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wszystkich: 304
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Wyniki wyszukiwania dla: TI DIMPLED TEMPLATES
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Ti-doped Sr2Fe1.4-xTixMo0.6O6-δ double perovskites with improved stability as anode materials for Solid Oxide Fuel Cells
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Evaluation of the relative thermoluminescence efficiency of LiF:Mg,Ti and LiF:Mg,Cu,P TL detectors to low-energy heavy ions
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Synthesis, Characterization, and Catalytic Applications of the Ti-SBA-16 Porous Material in the Selective and Green Isomerizations of Limonene and S-Carvone
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Correlation between structural and electrical properties in highly porous (Y,Sr)(Ti,Nb)O3-delta SOFC anodes
PublikacjaIn order to find a relationship between structural and electrical properties, niobium and yttrium doped SrTiO3 ceramics were prepared via solid-state reaction. The samples were sintered in hydrogen and air conditions. The samples were also fabricated with a pore-former to obtain highly porous specimens. The electrical properties of Nb-doped SrTiO3 samples and yttrium and niobium co-doped SrTiO3 were compared. The comparable electrical...
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Kα1,2x-ray linewidths, asymmetry indices, and[KM]shake probabilities in elements Ca to Ge and comparison with theory for Ca, Ti, and Ge
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Insightful Analysis of Phenomena Arising at the Metal|Polymer Interphase of Au-Ti Based Non-Enzymatic Glucose Sensitive Electrodes Covered by Nafion
PublikacjaThis paper focuses on the examination of glucose oxidation processes at an electrode material composed of gold nanoparticles embedded in a titanium template. Three dierent conditions were investigated: the chloride content in the electrolyte, its ionic conductivity and the presence of a Nafion coating. The impact of the provided environment on the oxidation reaction was evaluated by cyclic voltammetry (CV) and electrochemical impedance...
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Synthesis and structural properties of (Y, Sr)(Ti, Fe, Nb)O3−δ perovskite nanoparticles fabricated by modified polymer precursor method
PublikacjaThe yttrium, iron and niobium doped-SrTiO3 powders have been successfully fabricated by a modified low–temperature synthesis method from a polymer complex. The usage of strontium hydroxide precursor instead of conventional strontium nitrate or strontium carbonate provides to the possibility of significant decrease of annealing temperature. It allows to prepare a material with sphere-shape grains of nanometric size (15–70 nm). The...
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The conversion of multinuclear μ-oxo titanium(IV) species in the reaction of Ti(OiBu)4 with branched organic acids; results of structural and spectroscopic studies
PublikacjaW reakcji tetraizobutoksylanu tytanu z rozgałęzionymi kwasami karboksylowymi otrzymano szereg wielordzeniowych związków kompleksowych tytanu(IV). Otrzymane produkty scharakteryzowano wykorzystując techniki spektroskopowe: FTIR, 1H i 13C NMR oraz rentgenowską analizę strukturalną. Zaproponowano ścieżki reakcji prowadzące do konwersji poszczególnych związków w coraz stabilniejsze formy.
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Electrostatic self-assembly approach in the deposition of bio-functional chitosan-based layers enriched with caffeic acid on Ti-6Al-7Nb alloys by alternate immersion
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Modyfikacja struktury i właściwości warstwy wierzchniej stopu tytanu Ti-6Al-4V otrzymywanej metod,a nadtapiania laserowego w warunkach ultraszybkiej krystalizacji
PublikacjaPokazano wyniki badań wpływu nadtapiania laserowego przy zastosowaniu różnej mocy lasera na grubość i mikrostrukturę warstwy wierzchniej oraz zużycie tribokorozyjne w roztworze Ringera. Wykazano, że nadtapianie, choć powoduje powierzchniowe spękanie, prowadzi do znacznego wzrostu odporności na zużycie tribokorozyjne. Przyczyną jest znaczny wzrost twardości materiału przy równoczesnym zacieraniu pęknięć.
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Alpha-pinene isomerization over Ti-SBA-15 catalysts obtained by the direct method: The influence of titanium content, temperature, catalyst amount and reaction time
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
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Impedance Evaluation of the Effect of Ru[sub 0.3]Ti[sub 0.7]O[sub 2] on Electrochemical Properties of Polymeric Conducting Electrodes Used in Cathodic Protection
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Absorbciâ vodoroda i povedenie vodoroda v slaâh titanovyh silavov s modificirovannoj poverhnost''û = Hydrogen absorption and hydrogen effects in the modified surface layers of Ti alloys
PublikacjaW pracy przedstawiono rezultaty badań absorpcji wodoru w stopach tytanu ze zmodyfikowaną za pomocą metod multipleksowych powierzchnią. W wyniku badań stwierdzono, iż po nadtapianiu laserowym w warunkach kriogenicznych, stopy tytanu wykazuja najwyższą zdolność absorpcji wodoru w wytworzonej warstwie wierzchniej.
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The influence of synthesis method on the microstructure and catalytic performance of Y 0.07 Sr 0.93 Ti 0.8 Fe 0.2 O 3-δ in synthetic biogas operated solid oxide fuel cells
PublikacjaThe Y0.07Sr0.93Ti0.8Fe0.2O3-δ (YSTF) material was fabricated using three different synthesis methods: modified polymer precursor method (MPP), Pechini method and a solid state reaction method. It was applied as an anode catalytic material for biogas reforming in solid oxide fuel cells. Clear differences in the microstructure of fabricated catalytic layers were found, mainly with respect to a grain size and distribution of grains....
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Effect of the Cooling Time in Annealing at 350°C on the Phase Transformation Temperatures of a Ni<sub>5</sub><sub>5</sub>Ti<sub>4</sub><sub>5</sub> wt. Alloy
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Shape-Based Pose Estimation of Robotic Surgical Instruments
PublikacjaWe describe a detector of robotic instrument parts in image-guided surgery. The detector consists of a huge ensemble of scale-variant and pose-dedicated, rigid appearance templates. The templates, which are equipped with pose-related keypoints and segmentation masks, allow for explicit pose estimation and segmentation of multiple end-effectors as well as fine-grained non-maximum suppression. We train the templates by grouping examples...
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The Influence of Microstructure on the Passive Layer Chemistry and Corrosion Resistance for Some Titanium-Based Alloys
PublikacjaThe effect of microstructure and chemistry on the kinetics of passive layer growth and passivity breakdown of some Ti-based alloys, namely Ti-6Al-4V, Ti-6Al-7Nb and TC21 alloys, was studied. The rate of pitting corrosion was evaluated using cyclic polarization measurements. Chronoamperometry was applied to assess the passive layer growth kinetics and breakdown. Microstructure influence on the uniform corrosion rate of these alloys...
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Localization of impulsive disturbances in archive audio signals using predictive matched filtering
PublikacjaThe problem of elimination of impulsive disturbances from archive audio signals is considered and its new solution, called predictive matched filtering, is proposed. The new approach is based on the observation that a large percentage of noise pulses corrupting archive audio recordings have highly repetitive shapes that match several typical “patterns”, called click templates. To localize noise pulses, click templates can be correlated...
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Wytwarzanie i modyfikacja powierzchni porowatych struktur tytanowych przeznaczonych na implanty
PublikacjaCelem pracy było wytworzenie stopu Ti-13Nb-13Zr z wykorzystaniem technologii selektywnego topienia laserowego (SLM) oraz jego biofunkcjonalizacja za pomocą utleniania mikrołukowego (MAO), a następnie określenie wpływu parametrów procesowych na właściwości otrzymanych materiałów pod kątem ich zastosowania na implanty. Oceniono wpływ napięcia, natężenia i czasu procesu MAO przeprowadzanego w elektrolicie zawierającym wapń i fosfor...
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Localization of impulsive disturbances in audio signals using template matching
PublikacjaIn this paper, a new solution to the problem of elimination of impulsive disturbances from audio signals, based on the matched filtering technique, is proposed. The new approach stems from the observation that a large proportion of noise pulses corrupting audio recordings have highly repetitive shapes that match several typical “patterns”. In many cases a representative set of exemplary pulse waveforms can be extracted from the...
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Microstructure and electrical properties of SrTi0.98Nb0.02O3-δ-based composites applied as porous layers for SOFCs
PublikacjaPrzebadano właściwości elektryczne oraz strukturalne kompozytów Sr(Ti,Nb)O3-YSZ i Sr(Ti,Nb)O3-CeO2 naniesionych w postaci warstw porowatych na podłoża YSZ
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Methodology of Constructing and Analyzing the Hierarchical Contextually-Oriented Corpora
PublikacjaMethodology of Constructing and Analyzing the Hierarchical structure of the Contextually-Oriented Corpora was developed. The methodology contains the following steps: Contextual Component of the Corpora’s Structure Building; Text Analysis of the Contextually-Oriented Hierarchical Corpus. Main contribution of this study is the following: hierarchical structure of the Corpus provides advanced possibilities for identification of the...
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Structural and Transportation Properties of Strontium Titanate Composites with Ion Conductive Oxides
PublikacjaThis paper has been written based on the author’s doctoral dissertation “Structural and transportation properties of strontium and titanate composites with ion conductive oxides”, prepared under the supervision of Prof. Dr. Hab. Eng. Bogusław Kusz at the Department of Solid State Physics of Gdańsk University of Technology. It reports the idea of the thesis and conclusions from the study. Niobium doped strontium titanate (Sr(Ti,Nb)O3)...
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Preparation of the porous biomaterial based on titanium alloy for orthopaedic implants
PublikacjaObecnie tytan i jego stopy (Ti-6Al-4V lub Ti-13Nb-13Zr) są szeroko stosowane jako biomateriały dla implantów ortopedycznych. Stale prowadzone są badania nad ich najlepszą odpornością na korozję i zużycie ścierne oraz biozgodnością i bioaktywnością. Obecne badania również skoncentrowane są na projektowaniu, wytwarzaniu i właściwościach materiałów porowatych na podstawie na przykład stopu tytanu (Ti-13Nb-13Zr), które mogą być stosowane...
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Cyclic Behavior of Masonry Shear Walls Retrofitted with Engineered Cementitious Composite and Pseudoelastic Shape Memory Alloy
PublikacjaThe behavior of masonry shear walls reinforced with pseudoelastic Ni–Ti shape memory alloy (SMA) strips and engineered cementitious composite (ECC) sheets is the main focus of this paper. The walls were subjected to quasi-static cyclic in-plane loads and evaluated by using Abaqus. Eight cases of strengthening of masonry walls were investigated. Three masonry walls were strengthened with different thicknesses of ECC sheets using...
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Effect of nitrogen doping on TiOxNy thin film formation at reactive high-power pulsed magnetron sputtering
PublikacjaThe paper is focused on a study of formation of TiOxNy thin films prepared by pulsed magnetron sputtering of metallic Ti target. Oxygen and nitrogen were delivered into the discharge in the form of reactive gases O2 and N2. The films were deposited by high-power impulse magnetron sputtering working with discharge repetition frequency f = 250 Hz at low (p = 0.75 Pa) and high (p = 10 Pa) pressure. The substrates were on floating...
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Data Analysis in Bridge of Data
PublikacjaThe chapter presents the data analysis aspects of the Bridge of Data project. The software framework used, Jupyter, and its configuration are presented. The solution’s architecture, including the TRYTON supercomputer as the underlying infrastructure, is described. The use case templates provided by the Stat-reducer application are presented, including data analysis related to spatial points’ cloud-, audio- and wind-related research.
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Effect of synthesis method parameters on properties and photoelectrocatalytic activity under solar irradiation of TiO2 nanotubes decorated with CdS quantum dots
PublikacjaThe growing research interest on photoelectrocatalysis has encouraged the search for new materials with high activity and the development of methods for their synthesis. The successive ionic layer adsorption and reaction (SILAR) method is an effective way to synthesize materials with photoelectrocatalytic (PEC) properties that are active under visible radiation. Therefore, studies on the impact of the parameters of the SILAR method...
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Synthesis of compounds with C-P-P and C=P-P bond systems based on the phospha-Wittig reaction
PublikacjaA reactivity study of a β-diketiminate titanium(III) phosphanylphosphido complex [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}] (1) towards ketones such as benzophenone, 9-fluorenone, acetophenone, cyclopentanone, cyclohexanone and cycloheptanone is reported. The reactions of 1 with aromatic ketones (without α-protons) directly lead to the Ti(III) complex [MeNacNacTi(μ2-Cl)(OSiMe3)] (5) as well as Ti(IV) complexes with the pinacol condensation...
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Reasoning about trust in IT infrastructures
PublikacjaW artykule zaprezentowano metodę pozwalającą na ilościowe określenie poziomu zaufania do systemu TI.
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MOF/TiO2 erythrocyte-like heterostructures decorated by noble metals for use in hydrogen photogeneration and pollutant photodegradation
PublikacjaVarious metal–organic framework (MOF)/TiO2 heterostructures can be obtained by the partial hydrolysis or calcination of Ti-based MOFs. By adjusting the hydrolysis and calcination steps of NH2-MIL-125 (Ti), a novel photoactive material composed of a MOF (NH2-MIL-125 (Ti)) and TiO2, with a unique “erythrocyte” shape, was developed. Furthermore, modification of the composition prepared by the partial hydrolysis of NH2- MIL-125 (Ti)...
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Właściwości strukturalne i transportowe kompozytów tytanianu strontu z tlenkami przewodzącymi jonowo
PublikacjaW ramach pracy doktorskiej wytworzono i zbadano właściwości kompozytów tytanianu strontu domieszkowanego niobem (Sr(Ti,Nb)O3) z wybranymi tlenkami przewodzącymi jonowo (tlenek cyrkonu stabilizowany tlenkiem itru – YSZ, tlenek ceru - CeO2). Analizę dla różnych składów kompozytów prowadzono w szerokim zakresie temperatur i ciśnień parcjalnych tlenu. Właściwości strukturalne kompozytów zbadano metodami XRD, SEM, AFM i EDX, zaś właściwości...
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Meeting Requirements Imposed by Secure Software Development Standards and Still Remaining Agile
PublikacjaThe paper introduces the AgileSafe method of selecting agile practices for software development projects that are constrained by assurance requirements resulting from safety and/or security related standards. Such requirements are represented by argumentation templates which explain how the evidence collected during agile practices implementation will support the conformity with the requirements. Application of the method is demonstrated...
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Using Dempster-Shafer approach to support reasoning about trust in IT infrastructures
PublikacjaW artykule przedstawiono zastosowanie podejścia Dempstera-Shafera do do wnioskowania o poziomie zaufania do infrastruktur TI.
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Similarity Measures for Face Images: An Experimental Study
PublikacjaThis work describes experiments aimed at finding a straightforward but effective way of comparing face images.We discuss properties of the basic concepts, such as the Euclidean, cosine and correlation metrics, test the simplest version of elastic templates, and compare these solutions with distances based on texture descriptors (Local Ternary Patterns). The influence of selected image processing methods (e.g. bilateral ltering)...
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Porous biomaterial for orthopaedic implants based on titanium alloy
PublikacjaTytan i jego stopy są szeroko stosowane jako biomateriały dla zastosowań ortopedycznych. Badania związane z ich najlepszą odpornością na korozję i ścieranie, biozgodnością i bioaktywnością są stale prowadzone. Obecne badania koncentrują się również na projektowaniu i produkcji materiałów porowatych w oparciu o stopy np. Ti-13Nb-13Zr, które mogą być stosowane do wytwarzania implantów. Jedną z najbardziej efektywnych metod wytwarzania...
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Behavior Based Complete Coverage Task of Unknown Area by an Autonomous Mobile Robot SCORPION with Static Obstacles in Environment
PublikacjaIn the paper the behavior based control system of an autonomous mobile robot SCORPION is presented to execute the one of the most difficult navigation task, which is the complete coverage task of unknown area with static obstacles in the environment. The main principle assumed to design control system was that the robot should cover all area only once, if it possible, to optimize the length of path and energy consumption. All commercial...
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Variations in host surfaces morphology and biology of ciliate epibionts explaining distribution pattern of epibionts in the invasive signal crayfish Pacifastacus leniusculus (Dana, 1852)
Publikacjaciliates on the signal crayfish Pacifastacus leniusculus in relation to specialized structures of the host’s exoskeleton for the first time. This species is known to maintain a relatively clean carapace, but it is sometimes overgrown by other organisms. Epibionts cover different parts of the signal crayfish body, mainly antennae, antennules, maxillipedes III and pereiopods with inner edges of chelae; however, some parts of the...
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Degradation of metallic implants
PublikacjaPresence of metallic implants made of stainless steels, Co and Ti alloys is sometimes followed by some undesired allergic reactions and inflammatory processes and consequently the necessity of reimplantation.
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Biocompatibility and Bioactivity of Load-Bearing Metallic Implants
PublikacjaThe main objective of here presented research is to develop the titanium (Ti) alloy base composite materials possessing better biocompatibility, longer lifetime and bioactivity behaviour for load-bearing implants, e.g. hip joint and knee joint endoprosthesis. The development of such materials is performed through: modeling the material behaviour in biological environment in long time and developing of new procedures for such evaluation;...
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A Single-Carrier-Based Pulse-Width Modulation Template for Cascaded H-Bridge Multilevel Inverters
PublikacjaMultiplicity of the triangular carrier signals is a criterion for the extension of sinusoidal pulsewidth modulation, SPWM, to a number of output voltage levels per phase-leg in cascaded H-bridge (CHB) multilevel inverter (MLI). Considering medium and high voltage applications where appreciable number of output voltage levels from CHB MLI is needed, commensurate high number of carrier signals in either classical level- or phase-shifted...
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Odporność kawitacyjna laserowo kształtowanych struktur na stali 45
PublikacjaPrzedstawiono badania odporności kawitacyjnej różnych struktur otrzymanych na stali 45 po laserowym stopowaniu jej powierzchni proszkami Ni, Mn. Cr, Nb, Mo, Ti, Co.
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In Vitro Biological Characterization of Silver-Doped Anodic Oxide Coating on Titanium
PublikacjaDespite the high biocompatibility and clinical effectiveness of Ti-based implants, surface functionalization (with complex osteointegrative/antibacterial strategies) is still required. To enhance the dental implant surface and to provide additional osteoinductive and antibacterial properties, plasma electrolytic oxidation of a pure Ti was performed using a nitrilotriacetic acid (NTA)-based Ag nanoparticles (AgNP)-loaded calcium–phosphate...
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Influence of titanium layer on counter electrode on electrical parameters of DSSC
PublikacjaIn this paper the influence of the Ti layer thickness at counter-electrode on electrical parameters of DSSCs was examined. The transparent conductive oxide – less (TCO-less) counter electrodes (CE) with titanium layers and platinum as catalyst on Bk7 glass were prepared. Thin metallic films were deposited by means of magnetron sputtering (titanium) and Pulsed Laser Deposition (platinum). The counter electrode with Pt layer on Fluorine...
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Improving flexibility and performance of PVM applications by distributed partial evaluation
PublikacjaA new framework for developing both flexible and efficient PVM applications is described. We propose Architecture Templates Interface (ATI) that allows to control application granularity and parallelism. To ensure high application efficiency we extend partial evaluation strategy into domain of distributed applications obtaining Distributed Partial Evaluation (DPE). Both ATI and DPE were implemented using a new distributed programming...
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KOALA Graph Theory Internet Service
PublikacjaKOALA has been created with the idea of C++ library templates, implementing a broad set of procedures in the fields of algorithmic graph theory and network problems in discreate optimization. During the C2NIWA project, a library has been greatly ectended, the code refactored and enclosed with the internet service available in the public repository of thr project. Today it contains interconnected educational materials in the form...
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Badania tytanianu strontu - materiału anodowego dla ogniw paliwowych SOFC
PublikacjaW artykule opisano wyniki badan nad kompozytami Sr(Ti,Nb)O3-YSZ przygotowywane metoda mieszania proszkow w mozdzierzu agatowym. Scharakteryzowano ich wlasciwosci strukturalne, elektryczne i mechaniczne.
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Prediction of protein assemblies, the next frontier: The CASP14‐CAPRI experiment
PublikacjaWe present the results for CAPRI Round 50, the 4th joint CASP-CAPRI protein assembly prediction challenge. The Round comprised a total of 12 targets, including 6 dimers, 3 trimers, and 3 higher-order oligomers. Four of these were easy targets, for which good structural templates were available either for the full assembly, or for the main interfaces (of the higher-order oligomers). Eight were difficult targets for which only distantly...
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Coatings in arthroplasty [online]
PublikacjaThe modern coatings used in arthroplasty for long term implants are reviewed. The phosphate coatingsare the most popular technique to improve the bone-implant interfacial strength and promote theosseointegration. The plasma spraying, electrophoretic precipitation, powder metallurgy, ion beamsputtering, high velocity oxy-fuel (HVOF) combustion spraying, sol-gel technique, biomimeticdeposition are mostly used to obtain the phosphate,...
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Reactions of lithiated diphosphanes R2P-P(SiMe3)LiTHF (R = tBu, iPr) with [(PNP)TiCl2]. Two different coordination types of phosphanylphosphido ligand to the metal center.
Publikacja[(PNP)TiCl2] (PNP = N[2-PiPr2-4-methylphenyl]2) reacts with one equivalent of lithium derivative of diphosphane R2P-P(SiMe3)LinTHF (R = tBu, iPr) in toluene and forms the first complex with g1-coordination [(PNP)Ti(Cl){g1-P(SiMe3)-PtBu2}] (1) and complex with g2-coordination [(PNP)Ti(Cl){g2-P(SiMe3)-PiPr2}] (2) of phosphanylphosphido ligands to the titanium center. The similar reaction with two equivalents of tBu2P-P(SiMe3)LinTHF...
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Biocompatibility and bioactivity of load-bearing metallic implants
PublikacjaThe main objective of here presented research is to develop the titanium (Ti) alloy base composite materials possessing better biocompatibility, longer lifetime and bioactivity behaviour for load-bearing implants, e.g. hip joint and knee joint endoprosthesis. The development of such materials is performed through: modeling the material behaviour in biological environment in long time and developing of new procedures for such evaluation;...
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A simple modification to improve the accuracy of methylation-sensitive restriction enzyme quantitative polymerase chain reaction
PublikacjaDNA digestion with endonucleases sensitive to CpG methylation such as HpaII followed by polymerase chain reaction (PCR) quantitation is commonly used in molecular studies as a simple and inexpensive solution for assessment of region-specific DNA methylation. We observed that the results of such analyses were highly overestimated if mock-digested samples were applied as the reference.We determined DNA methylation levels in several...
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Context Search Algorithm for Lexical Knowledge Acquisition
PublikacjaA Context Search algorithm used for lexical knowledge acquisition is presented. Knowledge representation based on psycholinguistic theories of cognitive processes allows for implementation of a computational model of semantic memory in the form of semantic network. A knowledge acquisition using supervised dialog templates have been performed in a word game designed to guess the concept a human user is thinking about. The game,...
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Influence of Ultrasound on the Characteristics of CaP Coatings Generated Via the Micro-arc Oxidation Process in Relation to Biomedical Engineering
PublikacjaOver the past decade, bone tissue engineering has been at the core of attention because of an increasing number of implant surgeries. The purpose of this study was to obtain coatings on titanium (Ti) implants with improved properties in terms of biomedical applications and to investigate the effect of ultrasound (US) on these properties during the micro-arc oxidation (MAO) process. The influence of various process parameters, such...
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Semi-transparent ordered TiO2 nanostructures prepared by anodization of titanium thin films deposited onto the FTO substrate
PublikacjaIn a significant amount of cases, the highly ordered TiO2nanotube arrays grow through anodic oxidationof a titanium metal plate immersed in electrolyte containing fluoride ions. However, for some practicalapplications, e.g. solar cells or electrochromic windows, the semi-transparent TiO2formed directly onthe transparent, conductive substrate is very much desired. This work shows that high-quality Ti coatingcould be formed at room...
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Flow-induced stress corrosion failure of SS piping
PublikacjaPrzedstawiono uszkodzenie eksploatacyjne rurociągu ze stali austenitucznej typu 18Cr-10Ni-Ti w instalacji przepracowanych olejów napędowych w rafinerii ropy naftowej. Wyjaśniono mechanizm niszczenia środowiskowego stali w wyniku mechanicznego i elektrochemicznego działania strumieni procesowych.
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Solving Boundary Value Problems for Second Order Singularly Perturbed Delay Differential Equations by ε-Approximate Fixed-Point Method
PublikacjaIn this paper, the boundary value problem for second order singularly perturbed delay differential equation is reduced to a fixed-point problem v = Av with a properly chosen (generally nonlinear) operator A. The unknown fixed-point v is approximated by cubic spline vh defined by its values vi = vh(ti) at grid points ti, i = 0, 1, ... ,N. The necessary for construction the cubic spline and missing the first derivatives at the boundary...
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Laserowe stopowanie technicznego żelaza w celu zwiększenia jego odporności kawitacyjnej
Publikacjaprzedstawiono wyniki badań odporności kawitacyjnej technicznego żelaza po laserowym stopowaniu jego powierzchni proszkami Mn, Ti, Cr, Si. Obróbka laserowa spowodowała 6-krotny wzrost twardości i wzrost odporności na odkształcenia plastyczne spowodowane działaniem obciążeń kawitacyjnych.
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TensorHive: Management of Exclusive GPU Access for Distributed Machine Learning Workloads
PublikacjaTensorHive is a tool for organizing work of research and engineering teams that use servers with GPUs for machine learning workloads. In a comprehensive web interface, it supports reservation of GPUs for exclusive usage, hardware monitoring, as well as configuring, executing and queuing distributed computational jobs. Focusing on easy installation and simple configuration, the tool automatically detects the available computing...
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Some coatings of high cavitation resistance produced by CO2 laser beam. XIV International Symposium on Gas Flow, Chemical Lasers and High Power Lasers.
PublikacjaPrzedstawiono wyniki badań odporności kawitacyjnej stali 2H13, 45 i żelaza Armco po laserowym stopowaniu ich powierzchni różnymi kompozycjami proszków Co, Mo, Ni, Mn i Cr, Ti. Wykazano różne własności kawitacyjne otrzymanych warstw w zależności od otrzymanej mikrostruktury.
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Molecular Structures of the Phospha-Wittig Reaction Intermediate: Initial Step in the Synthesis of Compounds with a C═P–P Bond as Products in the Phospha-Wittig Reaction
PublikacjaThe phospha-Wittig reactivity ofβ-diketiminate titanium(III) complexes with phosphanylphosphido ligands was investigated. The reactions of [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}] and [MeNacNacTi(Cl){η2-P(SiMe3)-P(Ph)tBu}] with acetone conducted in toluene solution under mild conditions led to the phospha-Wittig intermediates [{(ArN=C(Me)CHC(Me)=NAr)(C(Me)2O}Ti(Cl){PtBu2-P(SiMe3)C(Me)2O}] (1) and [{(ArN=C(Me)CHC(Me)=NAr) (C-(Me)2O}Ti(Cl){P(Ph)tBu-P(SiMe3)C(Me)2O}]...
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Surgical tool tracking by on-line selection of structural correlation filters
PublikacjaIn visual tracking of surgical instruments, correlation filtering finds the best candidate with maximal correlation peak. However, most trackers only consider capturing target appearance but not target structure. In this paper we propose surgical instrument tracking approach that integrates prior knowledge related to rotation of both shaft and tool tips. To this end, we employ rigid parts mixtures model of an instrument. The rigidly...
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Randomly Functionalized Polyethylenes: In Quest of Avoiding Catalyst Deactivation
PublikacjaWell-defined randomly functionalized polyolefins produced by catalysis form an interesting class of polymers with great potential for various applications. One of the major challenges for the production of these materials forms the incompatibility of the commonly used electrophilic group 4 metal based catalysts and the desired nucleophilic, especially protic functionalities like hydroxyl and carboxylic acid groups. Although pacification...
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Oxidative Dimerisierung von Phosphanen und Hinweise auf das intermediare Auftreten des Phosphinophosphinidens tBu2P-P in Reaktionen von [(eta^5^-C5H5)2TiCl2] und [(eta^5^-C5H5)(eta^5^-C5Me5)TiCl2] mit tBu2P-P(SiMe3)Li und tBu2P-P(Li)-P-tBu2. Bildung von Titan(III)- Fulvalen-Komplexen.
PublikacjaReakcja dichlorku tytanocenu z tBu2P-P(Li)-P-tBu2 albo tBu2P-P(SiMe3)Li prowadzi do kompleksów Ti(III). Jednocześnie grupy fosfanowe dimeryzują dając (tBu2P)2P-P(P-tBu2)2 lub (tBu2P-PSiMe3)2. Znaleźliśmy produkty, które sugerują przejściowe występowanie tBu2P-P.
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Agent System for Managing Distributed Mobile Interactive Documents in Knowledge-Based Organizations
PublikacjaThe MIND architecture of distributed mobile interactive document is a new processing model defined to facilitate obtaining a proper solution in knowledge processes carried out by knowledge-based organizations. Such organizations have an established structure that defines document templates and knowledge process. The aim of the MIND architecture is to change the static document to mobile agents, which are designed to implement the...
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Synthesis of eosin modified TiO2 film with co-exposed {001} and {101} facets for photocatalytic degradation of para-aminobenzoic acid and solar H2 production
PublikacjaOwing to the increasing photosensitivity and DNA damage properties of para-aminobenzoic acid (PABA), concerns have been raised over the exposure of humans to PABA. Solar light-driven photocatalysis (SPC) provides a promising solution for the effective removal of organic pollutants especially when directed towards sulfate radical (SO4−) production. Herein, we have developed a sulfite-enhanced SPC using Eosin-Y sensitized TiO2/Ti...
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Materials Design for the Titanium Scaffold Based Implant
PublikacjaThe main objective of here presented research is a design the scaffold/porous titanium(Ti) alloy based composite material demonstrating better biocompatibility, longer lifetime andbioactivity behaviour for load-bearing implants. The development of such material is proposed bymaking a number of consecutive tasks. Modelling the mechanical, biomechanical and biologicalbehavior of porous titanium structure and an elaboration of results...
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Materials Design for the Titanium Scaffold Based Implant
PublikacjaThe main objective of here presented research is a design the scaffold/porous titanium(Ti) alloy based composite material demonstrating better biocompatibility, longer lifetime andbioactivity behaviour for load-bearing implants. The development of such material is proposed bymaking a number of consecutive tasks. Modelling the mechanical, biomechanical and biologicalbehavior of porous titanium structure and an elaboration of results...
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Synthesis and polymerisation techniques of molecularly imprinted polymers
PublikacjaMolecularly Imprinted Polymers (MIPs) are materials that has been processed using the molecular imprinting technique which permit to obtain well-defined three-dimensional cavities, with affinity to a template molecule, in the polymer matrix. Technology involves three strategies, i.e., covalent, non-covalent and semi-covalent approach, but the most popular is non-covalent approach. The most important components for the synthesis...
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Fusion of DNA-binding domain of Pyrococcus furiosus ligase with TaqStoffel DNA polymerase as a useful tool in PCR with difficult targets
PublikacjaThe DNA coding sequence of TaqStoffel polymer- ase was fused with the DNA-binding domain of Pyrococcus furiosus ligase. The resulting novel recombinant gene was cloned and expressed in E. coli. The recombinant enzyme was purified and its enzymatic features were studied. The fusion protein (PfuDBDlig-TaqS) was found to have enhanced processivity as a result of the conversion of the Taq DNA polymerase from a relatively low processive...
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Improvement of Task Management with Process Models in Small and Medium Software Companies
PublikacjaSmall and medium software companies exhibit many special features that give reason for a dedicated approach to process improvement. They often cannot afford implementing maturity models or quality standards both in terms of time and money. Instead, they expect simpler solutions that can allow to run projects in more systematic and repeatable way, increase quality and knowledge management. In this paper, we present a method focused...
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Annealing Rate as a Crucial Parameter Controlling the Photoelectrochemical Properties of AuCu Mosaic Core–Shell Nanoparticles
PublikacjaThermal processing is an essential step during the synthesis of various metal nanostructures and for tailoring their morphology, optical, and electrochemical properties. Herein, a profound impact of the annealing rate and time on photoactivity of gold–copper nanostructures by changes in the position and alignment of energy levels and surface states is reported. AuCu nanoparticles (NPs) are fabricated by sputtering of thin metal...
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Nanoporous TiO2 electrode grown by laser ablation of titanium in air at atmospheric pressure and room temperature
PublikacjaRecently, fabrication of the nanoporous TiO2 photoelectrode on metal foils by means of sputtering of the Ti film on preheatedmetal substrate followed by the TiO2 deposition (doctor blade technique) and sintering represents the frequently applied technique. This is despite the relatively complicated procedure and number of parameters to be controlled in order to fabricate films of required properties. In this work an approach is...
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Fuzzy reasoning system design and assessment of load-bearing endoprostheses and their fabrication processes
PublikacjaZaproponowano piec zastosowan podejscia rozumowania rozmytego do rozwiazania problemów w dziedzinie biomechanikioraz inzynierii biomateriałów. Obejmuja one: (A) oszacowanie maksymalnych naprezen kontaktowych działajacych naendoproteze, (B) zaprojektowanie procesu spiekania dla otrzymania porowatego implantu, (C) opracowanie planu utleniania wcelu otrzymania struktury nanorurkowej na stopach Ti, (D) oraz (E) zaprojektowanie osadzania...
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Cavitation erosion of some laser-produced iron-base corrosion-resistance alloys
PublikacjaW pracy przedstawiono badania kawitacyjne stali C45, X20Cr13 oraz X5CrNi18-10 po laserowym stopowaniu ich warstwy wierzchniej proszkami Mn, Cr, Ni, Si, Ti, Co, Al, Mo, B. Badania kawitacyjne prowadzono na stanowisku z wirującą tarczą. Zniszczenia powierzchni w okresie inkubacji oceniano metodą optyczną. Przedstawiono związek pomiędzy uzyskaną mikrostrukturą obrabianej warstwy i jej odpornością kawitacyjną.
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Donor-substituted SrTi1+xO3−δ anodes for SOFC
PublikacjaNonstoichiometric Nb-substituted SrTiO3 compounds were investigated in order to discuss the influence of nonstoichiometry at the sample properties in the light of recent results reported in the literature. Structural and electrical properties of samples were characterized. Investigated compounds were also applied as anodes for Solid Oxide Fuel Cells and their reactivity with YSZ electrolyte was examined. The defect chemistry explaining...
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Simulating Malware with MAlSim
PublikacjaThis paper describes MAlSim - Mobile Agent Malware Simulator - a mobile agent framework developed to address one of the most important problems related to the simulation of attacks against information systems i.e. the lack of adequate tools for reproducing behaviour of malicious software (malware). The framework can be deployed over the network of an arbitrary information system and it aims at simulating behaviour of each instance...
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Simulating malware with MAlSim
PublikacjaThis paper describes MAlSim - Mobile Agent Malware Simulator - a mobile agent framework developed to address one of the most important problems related to the simulation of attacks against information systems, i.e. the lack of adequate tools for reproducing behaviour of malicious software (malware). The framework can be deployed over the network of an arbitrary information system and it aims at simulating behaviour of each instance...
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Wpływ struktury siluminu na skrawalność = Effect of silumin structure on machinability
PublikacjaBadano odlewy ciśnieniowe ze siluminu EN AC-AlSi7Cu2 pochodzące z dwóch partii różniące się skrawalnością, w zakresie składu chemicznego, mikrostruktury na mikroskopie świetlnym i skaningowym z EDS oraz składu fazowego na dyfraktometrze rentgenowskim. Stop o niższej skrawalności posiadał mniejszą dyspersję eutektyki, większe stężenie tytanu w roztworze aluminium, wydzielenia fazy międzymetalicznej Al i Ti oraz większe skupiska...
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Texture or Linker? Competitive Patterning of Receptor Assembly toward Ultra-Sensitive Impedimetric Detection of Viral Species at Gold-Nanotextured Titanium Surfaces
PublikacjaIn this work, we study the electrodes with a periodic matrix of gold particles pattered by titanium dimples and modified by 3-mercaptopropionic acid (MPA) followed by CD147 receptor grafting for specific impedimetric detection of SARS-CoV-2 viral spike proteins. The synergistic DFT and MM/MD modeling revealed that MPA adsorption geometries on the Au–Ti surface have preferential and stronger binding patterns through the carboxyl...
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Mrówczan sodu z nowym pakietem inhibitorów korozji jako ekologiczny środek do odladzania infrastruktury lotniczej.
PublikacjaPrzedstawiono wyniki badań korozji kadmowej powłoki na stali oraz korozji po zanurzeniu stopów metali w mrówczanie sodu z nowym pakietem inhibitorów korozji, zawierającym synergiczną kompozycję poliasparaginianu sodu oraz imidazolu. Ponadto wyznaczono zdolność penetracji lodu przez badany układ. Właściwo- ści opracowanej kompozycji odladzającej porównano z właściwościami środków dostępnych na rynku. Uzyskane wyniki wskazują, że otrzymany...
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Degradation of cefadroxil drug by newly designed solar light responsive alcoholic template-based lanthanum ferrite nanoparticles
PublikacjaIn this work, lanthanum ferrite nanoparticles were synthesized via a simple co-precipitation method. Two different templates, namely sorbitol and mannitol, were used in this synthesis to tune the optical, structural, morphological, and photocatalytic properties of lanthanum ferrite. The synthesized lanthanum ferrite-sorbitol (LFOCo-So) and lanthanum ferrite-mannitol (LFOCo-Mo) were investigated through Ultraviolet–Visible (UV–Vis),...
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Reactions of solute species at an electrode modified with titanocene functionalized polypyrrole film: ferrocene and titanocene dichloride
PublikacjaPo raz pierwszy zbadano możliwość intermediacji ładunku poprzez centra tytanocenowe polimeru modyfikowanego chemicznie związanymi grupami dichloro tytanocenowymido polipirolu. Badano reakcje elektrodowe ferrocenu i dichlorotytanocenu. Wykazano aktywność elektrodową w zakresie potencjałów redoks pary Ti(IV/TiIII)w stosunku do reakcji redoks ferrocenu i reakcji dichlorotytanocenu. Wykazano, że centra TcCl2 polimeru są zadowalająco...
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Interactions between components of SrTi0.98 Nb0.02O3-δ-YSZ and SrTi0.98 Nb0.02O3-δ -CeO2 composites
PublikacjaComposites consisting of SrTiO3-based perovskite and either yttria-stabilized zirconia or ceria were investigated. The mechanical compatibility and possible inter-diffusion between phases were characterized by scanning electron microscopy, X-ray diffraction, and energy-dispersive X-ray spectroscopy. A gradual disappearance of Ce-containing phases with an increase in the temperature of reduction in hydrogen was noticed. Moreover,...
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Environmental degradation of titanium alloy in artificial saliva
PublikacjaThe titanium and its alloys are potentially prone to hydrogen embrittlement, including those proposed for dental implants. The research has been aimed to assess a susceptibility to environment-enhanced degradation of the Ti-13Zr-13Nb alloy in artificial saliva with or without hydrofluoric acid, subject or not to cathodic polarisation. The results have shown that even if artificial saliva is safe environment, both cathodic polarization...
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Optimization of carbamazepine photodegradation on defective TiO2-based magnetic photocatalyst
PublikacjaIn this work, carbamazepine (CBZ) degradation over defective Fe3O4@SiO2/d-TiO2/Pt photocatalyst was studied. Within the titania structure, Ti vacancies and Pt nanoparticles were introduced to enhance the photocatalyst’s light absorption and influence charge carriers’ mobility. For the carbamazepine degradation, process parameters, e.g., temperature, flux intensity, photocatalyst loading, aeration, pH, and addition of H2O2, were optimized...
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Raman studies of ferroelectric ceramics.
PublikacjaPrzedstawiono potencjał aplikacyjny spektroskopii Ramana w diagnostyce procesu technologicznego wytwarzania cienkowarstwowych struktur perowskitowych o strukturze Ba(Ti1 xZrx)O3, posiadających możliwość strojenia przenikalności elektrycznej za pomocą pola elektrycznego. Skonfigurowano systemy pomiarowe do badania zarówno próbek objętościowych, jak i struktur cienkowarstwowych. Zidentyfikowano najistotniejsze linie w widmach ramanowskich,...
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Influence of laser remelting at cryogenic conditions on corrosion resistance of non-ferrous alloys
PublikacjaCelem nadtapiania laserowego elementów wytwarzanych z stopów aluminium, miedzi i tytanu jest uzyskanie wysokiej twadrości i odporności na korozję dla wydłużenia okresu ich eksploatacji w rezultacie ich szybkiej krystalizacji. Końcowa mikrostruktura, skład fazowy i właściwości wymienionych stopów zależą od parametrów obróbki laserowej oraz budowy wykresów równowagi fazowej. W artykule przedstawiono wpływ laserowego nadtapiania...
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Electrochemically Obtained TiO2/CuxOy Nanotube Arrays Presenting a Photocatalytic Response in Processes of Pollutants Degradation and Bacteria Inactivation in Aqueous Phase
PublikacjaTiO2/CuxOy nanotube (NT) arrays were synthesized using the anodization method in the presence of ethylene glycol and different parameters applied. The presence, morphology, and chemical character of the obtained structures was characterized using a variety of methods—SEM (scanning electron microscopy), XPS (X-ray photoelectron spectroscopy), XRD (X-ray crystallography), PL (photoluminescence), and EDX (energy-dispersive X-ray spectroscopy)....
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Enhanced capacitance of composite TiO2 nanotube / boron-doped diamond electrodes studied by impedance spectroscopy
PublikacjaWe report on the novel composite nanostructures based on boron-doped diamond thin film grown on top of TiO2 nanotubes. The nanostructures made of BDD-modified titania nanotubes showed an increase in activity and performance when used as electrodes in electrochemical environments. The BDD thin films (~200-500 nm) were deposited using microwave plasma assisted chemical vapor deposition (MW PA CVD) onto anodically fabricated TiO2...
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Deposition of phosphate coatings on titanium within scaffold structure
PublikacjaPurpose: Existing knowledge about the appearance, thickness, and chemical composition of phosphate coatings on titanium inside porous structures is insufficient. Such knowledge is important for the design and fabrication of porous implants. Methods: Metallic scaffolds were fabricated by selective laser melting of 316L stainless steel powder. Phosphate coatings were deposited on Ti sensors placed either outside the scaffolds or...
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Characterization of the c-BN/TiC, Ti3SiC2 systems by element selectivespectroscopy.
PublikacjaPomimo dużego technologicznego zainteresowania tytanowymi kompozytami bazującymi na c-BN daje się zauważyć wyraźny brak danych dotyczących lokalnego otoczenia atomów Ti w tego typu materiałach. Główna przyczyna tego stanu rzeczy tkwi w trudności związanej z analizą układu wielofazowego o dużej twardości za pomocą konwencjonalnych metod. Praca poświęcona jest analizie składu i struktury tytanowych kompozytów za pomocą atomowo-selektywnych...
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3D Printing of Metallic Implants
PublikacjaThe fabrication of various elements, solid and open porous structures of stainless steel and Ti alloy is described. The process was started with the design of 3D models in CAD/CAM system. The 3D models were transformed into *.stl files and then the manufacturing process of the real structures by means of the selective laser melting with the SLM Realizer 100 3D printer was made. The paper shows the porous specimens made for possible...
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Application of INAA and ETAAS techniques for human samples analysis in evaluation of the impact of Gdansk Phosphatic Fertilizer Plant on its workers
PublikacjaW pracy przedstawiono wyniki badań wpływu Gdańskich Zakładów Nawozów Fosforowych na zdrowie pracowników. Oznaczano stężenia (techniką INAA) Al, As,Au, Br, Ca, Cl, Cu, Dy, I, In, K, La, Mg, Mn, Mo, Na, S, Sb, Sm, Ti, U, V,W, Zn we włosach, paznokciach i filtrach z pyłem zebranych od 21 pracowników fabryki oraz 5 osób z grupy kontrolnej nie związanej z zakładem. Ponadto oznaczono Cd, Cr, Cu, Fe, Mo, Ni i Zn w moczu przy użyciu...
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Volatile Compound Emissions from Stereolithography Three-Dimensional Printed Cured Resin Models for Biomedical Applications
PublikacjaStereolithography three-dimensional printing is used increasingly in biomedical applications to create components for use in healthcare and therapy. The exposure of patients to volatile organic compounds (VOCs) emitted from cured resins represents an element of concern in such applications. Here, we investigate the biocompatibility in relation to inhalation exposure of volatile emissions of three different cured commercial resins...
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An assessment of teeth quality of the mini gang saw blade
PublikacjaIn this work, the assessment of the effect of the operating time (90 min.) of the mini gang saw blades during sawing Scotch pine (Pinus sylvestris L.) samples upon changes of the saw blade teeth sharpness (bluntness), which was defined as an effective radius of the nose ρ , has been described. The research activities have been carried out on the Nikon Ti-S optical microscope equipped with the Nikon DS-30W camera allowing high-speed...
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Thermally tuneable optical and electrochemical properties of Au-Cu nanomosaic formed over the host titanium dimples
PublikacjaAu-Cu nanostructures offer unique optical and catalytic properties unlike the monometallic ones resulting from the specific interaction. Among others, they have the ability to exhibit surface plasmon resonance, electrochemical activity towards the oxygen and hydrogen evolution reaction (OER, HER) as well as improved photoresponse in relation to monometalic but those properties depend highly on the substrate where bimetallic structures...
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Formation of Porous Structure of the Metallic Materials Used on Bone Implants
PublikacjaResearch on improvement of structure and fabrication methods of the bone implants are carried out for many years. Research are aimed to shape the structures, that will have a Young's modulus value similar to the value of the human bones Young's modulus. Depending on theporosity, Young's moduli can even be tailored to match the modulus of bone closer than solid metals can, thus reducing the problems associated with stress shielding...
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Fabrication and properties of electrode material composed of ordered titania nanotubes and pEDOT:PSS
PublikacjaWe report on the two-stage preparation method of electrode material composed of titania nanotubes and poly(3,4-ethylenedioxythiopene):poly(2-styrenesulphonate) conductive polymer (pEDOT:PSS). Initially, titania nanotube arrays were produced by the anodization process of Ti substrate. Next, the polymer was potentiostatically deposited onto the thermally annealed nanotube arrays from the electrolyte containing monomer and counter...