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Search results for: km and green transformation
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Speed estimation of a car at impact with a W-beam guardrail using numerical simulations and machine learning
PublicationThis paper aimed at developing a new method of estimating the impact speed of a passenger car at the moment of a crash into a W-beam road safety barrier. The determination of such a speed based on the accident outcomes is demanding, because often there is no access to full accident data. However, accurate determination of the impact speed is one of the key elements in the reconstruction of road accidents. A machine learning algorithm...
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Application of deep eutectic solvents in bioanalysis
PublicationThe application of deep eutectic solvents (DESs) is sharply surging as a green alternative to conventional solvents due to their unique properties in terms of simplicity of preparation, designability and low cost. A great deal of attention has been paid to the application of these green solvents in analytical chemistry in recent years, and a lot of interesting work has been reported. This review summarizes the most relevant applications...
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The treatment of wastewater containing pharmaceuticals in microcosm constructed wetlands: the occurrence of integrons (int1–2) and associated resistance genes (sul1–3, qacEΔ1)
PublicationThe aim of this study was to analyze the occurrence of sulfonamide resistance genes (sul1–3) and other genetic elements as antiseptic resistance gene (qacEΔ1) and class 1 and class 2 integrons (int1–2) in the upper layer of substrate and in the effluent of microcosm constructed wetlands (CWs) treating artificial wastewater containing diclofenac and sulfamethoxazole (SMX), which is a sulfonamide antibiotic. The bacteria in the substrate...
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Spatial planning on regional level
PublicationPolish spatial planning results from typical for countries of Central and Eastern Europe transition . They have undergone the transformation from decentralized management system based on the dominance of state to the system of representative democracy, based on self-government administration; also territorial on regional level.
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Thermoplastic starch nanocomposites using cellulose-rich Chrysopogon zizanioides nanofibers
PublicationGreen thermoplastic starch (TPS) nanocomposite films aided by cellulose nanofibers (CNFs) from Chrysopogon zizanioides roots were developed and characterized. When compared to other lignocellulosic fibers, Chrysopogon zizanioides roots revealed exceptionally high cellulose content (~48%). CNFs were separated using an environmentally friendly acid isolation technique that included three stages: (i) alkali treatment; (ii) bleaching;...
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Szybka transmisja danych w systemie UMTS z wykorzystaniem turbokodu o zmniejszonej liczbie stanów
PublicationW referacie została przedstawiona budowa kodera i dekodera turbokodu o zmniejszonej liczbie stanów. Oba kodery splotowe wchodzące w skład tego turbokodera są 4-stanowe, czyli liczba stanów jest dwukrotnie mniejsza niż w standardowo stosowanym w systemie UMTS turbokoderze. Badania symulacyjne zostały przeprowadzone dla szybkości transmisji 384 kb/s w środowisku propagacyjnym miejskim, wokołobudynkowym i szybkości poruszania się...
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Szybka transmisja danych w systemie UMTS z wykorzystaniem turbokodu o zmniejszonej liczbie stanów
PublicationW referacie została przedstawiona budowa kodera i dekodera turbokodu o zmniejszonej liczbie stanów. Oba kodery splotowe wchodzące w skład tego turbokodera są 4-stanowe, czyli liczba stanów jest dwukrotnie mniejsza niż w standardowo stosowanym w systemie UMTS turbokoderze. Badania symulacyjne zostały przeprowadzone dla szybkości transmisji 384 kb/s w środowisku propagacyjnym miejskim, wokołobudynkowym i szybkości poruszania się...
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The Current State-of-the-Art in the Determination of Pharmaceutical Residues in Environmental Matrices Using Hyphenated Techniques
PublicationSeveral thousand tons of pharmaceuticals and their transformation products (metabolites and degradation products) are introduced into the environment each year. They affect both human health and the environment, therefore, analytical procedures enabling the determination of a wide range of pharmaceuticals at trace levelswithminimal effort, time, and energy are required. Nowadays, hyphenated techniques are commonly applied in pharmaceutical...
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Implementation of the FOPID Algorithm in the PLC Controller - PWR Thermal Power Control Case Study
PublicationIn the paper authors describe proposition of design and verification procedures of the discrete Fractional Order PID (FOPID) algorithm for control of the Pressurized Water Reactor (PWR) thermal power near its nominal operating point. The FOPID algorithm synthesis consists of: off-line optimal tunning of its parameters in continuous time-domain with LQ (Linear Quadratic) performance index and simplified models of nuclear reactor...
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The unstable thermoelectric effect in non-stoichiometric Cu2Se during the non-equilibrium phase transition
PublicationThe superionic α ↔ β phase transition in Cu1.96Se thermoelectric material is investigated by means of thermal analysis (DSC) and measurements of Seebeck coefficient and electrical conductivity. Results of the DSC measurements with 1–10 K/min heating and cooling rates show that the material is close to the equilibrium phase composition during the transformation. However, the kinetic limitation of the process exists, which is indicated...
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DYNAMIC ANALYSIS OF THE RAILWAY BRIDGES IN POLAND WITH REGARDS TO HIGH-SPEED TRAINS PASSAGE ADJUSTMENT
PublicationThe dynamic analysis of the railway bridge in Tczew was carried out in the article as an example of such bridges adaptation suitability to handle high-speed trains. Calculations of railway bridges are greatly complicated and labor-consuming. The bridge model and a rolling stock passage simulation were developed in the SOFISTIK software. Three types of elements were used for the correct mapping of the structure in the calculation...
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Investigation into MPI All-Reduce Performance in a Distributed Cluster with Consideration of Imbalanced Process Arrival Patterns
PublicationThe paper presents an evaluation of all-reduce collective MPI algorithms for an environment based on a geographically-distributed compute cluster. The testbed was split into two sites: CI TASK in Gdansk University of Technology and ICM in University of Warsaw, located about 300 km from each other, both connected by a fast optical fiber Ethernet-based 100 Gbps network (900 km part of the PIONIER backbone). Each site hosted a set...
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Drum Replacement Using Wavelet Filtering Podmienianie próbek perkusyjnych przy zastosowaniu filtracji falkowej
PublicationThe paper presents the solution that can be used to unify snare drum sound within a chosen fragment. The algorithm is based on the wavelet transformation and allows replacement of sub-bands of particular sounds, which are outside a certain range. Five experienced sound engineers put the algorithm under the test using
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Molecularly imprinted polymers based on deep eutectic solvents as a greenest materials for selective extraction of emerging contaminants from complex samples
PublicationSome of the reagents applied in the synthesis of molecularly imprinted polymers (MIPs) may impact on health and the environment. Thus, a new generation of promising green chemicals are nowadays introduced and investigated, including deep eutectic solvents (DESs). DESs seems to be a reasonable choice as they are characterized as non-toxic, low cost, easy to prepare and biodegradable chemicals. This review presents the information...
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Targ Węglowy as the keystone of two ring road complexes of Gdańsk city centre
PublicationThe urban structure of Gdansk city centre is determined by two ring road complexes. The first of them, the Gdansk Ring, has been created as a result of a city defortification at the turn of the 19th and 20th centuries and has been destroyed in the end of World War Two with the rest of Gdansk. The second, the Main Town Green Belt, has been formed in place of the medieval fortification system of the city’s most important historical...
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Synthesis, Structure and Properties of Poly(ester-Urethane-Urea)s Synthesized Using Biobased Diamine
PublicationModern polymer science and technology is focused on the development of partial or fully green polymers. This focus is related to green chemistry trends, which propose using natural and renewable resources as monomers in the synthesis of polymers. In this study, biobased diamine was used as a chain extender of ester-urethane prepolymer. Obtained poly(ester-urethane-urea) contains 16 wt% of biobased diamine. There is mention of an...
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Activation of N2O and SO2 by the P–B Bond System. Reversible Binding of SO2 by the P–O–B Geminal Frustrated Lewis Pair
PublicationHerein, we present the first transformation of borylphosphine into borylphosphinite using nitrous oxide. Borylphosphine reacts with N2O via insertion of a single oxygen atom into the P−B bond and formation of a P−O−B bond system. Borylphosphine and borylphosphinite capture SO2 and activate it in an irreversible and reversible manner, respectively.
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Phototransformation of Amlodipine: Degradation Kinetics and Identification of Its Photoproducts
PublicationNowadays, monitoring focuses on the primary compounds and does not include degradation products formed during various biological and chemical processes. Transformation products may have the same effects to human health and the environment or sometimes they can be more toxic than the parent compound. Unfortunately, knowledge about the formation of degradation products is still limited, however, can be very important for the environmental...
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On simplification of residue scaling process in pipelined Radix-4 MQRNS FFT processor
PublicationResidue scaling is needed in pipelined FFT radix-4 processors based on the Modified Quadratic Residue Number System (MQRNS) at the output of each butterfly. Such processor uses serial connection of radix-4 butterflies. Each butterfly comprises n subunits, one for each modulus of the RNS base and generates four complex residue numbers. In order to prevent arithmetic overflow intermediate results after each butterfly have to be...
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On configuration of residue scaling process in pipelined radix-4 MQRNS FFT processor
PublicationResidue scaling is needed in pipelined FFT radix-4 processors based on the Modified Quadratic Residue Number System (MQRNS) at the output of each butterfly. Such processor uses serial connection of radix-4 butterflies. Each butterfly comprises n subunits, one for each modulus of the RNS base and outputs four complex residue numbers. In order to prevent the arithmetic overflow in the succesive stage, every number has to be scaled,...
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FINANCIAL COMPARISON OF WESTERN BALKAN AND BALTIC SEA STATES USING THE CAMEL APPROACH
Publication• The aim - This article aims to compare the situation in the banking sectors of two regions, which due to their political and economic history have much in common. These are the Western Balkan States of Serbia, Croatia and Macedonia, and the Baltic Sea States of Lithuania, Estonia, and Latvia. • Methods - It presents three approaches to defining banking stability that can be found in the literature and carries out an initial...
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Open Innovation Competence for a Future-Proof Workforce: A Comparative Study from Four European Universities
PublicationDigital transformation is a key driving force of open innovation to capture and transfer knowledge inside and outside of a company’s bounds. New challenges in organizing multiple knowledge flows imply the need for increased competences related to this paradigm of future employees. In this article, we organize and aggregate the competencies required for open innovation collaboration and develop a competence profile that organizes...
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Advanced nanomaterials and metal-organic frameworks for catalytic bio-diesel production from microalgal lipids – A review
PublicationIncreasing energy demands require exploring renewable, eco-friendly (green), and cost-effective energy resources. Among various sources of biodiesel, microalgal lipids are an excellent resource, owing to their high abundance in microalgal biomass. Transesterification catalyzed by advanced materials, especially nanomaterials and metal-organic frameworks (MOFs), is a revolutionary process for overcoming the energy crisis. This review...
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Miniaturized solid phase microextratcion
PublicationWithout any doubt analytical laboratories have an essential role in environmental protection due to the fact that they takes an active part in the monitoring pollutants present in air, water or soil. From the other side, the analytical activity is involved in the generation of toxic waste what is associated with the use of not eco-friendly reagents and solvents. For these reasons, green analytical chemistry (GAC) was introduced...
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Is it possible to create a unified urban greenery management system (UGMS) on a national scale? The concept for EU Member State of Poland
PublicationMotives: Currently developed urban greenery management systems (UGMS) are limited in scope and profiled towards solving particular issues. Moreover, due to the lack of common standards and solutions, UGMS implementation requires considerable financial effort, which is only feasible for wealthy urban centres. There is a need for universal, cost-effective technological solutions which could constitute a common urban green infrastructure...
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AGREE—Analytical GREEnness Metric Approach and Software
PublicationGreen analytical chemistry focuses on making analytical procedures more environmentally benign and safer to humans. The amounts and toxicity of reagents, generated waste, energy requirements, the number of procedural steps, miniaturization, and automation are just a few of the multitude of criteria considered when assessing an analytical methodology’s greenness. The use of greenness assessment criteria requires dedicated tools. We...
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Polysaccharides in fabrication of membranes: A review
PublicationSustainability concerns have motivated and directed a great deal of interest over the past decade towards the development of green technologies. Polysaccharides are green polymers, which experienced growing demand to substitute chemically synthetic polymers. Different types of polysaccharides i.e. cellulose-, starch-, chitin- alginate-, and chitosan-based carbohydrate polymers have been applied in the fabrication of separation...
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Use of Bi-Temporal ALS Point Clouds for Tree Removal Detection on Private Property in Racibórz, Poland
PublicationTrees growing on private property have become an essential part of urban green policies. In many places, restrictions are imposed on tree removal on private property. However, monitoring compliance of these regulations appears difficult due to a lack of reference data and public administration capacity. We assessed the impact of the temporary suspension of mandatory permits on tree removal, which was in force in 2017 in Poland,...
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Sustainable Waste Management for Implementation of a Circular Economy Model in a Port
PublicationThe manuscript presents the management of waste from marine vessels and cargo handling companies in a selected European Union port. The main objective of the paper is to analyse and evaluate the existing waste management model in the port of Szczecin in the context of circular economy. The expert research carried out is aimed, inter alia, at identifying which of the solutions currently in use need to be improved from an environmental...
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Yacht harbour as a part of city public space
PublicationTransformation of harbors opens opportunities to introduce new functions into city centers. Very often abandoned ports’ infrastructure is adopted into a yacht harbor. The article elaborates typology of yacht harbors and theirs’ potential which can be used in creation of city center. Thesis are illustrated by examples of Port Vell, Barcelona, Spain and Sundby Harbour, Copenhagen, Denmark.
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Application of non-classical operational calculus to indicate hazards in numerical solutions of engineering problems
PublicationThe article addresses the application of non- classical operational calculus to approximative solutions of engineering problems. The engineering-sound examples show that a continuous–discrete problem transformation from differential unequivocal problem to a differential wildcard problem, triggering a change in solution quality. A number of approximative methods are capable to alter both quantitative and qualitative...
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Convenient and Efficient Synthesis of Functionalized 2-Sulfenylindoles
PublicationA simple, efficient, and practical sulfenylation at the C2 position of N-tosylindoles under mild conditions was developed. The designed transformation is based on the reaction of N-tosylindoles with BuLi and S-alkyl, and S-aryl phosphorodithioates or thiotosylates to produce 2-sulfenylindoles in moderate to high yields. The presence of additional hydroxy, carboxy, or amino functionalities did not disturb the formation of products
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Single and Three -Phase PWM AC/AC Converters as Semiconductor Transformers
PublicationAC voltage transformation circuits contain pure or reactance PWM AC/AC converters. These circuits can be treated as AC/AC semiconductor transformers. This paper reviews single-phase and three-phase topologies: both non-isolated and isolated, single as well as two quadrant structure. Additionally, this paper present selected examples of their applications.
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Long-term Hindcast Simulation of Currents, Sea Level, Water Temperature and Salinity in the Baltic Sea
PublicationThis dataset contains the results of numerical modelling of currents, sea level, water temperature and salinity over a period of 50 years (1958–2007) in the Baltic Sea. A long-term hindcast simulation was performed using a three-dimensional hydrodynamic model (PM3D) based on the Princeton Ocean Model (POM). The spatial resolution was 3 nautical miles, i.e. about 5.5 km. Currents, water temperature, and salinity were recorded...
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Efekty zmiany limitu prędkości na obszarach miejskich - ocena wstępna
PublicationW referacie przedstawiono główne zadania Krajowego Programu BRD GAMBIT 2005, związane z zarządzaniem prędkością. Nastepnie zaprezentowano wybrane wy6niki badań prędkości na polskich drogach i ulicach dla okresu przed zmianą limitu prędkości na terenach zabudowy. Przedstawiono także metodykę i wyniki badań skuteczności obniżenia limitu prędkości z 60 do 50 km/h na terenach zabudowy. Badania te odnoszą się do dwujezdniowych ulic...
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Badania jakości transmisji z wykorzystaniem turbokodera o zmniejszonej liczbie stanów
PublicationW referacie przedstawiono budowę kodera i dekodera turbokodu o zmniejszonej liczbie stanów. Zaprezentowano wyniki badań symulacyjnych jakości transmisji z wykorzystaniem tego turbokodera oraz porównano je z wynikami uzyskanymi w przypadku zastosowania standardowego w systemie UMTS turbokodera i kodera splotowego. Badania symulacyjne zostały przeprowadzone w środowisku propagacyjnym miejskim, wokołobudynkowym dla dwóch szybkości...
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Ab initio chemical kinetics of Isopropyl acetate oxidation with OH radicals
PublicationGlobal reactivity descriptors of isopropyl acetate (IPA) and thermo-kinetic aspects of its oxidation via OH radicals have been studied. Transition state theory (TST) was utilized to estimate the bimolecular rate constants. Ten oxidation pathways have been investigated, and all of them are exothermic. The potential energy diagram has been sketched using different pre- and post-reactive complexes for all reaction pathways. Rate coefficient...
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Use of hop cone extract obtained under supercritical CO2 conditions for producing antibacterial all-purpose cleaners
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Improving the prediction of biochar production from various biomass sources through the implementation of eXplainable machine learning approaches
PublicationExamining the game-changing possibilities of explainable machine learning techniques, this study explores the fast-growing area of biochar production prediction. The paper demonstrates how recent advances in sensitivity analysis methodology, optimization of training hyperparameters, and state-of-the-art ensemble techniques have greatly simplified and enhanced the forecasting of biochar output and composition from various biomass...
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Research, theories and practical experience of therapeutic landscapes as a tool for urban open space design
PublicationThis paper reviews the research on therapeutic landscapes and discusses the design of urban parks and open green space. Firstly, the most relevant research on therapeutic landscapes is reviewed. Secondly, the practical experience of healing and therapeutic gardens is discussed. Finally, the conclusions leading to future use of therapeutic landscape concept in urban open space design are presented.
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Large‐Scale Traveling Ionospheric Disturbances Over the European Sector During the Geomagnetic Storm on March 23–24, 2023: Energy Deposition in the Source Regions and the Propagation Characteristics
PublicationMultiple Large-Scale Traveling Ionospheric Disturbances (LSTIDs) are observed in the European sector in both day-time and night-time during the magnetic storm on March 23–24, 2023. The Total Electron Content (TEC) observation from a network of GNSS receivers shows the propagation of LSTIDs with amplitudes between around 0.5 and 1 TECU originating from auroral and polar cusp regions down to southern Europe (35°N) with velocities...
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Cloning, expression, and biochemical characterization of a coldactive GDSL-esterase of a Pseudomonas sp. S9 isolated from Spitsbergen island soil
PublicationAn estS9 gene, encoding an esterase of the psychrotolerant bacterium Pseudomonas sp. S9 was cloned and sequenced. The deduced sequence revealed a protein of 636 amino acid residues with a molecular mass of 69 kDa.Further amino acid sequence analysis revealed that the EstS9 enzyme contained a G-D-S-L motif centered at a catalytic serine, an N-terminal catalytic domain and a C-terminal autotransporter domain. Two recombinant E. coli...
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Influence of a Lighting Column in the Working Width of a W-Beam Barrier on TB51 Crash Test
PublicationRoad equipment, such as, e.g., road safety barriers and lighting columns, are subject to certification according to the EN1317 standard to be allowed for use on European roads. In engineering practice, due to the terrain conditions, there are cases where other road equipment is installed within the working width of road safety barriers. Such situations are not considered during the certification process. Hence, the aim of this...
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The impact of knowledge risk management on sustainability
PublicationPurpose The purpose of this study is to examine the effect of knowledge risk management (KRM) on organizational sustainability and the role of innovativeness and agility in this relationship. Methodology The study presents the results of a quantitative survey performed among 179 professionals from knowledge-intensive organizations dealing with knowledge risks and their management in organizations. Data included in this study are...
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Use of Neural Networks in Diagnostics of Rolling-Element Bearing of the Induction Motor
PublicationBearing defect is statistically the most frequent cause of an induction motor fault. The research described in the paper utilized the phenomenon of the current change in the induction motor with bearing defect. Methods based on the analysis of the supplying current are particularly useful when it is impossible to install diagnostic devices directly on the motor. The presented method of rolling-element bearing diagnostics used indirect...
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Entrepreneurship nests in a polish edge city
PublicationThe last two decades in Poland have been a period of both a dynamic development of the small and medium-sized enterprise sector and a transformation of the city surrounding territories. This development began during the economy transformation after 1989. Population migration and movement of economic entities away from central cities resulted in development of territorial structures within some Polish suburban areas, defined as...
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Thermodynamics of solid phases containing rare earth oxides
PublicationRare earth elements (RE) are incorporated into a large variety of complex oxide phases to provide tailored mechanical, electrical, optical, and magnetic properties. Thermodynamics control phase stability, materials compatibility in use, corrosion, and transformation. This review presents, in one compilation, the thermodynamic properties of a large number of such materials and discusses systematic trends in energetics and the factors...
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Selected issues related to the toxicity of ionic liquids and deep eutectic solvents—a review
PublicationGreen Chemistry plays a more and more important role in implementing rules of sustainable development to prevent environmental pollution caused by technological processes, while simultaneously increasing the production yield. Ionic liquids (ILs) and deep eutectic solvents (DESs) constitute a very broad group of substances. Apart from many imperfections, ILs and DESs have been the most promising discoveries in the world of Green...
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Application of TOPSIS for Selection and Assessment of Analytical Procedures for Ibuprofen Determination in Wastewater
PublicationThis paper describes the possible implementation of the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) as green analytical chemistry metrics tools. TOPSIS is one of the multi-criteria decision analysis (MCDA) tools that is applied in the selection of the best alternative from many possible. In this case we have applied it to assess the nineteen analytical procedures for ibuprofen determination in wastewater...
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Ultrasound assisted extraction
PublicationThe use of green and sustainable extraction techniques is very popular topic in the multidisciplinary area of chemistry, biology and technology. There is no doubt that extraction constitutes a very important step of analytical procedures of separation, detection, identification and determination of wide spectrum analytes from samples characterized by complex and very often nonhomogeneous composition of matrix. Traditional techniques...