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Search results for: LAYERED COMPOUNDS
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Chiral phonons in the honeycomb sublattice of layered CoSn-like compounds
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Dirac fermions and possible weak antilocalization in LaCuSb2
PublicationLayered heavy-metal square-lattice compounds have recently emerged as potential Dirac fermion materials due to bonding within those sublattices. We report quantum transport and spectroscopic data on the layered Sb square-lattice material LaCuSb2. Linearly dispersing band crossings, necessary to generate Dirac fermions, are experimentally observed in the electronic band structure observed using angle-resolved photoemission spectroscopy,...
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Novel method for metal-oxide glass composite fabrication for use in thermoelectric devices
PublicationA novel method for thermoelectric materials fabrication using a reduction of oxide precursors in hydrogen was reported. On the example of Bi-Sb, Bi-Sb-Te and Te-Ag-Ge-Sb compounds it was shown that this simple and easy method is suitable for fabrication of two-, three- and even multicomponent thermoelectric materials. It allows controlling a composition, microstructure and even type a of electrical charge carriers. As a result...
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Interplay between Aryl···Perfluoroaryl and Hydrogen Bonding Interactions in Cocrystals of Pentafluorophenol with Molecules of Trigonal Symmetry
PublicationCocrystals of seven star-shaped triaryl compounds with pentafluorophenol (pfp) were prepared and structurally characterized by the single-crystal X-ray diffraction method. Cocrystallization of pfp with planar (or almost planar) compounds gave six 3:1 molecular complexes with well-defined layered structures. The layers are composed of alternating pfp3 trimers, linked by hydrogen bonding, and triaryl molecules held together in planes...
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Aggregation properties of some zirconium phosphate loaded with dirhenium(III) complexes
PublicationOne of the important areas of modern science is the selection of the right forms of drug delivery. Layered inorganic nanoparticles, such as zirconium phosphate, have proven themselves well in this area. The study of the properties of these systems and methods of their preparation makes it possible to determine a rational technology of their manufacture, storage conditions as well as suggest a possible mechanism of therapeutic action....
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Crystal structure and electronic structure of CePt2In7
PublicationWe report a corrected crystal structure for the CePt2In7 superconductor, refined from single crystal x-ray diffraction data. The corrected crystal structure shows a different Pt–In stacking along the c-direction in this layered material than was previously reported. In addition, all of the atomic sites are fully occupied with no evidence of atom site mixing, resolving a discrepancy between the observed high resistivity ratio of...
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Ultrastructural analysis of the submandibular sialoliths: Raman spectroscopy and electron back-scatter studies
PublicationThe aim of work was the epidemiological analysis of the occurrence of sialolithiasis of the submandibular gland in adults and the evaluation of the ultrastructure of salivary stones. The study sample consisted of 44 sialoliths. Analysis of the structure and chemical composition of sialoliths was performed using a Scanning Electron Microscope and Raman Spectroscopy. Comparing our results with the literature we can say that the epidemiology...
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MXenes Antibacterial Properties and Applications: A Review and Perspective
PublicationThe mutations of bacteria due to the excessive use of antibiotics, and generation of antibiotic-resistant bacteria have made the development of new antibacterial compounds a necessity. MXenes have emerged as biocompatible transition metal carbide structures with extensive biomedical applications. This is related to the MXenes’ unique combination of properties, including multifarious elemental compositions, 2D-layered structure,...
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DETECTION OF DEBONDING IN STEEL BARS EMBEDDED IN CONCRETE USING GUIDED WAVE PROPAGATION
PublicationThe paper presents a non-destructive diagnostic technique based on guided wave propagation phenomenon used to assess the adhesive bonding between a steel bar and a concrete cover. Double-layered cylindrical specimens with different levels of debonding and its location were investigated. The influence of bonding length on the excitation of multiple modes of longitudinal guided waves was analysed. Numerical simulations of guided...
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Electro-thermal buckling of elastically supported double-layered piezoelectric nanoplates affected by an external electric voltage
PublicationPurpose Thermal buckling of double-layered piezoelectric nanoplates has been analyzed by applying an external electric voltage on the nanoplates. The paper aims to discuss this issue. Design/methodology/approach Double-layered nanoplates are connected to each other by considering linear van der Waals forces. Nanoplates are placed on a polymer matrix. A comprehensive thermal stress function is used for investigating thermal buckling....
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Multi-layered mineral glass units used as viewport elements of underwater ship structures
PublicationIn the paper, Authors deals with viewport elements of underwater marine constructions. If a single-plate viewport constructions are considered, big thicknesses of the glass plate are required to resist the pressure. To build the viewports from the commercially accessible glass panes, multi-layered glass units are proposed in the paper. Numerical calculations are presented, summarized and compared with experimental tests. Focusing...
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Bending of a Three-Layered Plate with Surface Stresses
PublicationWe discuss here the bending deformations of a three-layered plate taking into account surface and interfacial stresses. The first-order shear deformation plate theory and the Gurtin-Murdoch model of surface stresses will be considered and the formulae for stiffness parameters of the plate are derived. Their dependence on surface elastic moduli will be analyzed.
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Storing Matter’technique in SIMS depth profile analysis
PublicationSecondary ion mass spectrometry (SIMS) is a very useful technique for the analysis of layered systems. It is based on the primary ion beam sputtering of solids and mass analysis of the emitted secondary ions. A main limitation of this technique results from the direct quantitative analysis, since the ionization efficiency of a given atom is highly influenced by the neighbouring atoms at the surface. This phenomenon is known as...
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Ball milling induced borophene flakes fabrication
PublicationTo fill the knowledge gap for borophene, as the youngest member of the two-dimensional (2D)nanomaterials family, a facile, cost effective, scalable and reproducible fabrication route is still stronglyrequired. Among so far studied techniques the potential of pure mechanical processes such as ballmilling is not explored yet. Therefore, in this contribution, we explore the efficiency...
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Layer-by-layer polymer deposited fabrics with superior flame retardancy and electrical conductivity
PublicationSmart and multifunctional textiles and fabrics are progressively developing, such that multifunctional fabrics are becoming more widespread. We elaborated herein multi-layered flax fabrics with superior flame retardancy and conductivity, which revealed fireproof feature while keeping conductivity during burning. The flax fabric was reinforced by layer-by-layer (LbL) deposition of sodium polyacrylate (SPA), polyethylenimine (PEI),...
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Interlaboratory Test to Characterize the Cyclic Behavior of Bituminous Interlayers: An Overview of Testing Equipment and Protocols
PublicationThe performance assessment of multi-layered pavements strongly depends on the mechanical behavior of the interface between bituminous layers. So far, comprehensive studies have been carried out mainly using quasi-static laboratory tests focusing on the interlayer shear strength at failure. However, it is generally recognized that cyclic shear testing will lead to the determination of parameters which are more closely linked to...
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Mechanical analysis of eccentric defected bilayer graphene sheets considering the van der Waals force
PublicationIn this article, we have tried to simulate nonlinear bending analysis of a double-layered graphene sheet which contains a geometrical imperfection based on an eccentric hole. The first-order shear deformation theory is considered to obtain the governing equations. Also, the nonlinear von Kármán strain field has been assumed in order to obtain large deformations. Whereas the double-layered graphene sheet has been considered, the...
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Interlaboratory Test to Characterize the Cyclic Behavior of Bituminous Interlayers: An Overview of Testing Equipment and Protocols
PublicationThe performance assessment of multi-layered pavements strongly depends on the mechanical behavior of the interface between bituminous layers. So far, comprehensive studies have been carried out mainly using quasi-static laboratory tests focusing on the interlayer shear strength at failure. However, it is generally recognized that cyclic shear testing will lead to the determination of parameters which are more closely linked to...
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The influence of thermal treatment on electrocatalytic properties of Mn-Co nanofilms on nickel foam toward oxygen evolution reaction activity
PublicationThis work evaluates electrodeposited and differently treated Mn-Co catalysts for their oxygen evolution reaction activity. Catalysts are evaluated in the as-deposited and heat treated state: after 350 C and 600 C. Results show that the highest electrochemical activity is obtained for the as-deposited Mn-Co oxyhydroxide, which possibly possess a layered double hydroxide structure. After the heat treatment process, especially after...
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The (Un)Real City by Magdalena Abakanowicz: Guidelines for Cities in Times of Planetary Crisis
PublicationThree decades have passed since Magdalena Abakanowicz presented her concept of Bois de Nanterre — Arboreal Architecture, in response to a call for a broader reflection on approaches to urban landscaping and a reinterpretation of the meaning and evolution of the Grand Axis in Paris. This paper analyses the work presented by the artist from an urban planning perspective. It shows how the rich and multi-layered metaphor for the 21st-century...
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Improving web user experience with caching user interface
PublicationOften, Web technologies are used to operate or to configure network-enabled equipment, to configure and administer modular applications, or as teaching environments. The comfort of human work requires a similar response time in these applications as in the Internet. To improve response time, various forms of caching at different levels are employed. To improve the user experience in regard to response time when performing specific...
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INFLUENCE OF TIME ON THE BEARING CAPACITY OF PRECAST PILES
PublicationOne of the most popular types of foundations in layered subsoil with very differentiated soil shear strengths are precast piles. One of the reasons is a fact that we can well control the driving process during the installation of these piles. The principles of the assessment of bearing capacity and settlements of the piles given by Eurocode 7, concentrate on two main methods, i.e. Static Pile Load Tests (SPLT) and Dynamic Driving...
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On constitutive modeling for technical woven fabric
PublicationW pracy przestawiono kilka modeli konstytutywnych przyjmowanych do opisu zachowania się tkanin technicznych. Oprócz modeli zaczerpniętych z literatury autorzy prezentują własną koncepcje modelu stanowiąca rozszerzenie modelu sieci gęstej.This paper describes several types of the constitutive models used for the technical woven fabric description. Besides of the literatures examples of the constitutive models, the authors presented...
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Multi-layered tissue head phantoms for noninvasive optical diagnostics
PublicationExtensive research in the area of optical sensing for medical diagnostics requires development of tissue phantoms with optical properties similar to those of living human tissues. Development and improvement of in vivo optical measurement systems requires the use of stable tissue phantoms with known characteristics, which are mainly used for calibration of such systems and testing their performance over time. Optical and mechanical...
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Repeated Projectile Impact Tests on Multi-Layered FibrousCementitious Composites
PublicationThis research aims to experimentally evaluate the behaviour of multi-layered fibrous cementitious composites withintermediate Glass Fibre Meshes (GFM) under repeated projectile load. The impact load was subjected through a convexedge projectile needle at a low velocity on cylindrical specimens of three-layered fibrous cementitious composites, whichhave two different steel fibre distributions. In series A mixtures, a constant steel...
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Data Partitioning and Task Management in the Clustered Server Layer of the Volunteer-based Computation System
PublicationWhile the typical volunteer-based distributed computing system focus on the computing performance, the Comcute system was designed especially to keep alive in the emergency situations. This means that designers had to take into account not only performance, but the safety of calculations as well. Quadruple-layered architecture was proposed to separate the untrusted components from the core of the system. The main layer (W) consists...
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The impact of footing conditions of a vertical-axis floating-roof tank on structural shell deformation
PublicationStructural shells of fuel tanks are often subjected to geometric imperfections which may lead to exceeding the ultimate and serviceability limit states. One of the means triggering shell deformation is non-uniform settlement caused by incoherent soil conditions. Analysis carried out in the work concerns of vertical-axis, floating-roof cylindrical shell which volume is 50.000 m3, founded on a complex multi-layered soil. The sensitivity...
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Photoelectrochemical properties of BIMEVOX (ME=Cu, Zn, Mn) electrodes in contact with aqueous electrolyte
PublicationLayered oxide Bi4O2O11 and mixed oxides of bismuth, vanadium and a third metal (ME = Cu, Zn, Mn) were synthesized and characterized using XRD, Raman and SEM. The energy band gap (Eg) of samples determined using UV–VIS reflectance spectra equals to 2.46, 2.34, 2.27 and 2.18 eV for Bi4V2O11, BICUVOX (Bi2V1 − xCuxO5.5 − 3x/2), BIZNVOX (Bi2V1 − xZnxO5.5 − 3x/2) and BIMNVOX (Bi2V1 − xMnxO5.5 − x/2) (x = 0.1), respectively. Open circuit...
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Foundations of Grid Processing Architecture for the Comcute System
PublicationFundamental system algorithms and structures implemented in the Comcute system are described and analysed in detail. Layered architecture of the system model is highlighted. System tasks of the layers are elaborated, presented and described. Operational details of communication interfaces among layers are worked out and examined. The focus is put onto implemented system components with regard to their operability and efficiency....
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Sensitivity analysis in design process of sandwich U-shaped composite footbridge
PublicationThe structure of the sandwich composite footbridge of a 14 metre span length and U-shaped cross-section was analysed. Sensitivity analysis was performed to support the design process of this innovative object. Linear discrete sensitivity analysis was performed by means of finite element method. The influence of vari-ation of several design variables i.e. thicknesses of inner and outer laminates on the mid-span deflection, as-sumed...
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Defining the thermal conductivity of thermally heterogeneous hollow wall bricks used as elements for increasing the comfort of buildings
PublicationThe article presents numerical calculation analysis in the scope of determining thermal conductivity coefficientλeq[W/(m·K)] of thermally heterogeneous hollow bricks of thermally heterogeneous structure (a combinationof structural material with thermal insulation material). Numerical calculations were conducted by means ofprofessional software TRISCO-KOBRU 86, serving thermal circulation analysis in a 2D field in stationary approach.The...
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Equivalent Single Layer Models in Free Vibration Analysis of Laminated Multi-Layered Plates
PublicationThe performance of selected equivalent single-layer (ESL) models is evaluated within several classical benchmark tests for small amplitude free vibration analysis of multi-layered plates. The authors elaborated their own Finite Element software based on the first-order shear deformation (FOSD) theory with some modifications incorporated including a correction of the transverse shear stiffness and an application of zigzag type functions....
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MIEJSKIE PROJEKTY OŚWIETLENIOWE W KONTEKŚCIE REWITALIZACJI
PublicationUrban Lighting in the Context of Regeneration Processes. The article presents how multi-layered urban lighting projects fi t into the programs of integrated activities to improve the living conditions of the local community, the surrounding space, and its economic relations. The role of the electric lighting in revealing the night image of the city, its promotion and public spaces transformations off ering new impressions to city...
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Equivalent single-layer models in deformation analysis of laminated multilayered plates
PublicationThe performance of selected Equivalent Single-Layer (ESL) models is evaluated within several classical benchmark tests for linear static analysis of multi-layered plates. The authors elaborated their own Finite Element software based on the first-order shear deformation theory (FOSD) with some modifications incorporated including a correction of the transverse shear stiffness and an application of zig-zag type functions. Seven...
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Recent Advances in Graphene Oxide-Based Membranes for Heavy Metal Ions Separation
PublicationGraphene oxide (GO)-based membranes have been widely investigated for separation of dyes, salt ions, heavy metal ions, and biomolecules due to their high mechanical strength, single-layered structure, large surface area, and high affinity. However, due to irregular pore structure, nanochannels, interlayer distance, easy functionalization, swelling effect, and chemical stability under aqueous environment limited their separation...
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Noncentrosymmetric superconductor with a bulk three-dimensional Dirac cone gapped by strong spin-orbit coupling
PublicationThe layered, noncentrosymmetric heavy element PbTaSe2 is found to be superconducting. We report its electronic properties accompanied by electronic-structure calculations. Specific heat, electrical resistivity, and magnetic-susceptibility measurements indicate that PbTaSe2 is a moderately coupled, type-IIBCSsuperconductor (Tc = 3.72 K, Ginzburg–Landau parameter κ = 17) with an electron-phonon coupling constant of λep = 0.74. Electronic-structure...
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Preparation and characterization of rigid polyurethane-polyglycerolnanocomposite foams
PublicationThis work reports on the preparation of polyurethane-polyisocyanurate (PUR-PIR) foams containing different polyglycerols and layered silicate nanoclays. The rigid polyurethane foams were obtained in a laboratory scale, in a single step method, from a two-component system with a NCO to OH groups ratio equal to two. The reaction mixture consisted of the proper amounts of a commercial oligoetherpolyol, polyglycerol, catalysts, water,...
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Airstrip Ground Improvement Works by Blasting Charge Technique and Dredged-Ash Material Mixture
PublicationSoil improvement by blasting charge technique is known in geotechnics as one of the efficient and inexpensive method. It can be used in preparing of underground to found road construction and buildings as well. The technique proves usefulness especially when dynamic load is applied. It is because of non-stiff or rather resilient type soil after improvement. In noncohesive or organic soil, blasting charge...
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Bending and buckling formulation of graphene sheets based on nonlocal simple first-order shear deformation theory
PublicationThis paper presents a formulation based on simple first-order shear deformation theory (S-FSDT) for large deflection and buckling of orthotropic single-layered graphene sheets (SLGSs). The S-FSDT has many advantages compared to the classical plate theory (CPT) and conventional FSDT such as needless of shear correction factor, containing less number of unknowns than the existing FSDT and strong similarities with the CPT. Governing...
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Preparation and characterization of rigid polyurethane -polyglycerol nanocomposite foams
PublicationThis work reports on the preparation of polyurethane–polyisocyanurate (PUR–PIR) foams containing different polyglycerols and layered silicate nanoclays. The rigid polyurethane foams were obtained in a laboratory scale, in a single step method, from a two-component system with a NCO to OH groups ratio equal to two. The reaction mixture consisted of the proper amounts of a commercial oligoetherpolyol, polyglycerol, catalysts, water,...
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Sounding of Layered Marine Bottom - Model Investigations
PublicationThe necessary actions connected with interpretations of examining of physical properties of sea bottom structure is developing of proper procedure of modeling of the layered structure. The implementation of the acoustic waves for the determination of seabed stratification requires a precise diagnosis of the topic from both the theoretical and practical side. Little differences between the parameters of sediments, as well as irregular...
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The Influence of Selected Parameters of Numerical Modelling on Strains and Stresses at Weld Toe Notch
PublicationLatest development in the field of welding technology and prefabrication enabled massive production of thin-walled sandwich structures. Multi-layered sandwich structures are fabricated with the use of high-power CO2 lasers, friction welding, arc welding, hybrid welding, or other technique designed for the special purpose. Steel or aluminium alloy plates with thickness between 1 and 5 mm are connected by internal stiffeners. Strength...
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Thermal Buckling Analysis of Circular Bilayer Graphene sheets Resting on an Elastic Matrix Based on Nonlocal Continuum Mechanics
PublicationIn this article, the thermal buckling behavior of orthotropic circular bilayer graphene sheets embedded in the Winkler–Pasternak elastic medium is scrutinized. Using the nonlocal elasticity theory, the bilayer graphene sheets are modeled as a nonlocal double–layered plate that contains small scale effects and van der Waals (vdW) interaction forces. The vdW interaction forces between the layers are simulated as a set of linear springs...
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Optimization of adsorption of methyl orange from aqueous solution by magnetic CoFe2O4/ZnAl-layered double hydroxide composite using response surface methodology
PublicationThe CoFe2O4/ZnAl-layered double hydroxide (LDH) composite was successfully developed through a facile co-precipitation method, characterized, and applied as an effective adsorbent for the removal of methyl orange (MO) dye from aqueous solutions. The central composite design (CCD) of the response surface methodology (RSM) was employed to estimate and optimize process variables such as initial MO concentrations, solution pH, adsorbent...
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Dispersive Micro‐Solid Phase Extraction of Selected Metals in Water and Food Samples Followed by ICP‐OES Analysis: Method Development, Analysis of Real Samples and Greenness Evaluation
PublicationMultiwalled carbon nanotubes (MWCNTs) are well-known adsorbents because of their high surface area, layered and hollow architecture, hydrophobicity, and multiple and easily accessible adsorption sites. In this study, MWCNTs were used for dispersive micro-solid-phase extraction of various metal chelates in environmental and food samples. Different parameters such as concentration of the chelating reagent, the sorbent dosage, the...
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Facile synthesis and characterization of graphene and N-doped graphene by CVD method from liquid precursors for promising electrode materials
PublicationIn this study, high-quality and few-layered graphene was synthesized using the chemical vapor deposition (CVD) method from liquid sources. Two different liquid carbon sources, pyridine, and benzene, were used and deposited on nickel foam under heat conditions using a bubbler in a quartz tube. X-ray diffraction (XRD) and Raman analysis confirmed the crystalline properties of graphene and N-doped graphene, demonstrating the high...
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Rigid polyurethane foams modified with selected layered silicate nanofillers
PublicationThe aim of this study was to investigate the effect of three different nanofillers on the properties of rigid polyurethane foams, which were prepared by a one-step, laboratory-scale method from a two-component system at the ratio of NCO groups to OH groups equaled to 2. The reaction mixture consisted of the proper amounts of the commercial oligoether polyol, catalysts, water, nanoclays, and polymeric diphenylmethane diisocyanate....
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S-Shaped Suppression of the Superconducting Transition Temperature in Cu-Intercalated NbSe2
Publication2H-NbSe2 is the prototype and most frequently studied of the well-known transition metal dichalcogenide (TMDC) superconductors. As 2H-NbSe2 is widely acknowledged as a conventional superconductor, its transition temperature to the superconducting state (Tc) is 7.3 K, a Tc that is substantially higher than those seen for the majority of TMDCs, where Tc values between 2 and 4 K are the norm. Here we report the intercalation of Cu...
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Validation Process for Computational Model of Full-Scale Segment for Design of Composite Footbridge
PublicationExperimental tests and numerical simulations of a full-scale segment of a foot and cycle bridge made of polymer composites are presented in the paper. The analysed structure is made of sandwich panels, which consist of glass fibre reinforced polymer (GFRP) multi-layered laminate faces and a PET foam (obtained from recycling) core. The dimensions of the segment cross-section are the same as for the target footbridge; however, span...
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COMPOSITE MATERIAL SELECTION FOR A PATIENT TRANSFER ASSIST DEVICE
PublicationLaminates - layered composites containing at least two elements (matrix and reinforcement) widely used in industry have also found their usage in medicine. Their main feature is the ability to modify the material in order to obtain the required properties. Depending on the needs, we can modify reinforcement, type of resin or the method of bonding substrates. Commonly used fibers are: carbon fiber, glass and aramid fibers; resins...