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Search results for: THIOCYANATE ION
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Acoustic field and the entropy mode induced by it in a waveguide filled with some non-equilibrium gases
PublicationThe non-linear propagation of an acoustic beam in a rectangular waveguide is considered. The medium of sound propagation, is a gas where thermodynamically non-equilibrium processes take place: such as exothermic chemical reactions or excitation of vibrational degrees of a molecule’s freedom. The incident and reflected compounds of the acoustic field do not interact in the leading order in the case of periodic weakly nonlinear sound...
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Primo non nocere - Die Neuevaluierung und Revitalisierung des alten Universitaetsgelaendes in Danzig
PublicationKonstruując kompleksowy program rozwoju kampusu zespół specjalistów PG musiał odpowiedzieć na wiele kluczowych pytań wpływających na ostateczne decyzje przestrzenne. Historyczna część kampusu - jej spójność przestrzenna jest prawnie chroniona i nie może być zakłócona. Dlatego przy konstruowaniu programu rewitalizacji dla tej strefy przyjęto za nadrzędną dewizę Primo Non Nocere. Aby zminimalizować ingerencję w zastaną strukturę...
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Aluminum-TiO2 NPs Composites as Non-precious Catalysts for Efficient Electrochemical Generation of Hydrogen
PublicationIn this paper, we demonstrated, for the first time, aluminum titania nanoparticle (Al-TiO2 NP) composites with variable amounts of TiO2 NPs as nonprecious active catalysts for the electrochemical generation of H2. These materials were synthesized by mixing desired amounts of hydrogen titanate nanotubes (TNTs), fabricated here by a cost-effective approach at moderate hydrothermal conditions, with aluminum powder (purity 99.7%; size...
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Zero phase shift digital filtering for assessment of exposure to non-sinusoidal magnetic fields
PublicationAccuracy of assessment of human body exposure to magnetic fields is affected by several uncertainty sources. One of them is estimation of the total exposure to non-sinusoidal fields. Standard methods can be implemented using analogue or digital filters that introduce a phase shift that affect the result of total exposure level estimation. The paper presents a new method that allows performing more precise assessment of exposure...
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DZIAŁANIE AGENTÓW AUTONOMICZNYCH W SIECI TYPU ICN W OBECNOŚCI SYSTEMU REPUTACYJNEGO
PublicationCelem pracy jest przeprowadzenie symulacji sieci informacyjno-centrycznej (ICN) z agentami autonomicznymi. Architektura sieci została zmodyfikowana aby umożliwić kooperację pomiędzy agentami. Kooperacja ta przyjmuje formę porozumień nazwanych kontraktami – pojedynczy kontrakt zakłada iż dany agent będzie przetrzymywał w pamięci podręcznej daną treść przez określony czas. Do symulowanego środowiska wprowadzono agenty zachowujące...
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Influence of electropolymerization temperature on corrosion, morphological and electrical properties of PPy doped with salicylate on iron
PublicationIn this work, the influence of the electropolymerization temperature on corrosion, morphological and electrical properties of polypyrrole (PPy) film is studied. Polypyrrole is electrochemically synthesized on iron in the presence of sodium salicylate. The X-ray diffraction and scanning electron microscopy are performed in order to study the structure and morphology of electrodeposited PPy. The electroactive surface area, corrosion...
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Synthesis, structure and properties of novel poly(hydroxyurethane)s obtained by non-isocyanate route
PublicationNon-isocyanate polyurethanes (NIPUs) can be synthesized by polyaddition of five-membered bis(cyclic carbonate)s and primary diamines. NIPUs are an alternative for the commonly used (in the form of foams, elastomers, coatings or fibers) in the industry polyurethanes obtained using toxic and moisture sensitive diisocyanates, polyols and low-molecular weight chain extenders. The main aim of this work was to synthesize non-isocyanate...
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An Easy and Ecological Method of Obtaining Hydrated and Non-Crystalline WO3−x for Application in Supercapacitors
PublicationIn this work, we report the synthesis of hydrated and non-crystalline WO3 flakes (WO3−x) via an environmentally friendly and facile water-based strategy. This method is described, in the literature, as exfoliation, however, based on the results obtained, we cannot say unequivocally that we have obtained an exfoliated material. Nevertheless, the proposed modification procedure clearly affects the morphology of WO3 and leads to loss...
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The Influence of Iron Doping on Performance of SrTi1-XFexO3-δ Perovskite Oxygen Electrode for SOFC
PublicationSolid Oxide Fuel Cells (SOFC) are based on electrolytes and mixed ionic and electronic conductivity (MIEC) materials. The need to reduce costs causes an increase in interest of new compounds suitable for operating temperatures between 600 °C and 800 °C. The SrTi1-xFexO3 (STF) perovskite material is a perspective material that could be used for the oxygen electrodes. In this work STF materials with different content of iron (x =...
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New Method of Non-Linear Electrochemical Impedance Spectroscopy with an Amplitude-Modulated Perturbation Signal
PublicationThe paper presents a new method of non-linear electrochemical impedance spectroscopy (NLEIS), which allows fast and nondestructive evaluation of the corrosion rate and determination of the Tafel coefficients values for a corrosion system under investigation. This method employs amplitude modulation of the ac perturbation signal. The study demonstrated that it was possible to obtain impedance characteristic as a function of the...
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Application of non-classical operational calculus to indicate hazards in numerical solutions of engineering problems
PublicationThe article addresses the application of non- classical operational calculus to approximative solutions of engineering problems. The engineering-sound examples show that a continuous–discrete problem transformation from differential unequivocal problem to a differential wildcard problem, triggering a change in solution quality. A number of approximative methods are capable to alter both quantitative and qualitative...
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Response of cylindrical steel tank under stochastically generated non-uniform earthquake excitation
PublicationCylindrical steel tanks are very important structures in industrial facilities since their application is related to storing different types of products. Their safety and reliability have become a crucial issue because any damage may cause significant consequences, including ecological disaster. The most dangerous dynamic load acting on cylindrical steel tanks is related to earthquakes, especially that the seismic excitation may...
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Non-Salient Brushless Synchronous Generator Main Exciter Design for More Electric Aircraft
PublicationThis paper presents a prototype of high speed brushless synchronous generators (BSG) design for the application in autonomous electric power generation systems (e.g., airplane power grid). Commonly used salient pole field of the main generator part of BSG was replaced with a prototype non-salient pole field. The main objective of the research is an investigation into the advantages and disadvantages of a cylindrical field of the...
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Non-standard contact conditions in generalized continua: microblock contact model for a Cosserat body
PublicationGeneralized continuum theories involve non-standard boundary conditions that are associated with the additional kinematic variables introduced in those theories, e.g., higher gradients of the displacement field or additional kinematic degrees of freedom. Accordingly, formulation of a contact problem for such a continuum necessarily requires that adequate contact conditions are formulated for the additional kinematic variables and/or...
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Public valuation of social impacts. The comparison between mega and non-mega sporting events
PublicationThe main aim of this study is to assign value to intangible effects,including social impacts, which appear when organising sportingevents of various scales in the city of Gdansk located in northernPoland. A survey was conducted to determine the city residents’willingness-to-pay (WTP) using the contingent valuation method(CVM). The average WTP values, which ranged between PLN 6.04and PLN 46.34, show that the scale of the sporting...
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Non-ergodic fragmentation upon collision-induced activation of cysteine–water cluster cations
PublicationCysteine–water cluster cations Cys(H2O)3,6 + and Cys(H2O)3,6H+ are assembled in He droplets and probed by tandem mass spectrometry with collision-induced activation. Benchmark experimental data for this biologically important system are complemented with theory to elucidate the details of the collisioninduced activation process. Experimental energy thresholds for successive release of water are compared to water dissociation energies...
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Respiration rate estimation using non-linear observers in application to wastewater treatment plant
PublicationA problem of respiration rate estimation using two new non-linear observers for a wastewater treatment plant is addressed in this paper. In particular, a non-linear adaptive Luenberger-like observer and a super twisting sliding mode observer have been derived to produce stable and bounded estimates of the respiration rate. During the synthesis of the particular observer, an appropriate mathematical utility model was used. The observability...
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A Low-Cost System for Far-Field Non-Anechoic Measurements of Antenna Performance Figures
PublicationPrototype measurements are the key step in the development of antenna structures. Typically, their far-field characteristics are validated in expensive, dedicated facilities such as open range sites, or anechoic chambers. Despite being necessary for obtaining high-precision data (e.g., for device qualification), the use of costly infrastructure might not be fully justified when the main goal of measurements includes demonstration...
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Study of Integer Spin S = 1 in the Polar Magnet β-Ni(IO3)2
PublicationPolar magnetic materials exhibiting appreciable asymmetric exchange interactions can potentially host new topological states of matter such as vortex-like spin textures; however, realizations have been mostly limited to half-integer spins due to rare numbers of integer spin systems with broken spatial inversion lattice symmetries. Here, we studied the structure and magnetic properties of the S = 1 integer spin polar magnet β-Ni(IO3)2...
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Automated detection of pronunciation errors in non-native English speech employing deep learning
PublicationDespite significant advances in recent years, the existing Computer-Assisted Pronunciation Training (CAPT) methods detect pronunciation errors with a relatively low accuracy (precision of 60% at 40%-80% recall). This Ph.D. work proposes novel deep learning methods for detecting pronunciation errors in non-native (L2) English speech, outperforming the state-of-the-art method in AUC metric (Area under the Curve) by 41%, i.e., from...
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The selective salinity and hydrazine parameters for the start-up of non-anammox-specific biomass SBR
PublicationThe presence of ammonium (NH 4+ ) in wastewater above the permissible limits leads to undesirable ecological impact and public health concerns. In this study, the anaerobic ammonium oxidizing (anammox) bacteria-mediated nitrogen removal was investigated using a sequential batch reactor (SBR). Effects of different salinity levels were evaluated on the bacterial activity at: mild (below 0.2 g NaCl/L), elevated (18.2 g NaCl/L) and...
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Development of iron doped strontium titanates as oxygen electrode for solid oxide fuel cells
PublicationProducing efficient solid oxide fuel cells (SOFC) without the use of harmful elements is one of the current challenges. Increasing the safety of people and reducing production costs is possible, among others, thanks to the use of iron doped strontium titanates as porous oxygen electrodes. In this thesis, the results of research on iron doped strontium titanates as potential oxygen electrodes for SOFC are presented. The research...
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Benchmarking Scalability and Security Configuration Impact for A Distributed Sensors-Server IOT Use Case
PublicationInternet of Things has been getting more and more attention and found numerous practical applications. Especially important in this context are performance, security and ability to cope with failures. Especially crucial is to find good trade-off between these. In this article we present results of practical tests with multiple clients representing sensors sending notifications to an IoT middleware – DeviceHive. We investigate performance...
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Detection of Lexical Stress Errors in Non-Native (L2) English with Data Augmentation and Attention
PublicationThis paper describes two novel complementary techniques that improve the detection of lexical stress errors in non-native (L2) English speech: attention-based feature extraction and data augmentation based on Neural Text-To-Speech (TTS). In a classical approach, audio features are usually extracted from fixed regions of speech such as the syllable nucleus. We propose an attention-based deep learning model that automatically de...
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Non-Adaptive Rotor Speed Estimation of Induction Machine in an Adaptive Full-Order Observer
PublicationIn the sensorless control system of an induction machine, the rotor speed value is not measured but reconstructed by an observer structure. The rotor speed value can be reconstructed by the classical adaptive law with the integrator. The second approach, which is the main contribution of this paper, is the non-adaptive structure without an integrator. The proposed method of the rotor speed reconstruction is based on an algebraic...
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Weakly-Supervised Word-Level Pronunciation Error Detection in Non-Native English Speech
PublicationWe propose a weakly-supervised model for word-level mispronunciation detection in non-native (L2) English speech. To train this model, phonetically transcribed L2 speech is not required and we only need to mark mispronounced words. The lack of phonetic transcriptions for L2 speech means that the model has to learn only from a weak signal of word-level mispronunciations. Because of that and due to the limited amount of mispronounced...
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Comparing Apples and Oranges: A Mobile User Experience Study of iOS and Android Consumer Devices
PublicationWith the rapid development of wireless networks and the spread of broadband access around the world, the number of active mobile user devices continues to grow. Each year more and more terminals are released on the market, with the smartphone being the most popular among them. They include low-end, mid-range, and of course high-end devices, with top hardware specifications. They do vary in build quality, utilized type of material,...
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Bismuth-Doped Nano Zerovalent Iron: A Novel Catalyst for Chloramphenicol Degradation and Hydrogen Production
PublicationIn this study, we showed that doping bismuth (Bi) at the surface of Fe0 (Bi/Fe0, bimetallic iron system)—synthesized by a simple borohydride reduction method—can considerably accelerate the reductive degradation of chloramphenicol (CHP). At a reaction time of 12 min, 62, 68, 74, 95, and 82% degradation of CHP was achieved with Fe0, Bi/Fe0-1 [1% (w/w) of Bi], Bi/Fe0-3 [3% (w/w) of Bi], Bi/Fe0-5 [5% (w/w) of Bi], and Bi/Fe0-8 [8%...
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Estimation of the size of informal employment based on administrative records with non‐ignorable selection mechanism
PublicationIn this study, we used company level administrative data from the National Labour Inspectorate and The Polish Social Insurance Institution in order to estimate the prevalence of informal employment in Poland in 2016. Since the selection mechanism is non‐ignorable, we employed a generalization of Heckman’s sample selection model assuming non‐Gaussian correlation of errors and clustering by incorporation of random effects. We found...
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Conservation aspects of cast-iron platform shelters on the example of Vistula Pomerania railway stations
PublicationCast-iron shelters were used in the 19th century as cheaper alternatives to large platform halls. Nevertheless, they were aesthetically distinguishable from later riveted solutions. Because of their durability and continuous utility, they were not the subject of disassembly, as numerous transport infrastructure objects have been in recent decades. This article aims to indicate proper conservation practices during construction works...
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Numerical Modelling of Shear Localization in Granular Bodies using MPM and Non-local Hypoplasticity
PublicationThe paper deals with modelling of shear localization in granular bodies by means of an enhanced hypoplastic constitutive model and material point method (MPM). The calculations were carried out for plane strain compression of non-cohesive sand. In order to properly capture the width and inclination of shear zones, the constitutive model was enriched by a characteristic length of micro-structure by means of a non-local theory....
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A non-local elasto-plastic model to simulate localizations of deformations in quasi-brittle materials
PublicationW pracy omówiono wpływ długości charakterystycznej na szerokość lokalizacji odkształceń stycznych w materiałach kruchych. Obliczenia wykonano MES ma bazie nielokalnego sprężysto-plastycznego prawa konstytutywnego podczas ściskania jednoosiowego w płaskim stanie odkształcenia.
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A non local elasto-plastic model to simulate localisations of deformationin quasi-brittle materials.
PublicationOmówiono wyniki symulacji lokalizacji odkształceń stycznych w materiałach kruchych. Analizę przeprowadzono stosując metodę elementów skończonych i nielokalne prawo sprężysto-plastyczne. Obliczenia wykonano dla ściskania i rozciągania w płaskim stanie odkształceń.
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Numerical simulations of localization of deformation in quasibrittle materials within non-local softening plasticity.
PublicationW artykule przedstawiono model sprężysto-plastyczny z nielokalnym osłabieniem do obliczeń lokalizacji odkształceń w materiałach kruchych. Analizę przeprowadzono dla jednoosiowego ściskania i rozciągania. Obliczenia wykonano dla różnych długości charakterystycznych.
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Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based on p-tert-Butyl-calix[4]arene Thioamides.
PublicationTetra podstawione tioamidowe pochodne para-tert-butylokaliks[4]arenu (1-5) zostały zastosowane jako jonofory w membranowych elektrodach jonoselektywnych (EJS) selektywne na kationy Pb(II). Wyznaczono współczynniki selektywności. Czwartorzędowe kaliks[4]aren-tioamidy (1,2) wykazują nadzwyczaj dobrą selektywność na kationy Pb(II) w porównaniu z kaliks[4]aren-amidami. Membrany z tymi ligandami wykazują dużą trwałość, a charakterystyki...
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On the relationship between the structural and volumetric properties of solvated metal ions in O-donor solvents using new structural data in amide solvents
PublicationThe structures of the N,N-dimethylformamide (dmf), N,N-dimethylacetamide (dma), and N,N-dimethylpropionamide (dmp) solvated strontium and barium ions have been determined in solution using large angle X-ray scattering and EXAFS spectroscopy. The strontium ion has a mean coordination number (CN) between 6.2 and 6.8, and the barium ion has a mean CN between 7.1 and 7.8 in these amide solvents. The non-integer numbers indicates that...
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Mixed-ligand complexes of zinc(II), cobalt(II) and cadmium(II) with sulfur, nitrogen and oxygen ligands. Analysis of the solid state structure and solution behavior. Implications for metal ion substitution in alcohol dehydrogenase
PublicationScharakteryzowano strukturę heteroleptycznych kompleksów cynku(II), kobaltu(II) i kadmu(II) z 2-(2'-hydroksyetylopirydyną), tri-tert-butoksysilanotiolem i metanolem. Przy pomocy widm UV-Vis i NMR stwierdzono szybką wymianę N-liganda w roztworach tych kompleksów. Wyznaczono przesunięcia 15N NMR 2-(2'-hydroksyetylopirydyny) w kompleksach cynku(II) i kadmu(II). Na podstawie widm w podczerwieni i obliczeń DFT oszacowano względną moc...
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ON ESTIMATION OF OCCUPANT SAFETY IN VEHICULAR CRASHES INTO ROADSIDE OBSTACLES USING NON-LINEAR DYNAMIC ANALYSIS
PublicationThe article describes a comparison of two general methods of occupants safety estimation based on a numerical examples. The so-called direct method is mainly based on the Head Injury Criterion of a crash test dummy in a vehicle with passive safety system while the indirect method uses a European standards approach to estimate impact severity level. Numerical simulations in LS-DYNA have been conducted.
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Effective degradation of sulfide ions and organic sulfides in cavitation-based Advanced Oxidation Processes (AOPs)
PublicationThe paper presents the results of investigations on the effectiveness and reaction rate constants of the oxidation of sulfide ions and organic sulfides in real industrial effluents from the production of bitumens (2000 mg S2- L-1) using hydrodynamic and acoustic cavitation. The content of the effluents was analysed in terms carbon disulfide, dimethyl sulfide, and di-tert-butyl disulfide concentration. A possibility of complete...
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NON-LINEAR MASTIC CHARACTERISTICS BASED ON THE MODIFIED MSCR (MULTIPLE STRESS CREEP RECOVERY) TEST
PublicationMastic containing asphalt in its composition is an example of a viscoelastic material. It is an effective binder in asphalt. It consists of a filler (<0.063 mm) and asphalt mixed in the right proportions. Just like in asphalt, its response depends on the temperature level, the load and stress time. Changing the stress stiffness of the mastic affects the non-linear course of the stress-strain relationship. Modelling of the non-linear...
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Machine Learning Applied to Aspirated and Non-Aspirated Allophone Classification—An Approach Based on Audio "Fingerprinting"
PublicationThe purpose of this study is to involve both Convolutional Neural Networks and a typical learning algorithm in the allophone classification process. A list of words including aspirated and non-aspirated allophones pronounced by native and non-native English speakers is recorded and then edited and analyzed. Allophones extracted from English speakers’ recordings are presented in the form of two-dimensional spectrogram images and...
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Evaluation of the use of reindeer droppings for monitoring essential and non-essential elements in the polar terrestrial environment
PublicationExcess or toxic metals, non-metals and metalloids can be eliminated from the organism by deposition in inert tissue (e.g. fur) or excretion with body secretions, urine and faeces. Droppings are one of the main routes for the elimination of multiple elements and they can be collected without direct contact with the animal. Contaminant concentration has been examined in non-lethally collected tissues of several species (especially...
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Odpowiedź na zarzuty Pozwanego w związku z wykonaną opinią (1/IWN/2018)
PublicationDokument zawiera odpowiedzi na pytania strony pozwanej dotyczące wpływu transportu, rozpakowania, sposoby wykonania linii kablowej, diagnozowania linii kablowej, prac naprawczych na poziom uszkodzeń powłoki zewnętrznej.
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Improved Performance of 1-Ethyl-3-Methylimidazolium Tetrafluoroborate at Steel/HCl Interface by Iodide Ions
PublicationThe corrosion and corrosion inhibition of St37 steel in 0.1 M HCl solution by 1-ethyl-3-methylimidazolium tetrafluoroborate (EMITFB) and the effect of addition of KI on the inhibitive performance of EMITFB have been examined by electrochemical [electrochemical impedance spectroscopy, potentiodynamic polarization, and dynamic electrochemical impedance spectroscopy (DEIS)] and surface examination [scanning electron microscope (SEM)...
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Studies on Silver Ions Releasing Processes and Mechanical Properties of Surface-Modified Titanium Alloy Implants
PublicationDispersed silver nanoparticles (AgNPs) on the surface of titanium alloy (Ti6Al4V) and titanium alloy modified by titania nanotube layer (Ti6Al4V/TNT) substrates were produced by the chemical vapor deposition method (CVD) using a novel precursor of the formula [Ag5(O2CC2F5)5(H2O)3]. The structure and volatile properties of this compound were determined using single crystal X-ray diffractometry, variable temperature IR spectrophotometry...
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Syntheses, Structures and Reactivity of Terminal Phosphido Complexes of Iron(II) Supported by a β-Diketiminato Ligand
PublicationWe report the synthesis of the first series of terminal phosphido iron complexes supported by a β‐diketiminato ligand (Dippnacnac) and their catalytic activity in dehydrocoupling of secondary phosphines. Anionic and neutral mono‐ or diphosphido complexes were obtained from the reaction of [(Dippnacnac)FeCl2Li(dme)2] with the R2PLi (R = iPr, tBu, Cy, Ph) phosphides by tuning the stoichiometric ratio, polarity of the solvent, and...
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Study on 19th-century cast iron columns from the former financial office building in Kwidzyn
PublicationThe article presents the results for cast iron columns used as floor supports in the former financial office building in Kwidzyn (Poland).The stocktaking drawings provided the general and detailed data about the 19th century designer’s decisions. During the research, architectural and structural analysis was carried out. The graphics were used as a starting material for preparing 3D calculation models. The FEM-based numerical simulations...
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Multianalyte Calibration Methods for Potentiometric Integrated Sensors System for Determination of Ions Concentration in a Body Fluids
PublicationIn recent years, integration and miniaturization of ion-selective electrodes (ISEs) have brought many benefits resulting in the possibility of simultaneous determination of the ions concentration in a small sample volume. One of the key problems related to the preparation of integrated sensors systems (ISSs) is a calibration procedure due to the necessity to calibrate each particular sensor separately. The main aim of the research...
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Airfoil Design Under Uncertainty Using Non-Intrusive Polynomial Chaos Theory and Utility Functions
PublicationFast and accurate airfoil design under uncertainty using non-intrusive polynomial chaos (NIPC) expansions and utility functions is proposed. The NIPC expansions provide a means to efficiently and accurately compute statistical information for a given set of input variables with associated probability distribution. Utility functions provide a way to rigorously formulate the design problem. In this work, these two methods are integrated...
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Impact of inorganic ions and pH variations on toxicity and endocrine potential of selected environmentally relevant pharmaceuticals
PublicationAssessment of the impact of pharmaceutical residues on living organisms is a very complex subject. Apart from taking into account the toxicity of individual compounds, environmental factors should also be taken into account. In this paper, attempts were made to assess the impact of coexisting inorganic ions and changes in pH on the toxicity of ten selected pharmaceuticals. Two bioassays were used to measure the estrogenic and androgenic...