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Quenching effects in organic electroluminescence
PublicationWe examine various electronic processes that underlie the quenching of the emission from highly efficient phosphorescent and electrophosphorescent organic solid-state molecular systems. As an example, we study the luminescent efficiencies from the phosphorescent iridium (III) complex, fac tris (2-phenylpyridine) iridium [(Ir (ppy)3] doped into a diamine derivative doped polycarbonate hole-transporting matrix and in the form...
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Characteristics of volatile organic compounds emission profiles from hot road bitumens
PublicationA procedure for the investigation and comparison of volatile organic compounds (VOCs) emission profiles to the atmosphere from road bitumens with various degrees of oxidation is proposed. The procedure makes use of headspace analysis and gas chromatography with universal as well as selective detection, including gas chromatography–mass spectrometry (GC–MS). The studies revealed that so-called vacuum residue, which is the main component...
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Testing Students’ Entrepreneurial Self-Efficacy as an Early Predictor of Entrepreneurial Activities. Evidence From the SEAS Project
PublicationOver the last forty years, since Bandura (1977) introduced the concept of self-efficacy, there have been a constantly growing number of research publications using this concept. Its early development resulted in the creation of a new construct of entrepreneurial self-efficacy (ESE) proposed for the first time by (Chen et al. 1998). Since then, many different groups of research concerning ESE have emerged - one of them is the study...
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Deep learning for ultra-fast and high precision screening of energy materials
PublicationSemiconductor materials for energy storage are the core and foundation of modern information society and play important roles in photovoltaic system, integrated circuit, spacecraft technology, lighting applications, and other fields. Unfortunately, due to the long experiment period and high calculation cost, the high-precision band gap (the basic characteristic parameter) of semiconductor is difficult to obtain, which hinders the...
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Opracowanie nowych metodyk oznaczeń ilościowych i jakościowych izotiocyjanianów oraz związków indolowych w próbkach roślin z rodziny Brassicaceae
PublicationIzotiocyjaniany (ITC) i indole powstające w wyniku hydrolizy glukozynolanów obecnych w roślinach z rodziny Brassicaceae wykazują wysoką aktywność biobójczą w stosunku do fitofagów stanowiąc alternatywę dla syntetycznych pestycydów. Zaliczane są także do najważniejszych żywieniowych substancji przeciwzapalnych i przeciwrakotwórczych. Pomimo wielu zastosowań dotychczas brakowało metod analitycznych umożliwiających ich rutynowe oznaczanie....
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Highly crystalline colloidal nickel oxide hole transport layer for low-temperature processable perovskite solar cell
PublicationHighly crystalline NiOX usually requires high annealing temperature (>300 °C) which is incompatible with flexible substrate and might consume high amount of energy. Herein, we demonstrate a facile emulsion process to synthesize highly crystalline, low temperature deposition (<150 °C) and solution processable NiOx nanoparticles (NPs) as a hole transport layer for the perovskite solar cells (PVSCs). A novel surfactant of tetramethylammonium...
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Life cycle assessment - a new approach to the question of environmental strain caused by analytical laboratories = Ocena cyklu życia - nowe podejście do zagadnienia uciążliwości środowiskowej laboratorów analitycznych
PublicationPraca przedstawia wyniki porównawczej oceny cyklu życia dla procesów pozyskiwania ekstraktów końcowych metodą ekstrakcji w układzie ciecz - ciecz i ekstrakcji do fazy stałej. Rozważano jedynie aspekt ekologiczny pozyskiwania wyników, nie bacząc na koszty ekologiczne i inne. Badania oparte są na informacjach uzyskanych w określonym laboratorium analitycznym oraz danych zawartych w bibliotece programu SimaPro. Techniką bardziej przyjazną...
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Can Grand Design Doctrines Go Well with Locally Reinvented Urbanisms? Notes from Polish Cities in Transition
PublicationThe text explores how New Urbanism ideas, a comprehensive global design doctrine, transgress into the context of Polish planning practice. New Urbanism is considered through the perspective of the decentralization of a discussion on a planning policy and a modernization of a State, resulting form its post-Socialist urban change. In the text, New Urbanism is understood as a neotraditionalist movement i.e. drawing from the pre-modernist...
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Charakterystyka zgorzelin na elementach wyposażenia wewnętrznego ze stali 18Cr-10Ni-0,5Nb w reaktorze instalacji hydrokrakingu
PublicationBadano zgorzeliny siarczkowe na kołpakach z austenitycznej stali 18Cr-10Ni-0,5Nb z wnętrza reaktora instalacji hydrokrakingu. Wsad reaktora stanowiły ciekłe węglowodory i wodór o temperaturze 370 stopni C. Stężenie siarkowodoru w aparacie zawierało się w granicach 12 ppm - 1,2% obj. Posługując się elektronowym skaningowym mikroskopem sprzężonym ze spektrometrem rentgenowskim dyspersji energii określono mikrostrukturę i skład chemiczny...
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Comparison of efficiency of different sorbents used during clean-up of extracts for determination of polychlorinated biphenyls and pesticide residues in low-fat food
PublicationOkreślono przydatność i zakres zastosowania kolumienek sorpcyjnych zawierających złoża różnych sorbentów wykorzystywanych do oczyszczania ekstraktów z żywności o zawartości do 20 % tłuszczu z wykorzystaniem techniki ekstrakcji do fazy stałej (SPE). Udowodniono, że zastosowanie kolumienek sorpcyjnych zawierających złoże żelu krzemionkowego modyfikowanego fazą aminopropylową, tlenku glinu bądź krzemianu magnezu do oczyszczania ekstraktów...
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Influence of sensor design and optical properties of tissue on the photoplethysmographic signal
PublicationPhotopletysmography and an associated technique called pulse oximetry are still explored due to the expectations that they give a lot of information about the state of the patient and, also, due to the fact that they are non invasive. Knowledge about the impact of various parameters on the measured signal leads to a faster and a more reliable way of analyzing measurement results and finding the dependencies between the involved...
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Deep compaction control of sandy soils
PublicationVibroflotation, vibratory compaction, micro-blasting or heavy tamping are typical improvement methods for the cohesionless deposits of high thickness. The complex mechanism of deep soil compaction is related to void ratio decrease with grain rearrangements, lateral stress increase, prestressing effect of certain number of load cycles, water pressure dissipation, aging and other effects. Calibration chamber based interpretation...
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Evaluating Business Accelerator Participants’ Experiences – Effectuation at Play?
PublicationResponding to the new phenomena in entrepreneurship ecosystems in Poland, the author undertakes the study that aims to explore experiences of participants of (pre)accelerator programme for start-ups. Clipster is a business an acceleration and incubation programme, where participants have a unique co-living opportunity and work on their new venture ideas. With phenomenological interviews with six nascent entrepreneurs - participants...
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Tweet you right back: Follower anxiety predicts leader anxiety in social media interactions during the SARS-CoV-2 pandemic
PublicationRecent research has shown that organizational leaders’ tweets can influence employee anxiety. In this study, we turn the table and examine whether the same can be said about followers’ tweets. Based on emotional contagion and a dataset of 108 leaders and 178 followers across 50 organizations, we infer and track state- and trait-anxiety scores of participants over 316 days, including pre- and post the onset of the SARS-CoV-2 pandemic...
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Evaluating Business Accelerator Participants’ Experiences – Effectuation at Play?
PublicationResponding to the new phenomena in entrepreneurship ecosystems in Poland, the author undertakes the study that aims to explore experiences of participants of (pre)accelerator programme for start-ups. Clipster is a business an acceleration incubation programme, where participants have a unique co-living opportunity and work on their new venture ideas. With phenomenological interviews with six nascent entrepreneurs - participants...
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Dynamic electrochemical impedance spectroscopy of the adsorption and relaxation of polianiline chains during potentiodynamic redox transformations
PublicationZaprezentowano nowe podejście do analizy widm impedancyjnych uzyskanych dla warstwy przewodzącej polianiliny (PAni). Właściwości powyższej warstwy są często modelowane przy użyciu elementu stałofazowego (CPE), który w sposób dokładniejszy odzwierciedla wyniki eksperymentalne niż klasyczny element pojemnościowy (kondensator). W pracy zaproponowano nowy elektryczny obwód zastępczy oparty na modelu adsorpcyjnym Frumkin-Melik-Gaikazyan,...
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Cementite transformation in low carbon steel under the influence of sulphur.
PublicationBadano cementyt (węglik Fe3C) w przemysłowym gatunku stali niskowęglowej po długotrwałej eksploatacji w benzynie ciężkiej, zawierającej 0,3 ppm siarki, o temperaturze 200-220C. Wykazano, że cementyt na powierzchni i we wnętrzu stali ulega przemianie w niestabilną, quasi-krystaliczną fazę wzbogaconą w siarkę i pierwiastki domieszkowe a zubożoną w żelazo. Przemiana cementytu i rozpad zdegradowanej fazy związana jest z uwolnieniem...
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Parametrical Method for Determining Optimal Ship Carrying Capacity and Performance of Handling Equipment
PublicationThe paper presents a method of evaluating the optimal value of the cargo ships deadweight and the coupled optimal value of cargo handling capacity. The method may be useful at the stage of establishing the main owners requirements concerning the ship design parameters as well as for choosing a proper second hand ship for a given transportation task. The deadweight and the capacity are determined on the basis of a selected economic...
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Possible effects of the 1984 St. Clair River ice jam on bed changes
PublicationThis study examines the possible effect of the record ice jam of 1984 in the St. Clair River on river bed changes and conveyance. Numerical simulations were made to examine the flow and bed shear stresses during the jam formation and release periods. Simulation results indicate that the ice jam in the river did not cause a significant increase in bed shear stress compared to pre- and post-jam open water conditions. The insignificant...
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Dynamic Electrochemical Impedance Spectroscopy (DEIS) as a Tool for Analyzing Surface Oxidation Processes on Boron-Doped Diamond Electrodes
PublicationSurface oxidation processes play a key role in understanding electrochemical properties of boron-doped diamond (BDD) electrodes. The type of surface termination groups, which create the potential window of electrolytic water stability or hydrophobicity, influences such properties. In this study the kinetics of oxidation process under anodic polarization were studied in situ by means of Dynamic Electrochemical Impedance Spectroscopy...
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Application of gas chromatography to the analysis of spirit-based alcoholic beverages
PublicationSpirit-based beverages are alcoholic drinks, which production processes are dependent on the type and origin of raw materials. The composition of this complex matrix is difficult to analyze and scientists commonly choose a gas chromatography techniques for this reason. With a wide selection of extraction methods and detectors it is possible to provide qualitative and quantitative analysis for many chemical compounds with a various...
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THE INFLUENCE OF GESTALT THEORY ON ERNST CASSIRER’S PHENOMENOLOGY OF SYMBOLIC FORMS
PublicationIn the opinion of many scholars the notion of symbolic pregnancy is one of the key concepts in Ernst Cassirer’s philosophy of symbolic forms. Without a proper under-standing of its conceptual frame Cassirer’s philosophy lacks a consistent foundation. The notion symbolic pregnancy offers the mechanism of distinction of symbolic forms. The newest investigations (also in unpublished or less known, neglected writings of the philosopher)...
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Carbon dioxide photoconversion. The effect of titanium dioxide immobilization conditions and photocatalyst type.
PublicationBadanie efektywności procesu fotokonwersji CO2 prowadzono w fazie gazowej w obecności promieniowania UV-Vis, pary wodnej oraz fotokatalizatorów. Zbadano wpływ wybranych parametrów tj. masa, temperatura i czas suszenia fotokatalizatora oraz rodzaj nośnika na efektywność procesu fotokonwersji. Wyznaczono optymalne parametry prowadzenia procesu oraz przedstawiono wstępne wyniki badań w obecności fotokatalizatorów modyfikowanych nanoczastkami...
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Directed electromagnetic pulse dynamics: projecting operators method
PublicationIn this article, we consider a one-dimensional model of electromagnetic pulse propagation in isotropic media, takinginto account a nonlinearity of the third order. We introduce a method for Maxwell's equation transformation on thebasis of a complete set of projecting operators. The operators correspond to wave dispersion branches including thedirection of propagation. As the simplest result of applying the method, we derive a system...
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The control software of the portable raman spectrometer
PublicationThe paper contains a description of the control software of a portable Raman spectrometer which was built in the Department of Optoelectronics and Electronic Systems Faculty of Electronics, Telecommunications and Informatics Gdansk University of Technology. The software has modular structure, which includes the laser control module and the spectrum acquisition module (laser power selection, working mode and data acquisition time)...
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Koncepcja stanowiska oraz badania możliwości bezpompowego przetłaczania czynnika w rurce ciepła z pętlą obiegową. Część I - Wstęp-charakterystyka obiegu LHP
PublicationBezpompowa cyrkulacja czynnika roboczego występuje w rurkach ciepła z pętlą obiegową (LHP, ang. Loop Heat Pipe). Rurki ciepła oparte na pętli, to urządzenia dwufazowe służące do transportu ciepła, wykorzystujące grawitacyjne i kapilarne siły do wzbudzania obiegu czynnika roboczego. LHP stało się bardzo obiecującym urządzeniem, możliwym do wykorzystania w różnego rodzaju zaawansowanych urządzeniach pracujących naziemnie. W pierwszej...
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Water uptake in protective organic coatings and its reflection in measured coating impedance
PublicationWater uptake in commercially available epoxy coating on mild steel using impedance spectroscopy and gravimetry was studied. The water content in the coating was determined using the Brasher-Kingsbury equation and various methods of coating capacitance calculation used in the literature. The obtained results were compared with reference gravimetric data. An overestimation of values obtained from impedance data in relation to gravimetric...
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Different Ways to Apply a Measurement Instrument of E-Nose Type to Evaluate Ambient Air Quality with Respect to Odour Nuisance in a Vicinity of Municipal Processing Plants
PublicationThis review paper presents different ways to apply a measurement instrument of e-nose type to evaluate ambient air with respect to detection of the odorants characterized by unpleasant odour in a vicinity of municipal processing plants. An emphasis was put on the following applications of the electronic nose instruments: monitoring networks, remote controlled robots and drones as well as portable devices. Moreover, this paper presents...
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The effect of cable duct diameter on the ampacity of high-voltage power cables
PublicationThe ampacity of power cables depends, among others, on the conditions of heat dissipation from the cable to the environment. Cables are usually laid directly in the ground, but in some sections, they may be placed in ducts, which adversely affects the ampacity of the cable line. The paper presents heat transfer phenomena for cables installed in pipe-type ducts filled with air. The effect of cable duct diameter on this ampacity...
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Computational Fluid Dynamics Simulation of Gas–Liquid Multiphase Flow in T-junction for CO2 Separation
PublicationThe article presents the results of a computational fluid dynamics (CFD) analysis of gas-liquid multiphase flow. The simulation was conducted using CFD code and the Euler–Euler approach. The presented study relates to the non–reactive, steady-state, turbulent flow of water and carbon dioxide mixture in a 3D pipe. Separation phenomenon between phases is observed. The solution was obtained using a mixture model. Different values...
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Gas sensors based on conducting polymers-recent developments
PublicationThis work discusses sensing performance dependence of PEDOT polymer and its composites on the counter ions used in the polymerization process. The sensors based on PEDOT-RGO composite show reversible response to NO2, while on PEDOT/LiClO4 irreversible. As a result, PEDOT-RGO could be used as a typical gas sensor, while sensor based PEDOT/LiClO4 could be used as an integrating gas sensor, also known as an accumulating gas sensor....
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Wymiary klimatu pracy zespołowej
PublicationArtykuł prezentuje koncepcje klimatu pracy zespołowej jako determinanty zespołowej efektywności i innowacyjności. Zaprezentowano sześć modeli klimatu pracy zespołowej i przeanalizowano główne wymiary klimatu, opracowując na tej podstawie nowy, 5-wymiarowy model, który obejmuje: wsparcie oparte na zaufaniu, popieranie innowacji,odpowiedzialność, wizja i motywacja. Pokazano również kilka narzędzi do pomiaru klimatu pracy zespołowej.
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Actions of a nitric oxide donor on prostaglandin production and angiogenic activity in the equine endometrium
PublicationNitric oxide (NO) plays an important role in prostaglandin secretion and angiogenesis in the reproductive system. In the present study, the roles of the NO donor spermine NONOate and tumour necrosis factor-alpha (TNF; as a positive control) in prostaglandin production and angiogenic activity of equine endometria during the oestrous cycle were evaluated. In addition, the correlation between NO production...
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Electrical characterization of diamond/boron doped diamond nanostructures for use in harsh environment applications
PublicationThe polycrystalline boron doped diamond (BDD) shows stable electrical properties and high tolerance for harsh environments (e.g. high temperature or aggressive chemical compounds) comparing to other materials used in semiconductor devices. In this study authors have designed electronic devices fabricated from non-intentionally (NiD) films and highly boron doped diamond structures. Presented semiconductor devices consist of highly...
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Uptake, accumulation, and translocation of Zn, Cu, Pb, Cd, Ni, and Cr by P. australis seedlings in an urban dredged sediment mesocosm: impact of seedling origin and initial trace metal content
PublicationThe study presents results from 6 months of phytoremediation of sediments dredged from three urban retention tanks carried out in a mesocosm setup with the use of P. australis. Two kinds of P. australis seedlings were considered: seedlings originating from natural (uncontaminated - Suncont) and anthropogenically changed environments (contaminated – Scont); this distinction was reflected in the baseline concentrations of trace metals...
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Dimensionality-Reduced Antenna Modeling with Stochastically Established Constrained Domain
PublicationOver the recent years, surrogate modeling methods have become increasingly widespread in the design of contemporary antenna systems. On the one hand, it is associated with a growing awareness of numerical optimization, instrumental in achieving high-performance structures. On the other hand, considerable computational expenses incurred by massive full-wave electromagnetic (EM) analyses, routinely employed as a major design tool,...
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Zastosowanie techniki GC-FPD do oznaczania związków cynoorganicznych w próbkach osadów dennych pobranych w morskim porcie Gdańsk oraz w morskim porcie Gdynia
PublicationObecność tributylocyny (TBT-tributyltin) w osadach morskich, a w szczególności w osadach portowych wynika głównie z zastosowania tego związku w farbach do zabezpieczania kadłubów statków przed porastaniem przez florę i faunę morską. Związek ten uwolniony do środowiska wodnego ulega kumulacji głównie w osadach dennych. Wydobywanie lub przemieszczanie tych osadów w trakcie prac pogłębieniowych może prowadzić do poważnych zagrożeń...
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Does one currency mean one price?
PublicationEuropean Monetary Union was expected to have many consequences for the economies of participant countries. Theory suggested that through a higher volume of trade and stronger competition in the Eurozone, a single currency would lead to a reduction in price dispersion. As far as prices are concerned, two effects were expected: an immediate effect due to the technical characteristics of the changeover process, and a long-term one...
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LSA Is not Dead: Improving Results of Domain-Specific Information Retrieval System Using Stack Overflow Questions Tags
PublicationThe paper presents the approach to using tags from Stack Overflow questions as a data source in the process of building domain-specific unsupervised term embeddings. Using a huge dataset of Stack Overflow posts, our solution employs the LSA algorithm to learn latent representations of information technology terms. The paper also presents the Teamy.ai system, currently developed by Scalac company, which serves as a platform that...
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Solid phase extraction technique - trends, opportunities and applications
PublicationW pracy opisano wykorzystanie ekstrakcji do fazy stałej w chemii analitycznej. Ekstrakcja do fazy stałej może być przydatna nie tylko do izolacji i wzbogacania analitów z fazy wodnej, ale również do wymiany matrycy oraz oczyszczania ekstraktu. Stosowane sorbenty są analogiczne do stosowanych w chromatografii cieczowej. Omówione zostały: mechanizmy ekstrakcji, sposoby przeprowadzania ekstrakcji (kolumienki, krążki, pipety), rodzaje...
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Analogues of trypsin inhibitor SFTI-1 modified in the conserved P1′ position by synthetic or non-proteinogenic amino acids retain their inhibitory activity
PublicationA series of linear and monocyclic (with a disulfide bridge only) analogues of trypsin inhibitor SFTI-1 modified in the P-1 and/or P-1' positions were synthesized by the solid-phase method. In the substrate specificity P-1 position, Phe or N-benzylglycine (Nphe) were introduced, whereas the conserved Ser6 in Bownam-Birk (BBI) inhibitors was replaced by Hse (L-homoserine), Nhse [N-(2-hydroxyethyl)glycine], Sar, and Ala. Kinetic studies...
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3D Sound Intensity Measurement Around Organ Pipes Using Acoustic Vector Sensors
PublicationThe aim of the presented paper was to obtain and visualize sound intensity distribution of radiated acoustic energy around the organ pipes. The experimental setup consisted of the multichannel acoustic vector sensor and the specialized Cartesian robot. Measurements were performed in free field with spatial resolution of 0.1 [m]. Two organ pipes, i.e. wooden and metal were measured during the ex-periment. The organ pipes were activated...
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The effect of current signal filtering method on the value of cutting power while sawing wood
PublicationThe goal of this work was to investigate an effect of various signal pre-processings on the outline of the electrical power curve and its influence on the measured cutting force estimation. Two signal processing methods were selected for the needs of the experiment, including digital filter and wavelet transform. The filter used was Butterworth, 3rd order band-stop with the cut-out band from 45 Hz to 55 Hz. The second approach...
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Employing a biofeedback method based on hemispheric synchronization in effective learning
PublicationIn this paper an approach to build a brain computer-based hemispheric synchronization system is presented. The concept utilizes the wireless EEG signal registration and acquisition as well as advanced pre-processing methods. The influence of various filtration techniques of EOG artifacts on brain state recognition is examined. The emphasis is put on brain state recognition using band pass filtration for separation of individual...
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Quechers sample preparation method variants for analysis of pesticide residues in fruits and vegetables
PublicationThis article describes the comparison of different versions of an easy, rapid and low-cost sample preparation approach for the determination of pesticide residues in fruits and vegetables by concurrent use of gas and liquid chromatography coupled to MS or ECD for detection. The sample preparation approach is known as QuEChERS, which stands for quick, easy, cheap, effective, rugged and safe. It is a combination of liquid-liquid...
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Operational problems of constructed wetland for landfill leachates treatment: case study
PublicationIn the paper the quality fluctuations of leachate from municipal landfill in Gdansk (Poland) over the last 5 years and evaluation of a wetland system designed for treatment of the leachate are discussed.The research has been conducted during the 5 years period. The constructed wetland for leachate treatment, consisting of 2 horizontal subsurface flow reed beds, working in parallel was built in 2001. In the period 2005-06 it underwent...
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Photoconversion of carbon dioxide to methane and light hydrocarbons
PublicationFotokonwersja ditlenku węgla do lekkich węglowodorów jest czystym i przyjaznym dla środowiska procesem, pozwalającym na obniżenie emisji CO2 przy jednoczesnym generowaniu paliwa. Badanie efektywności procesu fotokonwersji CO2 prowadzono w obecności promieniowania UV-Vis, pary wodnej oraz fotokatalizatorów Ag-TiO2, Au-TiO2, Ag/Au-TiO2 otrzymanych w mikroemulsji woda/AOT/cykloheksan. Najwyższą aktywność w procesie fotoredukcji...
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MACHINE LEARNING SYSTEM FOR AUTOMATED BLOOD SMEAR ANALYSIS
PublicationIn this paper the authors propose a decision support system for automatic blood smear analysis based on microscopic images. The images are pre-processed in order to remove irrelevant elements and to enhance the most important ones - the healthy blood cells (erythrocytes) and the pathologic (echinocytes). The separated blood cells are analyzed in terms of their most important features by the eigenfaces method. The features are the...
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Reference-free determination of debonding length in reinforced concrete beams using guided wave propagation
PublicationThis paper presents theoretical and experimental investigations of guided wave propagation in reinforced concrete beams, with pre-existing debonding between steel rebars and concrete blocks, for the purpose of damage detection. The primary aim of these investigations was a detailed analysis of the possible applications of wave propagation in single and multiple debonding detection in reinforced concrete structures and reference-free...
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Application of non-metal doped titania for inverted polymer solar cells
PublicationDomieszkowany jodem oraz domieszkowany jodem ditlenek tytanu uzyto jako warstwę buforową w ogniwie ITO/X-TiO2?P3HT-PCMB /MnO2/ Ag.Warswty X-TiO2 nalożono metodą spin-coatingu z zawiesiny nanocząstek w DMSO. Jednorodne struktury scharakteryzowane pod względem morfologii mikroskopowo metodą AFM. Charakterystyka prądowo-napięciowa urzdzeń wskazuje iż domieszkowany jodem TiO2 pozwala osiągnąć lepsze parametry PCE (1,67%) i prąd zwarcia...