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Search results for: speech%20synthesis
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New Method for the Synthesis of Azocrown Compounds Containing Oxygen, Nitrogen and Oxygen, or Sulfur Atoms in the Macroring.
PublicationW publikacji opisano nową metodę syntezy azokoron z różnymi heteroatomami w makrocyklu i o różnej wielkości molekularnej wnęki. Metoda ta polega na reakcji 2,2´-difluoroazobenzenu z diolami, diaminami, aminodiolami i ditiolamiw obecności zasady.
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Poly(amidoamine) Dendrimer/Camptothecin Complex: From Synthesis to In Vitro Cancer Cell Line Studies
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Synthesis and photocatalytic performance of TiO2 nanospheres–graphene nanocomposite under visible and UV light irradiation
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Synthesis, characterization, and photocatalytic properties of core/shell mesoporous silica nanospheres supporting nanocrystalline titania
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A chromatography-free total synthesis of a ferrocene-containing dendrimer exhibiting the property of recognizing 9,10-diphenylanthracene
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Tris(ferrocenylmethidene)sumanene: synthesis, photophysical properties and applications for efficient caesium cation recognition in water
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Novel and effective synthesis protocol of AgNPs functionalized using L-cysteine as a potential drug carrier
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New Insight into the Synthesis and Biological Activity of the Polymeric Materials Consisting of Folic Acid and β‐Cyclodextrin
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Sulfonated carbon-encapsulated iron nanoparticles as an efficient magnetic nanocatalyst for highly selective synthesis of benzimidazoles
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Ribes nigrum L. Extract-Mediated Green Synthesis and Antibacterial Action Mechanisms of Silver Nanoparticles
PublicationSilver nanoparticles (Ag NPs) represent one of the most widely employed metal-based engineered nanomaterials with a broad range of applications in different areas of science. Plant extracts (PEs) serve as green reducing and coating agents and can be exploited for the generation of Ag NPs. In this study, the phytochemical composition of ethanolic extract of black currant (Ribes nigrum) leaves was determined. The main components...
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Studies on Aminoanthraquinone-Modified Glassy Carbon Electrode: Synthesis and Electrochemical Performance toward Oxygen Reduction
PublicationIn this paper, 9,10-anthraquinone (AQ) derivative-modified glassy carbon (GC) electrodes were studied towards the electrochemical reduction of oxygen in aqueous and non-aqueous solutions. The reaction of 1-chloro-9,10-anthraquinone with aliphatic diamines was applied for the synthesis of amino-9,10-anthraquinone derivatives. The obtained AQ derivatives were grafted onto the surface of glassy carbon electrodes by electropolymerisation...
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Fluorine ions in photocatalysts’ synthesis: an obstacle or an ally? The investigation of photocatalysts in Ti-O-F system
PublicationTitanium(IV) oxide (TiO2) is one of the most promising photocatalysts, which is expected to be applied in the photocatalytic degradation of xenobiotics. For sustainable development and green chemistry approach recently, much effort has been paid to enhance TiO2 photocatalytic activity in UV-vis light by modifying its structure. The photocatalytic process’s complexity cannot be simply described as electron-hole pairs generations...
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Multivariate Assessment of Procedures for Molecularly Imprinted Polymer Synthesis for Pesticides Determination in Environmental and Agricultural Samples
PublicationIn the case of quantitative and qualitative analysis of pesticides in environmental and food samples, it is required to perform a sample pre-treatment process. It allows to minimalize the impact of interferences on the final results, as well as increase the recovery rate. Nowadays, apart from routinely employed sample preparation techniques such as solid-phase extraction (SPE) or solid-phase microextraction (SPME), the application...
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Supramolecular Synthesis Based on a Combination of Se···N Secondary Bonding Interactions with Hydrogen and Halogen Bonds
PublicationExamination of the solid state structures of 2,1,3-benzoselenadiazole complexes with hydrogen or halogen bond donors has demonstrated that the 2,1,3-benzoselenadiazole molecules preferably form centrosymmetric dimers with use of [Se–N]2 supramolecular synthon, whereas the two remaining nitrogen atoms not involved in the [Se–N]2 supramolecular interactions can act as acceptors of hydrogen or halogen bonds. Cocrystallization of selenadiazoles...
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Synthesis and Characterization of Monometallic (Ag, Cu) and Bimetallic Ag-Cu Particles for Antibacterial and Antifungal Applications
PublicationIn this paper, the experimental studies are concerned with the effect of the synthesis parameters on the formation of monometallic Ag and Cu nanoparticles (NPs). We consider the synthesis strategies verification for the bimetallic core-shell and alloy particles preparation. It was successfully obtained by chemical reduction method. The obtained colloidal solution is characterized by the transmission electron microscopy (TEM) with...
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Synthesis and Testing of BCZY/LNZ Mixed Proton–electron Conducting Composites for Fuel Cell Applications
PublicationA composite of BaCe0.6Zr0.2Y0.2O3–δ and Li2O:NiO:ZnO was investigated for fuel cell applications. The composite was successfully synthesized and its phase stability was confirmed at temperatures up to 900 °C. The influence of sintering and pressing aids on density was also investigated. Electrical properties were measured. DC electrical conductivity was about 8•10-4 S/m at 845 K. Open circuit voltage measurements in wet hydrogen...
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Silica nanospheres as a key process element in the Green engineering for the synthesis of carbon nanotubes as a supercapacitors additives
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Waste-free synthesis of silica nanospheres and silica nanocoatings from recycled ethanol–ammonium solution
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Integrated Experimental and Theoretical Approach for Efficient Design and Synthesis of Gold-Based Double Halide Perovskites
PublicationApplied cutting-edge electronic structure and phonon simulations provide a reliable knowledge about the stability of perovskite structures and their electronic properties, which are crucial for design of effective nanomaterials. Gold is one of the exceptional elements, which can exist both as a monovalent and a trivalent ion in the B site of a double perovskite such as A2BI BIIIX6. However, until now, electronic properties of Cs2AuI AuIIIX6...
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Synthesis, Characterization and Biological Investigations of Half-Sandwich Ruthenium(II) Complexes Containing Benzimidazole Moiety
PublicationHalf-sandwich Ru(II) complexes belong to group of biologically active metallo-compounds with promising antimicrobial and anticancer activity. Herein, we report the synthesis and characteri- zation of arene ruthenium complexes containing benzimidazole moiety, namely, [(η6-p-cymene)RuC l(bimCOO)] (1) and [(η6-p-cymene)RuCl2(bim)] (2) (where bimCOO = benzimidazole-2-carboxylate and bim = 1-H-benzimidazole). The compounds were characterized...
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Mangiferin Affects Melanin Synthesis by an Influence on Tyrosinase: Inhibition, Mechanism of Action and Molecular Docking Studies
PublicationMangiferin is a strong antioxidant that presents a wide range of biological activities. The aim of this study was to evaluate, for the first time, the influence of mangiferin on tyrosinase, an enzyme responsible for melanin synthesis and the unwanted browning process of food. The research included both the kinetics and molecular interactions between tyrosinase and mangiferin. The research proved that mangiferin inhibits tyrosinase...
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Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═P Bond Systems
PublicationThis report provides an overview of the use of phosphaalkenes (C=P) in syntheses of various complexes. Going through successive complexes containing the d-block metals, we sought how this area of chemistry was formed over the years. Additionally, this work contains information on the possible coordination types and means of constructing the complexes. In addition, this review reveals the reactivities of phosphaalkene complexes...
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Ag modified ZnO microsphere synthesis for efficient sonophotocatalytic degradation of organic pollutants and CO2 conversion
PublicationThe synthesis and design of non-precious and efficient sonophotocatalyts by an environment friendly technique are requisites for solar energy conversion and environmental remediation. This work reports the preparation of Ag/ZnO microspheres with different Ag contents through deposition–precipitation method for pollutant degradation and CO2 conversion. Detail structural investigation reveals that ZnO microspheres and Ag-ZnO microspheres...
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Synthesis, Structure, and Spectroscopic Properties of Calcium Thiophenecarboxylate Polymers. Structural Comparison with Analogous Lead Complexes
PublicationThree novel calcium coordination polymers [Ca(2tpCOO)2(2mpa)(H2O)]n (1), [Ca(3tpCOO)2(2mpa)(H2O)]n (2), and {[Ca(3tpacCOO)2(H2O)2]⋅⋅⋅H2O}n (3) (2tpCOO− or 3tpCOO− – thiophene-2- or thiophene-3-carboxylate, 3tpacCOO− – thiophene-3-acetate, 2mpa – 2-methylpropanal), were synthesised using a self-assembly method. The obtained polymers were characterised using SC-XRD, FTIR, UV-Vis DRS, thermogravimetric and luminescence analyses. The...
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From tryptophan to novel mitochondria-disruptive agent, synthesis and biological evaluation of 1,2,3,6-tetrasubstituted carbazoles
PublicationMitochondrial targeting plays an important role in anticancer therapy. The Mn(III)-promoted cyclization of 5- (1H-indol-3-yl)-3-oxopentanoic acid allow to obtain novel substituted carbazole derivatives that can act as mitochondria-disruptive agents. The starting materials used for the synthesis of these new aminocarbazoles are oxopentanoate derivatives of tryptophan. The scope and limitation of this method of synthesis are determined...
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Synthesis, Structure and Properties of Poly(ester-Urethane-Urea)s Synthesized Using Biobased Diamine
PublicationModern polymer science and technology is focused on the development of partial or fully green polymers. This focus is related to green chemistry trends, which propose using natural and renewable resources as monomers in the synthesis of polymers. In this study, biobased diamine was used as a chain extender of ester-urethane prepolymer. Obtained poly(ester-urethane-urea) contains 16 wt% of biobased diamine. There is mention of an...
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Synthesis of 3-Carbamoyl b-Lactams via Manganese(III)-Promoted Cyclization of N-Alkenylmalonamides
PublicationManganese(III)-promoted cyclization of N-alkenylmalonamides (¼N-alkenylpropanediamides) gave 3-(aryl/(alkylamino)carbonyl) b-lactams as well as 3-(aryl/(alkylamino)thiocarbonyl) b-lactams. The relative configuration of the obtained products was unambiguously determined by X-ray crystallography. The proposed method is very useful for the one-pot synthesis of a number of 3-(aryl/ (alkylamino)carbonyl) b-lactams, especially those...
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The ILs-assisted solvothermal synthesis of TiO2 spheres: the effect of ionic liquids on morphology and photoactivity of TiO2
PublicationEffect of the ionic liquid (IL) structure (chain length in the imidazolium cation) on morphology and photoactivity of TiO2 particles has been systematically investigated. The TiO2 microspheres have been successfully synthesized via facile solvothermal method assisted by ionic liquids, such as 1-butyl-3-methylimidazolium chloride [BMIM][Cl] and 1-decyl-3-methylimidazolium chloride [DMIM][Cl] using tetra-tert-butyl orthotitanate...
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Fluorescent analogs of trypsin inhibitor SFTI-1 isolated from sunflower seeds-synthesis and applications
PublicationThis article describes the synthesis and enzymatic study of newly synthesized analogs of trypsin inhibitors SFTI-1 that were fluorescent labeled on their N-terminal amino groups. Two fluorescent derivatives of benzoxazole (3-[2-(4-diphenylaminophenyl) benzoxazol-5-yl]-L-alanine[(4NPh(2)) Ph] Box-Ala and 3-[2-(2', 4', 5'-trimethoxyphenyl) benzoxazol-5-yl]-l-alanine-[2,4,5-(OMe)3Ph] Box-Ala) were used as efficient fluorescent labels....
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Synthesis, Molecular Structure, Metabolic Stability and QSAR Studies of a Novel Series of Anticancer N-Acylbenzenesulfonamides
PublicationA series of novel N-acyl-4-chloro-5-methyl-2-(R1-methylthio)benzenesulfonamides 18–47 have been synthesized by the reaction of N-[4-chloro-5-methyl-2-(R1-methylthio) benzenesulfonyl]cyanamide potassium salts with appropriate carboxylic acids. Some of them showed anticancer activity toward the human cancer cell lines MCF-7, HCT-116 and HeLa, with the growth percentages (GPs) in the range from 7% to 46%. Quantitative structure-activity relationship...
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Synthesis and biological activity of ester derivatives of mycophenolic acid and acridines/acridones as potential immunosuppressive agents
PublicationImproved derivatives of mycophenolic acid (MPA) are necessary to reduce the frequency of adverse effects, this drug exerts in treated patients. In this study, MPA was coupled with N-(x-hydroxyalkyl)-9-acridone-4-carboxamides or N-(x-hydroxyalkyl)acridine-4-carboxamides to give respective ester conjugates upon Yamaguchi protocol. This esterification required protection of phenol group in MPA. Designed conjugates revealed higher...
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Trichrome Mallory's stain may indicate differential rates of RNA synthesis in eutopic and ectopic endometrium.
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Accidents, victims and risk levels on regional roads in pomorskie voivodeship, 2017-2019 - Excessive speed accidents
Open Research DataData contain risk classification on regional roads (voivodeship roads) in pomorskie voivodeship in 2017-2019, cause of accidents: Excessive speed accidents. Measures used to assess the level of risk are (5 classes low, low to medium, medium, medium to high, high):
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Experimental study on the selected aspects of bow thruster generated flow field at ship zero-speed conditions
PublicationThe paper presents the results of experimental study on the interaction between the bow thrusters understood as the flow field changes generated by bow tunnel thruster in deep water conditions operated as a single and twin units. The research was limited to zero-speed case for the ship dead in the water. The influence of the hull form and jet spread between the neighbouring thrusters for several combinations of the applied bow...
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Assessment of the Speed Management Impact on Road Traffic Safety on the Sections of Motorways and Expressways Using Simulation Methods
PublicationMethods used to evaluate the impact of Intelligent Transport System (ITS) services on road safety are usually based on expert assessments or statistical studies. However, commonly used methods are challenging to apply in the planning process of ITS services. This paper presents the methodology of research using surrogate safety measures calculated and calibrated with the use of simulation techniques and a driving simulator. This...
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The Use of Different Modes of Post-Activation Potentiation (PAP) for Enhancing Speed of the Slide-Step in Basketball Players
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Speed sensorless ac drive with inverter output filter and fault detection using load torque signal
PublicationIn this paper, a sensorless induction motor (IM) drive using speed observer system is presented. The system includes load torque computation for gear fault detection. Nonlinear control method is adopted for controlling the motor over a wide speed range. An LC filter for smoothing current and voltage waveforms is used at the output of the voltage inverter. The use of filter imposes more building of the used observer to avoid using...
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Appliance of High Speed Camera during Industrial Exploitation on the Example of Static and Dynamic Tests of Steel Probes
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Study of prototype multi-pole non-salient field winding for high speed brushless synchronous generator
PublicationIn this paper a non-salient field winding for a brushless synchronous generator working with high speed in an autonomous energy generation system (e.g. airplane power grid) has been presented. A conception of a six-pole cylindrical-rotor with distributed field winding has been proposed. Comparison study of salient and prototype non-salient field winding has been carried out. Chosen simulation and measurement results of the generator...
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Tilting pad thrust bearing with novel material selection - experimental comparison of low and medium speed operation
PublicationThe advances in material engineering led to the development of hard carbon based coatings applied in numerous applications in order to prevent or minimize wear of the parts in contact. With Triondur® coatings, the bearing company Schaeffler has succeeded in halving the friction losses in the valve trains of passenger cars. The coatings are optimized for high abrasive wear protection and low sliding friction moments. Altogether...
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Hydroacoustic System in a Biomimetic Underwater Vehicle to Avoid Collision with Vessels with Low-Speed Propellers in a Controlled Environment
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Research of low-speed high torque planet motors supplied with oil-in-water emulsion as working liquid.
PublicationWiększość hydraulicznych układów napędowych obecnie jest zasilanych olejami. Ale olej jako medium robocze nie może być stosowany wszędzie tam, gdzie istnieje ryzyko pożaru. dlatego też są stosowane trudnopalne i niepalne ciecze hydrauliczne ja: emulsje, mikroemulsje i roztwory. W referacie opisano stanowisko badawcze zaprojektowane i zbudowane w Katedrze Hydrauliki i Pneumatyki PG, przedstawiono wyniki badań hydraulicznego silnika...
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Sensorless Control of Induction Motor Based on Super-Twisting Sliding Mode Observer With Speed Convergence Improvement
PublicationThe super twisting sliding-mode observer (ST-SMO) has been proposed to achieve an effective method for alleviating low-order harmonics of measured quantities, issues related to DC drift, and suppression of chattering due to low-frequency sampling. The conventional ST-SMO, on the other hand, suffers from control delay in the convergence trajectory due to the system disturbance, resulting in decreased anti-disturbance capability...
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Experimental Study of Flow Rate in Hydraulic Satellite Motor with the Rotating Case at a Low Constant Rotational Speed
PublicationIn this article was described the methodology for the experimental study of flows in the prototype of a satellite hydraulic motor with a rotating body. The experimental tests of the motor were carried out at a low constant rotational speed in a wide range of pressure drop in this motor. The constant rotational speed of the motor was kept by a worm gear. Based on the test results, the leakage characteristics in the flat gaps of...
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Examining Impact of Speed Recommendation Algorithm Operating in Autonomous Road Signs on Minimum Distance between Vehicles
PublicationAn approach to a new kind of recommendation system design that suggests safe speed on the road is presented. Real data obtained on roads were used for the simulations. As part of a project related to autonomous road sign development, a number of measurements were carried out on both local roads and expressways. A speed recommendation model was created based on gathered traffic data employing the traffic simulator. Depending on...
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Modelling of the High Speed Multi-Pole Synchronous Generator for Application in More Electric Aircraft Power Systems
PublicationIn this paper different models of the synchronous generator are presented. The simulation results compared with the measurements are shown. Certain physical phenomena are included in described models for the porpoise of adequate analysis of the more electric aircraft power system. For different modelling levels, such as functional level or behavioural level, different physical phenomena have been included. Simulation results for...
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Speed Sensorless AC Drive with Inverter LC Filter and Fault Detection Using Load Torque Signal
PublicationThe industrial development in recent years has seen a major increase in the use of induction motors, whereby the cost has to be as low as possible and the lifetime as long as possible. To follow up this desire, investigations in this area have become very intense. For that reason, this paper presents a solution for driving an induction motor and simultaneous fault detection with no need for additional sensors. In order to achieve...
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Improvement of microstructure and mechanical properties of high dense sic ceramics manufactured by high-speed hot pressing
PublicationNon-oxide ceramics possess high physical-mechanical properties, corrosion and radiation resistance, which can be used as a protective materials for radioactive wastes disposal. The aim of the present study was the manufacturing of high density SiC ceramics with advanced physical and mechanical parameters. The high performance on the properties of produced ceramics was determined by the dense and monolithic structure. The densified...
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Pedestrian protection, speed enforcement and road network structure the key action for implementing Poland's Vision Zero
PublicationSince 1991 Poland's road safety has been systematically improving with a 60% reduction in road deaths. Despite the progress Poland continues to be one of the European Union' worst performing countries. The country's main road safety problems remain unchanged: dangerous behaviour of road users, underdeveloped system of road safety management and low quality of road infrastructure. This is why subsequent road safety programmes (implemented...
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Modeling the impact of rotor movement on non-linearity of motor currents waveforms in high-speed PMSM drives
PublicationMotor current measurement techniques as well as predictive control algorithms for electric drives rely on an assumption of linear motor currents changes resulting from constant inverter output voltages. Recent research has reported that this assumption does not hold in motors with short electrical time constant, and in drives whose rotor position advances substantially during a control period. This paper proposes a simulation model...