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Search results for: IONIC LIQUID VISCOSITY TEMPERATURE QSPR EXPERIMENTAL
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Structure redetermination, transport and thermal properties of the YNi3Al9 compound
PublicationSingle crystals of completely ordered variant of the YNi3Al9 compound were grown by self-flux method with excess of aluminum. The crystal structure of the title compound was redetermined from single crystal X-ray diffraction data. The structure adopts ErNi3Al9 type, space group R32, parameters of the unit cell a = 7.2838(2) Å, c = 27.4004(8) Å. The growth of relatively large single crystals of the YNi3Al9 compound, having completely...
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Optimization of capillary isotachophoretic method for determination of major macroelements in blue honeysuckle berries (Lonicera caerulea L.) and related products
PublicationA reliable and repeatable isotachophoretic method for the simultaneous determination of K+, Na+, Ca2+, Mg2+ and ammonium in berries of different blue honeysuckle cultivars was developed. The usefulness of the complex-forming equilibria in determining the cations mentioned above was studied. The addition of 7.5 mM 18-crown-6 and 2 mM α-hydroxyisobutyric acid to sulfuric acid enhanced the separation capacity of the leading electrolyte....
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Temperature Evolution, Material Flow, and Resulting Mechanical Properties as a Function of Tool Geometry during Friction Stir Welding of AA6082
PublicationThe friction stir welding process was simulated for joining AA6082 aluminum alloy with the use of the computational fluid dynamics method. Two different tool geometries were used—a tapered cylindrical pin (simple pin) and a hexagonal pin with grooves (complex pin). The analysis of the simulations performed was discussed in terms of temperature evolution during the process, total heat input, residual stresses and material flow....
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Detection and Model of Thermal Traces Left after Aggressive Behavior of Laboratory Rodents
PublicationAutomation of complex social behavior analysis of experimental animals would allow for faster, more accurate and reliable research results in many biological, pharmacological, and medical fields. However, there are behaviors that are not only difficult to detect for the computer, but also for the human observer. Here, we present an analysis of the method for identifying aggressive behavior in thermal images by detecting traces...
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Optimizing conductivity in Na-V-Te-O glass through controlled heat treatment
PublicationSemiconducting Na2O-V2O5-TeO2 glasses with various Na2O contents were melted and subjected to controlled heating to improve conductivity. Topography analysis were performed using confocal microscopy and scanning electron microscopy on both as-quenched and heat-treated samples. X-ray diffraction confirmed the amorphous nature of the samples post-melting, with subsequent heating resulting in the formation of nanocrystallites primarily...
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Electrical properties of Na2O-CaO-P2O5 glasses doped with SiO2 and Si3N4
PublicationSodium-calcium-phosphate glasses doped with SiO2 or Si3N4 having similar sodium ion concentrations were prepared by melt quenching. The conductivity was measured by impedance spectroscopy under nitrogen atmosphere in a wide frequency range (10 mHz–1 MHz) and wide temperature range (153–473 K). At 36.6 °C, DC conductivities of all glasses vary between 1.1 ∗ 10−12 and 8.9 ∗ 10−12 S cm−1 and have similar activation energies (between...
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Study of oxygen electrode reactions on symmetrical porous SrTi0.30Fe0.70O3-δ electrodes on Ce0.8Gd0.2O1.9 electrolyte at 800 °C–500 °C
PublicationIron doped strontium titanates (SrTi1-xFexO3-δ) are an interesting mixed ionic-electronic conductor model used to study basic oxygen reduction/oxidation reactions. In this work, we performed an impedance spectroscopy study on symmetrical porous SrTi0.30Fe0.70O3-δ (STF70) electrodes on a ceriabased electrolyte. The sample was measured in varying oxygen concentration: from 0.3% to 100% in 800 °C - 500 °C temperature range. Low polarisation...
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Morphology control through the synthesis of metal-organic frameworks
PublicationDesignable morphology and predictable properties are the most challenging goals in material engineering. Features such as shape, size, porosity, agglomeration ratio significantly affect the final properties of metal- organic frameworks (MOFs) and can be regulated throughout synthesis parameters but require a deep under- standing of the mechanisms of MOFs formation. Herein, we systematically summarize the effects of the indi- vidual...
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Diagnosis of Damage in a Steel Tank Model by Shaking Table Harmonic Tests
PublicationThe aim of the present paper is to show the results of the shaking table experimental study concerning the diagnosis of damage in a model of cylindrical steel tank with self-supported roof which is filled with liquid. During the tests, the base of the structure was excited under the harmonic loading with variable frequency. The tests were repeated for different stages of damage, which was introduced in the model by easing the bolts...
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Performance of a hybrid microjet – microchannel cooling module
PublicationThe paper presents the experimental investigation of a microjet- microchannel cooling module. In which microjets of water are impinging into the microchannels and forming a liquid film on the impingement surface. Applied technology takes benefits from two very attractive heat removal techniques. When lminar jets are impinging on the surface have a very high kinetic energy at the stagnation point, also in microchannels boundary...
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Sample preparation procedure using extraction and derivatization of carboxylic acids from aqueous samples by means of deep eutectic solvents for gas chromatographic-mass spectrometric analysis
PublicationThe paper presents a new procedure for the determination of organic acids in a complex aqueous matrixusing ultrasound-assisted dispersive liquid–liquid microextraction followed by injection port derivati-zation and GC–MS analysis. A deep eutectic solvent (choline chloride: 4-methylphenol in a 1:2 mol ratio)was used both as an extracting solvent and as a derivatizing agent to yield ion pairs which were next con-verted to methyl...
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Dispersive liquid-liquid microextraction combined with gas chromatography–mass spectrometry for in situ determination of biogenic amines in meat: Estimation of meat's freshness
PublicationA dispersive liquid-liquid microextraction (DLLME) gas chromatography–mass spectrometry (GC–MS) technique was developed for the determination of selected biogenic amines (BAs) in samples of poultry, pork and beef. Prior to the extraction process, an appropriate volume of sodium hydroxide solution was added to each of the portioned samples. Next, samples were homogenized, centrifuged and finally sonicated at an increased temperature....
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A new procedure for the determination of distillation temperature distribution of high-boiling petroleum products and fractions
PublicationThe distribution of distillation temperatures of liquid and semi-fluid products, including petroleum fractions and products, is an important process and practical parameter. It provides information on properties of crude oil and content of particular fractions, classified on the basis of their boiling points, as well as the optimum conditions of atmospheric or vacuum distillation. At present, the distribution of distillation temperatures...
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Identification of damages in the inlet air duct of a diesel engine based on exhaust gas temperature measurements
PublicationThe temperature of the exhaust gas of a diesel piston engine, measured in the characteristic control sections of its thermo-flow system, can be a valuable source of diagnostic information about the technical condition of the elements limiting the working spaces thus separated, including the turbocharging system, but also its fuel supply system and replacement of the medium. In standard marine engine measurement systems equipped...
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Gasification of Densified Biomass (DB) and Municipal Solid Wastes (MSW) Using HTA/SG Technology
PublicationThe necessity of economical and rational use of natural energy sources caused a rapid development of research on the possibilities of using non‐conventional energy resources. Taking the above into account, a new technological process of thermochemical conversion of biomass and communal waste, commonly known as High Temperature Air/Steam Gasification (HTA/SG) and Multi‐Staged Enthalpy Extraction Technology (HTAG‐MEET), was developed....
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Natural convection in symmetrically heated vertical channels
PublicationThe study describes natural convection through a vertical channel, open on four sides and bound by two isothermal walls. Both balancing and infrared experimental investigations were performed in air (Pr = 0.71) to estimate the impact of channel width s and wall-to-ambient temperature difference (tw - t∞) on natural convective heat transfer, the formation of air flow patterns and the rate of flow pattern formation. The study was...
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Dynamic state assessment of the water turbine with the power of 600 kW
PublicationThe article discusses the results of experimental studies to assess the dynamic state of the turbine set with the Kaplan turbine. The dynamic assessment was made on the basis of appropriate standards, based on the measurement results of selected parameters of vibration, which have been measured for several states of the machine load. In addition, we attempted to identify the causes of the increased vibration levels based on the...
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Performance of the PVT solar collector operated with water-Al2O3 nanofluid
PublicationAn experimental investigation of the hybrid module photovoltaic panel -solar collector (PVT) cooled by water-Al2O3 nanofluids has been conducted. The weight fractions of the nanoparticles were 1% and 3%. Thermal efficiency, power efficiency and overall efficiency have been determined for artificial source of light and sunlight. No noticeable effect of the nanoparticle concentration on the overall efficiency of the PVT module has...
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Analysis of pesticide residue in tomato samples using analytical protocol based on application of QuEChERS technique and GC-ECD system
PublicationQuEChERS sample preparation method was used for the determination of 10 pesticides and their metabolites in tomato samples, coupled to gas chromatography with electron capture detector (GCECD). The experimental parameters including oven temperature program, amount of the sample and purifying agent were optimized. The GC-ECD method was validated in terms of linearity, selectivity and recovery. The limits of detection (LODs) of the...
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Impedance Studies of Phosphate-iron Glasses Containing Niobium and Titanium
PublicationThe ac and dc conductivity in phosphate-iron-niobate glasses with addition of titanium oxide was investigated as a function of temperature and frequency with the use of impedance spectroscopy. The topography and microstructure of glasses were investigated by the means of X-ray diffraction (XRD), scanning electron microscopy (SEM), and confocal microscopy methods. The obtained results show that all samples are amorphous but they...
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PERFORMANCE OF THE PVT SOLAR COLLECTOR OPERATED WITH WATER –AL2O3 NANOFLUID
PublicationAn experimental investigation of the hybrid module photovoltaic panel -solar collector (PVT) cooled by water-Al2O3 nanofluids has been conducted. The weight fractions of the nanoparticles were 1% and 3%. Thermal efficiency, power efficiency and overall efficiency have been determined for artificial source of light and sunlight. No noticeable effect of the nanoparticle concentration on the overall efficiency of the PVT module has...
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Analysis of unsteady flow forces on the thermowell of steam temperature sensor
PublicationIn this paper, 3D numerical analysis of unsteady flow forces acting on the measuring sheath of steam temperature is presented. According to that purpose, the CFD (Computation Fluid Dynamic [1]) approach has been used. The nonstationary of fluid acting on the measuring sheath such as: Strouhal frequency, amplitude of pressure, structure of vortex, peak of pressure, field of pressure, field of velocity etc. are studied analytically...
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Ti4Ir2O : A time reversal invariant fully gapped unconventional superconductor
PublicationHere we report muon spin rotation (μSR) experiments on the temperature and field dependence of the effective magnetic penetration depth λ(T ) in the η-carbide-type suboxide Ti4Ir2O, a superconductor with a considerably high upper critical field. The temperature dependence of λ(T ), obtained from transverse-field (TF)-μSR measurements, is in perfect agreement with an isotropic fully gaped superconducting state. Furthermore, our...
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Resistive gas sensors – Perspectives on selectivity and sensitivity improvement
PublicationResistive gas sensors are very popular and relatively inexpensive; they can operate at elevated or room temperature for years on end. The main disadvantage of resistive gas sensors is their limited selectivity and sensitivity, but various methods have been applied to improve their behavior. The composition of the porous gas sensing layer, or changes in the sensor’s operating temperature, can enhance the gas detection ability. Furthermore, emerging...
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Modelling of saturated, subcooled and post-dryout flow boiling with the energy dissipation based semi-empirical model
PublicationA comprehensive semi-empirical model for saturated, subcooled and post dryout heat transfer is presented based on considerations of energy dissipation in the flow. The fundamental hypothesis in the model is the fact that heat transfer during flow boiling can be treated as a sum of two contributions constituting the total energy dissipation in the flow, namely the energy dissipation due to the shearing flow without the bubbles and...
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The Effect of Cryogenic Treatment on Microstructure and Mechanical Response of AISI D3 Tool Steel Punches
PublicationRecently, deep cryogenic treatment is performed to improve the mechanical responses (wear, hardness, fatigue, and thermal conductivity) of various steel components. Researchers have tried to evaluate the eco-friendly and nontoxic process to optimize the parameters. Cold-shearing punches used to manufacture various holes that undergo severe impact loading and wear in the metal forming process. This study concerns the effect of soaking...
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An Influence of Factors of Flow Condition, Particle and Material Properties on Slurry Erosion Resistance
PublicationThe degradation of materials due to slurry erosion is the serious problem which occurs in the power industries. The paper presents actual knowledge about an influence of individual factors connected with flow conditions, particles and material properties on the slurry erosion resistance. Among the factors connected with operating conditions, an influence of impact angle, and velocity of impact, particle concertation and liquid...
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Characterization of Sunflower Waste Carbonization: Energy Balance and Water Holding Properties
PublicationThis paper characterizes the carbonization process of biomass wastes, including sunflower husk pellets and sunflower sponge stalk pellets, at carbonization temperatures of 450 and 550 ◦C. These studies are important because of the reductions in wood resources for the preparation of barbecue charcoal, as well as agricultural benefits in terms of soil additives. In terms of energy balance, the obtained pyrolysis ensures the autothermal...
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Ferromagnetism in Pr-rich binary Pr7Ru3 intermetallic compound
PublicationWe present the synthesis and experimental characterization of the binary intermetallic compound Pr7Ru3. The polycrystalline sample was prepared by arc melting pure Pr and Ru, followed by homogenization at 500 °C and 600 °C for 48 and 89 h, respectively. Powder x-ray diffraction confirms that Pr7Ru3 crystallizes in an orthorhombic crystal structure (Pnma, space group no. 62) with the lattice parameters: a = 7.3606(7) Å, b = 23.120(1)...
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Ionogel sorbent coatings for determining organophosphorus and pyrethroid insecticides in water and fresh juice samples by headspace-solid phase microextraction
PublicationThe sol–gel method yielded three different ionogel sorbent coatings that were obtained based on a silica material containing ionic liquids (ILs) immobilized in its pores. Two ILs, triethylsulfonium bis(trifluoromethylsulfonyl) imide [Set3][TFSI] and 1-butyl-1-methylpiperidinium bis(trifluoromethylsulfonyl)imide [C4C1Pip][TFSI], as well as their equimolar mixture [Set3/C4C1Pip], were used to obtain ionogel fibers. The developed...
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A facile synthesis by spark plasma sintering of mobile lithium ions into oxynitride glass-ceramic matrix: Insight and perspective
PublicationThe quest for efficient energy storage solutions has led to the development of solid-state Li-on batteries (SSBs), which utilize solid-state electrolyte (SSE) materials instead of organic liquid electrolytes. This study investigates the effect of increasing Li content in a Ca11Al14Si16O49N10 glass-ceramic material on its structural, thermal, physical, and electrical properties. Spark Plasma Sintered (SPS) glass-ceramic samples...
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Bio-Based Polyurethane Networks Derived from Liquefied Sawdust
PublicationThe utilization of forestry waste resources in the production of polyurethane resins is a promising green alternative to the use of unsustainable resources. Liquefaction of wood-based biomass gives polyols with properties depending on the reagents used. In this article, the liquefaction of forestry wastes, including sawdust, in solvents such as glycerol and polyethylene glycol was investigated. The liquefaction process was carried...
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Performance Characteristics of a Micro-turbine, International
Publication. In the paper a design of a multi-stage micro-turbine with partial admission of all the stages is described in detail and the results of particular experimental investigations and numerical calculations are shown, followed by conclusions. The co-generative micro-power plant with the HFE7100 as a working medium was designed and built for experimental investigations. The values of the main cycle parameters were as follows:- heat...
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Performance Characteristics of a Micro-Turbine
PublicationIn the paper a design of a multi-stage micro-turbine with partial admission of all the stages is described in detail and the results of particular experimental investigations and numerical calculations are shown, followed by conclusions. The co-generative micro-power plant with the HFE7100 as a working medium was designed and built for experimental investigations. The values of the main cycle parameters were as follows:heat output:...
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The effect of reduced pressure on carbon dioxide flow boiling heat transfer in minichannels
Publication. In the paper presented are the results of the study on the effect of reduced pressure on flow boiling heat transfer data in minichannels as well as conventional ones. That effect renders that most of heat transfer correlations fail to return appropriate results of predictions. Mostly they have been developed for the reduced pressures from the range 0.1-0.3. The special correction has been postulated to the in-house model of flow...
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Analysis of the Heating Process of Hydraulic Motors during Start-Up in Thermal Shock Conditions
PublicationConditions that prevail during harsh winters and hot summers pose a serious challenge for machine designers building devices suitable for operation in extreme weather. It is essential for the designers and the users to define the principles and conditions for the safe operation of machines and devices with hydraulic drive in low ambient temperatures. Bearing in mind the above, the author tested the hydraulic motors in thermal shock...
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High Temperature Air Combustion and Gasification (HTAC; HTAG)
PublicationCombustion and gasification technology utilizing high-cycle regenerative air/steam preheater has drawn increased attention in many application areas. The process is to be realized at temperature level above ash melting point using highly preheated agent. The use of highly preheated media above 900oC provides additional energy in to conversion processes and results in considerable changes to the design of combustion and gasification...
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Analysis of Ceramic Elements with Ring-Crack Defects in Lubricated Rolling Contact
PublicationThe properties of ceramics, specifically low density, high hardness, high temperature capability and low coefficient of thermal expansion are of most interest to rolling element manufacturers. Surface ring cracks on lubricating rolling contact fatigue failure has been studied using numerical fracture analysis. Such cracks are very often found on ceramic bearing balls and decrease fatigue life rapidly. The numerical calculations...
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Wavelet Transform Analysis of Temperature Modulated Gas Sensor Response
PublicationThe aim of the study was to evaluate whether it is possible to extract the information about the gas concentration despite the influence of humidity. Commercial semiconductor sensor response was examined under the application of a periodic temperature change. The data was collected using measurement protocol for different concentrations of ammonia at specified levels of relative humidity. In this work we focused on the evaluation...
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Environmental Fate of Two Psychiatric Drugs, Diazepam and Sertraline: Phototransformation and Investigation of their Photoproducts in Natural Waters
PublicationExperimental studies were conducted to investigate the photodegradation of diazepam and sertraline, two of the most frequently used psychiatric drugs, induced by xenon lamp irradiation, which overlap the sunlight spectra, and natural sunlight. Degradation kinetics was established indicating the occurrence of autocatalytic reactions. The application of liquid chromatography coupled to quadrupole time-of-flight mass spectrometry...
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Performance tuning of chitosan-based membranes by protonated 2-Pyrrolidone-5-carboxylic acid-sulfolane DES for effective water/ethanol separation by pervaporation
PublicationToday, the applicability of deep eutectic solvents (DES) in various fields, including membrane science and technology, is extensively investigated. In pioneering works, we have implemented different DES as a component of chitosan (CS)-based flat membranes for pervaporation (PV) separation. Herein, we present a new protonated (by sulphuric acid) 2-Pyrrolidone-5-carboxylic acid: sulfolane DES, as a green additive for its chemical...
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Low temperature broad band dielectric spectroscopy of multiferroic Bi6Fe2Ti3O18 ceramics
PublicationIn the present research the tool of broadband dielectric spectroscopy was utilized to characterize dielectric behavior of Bi6Fe2Ti3O18 (BFTO) Aurivillius-type multiferroic ceramics. Dielectric response of BFTO ceramics was studied in the frequency domain (Δν=0.1Hz – 10MHz) within the temperature range ΔT=-100°C – 200°C. The Kramers-Kronig data validation test was employed to validate the impedance data measurements and it was found...
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An approach for estimation of water wall degradation within pulverized-coal boilers
PublicationThe main aim of this paper is to estimate the lifetime of water walls of pulverized-coal boilers at nominal conditions as well as after degradation of water tubes. An approach for a pulverized-coal chamber degradation process has been formulated based on operational and experimental data. This model was formulated using on-line state monitoring of a pulverized coal burner with aim of preventing the fireplace screens from high degradation...
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Anharmonic Infrared Spectroscopy through the Fourier Transform of Time Correlation Function Formalism in ONETEP
PublicationDensity functional theory molecular dynamics (DFT-MD) provides an efficient framework for accurately computing several types of spectra. The major benefit of DFTMD approaches lies in the ability to naturally take into account the effects of temperature and anharmonicity, without having to introduce any ad hoc or a posteriori corrections. Consequently, computational spectroscopy based on DFT-MD approaches plays a pivotal role in...
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Spinon excitations in the quasi-one-dimensional S=12 chain compound Cs4CuSb2Cl12
PublicationThe spin−1/2 Heisenberg antiferromagnetic chain is ideal for realizing one of the simplest gapless quantum spin liquids (QSLs), supporting a many-body ground state whose elementary excitations are fractional fermionic excitations called spinons. Here we report the discovery of such a one-dimensional (1D) QSL in Cs4CuSb2Cl12. Compared to previously reported S=1/2 1D chains, this material possesses a wider temperature range over...
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Anisotropic, multiband, and strong-coupling superconductivity of the Pb0.64Bi0.36 alloy
PublicationThis paper presents theoretical and experimental studies on the superconductivity of Pb0.64Bi0.36 alloy, which is a prototype of strongly coupled superconductors and exhibits one of the strongest coupling under ambient pressure among the materials studied so far. The critical temperature, the specific heat in the superconducting state, and the magnetic critical fields are experimentally determined. Deviations from the single-gap...
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Fast, sensitive and reliable multi-residue method for routine determination of 34 pesticides from various chemical groups in water samples by using dispersive liquid – liquid microextraction coupled with gas chromatography – mass spectrometry
PublicationA simple and efficient dispersive liquid-liquid microextraction technique (DLLME) was developed by using a mixture of two solvents: 40 μL of tetrachlorethylene (extraction solvent) and 1.0 mL of methanol (disperser solvent), which was rapidly injected with a syringe into 10mL ofwater sample. Some important parameters affecting the extraction efficiency, such as type and volume of solvents, water sample volume, extraction time,...
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Injectable biocomposite cement: A dual-setting formula with magnesium potassium phosphate and κ-carrageenan hydrogel for orthopedic advancements
PublicationMagnesium phosphate-based cements are highly regarded for their bioactive properties, making them excellent candidates as bone substitutes. Despite their promising attributes, challenges such as high reaction temperature, limited injectability, and brittleness limit their application. This study introduces a dual-setting biocomposite cement, which encompasses both cement hydration and hydrogel's cross-linking. The composition features...
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Negative CO2 Emission Gas Power Plant As Technology for Utilization of Sewage Sludge, Production of Electrical Energy, and CO2 Capture - Case of Chamber Under Transpiration Cooling
PublicationThis work focuses on the concept developed in the nCO2PP project, which aims to demonstrate a technology that allows to achieve negative CO2 emissions through Carbon Capture and Storage (CCS) applied to sewage sludge. A feedstock is first gasified, then the resulting syngas is burned in a semi-closed oxy-fuel gas turbine with pure oxygen and water, using the advantages of oxy-combustion, to ease the capture of CO2 in the resulting...
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Recent advances of selected passive heat transfer intensification methods for phase change material-based latent heat energy storage units: A review
PublicationThe following article overviews recent studies regarding heat transfer enhancement methods, explicitly focusing on fins and coils utilization, in phase change material-based latent heat thermal energy storage systems. It discusses the influence of various geometrical and material parameters on the melting and solidification processes, as well as the orientation of the heat transfer surface within the storage tank. Additionally,...