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Novel complexes possessing Hg–(Cl, Br, I)⋯O=C halogen bonding and unusual Hg₂S₂(Br/I)₄ kernel. The usefulness of τ₄′ structural parameter
PublicationOne mononuclear and two binuclear Hg(II) complexes have been synthesized and characterized by X-ray diffraction, ATR IR and Hirshfeld surface analysis. Single-crystal X-ray diffraction showed that binuclear compounds are centrosymmetric and isostructural. All complexes form bifurcated intermolecular N–H···O hydrogen bonds that contribute to a formation of the centrosymmetric dimers. In binuclear complexes, sulfur atoms of thiourea...
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Multifunctional Bandpass Filter/Displacement Sensor Component
PublicationThis paper presents the design and realization of a multifunctional bandpassfilter/displacement-sensor using an edge-coupled microstrip bandpass filter loaded by a pair of split ring resonators (SRRs). It is shown that while the structure acts as a bandpass filter at its operating frequency, the phase of the reflection coefficient from a movable loading resonator at the resonance frequency of the resonator can be used for displacement...
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Potential and Use of the Googlenet Ann for the Purposes of Inland Water Ships Classification
PublicationThis article presents an analysis of the possibilities of using the pre-degraded GoogLeNet artificial neural network to classify inland vessels. Inland water authorities monitor the intensity of the vessels via CCTV. Such classification seems to be an improvement in their statutory tasks. The automatic classification of the inland vessels from video recording is a one of the main objectives of the Automatic Ship Recognition and...
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Simplified approach to assess the dynamic response of a container ship subjected to bow slamming load
PublicationSimplified approach to assess the dynamic response of a container ship subjected to the bow slamming load, resulting in a transient vibratory response, typically called a 'whip-ping', is presented. The accurate numerical modelling is very complex and involves cou-pling of the hydrodynamic and structural solution at every time step, leading to huge com-putational and workload cost. Thus, the one-way coupling methodology is adopted,...
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System informacji przestrzennej do analizy, wizualizacji i zdalnego udostępniania danych o infrastrukturach krytycznych
PublicationOchrona ludności, jak i infrastruktur krytycznych państwa przed różnego rodzaju zagrożeniami w postaci ataków terrorystycznych, katastrof naturalnych, itp. wymaga w obecnej dobie podejmowania zdecydowanych i skutecznych działań. Powstajace zaawansowane narzędzia z dziedziny technologii informacyjnych i komunikacyjnych coraz skuteczniej pomagają przewidywać możliwość wystąpienia tych zagrożeń oraz wspomagać podejmowanie działań...
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A Comprehensive Analysis of Impedance of the Electrochemical Cell
PublicationA comprehensive impedance characteristics of two electrodes electrochemical cell has been pre sented. In this method a multisinusoidal current excitation signal is used. The change of potential of both the electrodes are all registered as a function of time. The proposed method gives the possibility of determining the impedance of both electrodes individually as well as the impedance of a twoelectrode system. Additional application...
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Real-Time Bleeding Detection in Gastrointestinal Tract Endoscopic Examinations Video
PublicationThe article presents a novel approach to medical video data analysis and recognition of bleedings. Emphasis has been put on adapting pre-existing algorithms dedicated to the detection of bleedings for real-time usage in a medical doctor’s office during an endoscopic examination. A real-time system for analyzing endoscopic videos has been designed according to the most significant requirements of medical doctors. The main goal of...
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Monte Carlo simulations of the fracture resistance of an asphalt pavement layer
PublicationThe purpose of the proposed numerical model is to analyze the cracking of the wearing course in a pavement overlay, assuming a pre-existing crack that passes through the binding layer and base. The computations employed the author's simulation-based Monte Carlo material model, which describes the failure process of a Semi-Circular Bend (SCB) specimen during standard laboratory testing of asphalt concrete. A key feature of this...
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The electrochemical determination of isatin at nanocrystalline boron-doped diamond electrodes: stress monitoring of animals
PublicationUltra-thin nanocrystalline boron-doped diamond electrodes (B:NCD) were used for the electrochemical determination of isatin in dog urine samples using cyclic voltammetry and square wave voltammetry in a phosphate buffer saline, pH = 7.2. No additional modification or pretreatment of the electrode surface was required in this approach, being of high importance for the facile detection procedure. The increase of the peak current...
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Application of passive sampling technique in monitoring research on quality of atmospheric air in the area of Tczew, Poland.
PublicationThis paper presents the results of atmospheric air quality research in Tczew (adjacent to the Vistula River) on the content of BTEX compounds. Analytical procedure applied during the sampling of the analytes from the air used the passive sampling technique (diffusive passive sampler, Radiello®). For determination of BTEX compounds in atmospheric air, two-stage thermal desorption technique combined with gas chromatography (TD-GC-FID)...
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Photophysics of Ru(II) Dyads Derived from Pyrenyl-Substitued Imidazo[4,5-f][1,10]phenanthroline Ligands.
PublicationThe photophysics of a series of Ru(II) dyads based on the 2-(1-pyrenyl)-1H-imidazo[4,5-f][1,10]-phenanthroline ligand was investigated. The ability of these metal complexes to intercalate DNA and induce cell death upon photoactivation makes them attractive photosensitizers for a range of photobiological applications, including photodynamic therapy. In the present study, time-resolved transient absorption and emission spectroscopy...
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Guided ultrasonic waves for detection of debonding in bars partially embedded in grout
PublicationThis paper deals with theoretical, numerical and experimental investigations of guided wave propagation in multilayered cylindrical bars with pre-existing debonding. The research focuses on a complex description of the nature of the wave phenomena occurring in a debonded specimen with a special emphasis on the influence of the location of damage on the wave conversion and diffraction. Experimental non-destructive and destructive...
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FRP-based reinforcement coatings of steel with application prospects in ships and offshore structures: a review
PublicationLatest research on novel FRP-based anti-corrosion structural coatings (for enhancing structural capacity and strengthening the coating layer) is discussed with application prospects for ships and offshore structures. In the marine environment, structures constantly face corrosion and fatigue cracks. Combining this with high operational and wave loads, it might cause a structural collapse. Recently, polymer composites have been...
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Buried Object Characterization Using Ground Penetrating Radar Assisted by Data-Driven Surrogate-Models
PublicationThis work addresses artificial-intelligence-based buried object characterization using 3-D full-wave electromagnetic simulations of a ground penetrating radar (GPR). The task is to characterize cylindrical shape, perfectly electric conductor (PEC) object buried in various dispersive soil media, and in different positions. The main contributions of this work are (i) development of a fast and accurate data driven surrogate modeling...
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Analyzing Preconditions to Introduce Internet Voting in Portugal: Insights from the Estonian Model
PublicationInternet voting has been trialed or introduced for several countries, including Norway, Portugal, United States, United Kingdom and Switzerland as an additional voting channel to increase voter turnout and, also to modernize the electoral process. However, only Estonia has successful introduced internet voting, deploying e-enabled elections in general governmental levels. This paper aims to provide an exploratory study on the Estonian...
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Arabinoxylans: A review on protocols for their recovery, functionalities and roles in food formulations
PublicationArabinoxylans (AXs) are compounds with high nutritional value and applicability, including prebiotics or supplementary ingredients, in food manufacturing industries. Unfortunately, the recovery of AXs may require advanced separation and integrated strategies. Here, an analysis of the emerging techniques to extract AXs from cereals and their by-products is discussed. This review covers distinct methods implemented over the last...
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Wpływ struktur wsparcia na efektywność nauczania języka pisanego w środowisku e-learningowym
PublicationThe process of knowledge and language skills development during an online course can be very effective if student engagement in learning is achieved. This can be attained by introducing general and specific support mechanisms prior to the commencement of the course and during it. The former relates to the technological aspect, that is to familiarizing students with the functionalities of the virtual learning environment they will...
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Debonding Detection in Reinforced Concrete Beams with the Use of Guided Wave Propagation
PublicationOne of the most frequent damage of the reinforced concrete structures is debonding between steel bar and concrete cover. In the case of debonding occurrence not only the strength of the structure decreases, but also it is more vulnerable to corrosion damages. For this reason fast and effective methods of debonding detection in an early stage of its development need a significant boost. The paper presents analytical and experimental...
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Direct Analysis of Samples of Various Origin and Composition Using Specific Types of Mass Spectrometry
PublicationOne of the major sources of error that occur during chemical analysis utilizing the more conventional and established analytical techniques is the possibility of losing part of the analytes during the sample preparation stage. Unfortunately, this sample preparation stage is required to improve analytical sensitivity and precision. Direct techniques have helped to shorten or even bypass the sample preparation stage; and in this...
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Wielopoziomowy przekształtnik trakcyjny SiC z izolacją od sieci 3kV DC realizowaną za pomocą transformatorów 30kHz do napędów EZT
PublicationW referacie przedstawiono wielopoziomowy izolowany kaskadowy przekształtnik DC-AC z tranzystorami SiC MOSFET 1,2kV, przeznaczony do napędów elektrycznych zespołów trakcyjnych (EZT). Zaproponowana konstrukcja przekształtnika, przeznaczonego do pracy przy zasilaniu z sieci trakcyjnej 3kV DC, spełnia założenia energoelektronicznego transformatora trakcyjnego (z ang. Power Electronic Traction Transformer). Budowa modułowa z niskonapięciowych...
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On symmetric extendibility of quantum states and its applications
PublicationThis dissertation is focused on analysis of the symmetric extendibility of quantum states and its applications in the quantum information theory, with special attention paid to the area of quantum entanglement distillation, quantum channels theory, quantum security, and monogamy of quantum entanglement in time. We analyze geometry of the set of symmetric extendible states, i.e. such states that possess symmetric extensions and...
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Novel Nystatin A1 derivatives exhibiting low host cell toxicity and antifungal activity in an in vitro model of oral candidosis
PublicationOpportunistic oral infections caused by Candida albicans are frequent problems in immunocompromised patients. Management of such infections is limited due to the low number of antifungal drugs available, their relatively high toxicity and the emergence of antifungal resistance. Given these issues, our investigations have focused on novel derivatives of the antifungal antibiotic Nystatin A1, generated by modifications at the amino...
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Comparison of hydrophilic interaction and reversed phase liquid chromatography coupled with tandem mass spectrometry for the determination of eight artificial sweeteners and common steviol glycosides in popular beverages
PublicationHydrophilic interaction liquid chromatography (HILIC) coupled with tandem mass spectrometry (MS/MS) was used to separate artificial and natural sweeteners approved for use in European Union (EU). Among three tested HILIC columns (BlueOrchid PAL-HILIC, Ascentis Express Si and Acclaim™ Trinity™ P2) the last one was selected for the development of HILIC method due to the best results obtained with it. Early eluting and coeluting compounds...
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Electroactive polymer/graphene oxide nanostructured composites; evidence for direct chemical interactions between PEDOT and GOx
PublicationThis work concerns electrochemical synthesis of nanocomposites consisting of conducting polymer and reduced graphene oxide (rGOx) as electrode materials for supercapacitors. The electrosynthesis was performed in an aqueous solution of the 3,4-ethylenedioxytiophene (EDOT) monomer and graphene oxide (GOx) without supporting electrolyte. The amount of GOx was optimized to obtain the best electrochemical performance of the nanocomposite...
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Fire-Retardant Flexible Foamed Polyurethane (PU)-Based Composites: Armed and Charmed Ground Tire Rubber (GTR) Particles
PublicationInadequate fire resistance of polymers raises questions about their advanced applications. Flexible polyurethane (PU) foams have myriad applications but inherently suffer from very high flammability. Because of the dependency of the ultimate properties (mechanical and damping performance) of PU foams on their cellular structure, reinforcement of PU with additives brings about further concerns. Though they are highly flammable and...
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Graphene oxide aerogels for adsorptive separation of aromatic hydrocarbons and cycloalkanes
PublicationEfficient separation of benzene and cyclohexane has critical importance for production of commodity chemicals, and is one of the most challenging separations in the industry. Physisorption by recyclable, porous solids has a significant potential in substituting energy-intensive azeotropic or extractive distillation methods. Reduced graphene oxide aerogels (rGOAs) are emerging materials holding great promise for connecting unique...
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Seismic Response of High-Rise Buildings Equipped with Base Isolation and Non-Traditional Tuned Mass Dampers
PublicationOne of the methods in structural control is the application of combinational control systems in order to reduce the response of structures during earthquakes. The aim of the present paper is to verify the effectiveness of a hybrid control strategy, combining base isolation and non-traditional tuned mass dampers (TMDs) (i.e., TMDs with dashpots directly connected to the ground) in suppressing structural vibrations of high-rise buildings....
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Tailoring the optical parameters of optical fiber interferometer with dedicated boron-doped nanocrystalline diamond thin film
PublicationOptical fiber interferometer using nanocrystalline boron-doped diamond film was investigated. The diamond films were deposited on glass plates using a Microwave Plasma-Enhanced Chemical Vapour Deposition (μPE CVD) sys-tem. The growth time was 3h, with boron doping level of 10 000 ppm producing films (B-NCD-10) of thickness ~ 200 nm. The presence of boron atoms in the diamond film is evident in Raman spectrum as peaks at 1212 cm-1...
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Evaluation of working spaces' technical condition of marine diesel engine on the basis of operation research
PublicationThe paper presents the method of evaluation of the technical state of working spaces of a marine diesel engine at the reduced control susceptibility. The method foresees making diagnosis on the basis of the measurements of exhaust gas pressure in the channels connecting engine cylinders with turbocharger's turbine. In the beginning of the article the research objects are characterized i.e. ZVIEZDA main engine of M401 type and the...
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Stability of softly switched multiregional dynamic output controllers with a static antiwindup filter: A discrete-time case
PublicationThis paper addresses the problem of model-based global stability analysis of discrete-time Takagi–Sugeno multiregional dynamic output controllers with static antiwindup filters. The presented analyses are reduced to the problem of a feasibility study of the Linear Matrix Inequalities (LMIs), derived based on Lyapunov stability theory. Two sets of LMIs are considered candidate derived from the classical common quadratic Lyapunov...
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Effects of La Content on the Densification, Microstructure, and Conductivity of Doped La10−x Ge6 O26±δ Electrolytes
PublicationIn this study, the influence of La content on the characteristics of Nb-, Mo-, and W-doped LaxGe6O26±δ electrolytes was investigated through sintering study, X-ray diffraction, scanning electron microscopy, and conductivity measurement. The densification of LaxGe5.5Nb0.5O26±δ and LaxGe5.5W0.5O26±δ was retarded as the x reached 9.75, while that of LaxGe5.5Mo0.5O26±δ improved with increasing La content. The average grain size slightly...
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Recognition of hazardous acoustic events employing parallel processing on a supercomputing cluster . Rozpoznawanie niebezpiecznych zdarzeń dźwiękowych z wykorzystaniem równoległego przetwarzania na klastrze superkomputerowym
PublicationA method for automatic recognition of hazardous acoustic events operating on a super computing cluster is introduced. The methods employed for detecting and classifying the acoustic events are outlined. The evaluation of the recognition engine is provided: both on the training set and using real-life signals. The algorithms yield sufficient performance in practical conditions to be employed in security surveillance systems. The...
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Weak localization competes with the quantum oscillations in a natural electronic superlattice: The case of Na1.5(PO2)4(WO3)20
PublicationWe report an investigation of the combined structural and electronic properties of the bronze Na1.5(PO2)4(WO3)20. Its low-dimensional structure and possible large reconstruction of the Fermi surface due to charge density wave instability make this bulk material a natural superlattice with a reduced number of carriers and Fermi energy. Signatures of multilayered two-dimensional (2D) electron weak localization are consequently reported,...
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Study of the Effect of Filling Thermoplastic Medical Polyurethane with PVA, PLA or Diatomite on the Relaxation Times Distributions of 1H NMR
PublicationIn this work, to characterize the mobility of diferent sections of the macromole‑ cules of polyurethane (PUR), polyvinyl alcohol (PVA), and polylactic acid (PLA), as well as the density of crosslinks of the polymer chains when using fllers, we used the distributions of spin–lattice and spin–spin relaxation times for the protons. It is shown that the rigidity of the thermoplastic polymers depends on the sizes of the granules of...
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Smart heating system for home extending utilization of renewable energy sources
PublicationIn the paper a modern approach to smart home heating is presented. Proposed solution utilizes at least two low-polluting energy source technologies. The main idea is to connect well known ecological energy sources in a way that they can support each other and minimize risks of failure when using single system or even both of them but managed in separate way. Considered energy technologies, used separatelly, have disadvan-tages,...
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Dissociation energies of protonated water clusters
PublicationRelative abundances of positively ionized water clusters formed in a low-pressure electrical discharge as function of reduced electric field were obtained by using drift cell and quadrupole mass spectrometer. It was noticed that some clusters say with n = 4 were more abundant than others, at comparable drift conditions. Dissociation energies have been derived from equilibrium conditions for relative clusters abundances. The Hartree-Fock...
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Initial Considerations
PublicationChemical processes have made use of a wide number of volatile organic solvents due to their efficiency in countless unit operations. The increasing knowledge on the environmental, health, and safety hazards associated to their use has significantly contributed to the search for greener alternatives. The primary purpose of this book is to provide an overview of alternative solvents with reduced issues that have successfully replaced...
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DME as alternative fuel for compression ignition engines – a review
PublicationThe ecological issues and the depletion of crude oil, has led the researchers to seeking for non-petroleum based alternative fuels, along with more advanced combustion technologies, and after-treatment systems. The use of clean alternative fuels is the one of the most perspective method that aiming at resolving of the said issues. One of the promising alternative fuels that can be used as a clean highefficiency compression ignition...
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Badania wpływu demulgacji i doboru optymalnego demulgatora na skład fazy gazowej i ciekłej ścieków pooksydacyjnych
PublicationOczyszczanie ścieków pooksydacyjnych, pochodzących z oksydacji pozostałości z destylacji próżniowej ropy naftowej i produkcji tzw. asfaltów utlenianych, szczególnie drogowych, a także przemysłowych, stanowi duży problem technologiczny i środowiskowy. Wynika to z obecności w ściekach różnych grup związków organicznych, w tym m.in. organicznych związków siarki, tlenu i azotu. Pewna ich część jest zaabsorbowana w wodzie i częściowo...
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Plasmon resonance in a TiO2-Au NPs structures
Open Research DataInvestigated structures were deposited on a pre cleaned Corning 1737 glass substrates, which provided flat optical transmission characteristics and high transmission coefficient in a visible light range. Plasmonic nanostructures were formed as a result of thermal annealing. For gold films with thickness of 2.8 nm depiction a table-top dc magnetron sputtering...
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Preparation of Well-Compatibilized PP/PC Blends and Foams Thereof
PublicationThe performance of polypropylene-poly(ethylene brassylate) block and graft copolymers and a polypropylene-polycaprolactone graft copolymer as compatibilizers for polypropylene-rich polypropylene/bisphenol A polycarbonate (PP/PC, 80/20 wt/wt) blends was elucidated. The copolymers were synthesized either by metal-catalyzed ring-opening polymerization or transesterification of a presynthesized polyester, initiated by hydroxyl-functionalized...
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Photosensitive and pH-dependent activity of pyrazine-functionalized carbazole derivative as promising antifungal and imaging agent
PublicationCarbazole skeleton plays a significant role as a structural scaffold of many pharmacologically active compounds. Pyrazine-functionalized carbazole derivative was constructed by coupling 2-amino-5-bromo-3-methylaminepyrazine (ABMAP) into 3 and 6 positions of the carbazole ring. Multi-experimental methods were used, e.g., potentiometric, spectroscopic (ATR, UV, XRD powder,1H and13C NMR), electrochemical (cyclic voltammetry), and...
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A Microwave Sensor with Operating Band Selection to Detect Rotation and Proximity in the Rapid Prototyping Industry
PublicationThis paper presents a novel sensor for detecting and measuring angular rotation and proximity, intended for rapid prototyping machines. The sensor is based on a complementary split-ring resonator (CSRR) driven by a conductor-backed coplanar waveguide. The sensor has a planar topology, which makes it simple and cost-effective to produce and accurate in measuring both physical quantities. The sensor has two components, a rotor, and...
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How acidic amino acid residues facilitate DNA target site selection
PublicationDespite the negative charge of the DNA backbone, acidic residues (Asp/Glu) commonly participate in the base readout, with a strong preference for cytosine. In fact, in the solved DNA/protein structures, cytosine is recognized almost exclusively by Asp/Glu through a direct hydrogen bond, while at the same time, adenine, regardless of its amino group, shows no propensity for Asp/Glu. Here, we analyzed the contribution of Asp/Glu...
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Shape Memory Alloy-Based Fluidically Reconfigurable Metasurfaced Beam Steering Antenna
PublicationA low-cost actuator-based fluidically programmable metasurface (FPMS) antenna is proposed to solve the slow tuning speed problem of the manually fluidic based reconfigurable antennas. The FPMS-based antenna is probe-fed and comprises a 4 × 4 square ring metasurface as a superstrate. Moreover, two shape memory alloy (SMA)-based electrically-controlled actuators are employed in the design for controlling the position of the 3D-printed...
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Analysing the impact of traffic incidents on express road traffic flow using FREEVAL
PublicationTraffic incidents occurring on motorways or express roads cause disruptions and deteriorate traffic conditions. The impact will differ depending on the type of incident, its duration and space blocked on the roadway and can be measured with e.g. average speed reduction, extension of travel time, time lost or overall costs of traffic disruptions. The aim of the paper is to analyse this impact, based on data from the Tri-City Ring...
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Cross sections for electron collision with pyridine [C5H5N] molecule
PublicationThe absolute grand -total cross section (TCS) for electron scattering from pyridine, C5H5N, molecules has been measured at impact energies from 0.6 to 300 eV in the linear electron-transmission experiment. The obtained TCS energy dependence appears to be typical for targets of high electric-dipole moment; the cross section generally decreases with rising energy, except for the 3–20 eV range, where a broad enhancement peaked near...
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Advanced oxidation processes for the removal of mono and polycyclic aromatic hydrocarbons – A review
PublicationAromatic hydrocarbons (AHs) are toxic environmental contaminants presented in most of the environmental matrices. Advanced oxidation processes (AOPs) for the removal of AHs in the account of complete mineralization from various environmental matrices have been reviewed in this paper. An in-depth discussion on various AOPs for mono (BTEX) and polyaromatic hydrocarbons (PAHs) and their derivatives is presented. Most of the AOPs were...
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Inter Applied Chemistry Programme 1 Morrison Forensic
e-Learning CoursesInter Applied Chemistry Programme 1 Lecture 1 background reading Read the following : Chapter 1 Introduction to Forensic Science ( From Jackson, Jackson, Mountain and Brealey, Forensic Science, Pearson 4th Ed (2016)) Very general professional guidance/Introduction United Nations can be found within these guides, (these are mainly for reference purposes) https://www.unodc.org/documents/scientific/Crime_scene_awareness__Ebook.pdf https://www.unodc.org/documents/justice-and-prison-reform/cjat_eng/Forensic_services_and_infrastructure.pdf Task...
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Cichy sonar - stan aktualny i perspektywy
PublicationW zastosowaniach militarnych często istnieje potrzeba prowadzenia obserwacji w sposób skryty za pomocą urządzeń emitujących sygnały trudne do przechwycenia przez przeciwnika. Rozwiązania stosowane w cichych radarach stanowiły punkt wyjścia do opracowania cichego sonaru. Prace nad projektem rozpoczęto na Politechnice Gdańskiej w roku 2010 w ramach Grantu NCBiR i są one dalej kontynuowane. W celu zachowania w cichym sonarze warunków...