Wyniki wyszukiwania dla: THERMOPLASTIC POLYURETHANE COMPOSITES
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Modeling of wood frame structures with different insulation materials under damaging dynamic loading
PublikacjaWood frame buildings are very popular in regions that are exposed to different dynamic excitations, such as damaging earthquakes. Their seismic resistance is really important in order to prevent structural damages and human losses. This paper presents the results of advanced numerical investigation carried out using the FEM. Based on the models of wall panels, the numerical model of real structure of the wood frame building has...
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Micro-Raman spectroscopy in the studies of multiphase separated polyurethanes. [online] W: [Proc.] UTECH Europe 2003 . The International Polyurethane Industry Conference and Exhibition. 25/26/27 March 2003, The Hague, Netherlands. London: Crain Communications Ltd. Dostępny w World Wide Web: http://UTECH-2003.com + wydruk.**2003 [s. 123-130 bibliogr. 41 poz.]Mikro-Ramanowska spektroskopia w badaniach poliuretanów wykazujących separację wielofazową.
PublikacjaPrzedmiotem badań były trzy próbki poliuretanowe o zawartości 30% segmentówsztywnych otrzymanych z politlenku propylenu, diizocyjanianu difenylometanui butanodiolu. Próbki te wykazują morfologię wielofazową, w której można wy-różnić globule i sferolity rozproszone w matrycy polimerowej.Za pomocą spek-troskopii mikro-Ramana przeprowadzono mikroanalizę chemiczną wszystkich ele-mentów morfologicznych. Stwierdzono odmienny skład...
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Inhibition of Polymer Photodegradation by Incorporation of Coffee Silverskin
PublikacjaOver the last years, the trend associated with the incorporation of materials from renewable resources into polymer technology is getting significantly more vital. Researchers are trying to transfer the properties of natural raw materials into the polymer world. Therefore, different natural materials are more often investigated as potential additives for polymers. Such an effect is noted for the coffee industry by-products, such...
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Coffee silverskin as a potential bio-based antioxidant for polymer materials: Brief review
PublikacjaCoffee silverskin is one of the by-products generated by the coffee industry. Although it is not the most burdensome one, because it stands only for ~4.2 wt % of coffee, it seems like an auspicious raw material for industrial processes. Coffee silverskin is characterized by a relatively low moisture content of ~5–7%, so it often does not require quite energy-consuming drying processes. The chemical composition of coffee silverskin,...
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Novel Structures and Applications of Graphene-Based Semiconductor Photocatalysts: Faceted Particles, Photonic Crystals, Antimicrobial and Magnetic Properties
PublikacjaGraphene, graphene oxide, reduced graphene oxide and their composites with various compounds/materials have high potential for substantial impact as cheap photocatalysts, which is essential to meet the demands of global activity, offering the advantage of utilizing “green” solar energy. Accordingly, graphene-based materials might help to reduce reliance on fossil fuel supplies and facile remediation routes to achieve clean environment...
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STRUKTURA SZKŁO-CERAMIKI ZAWIERAJĄCEJ FERROELEKTRYCZNĄ FAZĘ BiV
PublikacjaLiteratura opiusuje próby wytworzenia nanokompozytów, w których skład wchodzą matryca szkła i rozproszone w niej nanokrystality fazy ferroelektrycznej. Najczęstsza metoda wykorzystywana do otrzymywania takiej szkło - ceramiki polega na wytopie szkła, a następnie jego krystalizacji. W literaturze można znaleźć dużo przykładów wytwarzania tego typu materiałów dwu lub więcej składnikowych. Najwięcej badań dotyczy ferroelektrycznych...
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Eco-Friendly Electromagnetic Interference Shielding Materials from Flexible Reduced Graphene Oxide Filled Polycaprolactone/Polyaniline Nanocomposites
PublikacjaHybrid nanocomposites have the unique ability of enhancing material properties due to the existing synergistic effect of the fillers. In this study, the authors report such an eco-friendly hybrid nanocomposite comprising of polyaniline and reduced graphene oxide in polycaprolactone. The conducting polyaniline improved the processability of polycaprolactone, and the final composites were prepared by incorporating graphene oxide...
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Insight into (Electro)magnetic Interactions within Facet-Engineered BaFe12O19/TiO2 Magnetic Photocatalysts
PublikacjaA series of facet-engineered TiO2/BaFe12O19 composites were synthesized through hydrothermal growth of both phases and subsequent deposition of the different, faceted TiO2 nanoparticles onto BaFe12O19 microplates. The well-defined geometry of the composite and uniaxial magnetic anisotropy of the ferrite allowed alternate interfaces between both phases and fixed the orientation between the TiO2 crystal structure and the remanent...
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Chemical structures, rheological and physical properties of biopolyols prepared via solvothermal liquefaction of Enteromorpha and Zostera marina biomass
PublikacjaIn this work, liquefied biomass from the Baltic Sea was used for the preparation of rigid polyurethane (PUR) foams. The biomass contained 10 wt% of Enteromorpha macroalgae and 90 wt% of Zostera marina seagrass characterized by a high content of cellulose. The influence of time, temperature and the type of solvent on the efficiency of the liquefaction process and properties of biopolyols was determined. Obtained materials were analyzed...
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The changes of crosslink density of polyurethanes synthesised with using recycled component. Chemical structure and mechanical properties investigations.
PublikacjaThis paper aims at the utilisation of glycerolysate (Gly) obtained in polyurethane recycling process by means of crude glycerine, which has in its structure hydroxyl end groups that allow for further processing. Polyurethanes (PUs) were synthesised using prepolymer method with the mixture of neat polyol and glycerolysate, in different ratios, with 4,4-diphenylmethane diisocyanate (MDI). The prepolymer was subsequently extended...
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Electrochemical synthesis and characterization of nanocomposites based on poly(3,4-ethylenedioxythiophene) and functionalized carbon nanotubes
PublikacjaThis work is focused on new composite materials consisting of poly(3,4-ethylenedioxythiophene) (pEDOT) and functionalized multi-walled carbon nanotubes synthesized electrochemically. Three types of composites were synthesized: the first one containing carbon nanotubes with carboxyl groups (covalent functionalization), the second one containing oxidized carbon nanotubes ox-MWCNTs (with different oxygen-rich polar groups) (covalent...
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Material characterisation of biaxial glass-fibre non-crimp fabrics as a function of ply orientation, stitch pattern, stitch length and stitch tension
PublikacjaDue to their high density-specific stiffnesses and strength, fibre reinforced plastic (FRP) composites are particularly interesting for mobility and transport applications. Warp-knitted non-crimp fabrics (NCF) are one possible way to produce such FRP composites. They are advantageous because of their low production costs and the ability to tailor the properties of the textile to the reinforcement and drape requirements of the application....
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Aggregation properties of some zirconium phosphate loaded with dirhenium(III) complexes
PublikacjaOne of the important areas of modern science is the selection of the right forms of drug delivery. Layered inorganic nanoparticles, such as zirconium phosphate, have proven themselves well in this area. The study of the properties of these systems and methods of their preparation makes it possible to determine a rational technology of their manufacture, storage conditions as well as suggest a possible mechanism of therapeutic action....
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Environmental impact and industrial development of biorenewable resources for polyurethanes
PublikacjaPolyurethanes are among the most developed types of polymers. They are produced from the three primary components, i.e., polyols, low-molecular-weight glycols used as chain extenders, and diisocyanates. Until recently, all these substrates have been obtained via petrochemical processes. A decrease in petroleum-based resources and new ecological trends in chemistry, chemical technology, and materials engineering have generated increasing...
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The Taste of Waste: The Edge of Eggshell Over Calcium Carbonate in Acrylonitrile Butadiene Rubber
PublikacjaRubber technology experiences a new age by the use of biowaste or natural fillers. In this regard, taking properties of reinforcing agents from biowaste fillers remains as the challenging matter. Chicken eggshell (ES) biowaste has recently been introduced to substitute calcium carbonate (CaCO3) duo to its superior properties and low price. In this work, composites based on acrylonitrile butadiene rubber (NBR) reinforced with ES...
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Degradation of polycaprolactone modified with TPS or CaCO3 in biotic/abiotic seawater
PublikacjaThis paper is an investigation of the polymer degradation process in two types of seawater (with and without microorganisms) sourced from the Baltic Sea. The chosen polymeric materials were polycaprolactone modified with either thermoplastic starch (PCL/TPS>85%) or calcium carbonate (60% PCL/40% CaCO3) compared directly against unmodified polycaprolactone. All samples were incubated for 28 weeks in seawater with and without microorganisms...
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Anna Lisowska-Oleksiak prof. dr hab.
OsobyAnna Lisowska-Oleksiak, born in 1952, has been working at GUT since 1977. Currently is employed at the Faculty of Chemistry as a full professor. She was employed as a research assistant at the University of St Andrews in the group of C. A. Vincent and P.G. Bruce (1991-1994). She completed a two-month research internship in CEA Grenoble (2011). Anna Lisowska-Oleksiak obtained her MSc in chemistry at Nicolaus Copernicus University...
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Laboratory fatigue assessment of large geocomposite-reinforced double-layered asphalt concrete beams
PublikacjaGeosynthetic reinforcement of asphalt layers has been used for several decades. Evaluation of the influence of these materials on pavement fatigue life is still ongoing, especially for new types of geocomposites. This paper presents the evaluation of fatigue performance of large asphalt concrete beams reinforced with a new type of composite in which square or hexagonal polypropylene stiff monolithic paving grid with integral junctions...
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Laboratory fatigue assessment of large geocomposite-reinforced double-layered asphalt concrete beams
PublikacjaGeosynthetic reinforcement of asphalt layers has been used for several decades. Evaluation of the influence of these materials on pavement fatigue life is still ongoing, especially for new types of geocomposites. This paper presents the evaluation of fatigue performance of large asphalt concrete beams reinforced with a new type of composite in which square or hexagonal polypropylene stiff monolithic paving grid with integral junctions...
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Study on polymer modified road asphalt mixture
PublikacjaThe formulation of ternary asphalt-additives blend composed of crumb rubber : low-density polyethylene (CR : LDPE) and crumb rubber : textile fiber (CR : TF) couples, and quaternary asphalt additives-blend composed of (CR : LDPE : TF) triplets on the virgin asphalt to optimize the asphalt basic and rheological properties and to use the extrusion process of two or three additives to obtain composite materials of them, as well as...
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A Method and Device for 3D Recognition of Cutting Edge Micro Geometry
PublikacjaA very useful method was successfully applied in the investigation of tools for machining wood and wood based composites. It allows scanning of the cutting edge micro geometry in three dimensions and reproducing it in a virtual space as a 3D surface. The application of the method opens new possibilities of studying tool wear by scanning, including the calculation of volume loss and other analysis of tool wedge geometry along and...
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The use of GFRP tubes as load-bearing jackets in concrete-composite columns
PublikacjaThe paper presents the fields of applications of polymer composites in building structures. The use of composite glass fibre tubes is discussed in more detail. The laboratory methods used to test the mechanical properties of these pipes are presented. An original research program is presented, including six concrete-filled glass fibre tubes. The cylinders and columns made in this way were tested for their axial load capacity. Conclusions...
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TiO 2 Co x O y composite nanotube arrays via one step electrochemical anodization for visible light–induced photocatalytic reaction
PublikacjaTiO2CoxOy (x = 1, y = 1 or x = 3, y = 4) composite photocatalysts have been synthesized via one step anodic anodization of TiCo alloys. The effects of the cobalt content in the alloy (5, 10 and 15 wt%), water content (2, 5 and 10%) in the electrolyte solution, and applied voltage (30, 40 and 50 V) during the anodization process on the morphology and surface properties. Additionally, the dependence of cobalt content in the nanotubes...
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Design and Synthesis of NTU-9/C3N4 Photocatalysts: Effects of NTU-9 Content and Composite Preparation Method
PublikacjaHybrid materials based on graphitic carbon nitride (g-C3N4) and NTU-9 metal–organic frameworks (MOF) were designed and prepared via solvothermal synthesis and calcination in air. The as-prepared photocatalysts were subsequently characterized using Brunauer–Emmett–Teller (BET) analysis, UV-Vis diffuse reflectance spectroscopy (DRS), photoluminescence (PL) emission spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy...
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Modification of thermal and rheological characteristics of bitumen by waste PET/GTR blends
PublikacjaWaste poly(ethylene terephthalate) (wPET)/ground tire rubber (GTR) blends with variable compositions were applied as low-cost modifiers into bitumen and their performance has been evaluated via morphological, thermal and rheological analyses. Depending on the weight ratio of wPET/GTR, dispersion of single/composite domains of waste polymers in the bitumen has promoted the interaction between bitumen and blend components. Fourier...
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Thermal decomposition kinetics of dynamically vulcanized polyamide 6-acrylonitrile butadiene rubber-halloysite nanotube nanocomposites
PublikacjaThermally stable thermoplastic elastomer nanocomposites based on polyamide 6 (PA6), acrylonitrile butadiene rubber (NBR), and halloysite nanotubes (HNTs) were dynamically vulcanized, and their nonisothermal decomposition kinetics were examined. The Friedman, Kissinger–Akahira–Sunose (KAS), Ozawa–Wall–Flynn (FWO), and modified Coats–Redfern (m‐CR) isoconversional models were used to obtain information about the kinetics of the thermal...
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The porosity and morphology of PU foams prepared by solvent casting/salt leaching method with different solvents
PublikacjaIn this study, the polyurethane (PU) system based on poly(ethylene-butylene) adipate diol, 1,6-hexamethylene diisocyanate, 1,4-butanediol and ascorbic acid is used to prepare a foamed material. Polymer foams were created using solvent casting/salt-particle leaching (SC/PL) method. The influence of the PU concentration in different solutions [either in a DMF or in DMF with THF as a co-solvent] on the morphology and porosity of the...
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Geometrically nonlinear FEM analysis of FGM shells based on neutral physical surface approach in 6-parameter shell theory
PublikacjaThe paper presents the formulation of the elastic constitutive law for functionally graded materials (FGM) on the grounds of nonlinear 6-parameter shell theory with the 6th parameter being the drilling degree of freedom. The material law is derived by through-the-thickness integration of the Cosserat plane stress equations. The constitutive equations are formulated with respect to the neutral physical surface. The influence of...
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Mechanical properties of Precontraint 1202 S2 based on uniaxial tensile and creep tests
PublikacjaThe purpose of the paper is the estimation of the polyvinyl chloride – polyester-coated fabric (Precontraint 1202 S2) mechanical properties under uniaxial tensile tests as well as short- and long-time creep tests. The uniaxial tests are the basis of non-linear elastic description while the creep tests are used for the evaluation of the stiffness parameters in time and for the identification of the standard viscoelastic model. The...
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Elastoplastic nonlinear FEM analysis of FGM shells of Cosserat type
PublikacjaThe paper is a continuation of [1] where the formulation of the elastic constitutive law for functionally graded materials (FGM) on the grounds of nonlinear 6-parameter shell theory with the 6th parameter (the drilling degree of freedom) was presented. Here the formulation is extended to the elasto-plastic range. The material law is based on Cosserat plasticity and employs the well-known Tamura-Tomota-Ozawa (TTO) [2] mixture...
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Transient response of oscillated carbon nanotubes with an internal and external damping
PublikacjaThe present works aims at modeling a viscoelastic nanobeam with simple boundary conditions at the two ends with the introduction of the Kelvin-Voigt viscoelasticity in a nonlocal strain gradient theory. The nanobeam lies on the visco-Pasternak matrix in which three characteristic parameters have a prominent role. A refined Timoshenko beam theory is here applied, which is only based on one unknown variable, in accordance with the...
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Effects of manufacturing and face /core bonding on impact damage in glass/polyester - PVC foam core sandwich panels
PublikacjaZbadano podatność na inicjację uszkodzeń pod wpływem spadającego obciążenia w konstrukcjach przekładkowych poliestrowo szklanych z rdzeniem z pianki PVC przy dwóch sposobach łączenia okładek z rdzeniem: przy pomocy 2 klejów proponowanych do tego celu przez ich producentów oraz czystej żywicy. Zastosowano oprzyrządowany młot spadowy , określając rozmiar zniszczeń na powierzchni próbki metodą wizualna i ultradźwiękową. Inicjacja...
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Magnetization enhancement in magnetite nanoparticles capped with alginic acid
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Synergistic effect of nanoscale carbon black and ammonium polyphosphate on improving thermal stability and flame retardancy of polypropylene: A reactive network for strengthening carbon layer
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Na3PO4 assistant dispersion of nano-CaCO3 template to enhance electrochemical interface: N/O/P co-doped porous carbon hybrids towards high-performance flexible supercapacitors
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Mechanical properties of polyvinyl chloride-coated fabric under cyclic tests
PublikacjaThe aim of the present paper is to propose a method of laboratory tests necessary for the identification of mechanical properties of the coated fabric. The material parameters of the coated fabric AF 9032 are specified on the basis of the uniaxial and biaxial tensile tests. For the identification process, the techniques based on the least squares methods are used. Additionally, the uniaxial and biaxial cyclic tests are performed...
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Mechanical testing of technical woven fabrics
PublikacjaThis article presents a review of technical fabrics testing methods used by the authors on the basis of their experience with research on properties of polytetrefluoroethylene-coated fabrics used for Forest Opera in Sopot (Poland). First, the different types of testing methods used for description of mechanical properties (uniaxial tensile tests, biaxial tensile tests and shear tests) of technical woven fabrics are described. The...
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Influence of thermal effects on mechanical properties of PVDF-coated fabric
PublikacjaThis paper describes the method of laboratory tests necessary for identification of temperature influence on mechanical properties of polyvinylidene fluoride-coated polyester fabric often used for tensile structures. Two nonlinear model descriptions are investigated. The first one is based on the piece-wise linear relations between stress and strain and the second one on the Murnaghan model of solid behavior. This paper is proposed...
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A new type of (TiZrNbTaHf)N/MoN nanocomposite coating: Microstructure and properties depending on energy of incident ions
PublikacjaA novel (TiZrNbTaHf)N/MoN nanocomposite coatings, which consist of the nitride of the high-entropy alloy and the binary nitride, were synthesized by vacuum-arc deposition at various substrate biases. The elemental composition, chemical bonding state, phase structure, microstructure and mechanical properties of the coatings were studied by high-resolution experimental methods: SIMS, GDMS, XPS, XRD, HR-TEM and nano-indentation. It...
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2-D constitutive equations for orthotropic Cosserat type laminated shells in finite element analysis
PublikacjaWe propose 2-D Cosserat type orthotropic constitutive equations for laminated shells for the purpose of initial failure estimation in a laminate layer. We use nonlinear 6-parameter shell theory with asymmetric membrane strain measures and Cosserat kinematics as the framework. This theory is specially dedicated to the analysis of irregular shells, inter alia, with orthogonal intersections, since it takes into account the drilling...
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A facile approach to fabricate load-bearing porous polymer scaffolds for bone tissue engineering
PublikacjaBiodegradable porous scaffolds with oriented interconnected pores and high mechanical are load-bearing biomaterials for bone tissue engineering. Herein, we report a simple, non-toxic, and cost-effective method to fabricate high-strength porous biodegradable scaffolds, composed of a polymer matrix of polycaprolactone (PCL) and water-soluble poly (ethylene oxide) (PEO) as a sacrificial material by integrating annealing treatment,...
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Effects of liquid phase modification on the performance of biotrickling filters
Dane BadawczeDataset presents the effects of liquid phase modification on the biotrickling filtration (BTF) performance of air polluted with toluene, ethylbenzene, xylene and styrene.
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Biopolyols obtained via crude glycerol-based liquefaction of cellulose: their structural, rheological and thermal characterization
PublikacjaIn this work lignocellulose biomass liquefaction was used to produce biopolyols suitable for the manufacturing of rigid polyurethane foams. In order to better evaluate the mechanism of the process, pure cellulose was applied as a raw material. The effect of time and temperature on the effectiveness of liquefaction and the parameters of resulting biopolyols were characterized. The prepared materials were analyzed in terms of their...
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Modyfikacja kompozytów elastomerowych NR za pomocą ligniny i glicerolizatu
PublikacjaPrzedmiotem opisanych w niniejszym artykule badań są wulkanizaty kauczuku naturalnego. Celem pracy było zbadanie wpływu ligniny oraz glicerolizatu na wybrane właściwości kompozytów zawierających kauczuk naturalny. Strukturę chemiczną przygotowanych materiałów potwierdzono, wykorzystując analizę spektroskopową w podczerwieni (FTIR). Zbadano również właściwości mechaniczne przy statycznym rozciąganiu, twardość, ścieralność oraz odbojność...
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Polyurethanes for Coating, Adhesives, and Other Applications
PublikacjaAn interesting group of polyurethane (PU) materials are coatings, adhesives, sealants, and thickeners. A wide base of raw materials and various methods of PU synthesis allows production of materials with a wide range of properties that can be commonly used in many industries. This chapter describes the main types of PU coatings and adhesives and special application PUs and the methods of their production. The materials described...
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Ni-based compounds in multiwalled graphitic shell for electrocatalytic oxygen evolution reactions
Dane BadawczeThis study investigates Ni-based compounds (Ni, NiO, Ni3C) coated with a graphitic shell as electrocatalysts for the oxygen evolution reaction (OER). Electron paramagnetic resonance (EPR) and X-ray diffraction (XRD) are employed to identify the presence and contribution of Nickel ions (Ni0, Ni2+, Ni3+) and determine the phase composition. Electrochemical...
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Band engineering of BiOBr based materials for photocatalytic wastewater treatment via advanced oxidation processes (AOPs) – A review
PublikacjaSemiconductor based photocatalysts have been an efficient technology for water and wastewater remediation, addressing the concepts of green chemistry and sustainable development. Owing to narrow and suitable band structure, BiOBr is a promising candidate for efficient wastewater treatment via photocatalysis. Enhancement of photocatalytic properties can be obtained by various techniques like doping, element rich strategy, facet...
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Novel Biodegradable Potato Starch-based Compositions as Candidates in Packaging Industry, Safe for Marine Environment
PublikacjaAbout 70 % of our planet’s surface is covered by seas and oceans to which even 10 million tons of waste go every year. It makes these places the largest global landfills, containing up to 90 % of plastic waste. In this article we present the results of research on novel starch-based compositions expected to be more safe for the marine environment. For these purpose biopolymers such as, thermoplastic starch (TPS), polylactide (PLA)...
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Influence of Fragment Size on the Time and Temperature of Ethylene Vinyl Acetate Lamination Decomposition in the Photovoltaic Module Recycling Process
PublikacjaPhotovoltaics is a commercially available and reliable technology with significant potential for long-term growth in nearly all global regions. Several research institutes and companies are working on recycling concepts for thin film modules and modules with crystalline cells. The establishment of recycling and reuse technologies appropriate and applicable to all photovoltaics (PV) modules is a key issue to be addressed as part...
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A Generalized Framework Towards Structural Mechanics of Three-layered Composite Structures
PublikacjaThree-layered composite structures find a broad application. Increasingly, composites are being used whose layer thicknesses and material properties diverge strongly. In the perspective of structural mechanics, classical approaches to analysis fail at such extraordinary composites. Therefore, emphasis of the present approach is on arbitrary transverse shear rigidities and structural thicknesses of the individual layers. Therewith...
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Recent progress in ultra-low formaldehyde emitting adhesive systems and formaldehyde scavengers in wood-based panels: a review
PublikacjaTraditional wood-based panels are produced with synthetic, formaldehyde-based adhesives, commonly made from fossil-derived constituents, such as urea, phenol, melamine, etc. Along with their numerous advantages, such as chemical versatility, high reactivity and excellent adhesive performance, these adhesives are characterized by certain problems, connected with the hazardous volatile organic compounds (VOCs), mostly free formaldehyde...
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Polyisocyanates from Sustainable Resources
PublikacjaIsocyanates, next to polyols, constitute the major components essential for polyurethane (PU) production. They have a significant impact on physicochemical, mechanical, and thermal properties of PU materials. They also have an impact on those materials’ purposes, forms, textures, and other features. The available and used isocyanates are of a petrochemical origin. With the development of a trend toward green chemistry in the science...
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Biotrickling filtration of air polluted with hexane and cyclohexane: effects of trickling liquid modification with DES solutions
Dane BadawczeDataset presents selected parameters monitored during processes of biotrickling filtration of air polluted with hexane and cyclohexane.
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Thermal and Mechanical Properties of Microporous Polyurethanes Modified with Reduced Graphene Oxide
PublikacjaMicroporous polyurethanes (MPU) were modified by adding 0.25%–1.25 wt% of reduced graphene oxide (RGO). The materials were prepared without solvent via in situ polymerization. From a technological point of view, it is very important to obtain functional materials by using reacting compounds only. The thermal characteristics of obtained MPU were investigated using TGA, DSC, and DMA techniques. In comparison to nonmodified microporous...
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Two-step Conversion of Crude Glycerol Generated by Biodiesel Production into Biopolyols: Synthesis, Structural and Physical Chemical Characterization
PublikacjaIn this work biopolyols were synthesized via two-step process from crude glycerol and castor oil. For better evaluation of analyzed process, the impact of its time and temperature on the structure and properties of biopolyols was determined. Obtained results fully justified conducting of synthesis in two steps. Prepared materials were characterized by hydroxyl value and water content comparable to polyols industrially applied in...
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Renewable natural resources as green alternative substrates to obtain bio-based non-isocyanate polyurethanes-review
PublikacjaCommercially available polyurethanes are synthesized by the polyaddition of diisocyanates with polyols and low molecular weight chain extenders. A new approach to polyurethanes synthesis is realized via non-isocyanate routes. Negative impacts of petroleum-based chemicals on the environment and human health as well as gradual reduction of fuel-based resources, which leads to an increase in their prices, are an incentive to looking...
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Thermal and mechanical properties of polyurethanes modified with L-ascorbic acid
PublikacjaIn this study we report the thermal and mechanical properties of polyurethanes modified with ascorbic acid (AA). Ascorbic acid was used as a modifier at concentration of 1 or 2 mass%. The antioxidative properties of AA may improve the biocompatibility of the obtained materials, which were designed for biomedical applications. In this paper we describe characterization of obtained unmodified and ascorbic acid modified polyurethanes...
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A Simple Replica Method as the Way to Obtain a Morphologically and Mechanically Bone-like Iron-Based Biodegradable Material
PublikacjaPorous iron-based scaffolds were prepared by the simple replica method using polyurethane foam as a template and applying the sintering process in a tube furnace. Their surface morphology was characterized using scanning electron microscopy (SEM) and phase homogeneity was confirmed using X-ray diffraction (XRD). Corrosion behavior was determined using immersion and potentiodynamic polarization methods in phosphate buffered saline...
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Technological aspects of manufacturing polymer packaging materials degradable in seawater environment
PublikacjaIn recent years, the number of polymer materials used in the food packaging market was growing extremely fast. This contributed to depletion of non-renewable resources and more intense degradation of the environment due to resistant polymer. Therefore, such a dramatic situation has forced researchers to look for biodegradable materials, decomposable under action of microorganism. Currently, only a small number of researches examine...
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Fe local structure in Pt-free nitrogen-modified carbon based electrocatalysts: XAFS study
PublikacjaThe paper presents a new results on the bonding environment (coordination number and geometry) and on oxidation states of Fe in nitrogen-modified Fe/C composites used as Pt-free catalysts for oxygen reduction in Direct Hydrogen Fuel Cells. Starting from glucose or fructose, two catalysts displaying different electrochemical performance were prepared and studied in the form of pristine powder and thin catalytic layer of electrode...
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Novel Low-Loss Substrates for 5G Applications
PublikacjaThis paper presents a feasibility study of a new type of microwave low-loss dielectric substrates for 5G network applications. The new substrate materials are composites of polypropylene and high-dielectric-constant micro-ceramics. This combination is expected to form a very low-loss dielectric material at low fabrication cost. Two substrate samples with different dielectric properties are fabricated and their characteristics at...
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Prediction of maximum tensile stress in plain-weave composite laminates with interacting holes via stacked machine learning algorithms: A comparative study
PublikacjaPlain weave composite is a long-lasting type of fabric composite that is stable enough when being handled. Open-hole composites have been widely used in industry, though they have weak structural performance and complex design processes. An extensive number of material/geometry parameters have been utilized for designing these composites, thereby an efficient computational tool is essential for that purpose. Different Machine Learning...
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The effect of metal cluster deposition route on structure and photocatalytic activity of mono- and bimetallic nanoparticles supported on TiO2 by radiolytic method
PublikacjaTiO2 (P25) was modified with small and relatively monodisperse mono- and bimetallic clusters (Ag, Pd, Pt, Ag/Pd, Ag/Pt and Pd/Pt) induced by radiolysis to improve its photocatalytic activity. The as-prepared samples were characterized by X-ray fluorescence spectrometry (XRF), photoluminescence spectrometry (PL), diffuse reflectance spectroscopy (DRS), X-ray powder diffractometry (XRD), scanning transition electron microscopy (STEM)...
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Estimation of Broadband Complex Permeability Using SIW Cavity-Based Multimodal Approach
PublikacjaIn this article, an attractive multimodal substrate integrated waveguide (SIW) based methodology is presented for the characterization of magnetic materials in the broadband microwave frequency. The proposed approach employs a modified feed under-coupled SIW cavity instead of conventional feed over-coupled multiple SIW cavities; it uses the modified closedform expression, developed from the first principle to consider the effect...
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The impact of thermomechanical and chemical treatment of waste Brewers’ spent grain and soil biodegradation of sustainable Mater-Bi-Based biocomposites
PublikacjaDue to the massive plastic pollution, development of sustainable and biodegradable polymer materials is crucial to reduce environmental burdens and support climate neutrality. Application of lignocellulosic wastes as fillers for polymer composites was broadly reported, but analysis of biodegradation behavior of resulting biocomposites was rarely examined. Herein, sustainable Mater-Bi-based biocomposites filled with thermomechanically-...
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Tuning of microstructure in engineered poly (trimethylene terephthalate) based blends with nano inclusion as multifunctional additive
PublikacjaImmiscible blends and their composites are heterogeneous and have variable morphology due to variation in mesophase regions. Tuning, i.e. controlling the phase dimension is important, thereof we report a “super-combo” effect of multiwalled carbon nanotubes (MWCNTs) in poly (trimethylene terephthalate)/polypropylene (PTT/ PP) blend system. MWCNTs act as a good reinforcing agent and compatibilizer in the otherwise immiscible PTT/...
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Właściwości elektryczne szkło-ceramiki zawierającej ferroelektryczną fazę BiV
PublikacjaKompozyty szklano - ceramiczne zawierające nanokryształy posiadają właściwości fizyczne, które nie są możliwe do uzyskania w innych materiałach. Dzięki możliwości wytworzenia szkło - ceramik posiadających kryształy o różnej wielkości (nano, mikro...) i różnorodnego typu, można w istotny sposób kontrolować właściwości elektryczne takich materiałów. Stała dielektryczna faz ferroelektrycznych jest bardzo wrażliwa na zmiany rozmiarów...
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Evaluation of Immobilization of Selected Peat-Isolated Yeast Strains of the Species Candida albicans and Candida subhashii on the Surface of Artificial Support Materials Used for Biotrickling Filtration
PublikacjaThe paper describes the process of n-butanol abatement by unicellular fungi, able to deplete n-butanol content in gas, by using n-butanol as source of carbon. Isolated and identified fungi species Candida albicans and Candida subhashii were subjected to a viability process via assimilation of carbon from hydrophilic and hydrophobic compounds. The isolates, which exhibited the ability to assimilate carbon, were immobilized on four...
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Mathematical Modelling of a Seismic Isolation System to Protect Structures During Damaging Earthquakes
PublikacjaThe present study aims to determine the effectiveness of a nonlinear mathematical model in simulating complex mechanical behaviour of a seismic isolation system to protect structures during strong and damaging earthquakes. In order to construct the Polymeric Bearings considered in this research, a specially prepared flexible polyurethane elastomer with increased damping properties has been used. The usefulness of the proposed mathematical...
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Green TPUs from Prepolymer Mixtures Designed by Controlling the Chemical Structure of Flexible Segments
PublikacjaThis study concerns green thermoplastic polyurethanes (TPU) obtained by controlling the chemical structure of flexible segments. Two types of bio-based polyether polyols—poly(trimethylene glycol)s—with average molecular weights ca. 1000 and 2700 Da were used (PO3G1000 and PO3G2700, respectively). TPUs were prepared via a two-step method. Hard segments consisted of 4,4?- diphenylmethane diisocyanates and the bio-based 1,4-butanodiol...
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Formation of surface layer in metal matrix composite A359/20SiCP during laser assisted turning
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Reactive construction of catalytic carbonization system in PP/C60/Ni(OH)2 nanocomposites for simultaneously improving thermal stability, flame retardancy and mechanical properties
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Gas sensors based on conducting polymers-recent developments
PublikacjaThis work discusses sensing performance dependence of PEDOT polymer and its composites on the counter ions used in the polymerization process. The sensors based on PEDOT-RGO composite show reversible response to NO2, while on PEDOT/LiClO4 irreversible. As a result, PEDOT-RGO could be used as a typical gas sensor, while sensor based PEDOT/LiClO4 could be used as an integrating gas sensor, also known as an accumulating gas sensor....
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Fabrication of ILs-Assisted AgTaO3 Nanoparticles for the Water Splitting Reaction: The Effect of ILs on Morphology and Photoactivity
PublikacjaThe design of an active, stable and ecient photocatalyst that is able to be used for hydrogen production is of great interest nowadays. Therefore, four methods of AgTaO3 perovskite synthesis, such as hydrothermal, solvothermal, sol-gel and solid state reactions, were proposed in this study to identify the one with the highest hydrogen generation eciency by the water splitting reaction. The comprehensive results clearly show that...
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The structure of strontium–borate glasses and glass-ceramics containing nanocrystallites of Bi2VO5.5. measured with X-ray diffraction method
Dane BadawczeThe structure of strontium–borate glasses and glass-ceramics containing Bi2VO5.5 nanocrystallites was measured by XRD.
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Thermal properties of strontium–borate glasses and glass-ceramics containing nanocrystallites of Bi2VO5.5. measured with DSC method
Dane BadawczeThermal properties of strontium–borate glasses and glass-ceramics containing nanocrystallites of Bi2VO5.5. was measured by DSC.
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Preliminary Testing of the Influence of Modified Polycaprolactones on Anabaena Variabilis Growth in Seawater
PublikacjaSeveral new biodegradable polymer materials have recently come onto the global market. Mostly the results on degradation kinetic studies are presented. This paper suggests using one of the tests to estimate the impact of polymer packaging material on sea life. The microorganism chosen was Anabaena variabilis (identified in many waters, including those of the Baltic Sea, especially in the Gulf of Gdansk and Puck Bay; this cyanobacterium...
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POM/EVA Blends with Future Utility in Fused Deposition Modeling
PublikacjaPolyoxymethylene (POM) is one of the most popular thermoplastic polymers used in the industry. Therefore, the interest in its potential applications in rapid prototyping is understandable. Nevertheless, its low dimensional stability causes the warping of 3D prints, limiting its applications. This research aimed to evaluate the effects of POM modification with ethylene-vinyl acetate (EVA) (2.5, 5.0, and 7.5 wt.%) on its processing...
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Novel Biomass-Based Polymers: Synthesis, Characterization, and Application
PublikacjaA wide range of polymers were prepared from biomass-derivatives, using different polymerization mechanisms. Well-defined, fully hydroxy-functional polyesters based on aliphatic diols were synthesized, using either conventional metal-based catalysts or the organic superbase 1,5,7-triazabicyclododecene (TBD). Unsaturated polyesters were also made, offering additional functionality to these biobased resins. Metal-catalyzed or enzymatic...
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Some kind of joints in composite polymer bridges
PublikacjaContemporary, polymer composites bridge structures are of two types: truss or arch structures(with many joints along the length) and beam structures with limited number of joints. Both of them have special types of composite polymer decks. An ideal solution is to join advantages of two types of structuresdescribed below and create long span FRP beam bridge structure system using joints along the length. Theproblem is to find the...
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Photocatalytic Decomposition of Air Pollutants using Electrodeposited Photocatalysts on Stainless Steel
PublikacjaThe aim of research was to develop an immobilization method for photocatalysts, which is an alternative to the sol-gel or dip coating methods and can be simply scaled up for technical applications. The investigated photocatalyst was TiO2, which was electrochemically deposited onto a cathode made of stainless steel. This deposited film was photocatalytically active. In order to enhance the photoactivity of the TiO2 film, commercially...
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Composite GFRP U-shaped footbridge
PublikacjaThe paper presents proposals for the use of glass fiber reinforced polymer composites for the construction of engineering objects, known and commonly used in the shipbuilding industry. An example of a pedestrian footbridge was used in this case, which, despite the considerable thickness of the structural material, was made using infusion technology in one production cycle. The designed and produced footbridge span is durable, dynamically...
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Fabrication and photoactivity of organic-inorganic systems based on titania nanotubes and PEDOT containing redox centres formed by different Prussian Blue analogues
PublikacjaHerein, the heterojunction composed of an inorganic substrate: ordered hydrogenated titania nanotubes (H-TiO2NTs) and a deposited organic film: poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. The conducting polymer is modified with different transition metal haxacyanoferrates (Mehcf), wherein as metal: copper, iron, cobalt and nickel are introduced. The presence of various metal centres provides characteristic redox activity...
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Shape Memory Materials from Rubbers
PublikacjaSmart materials are much discussed in the current research scenario. The shape memory effect is one of the most fascinating occurrences in smart materials, both in terms of the phenomenon and its applications. Many metal alloys and polymers exhibit the shape memory effect (SME). Shape memory properties of elastomers, such as rubbers, polyurethanes, and other elastomers, are discussed in depth in this paper. The theory, factors...
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Structure-rheology relationship of fully bio-based linear polyester polyols for polyurethanes - Synthesis and investigation
PublikacjaThe synthesis of polyols from renewable substances as an alternative for petrochemical-based polyols play important matter in the polyurethane industry. In this work, the fully bio-based linear polyester polyols with different catalyst amounts were synthesized via two-step polycondensation method. The effect of various catalyst content on the structure and rheological behavior were established. Fourier Transform Infrared Spectroscopy,...
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Systematic comparison of a biotrickling filter and a conventional filter for the removal of a mixture of hydrophobic VOCs by Candida subhashii
PublikacjaThis work systematically compared the potential of a conventional fungal biofilter (BF) and a fungal biotrickling filter (BTF) for the abatement of a mixture of hydrophobic volatile organic compounds (VOCs). Candida subhashii was herein used for the first time, to the best of the author's knowledge, to remove n-hexane, trichloroethylene, toluene and α-pinene under aerobic conditions. C. subhashii immobilized on polyurethane foam...
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Poroelastic Road Surfaces - State of The Art
PublikacjaPoroelastic Road Surfaces (PERS) constitute a specific group of pavements containing a great amount of crumbled rubber. In most cases rubber aggregate constitutes about 20% of the mixture (by weight) and a polyurethane resin is used as a binder. As a result, PERS is characterized by a much higher elasticity than asphalt and a high porosity typical for drainage pavements. Due to this, tire/road noise is greatly reduced and on top...
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Preparation and characterization of biodegradable and compostable PLA/TPS/ESO compositions
PublikacjaIn this study, biodegradable and compostable compositions, derived from totally natural feedstock/raw materials, namely polylactide (PLA), potato thermoplastic starch (TPS) and plant glycerin have been made by melt extrusion with epoxydized soybean oil (ESO) as reactive modifier in order to improve PLAs ductility and reduce the products cost without compromising biodegradation. The obtained PLA/mTPS(0,5ESO)[75/25] and PLA/ mTPS(2ESO)[75/25]...
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Characterization and Filtration Efficiency of Sustainable PLA Fibers Obtained via a Hybrid 3D-Printed/Electrospinning Technique
PublikacjaThe enormous world demand for personal protective equipment to face the current SARS-CoV-2 epidemic has revealed two main weaknesses. On one hand, centralized production led to an initial shortage of respirators; on the other hand, the world demand for single-use equipment has had a direct and inevitable effect on the environment. Polylactide (PLA) is a biodegradable, biocompatible, and renewable thermoplastic polyester, mainly...
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Enhancement of PUR/PIR foam thermal stability after addition of Zostera marina biomass component investigated via thermal analysis and isoconversional kinetics
PublikacjaIn the present work, a thorough thermogravimetric (TG) analysis of bio-based polyurethane–polyisocyanurate (PUR–PIR) foams in both nitrogen and oxygen atmosphere is performed. A sustainable element of the foam is a biopolyol obtained via acid-catalyzed liquefaction of Zostera marina and Enteromorpha Algae biomass. Based on isoconversional analysis and apparent activation energies, several conclusions are obtained. In contradiction...
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Dynamic tests of composite footbridge segment – experimental and numerical studies
PublikacjaExperimental dynamic tests and numerical simulations of a 3 meters long segment of a footbridge made of polymer composites are presented in the paper. The span-length is reduced, however dimensions of cross-section are the same as the target footbridge. The segment structure is made of sandwich panels, which consist of fibre reinforced polymer (GFRP) laminates (skins) and a PET foam (core). The first part of the paper contains...
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Widening of the electroactivity potential range by composite formation – capacitive properties of TiO2/BiVO4/PEDOT:PSS electrodes in contact with an aqueous electrolyte
PublikacjaComposites based on the titania nanotubes were tested in aqueous electrolyte as a potential electrode material for energy storage devices. The nanotubular morphology of TiO2 was obtained by Ti anodization. TiO2 nanotubes were covered by a thin layer of bismuth vanadate using pulsed laser deposition. The formation of the TiO2/BiVO4 junction leads to enhancement of pseudocapacitance in the cathodic potential range. The third component,...
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Thermal properties of ceramic Bi2VO5.5 and strontium–borate glass-ceramics containing crystalites of Bi2VO5.5. measured with DSC
Dane BadawczeThermal properties of ceramic Bi2VO5.5 and strontium–borate glass-ceramics containing Bi2VO5.5 crystallites was measured by DSC.
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Shaking table experimental study on the effectiveness of polymer bearings for seismic isolation of structures
PublikacjaSeismic isolation has been recognised to be a very effective way of protecting structures from damage during earthquakes. It allows us to extend the natural period of the structure and therefore avoid resonance with the ground motion. Moreover, by increasing damping in the isolation devices, more energy can be dissipated and thus the structural response can be further reduced. The aim of this paper is to show the results of the...
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Rheological properties, oxidative and thermal stability, and potential application of biopolyols prepared via two-step process from crude glycerol
PublikacjaIn this work, previously synthesized biopolyols were analyzed in terms of their rheological and thermal properties, very important from the technological point of view. For better evaluation of performed synthesis, the influence of its time and temperature on the properties of biopolyols was determined. In the end, obtained materials were used to prepare rigid polyurethane-polyisocyanurate (PUR-PIR) foams, to evaluate their potential...
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Analysis of Validation and Simplification of Timber-Frame Structure Design Stage with PU-Foam Insulation
PublikacjaThe transition from experimental studies to the realm of numerical simulations is often necessary for further studies, but very difficult at the same time. This is especially the case for extended seismic analysis and earthquake-resistant design. This paper describes an approach to moving from the experimental testing of an elementary part of a wood-frame building structure to a numerical model, with the use of a commercial engineering...
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Increasing the Seismic Resistance of Wood-frame Buildings by Applying PU Foam as Thermal Insulation
PublikacjaWood-frame buildings are very common in regions that are exposed to earthquakes. Most of residential buildings are constructed using this technology; therefore, the seismic resistance of them is really essential in order to prevent human losses and structural damage. The aim of the present article is to show the results of the detailed numerical FEM analysis focused on the seismic behaviour of the wood-frame house with different...
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Removal of cyclohexane and ethanol from air in biotrickling filters inoculated with Candida albicans and Candida subhashii
PublikacjaThis paper presents investigations on the removal of cyclohexane and ethanol from air in polyurethane- -packed biotrickling filters, inoculated with Candida albicans and Candida subhashii fungal species. Results on process performance together with flow cytometry analyses of the biofilm formed over packing elements are presented and discussed. The results indicate that the presence of ethanol enhances the removal efficiency of cyclohexane...
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Influence of conductive carbon and MnCo2O4 on morphological and electrical properties of hydrogels for electrochemical energy conversion
PublikacjaIn this work, a strategy for one-stage synthesis of polymer composites based on PNIPAAm hydrogel was presented. Both conductive particles in the form of conductive carbon black (cCB) and MnCo2O4 (MCO) spinel particles were suspended in the three-dimensional structure of the hydrogel. The MCO particles in the resulting hydrogel composite acted as an electrocatalyst in the oxygen evolution reaction. Morphological studies confirmed...
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NON-LINEAR MASTIC CHARACTERISTICS BASED ON THE MODIFIED MSCR (MULTIPLE STRESS CREEP RECOVERY) TEST
PublikacjaMastic containing asphalt in its composition is an example of a viscoelastic material. It is an effective binder in asphalt. It consists of a filler (<0.063 mm) and asphalt mixed in the right proportions. Just like in asphalt, its response depends on the temperature level, the load and stress time. Changing the stress stiffness of the mastic affects the non-linear course of the stress-strain relationship. Modelling of the non-linear...