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Search results for: acridinium esters
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Thermoplastic polyurethanes derived from petrochemical or renewable resources: A comprehensive review
PublicationThermoplastic polyurethanes (TPUs) materials are obtained by the reaction of polyol (ether-, ester-, and carbonate-based diols with average molecular weight in the range from 1,000 to 3,000 g/mol) with aliphatic or aromatic diisocyanates. Synthesized materials consist of the hard and soft segments which are separated in different level. All mechanical and thermal properties of TPUs depend on the chemical structure of used monomers,...
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Performance of Coherent Modulation Scheme Used in Acoustic Underwater Communication System
PublicationThe development of an acoustic underwater communication system for shallow waters is still a big scientificand construction challenge. Currently, non-coherent modulations in combination with strong channel coding are used to achieve reliable communication with low rate in such a channel. To obtain transmission with a higher transmission rate, it is required to use coherent modulation. This paper presents the assumptions of such...
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The demand for skills and the labor cost in partner countries: evidence from the enlarged EU
PublicationWe analyse the consequences of trade integration in Europe (1995-2005) detecting how thelabor costs in partner countries affects the demand for domestic high- and low-skilled labor inthe EU-15 (Old) and five New member states. In general, independently on the skill level, the resultshint at complementarity between domestic and foreign labor. However, the demand for thehigh skilled in New EU members' low skill intensive sectors...
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Badanie wpływu rodzaju obciążeń testujących na wytrzymałość zmęczeniową stopu łożyskowego
PublicationPrzedstawiono wyniki badań nad wytrzymałością zmęczeniową warstwy ślizgowej dwuwarstwowej taśmy łożyskowej wykonanej ze stopu AlSn11,3Cu1,2. Badania przeprowadzono za pomocą testera SKMR-1. Przedstawiono metodykę badań, zaobserwowane pęknięcia zmęczeniowe badanych próbek oraz oszacowano odpowiadające im krytyczne wartości naprężeń w warstwie ślizgowej. Porównano i przeanalizowano wartości naprężeń generowanych w próbkach przy różnych...
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Proposed concept for the development of residential floating facilities
PublicationCurrently, a dynamic growth of interest in residential buildings located on the water can be observed in Poland. However, the lack of legal regulations, the increase in society's affluence and overpopulation in city centers lead to reflection on the development strategy that should be implemented for maritime construction. The publication presents a proposal of four development strategy concepts: aggressive,...
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Underwater acoustic communication system using broadband signal with hyperbolically modulated frequency
PublicationThe implementation of reliable acoustic underwater communication in shallow waters is a scientific and engineering challenge, mainly due to the permanent occurrence of the multipath phenomenon. The article presents the concept of a transmission system using a broadband signal with hyperbolically modulated frequency (HFM) to transmit data symbols and synchronize data frames. The simulation tests were carried out in channels with...
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Monitoring of underdeck corrosion by using acoustic emission method
PublicationThis paper presents first short characteristics of underdeck corrosion process as well as a problem of its monitoring. Next is described an acoustic emission (AE) method elaborated by Department of Ship Technology , Quality Systems and Material Engineering, Gdańsk University of Technology in cooperation with partners of CORFAT project realized within 7th EU Frame Program . Further are presented short characteristics of the emission...
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Występowanie bakterii siarkowych a jakość wód podziemnych ujęcia Osowa
PublicationAbstrakt. Microorganisms that live in groundwater should be considered not only from the sanitary-hygienic point of view but also in terms of adverse changes in groundwater chemistry in the aquifer layer and its negative influence on the installed devices. For these reasons, it is important to correct approach to the problem of bacterial contamination of groundwater. The paper presents selected results of physicochemical and bacteriological...
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Changes in Manufacturing Industries- an Empirical Verifiction of the Kaldor-Verdoorn Laws
PublicationThis paper focus on showing the importance of manufacturing industry for the growth of selected european countries from a kaldorian perspective. the author discusses and testes two (the first and the second) kaldor-verdoorn laws, which state that manufacturing is the engine of growth (the first law) and that exist positive relation between labour productivity and output in manufacturing industries because of increasing returns...
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Porphyrazines Peripherally Functionalized with Hybrid Ligands as Molecular Scaffolds for Bimetallic Metal-Ion Coordination
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Spatiotemporal dynamics of the active perirheic zone in a natural wetland floodplain
PublicationAbstract The ecologically and biogeochemically significant perirheic zone is a part of the floodplain where waters originating from both the river and adjacent floodplain are present. In this study, we investigate the spatiotemporal dynamics of the active perirheic zone, i.e. river and floodplain waters and their transient mixing extent. This is achieved by using the Hydraulic Mixing-Cell method, a complement to a fully integrated...
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An analytical four-layer horizontal electric current dipole model for analysing underwater electric potential in shallow seawater
PublicationThe paper presents a new analytical four‑layer (air–water–bottom–non‑conductive layer) horizontal electric dipole model which allows an accurate approximation of ship’s Underwater Electric Potential (UEP) from a sufficient depth in shallow coastal marine waters. The numerical methods, usually Finite Element Method (FEM) or Boundary Elements Method (BEM), are typically used to estimate the electric field and the distribution of...
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Organic Supercritical Thermodynamic Cycles with Isothermal Turbine
PublicationOrganic Rankine cycles (ORC) are quite popular, but the overall efficiencies of these plants are rather very low. Numerous studies have been conducted in many scientific centers and research centers to improve the efficiency of such cycles. The research concerns both the modification of the cycle and the increase in the parameters of the medium at the inlet to the turbine. However, the efficiency of even these modified cycles rarely...
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Renewable Resources for Polyurethanes and Polyurethane Composites: A Review
PublicationEach year, more than two million tons of polyurethane is produced in the EU by reacting isocyanates with polyols made from fossil fuel. In addition, there are appreciable quantities of petroleum based functional additives applied in the industry nowadays for both polyols and polyurethane materials. It is therefore of key importance to develop sustainable economically viable polyols with enhanced functionalities, and thereby reducing...
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Molecularly imprinted polymers based on deep eutectic solvents as a greenest materials for selective extraction of emerging contaminants from complex samples
PublicationSome of the reagents applied in the synthesis of molecularly imprinted polymers (MIPs) may impact on health and the environment. Thus, a new generation of promising green chemicals are nowadays introduced and investigated, including deep eutectic solvents (DESs). DESs seems to be a reasonable choice as they are characterized as non-toxic, low cost, easy to prepare and biodegradable chemicals. This review presents the information...
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Enhancing environmental literacy through urban technology-based learning. The PULA app case
PublicationThis study addresses the need to enhance environmental literacy, focusing on urban adults through mobile applications, based on the example of PULA app that engages early adopters in gamified pro- environmental activities, offering insights into informal learning. Grounded in 'urban pedagogy,' the study combines semi-structured interviews with 17 application testers and quantitative data analysis, unveiling motivations, user feedback,...
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The chapter analyses the K-Means algorithm in its parallel setting. We provide detailed description of the algorithm as well as the way we paralellize the computations. We identified complexity of the particular steps of the algorithm that allows us to build the algorithm model in MERPSYS system. The simulations with the MERPSYS have been performed for different size of the data as well as for different number of the processors used for the computations. The results we got using the model have been compared to the results obtained from real computational environment.
PublicationThe chapter analyses the K-Means algorithm in its parallel setting. We provide detailed description of the algorithm as well as the way we paralellize the computations. We identified complexity of the particular steps of the algorithm that allows us to build the algorithm model in MERPSYS system. The simulations with the MERPSYS have been performed for different size of the data as well as for different number of the processors used...
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SatBałtyk – A Baltic environmental satellite remote sensing system – an ongoing project in Poland. Part 2: Practical applicability and preliminary results**This work was carried out within the framework of the SatBałtyk project funded by the European Union through European Regional Development Fund, (contract No. POIG.01.01.02-22-011/09 entitled ‘The Satellite Monitoring of the Baltic Sea Environment’) and also as a part of IO PAS’s statutory research.The paper was presented in part at the 6th International Conference ‘Current Problems in the Optics of Natural Waters’, St. Petersburg, Russia, 6–10 September 2011.
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SatBałtyk – A Baltic environmental satellite remote sensing system – an ongoing project in Poland. Part 1: Assumptions, scope and operating range**This work was carried out within the framework of the SatBałtyk project funded by the European Union through European Regional Development Fund, (contract No. POIG.01.01.02-22-011/09 entitled ‘The Satellite Monitoring of the Baltic Sea Environment’) and also as a part of IO PAS’s statutory research.The paper was presented in part at the 6th International Conference ‘Current Problems in the Optics of Natural Waters’ St. Petersburg, Russia, 6–10 September 2011.
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Synteza, struktura chemiczna i właściwości bezizocyjanianowych poliuretanów otrzymywanych z wykorzystaniem CO2 oraz surowców pochodzenia naturalnego.
PublicationZ uwagi na wciąż rosnącą świadomość proekologiczną, politykę zrównoważonego rozwoju, a także nurt zielonej chemii wiodącym trendem w przemyśle tworzyw sztucznych jest poszukiwanie alternatywnych metod otrzymywania materiałów polimerowych. Komercyjnie poliuretany otrzymywane są w wyniku reakcji poliaddycji di- lub poliizocyjanianów z poliolami i małocząsteczkowymi przedłużaczami łańcucha. Z uwagi na niekorzystne właściwości diizocyjanianów,...
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The conditions of the business services sector in Poland and its competitiveness in the global market
PublicationThe following article presents the conditions of the business services sector (BSS) in Poland and the assessment of its competitiveness in the global market. The first section discusses the BSS sector and the categories of the provided services, in the division of business process outsourcing, shared services center, information technology outsourcing, research and development. Next the authors presents the status of the business...
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Maritime heritage of small port towns of the Polish coast
PublicationThe article describes problems of the gradual disappearance of real maritime heritage in small Polish port cities. The maritime heritage of small port cities was shaped by coastal processes and urban historical conditions what has led to creation of specific types of landscapes. Special architectural objects of the post-port heritage of small ports of the Polish coast are hydrotechnical constructions (i.e. breakwaters, quays),...
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Die Sandgrube „Köplitz“ – ein interessanter geologischer Aufschluss am Nordwestrand der Schmiedeberger Stauchendmoräne
PublicationDie Kiessandgrube Köplitz ermöglicht einen Einblick in die komplizierten, durch glazidynamische Überprägung gekennzeichneten geologischen Lagerungsverhältnisse im Bereich der Schmiedeberger Stauchendmoräne. Anhand neuer Geländedokumentationen wird ein kleiner Eindruck vom komplizierten injektiven „Fließfalten-Schuppenbau“ der Stauchendmoräne vermittelt. Die steil aufgerichteten, aus tertiären (Untermiozän bis Oligozän) und quartären...
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Chromogenic macrocyclic derivatives of azoles - synthesis and properties,
PublicationNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
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Azomacrocyclic derivatives of imidazole: synthesis, structure, and metal ion complexation properties
PublicationNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
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Nowe stanowiska Dicranum viride (Dicranaceae) w północno-wschodniej Polsce na tle jego rozmieszczenia w województwie podlaskim
PublicationDicranum viride (Sull. & Lesq.) Lindb. is a rare moss species from the Dicranaceae family. It is strictly protected in Poland and is considered as a relic of primeval forests. The plant is also included in Annex II of the Natura 2000 Habitats Directive and Annex I of the Bern Convention. Its populations are threatened by habitat fragmentation and economic use of forest...
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Removal of sulfur from a solvent extract
PublicationThe presence of sulfur in a solvent extract that is to be analyzed chromatographically impairs and sometimes precludes properinterpretation of the chromatogram, as the sulfur peak masks the peaks of other compounds present in the sample, and sulfur alsodisrupts the operation of the mass detector. This means that discrepancies in the results can lead to erroneous interpretations andfalse assessments of environmental risk. For this...
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Badanie wpływu wybranych czynników na wytrzymałość zmęczeniową stopu łożyskowego
PublicationPrzedstawiono wyniki badań nad wytrzymałością zmęczeniową warstwy ślizgowej ze stopu AlSn11Cu1,2 w środowisku oleju silnikowego Selektol Special przy różnych wartościach temperatury i obciążeniach odpowiadających różnym wartościom współczynnika stałości obciążenia κ. Badania przeprowadzono za pomocą testera SKMR-2. Przedstawiono metodykę badań, zaobserwowane pęknięcia zmęczeniowe badanych próbek oraz oszacowano odpowiadające im...
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Effect of the let-through energy of overcurrent protective devices on the temperature of conductors during short-circuits
PublicationThe scope of the verification of low-voltage systems covers the earth fault loop impedance measurement. This measurement is usually performed with the use of low-value current meters, which force a current many times lower than the one occurring during a real short-circuit. Therefore, the international standard recommends consideration of the increase of resistance of conductors with the increase of temperature, which may occur...
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In situ transformation boosts the pseudocapacitance of CuNi-MOF via cooperative orientational and electronic governing
PublicationThe disordered arrangement and thereof inferior conductivity of 2D MOF sheets seriously hinder their practical application. Herein, we propose in situ transformation strategy to architect vertically oriented bimetallic CuNi-MOF as a self-supporting electrode, leading to a decuple high specific capacitance of 1262 C g-1 in comparison with the pristine Ni-MOF powder of 114 C g-1 at 2 A g-1. DFT calculations reveal that introduction...
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Efektywność naukowa uczelni publicznych
PublicationArtykuł prezentuje kluczowe wnioski z badań będących podstawą raportu "Produktywnośćnaukowa wyższych szkół publicznychw Polsce. Bibliometryczna analizaporównawcza''. W badaniu przeanalizowano grupę291 europejskich uczelni publicznychw latach 1995-2008. W badaniu ujęto34 uczelnie z Polski (uniwersytety orazpolitechniki), porównując ich aktywnośćpublikacyjną do szkół wyższych z Austrii,Finlandii, Niemiec, Włoch, Szwajcariii Wielkiej...
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EGNOS-based GNSS receiver for precise positioning in restricted areas
PublicationPositioning accuracy is very important in many areas, whereas the typical GPS receiver accuracy is often not sufficient. The European Geostationary Navigation Overlay Service (EGNOS), Europe’s first venture into satellite navigation, improves the open public service offered by the Global Positioning System (GPS). As a satellite navigation augmentation system, EGNOS improves the accuracy of GPS by providing a positioning accuracy...
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Lead(II)-selective ionophores for ion-selective electrodes: A review
PublicationIn potentiometry, high selectivity of the ion-selective membranes must be assured in order to reliably measure various analytes in clinical, industrial and environmental samples. Due to the toxic nature of lead(II) it is important to monitor Pb2+ distribution in natural waters. This may be achieved by implementation of ion-selective electrodes (ISEs) with high selectivity towards lead(II) and low detection limit. A great number...
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Diagnostyka analogowych filtrów wielosekcyjnych oparta na magistrali testującej IEEE1149.1
PublicationPrzedstawiono nową koncepcję testera JTAG BIST do samo-testowania torów analogowych opartych na wielosekcyjnych filtrach wyższego rzędu w mieszanych sygnałowo mikrosystemach elektronicznych sterowanych mikrokontrolerami i wyposażonych w magistralę testującą IEEE1149.1 (JTAG). Bazuje ona na metodzie diagnostycznej opartej na przekształce-niu transformującym próbki odpowiedzi czasowych kolejnych sekcji filtra pobudzonego impulsem...
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Flood risk assessment for office and services building Alchemia II at Al. Grunwaldzka 409 in Gdansk.
PublicationThe aim of the study is to assess the risk of flood from natural meteorological and hy-drological phenomena, for office and services building Alchemia II in Gdansk at Al. Grun-waldzka 409. The project includes the analysis of potential sources of floods in Gdansk re-garding the Baltic Sea and the Gulf of Gdansk, the Vistula River basin and excessive rainfall and snowmelt waters being a significant element of hydrological processes...
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Wake-Up Receiver for Underwater Acoustic Communication Using in Shallow Water
PublicationA data frame transmitted over the underwater acoustic channel usually begins with a preamble. Therefore, underwater communication systems have a dedicated receiver that constantly listens to the preamble signals. A receiver that is to work effectively in shallow waters must have solutions that effectively reduce the impact of the permanently occurring multipath propagation. The article presents a solution based on complementary...
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Auto-tuning methodology for configuration and application parameters of hybrid CPU + GPU parallel systems based on expert knowledge
PublicationAuto-tuning of configuration and application param- eters allows to achieve significant performance gains in many contemporary compute-intensive applications. Feasible search spaces of parameters tend to become too big to allow for exhaustive search in the auto-tuning process. Expert knowledge about the utilized computing systems becomes useful to prune the search space and new methodologies are needed in the face of emerging heterogeneous...
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Recycling of Polyurethanes Containing Flame-Retardants and Polymer Waste Transformed into Flame-Retarded Polyurethanes
PublicationThe growing number of polyurethanes (PUs) produced every year has developed methods for their mechanical and chemical recycling which yield valuable products like substitutes for commercial polyols or flame-retardants. PUs can be produced in different shapes and forms (i.e., elastomers, flexible or rigid foams, coatings, etc.) using several different components (i.e., di- or polyisocyanates, ester- or ether-based polyols, low-molecular...
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Zintegrowane działania komunikacyjne w internecie na przykładzie marki Żywiec Zdrój Smako-Łyk
PublicationArtykuł ma na celu ukazanie przykładów angażowania polskich internautów w kampanie komunikacji marketingowej realizowane dla marki Żywiec Zdrój Smako-Łyk. Analizie poddano treści odnoszące się bezpośrednio do marki oraz wybranych kampanii online prowadzonych w latach 2009–2015. W ostatnich latach w Polsce można obserwować coraz więcej kampanii wykorzystujących potencjał, jaki mają w sobie internauci. Cenne pomysły można pozyskać...
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Analyzing the Impact of Simulated Multispectral Images on Water Classification Accuracy by Means of Spectral Characteristics
PublicationRemote sensing is widely applied in examining the parameters of the state and quality of water. Spectral characteristics of water are strictly connected with the dispersion of electromagnetic radiation by suspended matter and the absorp-tion of radiation by water and chlorophyll a and b.Multispectral sensor ALI has bands within the ranges of electromagnetic radia-tion: blue and infrared, absent in sensors such as Landsat, SPOT,...
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Shallow Water Experiment of OFDM Underwater Acoustic Communications
PublicationThe large variability of communication properties of underwater acoustic channels, and especially the strongly varying instantaneous conditions in shallow waters, is a challenge for the designers of underwater acoustic communication (UAC) systems. The use of phase modulated signals does not allow reliable data transmission through such a tough communication channel. However, orthogonal frequency-division multiplexing (OFDM), being...
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The Efficiency of Post‐Communist Countries’ Health Systems
PublicationHealth‐care costs are a major financial burden for the transition economies, which have experienced rapidly increasing demand for health‐care services. The former communist countries of the Central and Eastern Europe and Central Asia needed to reform the financing of their health‐care systems and make efforts to strengthen the role of primary care while limiting the role of hospital care. The growing health needs and, consequently,...
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Estimating the uncertainty of the liquid mass flow using the orifice plate
PublicationThe article presents estimation of measurement uncertainty of a liquid mass flow using the orifice plate. This subject is essential because of the widespread use of this type of flow meters, which renders not only the quantitative estimation but also qualitative results of this type so those measurements are important. To achieve this goal, the authors of the paper propose to use the theory of uncertainty. The article shows the...
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Identification of diagnostic parameter sensitivity during dynamic processes of a marine engine
PublicationChanging some parameters of the engine structure alters the emission of harmful components in the exhaust gas. This applies in particular to the damage of charge exchange system as well as fuel system and engine supercharger. These changes are much greater during the dynamic states and their accompanying transitional processes. The different sensitivity of diagnostic parameters to the same force, coming from the engine structure, but...
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Stimulated by cyclodextrins high yield synthesis of azocrown analogues comprising pyrrole or imidazole residues
PublicationThe influence of cyclodextrins (CDs) on the formation of azocrown ethers comprising pyrrole, imidazole and substituted imidazole has been studied. Pyrrole, imidazole, 2-methyl-, 4-methyl- and 4-phenylimidazole were coupled with bisdiazonium salts derived from bis-1,5-(2-aminophenoxy)-3-oxapentane or bis-1,8-(2-aminophenoxy)-3,6-dioxaoctane to form macrocyclic compounds with two azo units. The syntheses were performed under standard...
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Calix[4]arene-Thioamides as Ionophores for Transition and Heavy Metal cations
PublicationCalix[4]arene derivatives play an important role as sensing materials in Ion Selective Electrodes(ISEs). Nowadays a high impact is put to control in natural waters the level of toxic heavy metals, like Pb ,Cd, Hg or Cu which may cause the great risk to human health. Our goal was to design and to synthesize ligands possessing ability to bind transition and heavy metal cations. The synthesis, crystal structures,extractive and ionophoric...
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Modeling and simulation of tool cycle in manufacturing cell
PublicationThe paper addresses issues concerning modeling and analysis of tool flow within a three-machine manufacturing cell used for small batch manufacturing of a definite spectrum of prismatic parts. The approach utilizes a method for job and tool allocation to work centers with limited number of machines and capacity of tool resources, based on the analysis of formalized relations: job - tool sets required. Selected tool flow control...
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Wpływ smaru i wymuszeń mechanicznych i cieplnych na wytrzymałość zmęczeniową stopu łożyskowego
PublicationPrzedstawiono wyniki badań nad wytrzymałością zmęczeniową warstwy ślizgowej ze stopu AlSn11Cu1 w środowisku trzech olejów smarowych: bazowego, mineralnego i syntetycznego przy różnych wartościach temperatury i wymuszeniach mechanicznych odpowiadających różnym wartościom współczynnika stałości obciążenia κ. Badania przeprowadzono za pomocą testera SKMR-2. Przedstawiono metodykę badań, zaobserwowane pęknięcia zmęczeniowe badanych...
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Application of vertical flow cw for highly contaminated wastewater treatment
PublicationBasing on quantitative and qualitative characteristics of reject waters generated during digested sewage sludge dewatering on centrifuges in conventional WWTP (RWC) and municipal landfill leachate (LL), the pilot constructed wetlands for treatment of both types of highly contaminated wastewater were designed. In the paper the characteristics of the pilot plants and assumed treatment efficiencies are presented. According to the...
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The Chernobyl effect
PublicationThe 1986 Chernobyl catastrophe was not only a human and ecological disaster, but also a political-ideological one, severely discrediting Soviet governance and galvanizing dissidents in the Eastern Bloc. In the case of Poland, what began as isolated protests against the Soviet nuclear site grew to encompass domestic nuclear projects in general, and in the process spread across the country and attracted new segments of society. This...