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Search results for: BIO-BASED POLYURETHANES · BIO-BASED POLYOLS · ENVIRONMENTALLY FRIENDLY MATERIALS · HYDROLYTIC STABILITY · THERMAL STABILITY
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Fully Isohexide-Based Polyesters: Synthesis, Characterization, and Structure-Properties Relations
PublicationHere we present a novel series of biobasedpolyesters solely based on renewable isohexide building blocks,synthesized via melt polymerization. The recently developedisoidide dicarboxylic acid (IIDCA) was polymerized with rigidrenewable diols such as isosorbide (IS), isomannide (IM),isoidide (II), and the novel 2,5-methylene-extended isoididedimethanol (IIDML). Both IIDCA and IIDML weredeveloped to increase the reactivity of the...
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Simplified saturation modelling in three-leg power transformer for the system stability analisys
PublicationThe paper presents a simplified method for modelling non-linearity of the magnetic circuit of the power transformer. The saturation effect is implemented by describing the self and mutual inductances as a function of the magnetic flux. The most important element of this function is the saturation coefficient which is calculated based on transient state during the unloaded transformer switch on. The transformer model is described...
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Implementation of Non-Probabilistic Methods for Stability Analysis of Nonlocal Beam with Structural Uncertainties
PublicationIn this study, a non-probabilistic approach based Navier’s Method (NM) and Galerkin Weighted Residual Method (GWRM) in term of double parametric form has been proposed to investigate the buckling behavior of Euler-Bernoulli nonlocal beam under the framework of the Eringen's nonlocal elasticity theory, considering the structural parameters as imprecise or uncertain. The uncertainties in Young’s modulus and diameter of the beam are...
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The effect of nanomaterials on thermal resistance of cement-based composites exposed to elevated temperature
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The characterization of collagen‑based scaffolds modified with phenolic acids for tissue engineering application
PublicationThe aim of the experiment was to study the morphology of collagen-based scaffolds modified by caffeic acid, ferulic acid, and gallic acid, their swelling, and degradation rate, as well as the biological properties of scaffolds, such as antioxidant activity, hemo- and cytocompatibility, histological observation, and antibacterial properties. Scaffolds based on collagen with phenolic acid showed higher swelling rate and enzymatic...
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Thermal ablation modeling via the bioheat equation and its numerical treatment
PublicationThe phenomenon of thermal ablation is described by Pennes’ bioheat equation. This model is based on Newton’s law of cooling. Many approximate methods have been considered because of the importance of this issue. We propose an implicit numerical scheme which has better stability properties than other approaches.
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Gelatin and gelatin/starch-based films modified with sorbitol for wound healing
PublicationGelatin-based films modified with sorbitol were produced from gelatin solution or gelatin/starch blends using a simple and low-cost solvent casting method, and subsequently, their physicochemical, mechanical, and biocompatibility properties were characterized. This work focused on developing and optimizing a biopolymeric blend to improve the pure biopolymers’ properties for potential biomedical applications such as wound dressing....
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Thermal Transitions in P3HT:PC60BM Films Based on Electrical Resistance Measurements
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Thermal performance of Si and GaAs based solar cells and modules.
PublicationPraca przedstawia aktualny stan wiedzy na temat wpływu temperatury na parametry pracy ogniw i modułów fotowoltaicznych z amorficznego krzemu i GaAs. Przedstawiono ogólna analizę rezultatów zastosowania modułów fotowoltaicznych w budownictwie ze szczególnym uwzględnieniem systemów hybrydowych, przekształcających energie słoneczną w prąd elektryczny i ciepło.
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A closer look at how the dispersive liquid–liquid microextraction method works. Investigation of the effect of solvent mixture composition on the quality and stability of the cloudy state
PublicationThe dispersive liquid–liquid microextraction (DLLME) is one of the most popular miniaturized extraction procedures. In this paper, the degree of dispersion and dispersion stability were studied with the aim to assess the correlations of these parameters with efficiency for the selected analytical application. The dependence between the degree of dispersion (cloudy state quality) and its stability obtained by various emulsification...
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Thermal Buckling Analysis of Circular Bilayer Graphene sheets Resting on an Elastic Matrix Based on Nonlocal Continuum Mechanics
PublicationIn this article, the thermal buckling behavior of orthotropic circular bilayer graphene sheets embedded in the Winkler–Pasternak elastic medium is scrutinized. Using the nonlocal elasticity theory, the bilayer graphene sheets are modeled as a nonlocal double–layered plate that contains small scale effects and van der Waals (vdW) interaction forces. The vdW interaction forces between the layers are simulated as a set of linear springs...
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Novel stationary phases based on asphaltenes for gas chromatography
PublicationWe present the results of investigations on the possibility of the application of the asphaltene fraction isolated from the oxidized residue from vacuum distillation of crude oil as a stationary phase for gas chromatography. The results of the investigation revealed that the asphaltene stationary phases can find use for the separation of a wide range of volatile organic compounds. The experimental values of Rohrschneider/McReynolds...
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Synergistic effect of carbon fibers and carbon nanotubes on improving thermal stability and flame retardancy of polypropylene: a combination of a physical network and chemical crosslinking
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The Use of Raman Spectroscopy to Monitor Changes in the Intensity of Ratio of Integral Unsaturated Bands in Bio-Greases
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High dimensional Bio medical images denoising using wavelet transform and modified bilateral filter
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Effect of bio-polyol molecular weight on the structure and properties of polyurethane-polyisocyanurate (PUR-PIR) foams
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Biopolyols obtained via microwave-assisted liquefaction of lignin: structure, rheological, physical and thermal properties
PublicationThe present study examined the application of polyols obtained via microwave-assisted liquefaction of lignin in the production of rigid polyurethane foam. Lignin was liquefed in crude glycerol and 1,4-butanediol at diferent temperatures (130–170 °C), without a catalyst and using various biomass concentrations (15 and 30 wt%). The physicochemical properties, process yield, and FTIR-based identifcation of the obtained polyols were...
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Stability Analysis of the Floating Offshore Wind Turbine Support Structure of Cell Spar Type During its Installation
PublicationThe article presents the results of selected works related to the wider subject of the research conducted at the Faculty of Ocean Engineering and Ship Technology of the Gdansk University of Technology, which concerns design and technology of construction, towing, and settlement on the seabed, or anchoring, of supporting structures for offshore wind farms. As a result of this research, several designs of this type of objects were...
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Reliability Analysis of Sea Cliff Slope Stability by Point Estimate Method
PublicationThe paper presents a reliability analysis of a sea cliff slope. The cliff, located in Jastrzębia Góra, is characterised by a complicated geological structure. Although currently stable, it is in fact close to the limit state. The objective of this paper is to present the point estimate method (PEM) of determining the mean value and standard deviation of the safety factor of the slope. Assuming its normal distribution, these statistical...
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Tuning of food wastes bioavailability as feedstock for bio-conversion processes by acoustic cavitation and SPC, SPS, or H2O2 as external oxidants
PublicationThe growing amount of food wastes makes them a suitable source for the generation of bioproducts through anaerobic digestion. Appropriate hydrolysis of the feedstock can enhance the efficiency of production of desired products. In this work, acoustic cavitation (AC) was employed as a pretreatment method to enhance hydrolysis stage by the modification of model (potato-based) food waste for increase in soluble chemical oxygen demand...
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One Year Evaluation of Material Properties Changes of Polylactide Parts in Various Hydrolytic Degradation Conditions
PublicationBiodegradable biocompatible materials are widely used in medical applications. Determining the possibility of using biodegradable materials depends on determining the changes in their parameters over time due to degradation. The current scientific research on biodegradable materials has presented results based on research methods characterized by the different geometry and cross-section size of the specimen, type of degradation...
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Non-linear static stability of bi-layer carbon nanosheets resting on an elastic matrix under various types of in-plane shearing loads in thermo-elasticity using nonlocal continuum
PublicationIn this research, the shear and thermal buckling of bi-layer rectangular orthotropic carbon nanosheets embedded on an elastic matrix using the nonlocal elasticity theory and non-linear strains of Von-Karman was studied. The bi-layer carbon sheets were modeled as a double-layered plate, and van der Waals forces between layers were considered. The governing equations and boundary conditions were obtained using the first order shear...
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Recurrent Neural Network Based Adaptive Variable-Order Fractional PID Controller for Small Modular Reactor Thermal Power Control
PublicationThis paper presents the synthesis of an adaptive PID type controller in which the variable-order fractional operators are used. Due to the implementation difficulties of fractional order operators, both with a fixed and variable order, on digital control platforms caused by the requirement of infinite memory resources, the fractional operators that are part of the discussed controller were approximated by recurrent neural networks...
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Thermal simulation of building performance with different loadbearing materials
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Recent Advances in Accelerated Multi-Objective Design of High-Frequency Structures using Knowledge-Based Constrained Modeling Approach
PublicationDesign automation, including reliable optimization of engineering systems, is of paramount importance for both academia and industry. This includes the design of high-frequency structures (antennas, microwave circuits, integrated photonic components), where the appropriate adjustment of geometry and material parameters is crucial to meet stringent performance requirements dictated by practical applications. Realistic design has...
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Green thermoplastic poly(ether-urethane)s – synthesis, chemical structure and selected properties investigation
PublicationThis work aimed to characterize the effect of the monomers chemical structure on the selected properties of the green thermoplastic poly(ether-urethane)s. During synthesis two types of polyether biopolyols, 4,4′-diphenylmethane diisocyanate and bio-based 1,3-propanediol were employed. Materials were synthesized with the use of two step method and two different prepolymers, which were mixed together in equimolar quantities. Obtained...
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Efficient, fast, simple, and eco-friendly methods for separation of toxic chromium(VI) ions based on ion exchangers and polymer materials impregnated with Cyphos IL 101, Cyphos IL 104, or D2EHPA
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Mechanical and physical assessment of epoxy, mineral, solvent-based, and water-soluble coating materials
PublicationThis paper assesses the behavior of mineral, epoxy (EP), solvent, and water-soluble coatings when exposed to salt and regular water for 28 days. Also, it evaluates the pull-off adhesion strength of the same coating materials applied to concrete slabs saturated with oil and water and dried with two different processes: air-dried for 28 days and air-dried for 14 days plus 14 days in the oven at 70 °C. Properties such as carbonation,...
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The structure of novel polyurethanes containing synthetic poly[(R,S)-3-hydroxybutyrate]
PublicationThe aim of this study was to estimate the structure of new polyurethanes with the potential to be used in medicine. Atactic poly[(R,S)-3-hydroxybutyrate], obtained via a ring-opening polymerization, and polycaprolactonediol or polyoxytetramethylenediol were used to built the soft segments. 4,4'-methylene dicyclohexyl diisocyanate and 1,4-butanediol were the components to form hard segments. Polyurethanes with low-molecular weight...
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Morphology and the physical and thermal properties of thermoplastic polyurethane reinforced with thermally reduced graphene oxide
PublicationIn this study, thermally reduced graphene oxide (TRG)-containing polyurethane nanocomposites were obtained by the extrusion method. The content of TRG incorporated into polyurethane elastomer systems equaled 0.5, 1.0, 2.0 and 3.0 wt%. The morphology, static and dynamic mechanical properties, and thermal stability of the modified materials were investigated. The application of TRG resulted in a visible increase in material stiffness...
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The Application of Phenolic Acids in The Obtainment of Packaging Materials Based on Polymers—A Review
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Stability of thin film diamond mirror for applications in interferometers under the short-time exposure on selected aggressive chemicals
PublicationIn presented study a thin boron-doped diamond film was proposed for application in the interferometry as a highly durable optical mirror. The unique properties of the diamond films, like high chemical stability and hardness, allow them to be used even in the chemically aggressive environment, where the commonly used silver mirrors can be susceptible to damage. The investigated nanodiamond layer was fabricated by uPE CVD method...
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Preparation and Characterization of Films Based on Disintegrated Bacterial Cellulose and Montmorillonite
PublicationThe food packaging materials from natural polymers including polysaccharides offer an ecologically important alternative to commonly used synthetic, non-biodegradable counterparts. The purpose of this work was to modify of bacterial cellulose (BC) leading to the improvement of its functional properties in terms of use as a food packaging material. Effects of disintegration of BC and addition of montmorillonite (MMT) on its water...
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A solvent selection guide based on chemometrics and multicriteria decision analysis
PublicationThe selection of suitable solvents is a crucially important subject in a wide range of chemical processes. This study presents a solvent selection guide where 151 solvents were assessed, including a significant number of recently reported bio-based solvents. The assessment procedure involves grouping of solvents according to their physicochemical parameters and ranking within clusters according to their toxicological and hazard...
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Modification of cellulosic filler with diisocyanates – volatile organic compounds emission assessment and stability of chemical structure over time
PublicationThis paper investigated the impact of type and content of diisocyanate on the structure of modified cellulose fillers. Four the most popular isocyanates were applied – isophorone, hexamethylene, toluene and methylene diphenyl diisocyanate – at loadings of 1–15 wt%. Chemical structure, and its short-term storage stability, were investigated for eight weeks. Moreover, the main volatile organic compounds detected during modification,...
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Quantitative determination of mechanical stability in the novel coronavirus spike protein
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Magnetically induced dynamical stability of a Fe monolayer on W(110)
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Real-Time stability monitoring for expansion of the UCTE synchronous area
PublicationW referacie przedstawiono zasady wykorzystania systemu WAMS dla potrzeb oceny zapasu stabilności lokalnej systemu elektroenergetycznego.
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On convergence and stability of a numerical scheme of Coupled Nonlinear Schrödinger Equations
PublicationRozważamy rozwiązania numeryczne układu sprężynowych równań nieliniowych Schrödingera. Udowodniliśmy stabilność i zbieżność. Testujemy za pomocą rozwiązań solitonowych.
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The work of Professor Andrzej Lasota on asymptotic stability and recent progress
PublicationPraca poświęcona jest wkładowi Profesora Andrzeja Lasoty w teorię asymptotycznej stabilności iteracji operatorów stochastycznych na przestrzeni ostatnich 36 lat. Podkreślono aplikacyjny charakter wyników, pokazując stosowne przykłady z modelowania rozwoju komórki, optymalizacji wierceń geologicznych i ewolucji modeli kwantowych.
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The stability of a damaged roll-on roll-off vessel with water on deck
PublicationPrzeprowadzono analizę stateczności statku ro-ro w stanie awaryjnym z wodą na pokładzie. Pokazano, że moment przechylający związany jest z wypiętrzeniem wody na pokładzie ponad poziom wody zaburtowej, pochodzącym od fali. Omówiono trzy metody wyznaczania kąta przechyłu, wywołanego wodą na pokładzie. Zidentyfikowano krytyczne wypiętrzenie wody, przy którym następuje utrata stateczności statku.
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Effect of Newly Created Water Reservoirs on Agricultural Landscape Stability
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N6-methyladenosine regulates the stability of RNA:DNA hybrids in human cells
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Ridging, strength, and stability in high-resolution sea ice models
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Wettability and Stability of Naproxen, Ibuprofen and/or Cyclosporine A/Silica Delivery Systems
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Rheological properties and stability of water in Canola oil ethyl esteremulsion.
PublicationWyznaczono krzywe płynięcia i podatność na rozdział dla emulsji fazy wodnej w estrze etylowym oleju Canola. Właściwości te stanowią o podatności tej emulsji jako symulanta ropy naftowej w badaniach terenowych rozlewów olejowych.
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Multimachine power system stability improvement using fuzzy control.
PublicationW celu poprawienia stabilności dynamicznej turbogeneratora i powiększenia tłumienia kołysań elektromechanicznych opracowano regulator napięcia wraz z stabilizatorem systemowym z wykorzystaniem teorię zbiorów rozmytych. Efektywność opracowanego rozmytego algorytmu oceniono w układzie wielomaszynowym.
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Pre-arrangement of solvability, complexity, stability and quality of GPC systems
PublicationPraca dotyczy podstawowych problemów strojenia algorytmów dyskretnoczasowego uogólnienia sterowania predykcyjnego (GPC). Optymalne sterowanie predykcyjne, w sensie pewnego kwadratowego funkcjonału kosztów, wyznacza się rozwiązując odpowiednie liniowe zadanie. W pracy podano warunki, przy których macierz tego zadania jest macierzą o pełnym kolumnowym rzędzie - co gwarantuje istnienie optymalnego sterownika. W następnej kolejności...
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Preliminary experimental research on stability of truss' joint with positive eccentricity
PublicationRecently, a very large interest in lightweight steel structures made from cold-formed sections has been noticeable. In the design practice, a large emphasis is put on rational shaping of both the thin-walled elements and constructions designed on them. The aim of this paper is to present the methodology for preparation of experimental research that model the behaviour of members in trusses made of cold-formed sections with positive...
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Group 11 complexes with a phosphanylphosphaalkene ligand: preparation and stability study
PublicationThe reactivities of two selected phosphanylphosphaalkenes, Ph2C=P-PtBu2 (1a) and (p-MeO-Ph)2C=P-PtBu2 (1b), toward CuCl, AgCl and (tht)AuCl (tht = tetrahydrothiophene) were investigated. As a result, new phosphanylphosphaalkene dimeric and monomeric complexes were formed (Cu and Ag dimeric and Au monomeric). All obtained products were air and moisture stable and light insensitive.