Search results for: TRI-TERT-BUTOXYSILANETHIOL
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Programmed metalloporphyrins for self-assembly within light-harvesting stacks: 5,15-dicyano-10,20-bis(3,5-di-tert-butylphenyl)-porphyrinato zinc(II) and its push-pull 15-N,N-dialkylamino-5-cyano congeners obtained by a facile direct amination.
PublicationThe title dicyano compound was synthesized via cyanation and it self-assembles in nonpolar solvents giving red-shifted and broad absorption maxima just as the bacteriochlorophylls which are encountered in the light-harvesting organelles of early photosynthetic bacteria. In the crystal, stacks are formed through a hierarchic combination of π-stacking and a CNZn electrostatic interaction. Push−pull 15-N,N-dialkylamino-5-cyano congeners...
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Kamil Brodnicki dr inż.
PeopleKamil Brodnicki is an assistant at the Department of Applied Informatics in Management at the Faculty of Economics and Management at the Gdańsk University of Technology. From 2017, he is the head of the Customer Experience laboratory. Since 2011, he has been working in one of the Tri-City IT companies as an IT Systems Analyst, implementing projects in the financial sector. His research interests are focused on the following areas:...
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Permanent traffic counting stations - Expressway S7 in Gdansk, Poland
Open Research DataThe data includes traffic data from permanent traffic count station located on the expressway S7 in the Tri-City Agglomeration area in Poland. The data covers the 2 months of 2015 (May, October) and one direction of traffic (eastbound).
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Koncepcja połączenia kolejowego Morskiego Portu Gdynia S.A. z Kolejową Obwodnicą Trójmiasta
PublicationZapotrzebowanie na połączenie rozwijającego się Morskiego Portu Gdynia z Kolejową Obwodnicą Trójmiasta. Utworzenie tak zwanych „długich pociągów”. Wpływ katastrof kolejowych na warunki gruntowe i środowisko. Potrzeba modernizacji linii kolejowych. Kolejowa Obwodnica Trójmiasta jako alternatywa dla przejazdu pociągów przez obszar Aglomeracji Trójmiejskiej.
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Pochodne kwasu neopentylidenofosforoditiowego jako substraty do syntezy ugrupowania trisulfidowego
PublicationBadania przeprowadzone w Katedrze Chemii Organicznej Wydziału Chemicznego Politechniki Gdańskiej na przestrzeni ostatnich kilku lat, pokazały wszechstronność pochodnych kwasu neopentylidenofosforoditiowego [32] w syntezie symetrycznie i niesymetrycznie podstawionego ugrupowania disulfidowego. Wyniki powyższych badań doprowadziły do opracowania nowej strategii syntetycznej, umożliwiającej otrzymywanie...
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Anion recognition by phosphonium calix[4]arens: synthesis and physico-chemical studies
Publicationp-tert-butylcalix[4]arenes in the cone conformation, di-and tetra substituted at the narrow rim with charged phosphonium groups have been synthesies and characterised.
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High-performance anode-supported solid oxide fuel cells with co-fired Sm0.2Ce0.8O2-δ/La0.8Sr0.2Ga0.8Mg0.2O3−δ/Sm0.2Ce0.8O2-δ sandwiched electrolyte
PublicationIn this study, intermediate-temperature solid oxide fuel cells (IT-SOFCs) with a nine-layer structure are constructed via a simple method based on the cost-effective tape casting-screen printing-co-firing process with the structure composed of a NiO-based four-layer anode, a Sm0.2Ce0·8O2-δ(SDC)/La0·8Sr0.2Ga0.8Mg0·2O3−δ (LSGM)/SDC tri-layer electrolyte, and an La0·6Sr0·4Co0·2Fe0·8O3-δ (LSCF)-based bi-layer cathode. The resultant...
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Reactions of Lithium Salts of Triphosphanes tBu2P-PLi-PtBu2 and tBu2P-PLi-P(NEt2)2 with Metal Complexes [(R3P)2MCl2] (M = Ni, Pd, Pt, R3P = Et3P, pTol3P, Ph2EtP, iPr3P)
PublicationtBu2P-PLi-PtBu2·2THF reacts with [(R3P)2MCl2] (M = Pt, Pd, Ni; R3P = Et3P, pTol3P, Ph2EtP, iPr3P) to yield isomers of [(1,2-η-tBu2P=P-PtBu2)M(PR3)Cl], in which the tBu2P-P-PtBu2 ligand adopts the arrangement of a side-on bonded 1,1-di-tert-butyl-2-(di-tert-butylphosphanyl)diphosphenium cation. tBu2P-PLi-P(NEt2)2·2THF reacts with [(R3P)2MCl2] but does not form complexes with a tBu2P-P-P(NEt2)2 moiety, however, splitting...
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Morphology, Thermo-Mechanical Properties and Biodegradibility of PCL/PLA Blends Reactively Compatibilized by Different Organic Peroxides
PublicationReactive blending is a promising approach for the sustainable development of bio-based polymer blends and composites, which currently is gaining more and more attention. In this paper, biodegradable blends based on poly(ε-caprolactone) (PCL) and poly(lactic acid) (PLA) were prepared via reactive blending performed in an internal mixer. The PCL and PLA content varied in a ratio of 70/30 and 55/45. Reactive modification of PCL/PLA...
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Przewodnik Architektoniczny=Architectural Guide=Architekturführer. Gdynia
PublicationGdynia is a unique city that is particularly interesting for architects due to its homogeneous architecture. The city, based on the structure of an earlier fishing village, was entirely designed and built from scratch in the interwar period, as was the case later for cities such as Brasilia and Chandigarh. Today, Gdynia is a modern port town that forms the Tri-City metropolitan area together with Gdańsk, the city of amber, and...
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2,2,6,6-Tetramethylpiperidinium triisopropoxysilanethiolate
PublicationTytułowy związek został otrzymany poprzez reakcję tri-izo-propoksysilanotiolu z 2,2,6,6-tetrametylopiperydyną. Oba fragmenty jonowe powiązane są wiązaniami wodorowymi N-H...S. Strukturę cząsteczkową i krystaliczną wyznaczono posługując się rentgenowską analizą strukturalną.
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Struktury wybranych tiosiarczanów amoniowych
PublicationPrzedstawiono syntezę i struktury rentgenowskie trzech tiosiarczanów amoniowych. Były to: tiosiarczan bis(cykloheksyloamoniowy), dwuwodny tiosiarczan bis(tert-butyloamoniowy) i bis(tiosiarczan) 1,6-heksanodiamoniowo diamonowy. Omówiono układy wiązań wodorowych występujące w powyższych strukturach.
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Structure-property relationships in peroxide-assisted blends of poly(ε-caprolactone) and poly(3-hydroxybutyrate)
PublicationPoly(ε-caprolactone) and poly(3-hydroxybutyrate) (PCL/PHB) blends in two weight ratios (75/25 and 50/50) were reactively compatibilized in the presence of di-(2-tert-butyl-peroxyisopropyl)-benzene and dicumyl peroxide as free radical initiators. Rheological, mechanical, thermal properties and morphological features, as well as the chemical structure of PCL/PHB blends were investigated. It was found that regardless of PCL/PHB blend...
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Wybrane problemy geotechniczne na terenach zurbanizowanych na przykładzie Trójmiasta
PublicationWybrane, współczesne problemy geotechniczne na terenach zurbanizowanych, miejskich i poprzemysłowych na przykładzie Trójmiasta. Dwie grupy problemów związane z podłożem oraz z otoczeniem inwestycji. Problemy związane z wodą gruntową i jej przepływem, z zanieczyszczeniami oraz pozostałościami budowlanymi z przeszłości. Sąsiedztwo zabudowy i brak miejsca. Przykłady z zrealizowanych obiektów budowlanych. Europejskie Centrum Solidarności,...
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Die reaktion von tBu2P-P=P(Me)tBu2 mit [Fe2(CO)9] und [(n2-C8H14)2Fe(CO)3]
PublicationFosfanofosfinidenofosforan reaguje z nonakarbonylkiem diżelaza oraz z trikarbonylo(diokten)żelazem(0) dając mieszaniny produktów z których udało się wyizolować pochodne będące kompleksami dimeru di(tert)butylo-fosfinofosfini-denu i centrów koordynacji Fe(0).
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Agata Kot-Wasik prof. dr hab. inż.
PeopleAgata Kot-Wasik, born in 1964 in Siedlce, graduated in 1988 from the Faculty of Chemistry, Gdańsk University of Technology in Industrial and Technical Analysis. In 1988-1992 she was employed in the Department of Organic Chemistry. In 1990, she completed postgraduate studies "Instrumental techniques in the traces analysis and Environmental Protection" at GUT, and in 1992 began PhD Studies at the Faculty of Chemistry, GUT, which...
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Reaction of thio and seleno phosphoric acid derivatives with O-thioacylated hydroxylamine
PublicationZbadano reakcję siarkowych i selenowych analogów kwasu O,O-neopentylidenofosforowego z O-tiopiwaloilo-N-tert-butylohydroksyloaminą, w której to następuje rozszczepienie wiązania N-O. Znaleziono korelację pomiędzy potencjałem utleniającym anionu pochodnej kwasu fosforowego a przebiegiem badanej reakcji.
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MEASUREMENT AND ANALYSIS OF A FLOOD WAVE PROPAGATION ON THE KACZA RIVER IN GDYNIA IN NORTHERN POLAND
PublicationKacza river is located in northern Poland in the neighborhood of the Gulf of Gdansk and the Baltic Sea. A Kacza having length of 15 km and catchment area of 53 km2 collects the water into the Gulf mostly from inhabited and forested areas within the administrative boundaries of the city of Gdynia. On the 14th and 15th of July 2016 in northern Poland on the large area of Tri-City agglomeration (Gdynia, Gdansk and Sopot) total daily...
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The structure of the data flow in integrated urban traffic management systems – the case of TRISTAR system
PublicationThe purpose of the article is to offer some insight into the data flow architecture in the Tri-City’s integrated traffic management system called TRISTAR. To that end selected elements of TRISTAR are identified and described as well as the structure for collecting and exchanging data within different sub-systems. Finally, the article highlights how the TRISTAR system can be extended by adding new elements and modules.
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Occurrence and Determination of Volatile Fatty Acids in Wastewater of Different Origin
PublicationOpracowano metodykę oznaczania krótkołańcuchowych alifatycznych kwasów monokarboksylowych w ściekach rożnego pochodzenia stosując ekstrakcję za pomocą eteru metylo-tert-butylowego na etapie przygotowania próbek i chromatografię gazową z kolumną kapilarną Stabilwax-DA i Rtx-624, natomiast na etapie detekcji stosowano spektrometr mas.
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Travel Time of Public Transport Vehicles Estimation
PublicationEffective prediction of speed is central to advanced traveler information and transportation management systems. The speed of public transport vehicles is affected by many external factors including traffic volume, organization and infrastructure. The literature presents methods for estimating travel time on sections of a transport network and vehicle arrival at stops, often making use of the AVL (automatic vehicle location). The...
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ANALYSIS OF POSSIBILITIES FOR THE USE OF VOLUME-DELAY FUNCTIONS IN THE PLANNING MODULE OF THE TRISTAR SYSTEM
PublicationTravel time is a measure commonly used for traffic flow modelling and traffic control. It also helps to evaluate the quality of traffic control systems in urban areas. Traffic control systems that use traffic models to predict changes and disruptions in vehicle flows have to use vehicle speed-prediction models. Travel time estimation studies the effects of traffic volumes on a street section at an average speed. The TRISTAR Integrated...
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Module of priorities for public transport vehicles in the TRISTAR system
PublicationOne of the most important elements of the intelligent traffic control systems is the ability to control movement in such a way as to privilege the selected users movement, in particular public transport vehicles. Implemented at the Tri-City the TRISTAR system will also have a module for prioritizing public transport vehicles. The article presents a characteristics of the priority action system: the way of communication with the...
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Problem oznaczania pozostałości rozpuszczalników organicznych w wybranych produktach spożywczych i farmaceutycznych, cz. II
PublicationW artykule opisano metody stosowane do oznaczania pozostałości rozpuszczalników w próbkach spożywczych i farmaceutycznych, ze szczególnym uwzględnieniem etapu przygotowania próbki do analizy. Dokładniej opisano technikę analizy fazy nadpowierzchniowej (HS- headspace) i mikroekstrakcję do fazy stacjonarnej (SPME- solid phase microextraction). Oznaczano następujące zanieczyszczenia: węglowodory aromatyczne i alifatyczne (hexan, benzen,...
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Interrelationship between total volatile organic compounds emissions, structure and properties of natural rubber/polycaprolactone bio-blends cross-linked with peroxides
PublicationNatural rubber/polycaprolactone (NR/PCL) bio-based blends with different organic peroxides were prepared using an internal batch mixer and subsequently cross-linked at 170°C. Two types of commonly used organic peroxides, dicumyl peroxide and di(tert-butylperoxyisopropyl)benzene peroxide, were applied as free-radical initiator. Cross-linking efficiency of NR/PCL blends were investigated using oscillating disc rheometer measurements,...
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Application of gas chromatography-mass spectrometry preceded by solvent extraction to determine volatile fatty acids in wastewater of municipal, animal farm and ladfill origin
PublicationW ramach przeprowadzonych badań została opracowana metodyka oznaczania lotnych kwasów tłuszczowych (LKT) z próbek ścieków pochodzących z oczyszczalni ścieków komunalnych, farm zwierząt oraz ze składowiska odpadów organicznych, techniką ekstrakcji ciecz-ciecz (LLE) za pomocą eteru metylo-tert-butylowego (MTBE) jako ekstahenta. Dobrano optymalne warunki chromatograficznego rozdzielania i oznaczania LKT w próbkach środowiskowych,...
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Thermgravimetric analysis (TGA) data of cement pastes containing pristine and silica-coated bismuth oxide and gadolinium oxide particles
Open Research DataThermogravimetric (TGA) data of cement pastes after 2, 7 and 28 days. Samples designations: Control, BG, BG-A and BG-B are associated with the specimen names in the associated publication.
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Silver complexes stabilized by large silanethiolate ligands – crystal structures and luminescence properties
PublicationBulky silanethiolate and disiladithiolate ligands were applied to synthesize one mononuclear and three trinuclear silver complexes including two cyclic “microclusters” and a linear tri-nuclear silanethiolate complex. All obtained compounds are characterized by X-ray diffraction and FT-IR. NMR and emission spectroscopies were used where possible. The first trinuclear anionic silver thiolate is structurally characterized. The influence...
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Comparison of the tests for equivalence of the measurement methods for measurement of PM10 dust in ambient air
PublicationThe paper presents the motives for conducting the equivalence tests and the reasons of discrepancies between the results of PM10 dust concentration obtained via the reference method and the methods based on 'on-site' measurement. The reference and non-reference methods of measurement of PM10 dust concentration in air have been discussed. Field tests for equivalence, following the Polish standard and the European Union (EU) guidelines,...
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Shaft friction from the DMT and direct shear interface tests
PublicationThe article presents preliminary attempt to create tri-linear transfer curves for describing pile behaviour under axial loading. Transfer curves would use the parameter measured in dilatometer test, particularly a constrained modulus MDMT. The proposed method is based on concrete rough and smooth interface tests performed in a direct shear apparatus. Based on the obtained mobilization curves, relationships were created between...
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A new phosphonium calix[4]arene for selective anion recognition: synthesis and studies in solution and in ion selective electrodes
PublicationZaprezentowana została synteza i charakteryzacja tetra (trifenylofosfoniowego) p-tert-butylkaliks[4]arenu 2. Oddziaływania z anionami były badane z użyciem (1)H oraz (31)P NMR i spektrofotometrii absorpcyjnej UV. Badania wykazały oddziaływania z anionami: CLO4-, I-, oraz SCN-. Selektywność jonoforu 2 badano również w membranowych elektrodach jonoselektywnych (ISE) PCV/o-NPOE. Elektroda zawierająca związek 2 generuje odpowiedź potencjometryczną...
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The Possibility to use a Nuclear Power Plant as a Source of Electrical Energy and Heat
PublicationIn this article issues concernig the possibility of nuclear power plant (NPP) operation also as a source of heat, which means combined heat and power production, have been described. CHP work is possible and profitable only in those areas where high thermal power demand occurs, which means near city agglomerations such as Warsaw or the Tri-City. Two levels of thermal power delivered to the heating system have been considered. Preliminary...
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Molecular structures and supramolecular architectures of two chromogenic 13-membered azobenzocrown ethers with a peripheral hydroxyl group in the benzene ring.
PublicationOkreślono strukturę krystaliczną dwóch pochodnych 13-członowego eteru azobenzokoronowego z peryferyjną grupą hydroksylową, metodą analizy rentgenostrukturalnej monokryształów. W stanie stałym 13-członowy eter azobenzokoronowy zawierający grupę OH jako podstawnik w pierścieniu aromatycznym w pozycji para do grupy azowej występuje w formie chinono-hydrazonu. Forma ta stabilizowana jest przez silne wewnątrzcząsteczkowe wiązanie wodorowe....
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Water sorption and blistering of GFRP laminates with varying structures
PublicationThe microstructures, water absorption as well as blistering was studied for bi- and tri- axial glass fibre vinyl ester and polyester -matrix laminates coated with gel coat layer and uncoated. The effect of manufacturing technique on water sorption characteristics was considered. It was found that water sorption characteristics of GFRP depend on manufacturing methods. The least water intake was found for specimens having perfect...
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Teloxantron inhibits the processivity of telomerase with preferential DNA damage on telomeres
PublicationTelomerase reactivation is one of the hallmarks of cancer, which plays an important role in cellular immortalization and the development and progression of the tumor. Chemical telomerase inhibitors have been shown to trigger replicative senescence and apoptotic cell death both in vitro and in vivo. Due to its upregulation in various cancers, telomerase is considered a potential target in cancer therapy. In this study, we identified...
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Interplay of hydrogen bonding and aryl-perfluoroaryl interactions in construction of supramolecular aggregates
PublicationThe stacking between aryl and perfluoroaryl units is an important class of the aromatic – aromatic interactions that has attracted rapidly growing interest in recent years. Continuing interest of our group in this subject it had been prepared three new complexes of pentafluorobenzoic acid with benzyl alcohol, 4-methylbenzyl alcohol and 4-tert-butylbenzyl alcohol and in the next step investigated their self-assembly modes by...
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Calixthioamides as ionophores for transition and heavy-metal cations
PublicationThere is an increasing interest in applying p-tert-butylcalix[4]arenes as sensing materials in ion-selective electrodes(ISEs). Considerable efforts were made to design calixarenes that are selective for some heavy- or transitionmetal ions to be used in ISEs for controlling and monitoring the level of such pollutants in the environment. It has been reported that introduction of softer sulfur atoms instead of oxygen atoms in calix[4]arene...
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Synthesis, Antimicrobial and Mutagenic Activity of a New Class of d-Xylopyranosides
PublicationEight N-[2-(2′,3′,4′-tri-O-acetyl-α/β-d-xylopyranosyloxy)ethyl]ammonium bromides, a new class of d-xylopyranosides containing a quaternary ammonium aglycone, were obtained. Their complete structure was confirmed using NMR spectroscopy (1H, 13C, COSY and HSQC) and high-resolution mass spectrometry (HRMS). An antimicrobial activity against fungi (Candida albicans, Candida glabrata) and bacteria (Staphylococcus aureus, Escherichia...
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Sposób otrzymywania hydroksamowych pochodnych 5,11,17,23-tetrakis-p-tert-butylkaliks[4]arenu i nowe hydroksamowe pochodne 5,11,17,23-tetrakis-p-tert-butylkaliks[4]arenu
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Adam Inglot dr inż.
PeopleAdam Inglot (born October 3, 1984), studied Environmental Engineering and Geodesy and Cartography at the Faculty of Mine Surveying and Environmental Engineering of AGH University of Science and Technology in Krakow. He graduated in 2011 as a M.Sc. in Environmental Engineering, defending his thesis "Verification of usefulness of GeoMod model for prediction of the urbanization process in Cracow agglomeration" under the guidance of...
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New heterometallic Co/Zn, Ag/Co, and Ag/Zn imidazolates: structural characterization and catalytic activity in the oxidation of organic compounds
PublicationNanocrystalline powders of monometallic and bimetallic imidazolates of Co, Zn, and Ag were produced by a reaction carried out in water. The powders were characterized by powder X-ray diffraction and the crystal structures of new compounds Ag2ZnIm4 and Ag2CoIm4 (Im = imidazolate) were solved. Heterometallic Co/Zn imidazolates showed the standard ZIF-8 crystal structure while Ag/Zn and Ag/Co systems were isostructural with the copper...
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Permanent traffic count stations - expressway S6 Poland 2016
Open Research DataThe data includes traffic data from permanent traffic count stations located on the expressway S6 in the Tri-City Agglomeration area in Poland. The data covers the 12 months of 2016.
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Modification of Ground Tire Rubber—Promising Approach for Development of Green Composites
PublicationGround tire rubber (GTR) was mechano-chemically modified using a road bitumen 100/150 and two types of organic peroxides: di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB) and dicumyl peroxide (DCP). The impact of used additives on reactive sintering efficiency and physico-mechanical properties of modified GTR was investigated using oscillating disc rheometer measurements, followed by tensile tests and swelling behavior studies....
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Pomiar lojalności klientów - wybrane wskaźniki
PublicationSytuacja na rynkach sprawia, że konieczne jest konkurowanie poprzez dbałość o satysfakcję i lojalność klientów. Wymaga to od przedsiębiorstw podejmowania wielu działań, ale także monitorowania ich rezultatów. Celem artykułu jest przedstawienie wybranych metod mierzenia lojalności klientów. Skoncentrowano się na wskaźnikach satysfakcji takich jak CSI, ACSI, EPSI, a także wskaźnikach lojalności, ujmujących różne aspekty tego zjawiska...
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Integration of natural and artificial intelligence in production systems
PublicationIntegration processes play an increasingly important role in modern economy, and seriously co-decide about the effectiveness of the company. Integration phase occurs in the system life cycle by preceding the final stages of its implementation and activation. In turn, used in software engineering (SE) iteration-evolutionary models, such as spiral model make that the integration activities can occur in varying degrees in all phases...
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Information System for Drivers Within the Integrated Traffic Management System - TRISTAR
PublicationAdvanced traveler information systems (ATIS) for drivers are a very important element of modern traffic management. In recent years ITS infrastructure is being developed also in Poland. It allows for delivering to drivers information related to the conditions in the road network through, inter alia, dedicated Variable Message Signs (VMS). Such information enables drivers to take decisions, contributing to improving the efficiency...
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Video traffic data - Interchange Karczemki (S6-501)
Open Research DataThe data includes video traffic data registered with 5 video cameras at weaving area (weaving section type A) of the Karczemki interchange within S6 expressway in Poland (interchange of expressway S6 and regional road 501), located in the Tri-City Agglomeration . The data covers the one day: 10.10.2017 (expressway S6).
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Video traffic data - Interchange Gdansk Poludnie (S6-S7), Poland
Open Research DataThe data includes video traffic data registered with 8 video cameras at exit and entry lanes of the Gdansk Poludnie interchange within S6 expressway in Poland (interchange of expressway S6 and S7), located in the Tri-City Agglomeration . The data covers the two days: 4.08.2020 and 6.08.2017 (expressway S6).
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Video traffic data - Interchange Lotnisko (S6-472) - Exit +entry lanes, Poland
Open Research DataThe data includes video traffic data registered with 6 video cameras at entry or exit lanes of the Lotnisko interchange within S6 expressway in Poland (interchange of expressway S6 and regional road 472), located in the Tri-City Agglomeration. The data covers the two days: 10.04.20187 and 12.04.2017(expressway S6).
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Study of Cloud Water Samples Collected over Northern Poland
PublicationThe paper gives the results of the first studies on the chemistry of cloud water collected during 3 mo (Aug.–Oct. 2010) in the free atmosphere over the area to the south of the Tri-City (Gdansk-Sopot-Gdynia) conurbation on the Gulf of Gdansk, Poland. Taken from cumulus, stratus, and stratocumulus clouds by means of an aircraft-mounted collector, the water samples were analyzed for the following contaminants: anions (chlorides,...