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Do Phenyl Substituents Affect the Properties of Azobenzocrown Derivatives?
PublicationNew products of photo- and thermal rearrangements of 19-membered azoxybenzocrown with phenyl substituents in benzene rings in the para positions to oligooxyethylene fragments are characterized. The yields of photochemical transformations depend on the solvent. Para-hydroxyazocrown is formed with yields over 50% in propan-2-ol. Ortho-hydroxyazobenzocrown is obtained with yields up to 70% in toluene/acetic acid mixture. Macrocyclic...
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The importance of anchoring ligands of binuclear sensitizers on electron transfer processes and photovoltaic action in dye-sensitized solar cells
PublicationThe relatively low photon-to-current conversion efficiency of dye-sensitized solar cells is their major drawback limiting widespread application. Light harvesting, followed by a series of electron transfer processes, is the critical step in photocurrent generation. An in-depth understanding and fine optimization of those processes are crucial to enhance cell performance. In this work, we synthesize two new bi-ruthenium sensitizers...
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A Comparison of the Efficiency of Deammonification under Different Aeration Strategies in a Laboratory-Scale Sequencing Batch Reactor
PublicationAn important source of nitrogen load entering the biological part of wastewater treatment plants (WWPTs) is derived from the anaerobic sludge digestion processes. Sludge digestion liquors constitute only 1-2% of the inflow to the plant, but the load of nitrogen directed with them to the main stream may be as high as 10-20% of the total nitrogen load. Therefore, numerous studies have focused on treatment of sludge digestion liquors...
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Inhibition effect of free ammonia on deammonification process under different intermittent aeration strategies in sequencing batch reactor
PublicationThe deammonification process involves two steps. The first step is the partial nitrification of ammonia (NH4-N) by ammonia oxidizing bacteria (AOB) to produce nitrite (NO2-N) and the second step is the anammox process to “anaerobically” oxidize ammonia to nitrogen gas with nitrite as an electron acceptor (Lackner et al., 2014). Free ammonia (FA) plays a significant role in the stable, long-term deammonification system operation....
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Evaluating calibration and robustness of pedestrian detectors
PublicationIn this work robustness and calibration of modern pedestrian detectors are evaluated. Pedestrian detection is a crucial perception com- ponent in autonomous driving and here we study its performance under different image corruptions. Furthermore, we provide analysis of classifi- cation calibration of pedestrian detectors and we show a positive effect of using style-transfer augmentation technique. Our analysis is aimed as a step...
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Validation of a sampling procedure
PublicationEach step of the analytical procedure influences the final results in a significant way. In the majority of cases the analytical procedure encompasses sampling because the analysis of the entire object (material) is usually not possible. Thus it is necessary to include the uncertainty related to sampling procedure in the uncertainty budget calculations. This paper describes two basic ways of estimating the sampling uncertainty,...
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Wykorzystanie środowiska ekspertowego do projektowania wybranych podsystemów energetycznych statków
PublicationW artykule przedstawiono koncepcję wykorzystania badań symulacyjnych oraz systemu ekspertowego z bazą wiedzy do wspomagania projektowania podsystemów energetycznych statków. Opisano przykładową strukturą steru strumieniowego oraz poszczególne jej elementy składowe.This paper presents a concept of application of simulation investigations and an expert system with a knowledge-base and data-base to improve design procedures of a ship...
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Factory Acceptance Test – Strain Gauge Measurement - Report no: WOiO /II/88/2014
PublicationTested object was 40 meters long jib and its foundation, placed in Gdansk Shiprepair Yard, manufactured by KMK. The contruction was dedicated to the passenger cruise vessel "North Star" The Strain Gauge measurement in different location and load situation was done in order to validate calculation finite element models used during strength analysis for project. The expertise contains: methodology of the measurements, description...
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Does Culture Moderate Gender Stereotypes? Individualism Predicts Communal (but Not Agentic) Prescriptions for Men Across 62 Nations
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Photophysics of Soret-Excited Tin(IV) Porphyrins in Solution
PublicationThe photophysics of low-chlorin tin(IV) tetraphenylporphyrin dihydroxide, a core building block for axially substituted supramolecular tin porphyrin constructs, has been studied in a variety of hydrogen-bonding, nonpolar, and aprotic polar solvents using steady-state, nanosecond, and femtosecond time-resolved emission, and femtosecond time-resolved absorption methods. In hydrogen-bonding solvents the metalloporphyrin exists as...
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Modelowanie wpływu zasilania na pracę odbiorników systemu elektroenergetycznego statku
PublicationDuże odbiorniki energii elektrycznej na statkach, a zwłaszcza silniki indukcyjne charakteryzują się zmiennym poborem prądu. Przy ocenie wpływu obwodów zasilania na pracę odbiorników należy stosować złożone modele matematyczne. W artykule zaproponowano zastosowanie oryginalnego modelu węzła, który umożliwia modelowane połączenia szeregowego dwóch oddzielnych elementów: obwodu zasilania i odbiornika bez obliczania przepływu prądu....
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Powstanie politechniki w Gdańsku
PublicationPrzedstawione w poprzednim artykule rozważania (patrz Pismo PG nr 2/2000) dotyczące formowania się wyższego szkolnictwa technicznego w ścisłym związku z przewodzącym na określonym obszarze przemysłem, przy równoczesnym poparciu ze strony sfer rządzących, odpowiadają w pełni warunkom panującym w Gdańsku w końcu XIX wieku, a więc w okresie realizacji działań mających na celu utworzenie politechniki w Gdańsku.
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Krótkoterminowe papiery dłużne w finansowaniu przedsiębiorstw w Polsce
PublicationKrótkoterminowe papiery dłużne stanowią jedno ze źródeł finansowania działalności przedsiębiorstwa. Jednocześnie banki komercyjne w procesie dezintermediacji, poszukują nowych sfer działalności. Uczestnictwo w organizowaniu i emitowaniu krótkoterminowych papierów dłużnych, stało się dla nich kolejnym źródłem aktywności gospodarczej, wychodzącym naprzeciw poszukiwaniom alternatywnych źródeł finansowania przez podmioty gospodarcze....
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The Influence of External Load on the Performance of Microbial Fuel Cells
PublicationIn this work, the effect of the external load on the current and power generation, as well as on the pollutant removal by microbial fuel cells (MFCs), has been studied by step-wise modifying the external load. The load changes included a direct scan, in which the external resistance was increased from 120 Ω to 3300 Ω, and a subsequent reverse scan, in which the external resistance was decreased back to 120 Ω. The reduction in the...
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Angiopoietin-like growth factor-derived peptides as biological activators of adipose-derived mesenchymal stromal cells
PublicationAdipose-derived mesenchymal stromal cells (AD-MSCs) are an essential issue in modern medicine. Extensive preclinical and clinical studies have shown that mesenchymal stromal/stem cells, including AD-MSCs, have specific properties (ability to differentiate into other cells, recruitment to the site of injury) of particular importance in the regenerative process. Ongoing research aims to elucidate factors supporting AD-MSC culture...
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Exploring novel Cd(ii) complexes with 5-methyl-4-imidazolecarboxaldehyde: synthesis, structure, computational insights, and affinity to DNA through switchSense methodology
PublicationA series of four Cd(II) complexes with 5-methyl-4-imidazolecarboxaldehyde (L) with different inorganic anions within or outside the coordination sphere of general formula: [CdCl2 L2 ] (1), [CdBr2 L 2] (2), [CdI2L 2] (3), and [CdL4 ](PF6 )2 ·3H2 O (4) was synthesized through one-step and two-step reactions, respectively. All complexes were obtained as colorless crystals without the need for recrystallization and exhibited solubi- lity...
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General concept of reduction process for big data obtained by interferometric methods
PublicationInterferometric sonar systems apply the phase content of the sonar signal to measure the angle of a wave front returned from the seafloor or from a target. It collect a big data – datasets that are so large or complex that traditional data processing application software is inadequate to deal with them. The recording a large number of data is associated with the difficulty of their efficient use. So data have to be reduced. The main...
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Stages of project implementation based on design-thinking concept
PublicationIn this chapter there were presented basic aspects of project management focused on an improvement of the final effect. Firstly the project ter was defined including a discusion of its core attributes and determinants of its management procedure. Next design-thinking concept was introduced as an approach to use in project management for achieving maximum consumer satissfaction.
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DETERMINATION OF SURFACTANTS IN ENVIRONMENTAL SAMPLES. PART II. ANIONIC COMPOUNDS
PublicationSurfactants (SAA) with negative charge of polar group are named as anionic compounds. They are main constituent of most products containing synthetic surfactants. The linear alkylbenzene sulfonates (LAS), alkyl ethoxysulfates (AES) and alkyl sulfates (AS) are typically applied from this class of compounds. Those surfactants are ingredients of household detergents and cleaners, laundry detergents, cosmetic. Moreover they can be...
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A Study of Cross-Linguistic Speech Emotion Recognition Based on 2D Feature Spaces
PublicationIn this research, a study of cross-linguistic speech emotion recognition is performed. For this purpose, emotional data of different languages (English, Lithuanian, German, Spanish, Serbian, and Polish) are collected, resulting in a cross-linguistic speech emotion dataset with the size of more than 10.000 emotional utterances. Despite the bi-modal character of the databases gathered, our focus is on the acoustic representation...
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Estakada E2 - kluczowy obiekt Obwodnicy Wałcza
PublicationW artykule przedstawiono uwarunkowania i przebieg projektowania estakady E2 z betonu sprężonego w ciągu Obwodnicy Wałcza. Pokazano efekt procesu optymalizacji projektu pierwotnego. Opisano przeprowadzone analizy wynikające z przyjętej technologii nasuwania podłużnego oraz istotne aspekty, które należy poruszyć przy wyborze tej technologii. Zaprezentowano modele numeryczne konstrukcji przęseł i metodę analizy z uwzględnieniem pracy...
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3D Model Preparing Patterns for Interactive Urban Visualization - Guidelines for Graphic Designers Preparing 3D Models for Virtual Reality Applications
PublicationWhile working on architectural visualizations, the software developer often has to work with graphic designers who create models in a different environment what can cause many complications. For this reason, it is very important to have some guidelines which can protect both the developer and the designer from commixing mistakes. The paper presents a list of such guidelines based on the authors’ experience. The reader can treat...
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The influence of small amount of substances present in tissue on the optical spectrum of immunosuppressive drug
PublicationIn this paper, we describe how commonly present in tissue substances - sodium chloride and glucose - affect the optical spectrum of an immunosuppressive drug (Cyclaid® by Apotex). Prepared samples were investigated using the spectrophotometer in the spectrum range from 250 nm to 1100 nm. The maximum wavelength shift calculated on the basis of measurement results is not bigger than the measurement wavelength step. So, it can be...
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Camera angle invariant shape recognition in surveillance systems
PublicationA method for human action recognition in surveillance systems is described. Problems within this task are discussed and a solution based on 3D object models is proposed. The idea is shown and some of its limitations are talked over. Shape description methods are introduced along with their main features. Utilized parameterization algorithm is presented. Classification problem, restricted to bi-nary cases is discussed. Support vector...
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The influence of esterification time on the physicochemical properties of poly (glycerol sebacate-co- butylene sebacate)
PublicationThe study presents the results of the physicochemical properties of ester elastomer based on sebacic acid, glycerol and 1,4 - butanediol. The process of obtaining elastomers at variable esterification times of 14, 16 and 21 h is described. It was found that the material with an esterification time of 21 h is characterized by the best mechanical properties while maintaining high content of the gel fraction. In the technological...
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Application of muscle model to the musculoskeletal modeling
PublicationThe purpose of this paper is to investigate new fusiform muscle models. Each of these models treats a muscle as a system composedof parts characterized by different mechanical properties. These models explain the influence of differences in the stiffness of lateral parts and the degree of muscle model discretization. Each muscle model is described by a system of differential equations and a single integro-differential equation....
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STEADY STATE VISUALLY EVOKED POTENTIALS FOR BRAIN COMPUTER INTERFACE
PublicationAn experiment conducted to validate a possibility of use a single active electrode EEG device for detecting Steady State Visually Evoked Potentials (SSVEP) is shown. A LED stimulator was applied to stimulate patients with two different frequencies - 13 Hz and 17 Hz. First, EEG signals were recorded and pre-processed using MATLAB software. In the next step recordings were analysed and classified employing the WEKA software. As indicated...
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Towards Universal Visualisation of Emotional States for Information Systems
PublicationThe paper concerns affective information systems that represent and visualize human emotional states. The goal of the study was to find typical representations of discrete and dimensional emotion models in terms of color, size, speed, shape, and animation type. A total of 419 participants were asked about their preferences for emotion visualization. We found that color, speed, and size correlated with selected discrete emotion...
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Properties of chitosan/CuNPs coatings electrophoretically deposited on TiO2 nanotubular oxide layer of Ti13Zr13Nb alloy
PublicationCoatings based on chitosan/CuNPs (chit/CuNPs) were obtained by a one-step electrophoretic deposition (EPD) on nanotubular oxide layer of Ti13Zr13Nb alloy. The deposition was carried out for 1 min applying voltages of 10 and 20 V with and without the addition of dispersing agent (Polysorbate 20) to the suspension. The coatings obtained for the lower voltage were more uniform than for the higher voltage. By adding a dispersing agent,...
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Integrating Confidence And Assurance Arguments
PublicationTo be considered compelling an assurance case should address its potential deficits, possibly with the use of a confidence argument. Assurance argument and confidence argument should be clearly separated and consistent at the same time. We propose a way of their integration with the use of an element representing rationale for each argumentation strategy. The rationale integrates confidence argument for a given argumentation step...
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Sampling Strategies: Statistics of Sampling
PublicationEach step of the analytical procedure has a significant influence on the final result of the analysis. In the majority of cases the analytical procedure encompasses sampling because the analysis of the entire object (material) is usually not possible. Thus it is necessary to include the uncertainty related to sampling procedure in the uncertainty budget calculations. In the paper: the most important properties of the analysed...
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Fatty acids as molecular carriers in cleavable antifungal conjugates
PublicationConjugates composed of C2-18 fatty acid (FA) residues as a molecular carrier and 5-fluorocytosine (5-FC) as an active agent, released upon the action of intracellular esterases on the ester bond between FA and “trimethyl lock” intramolecular linker, demonstrate good in vitro activity against human pathogenic yeasts of Candida spp. The minimal inhibitory concentrations (MIC) values for the most active conjugates containing caprylic...
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Ship Dynamic Positioning Based on Nonlinear Model Predictive Control
PublicationThe presented work explores the simulation test results of using nonlinear model predictive control algorithm for ship dynamic positioning. In the optimization task, a goal function with a penalty was proposed with a variable prediction step. The results of the proposed control algorithm were compared with backstepping and PID. The effect of estimation accuracy on the control quality with the implemented algorithms was investigated....
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A predictive estimation based control strategy for a quasi-resonant dc-link inverter
PublicationIn this paper the predictive estimation based control strategy for a quasi-resonant dc link inverter (PQRDCLI) is developed. Instead of direct measurement of dc link input inverter current – its estimation with one step prediction is applied. The PQRDCLI fed induction motor, controlled with a predictive current estimation stabilized inverter output voltage slopes independently of load. Moreover, reduction of overvoltage spikes...
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Numerical solution analysis of fractional point kinetics and heat exchange in nuclear reactor
PublicationThe paper presents the neutron point kinetics and heat exchange models for the nuclear reactor. The models consist of a nonlinear system of fractional ordinary differential and algebraic equations. Two numerical algorithms are used to solve them. The first algorithm is application of discrete Grünwald-Letnikov definition of the fractional derivative in the model. The second involves building an analog scheme in the FOMCON Toolbox...
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Numerical Studies on Propellers in Open Water and behind Hulls aiming to support the Evaluation of Propulsion Tests
PublicationA RANS based numerical analysis of propellers can contribute considerably to our understanding of propeller/hull interaction. It may also allow for a review of scaling procedures on results from experimental fluid dynamics (EFD). Using various RANS codes (Fluent, CFX, STAR-CCM+ and FreSCo+) on common test cases the authors first focused on propeller open water (POW) calculations. Next we simulated the propeller hull interaction...
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Theoretical analysis of a new approach to order determination for a modified Prony method in swath mapping application
PublicationThis article presents a new approach to determine the model order (number of principal components) in the modified Prony method applied to swath acoustic mapping. Determination of the number of principal components is a crucial step in the modified Prony method. In the proposed approach the model order is chosen based on the underlying physical model of the underwater acoustic environment, and utilised signal processing operations....
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The use of recycled semiconductor material in crystalline silicon photovoltaic modules production - A life cycle assessment of environmental impacts
PublicationTo offset the negative impact of photovoltaic modules on the environment, it is necessary to introduce a longterm strategy that includes a complete lifecycle assessment of all system components from the production phase through installation and operation to disposal. Recycling of waste products and worn-out systems is an important element of this strategy. As the conclusions from the previous studies have shown, thermal treatment...
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Novel molecules containing structural features of NSAIDs and 1,2,3-triazole ring: Design, synthesis and evaluation as potential cytotoxic agents
PublicationFor the first time the template containing structural features of more than one NSAIDs and the 1,2,3-triazole ring was explored for the identification of potential cytotoxic agents. These new and complex molecules were predicted to be effective inhibitors of PDE4B by molecular modelling studies in silico. The multi-step synthesis of these compounds were carried out starting from the well-known drug nimesulide and involved the use...
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Synthesis and characterization of biopolyols through biomass liquefaction of wood shavings and their application in the preparation of polyurethane wood composites
PublicationThe sustainability of production systems in wood processing, wood industry, and wooden waste disposal is an important issue for European industry and society. Proper development of products based on renewable wood resources gives an opportunity to provide materials with long-term environmental, social, and economic sustainability. This study aims to establish a new way of forestry and agricultural waste materials utilization by...
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New nanoadsorbent based on magnetic iron oxide containing 1,4,7,10-tetraazacyclododecane in outer chain (Fe3O4@SiO2-cyclen) for adsorption and removal of selected heavy metal ions Cd2+, Pb2+, Cu2+
PublicationMagnetic Fe3O4@SiO2-cyclen nanoparticles were prepared and used as adsorbent for Cd2+, Pb2+ and Cu2+ from aqueous solution removal process controlled with differential pulse anodic stripping voltammetry (DPASV) and hanging mercury drop electrode (HDME). Nanomaterial was synthesised in three-step process co-precipitation of Fe3O4 core, coating with silane and N-(3-(triethoxysilyl)propyl)-1,4,7,10-tetraazacyclododecane-1-carboxamide...
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Feasibility Study of Biohydrogen Production from Acid Cheese Whey via Lactate-Driven Dark Fermentation
PublicationThe high loading of lactic acid bacteria (LAB) present in cheese whey still limits its use as hydrogen feedstock. This study aims to investigate the feasibility of producing hydrogen from acid cheese whey via lactate-driven dark fermentation (LD-DF). Mesophilic batch fermentations were performed with delipidated acid cheese whey at a fixed pH of 5.8 and driven by an acidogenic bacterial culture containing LAB and lactate-oxidizing...
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Model Management for Low-Computational-Budget Simulation-Based Optimization of Antenna Structures Using Nature-Inspired Algorithms
PublicationThe primary objective of this study is investigation of the possibilities of accelerating nature-inspired optimization of antenna structures using multi-fidelity EM simulation models. The primary methodology developed to achieve acceleration is a model management scheme which the level of EM simulation fidelity using two criteria: the convergence status of the optimization algorithm, and relative quality of the individual designs...
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The In-House Method of Manufacturing a Low-Cost Heat Pipe with Specified Thermophysical Properties and Geometry
PublicationVarious types of heat pipes are available to purchase off the shelf, from various manufacturers, but most of them have strictly defined geometry and technical parameters. However, when there is a need to use a heat pipe (HP) with an unusual size and shape or working conditions other than the standard ones, it becomes very costly to order them from manufacturers, especially in small quantities, and only a few producers are willing...
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Modeling hydrolysis of slowly biodegradable organic compounds in biological nutrient removal activated sludge systems
PublicationHydrolysis is an important process in biological wastewater treatment and is known to be the ratelimiting step in organic carbon removal from municipal or industrial wastewater. The influence of the readily biodegradable chemical oxygen demand fraction in biological wastewater treatment systems has been extensively investigated, but little is known about the effects of slowly biodegradable substrate (XS) on denitrification and...
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Investigations on the immunosuppressive activity of derivatives of mycophenolic acid in immature dendritic cell
PublicationThe main activity of mycophenolic acid (MPA) and its analogs is the inhibition of proliferation of T cells. Here, we hypothesized that MPA and its conjugates inhibits also the activity of antigen-presenting cells (APC) including dendritic cells (DCs). We tested the effect of novel amino acid derivatives of MPA and conjugates of MPA with acridines/acridones on DCs by flow cytometry, ELISA and MLR assay. Both acridines/acridone derivatives...
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Novel fast analytical method for indirect determination of MCPD fatty acid esters in edible oils and fats based on simultaneous extraction and derivatization
PublicationA novel method for indirect determination of MCPD esters levels in lipid samples has been developed. The method is based on combination of extraction and derivatisation in the same sample preparation step. It is achieved by the application of diethyl ether as extraction solvent for isolation of released from esterified forms analytes from water phase and dilution solvent for solid PBA – derivatisation agent. It is a noteworthy...
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Ionic liquids-based microextraction techniques
PublicationIn recent years, the development of highly efficient analytical techniques is of great importance, however, the direct analysis of complex sample matrix is still impossible in many cases. Therefore, the step of sample preparation is commonly involved in an analytical procedure. Over the years, it has been realized that the major source of inaccuracy and imprecision on general analysis results from the operations associated to sample...
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Long range molecular dynamics study of interactions of the eukaryotic glucosamine-6-phosphate synthase with fructose-6-phosphate and UDP-GlcNAc
PublicationGlucosamine-6-phosphate synthase (EC 2.6.1.16) is responsible for catalysis of the first and practically irreversible step in hexosamine metabolism. The final product of this pathway, uridine 5 diphospho Nacetyl- d-glucosamine (UDP-GlcNAc), is an essential substrate for assembly of bacterial and fungal cell walls. Moreover, the enzyme is involved in phenomenon of hexosamine induced insulin resistance in type II diabetes, which...
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Distribution Transformer with Multi-Zone Voltage Regulation for Smart Grid System Application
PublicationThe article presents four concepts of the multi-zone voltage regulation (MZVR) system. It is a combination of a distribution transformer with an on-load tap-changer, for step voltage regulation, and a power electronic converter, dimensioned for a fraction of MZVR power, realizing continuous voltage regulation, supplemented by a special switch, the so-called bypass. This allows voltage regulation at high resolution, wide range and...