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Search results for: DEFECT ENGINEERING
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Defect engineering, microstructural examination and improvement of ultrafast third harmonic generation in GaZnO nanostructures: a study of e-beam irradiation
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Defect and Diffusion Forum
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Band engineering of BiOBr based materials for photocatalytic wastewater treatment via advanced oxidation processes (AOPs) – A review
PublicationSemiconductor based photocatalysts have been an efficient technology for water and wastewater remediation, addressing the concepts of green chemistry and sustainable development. Owing to narrow and suitable band structure, BiOBr is a promising candidate for efficient wastewater treatment via photocatalysis. Enhancement of photocatalytic properties can be obtained by various techniques like doping, element rich strategy, facet...
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Guided waves for monitoring of plate structures with linear cracks of variable length
PublicationDamage occurring at the work of plate structures may grow to a considerable size. The joint action – the detection of a defect at the earliest possible stage, the monitoring of its growth and the determination of its critical size in the context of structural reliability allows optimizing the cost of the maintenance and repair of structural elements. Thus the development of monitoring systems for permanent observation of fault...
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Performance of organic coatings upon cyclic mechanical load
PublicationA number of engineering structures fail due to the fatigue damage resulting from cyclic mechanical stress. However, as far as organic coatings are concerned this degradation factor remains underestimated. In the paper the authors propose a methodology combining global electrochemical impedance spectroscopy and local atomic force microscopy measurements for evaluation of coating resistance to an impact of repetitive mechanical stress. Typical...
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Guided wave propagation in debonding detection in CFRP-reinforced steel plate-like structures
PublicationThe present study investigates the guided wave propagation in multilayered steel specimens reinforced with carbon fiber reinforced polymer (CFRP) through theoretical, numerical, and experimental means. The effectiveness of externally bonded reinforcement (EBR) relies heavily on the bonding quality between the CFRP and the substrate. Premature debonding, a prevalent and hazardous defect, can arise from suboptimal manufacturing processes,...
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Use of Neural Networks in Diagnostics of Rolling-Element Bearing of the Induction Motor
PublicationBearing defect is statistically the most frequent cause of an induction motor fault. The research described in the paper utilized the phenomenon of the current change in the induction motor with bearing defect. Methods based on the analysis of the supplying current are particularly useful when it is impossible to install diagnostic devices directly on the motor. The presented method of rolling-element bearing diagnostics used indirect...
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Impact of high temperature drying process on beech wood containing tension wood
PublicationThe technology of high temperature drying has a great inuence on dimensional and selected physical changes in tension wood. Article is focused on the measurement properties such as moisture content, color changes and longitudinal warping. The quality of beech wood is determined based on structure and properties of wood, frequency of defects in wood material. The tension wood is considered as an important wood defect causing negative...
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Tailoring Defects in B, N-Codoped Carbon Nanowalls for Direct Electrochemical Oxidation of Glyphosate and its Metabolites
PublicationTailoring the defects in graphene and its related carbon allotropes has great potential to exploit their enhanced electrochemical properties for energy applications, environmental remediation, and sensing. Vertical graphene, also known as carbon nanowalls (CNWs), exhibits a large surface area, enhanced charge transfer capability, and high defect density, making it suitable for a wide range of emerging applications. However, precise...
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A Comparative Study on Methods of Distinction Between Near- and Far-Side Defects as Techniques Used Alongside with the Magnetic Flux Leakage Testing
PublicationResults of the finite element analysis show that a far-side defect in a steel plate, with the depth greater by 10% of the plate thickness than a near-side defect, can produce a very similar magnetic flux leakage (MFL) signal. Due to the fact that a measurement of MFL itself can lead to misclassification of a far-side defect as a near-side one, and thus to underestimation of its depth, a comparative study of three complementary...
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Assessment of image processing methods for the determination of propagation of squat-type defects in rails
PublicationWe demonstrate the idea of squat-type defect measurement in the rail and the concept of tracking of the defect development using the techniques of image acquisition and image processing as well as the methods of metric spaces. We introduce the concepts of a set diameter δ(A) and the metric ρ1, which come from the properties of plane figures, to compare and to observe the development of the defects. We characterize the feasibility...
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NON-LOCAL VOLUMETRIC APPROACH TO ANALYSIS DEFECT'S SHAPE INFLUENCE ON SPECIMENS DURABILITY SUBJECTED TO BENDING AND TORSION
PublicationThe influence of defect features on fatigue behaviour is a complex trivial issue. Although the important advances over the last decades, the dialectical relationship between the defect orientation and durability is not clearly understood. The paper aims at studying the influence of the orientation of elliptical defects on the durability of samples made of C45 steel. Three types of samples with elliptical defects were subjected...
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Polarization-sensitive optical coherence tomography for ceramic materials inspection
PublicationCeramics production is looking for a fast, reliable and non-destructive method that can be implemented on site for defect detection and analysis. In this paper we present polarization-sensitive optical coherence tomography (PS-OCT) as a method for defect inspection. Proposed extensions to standard OCT provide additional information for complete characterization of tested object. We compare OCT and microscope imaging that can easily...
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Application of Electrochemical Impedance Spectroscopy to evaluate cathodically protected coated steel in seawater
PublicationTwo types of organic coated carbon steel (S235JR2 grade) electrodes were exposed to artificial seawater environment. One prepared type was defect free while the other one had an intentionally introduced φ0,5 cm coating defect. Both kinds of samples were polarized during the exposure to four potentials corresponding to four different cathodic protection levels. Evolution of their EIS spectra is presented in this paper. Results obtained...
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Effects of FSW Tool Plunge Depth on Properties of an Al-Mg-Si Alloy T-Joint: Thermomechanical Modeling and Experimental Evaluation
PublicationOne of the main challenging issues in friction stir welding (FSW) of stiffened structures is maximizing skin and flange mixing. Among the various parameters in FSW that can affect the quality of mixing between skin and flange is tool plunge depth (TPD). In this research, the effects of TPD during FSW of an Al-Mg-Si alloy T-joint are investigated. The computational fluid dynamics (CFD) method can help understand TPD effects on FSW...
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Planar Microwave Bragg Reflector Resonant Dielectric Sensor
PublicationIn this paper, a periodic structure is used to design a microwave Bragg reflector with the help of hexagonal lattice, which provides a 5 GHz wide stopband between the low-pass band with cut-off frequency 2.6 GHz and the bandpass response with start and stop frequency 7.8 GHz and 10.5 GHz, respectively. A defect in lattice allows passing a narrowband signal at 6 GHz which is found, from the dispersion relation, to be in the region...
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Conductivity, structure, and thermodynamics of Y2Ti2O7–Y3NbO7 solid solutions
PublicationThe defect fluorite yttrium niobate Y3NbO7 and pyrochlore yttrium titanate Y2Ti2O7 solid solutions have been synthesized via a solid state synthesis route. The resulting stoichiometry of the oxides is Y2+xTi2−2xNbxO7, where x = 0 to x = 1. All of the samples were single-phase; however, for those with a predominant fluorite phase, a small amount of additional pyrochlore phase was detected. The volume of the solid solution unit cells...
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Microstructural and electrical properties of Y0.07Sr0.93-xTiO3-δ perovskite ceramics
PublicationIn order to find a relationship between electrical and microstructural properties, yttrium-doped strontiumtitanate (7 mol%) with various values of strontium nonstoichiometry was investigated and shown in this work.It has been observed that yttrium doping can affect the electrical properties of SrTiO3 to a great extent.Moreover, the microstructural and electrical properties can be influenced by strontium nonstoichiometry.The defect...
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Improved selectivity compact band-stop filter with gosper fractal-shaped defected ground structures
PublicationA novel band-stop filter using Gosper fractal-shaped defected ground structures has been designed and manufactured. The improvement in the filter selectivity has been achieved by introducing a multiresonance fractal-shaped defect leading to a higher filter order, simultaneously maintaining its compact size. The experimental results prove the validity of proposed solution and its utility in novel miniaturized and severe requirement...
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Microstructural and electrical properties of Y0.07Sr0.93-xTiO3 perovskite ceramics
PublicationIn order to find a relationship between electrical and microstructural properties, yttrium-doped strontium titanate (7 mol%) with various values of strontium nonstoichiometry was investigated and shown in this work. It has been observed that yttrium doping can affect the electrical properties of SrTiO3 to a great extent. Moreover, the microstructural and electrical properties can be influenced by strontium nonstoichiometry. The...
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Microstructural and electrical properties of Y0:07Sr0:93−xTiO3− perovskite ceramics
PublicationIn order to find a relationship between electrical and microstructural properties, yttrium-doped strontium titanate (7 mol%) with various values of strontium nonstoichiometry was investigated and shown in this work. It has been observed that yttrium doping can affect the electrical properties of SrTiO3 to a great extent. Moreover, the microstructural and electrical properties can be influenced by strontium nonstoichiometry. The...
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Donor-substituted SrTi1+xO3−δ anodes for SOFC
PublicationNonstoichiometric Nb-substituted SrTiO3 compounds were investigated in order to discuss the influence of nonstoichiometry at the sample properties in the light of recent results reported in the literature. Structural and electrical properties of samples were characterized. Investigated compounds were also applied as anodes for Solid Oxide Fuel Cells and their reactivity with YSZ electrolyte was examined. The defect chemistry explaining...
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Application of wavelet transform in analysis of guided wave propagation signals for damage detection in a steel plate
PublicationThe paper presents results of experimental investigations on damage detection using guided wave propagation technique. The tested specimen was a steel plate with a defect in the form of a rectangular notch. Lamb waves were excited by a PZT actuator and sensed by a laser vibrometer. Since reflections from damage in registered signals are often masked by measurement noise, for identification of time of reflections from damage, continuous...
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The study on the appearance of deformation defects in the yacht lamination process using an AI algorithm and expert knowledge
PublicationThis article describes the application of the A-priori algorithm for defining the rule-based relationships between individual defects caused during the lamination process, affecting the deformation defect of the yacht shell. The data from 542 yachts were collected and evaluated. For the proper development of the algorithm, a technological process of the yacht lamination supported by expert decisions was described. The laminating...
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Investigation on polypropylene friction stir joint: effects of tool tilt angle on heat flux, material flow and defect formation
PublicationTool tilt angle (TTA) is a critical factor that can control material flow in polymeric materials' friction stir joining (FSJ). This study selected a TTA range between 0° to 4° for FSJ of polypropylene (PP) polymer sheet. A modified computational fluid dynamic (CFD) technique was implemented to gain a deep understanding of the effects of TTA during FSJ of PP. The PP joint's internal flow, defect formation, heat generation, and tensile...
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Modelling of in-plane wave propagation in a plate using spectral element method and Kane-Mindlin theory with application to damage detection
PublicationThis paper presents results of experimental and numerical analyses of in-plane waves propagatingin a 5 mm-thick steel plate in the frequency range of 120-300 kHz. For such a thickness/frequency ratio,extensional waves reveal dispersive character. To model in-plane wave propagation taking into account thethickness-stretch effect, a novel 2D spectral element, based on the Kane-Mindlin theory, was formulated. Anapplication of in-plane...
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Quality 5.0: A Paradigm Shift Towards Proactive Quality Control in Industry 5.0
PublicationIndustry 5.0, the latest wave of industrial revolution, is redefining the traditional manufacturing and production landscapes by leveraging advanced technologies, promoting sustainability, and fostering a human-centric approach. An inevitable consequence of this progression is Quality 5.0, the next phase of quality control and assurance. Quality 5.0 aims to transcend the limitations of conventional quality control techniques, which...
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Fabrication, structural and electrical properties of Sr(V,Nb)O 3-δ perovskite materials
PublicationThe SrV1-xNbxO3-δ materials with different niobium content in perovskite B-sublattice were prepared by a solid-state reaction process. The microstructure and phase compositions of obtained samples were analyzed by the X-ray diffraction technique (XRD) and scanning electron microscopy (SEM). The electrical conductivity of samples was measured by a DC 4-wire method in range of 100–600 °C in different gas conditions. The oxidation...
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Lamb wave propagation in a single lap adhesive joint
PublicationThe aim of the paper is the analysis of Lamb wave propagation in adhesive joints. The research was performed on a single lap adhesive joint of two steel plates. Two types of joints, namely an intact and with defect were considered. In experimental investigations the condition assessment of the joint was performed with the use of antisymmetric Lamb waves excited by a plate piezo actuators and measured by a laser vibrometer. Numeri-cal...
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Measurement methods for assessing insulation condition of underground pipelines
PublicationThe paper discusses the most frequently applied measurement methods for assessing the quality of external insulation along pipelines and detecting defect locations in the protective coating. The quality of coating along a given pipeline section under investigation is assessed by determining unitary resistance of the coating, which is calculated on the basis of measurement results obtained along a pipeline subjected to cathodic...
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Higher Responsiveness to Rosuvastatin in Polygenic versus Monogenic Hypercholesterolemia: A Propensity Score Analysis
PublicationBackground: The monogenic defect in familial hypercholesterolemia (FH) is detected in ∼40% of cases. The majority of mutation-negative patients have a polygenic cause of high LDL-cholesterol (LDL-C). We sought to investigate whether the underlying monogenic or polygenic defect is associated with the response to rosuvastatin. Methods: FH Individuals were tested for mutations in LDLR and APOB genes. A previously established LDL-C-specific...
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A comprehensive study on nonlinear hygro-thermo-mechanical analysis of thick functionally graded porous rotating disk based on two quasi three-dimensional theories
PublicationIn this paper, a highly efficient quasi three-dimensional theory has been used to study the nonlinear hygro-thermo-mechanical bending analysis of very thick functionally graded material (FGM) rotating disk in hygro-thermal environment considering the porosity as a structural defect. Two applied quasi three-dimensional displacement fields are assumed in which the strain along the thickness is not zero unlike most of the other plate...
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Analysis of Measurement Errors in Rail Vehicles’ Pantograph Inspection System
PublicationThe paper presents an approach to evaluation of height measurement errors in laser scanning inspection system. The system, consisting of a laser line generator and a specialized camera, is dedicated to diagnosing carbon contact strips of railway vehicles’ pantographs. While height measurement resolution is easily computable based on system parameters, determining the measurement error is troublesome due to numerous impacts. As...
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Water uptake and energetics of the formation of barium zirconate based multicomponent oxides
PublicationA group of multi-component oxides based on BaZrO3 have been prepared using a solid-state reaction method and examined in terms of their water uptake and thermodynamics of formation. Depending on the type and amount of acceptor substitution, the synthesized compounds exhibit various proton defect concentrations, reaching up to 0.2 mol/mol for a compound containing 10 different elements in the B-sublattice, where 50% of them are...
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Global sensitivity analysis of membrane model of abdominal wall with surgical mesh
PublicationThe paper addresses the issue of ventral hernia repair. Finite Element simulations can be helpful in the optimization of hernia parameters. A membrane abdominal wall model is proposed in two variants: a healthy one and including hernia defect repaired by implant. The models include many uncertainties, e.g. due to variability of abdominal wall, intraabdominal pressure value etc. Measuring mechanical properties with high accuracy...
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Fault diagnosing system of wheeled tractors
PublicationA defect of complex wheeled tractor assembles most frequently negative influence on exploitation efficiency, safety and exhaust gases emission. Structure complexity of wheeled tractors requires more and more advanced diagnostic methods for identification of their serviceable possibilities as well in manufacturing step as in exploitation. In classical diagnosing methods of wheeled tractor defects states mapping by measured diagnostic...
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Analysis of the Ways to Identify Rail Running Surface Defects by Means of Vibration Signals
PublicationTh e article discusses a preliminary concept of a method enabling the identifi cation of chosen rail running surface defects, such as squats, spalling, and running surface defects, by analysing the parameters of vibration signals. It features a description of the methodology of the conducted tests, the scope thereof, and the selection of the measurement points with specifi c defect types. Th e article covers selected results of...
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Inhibitors of amino acids biosynthesis as antifungal agents
PublicationFungal microorganisms, including the human pathogenic yeast and filamentous fungi, are able to synthesize all proteinogenic amino acids, including nine that are essential for humans. A number of enzymes catalyzing particular steps of human-essential amino acid biosynthesis are fungi specific. Numerous studies have shown that auxotrophic mutants of human pathogenic fungi impaired in biosynthesis of particular amino acids exhibit...
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Analysis of a caustic formed by a spherical reflector: Impact of a caustic on architectural acoustics
PublicationFocusing sound in rooms intended for listening to music or speech is an acoustic defect. Design recommendations provide remedial steps to effectively prevent this. However, there is a category of objects of high historical or architectural value in which the sound focus correction is limited or even abandoned. This also applies to indoor or outdoor concert shells, installations for teaching and acoustic presentations, etc. The...
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Higher responsiveness to rosuvastatin in polygenic versus monogenic hypercholesterolaemia: a propensity score analysis
PublicationBackground The underlying monogenic defect in familial hypercholesterolemia (FH) can be detected in ∼40% of cases. The majority of mutation-negative patients have a polygenic cause of high LDL-cholesterol (LDL-C) due to having inherited a greater than average number of common LDL-C raising single nucleotide polymorphisms (SNPs). Purpose We sought to investigate, whether the monogenic or polygenic defect in FH is associated with...
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High-temperature properties of titanium-substituted yttrium niobate
Publicationhe defect fluorite titanium-doped yttrium niobate samples Y3Nb1−xTixO7−δ have been synthesized and investigated by the means of high-temperature X-ray diffraction, dilatometry, and thermogravimetry. Thermal expansion coefficients (TECs) as well as chemical expansion coefficients for material with 5, 10, and 15 mol% of titanium were determined. All investigated samples exhibit chemical contraction caused by Ti doping. The values...
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On Symmetry of Uniform and Preferential Attachment Graphs
PublicationMotivated by the problem of graph structure compression under realistic source models, we study the symmetry behavior of preferential and uniform attachment graphs. These are two dynamic models of network growth in which new nodes attach to a constant number m of existing ones according to some attachment scheme. We prove symmetry results for m=1 and 2 , and we conjecture that for m≥3 , both models yield asymmetry with high...
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Influence of friction stir welding technological parameters on the properties of the joints of selected aluminum alloys
PublicationThe purpose of this dissertation was to determine the effect of friction stir welding technological parameters on the properties of selected aluminum alloy joints, with consideration of the residual stresses and dislocation density in the joints. The goal of the present work was also to produce defect-free joints with high mechanical and electrochemical properties. In the dissertation, similar welds of AA6082 alloy and dissimilar...
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A novel hierarchically-porous diamondized polyacrylonitrile sponge-like electrodes for acetaminophen electrochemical detection
PublicationA novel composite electrode material consisting of tangled fibrous polyacrylonitrile-based hierarchically-struc- tured nanocomposites has been produced by wet-spinning, carbonized and decorated with a carbon nano- architecture by microwave plasma-enhanced chemical vapor deposition and investigated as a metal-free electrode for the enhanced electrochemical detection of acetaminophen. Surprisingly, the hierarchical fiber ar- chitecture...
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Thermochemistry of rare earth perovskites Na3xRE0.67−xTiO3 (RE = La, Ce)
PublicationHigh-temperature oxide melt solution calorimetry using sodium molybdate (3Na2O·4MoO3) solvent at 973 K was performed for the Na3xRE0.67−xTiO3 (RE = La, Ce) perovskite series. The enthalpies of formation of lanthanum perovskites from oxides (La2O3, Na2O, TiO2), are −107.25 ± 2.56, −93.83 ± 6.06, −80.68 ± 5.93, and −33.49 ± 4.26 kJ/mol and enthalpies of formation from elements are −1614.05 ± 5.37, −1596.44 ± 7.68, −1594.03 ± 7.58,...
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Organic semiconductor rubrene thin films deposited by pulsed laser evaporation of solidified solutions
PublicationOrganic semiconductor rubrene (C42H28) belongs to most preferred spintronic materials because of the high charge carrier mobility up to 40 cm2(V·s)-1. However, the fabrication of a defect-free, polycrystalline rubrene for spintronic applications represents a difficult task. We report preparation and properties of rubrene thin films deposited by pulsed laser evaporation of solidified solutions. Samples of rubrene dissolved in aromatic...
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Effect of Different Bromine Sources on the Dual Cation Mixed Halide Perovskite Solar Cells
PublicationRecent research has shown that perovskite solar cells with a mixed dual A-cation have much better structural stability without loss of efficiency than single cation devices. Mixed cation perovskites create a lot of questions about the salts being used for the formation of the best-quality layer. Here, we have investigated three sources of bromide in the perovskite absorption layer, using lead bromide (PbBr2), formamidinium bromide...
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A novel luminescent chemical sensor for the determination of Pb 2+ and Cu 2+ ions
PublicationSilica xerogel surface grafted with aminopropyl (PrNH2) groups was additionally treated by cetyltrimethylammonium bromide (CTAB) surfactant and ascorbic acid (asc) in alkaline solution. This material symbolized as SiO2-PrNH2-CTAB/asc, proved to be a stable luminescent material, exhibited an emission band peaked at 393 nm under excitation wavelength 335 nm. Time evolution of the band intensity suggests changes of defect concentration...
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Applying molecular dynamics simulation to take the fracture fingerprint of polycrystalline SiC nanosheets
PublicationGraphene-like nanosheets are the key elements of advanced materials and systems. The mechanical behavior of the structurally perfect 2D nanostructures is well documented, but that of polycrystalline ones is less understood. Herein, we applied molecular dynamics simulation (MDS) to take the fracture fingerprint of polycrystalline SiC nanosheets (PSiCNS), where monocrystalline SiC nanosheets (MSiCNS) was the reference nanosheet....
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Thermal and Chemical Expansion in Proton Ceramic Electrolytes and Compatible Electrodes
PublicationThis review paper focuses on the phenomenon of thermochemical expansion of two specific categories of conducting ceramics: Proton Conducting Ceramics (PCC) and Mixed Ionic-Electronic Conductors (MIEC). The theory of thermal expansion of ceramics is underlined from microscopic to macroscopic points of view while the chemical expansion is explained based on crystallography and defect chemistry. Modelling methods are used to predict...