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Search results for: SEPARACJA CO2
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Analiza Nagrań Ruchu Drogowego w Kontekście Akustycznej Klasyfikacji Typu Pojazdu
PublicationCelem niniejszej pracy jest przeprowadzenie analizy sygnału fonicznego w kontekście klasyfikacji typu pojazdu. Część teoretyczna zawiera krytyczny przegląd systemów monitorowania ruchu drogowego, w szczególności systemów ITS (Intelginet Transport System). Część praktyczna przedstawia założenia dotyczące przygotowania bazy nagrań testowych, uwzględniających różne scenariusze ruchu drogowego. Zarejestrowane sesje nagraniowe przetworzono,...
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Polimery przewodzące jako fotokatalizatory aktywne w świetle widzialnym do degradacji zanieczyszczeń w fazie wodnej
PublicationZanieczyszczenie środowiska wodnego trudno degradowalnymi związkami organicznymi stanowi jeden z ważniejszych problemów XXI wieku. Procesy fotokatalityczne wykorzystujące promieniowanie widzialne oraz słoneczne są obiecującą technologią oczyszczania wody. Wśród materiałów mających zastosowanie w fotokatalizie coraz większe znaczenie odgrywają polimery przewodzące, charakteryzujące aktywnością w świetle widzialny. Na podstawie dokonanego...
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Efficient handover scheme for Mobile IPv4 over IEEE 802.11 networks with IEEE 802.21 triggers.
PublicationEfektywność przełączania jest bardzo istotnym parametrem, decydującym o pracy sieci bezprzewodowych, realizujacych usługi multimedialne na wysokim poziomie jakości. Użytkownicy takich sieci oczekują ciągłej obsługi podczas procesu przemieszczania się. Okazuje się, że istotnym źródlem opóźnień są nieefektywne procedury przełączania w warstwach drugiej i trzeciej, wynikający częściowo z postulatu o separacji funkcji realizowanych...
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Na3PO4 assistant dispersion of nano-CaCO3 template to enhance electrochemical interface: N/O/P co-doped porous carbon hybrids towards high-performance flexible supercapacitors
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Magnetic anisotropy and structural flexibility in the f ield-induced single ion magnets [Co{(OPPh2) (EPPh2)N}2], E = S, Se, explored by experimental and computational methods
PublicationDuring the last few years, a large number of mononuclear Co(II) complexes of various coordination geometries have been explored as potential single ion magnets (SIMs). In the work presented herein, the Co(II) S = 3/2 tetrahedral [Co{(OPPh2)(EPPh2)N}2], E = S, Se, complexes (abbreviated as CoO2E2), bearing chalcogenated mixed donor-atom imidodiphosphinato ligands, were studied by both experimental and computational techniques. Specifically,...
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Magazynowanie energii elektrycznej
PublicationŚwiatowa gospodarka opiera się na energii, dlatego wymaga się, aby energia była łatwo dostępna, stosunkowo tania, a jej dostawy niezawodne. Zmiany klimatyczne powodują jednak, że wzrastają wymogi dotyczące redukcji emisji CO2, a co za tym idzie – zwiększenia udziału „zielonej energii” pochodzącej ze źródeł odnawialnych. Ramy europejskiej polityki klimatyczno-energetycznej do roku 2030 zakładają m.in. redukcję emisji ditlenku węgla...
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The Reactivity of Phosphanylphosphinidene Complexes of Transition Metals Toward Terminal Dihaloalkanes
PublicationThe reactivities of phosphanylphosphinidene complexes [(DippN)2W(Cl)(η2-P−PtBu2)]− (1), [(pTol3P)2Pt(η2- P=PtBu2)] (2), and [(dppe)Pt(η2-P=PtBu2)] (3) toward dihaloalkanes and methyl iodide were investigated. The reactions of the anionic tungsten complex (1) with stochiometric Br(CH2)nBr (n = 3, 4, 6) led to the formation of neutral complexes with a tBu2PP(CH2)3Br ligand or neutral dinuclear complexes with unusual tetradentate...
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Modification of ASM3 for the determination of biomass adsorption/storage capacity in bulking sludge control
PublicationSystemy osadu czynnego z selektorami (SAS) umożliwiają ograniczenie nadmiernego wzrostu bakterii nitkowatych, które odpowiadają za zjawisko zwanę ''puchnięciem osadu''. Celem tych badań było opracowanie modelu matematycznego opisującego szybkie usuwanie substratu w systemach SAS. W tym celu zmodyfikowano Model Osadu Czynnego nr 3 (ASM3) poprzez dodanie równań opisujących zjawiska adsorpcji i bezpośredniego wzrostu bakterii na zaadsorbowanym...
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Synthesis and characterization of novel renewable polyesters based on 2,5-furandicarboxylic acid and 2,3-butanediol
PublicationNovel polyesters from 2,5-furandicarboxylic acid or 2,5-dimethyl-furandicarboxylate and 2,3-butanediol have been synthesized via bulk polycondensation catalyzed by titanium (IV) n-butoxide, tin (IV) ethylhexanoate, or zirconium (IV) butoxide. The polymers were analyzed by size exclusion chromatography, nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy (FTIR), matrix-assisted laser ionization-desorption...
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Kinetics of Cross-Linking Reaction of Epoxy Resin with Hydroxyapatite-Functionalized Layered Double Hydroxides
PublicationThe cure kinetics analysis of thermoset polymer composites gives useful information about their properties. In this work, two types of layered double hydroxide (LDH) consisting of Mg2+ and Zn2+ as divalent metal ions and CO32− as an anion intercalating agent were synthesized and functionalized with hydroxyapatite (HA) to make a potential thermal resistant nanocomposite. The curing potential of the synthesized nanoplatelets in the...
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Fitted impedance spectra of a symmetrical porous Sr0.86Ti0.65Fe0.35O3 oxygen electrode (sintered at 1000 °C, measured at 700 °C and 0.1% pO2) with an individual contributions of the respective fitting elements
Open Research DataThis dataset contains exemplary impedance spectra (measured at 700 °C and 0.1% pO2) for porous Sr0.86Ti0.65Fe0.35O3 oxygen electrode sintered at 1000 °C. Results of symmetric cell impedance measurement were converted to electrode surfaces area and dived by two electrodes. Dataset conatins also fitting results and individual contributions of the respective...
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Fitted impedance spectra of a symmetrical porous Sr0.86Ti0.65Fe0.35O3 oxygen electrode (sintered at 1000 °C, measured at 800 °C and 0.1% pO2) with an individual contributions of the respective fitting elements
Open Research DataThis dataset contains exemplary impedance spectra (measured at 800 °C and 0.1% pO2) for porous Sr0.86Ti0.65Fe0.35O3 oxygen electrode sintered at 1000 °C. Results of symmetric cell impedance measurement were converted to electrode surfaces area and dived by two electrodes. Dataset conatins also fitting results and individual contributions of the respective...
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On the possibility of the application of magnetoacoustic emission intensity measurements for the diagnosis of thick-walled objects in the industrial environment
PublicationArtykuł przedstawia wyniki pomiarów sygnału emisji magnetoakustycznej (EMA) wykonanych na obiektach grubościennych w środowisku przemysłowym oraz omawia możliwe sposoby jego dalszej analizy. Pomimo tego, ze bezpośredni pomiar sygnału EMA nie pozwala na określenie jego natężenia w artykule wykazano, że możliwa jest separacja użytecznego sygnału od szumów tła albo poprzez analogowe filtrowanie sprzętowe albo poprzez cyfrową analizę...
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Barbara Becker prof. dr hab. inż.
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An improved method for flow boiling heat transfer with account of the reduced pressure effect
PublicationIn the paper are presented the results using the authors own model to predict heat transfer coefficient during flow boiling. The model has been tested against a large selection of experimental data to investigate the sensitivity of the in-house developed model. In the work are presented the results of calculations obtained using the semi-empirical model on selected experimental flow boiling data of the refrigerants: R134a, R1234yf,...
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Multistage treatment wetland for treatment of reject waters from digested sludge dewatering
PublicationThe paper presents the influence of sewage composition on treatment in pilot-scale facility for reject waters (RW) from sewage sludge centrifugation. The facility consisted of mechanical (two tanks with 10 d retention each) and biological parts composed of three subsurface flow reed beds working in batch. Two years of monitoring of the facility proved high efficiency removal of predominant pollutants: COD 75–80%, BOD 82.2–95.5%...
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Clinical studies of detecting COVID-19 from exhaled breath with electronic nose
PublicationThe COVID‑19 pandemic has attracted numerous research studies because of its impact on society and the economy. The pandemic has led to progress in the development of diagnostic methods, utilizing the polymerase chain reaction (PCR) as the gold standard for coronavirus SARS‑CoV‑2 detection. Numerous tests can be used at home within 15 min or so but of with lower accuracy than PCR. There is still a need for point‑of‑care tests available...
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Exsolution of Ni nanoparticles on the surface of cerium and nickel co-doped lanthanum strontium titanate as a new anodic layer for DIR-SOFC. Anti-coking potential and H2S poisoning resistance of the prepared material
PublicationThe aim of this study was to evaluate a new catalytic material for biogas fueled DIR-SOFC. This material was a perovskite-type SrTiO3 doped with La, Ce and Ni of a general formula La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-σ (LSCNT). Additional preparation steps were undertaken to promote a nickel exsolution process. Heat post-treatment of powders in a humidified H2 resulted in an intensive growth of nickel nanoparticles (NPs) while the temperature...
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Nitrogen mass balance and mathematical model of a Structured- Bed Reactor (SBRRIA)
PublicationAn up-flow structured-bed reactor subjected to recirculation and intermittent aeration (SBRRIA) was operated under varying influent conditions. The influent COD/N ratio was adjusted by maintaining a stable organic loading rate (average of 1.07 kgCOD m-3 d-1) and changing the nitrogen loading rate from 0.1 to 0.4 kg N m-3. Therefore, three different COD/N ratios were tested: 9.7±1 (Scenario 1); 7.6±1 (Scenario 2) and 2.9±1 (Scenario...
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The joint effect of electrical conductivity and surface oxygen functionalities of carbon supports on the oxygen reduction reaction studied over bare supports and Mn–Co spinel/carbon catalysts in alkaline media
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Salinity enhances high optically active L-lactate production from co-fermentation of food waste and waste activated sludge: Unveiling the response of microbial community shift and functional profiling
PublicationLactic acid (LA), a versatile platform molecule, can be fermented from organic wastes, such as food waste and waste activated sludge. In this study, an efficient approach using salt, a component of food waste as an additive, was proposed to increase LA production. The LA productivity was increased at 10 g NaCl/L and optical pure L-lactate was obtained at 30 g NaCl/L. The enhancement of LA was in accordance with the increased solubilization...
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Design, engineering, and performance of nanorod-Fe2O3@rGO@LaSrFe2-Co O6 (n = 0, 1) composite architectures: The role of double oxide perovskites in reaching high solar to hydrogen efficiency
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Anisotropic optical properties of few-layer black phosphorus coatings: from fundamental insights to opto-electrochemical sensor design
PublicationFew-layer black phosphorus (FLBP) is characterised by a tuneable bandgap, high carrier mobility and anisotropic optical properties. It therefore has the potential to find applications in electronics and photonics. FLBP oxidizes upon exposure to air, limiting its utility in devices and components. To address this issue, the thesis introduces methods and tools developed for studying FLBP's optical parameters, with a particular emphasis...
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Projektowanie i budowa w czasie zagrożenia SARS-CoV-2-webinar
e-Learning CoursesProjektowanie i budowa w czasie zagrożenia SARS-CoV-2 - webinar prowadzący: dr inż. Marcin Szczepański oraz goście online
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Nuclear power plant as a source of electrical energy and heat
PublicationIn this paper certain issues concerning usage of nuclear power plants as sources of not only electric power but also thermal energy will be discussed. For such a solution appeals most of all the need to limit harmful emissions of gases (including CO2) and ashes, which come from the process of burning fossil fuels, as well as the raising demand for network heat and chill. Additionally combined heat and power production brings measurable...
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Wytwarzanie energii elektrycznej - diagnoza i terapia
PublicationW artykule przeanalizowano stan i dalszy rozwój krajowego sektora wytwarzania energii elektrycznej w świetle najnowszych raportów Międzynarodowej Agencji Energetycznej, wskazujących potencjalne trendy i perspektywy w światowej energetyce. Na tle przewidywanego wzrostu zapotrzebowania na energię elektryczną wskazano na możliwość istotnego ograniczenia emisji CO2 drogą zastąpienia przestarzałych, nieefektywnych...
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Ambiphilic phosphorous compounds 2
Open Research DataResults of theoretical and experimental studies on ambiphilic phosphorous compounds:
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From phosphanylphosphaalkenes to coordination copper and silver polymers containing P–P bonds
PublicationThis study was focused on the activation of the C[double bond, length as m-dash]P bond via reactions of Ph2C[double bond, length as m-dash]P-PtBu2 (1) with 1,6-hexanediol and selected dithiols (1,4-butanedithiol, 1,4-benzenedithiol and 1,4-benzenedimethanethiol). These reactions proceed according to a 1,2-addition mechanism, providing new compounds with formulas {(Ph)2(H)C-P-PtBu2}{μ2-(O-(CH2)6-O)}{tBu2P-P-C(H)(Ph)2} (2), {(Ph)2(H)C-P-PtBu2}{μ2-(S-(CH2)4-S)}{tBu2P-P-C(H)(Ph)2}...
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Treatment of bitumen post oxidative effluents by sulfate radicals based advanced oxidation processes (S-AOPs) under alkaline pH conditions
PublicationSulfate radicals based Advanced Oxidation Processes (S-AOPs), namely Persulfate and peroxymonosulfate, were used for the treatment of post oxidative effluents from a production of petroleum bitumens under alkaline pH. Studies on the identification and monitoring of the volatile organic compounds (VOCs) along with COD, BOD and sulfide ions reduction were performed. Persulfate with a ratio between the oxygen from the oxidant and...
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Study of Different Advanced Oxidation Processes for Wastewater Treatment from Petroleum Bitumen Production at Basic pH
PublicationEffluents from production of petroleum bitumens were submitted to treatment by three different AOPs at basic pH (i.e., O3, H2O2 and the combination of O3 and H2O2, a so-called peroxone). The paper presents studies on the identification and monitoring of the volatile organic compounds (VOCs) degradation present in the effluents and formation of byproducts, COD, BOD5, sulfide ions, biotoxicity, and biodegradability changes during...
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Raman data of based on BDD, Mn-BDD, Mn-BDD(AN) electrodes
Open Research DataRaman spectra of samples : ion implanted BDD (Mn-BDD) films; prepared by high dose (1015-1017 ions/cm2) Mn ion implantation and post-annealing treatment.
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Phosphorus and nitrogen forms in liquid fraction of digestates from agricultural biogas plants
PublicationThe novelty of the presented research is the determination of the nitrogen and phosphorus fraction in the liquid fraction of digestate from agricultural biogas plants. This information is important because it can help in proposing possible further liquid fraction management or developing of new technologies for their purification. The research covered digestates from agricultural biogas plants, obtained from the fermentation of...
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Structure, Physicochemical and Biological Properties of an Aqua (2,2′,2′′-Nitrilotriacetato)-oxidovanadium(IV) Salt with 4-Methylpyridinium Cation
PublicationThe crystal structure of a nitrilotriacetate (nta) oxidovanadi-um(IV) salt with 4-methylpyridinium cation, [4-Me(Py)H]+, of [4-Me(Py)H][VO(nta)(H2O)] stoichiometry was determined. The com-plex comprises a discrete mononuclear [VO(nta)(H2O)]–coordinationentity that can be rarely found among other known compounds con-taining nitrilotriacetate oxidovanadium(IV) moieties. The complex wascharacterized by spectroscopic (IR and EPR) methods,...
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Green porous benzamide-like nanomembranes for hazardous cations detection, separation, and concentration adjustment
PublicationGreen biomaterials play a crucial role in the diagnosis and treatment of diseases as well as health-related problem-solving. Typically, biocompatibility, biodegradability, and mechanical strength are requirements centered on biomaterial engineering. However, in-hospital therapeutics require an elaborated synthesis of hybrid and complex nanomaterials capable of mimicking cellular behavior. Accumulation of hazardous cations like...
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Electrical conductivity relaxation measurements - oxidation and reduction of BaCe0.6Zr0.2Y0.1Tb0.1O3-δ
Open Research DataThe dataset consists of 2 main catalogs: measurements performed for oxidation/reduction in dry conditions and in humid conditions. For Electrical Conductivity Relaxation (ECR) measurements, platinum reversible electrodes were applied in a four-probe arrangement and the sample was measured in the ProboStat™ measurement system. The ECR measurements were...
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Carbon dioxide photoconversion. The effect of titanium dioxide immobilization conditions and photocatalyst type.
PublicationBadanie efektywności procesu fotokonwersji CO2 prowadzono w fazie gazowej w obecności promieniowania UV-Vis, pary wodnej oraz fotokatalizatorów. Zbadano wpływ wybranych parametrów tj. masa, temperatura i czas suszenia fotokatalizatora oraz rodzaj nośnika na efektywność procesu fotokonwersji. Wyznaczono optymalne parametry prowadzenia procesu oraz przedstawiono wstępne wyniki badań w obecności fotokatalizatorów modyfikowanych nanoczastkami...
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Influence of cavitation intensity on the relative cavitation resistance of laser processed C45 carbon steel
PublicationPraca przedstawia badania względnej odporności kawitacyjnej we wstępnym okresie niszczenia laserowo przetopionej 6 kW laserem CO2 stali C45. Badania odporności kawitacyjnej wykonano na stanowisku z wirującą tarczą. Na erodowanej przetopionej warstwie powierzchniowej określono trzy obszary o różnej intensywności oddziaływania obciążeń kawitacyjnych. Określano wielkość odkształceń plastycznych w analizowanych obszarach, spowodowanych...
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Perspektywy wykorzystania gazu ziemnego do produkcji energii elektrycznej w Polsce
PublicationW artykule omówiono podstawowe przesłanki, które mogą decydować o wykorzystaniu technologii gazowych do produkcji energii elektrycznej w Polsce. Przedstawiono aktualną strukturę wytwarzania energii elektrycznej w krajowym systemie elektroenergetycznym. Zostały przedstawione prognozy wzrostu zapotrzebowania na energię elektryczną w perspektywie 2030 r. Wskazano na konieczność zmiany bazy paliw dla systemu elektroenergetycznego....
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Natural ventilation performance of family building in cold climate during windy days
PublicationAdequately designed natural ventilation is the cheapest and easiest way to effectively remove indoor pollutants and keep the fresh air inside a building. A prediction of performance and effectiveness of ventilation in order to determine the design of a ventilation system can provide real and long term cost savings. The paper presents results of performance (air change rate ACH) and effectiveness (CO2 concentration in the breathing...
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Singlet oxygen-dominated peroxymonosulfate activation by layered crednerite for organic pollutants degradation in high salinity wastewater
PublicationAdvanced oxidation processes have been widely studied for organic pollutants treatment in water, but the degradation performance of radical-dominated pathway was severely inhibited by the side reactions between the anions and radicals, especially in high salinity conditions. Here, a singlet oxygen (1O2)-dominated non-radical process was developed for organic pollutants degradation in high salinity wastewater, with layered crednerite...
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Structural analysis and physico-chemical characterization of mononuclear manganese(II) and polynuclear copper(II) complexes with pyridine-based alcohol
PublicationTwo novel manganese(II) and copper(II) complexes, mononuclear [Mn(H2O)2(2-(CH2)2OHpy)2](NO3)2 (1) and polynuclear [Cu(SO4)(2-(CH2)2OHpy)2]n (2), based on 2-(hydroxyethyl)pyridine (2-(CH2)2OHpy) were synthesised and fully characterised using X-ray structure analysis as well as spectroscopic, magnetic and thermal methods. Both central metal ions Mn(1) and Cu(1) are coordinated by two N,O-donor 2-(CH2)2OHpy ligands and possess an...
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Changes in enzymatic activity of fish and slaughter animals meat after high pressure treatment at subzero temperatures
PublicationThe aim of this study was to determine changes in the activity of proteolytic enzymes and transglutaminase of fish and mammal meat after pressurization at subzero temperatures. The activity was measured at the optimal pHs determined for enzymes from particular types of tested meat. It was found that increasing the pressure in the range of 60–193 MPa, did not change significantly the activity of acidic proteases of cod flesh, while...
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Investigation of catalytic layers on anode for solid oxide fuel cells operating with synthetic biogas
PublicationIn this paper solid oxide fuel cells operating with dry synthetic biogas have been examined. In order to increase their stability the layers of CuO-CeO2, Cu1.3Mn1.7O4 and Y0.08Sr0.92Ti0.8Fe0.2O3 -δ have been deposited on the Ni-YSZ anode site. These layers should catalyze the internal biogas reforming and prevent the carbon deposition on the anode site. It has been found that CuO-CeO2 and Cu1.3Mn1.7O4 catalysts led to an increase...
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Laser induced formation of copper species over TiO2 nanotubes towards enhanced water splitting performance
PublicationWe proposed fast and scalable route where the ordered TiO2 nanotubes coated with thin copper layers were annealed by the laser beam of 355 nm wavelength at different fluencies in the range of 15–120 mJ/cm2. As a result, copper species are integrated with the titania substrate and the formed material exhibits unique optical absorption bands in the visible range. Moreover, X-ray photoelectron spectroscopy analysis reveals the formation...
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Highly stable organic–inorganic junction composed of hydrogenated titania nanotubes infiltrated by a conducting polymer
PublicationA poly(3,4-ethylenedioxythiophene) conducting polymer doped with poly(2-styrene sulfonate) (pEDOT:PSS) was efficiently electrodeposited on a layer composed of ordered titania nanotubes. TiO2 nanotubes were formed during an anodization process and, after calcinations, a layer was subjected to hydrogen plasma. Hydrogenation leads to Ti(III) formation, a decrease in resistance, and a huge increase of donor density when compared with...
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Nonlinear impedance of as-quenched Bi2VO5.5 glass-ceramic was measured with impedance spectroscopy method at low temperature region
Open Research DataThe nonlinear electrical properties of as-quenched Bi2VO5.5 glass-ceramic was measured by impedance spectroscopy method.
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Fluctuation of nitrogen fraction during wastewater treatment in a multistage treatment wetland
PublicationFactors influencing COD and removal and transformation of N fractions have been investigatedin the conditions of horizontal (SSHF) and vertical (SSVF) flow reed beds. Multistage treatment wetlandin Wiklino ensured a stable and very effective removal of all the analysed pollutants. Based onthe resultsof investigation, it could be assumed that the working conditions of SSHF beds play an importantrole in the transformation of particulate...
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Relationships Between Geographical and Virtual Proximity in Cluster Organisations
PublicationThe purpose of the paper is to explore the relationships between geographical and virtual proximity in cluster organizations (COs). The authors report the findings of a qualitative study conducted in four COs in Poland. The basic technique for collecting and analyzing data was an in-depth individual interview and qualitative content analysis. The research has shown that the relationships between geographical and virtual proximity...
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Influence of composition of raw wastewater on removal of nitrogen compounds in multistage treatment wetlands
PublicationInfluence of composition of raw wastewater on the efficiency of organic matter and nitrogen removal in multistage treatment wetlands has been examined. Commonly used indicators, like COD/BOD5 and BOD5/TN ratio, determining wastewater susceptibility to biodegradation in conventional treatment technologies were assessed. It was confirmed that multistage treatment wetland may be used for treatment of wastewater with high loads of...
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Effect of organic nitrogen concentration on the efficiency of trickling filters
PublicationThe study was conducted in Poland at six selected wastewater treatment plants (WWTP) based on the trickling filters Bioclere® technology. The aim of the study was to find the relationship between the influent organic nitrogen concentration and the purification efficiency expressed as effluent COD concentration. In the tests performed, the COD to BOD5 relationship was close to 2 and the ratio of BOD5 to TN was lower than 4. The...