation products
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TiO2-Nitrogen Modified for Water Decolourisation under VIS Radiation
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TiO2/C Photocatalyst Prepared by Ethanol Vapour Treatment of TiO(OH)2
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Activity of TiO2 Photocatalyst Modified with H2WO4 for Degradation of Organic Compounds in Water
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Effect of TiO2 Precursor on the Photoactivity of Fe-C-TiO2 Photocatalysts for Acid Red (AR) Decomposition
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Preparation of TiO2/C Photocatalyst by Ethanol Modification of Hydrolysed Titania TiO(OH)2 in a Pressure Reactor
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The Photocatalytic Performance of Benzene- Modified TiO2 Photocatalysts under UV-vis Light Irradiation
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Characterization of TiO2 Modified with Bimetallic Ag/Au Nanoparticles Obtained in Microemulsion System
PublikacjaFotokatalizatory TiO2 modyfikowane nanocząstkami bimetalicznymi Ag/Au przygotowano metodą mikroemulsyjną w układzie woda/surfaktant/cykloheksan. Aktywność fotokatalityczna próbek Ag/Au-TiO2 oszacowano przez wyznaczenie stopnia degradacji fenolu pod wpływem światła VIS. Fenol został użyty jako model zanieczyszczeń, ponieważ jest substancją niebezpieczną dla środowiska. Najwyższą aktywność w zakresie światła widzialnego wykazała...
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From ashes to porous hierarchical nanocarbon electrode: Upcycling secondary waste materials through self-catalytic chemical vapour deposition
PublikacjaMetal and metal oxide particles are abundant in various ash-based wastes. Utilizing these as catalyst sources for the fabrication of carbon nanomaterials could present a valuable approach to reduce our reliance on non-renewable and costly catalyst sources, thereby facilitating large-scale nanomaterial production. In this context, secondary waste materials (SWMs) are by-products resulting from the (complete or partial) combustion...
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Cost-effective methods of fabricating thin rare-earth element layers on SOC interconnects based on low-chromium ferritic stainless steel and exposed to air, humidified air or humidified hydrogen atmospheres
PublikacjaMost oxidation studies involving interconnects are conducted in air under isothermal conditions, but during real-life solid oxide cell (SOC) operation, cells are also exposed a mixture of hydrogen and water vapor. For this study, an Fe–16Cr low-chromium ferritic stainless steel was coated with different reactive element oxides – Gd2O3, CeO2, Ce0.9Y0.1O2 – using an array of methods: dip coating, electrodeposition and spray pyrolysis....
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Electrochemical degradation of textile dyes in a flow reactor: effect of operating conditions and dyes chemical structure
PublikacjaIn this study, electrochemical oxidation of five azo dyestuffs (Yellow D-5GN, Red D-B8, Ruby F-2B, Blue D-5RN, Black DN), that are widely used in the textile industry, was investigated in a flow reactor. BDD electrode with a high boron doping level (C/B = 10 000) was prepared and used. Two configurations of reactor were considered, i.e., one with the undivided cell, and the other with the cell divided by anodic and cathodic compartments....
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Reaction quotients of reforming reactions for SOFC and SOFC with LSCNT layer fueled by biogas mixture at 750 C - longterm
Dane BadawczeThe dataset contains the calculated reaction quotients of reforming reactions for the SOFC and SOFC with LSCNT layer (La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-s) fueled by synthetic biogas mixture (60:40 CH4:CO2). The outlet concentration of the gases from SOFC were measured using novel FTIR-based unit.
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Determination of viscosity changes of protein hydrolyzate solutions depending on shear rate
Dane BadawczeRheological characteristics of connective tissue protein solutions were made on the basis of viscosity measurement using a Brookfield viscometer using LV SC4 - 27 spindles and shear rate of 85 s-1 (Fig. 1). Solutions of protein hydrolysates with a concentration of 2% in 0.5M acetic acid were prepared.
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The effect of heating and fermenting on antioxidant properties of white cabbage
PublikacjaIt is widely believed that natural antioxidants found in food are significantly lost during processing. Nevertheless, it was recently demonstrated that processed fruits and vegetables may retain their antioxidant activity. In the present work, the changes in the overall antioxidant properties as a consequence of fermentation of cabbage and/or heat treatment of cabbage juices and extracts were studied. Fermentation processes as...
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Hydrogen-enhanced degradation and oxide effects in zirconium alloys for nuclear applications
PublikacjaThe zirconium alloys used in nuclear industry include mainly ZreSn and ZreNb alloys ofdifferent chemical composition, microstructure and susceptibility to both hydrogendegradation and oxidation. The hypothetic nuclear accidents can create a real danger tothe Zr alloys and stability of parts made of these alloys, and especially such as loss ofcoolant accident (LOCA) and reactivity initiated accidents (RIA). The hydrogen degradationcan...
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Wpływ ciągłego i naprzemiennego napowietrzania na efektywność usuwania amoniaku z wód osadowych w procesie nitrytacja-ANAMMOX
PublikacjaOkreślenie wpływu ciągłego i naprzemiennego napowietrzania, a także stężenie rozpuszczonego tlenu na tempo procesu beztlenowego utleniania amoniaku. Badania oparte zostały o dwa systemy napowietrzania „niemiecki” stosowany przez Jardina i Hennerkesa (2012), który polegał na wprowadzeniu krótkich naprzemiennych faz napowietrzania i mieszania oraz system „szwajcarski” opisany przez Jossa i wsp. (2009, 2011) w którym reaktor...
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Determination of Antioxidant Activity of Vitamin C by Voltammetric Methods
PublikacjaVoltammetric methods—cyclic (CV) and differential pulse voltammetry (DPV) are considered the most appropriate way to evaluate antioxidant activity of redox active compounds. They provide information about both mechanism and kinetics of electrochemical oxidation of antioxidants as well as their physical and chemical properties such as the redox potential or the number of electrons transferred. These methods are helpful for understanding...
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Electrohydrodynamic secondary flow in the electrostatic precipitator with spiked electrodes
PublikacjaIn this work, the results of electrohydrodynamic (EHD) secondary flow measurements in an electrostatic precipitator (ESP) with one-sidedspike electrodes are presented. The EHD secondary flow was measured for one-sided spike electrodes with the spike tips directed either upstream or downstream the primary flow. The results showed different flow patterns for different spike tips direction in respect to the primary flow direction....
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Fruit Pomace as a Component Shaping the Content of Bioactive Compounds and Nutritional, Health-Promoting (Anti-Diabetic and Antioxidant) of Shortcrust Pastries Sweetened with Sucrose and Erythritol
Dane BadawczeIn this study, an attempt was made to develop shortcrust pastries containing different amounts of chokeberry, apple and blackcurrant pomace (0%, 10%, 30%, 50%), modulating their degree of sweetness via the application of sucrose or erythritol. The obtained products were assessed for their nutritional value (energy value, protein, fats, dietary fibre,...
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X-Ray Computer Tomography Study of Degradation of the Zircaloy-2 Tubes Oxidized at High Temperatures
PublikacjaThe investigations of high-temperature oxidation of zirconium alloys, applied for fuel pellets in nuclear power plants, are usually limited to oxidation kinetics, phase transformations and microstructural characterization. The purpose of this research was to characterize the degradation phenomena occurring within oxide layer and at the interface oxide/metal, on internal and external Zircaloy-2 tube...
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Team project I (2020/21)
Kursy OnlineWithin this team project, students will be designing a space mission. Each student will choose a subsystem: mission analysis, propulsion, communication, structure, mechanisms, power, thermal, onboard data handling. Together, by means of concurrent engineering a primary system definition will be completed.
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Electrochemistry meets enzymes: Investigation of the biotransformation pathway of C-1311 based on electrochemical simulation in comparison to in vitro methods.
PublikacjaThe knowledge of the metabolic pathways and the biotransformation of new drugs is one of the major challenges in pharmaceutical research. It is crucial for elucidation of degradation routes of the new biologically active compounds, especially in the area of possible toxicity. Conventional in vitro drug metabolism studies are based on incubating drug candidate with e.g. hepatocytes or, most importantly, liver cell microsomes and...
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A study on the protection of methionine and the reduction of methionine sulfoxide in methionine-containing analogues of the growth-modeling factor Gly-His-Lys
PublikacjaThe protection of methionine and the reduction of methionine sulfoxide in methionine-containing analogues of Gly-His-Lys are described. The peptides were synthesized by a solid-phase method using the standard Fmoc procedure. Simultaneous deprotection of the peptide side chain and liberation from the resin were achieved using an appropriate TFA cocktail. The TFA cocktail was selected to minimize oxidation of the methionine residue....
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Insightful Analysis of Phenomena Arising at the Metal|Polymer Interphase of Au-Ti Based Non-Enzymatic Glucose Sensitive Electrodes Covered by Nafion
PublikacjaThis paper focuses on the examination of glucose oxidation processes at an electrode material composed of gold nanoparticles embedded in a titanium template. Three dierent conditions were investigated: the chloride content in the electrolyte, its ionic conductivity and the presence of a Nafion coating. The impact of the provided environment on the oxidation reaction was evaluated by cyclic voltammetry (CV) and electrochemical impedance...
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Experimental and theoretical investigation of the reactivity of [(BDI*)Ti(Cl){η2-P(SiMe3)-PiPr2}] towards selected ketones
PublikacjaIn this work, we report a new type of reactivity of [(BDI*)Ti(Cl){η2-P(SiMe3)-PiPr2}] (1) towards ketones (BDI* = 2,6-diisopropylphenyl-β-methyldiketiminate ligand). In the reaction of 1 with acetone, cyclopentanone or cyclohexanone, a ketone moiety is inserted into Ti–Pphosphanyl or Ti–Pphosphido bonds to form complexes with a new C–P–P moiety, providing [(BDI*)Ti(Cl){η2-P(SiMe3)-PiPr2-C(Me)2O}] (2a), [(BDI*)Ti(Cl){η2-OC(Me)2P(SiMe3)-PiPr2}]...
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Microwave-assisted synthesis of a TiO2-CuO heterojunction with enhanced photocatalytic activity against tetracycline
PublikacjaA microwave method was used for the synthesis of TiO2-CuO oxide systems. A detailed investigation was made of the effect of the molar ratio of components (TiO2:CuO=9:1, 7:3, 5:5, 3:7, 1:9) on the crystalline structure and morphology. Transmission electron microscopy (TEM) confirmed the presence of octahedral and rod-shaped titania particles and sheet copper(II) oxide particles; moreover, HRTEM analysis indicated the presence of...
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Katarzyna Kubiszewska dr
OsobyKatarzyna Kubiszewska pracuje w Katedrze Finansów o 2008 r. i prowadzi zajęcia z finansów i bankowości. W pracy naukowej interesuje się transformacją systemów bankowych w regionie Europy Centralno - Wschodniej, ale także finansowaniem sektora kultury. Publikacje dotyczą dziedziny nauk społecznych w zakresie dyscypliny ekonomia i finanse. Od 2019 r. współpracuje z czasopismami takimi jak Economic Research-Ekonomska Istrazivanja,...
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Non-Coaxially Rotating Motion in Casson Martial along with Temperature and Concentration Gradients via First-Order Chemical Reaction
PublikacjaThe effect of non-coaxial rotation on the transport of mass subjected to first-order chemical reaction is studied analytically. The effects of thermal radiation, buoyancy, constructive and destructive chemical reactions along with Casson fluid in rotating frame are discussed. Time evolution of primary and secondary velocities, energy and solute particles are analyzed. The behavior of flow under the variation of intensity of magnetic...
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Sample preparation techniques for determination of pesticide residues in food samples
PublikacjaPesticides are very important in increasing the efficiency and quality of agricultural production. They are applied in many spheres of life, not only in agriculture, and their applications are expanding. Despite their numerous merits, pesticides are some of the most toxic substances contaminating our environment and have a negative impact on the human health. Properties of pesticides such as stability, ability to bioaccumulation...
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The role of hydrodynamic cavitation in tuning physicochemical properties of food items: A comprehensive review
PublikacjaBackground: Today, food processing industries are looking for alternative technologies with an eco-friendly character for the processing of food, beverages and agricultural crops. Ideally, such technologies may preserve the original properties of the food products while reaching their primary target of application. Scope and approach: At this point, hydrodynamic cavitation (HC) is recognized as one of the potential technologies...
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Raman spectra and electrochemical data of carbon nanowall with tailored defects
Dane BadawczeThis dataset comprises of Raman spectra aquired with different excitation laser sources and the electrochemical data of defect-induced carbon nanowall electrodes (CNW).
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Badanie modułu odkształcenia podłoża gruntowego w nasypie kontrolowanym za pomocą płyty statycznej i lekkiej płyty dynamicznej
PublikacjaW praktyce inżynierskiej, zarówno projektowej, jak i wykonawczej, niewątpliwie przydatne są korelacje między parametrami geotechnicznymi. Artykuł przedstawia polowe badania porównawcze lekką płytą dynamiczną (LFWD) oraz płytą statyczną (VSS), wraz określeniem zależności korelacyjnych pomiędzy modułem odkształcenia podłoża wyznaczonym za pomocą lekkiej płyty dynamicznej EVd oraz pierwotnym i wtórnym modułem odkształcenia EV1, EV2....
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NADBUDOWY I RENOWACJE ELEWACJI Z WYKORZYSTANIEM MATERIAŁÓW I ELEMENTÓW LEKKIEJ OBUDOWY
PublikacjaW artykule omówiono podział i charakterystykę lekkich przegród budowlanych. Przedstawiono możliwości zmian elewacji i wykonywania nadbudowy. Opisano kolejne kroki przygotowania inwestycji dotyczącej projektowania i realizacji nadbudowy obiektu budowlanego.
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Pesticide analysis of bee and bee product samples
PublikacjaBee products possess therapeutic properties and are the source of many essential trace elements,which is why they are regarded as valuable food products. Honey bees may bring to thehive numerous contaminants deposited on the plants they visit, including pesticide withoutxenobiotics. The large-scale application of pesticides in agriculture and horticulture can lead tomass mortality among bees, and the chemicals find their way into...
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Pesticide Analysis of Bee and Bee Product Samples
PublikacjaBee products possess therapeutic properties and are the source of many essential trace elements,which is why they are regarded as valuable food products. Honey bees may bring to thehive numerous contaminants deposited on the plants they visit, including pesticide withoutxenobiotics. The large-scale application of pesticides in agriculture and horticulture can lead tomass mortality among bees, and the chemicals find their way into...
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Karol Kufel mgr inż.
OsobyKarol Kufel od 2010 roku pracuje na Wydziale Zarządzania i Ekonomii PG. Od 2014 pełni funkcję asystenta w Katedrze Zarządzania w Przemyśle. Jest absolwentem Wydziału Mechanicznego PG na specjalności Robotyka oraz Wydziału Zarządzania i Ekonomii PG na specjalności Zarządzanie systemami produkcyjnymi. Jego zainteresowania naukowo-badawcze obejmują projektowanie oraz doskonalenie systemów produkcyjnych i logistycznych, a także rozwój...
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High temperature corrosion evaluation and lifetime prediction of porous Fe22Cr stainless steel in air in temperature range 700–900 °C
PublikacjaThis work describes a high temperature corrosion kinetics study of ~30% porous Fe22Cr alloys. The surface area of the alloy (~0.02 m2 g-1) has been determined by tomographic microscopy. The weight gain of the alloys was studied by isothermal thermogravimetry in the air for 100 hours at 700 - 900 °C. Breakaway oxidation was observed after oxidation at 850 °C (~100 hours) and 900 °C (~30 hours). The lifetime prediction shows the...
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High-temperature kinetics study of 430L steel powder oxidized in air at 600–850 °C
PublikacjaThe 430L stainless steel powder with a mean particle size of 95 μm was studied to determine its high-temperature oxidation properties. Continuous thermogravimetric measurements were carried out for 100 h in air at temperatures in the range of 600–850 °C. Even though a considerable amount of Cr (up to ˜5 wt.% Cr) inside the grains was depleted – especially inside small grains – no breakaway oxidation was observed. This indicates...
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GDP growth in Iran
Dane BadawczeThe economy of the Islamic Republic of Iran is one of the fastest growing in the Middle East. Iran should not only be associated with crude oil industry but also other areas of the economy. The sanctions that hindered oil exports from Iran meant that the authorities had to take measures to increase exports of other products. There was an increase in...
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Impact of binary mixtures of diclofenac and buthylparaben of the model organism Saccharomyces Cerevisiae (using XenoScreen YES/YAS test)
Dane BadawczeData shown in data set illustrate the results of the edorin processes of miture of diclofenac and buthylparaben on S cerevisiae is used as a model organism in the monitoring of endocrine disruptors in environmental and reference samples in Xenometrix® systems - XenoScreen®. Tested substances have bakeriosis and fungicide properties and are used in...
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Insights into modification of lignocellulosic fillers with isophorone diisocyanate: structure, thermal stability and volatile organic compounds emission assessment
PublikacjaThis study presents an analysis of the structure and properties of different types of lignocellulosic fillers modified by isophorone diisocyanate (IPDI) to provide insights into the possibility of their application to the manufacturing of wood polymer composites (WPCs). Moreover, it deals with the environmental aspects of modified fillers, by assessment of volatile organic compounds (VOCs) emitted during modification, as well as...
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Application of BDD thin film electrode for electrochemical decomposition of heterogeneous aromatic compounds
PublikacjaThe aim of the presented study is to investigate the applicability of electrochemical oxidation of aromatic compounds containing heteroatoms, e.g. waste from production of pesticides or pharmaceutics, at a borondoped diamond (BDD) electrode. The BDD electrodes were synthesized by microwave plasma enhanced chemical vapour deposition (MW PE CVD). Investigation of the electrode surface by optical microscopy and scanning electron microscopy...
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The BDD electrodes wettability modification by anodic polarization treatment
Dane BadawczeThe dataset contains the raw images, photographs obtained for the contact angle measurement at the surface of the boron-doped diamond (BDD) electrode. The measurements were carried out on after potentiodynamic polarization procedure, at various anodic polarization scan range (no polarization - HTBDD; 1.0 V; 1.4 V; 1.9 V; 2.5 V vs Ag|AgCl, scan rate...
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Synthesis of Titanium Dioxide via Surfactant-Assisted Microwave Method for Photocatalytic and Dye-Sensitized Solar Cells Applications
PublikacjaIn this study, titania nanoparticles were obtained using the microwave-assisted technique. Moreover, different surfactants (PEG (Mn = 400), Pluronic P123 and Triton X−100) were used during the synthesis in order to determine their impact on the crystallinity and morphology of the final products. Subsequently, techniques such as XRD, SEM and TEM (performed in high contrast and high-resolution mode), diffuse reflectance spectroscopy...
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SMART SHOP SERVICES FOR BUILDING CUSTOMER-ORIENTED SCENARIOS
PublikacjaThe shops of today mostly support the customer by offering him or her products based on basic relationships between products viewed or ordered by users with similar tastes. This common approach may fail in many cases especially when the user does not have sufficient knowledge about the market, or when he or she wants to build a set of products in more than one shop. New categories of smart shop services are proposed in order to...
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Potential of bioethanol production from biomass of various Miscanthus genotypes cultivated in three-year plantations in west-central Poland
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Prenylated Stilbenoids Affect Inflammation by Inhibiting the NF-κB/AP-1 Signaling Pathway and Cyclooxygenases and Lipoxygenase
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Sawing frozen wood with narrow kerf saws: Energy and quality effects.
PublikacjaOpór skrawania zależy podczas przecinania nie tylko od wilgotności drewna lecz również od jego temperatury. W pracy przedstawiono wyniki badań eksperymentalnych przecinania drewna sosnowego zmrożonego na pilarce ramowej wielopiłowej. Dla porównania wykonano również testy dla drewna o temperaturze pokojowej. Czynnikami badanymi były: moc skrawania, dokładność przecinania w postaci grubości elementów, a także chropowatość powierzchni....
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Synthesis of Usnic Acid Derivatives and Evaluation of Their Antiproliferative Activity against Cancer Cells
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Silybum marianum glycerol extraction for the preparation of high-value anti-ageing extracts
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Anti-inflammatory Potential of Flavonoids from the Aerial Parts of Corispermum marschallii
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