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Triplet–Triplet Annihilation Upconverting Liposomes: Mechanistic Insights into the Role of Membranes in Two-Dimensional TTA-UC
PublicationTriplet−triplet annihilation upconversion (TTA-UC) implemented in nanoparticle assemblies is of emerging interest in biomedical applications, including in drug delivery and imaging. As it is a bimolecular process, ensuring sufficient mobility of the sensitizer and annihilator to facilitate effective collision in the nanoparticle is key. Liposomes can provide the benefits of two-dimensional confinement and condensed concentration...
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Enhanced Mechanical and Electromechanical Properties of Compositionally Complex Zirconia Zr1–x(Gd1/5Pr1/5Nd1/5Sm1/5Y1/5)xO2−δ Ceramics
PublicationCompositionally complex oxides (CCOs) or high-entropy oxides (HEOs) are new multi-element oxides with unexplored physical and functional properties. In this work, we report fluorite structure derived compositionally complex zirconia with composition Zr1- x(Gd1/5Pr1/5Nd1/5Sm1/5Y1/5)xO2-δ (x = 0.1 and 0.2) synthesized in solid-state reaction route and sintered via hot pressing at 1350 °C. We explore the evolution of these oxides'...
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Tailoring Defects in B, N-Codoped Carbon Nanowalls for Direct Electrochemical Oxidation of Glyphosate and its Metabolites
PublicationTailoring the defects in graphene and its related carbon allotropes has great potential to exploit their enhanced electrochemical properties for energy applications, environmental remediation, and sensing. Vertical graphene, also known as carbon nanowalls (CNWs), exhibits a large surface area, enhanced charge transfer capability, and high defect density, making it suitable for a wide range of emerging applications. However, precise...
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Synthesis and Characterization of Size- and Charge-Tunable Silver Nanoparticles for Selective Anticancer and Antibacterial Treatment
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Near-Infrared-Triggered Nitrogen Fixation over Upconversion Nanoparticles Assembled Carbon Nitride Nanotubes with Nitrogen Vacancies
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Narrow Red Emission Band Fluoride Phosphor KNaSiF6:Mn4+ for Warm White Light-Emitting Diodes
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Aluminate Red Phosphor in Light-Emitting Diodes: Theoretical Calculations, Charge Varieties, and High-Pressure Luminescence Analysis
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Enhance Color Rendering Index via Full Spectrum Employing the Important Key of Cyan Phosphor
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Formation and Near-Infrared Emission of CsPbI3 Nanoparticles Embedded in Cs4PbI6 Crystals
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Thermally Stable and Deep Red Luminescence of Sr1–xBax[Mg2Al2N4]:Eu2+ (x = 0–1) Phosphors for Solid State and Agricultural Lighting Applications
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Carbon-Coated Tellurium for Optical Data Storage
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Size-Dependent in Vitro Biocompatibility and Uptake Process of Polymeric Carbon Nitride
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Tuning Electrochemical Performance by Microstructural Optimization of the Nanocrystalline Functional Oxygen Electrode Layer for Solid Oxide Cells
PublicationFurther development of solid oxide fuel cell (SOFC) oxygen electrodes can be achieved through improvements in oxygen electrode design by microstructure miniaturisation alongside nanomaterials implementation. In this work, improved electrochemical performance of an La0.6Sr0.4Co0.2Fe0.8O3-d (LSCF) cathode was achieved by the controlled modification of the La0.6Sr0.4CoO3-d (LSC) nanocrystalline interlayer introduced between a porous...
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Spin-Resolved Band Structure of Hoffman Clathrate [Fe(pz)2Pt(CN)4] as an Essential Tool to Predict Optical Spectra of Metal–Organic Frameworks
PublicationParamount spin-crossover properties of the 3D-Hoffman metalorganic framework (MOF) [Fe(pz)2Pt(CN)4] are generally described on the basis of the ligand field theory, which provides adequate insight into theoretical and simulation analysis of spintronic complexes. However, the ligand field approximation does not take into account the 3D periodicity of the actual complex lattice and surface effects and therefore cannot predict a full-scale...
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Aluminum-TiO2 NPs Composites as Non-precious Catalysts for Efficient Electrochemical Generation of Hydrogen
PublicationIn this paper, we demonstrated, for the first time, aluminum titania nanoparticle (Al-TiO2 NP) composites with variable amounts of TiO2 NPs as nonprecious active catalysts for the electrochemical generation of H2. These materials were synthesized by mixing desired amounts of hydrogen titanate nanotubes (TNTs), fabricated here by a cost-effective approach at moderate hydrothermal conditions, with aluminum powder (purity 99.7%; size...
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Boron-Enhanced Growth of Micron-Scale Carbon-Based Nanowalls: A Route toward High Rates of Electrochemical Biosensing
PublicationIn this study, we have demonstrated the fabrication of novel materials called boron-doped carbon nanowalls (B:CNWs), which are characterized by remarkable electrochemical properties such as high standard rate constant (k°), low peak-to-peak separation value (ΔE) for the oxidation and reduction processes of the [Fe(CN)6]3–/4– redox system, and low surface resistivity. The B:CNW samples were deposited by the microwave plasma-assisted...
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Is the Solid Electrolyte Interphase an Extra-Charge Reservoir in Li-Ion Batteries?
PublicationAdvanced metal oxide electrodes in Li-ion batteries usually show reversible capacities exceeding the theoretically expected ones. Despite many studies and tentative interpretations, the origin of this extra-capacity is not assessed yet. Lithium storage can be increased through different chemical processes developing in the electrodes during charging cycles. The solid electrolyte interface (SEI), formed already during the first...
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Influence of Annealing Atmospheres on Photoelectrochemical Activity of TiO2 Nanotubes Modified with AuCu Nanoparticles
PublicationIn this article, we studied the annealing process of AuCu layers deposited on TiO2 nanotubes (NTs) conducted in various atmospheres such as air, vacuum, argon, and hydrogen in order to obtain materials active in both visible and UV–vis ranges. The material fabrication route covers the electrochemical anodization of a Ti plate, followed by thin AuCu film magnetron sputtering and further thermal treatment. Scanning electron microscopy...
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Nitrogen-Incorporated Boron-Doped Nanocrystalline Diamond Nanowires for Microplasma Illumination
PublicationThe origin of nitrogen-incorporated boron-doped nanocrystalline diamond (NB-NCD) nanowires as a function of substrate temperature (Ts) in H2/CH4/B2H6/N2 reactant gases is systematically addressed. Because of Ts, there is a drastic modification in the dimensional structure and microstructure and hence in the several properties of the NB-NCD films. The NB-NCD films grown at low Ts (400 °C) contain faceted diamond grains. The morphology...
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New Unsymmetrical Bisacridine Derivatives Noncovalently Attached to Quaternary Quantum Dots Improve Cancer Therapy by Enhancing Cytotoxicity toward Cancer Cells and Protecting Normal Cells
PublicationThe use of nanoparticles for the controlled drug delivery to cells has emerged as a good alternative to traditional systemic delivery. Quantum dots (QDs) offer potentially invaluable societal benefits such as drug targeting and in vivo biomedical imaging. In contrast, QDs may also pose risks to human health and the environment under certain conditions. Here, we demonstrated that unique combination of nanocrystals core components...
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Scalable Route toward Superior Photoresponse of UV-Laser-Treated TiO2 Nanotubes
PublicationTitanium dioxide nanotubes gain considerable attention as a photoactive material due to chemical stability, photocorrosion resistance, or lowcost manufacturing method. This work presents scalable pulsed laser modification of TiO2 nanotubes resulting in enhanced photoactivity in a system equipped with a motorized table, which allows for modifications of both precisely selected and any-large sample area. Images obtained from scanning...
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Diiodo-BODIPY Sensitizing of the [Mo3S13]2– Cluster for Noble-Metal-Free Visible-Light-Driven Hydrogen Evolution within a Polyampholytic Matrix
PublicationWe report on a photocatalytic setup that utilizes the organic photosensitizer (PS) diiodo-BODIPY and the non-precious-metal-based hydrogen evolution reaction (HER) catalyst (NH4)2[Mo3S13] together with a polyampholytic unimolecular matrix poly(dehydroalanine)-graft-poly(ethyleneglycol) (PDha-g-PEG) in aqueous media. The system shows exceptionally high performance with turnover numbers (TON > 7300) and turnover frequencies (TOF...
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New methods for assessment and stimulation of non-communicative patients employing advanced multimodal HCI . Nowe metody oceny i stymulacji pacjentów niekomunikatywnych z wykorzystaniem zaawansowanych interfejsów multimodalnych człowiek-komputer
PublicationIn most cases of patients with locomotor system damage it is possible to find a solution to the medical problems originating from the injury. However, it is much more difficult to prevent cognitive and emotional impairments. Therefore, we believe that the technological support of therapists working with such patients on an everyday basis may be essential. We have acquired experience in designing and providing diagnostic and therapeutic...
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Accuracy analysis of the RSSI BLE SensorTag signal for indoor localization purposes
PublicationIn this paper we describe possibility of use the RSSI signal (Radio Signal Strength Indication) from Texas Instruments SensorTag CC2650 for indoor positioning purposes. This idea is not a new but in our opinion it is possible to use SensorTags with Bluetooth LE wireless interface for positioning inside buildings in such applications as people findings in hospitals, senior come care, etc. RSSI is mostly selected as the sensor localization...
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Virtual Keyboard controlled by eye gaze employing speech synthesis
PublicationThe article presents the speech synthesis integrated into the eye gaze tracking system. This approach can significantly improve the quality of life of physically disabled people who are unable to communicate. The virtual keyboard (QWERTY) is an interface which allows for entering the text for the speech synthesizer. First, this article describes a methodology of determining the fixation point on a computer screen. Then it presents...
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Virtual keyboard controlled by eye gaze employing speech synthesis
PublicationThe article presents the speech synthesis integrated into the eye gaze tracking system. This approach can significantly improve the quality of life of physically disabled people who are unable to communicate. The virtual keyboard (QWERTY) is an interface which allows for entering the text for the speech synthesizer. First, this article describes a methodology of determining the fixation point on a computer screen. Then it presents...
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Ancillary services to grids provided with distributed generation
PublicationThe paper introduces system for utilization of the customer-side generated energy. Additionally system can secure some ancillary services to grids. Those services include: current active filtering, load voltage stabilization and in case of grid voltage faults - uninterruptible load supplying (possible with energy storage device). Presented experimental results confirm flexibility of this arrangement in processes of power delivery...
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Advanced Control With PLC—Code Generator for aMPC Controller Implementation and Cooperation With External Computational Server for Dealing With Multidimensionality, Constraints and LMI Based Robustness
PublicationThe manufacturers of Programmable Logic Controllers (PLC) usually equip their products with extremely simple control algorithms, such as PID and on-off regulators. However, modern PLCs have much more efficient processors and extensive memory, which enables implementing more sophisticated controllers. The paper discusses issues related to the implementation of matrix operations, time limitations for code execution within one PLC...
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Microstructure and mechanical properties of a dissimilar metal welded joint of Inconel 617 and P92 steel with Inconel 82 buttering layer for AUSC boiler application
PublicationThe application of the novel dissimilar metal welded (DMW) joint, utilizing Inconel 617 and P92 steel, was showcased in the advanced ultra-supercritical (AUSC) boiler. The work has been performed to investigate the effect of Inconel 82 (ERNiCr-3) buttering layer on microstructure and mechanical properties (high-temperature tensile strength, impact strength and microhardness) of gas tungsten arc welded (GTAW) dissimilar joint between...
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Strony WWW bibliotek jako element promocji i narzędzie komunikacji z użytkownikiem
PublicationW artykule przedstawiono zasady tworzenia stron WWW bibliotek, ze szczególnym uwzględnieniem bibliotek kościelnych. Zwrócono uwagę na elementy interfejsu i narzędzia służące informacji o zbiorach i usługach, a także promocji działalności biblioteki. Omówiono narzędzia z obszaru Web 2.0, służące komunikacji z użytkownikami w przestrzeni wirtualnej w czasie rzeczywistym (takie jak komunikatory, czaty, formularze zapytań) na przykładzie...
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Hybrid Laboratory of Radio Communication With Online Simulators and Remote Access
PublicationContribution: Two toolsets for the remote teaching of radio communication laboratory classes: 1) online simulators for individual work of students and 2) a remote access system to laboratory workstations for group work. Initial assumptions and method of implementation of both tools are presented. Background: The COVID-19 pandemic has forced a change in teaching at all levels of education. The specificity of practical classes, such...
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Wire Arc Additive Manufactured Mild Steel and Austenitic Stainless Steel Components: Microstructure, Mechanical Properties and Residual Stresses
PublicationWire arc additive manufacturing (WAAM) is an additive manufacturing process based on the arc welding process in which wire is melted by an electric arc and deposited layer by layer. Due to the cost and rate benefits over powder-based additive manufacturing technologies and other alternative heat sources such as laser and electron beams, the process is currently receiving much attention in the industrial production sector. The gas...
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Yade-open DEM: an open-source software using a discrete element methodto simulate granular material
PublicationPurpose - YADE-OPEN DEM is an open source software based on the Discrete Element Method which uses object oriented programming techniques. The paper describes the softwarearchitecture.Design/methodology/approach - The DEM chosen uses position, orientation, velocity and angular velocity as independent variables of simulated particles which are subject to explicit leapfrog time-integration scheme (Lagrangian method). The three-dimensional...
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Pre-arrangement of solvability, complexity, stability and quality of GPC systems
PublicationPraca dotyczy podstawowych problemów strojenia algorytmów dyskretnoczasowego uogólnienia sterowania predykcyjnego (GPC). Optymalne sterowanie predykcyjne, w sensie pewnego kwadratowego funkcjonału kosztów, wyznacza się rozwiązując odpowiednie liniowe zadanie. W pracy podano warunki, przy których macierz tego zadania jest macierzą o pełnym kolumnowym rzędzie - co gwarantuje istnienie optymalnego sterownika. W następnej kolejności...
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Asynchronous distributed state estimation based on a continuous-time stochastic model
PublicationW artykule rozważa się ogólny problem estymacji stanu w asynchronicznych rozłożonych systemach (ADE) opartych na wielu czujnikach. W takich systemach stan obiektu jest oceniany przez grupę lokalnych estymatorów, z których każdy oparty zwykle na filtrze Kalmana, dokonuje fuzji danych zebranych poprzez jego lokalne czujniki oraz danych uzyskanych od innych (zdalnych) procesorów, w celu wyznaczenia możliwie najlepszych estymat. Przeprowadzając...
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Hybrid SONIC: joint feedforward–feedback narrowband interference canceler
PublicationSONIC (self-optimizing narrowband interference canceler) is an acronym of a recently proposed active noise control algorithm with interesting adaptivity and robustness properties. SONIC is a purely feedback controller, capable of rejecting nonstationary sinusoidal disturbances (with time-varying amplitude and/or frequency) in the presence of plant (secondary path) uncertainty. We show that although SONIC can work reliably without...
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Marek Tobiszewski dr hab. inż.
PeopleBorn on April 7, 1984 in Gdańsk. In 2012, he defended his doctorate with honors, in 2017 he obtained his habilitation on the basis of the scientific achievement "Development of analytical procedures and solvents for the assessment of environmental nuisance". He has been working at the Department of Analytical Chemistry since 2012. His research interests includes analytical chemistry, especially the analytics of organic compounds...
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Information Extraction from Polish Radiology Reports using Language Models
PublicationRadiology reports are vital elements of directing patient care. They are usually delivered in free text form, which makes them prone to errors, such as omission in reporting radiological findings and using difficult-to-comprehend mental shortcuts. Although structured reporting is the recommended method, its adoption continues to be limited. Radiologists find structured reports too limiting and burdensome. In this paper, we propose...
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On phase equilibrium of an elastic liquid shell with wedge disclination
PublicationBased on the six-parameter shell theory we consider the phase equilibrium of a two-phase liquid membrane containing a wedge disclination. The considered problems are related to modelling of phase transitions in biological or lipid membranes. In order to capture the membrane behaviour we consider a special case of elastic shells which energy is invariant under major transformations of a reference configuration and can be treated...
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LOW COST MEASUREMENT MODULE FOR MATRIX OF AMPEROMETRIC GAS SENSOR
PublicationThis paper describes an amperometric sensor module for gas concentration measurement. A module can be used for many types of electrochemical gas sensors without major hardware changes. Device is based on AVR ATmega8 microcontroller. As signal processing circuit a specialized integrated circuit LMP9l000 configurable via I2C interface is used. The concept of a measuring system composed of several modules dedicated for a gas sensors...
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An approach to determining tinnitus acoustical characteristic
PublicationFor many treatment methods, accurate estimation of Tinnitus(ringing in ears) concerning sound type, level, and bandwidth or frequency is inevitable. The proposed way of obtaining Tinnitus parameters is described in this paper. The method employs sound synthesis, aimed at obtaining sound which is closest to perceived Tinnitus. The proposed method assumes running a designed application on a multimedia PC provided with a special graphical...
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CMOS implementation of an analogue median filter for image processing in real time
PublicationAn analogue median filter, realised in a 0.35 μm CMOS technology, is presented in this paper. The key advantages of the filter are: high speed of image processing (50 frames per second), low-power operation (below 1.25 mW under 3.3 V supply) and relatively high accuracy of signal processing. The presented filter is a part of an integrated circuit for image processing (a vision chip), containing: a photo-sensor matrix, a set of...
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A Strategy for Managing the Operation of Technical Infrastructure Based on the Analysis of “Bad Actors”—A Case Study of LOTOS Group S.A.
PublicationThe article covers issues related to the selection of a management strategy for the operation of technical infrastructure. It contains the approaches, methodology and a general model of the system of operation of the Maintenance Services of the LOTOS Group production company, which is an example of a large oil concern. Nowadays, an increasing aspect is put on the efficiency of individual repair processes, as well as the operation...
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PV installations and the safety of residential buildings
PublicationThe dynamic development of the photovoltaic industry entails threats that have a direct impact on the safety of residential buildings. Appropriate design of a PV installation can be a challenge due to the multifaceted nature of this issue. The designer should take into account issues related to the selection of electrical parameters of the installation, adapting lightning and surge protection in accordance...
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Drewno w adoptowanym zabytku - studium przypadku. Budynek nr 2 w dawnych koszarach garnizonu we Wrzeszczu
PublicationThe current structure along with adapted listed buildings and surroundings will create "Garrison of Culture".This part of Gdańsk and Wrzeszcz has been reconnected after eight decades of isolation from the city by joining the square area formed by Grunwaldzka, Słowackiego, Chrzanowskiego, Szymanowskiego streets and the city center. It is a project whitch fits into an aspect of revitalisation related to the socio-economic and environmental...
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Adaptive Expectation Maximization Smoothing (AEMS) inverse technique forindirect fish target strenght estimation. W: [CD-ROM] Full Papers. 6th ICES Symposium on Acoustics in Fisheries and Aquatic Ecology. Montpellier, 10-14 June 2002. [Montpellier: Ifremer]**2002, [6 s.] 5 rys. bibliogr. 5 poz. Zastosowanie adaptacyjnej metody EMS do pośredniej estymacji siły celu ryb.
PublicationW pracy przedstawiono modyfikację statystycznej metody EMS (ang. Expecta-tion, Maximization, Smoothing) stosowanej w zagadnienia odwrotnych, polega-jącą na iteracyjnym rozwiązaniu równania Fredholma. Pokazano jej zastosowa-nie do pośredniej estymacji siły celu ryb stosowanej dla danych pozyskanychprzez hydroakustyczne systemy jednowiązkowe wykorzystywane w przeszukiwa-niach akustycznych. Wyniki porównano z rezultatami uzyskanymi...
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BET adsorption-desorption isotherm of nano-CeO2
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The catalyts powder composed of nanoCeO2 (AlfaAesar)
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Stereoscopy in Graphics APIs for CAVE Applications
PublicationThe paper compares the advantages and disadvantages of a variety of Graphics Application Programming Interfaces (APIs) from the perspective of obtaining stereoscopy in applications written for a CAVE virtual reality environment. A number of problems have been diagnosed and an attempt has been made to solve them using OpenGL, DirectX 11 and 12, Vulkan, as well as the Unity Engine which can internally use DirectX, OpenGL and Vulkan,...
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Prediction of protein assemblies, the next frontier: The CASP14‐CAPRI experiment
PublicationWe present the results for CAPRI Round 50, the 4th joint CASP-CAPRI protein assembly prediction challenge. The Round comprised a total of 12 targets, including 6 dimers, 3 trimers, and 3 higher-order oligomers. Four of these were easy targets, for which good structural templates were available either for the full assembly, or for the main interfaces (of the higher-order oligomers). Eight were difficult targets for which only distantly...
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Joanna Rymaszewska prof. dr hab. n. med.
PeopleCV Joanna Rymaszewska Wroclaw University of Science and Technology, Wroclaw, Poland +48 601 98 26 24, joanna.rymaszewska@pwr.edu.pl orcid.org/0000-0001-8985-3592 2023 → Professor of Wroclaw University of Science and Technology (WUST), Poland 2011 → 2023 Professor of Wroclaw Medical University (WMU), PL 2016 → 2022 Head of the Department of Psychiatry, Wroclaw Medical University 2016 → 2022 Head of the Clinic of Psychiatry,...