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Search results for: BIT KWANTOWY
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A versatile and convenient preparation of unsymmetrical diaryl disulfides
PublicationWe have developed a convenient method for the synthesis of unsymmetrical diaryl disulfides under mild conditions in excellent yields. The described method is based on the straightforward preparation of 5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinane-2-sulfenyl bromide from readily available 5,5-dimethyl-2-thiolo-2-thioxo-1,3,2-dioxaphosphorinane or bis(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl) disulfide. The unsymmetrical...
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Numerical investigations of the engine cooling system in a small power vesel pod propulsion system
PublicationThe development of electronics and electrotechnology enabled to put electric motors of the alternating current in the pod and to use them for the main drive of ships. A lot of heat which must be picked up from the system is a problem which is turning up at applying the system of this type. Many big ships lately contended with these problems. Building the small propeller for the boat powered with solar power we decided to check...
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Environmental impact and industrial development of biorenewable resources for polyurethanes
PublicationPolyurethanes are among the most developed types of polymers. They are produced from the three primary components, i.e., polyols, low-molecular-weight glycols used as chain extenders, and diisocyanates. Until recently, all these substrates have been obtained via petrochemical processes. A decrease in petroleum-based resources and new ecological trends in chemistry, chemical technology, and materials engineering have generated increasing...
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Comparison of image pre-processing methods in liver segmentation task
PublicationAutomatic liver segmentation of Computed Tomography (CT) images is becoming increasingly important. Although there are many publications in this field there is little explanation why certain pre-processing methods were utilised. This paper presents a comparison of the commonly used approach of Hounsfield Units (HU) windowing, histogram equalisation, and a combination of these methods to try to ascertain what are the differences...
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Greener organic solvents in analytical chemistry
PublicationThe paper presents the most recent advances in analytical applications of greener organic solvents. Substitution of problematic solvents with more benign organic ones is much easier than shifting to technique applying alternative solvents, such as ionic liquids or supercritical fluids. In the area of liquid chromatography greener mobile phases, much attention is given to application ethanol or acetone instead of acetonitrile. Solvent-based...
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Free randomness amplification using bipartite chain correlations
PublicationA direct analysis of the task of randomness amplification from Santha-Vazirani sources using the violation of the chained Bell inequality is performed in terms of the convex combination of no-signaling boxes required to simulate quantum violation of the inequality. This analysis is used to find the exact threshold value of the initial randomness parameter from which perfect randomness can be extracted in the asymptotic limit of...
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Characteristic of Morpholinium Ionic Liquids as Gas Chromatography Stationary Phases with McReynolds Constants and Activity Coefficients at Infinite Dilution
PublicationIn this work, four ionic liquids based on N-alkyl-N-methylmorpholinium cation ([Mor1,R] where R= 2, 4, 8, 10) and bis(trifluoromethanesulfonyl)imide anion [TFSI] were synthesized. Using gas-liquid chromatography a number of parameters describing the sorption properties of the investigated ionic liquids were determined. The values of Kovats indices, McReynolds constants, and activity coefficients at infinite dilution were the basis...
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Dynamic effect of the vehicle passing under lightweight footbridge.
PublicationThe paper describes a numerical study of dynamic response of cable-stayed steel footbridge for a big lorry passing underneath. The footbridge is an existing object crossing Wolska street in Warsaw. The structural model of footbridge was verified by dynamic test loading. A numerical study of a vehicle passing under footbridge is presented. 2D and 3D incompressible flow fields are modeled using sliding mesh in transient CFD computation....
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Synthesisand cytotoxic activity of conjugates of muramyl and normuramyl dipeptides with batracylin derivatives
PublicationOpisano syntezę analogów MDP oraz nor-MDP modyfikowanych w części peptydowej batracyliną i pochodnymi batracyliny. Opracowano udoskonaloną metodę syntezy batracyliny. Zaproponowana metoda pozwala na otrzymanie BAT w skali multi-gramowej. Zsyntetyzowane analogi nie wykazały aktywności cytotoksycznej w badaniach prowadzonych w NCI (Bethesda, USA). W testach in vitro przeprowadzonych w Akademii Medycznej w Gdańsku dwa analogi redukowały...
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Rozumienie cechą inteligentnego przedsiębiotstwa
PublicationW artykule podniesiono istotę pojęcia ‘rozumienie’ w aspekcie inteligentnego przedsiębiorstwa. Przeprowadzone badania teoretyczne i empiryczne pozwoliły na wyłonienie rozumienia wewnętrznego i zewnętrznego. Rozumienie wewnętrzne w inteligentnym przedsiębiorstwie dotyczy sfer: pracowników oraz całego przedsię-biorstwa. Natomiast rozumienie zewnętrzne skierowane jest na otoczenie i potrze-bę dostosowania przedsiębiorstwa.
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A Preliminary Study and Analysis of Tidal Stream Generators
PublicationFor a sustainable future, tidal energy can play a vital role. Tidal energy relies on the gravitational pull of the Moon and the Sun along with the centrifugal forces created by the Earth. Tidal barrage uses the potential energy from the tide and has been very successful in electricity production. With the help of a turbine, kinetic energy can also be harnessed from tidal currents to generate electricity. However, it is not economically...
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Electro-photoluminescence in organics
PublicationElektro-fotoluminescencję zaobserwowano w układzie ITO(+)/emiter/Ca(-), gdzie emiter wzbudzany światłem UV (350nm) zawierał dendrymer aminowy m-MTDATA, pochodną fenantroliny BPT i organiczny kompleks platyny PtL2Cl. Widmo fotoluminescencji pochodzi od singletowych ekscypleksów m-MTDATA:BPT i trypletowych ekscypleksów m-MTDATA:PtL2Cl. Ze wzrostem pola elektrycznego następuje wygaszanie ekscypleksów na skutek ich dysocjacji na nośniki...
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Marine Fuel Sulphur Limit Impact on Air Pollution
PublicationThe article presents calculation of Sulphur oxides percentage drop rate in marine industry recorded after 01.01.2020 when new limits, provided by International Maritime Organizations legislation, became effective. Ships’ SOx global emission was estimated and compared between 4th quarter 2019 and 1st quarter 2020. For more accurate estimation 3 seaside cities with big harbors were selected for statistical analysis. Noticeable...
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The Determinants of False Self-Employment: A Survey of Polish Enterprises
PublicationThe main goal of this article is to advance the emergent research on tax evasion in Poland in the form of false self-employment (FSE), in particular to identify its causes. The dependent character of some self-employed workers is a big problem in the Polish economy, which has been completely unexplored because of the lack of available data. In this article, we use data from a survey of Polish companies. Our empirical results show...
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Zwiększenie wydajności hydrolizy enzymatycznej biomasy wskutek obróbki mechanicznej
PublicationWytwarzanie biogazu z biomasy odpadowej i innych odpadów frakcji Bio wymaga zastosowania etapu obróbki wstępnej. W literaturze opublikowano szereg prac związanych z obróbką mechaniczną, fizyczną, fizykochemiczną, chemiczną, a także biologiczną i enzymatyczną surowców o bogatej matrycy związków chemicznych. Na znaczeniu zyskują metody pozwalające jednocześnie uzyskać biopaliwo gazowe, ale także ciekłe produkty depolimeryzacji, które...
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RF Indoor Positioning System Supported by Wireless Computer Vision Sensors
PublicationIn this paper the possibility of increase the accuracy of RF fingerprinting indoor tracking system by the use of additional information from simple vision system is examined. As the distances in signal space differs from ones in real environment the ambiguity in decision process of fingerprinting algorithm can occur when set of closest distances between tag and map points in signal space corresponds to big distances differences...
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The analysis of temperature changes of the saliva traces left on the fur during laboratory rats social contacts
PublicationAutomatic analysis of complex rodent social be- havior, especially aggressive ones, is of important scientific interest. In this paper we analyze the properties of the data created as a result of aggressive rodent social behavior. Detec- tion of specific aggressive behaviors is based on the event of leaving traces of saliva on the fur of the attacked individual, which are clearly visible in the thermal imaging. The traces change...
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Emulsifi ers from renewable materials: an eco-friendly synthesis and properties
PublicationThe focus of this study was the preparation of novel bio based polyglycerol emulsifiers characterized by a one pot synthesis, thus by modified properties with respect to interfacial activity and effectiveness as emulsion stabilizers. The final products of the esterification process, carried out in the presence of carboxylates were used directly as emulsifiers (without purification or fractionation). Polyglycerol emulsifiers obtained...
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Implementacja zmodyfikowanej metody biliniowej 2D w elektronicznym systemie wbudowanym
PublicationPrzedstawiono implementację zmodyfikowanej metody biliniowej 2D diagnostyki sieci analogowych we wbudowanych mikrosystemach mieszanych sygnałowo sterowanych mikrokontrolerami. Metoda cechuje się prostym algorytmem diagnostycznym, który z powodzeniem można zaimplementować w 8-bitowych, powszechnie stosowanych mikrokontrolerach z interfejsem SPI, oraz nie wymaga nadmiernej rozbudowy mikrosystemu o część testującą (BIST). Zaletą metody...
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Metody projektowania ułatwiającego testowanie dla układów cyfrowych
PublicationPrzedstawiono przegląd metod ułatwiających testowanie DFT (Design for Testability) dla układów cyfrowych. Zaprezentowano metody stosowane na poziomie układów scalonych, pakietów oraz systemów elektronicznych. Pokazano heurystyczne metody projektowania pozwalające na zwiększenie sterowalności i obserwowalności układów oraz metody strukturalne, a wśród nich układy BILBO (Built-In Logic Block Observer), BIST (Built-In Self Test),...
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A Universal Theory of Wisdom . A Mind - oriented Approach
PublicationThe purpose of the paper is to synthesize the issues of human wisdom in terms of minds which create knowledge-based judgment. We form a transdisciplinary, big-picture view of the wisdom of humans. Findings: Wisdom is the right judgment and choice in the context of the art of living. Practical implications: Wisdom can be developed within the set of minds. Social implications: To pursue wisdom in thinking and action, one must extend...
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Performance of Coherent Modulation Scheme Used in Acoustic Underwater Communication System
PublicationThe development of an acoustic underwater communication system for shallow waters is still a big scientificand construction challenge. Currently, non-coherent modulations in combination with strong channel coding are used to achieve reliable communication with low rate in such a channel. To obtain transmission with a higher transmission rate, it is required to use coherent modulation. This paper presents the assumptions of such...
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The Action Mechanisms, Anti-Cancer and Antibiotic-Modulation Potential of Vaccinium myrtillus L. Extract
PublicationHerbal medicinal products containing Vaccinium myrtillus L. (bilberry) fruits and fruit extracts are widely available in the market. Although bilberry leaves and stems are considered as bio-waste, they contain much higher levels of phenolic compounds than fruits. The study aimed to investigate the antimicrobial and anticancer potential of aerial part extracts from Vaccinium myrtillus L. (V. myrtillus, VM) plants harvested at high...
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PLA–Potato Thermoplastic Starch Filament as a Sustainable Alternative to the Conventional PLA Filament: Processing, Characterization, and FFF 3D Printing
PublicationThe growing popularity of the fused filament fabrication (FFF) 3D printing technology in science, industry, and in-home use is associated with an increased demand for high-quality polymer filaments. This study presents an in-depth characterization and analysis of a self-made bio-based polylactide (PLA)/thermoplastic potato starch (TPS) filament dedicated for the FFF 3D printing technology. The obtained results were compared with...
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Game Theory Analysis of Bidding for a Construction Contract
PublicationThe authors are concerned with a bidding problem. There are two companies (P1 and P2) bidding for a highway construction project. In order to be more competitive, P1 considers buying a new gravel pit near the construction site. The basic cost of the pit is known to both companies. However, there is also an additional, hidden, cost (C) known only to P1. P2 is uncertain whether the hidden cost is C = 0 or C = x. P1 plans to bid for...
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Władza misjonarzy. Zmierzch i świt świeckiej religii w Dolinie Krzemowej
Publication"Władza misjonarzy" to książka o misjonarskim zapale zmieniania świata i o kryzysie świeckiej religii towarzyszącej liderom nowych technologii, o ich świętokradztwach i sprofesjonalizowanej pokucie mającej przywrócić harmonię technologicznego raju na ziemi z Alphabetem, Metą, Apple i TikTokiem w roli głównej. Także o skruszonych inżynierach, żałujących każdej chwili, którą poświęcili na wymyślanie uzależniających algorytmicznych rozwiązań...
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The influence of crude glycerol and castor oil-based polyol on the structure and performance of rigid polyurethane-polyisocyanurate foams
PublicationIn this work, biopolyol obtained from two types of industrial crops’ processing products: crude glycerol and castor oil was used for preparation or rigid polyurethane-polyisocyanurate foams. Bio-based polyol was obtained via crude glycerol polymerization and further condensation of resulting polyglycerol with castor oil. Rigid polyurethane-polyisocyanurate foams were prepared at partial substitution (0–70 wt.%) of petrochemical...
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Otrzymywanie nowych fotokatalizatorów o podwyższonej aktywności w świetle UV oraz VIS
PublicationGłównym celem naukowym pracy było opracowanie nowych metod otrzymywania fotokatalizatorów oraz lepszy zrozumienie mechanizmu ich działania poprzez korelację właściwości powierzchniowych z ich aktywnością fotokatalityczną. Prace badawcze obejmowały preparatykę TiO2 domieszkowanego borem, wolframem i modyfikowanego klastrami metali. Dla otrzymanych nanokompozytów B/TiO2, W/TiO2, Ag/TiO2, Au/TiO2, oraz Pt-TiO2, zbadano aktywność fotokatalityczną...
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Recent progress in ultra-low formaldehyde emitting adhesive systems and formaldehyde scavengers in wood-based panels: a review
PublicationTraditional wood-based panels are produced with synthetic, formaldehyde-based adhesives, commonly made from fossil-derived constituents, such as urea, phenol, melamine, etc. Along with their numerous advantages, such as chemical versatility, high reactivity and excellent adhesive performance, these adhesives are characterized by certain problems, connected with the hazardous volatile organic compounds (VOCs), mostly free formaldehyde...
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Human Resource Management Digitalisation in Multidisciplinary Ship Design Companies
PublicationThe digitalisation in the ship design sector is currently applied to the design process itself and is well defined, partially standardised and practically implemented by both independent design companies and the design departments of shipyards. The situation is similar in other sectors of engineering. However, the requirements for the digitalisation of other processes in design and engineering companies have not previously been...
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Mosty obrotowe o dużych rozpiętościach - idea, kształtowanie, wady i zalety
PublicationPierwowzorem tej idei jest most Song Han z obrotowym pylonem w miejscowości Dan Nang w Wietnamie. Autora urzekła prostota jego konstrukcji i funkcjonalność, polegająca na tym, że każdej wielkości statek może przepłynąć po obróceniu przęsła z obrotowym pylonem wokół osi pionowej o 90 stopni. Zastanawiając się nad problemem budowy mostów o dużych rozpiętościach, autor doszedł do wniosku, że obecnie stosowana metoda montażu mostów...
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Using Decisional DNA to Enhance Industrial and Manufacturing Design: Conceptual Approach
PublicationDuring recent years, manufacturing organizations are facing market changes such as the need for short product life cycles, technological advancement, intense pressure from competitors and the continuous customers’ expectation for high quality products at lower costs. In this scenario, knowledge and its associated engineering/management of every stage involved in the industrial design has become increasingly important for manufacturing...
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Provenance studies on Late Neolithic amber ornaments from North-East Poland
PublicationThe area of North-East Poland was in prehistory, and still is today, an area with easy access to amber as a raw material, as is evidenced in part by numerous Late Neolithic (3rd millennium) amber workshops located in the Gulf of Gdańsk and Żuławy Wiślane (Vistula Fens). Given this fact, it is surprising that only a few finished amber products have been recovered from this area. Among them are unique ornaments from the Late Neolithic...
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Struktura szkieł krzemianowych z atomami Pb i Bi w świetle badań widm ab-sorpcyjnych promieniowania rentgenowskiego i symulacji dynamiczno-moleku- larnych.**2002, 156 s. 96 rys. 21 tab. bibliogr. 163 poz. maszyn. Rozprawa doktorska /20.12.2002/ WFTiMS PG. Promotor: dr hab.inż. L. Murawski, prof. ndzw. PG.
PublicationCelem niniejszej rozprawy było zbadanie blisko- i średniozasięgowego upo-rządkowania wokół atomów Pb, Bi w szkłach niemodyfikowanych i modyfikowanychpoprzez wygrzewanie w atmosferze wodoru, zbadanie wpływu warunków redukcji iskładu szkła na proces aglomeracji atomów Pb i Bi, określenie podatności ba-danych szkieł na modyfikącję strukturalną oraz weryfikacja oddziaływań mię-dzyatomowych używanych w symulacjach MD.
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Integrated development plans of the functional urban areas in Pomeranian region in Poland
PublicationThe European Commission put a growing emphasis on the territorial and integrated app roach to policy support addressed in the frame of regional policy. In a special way this process refers to cities along with their functional environment. In Poland the National Spatial Development Concept 2030 has introduced the concept of functional areas, among others – Functional Urban Areas (FUAs). There is...
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CZYNNIKI DECYDUJĄCE O PRZYDATNOŚCI KOMPUTEROWEGO MODELU PRZEPŁYWÓW W SIECI WODOCIĄGOWEJ
PublicationW pracy poddano analizie wielozadaniowy proces tworzenia komputerowego modelu przepływów. W efekcie zidentyfikowano szereg czynników ograniczających obszar stosowania modelu w praktyce inżynierskiej. W zakresie pozyskiwania danych strukturalnych i operacyjnych wskazano potencjalne źródła błędów, które przyczyniają się do zmniejszenia dokładności odwzorowania stanu rzeczywistego. Specjalną rangę nadano specyfikacji czynników związanych...
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Chromogenic macrocyclic derivatives of azoles - synthesis and properties,
PublicationNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
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Azomacrocyclic derivatives of imidazole: synthesis, structure, and metal ion complexation properties
PublicationNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
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O urodzie budownictwa socjalnego = About beauty of social housing
PublicationBudownictwo socjalne jest jednym z istotnych aspektów odnowy krajobrazu miejskiego. NAjczęściej kojarzy się ono z tanią architekturą o niskich walorach estetycznych - jednak tanie wcale nie musi oznaczać brzydkie. Mozna projektować i realizować osiedla, które nie tylko zapewniaja byt uboższej zcęści społeczeństwa, ale wnoszą również istotny wkład w wizerunek miasta. Ponadto sektor budowenictwa socjalnego stanowi świetne pole dla...
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Local Dye Concentration and Spectroscopic Properties of Monomer−Aggregate Systems in Hybrid Porous Nanolayers
PublicationAnalysis of absorption, fluorescence, and time-resolved emission spectra of rhodamine 6G in hybrid porous nanolayers at high dye concentration allowed identification of two fluorescent species: monomers and fluorescent aggregates. The method of determination of mean local concentration of aggregates in matrices is proposed based on the energy transfer process between monomers and fluorescent aggregates. Evaluation of aggregate...
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The state of the art in the field of decrease the pollution in the South Baltic area
PublicationVarious form of human activity such as maritime transports, industrial activities, busy traffic, intensive farming and animal husbandry can have negative impact on natural marine environment. Baltic Sea catchment area is characterized by the high river water flux and wastewater treatment plants discharges. Additionally, the limited shallow connection to the North Sea results in little water exchange and residence time of approximately...
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A simple access to o-acyl bicyne
PublicationW publikacji przedstawiono prostą metodę otrzymywania o-acylowych pochodnych bicyny. Substratem do syntezy była n,n-bis(2-hydroksyetylo)glicyna - bicyna. Bicynę najpierw przeprowadzano w ester benzylowy w reakcji z alkoholem benzylowym i kwasem p-toluenosulfonowym w temp. 75 st. C. Tak otrzymany związek, acylowano kwasami organicznymi w obecności DCC ( dicyklokeksylokarbodiimid)i DMAP (dimetyloaminopirydyna), otrzymując o-acylowe...
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KTaO3-based nanocomposites for air treatment
PublicationA series of single semiconductors and their nanocomposites combination (such as KTaO3 + CdSe + SrTiO3; KTaO3 + CdS +WO3; KTaO3 + CdS + MoS2) were prepared using hydrothermal route. Photocatalytic activity of as-prepared nanocomposites was estimated by photocatalytic degradation of toluene in the gas phase using light-emitting diodes (LEDs, 375 nm) in four subsequent cycles. The nanocomposites were characterized by scanning electron...
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Anion binding by p-aminoazobenzene-derived aromatic amides: spectroscopic and electrochemical studies
PublicationThe synthesis and complexing properties of p-aminoazobenzene-derived mono-, bis-, and trisamides were described. Ligands 3 and 4 bind anions, including fluorides, chlorides, bromides, acetates, benzoates, dihydrogen phosphates, hydrogen sulfates, and p-toluenesulfonates, in chloroform forming 1 : 1 complexes. The highest value of stability constant was evaluated for the 4-F− complex (log K = 5.63 ± 0.21). On the basis of 1H NMR,...
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Analytical eco-scale for assessing the greenness of analytical procedures
PublicationWe propose the analytical eco-scale as a novel comprehensive approach to evaluating the greenness of analytical methodology. It is based on assigning penalty points to parameters of an analytical process that are not in agreement with the ideal green analysis. This approach compares different parameters and different steps of the analytical process. Traditional green chemistry metrics 9e.g. Atom Economy, E-factor and Reaction Mass...
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State of the Art of Automated Buses
PublicationUrban transportation in the next few decades will shift worldwide towards electrification and automation, with the final aim of increasing energy efficiency and safety for passengers. Such a big change requires strong collaboration and efforts among public administration, research and stakeholders in developing, testing and promoting these technologies in the public transportation. Working in this direction, this work provides...
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Guanosine Dianions Hydrated by One to Four Water Molecules
PublicationIntermolecular interactions such as those present in molecule···water complexes may profoundly influence the physicochemical properties of molecules. Here, we carried out an experimental–computational study on doubly deprotonated guanosine monophosphate···water clusters, [dGMP – 2H]2–·nH2O (n = 1–4), using a combination of negative anion photoelectron spectroscopy (NIPES) with molecular dynamics (MD) and quantum chemical (QM) calculations....
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Wykorzystanie obszarów morskich pod zabudowę o przeznaczeniu wielofunkcyjnym
PublicationW artykule opisano możliwości zagospodarowania obszarów wodnych na potrzeby rozwoju obszarów miejskich. W kontekście obecnych uwarunkowań ekologicznych oraz bogactwa zasobów obszarów wodnych budownictwo wielofunkcyjne na wodzie ma duże szanse na rozwiązanie problemów dotyczących braku przestrzeni na lądzie. Wiąże się to z rozszerzeniem tradycyjnego podejścia stosowanego przy projektowaniu o elementy związane ze specyfiką konstrukcji...
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Protokół głosowania większościowego w narzędziu wsparcia decyzji handlowych
PublicationIstnieje szerokie spektrum narzędzi i metod wspierających decyzje handlowe, lecz brakuj jasnych reguł ich stosowania. Zaproponowano samoorganizujacy się system agentowy do wspierania decyzji handlowych. System bazując na glosowaniu z dynamicznymi wagami, wskazuje efektywne indykatory na podstawie ich poprzednich osiągnięć. Przedstawiono analizę formalną i wyniki weryfikacji, potwierdzającej cechy rozwiązania.
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Built-in Test Scheme for detection, classification and evaluation of nonlinearities
PublicationW artykule przedstawiono koncepcję testera wbudowanego (BIST) przeznaczonego do detekcji nieliniowości, klasyfikacji rodzaju nieliniowości i oceny zniekształceń nieliniowych sygnału testowanego, bez użycia drogiego systemu automatycznego testowania. Tester bazuje na modulatorze sigma-delta umieszczonym na pakiecie testowanym i sztucznej sieci neuronowej zaimplementowanej w komputerze osobistym. Koncepcję testera zweryfikowano poprzerz...