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Modifications at the C(5) position of pyrimidine nucleosides
PublicationThis review summarizes the state of knowledge on the chemical methods of C(5)-modifications of uridine and cytidine derivatives and may serve as a useful tool for synthetic chemists to choose an appropriate reaction protocol. The synthesis of 5-substituted uracil derivatives is gaining an increasing interest because of their possible applications in medicine and pharmacy. Modifications at the C(5) position of pyrimidine nucleosides...
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The influence of the type of halogen substituent and its position on the molecular conformation, intermolecular interactions and crystal packing for a series of 1-benzoyl-3-(halogenophenyl)thioureas
PublicationBy the reaction of benzoyl chloride, potassium isothiocyanate and the appropriate halogenoaniline, i.e. 2/3/4-(bromo/iodo)aniline, we have obtained five new 1-benzoyl-3-(halogenophenyl)thioureas, namely, 1-benzoyl-3-(2-bromophenyl)- thiourea and 1-benzoyl-3-(3-bromophenyl)thiourea, C14H11BrN2OS, and 1-benzoyl-3-(2-iodophenyl)thiourea, 1-benzoyl-3-(3-iodophenyl)thiourea and 1-benzoyl-3-(4-iodophenyl)thiourea, C14H11IN2OS. Structural...
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Wielopoziomowy przekształtnik trakcyjny SiC z izolacją od sieci 3kV DC realizowaną za pomocą transformatorów 30kHz do napędów EZT
PublicationW referacie przedstawiono wielopoziomowy izolowany kaskadowy przekształtnik DC-AC z tranzystorami SiC MOSFET 1,2kV, przeznaczony do napędów elektrycznych zespołów trakcyjnych (EZT). Zaproponowana konstrukcja przekształtnika, przeznaczonego do pracy przy zasilaniu z sieci trakcyjnej 3kV DC, spełnia założenia energoelektronicznego transformatora trakcyjnego (z ang. Power Electronic Traction Transformer). Budowa modułowa z niskonapięciowych...
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Effects of La Content on the Densification, Microstructure, and Conductivity of Doped La10−x Ge6 O26±δ Electrolytes
PublicationIn this study, the influence of La content on the characteristics of Nb-, Mo-, and W-doped LaxGe6O26±δ electrolytes was investigated through sintering study, X-ray diffraction, scanning electron microscopy, and conductivity measurement. The densification of LaxGe5.5Nb0.5O26±δ and LaxGe5.5W0.5O26±δ was retarded as the x reached 9.75, while that of LaxGe5.5Mo0.5O26±δ improved with increasing La content. The average grain size slightly...
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Initial Considerations
PublicationChemical processes have made use of a wide number of volatile organic solvents due to their efficiency in countless unit operations. The increasing knowledge on the environmental, health, and safety hazards associated to their use has significantly contributed to the search for greener alternatives. The primary purpose of this book is to provide an overview of alternative solvents with reduced issues that have successfully replaced...
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Stability of softly switched multiregional dynamic output controllers with a static antiwindup filter: A discrete-time case
PublicationThis paper addresses the problem of model-based global stability analysis of discrete-time Takagi–Sugeno multiregional dynamic output controllers with static antiwindup filters. The presented analyses are reduced to the problem of a feasibility study of the Linear Matrix Inequalities (LMIs), derived based on Lyapunov stability theory. Two sets of LMIs are considered candidate derived from the classical common quadratic Lyapunov...
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Recognition of hazardous acoustic events employing parallel processing on a supercomputing cluster . Rozpoznawanie niebezpiecznych zdarzeń dźwiękowych z wykorzystaniem równoległego przetwarzania na klastrze superkomputerowym
PublicationA method for automatic recognition of hazardous acoustic events operating on a super computing cluster is introduced. The methods employed for detecting and classifying the acoustic events are outlined. The evaluation of the recognition engine is provided: both on the training set and using real-life signals. The algorithms yield sufficient performance in practical conditions to be employed in security surveillance systems. The...
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Smart heating system for home extending utilization of renewable energy sources
PublicationIn the paper a modern approach to smart home heating is presented. Proposed solution utilizes at least two low-polluting energy source technologies. The main idea is to connect well known ecological energy sources in a way that they can support each other and minimize risks of failure when using single system or even both of them but managed in separate way. Considered energy technologies, used separatelly, have disadvan-tages,...
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Dissociation energies of protonated water clusters
PublicationRelative abundances of positively ionized water clusters formed in a low-pressure electrical discharge as function of reduced electric field were obtained by using drift cell and quadrupole mass spectrometer. It was noticed that some clusters say with n = 4 were more abundant than others, at comparable drift conditions. Dissociation energies have been derived from equilibrium conditions for relative clusters abundances. The Hartree-Fock...
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DME as alternative fuel for compression ignition engines – a review
PublicationThe ecological issues and the depletion of crude oil, has led the researchers to seeking for non-petroleum based alternative fuels, along with more advanced combustion technologies, and after-treatment systems. The use of clean alternative fuels is the one of the most perspective method that aiming at resolving of the said issues. One of the promising alternative fuels that can be used as a clean highefficiency compression ignition...
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Evaluation of working spaces' technical condition of marine diesel engine on the basis of operation research
PublicationThe paper presents the method of evaluation of the technical state of working spaces of a marine diesel engine at the reduced control susceptibility. The method foresees making diagnosis on the basis of the measurements of exhaust gas pressure in the channels connecting engine cylinders with turbocharger's turbine. In the beginning of the article the research objects are characterized i.e. ZVIEZDA main engine of M401 type and the...
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Weak localization competes with the quantum oscillations in a natural electronic superlattice: The case of Na1.5(PO2)4(WO3)20
PublicationWe report an investigation of the combined structural and electronic properties of the bronze Na1.5(PO2)4(WO3)20. Its low-dimensional structure and possible large reconstruction of the Fermi surface due to charge density wave instability make this bulk material a natural superlattice with a reduced number of carriers and Fermi energy. Signatures of multilayered two-dimensional (2D) electron weak localization are consequently reported,...
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Study of the Effect of Filling Thermoplastic Medical Polyurethane with PVA, PLA or Diatomite on the Relaxation Times Distributions of 1H NMR
PublicationIn this work, to characterize the mobility of diferent sections of the macromole‑ cules of polyurethane (PUR), polyvinyl alcohol (PVA), and polylactic acid (PLA), as well as the density of crosslinks of the polymer chains when using fllers, we used the distributions of spin–lattice and spin–spin relaxation times for the protons. It is shown that the rigidity of the thermoplastic polymers depends on the sizes of the granules of...
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Plasmon resonance in a TiO2-Au NPs structures
Open Research DataInvestigated structures were deposited on a pre cleaned Corning 1737 glass substrates, which provided flat optical transmission characteristics and high transmission coefficient in a visible light range. Plasmonic nanostructures were formed as a result of thermal annealing. For gold films with thickness of 2.8 nm depiction a table-top dc magnetron sputtering...
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Badania wpływu demulgacji i doboru optymalnego demulgatora na skład fazy gazowej i ciekłej ścieków pooksydacyjnych
PublicationOczyszczanie ścieków pooksydacyjnych, pochodzących z oksydacji pozostałości z destylacji próżniowej ropy naftowej i produkcji tzw. asfaltów utlenianych, szczególnie drogowych, a także przemysłowych, stanowi duży problem technologiczny i środowiskowy. Wynika to z obecności w ściekach różnych grup związków organicznych, w tym m.in. organicznych związków siarki, tlenu i azotu. Pewna ich część jest zaabsorbowana w wodzie i częściowo...
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Saccharides
PublicationSaccharides are widely distributed in nature as the major component of fruits and vegetables (primarily monosaccharides), milk and malt (mainly disaccharides), and grains (mostly polysaccharides). They are an important source of energy, structural material, as well as flavor and taste factors. Molecules of this class of compounds contain mainly carbon, hydrogen, and oxygen atoms; however, most natural saccha- rides do not have...
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Low Power Baseband Processor for M2M Reconfigurable Radio Test Platform
PublicationSoftware Defined Radio (SDR) is becoming more andmore frequently used technique for wireless communication. Itfacilitates as fast prototyping and is a versatile method fordeveloping new communication systems. SDR can be realizedbased on high computational capacity platform, where powerconsumption is no a primary concern like i.e. DVB or BTStransmitters. Another trend are low power systems, whereavailable power in reduced and more...
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The role of slowly biodegradable substrate in a full-scale biological nutrient removal activated sludge systems
PublicationThis paper contains futher results obtained at ''Wschod'' WWTP in Gdańsk under transient conditions (spring season) and comparation of similar experiments carried out at a recently upgraded ''Debogorze'' WWTP in Gdynia. The removal of colloidal and particulate fractions resulted in similar effects (reduced process rates) at both plants. For example, the initial denitrification rates (NUR1) were up to 30% lower during the ''conventional''...
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Optimizing control by robustly feasible model predictive control and application to drinking water distribution systems
PublicationThe paper considers optimizing Model Predictive Control (MPC) for nonlinear plants with output constraints under uncertainties. Although the MPC technology can handle the constraints in the model by solving constraint model based optimization task, satisfying the plant output constraints under the model uncertainty still remains a challenge. The paper proposes Robustly Feasible MPC (RFMPC), which achieves feasibility of the outputs...
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Synthesis and characterisation of starch cuprate
PublicationThe cupration of granular potato starch with ammonium tetrachlorocuprate(II) was performed by a 20 min lasting microwave-assisted process and by 40 min convectional heating. In both cases the degree of esterification (DE) did not exceed 0.0064. A higher dose of cuprate had a positive effect on DE, regardless of whether the microwave irradiation or the convectional heating was applied, and on the thermal stability of the starch...
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E-cohomological Conley index
PublicationIn this thesis we continue with developing the E-cohomological Conley index which was introduced by A.Abbondandolo. In particular, we generalize the index to non-gradient flows, we show that it an possesses additional multiplicative structure and we prove the continuation principle. Then, using continuation principle, we show how the computation of the E-cohomological Conley index can be reduced to the computation of the classical...
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Structure and thermoelectric properties of bismuth telluride—Carbon composites
PublicationCarbon nanotubes and amorphous carbon have been introduced into a bismuth telluride matrix (0.15 and 0.30 wt.% ratio) to investigate the influence of the carbon on the composite’s thermoelectric properties. Composites with well-dispersed additives have been obtained by sonication and ball-milling methodology. Carbon nanotubes and an amorphous carbon addition led to a decrease in electric conductivity from 1120 S/cm to 77 S/cm....
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Experimental tests and numerical simulations of full scale composite sandwich segment of a foot- and cycle- bridge
PublicationIn the paper experimental tests and numerical simulations of a full cross-section segment of ultimately designed foot-and cycle-bridge are presented. The experimental tests were conducted on element with length reduced to 3 m and unchanged (target) cross-section dimensions. The external skin of structure is GFRP laminate while internal core is PET foam. Several quasi-static tests were performed using hydraulic cylinder to generate...
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Calculation method for flow boiling and flow condensation of R134a and R1234yf in conventional and small diameter channels
PublicationThe paper presents the results of calculations performed using the authors’ model to predict the heat transfer coefficient during flow boiling for two refrigerants R134a and R1234yf. The experimental data from various past studies have been collected and the calculations have been conducted for the full range of quality variation and a wide range of mass velocity. The aim of the study was to test the sensitivity of the in-house...
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Modelling of Mechatronic Systems with Distributed Parameter Components
PublicationThe paper presents an uniform, port-based approach to modelling of both lumped and distributed parameter systems. Port-based model of distributed system has been defined by application of the bond graph methodology and the distributed transfer function method (DTFM). The proposed method of modelling enables to formulate input data for computer analysis by application of the DTFM. The computational package for the analysis of complex...
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Molecular Umbrellas Modulate the Selective Toxicity of Polyene Macrolide Antifungals
PublicationAntifungal polyene macrolide antibiotics Amphotericin B (AmB) and Nystatin (NYS) were conjugated through the ω-amino acid linkers with diwalled “molecular umbrellas” composed of spermidine-linked deoxycholic or cholic acids. The presence of “umbrella” substituents modulated biological properties of the antibiotics, especially their selective toxicity. Some of the AmB-umbrella conjugates demonstrated antifungal in vitro activity...
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EXPERIMENTAL VERIFICATION OF THE METHOD OF FLOW BOILING AND FLOW CONDENSATION HEAT TRANSFER PREDICTION FOR SELECTED FLUIDS
PublicationIn the paper presented are the results of calculations using authors own model to predict heat transfer coefficient during flow boiling of different refrigerants. The experimental data from various research studies from literature were collected. Calculations were conducted for a full range of quality variation and a wide range of mass velocity. The aim of the study was to test the sensitivity of the in- house developed model....
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Probabilistic estimation of diverse soil condition impact on vertical axis tank deformation
PublicationThe calculations of fuel tanks should take into account the geometric imperfections of the structure as well as the variability of the material parameters of the foundation. The deformation of the tank shell can have a significant impact on the limit state of the structure and its operating conditions. The paper presents a probabilistic analysis of a vertical-axis, floating-roof cylindrical shell of a tank with a capacity of 50000...
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Dynamic mechanical properties and flexing fatigue resistance of tire sidewall rubber as function of waste tire rubber reclaiming degree
PublicationA stepwise downsizing method of gel particles in reclaimed rubber to a micro-nano scale and its excellent dynamic performance in tire sidewall were introduced by this work. The results showed that the size of gel particles decreased from several micrometers to micro-nanometers with the increase of reclaiming degree, accompanied by reduced molecular weight and widened molecular weight distribution of sol fraction. The addition of...
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Effects of Basalt and Carbon Fillers on Fire Hazard, Thermal, and Mechanical Properties of EPDM Rubber Composites
PublicationDue to growing restrictions on the use of halogenated flame retardant compounds, there is great research interest in the development of fillers that do not emit toxic compounds during thermal decomposition. Polymeric composite materials with reduced flammability are increasingly in demand. Here, we demonstrate that unmodified graphene and carbon nanotubes as well as basalt fibers or flakes can act as effective flame retardants...
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Influence of Surface Laser Treatment on Mechanical Properties and Residual Stresses of Titanium and its Alloys
PublicationSurface modification of the titanium and its alloys used in implantology with a long-pulse laser can change the surface topography, but it also leads to changes in the stress sign and magnitude in the resulting subsurface layer. The presented research was aimed at evaluating the state of stress after laser remelting with the Nd:YAG laser of pre-etched titanium alloys Ti6Al4V and Ti13Nb13Zr and pure titanium. The obtained surface...
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Efficiency of linear and non-linear classifiers for gas identification from electrocatalytic gas sensor
PublicationElectrocatalytic gas sensors belong to the family of electrochemical solid state sensors. Their responses are acquired in the form of I-V plots as a result of application of cyclic voltammetry technique. In order to obtain information about the type of measured gas the multivariate data analysis and pattern classification techniques can be employed. However, there is a lack of information in literature about application of such...
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Designate CTOD Heat Affected Zone of butt weld, Report No: WOiO/II/76/2013
PublicationTypical (normative) testing of materials and/or welded joints do not answer on all questions about material or welded joint properties. In ship building and off-shore sectors, many strucures requires materials and joint with higher than typical fatigue resistance. Imact tests, which are carried out during welding technology qualification, gives answer about ductility, CTOD tests results about material or welded joint ability...
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Designate of CTOD for WM and HAZ, report no: WOiO/II/122/2014
PublicationTypical (normative) testing of materials and/or welded joints do not answer on all questions about material or welded joint properties. In ship building and off-shore sectors, many strucures requires materials and joint with higher than typical fatigue resistance. Imact tests, which are carried out during welding technology qualification, gives answer about ductility, CTOD tests results about material or welded joint ability to...
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Innovative management of IT projects with the use of the agent-based approach on the basis of intelligent agents
PublicationProject management is one of the major challenges for the modern economy. Dynamic changes in the structures of organizations which form the core of the economy imply changes in both management processes and structures. One element of these changes is a new approach to the manufacturing of modern and rapidly changing products (due to changing market requirements). As part of these changes, traditional organizational structures are...
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Designate CTOD of Weld Metal of butt weld, No WOiO/II/108/2013
PublicationTypical (normative) testing of materials and/or welded joints do not answer on all questions about material or welded joint properties. In ship building and off-shore sectors, many strucures requires materials and joint with higher than typical fatigue resistance. Imact tests, which are carried out during welding technology qualification, gives answer about ductility, CTOD tests results about material or welded joint ability...
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"Creating a numerical model of noise conditions based on the analysis of traffic volume changes in cities with low and medium structure.
PublicationThe subject of this research study is to analyze noise conditions of the selected area in the city of Gdańsk using data related to traffic volume changes during a day. This is because daily distribution of noise levels is much more helpful for noise control and reduction than traditional maps with Lden levels indicated. Calculations are made with the use of a numerical model developed at the Gdansk Univ. of Technology and implemented...
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"Creating a numerical model of noise conditions based on the analysis of traffic volume changes in cities with low and medium structure.
PublicationThe subject of this research study is to analyze noise conditions of the selected area in the city of Gdańsk using data related to traffic volume changes during a day. This is because daily distribution of noise levels is much more helpful for noise control and reduction than traditional maps with Lden levels indicated. Calculations are made with the use of a numerical model developed at the Gdansk Univ. of Technology and implemented...
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Rough Set Based Modeling and Visualization of the Acoustic Field Around the Human Head
PublicationThe presented research aims at modeling acoustical wave propagation phenomena by applying rough set theory in a novel manner. In a typical listening environment sound intensity is determined by numerous factors: a distance from a sound source, signal levels and frequencies, obstacles’ locations and sizes. Contrarily, a free-field is characterized by direct, unimpeded propagation of the acoustical waves. The proposed approach is...
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CTOD designation for WM and HAZ in butt joint made from S460 ML steel, Expertise No. WOiO/II/82/2015
PublicationTypical (normative) testing of materials and/or welded joints do not answer on all questions about material or welded joint properties. In ship building and off-shore sectors, many strucures requires materials and joint with higher than typical fatigue resistance. Imact tests, which are carried out during welding technology qualification, gives answer about ductility, CTOD tests results about material or welded joint ability to...
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Porównanie atrakcyjności zajęć chemicznych z wykorzystaniem doświadczeń chemicznych, eksperymentów w rzeczywistości rozszerzonej oraz multimediów dla uczniów gimnazjów
PublicationPrzeprowadzone badania wykazały, że istnieją statystycznie istotne różnice w ocenie atrakcyjności poszczególnych narzędzi. Możliwość eks- perymentowania (samodzielnego oraz przy zastosowaniu środowiska AR) przekładała się na odbiór takiej metody jako bardziej atrakcyjnej – w po- równaniu z zastosowaniem multimediów. I jak wskazują zebrane dane nie ma na to wpływu ani płeć, ani obszar pochodzenia ucznia. Proponowane badania pozwoliły...
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CPTU/DMT control of heavy tamping compaction of sands
PublicationHeavy tamping compaction method in cohesionless alluvial soil was evaluated with CPTU and DMT tests. Some examples of interpretation of soundings in pre-treated and compacted sands are given. The compaction work was performed in two stages. Compaction control was performed after each stage of tamping. Additional tests were performed two weeks after the compaction works completion to study the set-up effect. While typical increase...
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Green, simple analytical method for biogenic amines determination in fruit juice samples using salting-out assisted liquid-liquid microextraction and gas chromatography-mass spectrometry
PublicationSalting-out assisted liquid-liquid microextraction (SALLME) was integrated with the derivatization procedure to establish a one-step sample pre-treatment approach for rapid analysis of 14 biogenic amines (BAs) in fruit juices. The methodology consists of salting-out of analytes, derivatization with ethyl chloroformate (ECF), extraction with ethyl acetate (EtAc), and the analysis of the derivatized BAs using gas chromatography-mass...
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ColorNephroNet: Kidney tumor malignancy prediction using medical image colorization
PublicationRenal tumor malignancy classification is one of the crucial tasks in urology, being a primary factor included in the decision of whether to perform kidney removal surgery (nephrectomy) or not. Currently, tumor malignancy prediction is determined by the radiological diagnosis based on computed tomography (CT) images. However, it is estimated that up to 16% of nephrectomies could have been avoided because the tumor that had been...
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Entangled rendezvous: a possible application of Bell non-locality for mobile agents on networks
PublicationRendezvous is an old problem of assuring that two or more parties, initially separated, not knowing the position of each other, and not allowed to communicate, are striving to meet without pre-agreement on the meeting point. This problem has been extensively studied in classical computer science and has vivid importance to modern and future applications. Quantum non-locality, like Bell inequality violation, has shown that in many...
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Service-based Resilience via Shared Protection in Mission-critical Embedded Networks
PublicationMission-critical networks, which for example can be found in autonomous cars and avionics, are complex systems with a multitude of interconnected embedded nodes and various service demands. Their resilience against failures and attacks is a crucial property and has to be already considered in their design phase. In this paper, we introduce a novel approach for optimal joint service allocation and routing, leveraging virtualized...
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Gdańsk’s Cultural Heritage. The City Centre District and Municipal Historical Policy
PublicationThe current municipal historical policy of Gdańsk focuses on two major museum projects purported to be a unique embodiment of the city’s cultural heritage. Their underlying narrative, which is told from the European perspective, is based on two great events of the 20th century and seems to disregard the cultural heritage recorded in the urban structure of the city centre. However, it is precisely this urban structure that exerts...
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Shape Memory Alloy-Based Fluidically Reconfigurable Metasurfaced Beam Steering Antenna
PublicationA low-cost actuator-based fluidically programmable metasurface (FPMS) antenna is proposed to solve the slow tuning speed problem of the manually fluidic based reconfigurable antennas. The FPMS-based antenna is probe-fed and comprises a 4 × 4 square ring metasurface as a superstrate. Moreover, two shape memory alloy (SMA)-based electrically-controlled actuators are employed in the design for controlling the position of the 3D-printed...
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Cross sections for electron collision with pyridine [C5H5N] molecule
PublicationThe absolute grand -total cross section (TCS) for electron scattering from pyridine, C5H5N, molecules has been measured at impact energies from 0.6 to 300 eV in the linear electron-transmission experiment. The obtained TCS energy dependence appears to be typical for targets of high electric-dipole moment; the cross section generally decreases with rising energy, except for the 3–20 eV range, where a broad enhancement peaked near...
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A Microwave Sensor with Operating Band Selection to Detect Rotation and Proximity in the Rapid Prototyping Industry
PublicationThis paper presents a novel sensor for detecting and measuring angular rotation and proximity, intended for rapid prototyping machines. The sensor is based on a complementary split-ring resonator (CSRR) driven by a conductor-backed coplanar waveguide. The sensor has a planar topology, which makes it simple and cost-effective to produce and accurate in measuring both physical quantities. The sensor has two components, a rotor, and...