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Search results for: SPEKTROMETRIA MAS (MS)
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Phenolic compounds from Nerium oleander leaves: microwave assisted extraction, characterization, antiproliferative and cytotoxic activities
PublicationA microwave-assisted extraction (MAE) method was used for the extraction of phenolic compounds from Nerium oleander leaves. The influence of variables such as ethanol concentration, microwave power, irradiation time and liquid/solid ratio on polyphenol extraction was modelled using a second-order regression equation based on response surface methodology (RSM). The optimal conditions for MAE were: extraction solvent 35% ethanol...
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Ekspertyza silnika trakcyjnego tramwaju Dűwag N8C pod kątem wyjaśnienia przyczyny występowania uszkodzeń tego typu silników
PublicationCelem badań było wykonanie ekspertyzy silnika trakcyjnego typu BGK, eksploatowanego w tramwaju Düwag N8C, pod kątem występowania uszkodzeń tych silników. W celu realizacji tego zadania przeprowadzono obserwowaną eksploatację w/w silnika w warunkach rzeczywistych. W tym celu opomiarowano silnik rejestrując w sposób ciągły bieżące wartości prądów i napięć występujących na obu uzwojeniach silnika tj, na uzwojeniu twornika i wzbudzenia....
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Determination of Metals Content in Wine Samples by Inductively Coupled Plasma-Mass Spectrometry
PublicationKnowledge about the metal content of wine is very important, for many reasons. Depending on the element, its quantity varies in wine from ng/L to mg/L. Despite the fact that metals are not directly connected to the taste and aroma of the wine, their content should be determined and controlled, because excess is undesirable, and in some cases prohibited, due to potential toxicity. Several analytical procedures for metal determination...
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Presence of antibiotics in the aquatic environment in Europe and their analytical monitoring: Recent trends and perspectives
PublicationThe presence of antibiotics and their metabolites in the aquatic environment exerts a negative impact on all organisms. Moreover, the easy migration of these substances to drinking water may also have serious consequences for public health, such as drug resistance. Although antibiotics and their metabolites are detected in surface waters and wastewater, there are still no systemic solutions preventing environmental pollution with...
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Solid Phase Microextraction: Apparatus, Sorbent Materials, and Application.
Publicationhe primary objective of this review article is to strategically screen and highlight the advancements in the area of solid phase microextraction (SPME). The plenty of review articles have been written on different aspects of SPME, this review is dedicated to provide the brief but clear overview of the research footprints so produced from SPME. Some of the key advancements in types and designs, coating materials, coating strategies,...
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Bioakumulacja rtęci w łańcuchu troficznym organizmów morskich
PublicationJednym spośród wielu zagrożeń dla środowiska, nieustannie przybierającym na znaczeniu oraz mającym ogromny wpływ na zdrowie organizmów żywych, jest niewątpliwie niebezpieczeństwo związane z rozprzestrzenianiem się metali ciężkich, a zwłaszcza rtęci. Pierwiastek ten i jego związki wykazują dużą toksyczność oraz zdolność do akumulacji w tkankach i organach zwierzęcych i roślinnych. Problem związany ze wzrostem stężeń niebezpiecznych...
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Thermal analysis of copper(II) complexes of general formula [Et4N]2[CuBrnCl4-n]
PublicationBadano dekompozycję termiczną związków składających sie z anionów: [CuBrnCl4-n]2- (n=0-4) i kationów tetrametyloamoniowych. Stosowano następujące metody badawcze: TG-FTIR, TG-MS, DTA i DTG. Pomiary przeprowadzono w atmosferze argonu i powietrza w zakresie temperatur od 293 K do 1073 K. Produkty dekompozycji identyfikowano metoda spektroskopii w podczerwieni (IR i FIR) oraz metodą dyfrakcji promieniowania rentgenowskiego.
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Relationships and bioaccumulation of chemical elements in the Baikal seal (Phoca sibirica)
PublicationOznaczono stężenia w próbkach wątroby foki bajkalskiej, planktonu i zoobentosu ryb stanowiących źródło pokarmu dla fok. Badania przeprowadzono z wykorzystaniem technik ICP-MS oraz ICP-AES. Zbadano wpływ czynników wewnętrzynch i zewnętrznych (środowiskowych) na proces bioakumulacji z wykorzystaniem technik wielowymiarowych (ANOVA, analiza czynników) oraz analizy korelacyjnej. Stwierdzono istotny wpływ płci oraz wieku na proces akumulacji...
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Cyanobacterial toxins in fresh and brackish waters of Pomorskie Province (Northern Poland)
PublicationPraca dotyczy oznaczania toksyn należących do grupy hepatotoksycznych peptydów cyklicznych oraz neurotoksycznych alkaloidów. Są one odpowiedzialne za uszkodzenia ryb i ptaków, które powstają w wyniku zakwitu glonów. Badano zakwity w wodach słodkich Pomorza. Oznaczano hepatoksyny, mikrocysty oraz nodularynę. Opracowano w tym celu warunki analityczne przy zastosowaniu techniki HPLC-DAD. Do identyfikacji anatoksyny-A użyto techniki...
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Path Loss Modelling for Location Service Applications
PublicationThe aim of this paper is the path loss modeling for the radiolocation services in radiocommunication networks, particularly in cellular networks. The main results of the measurements obtained in the physical layer of the UMTS are introduced. A new method for the utilization of the multipath propagation phenomenon to improve the estimation of the distance between the mobile station (MS) and the base station (BS) is outlined. This...
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Load test of new European record holder in span length among extradosed type bridges
PublicationThe article presents acceptance load tests of a newly built extradosed MS-3 bridge located along the national road DK-16 near Ostróda (Poland). The structure features significant dimension in European reference scale. It is a new record holder in span length regarding this distinct bridge category. Its length ranges 206 m. Static and dynamic load tests were performed here. The program was extended by entire structural laser scanning...
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Development of a liquid chromatography–tandem mass spectrometryprocedure for determination of endocrine disrupting compounds infish from Mediterranean rivers
PublicationA new, sensitive and rapid method based on QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe)approach followed by ultra high performance liquid chromatography coupled with tandem mass spec-trometry (UHPLC–MS/MS) was developed for the determination of nineteen endocrine disruptors (EDCs)and related compounds belonging to different classes in various fish species. Matrix effect on the analyti-cal performance was evaluated,...
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Polychlorinated biphenyls (PCBs) and polychlorodibenzo-p-dioxins (PCDDs) determination in disposable baby diapers with the application of natural deep eutectic solvent
PublicationIn this work a new method involving solvent extraction of porous membrane-packed solid samples (SE-PMSS) coupled to gas chromatography-mass spectrometry (GC–MS) has been developed for the determination of six polychlorinated biphenyls (PCBs) and five polychlorodibenzo-p-dioxines (PCDDs) in disposable baby diapers. In that aim, a terpenoid-based natural deep eutectic solvent (NADES) composed of carvone and camphor in a 1:1 M ratio...
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Assessment of baby disposable diapers application for urine collection and determination of phthalate metabolites
PublicationThe baby disposable diapers were investigated as a sampling material for urine collection and validated for the evaluation of the exposure of children to xenobiotics. Phthalate metabolites detected in urine samples were chosen as proof-of-concept analytes. For the determination of phthalate metabolites in children’s urine samples, high performance liquid chromatography coupled with tandem mass spectrometry (HPLC-MS/MS) was used. Two...
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Closing the loop: Upcycling secondary waste materials into nanoarchitectured carbon composites for the electrochemical degradation of pharmaceuticals
PublicationIn this study, we demonstrated the application of electrochemical oxidation as a safer and cleaner technology for minimizing the impact of pharmaceuticals in wastewaters, simultaneously mediated by upcycled secondary waste materials (SWMs)-derived electrodes, to further reduce their environmental impact. The modularity, scalability, ease of operation and reliability make electrochemical oxidation an ideal process for the destruction...
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Mass Spectrometric Identification of 13C-labeled Metabolites During anaerobic Propanoic Acid Oxidation
PublicationBiowaste digestion is a possibility to gain biogas as a renewable fuel source. However, the anaerobic food chain may be disrupted by, e.g., substrate overload or by inhibitors, leading to the accumulation of volatile fatty acids (VFAs), predominantly of propanoic acid (PA). VFA Accumulation may cause a rapid pH decrease, less biogas production, or even a total inhibition. To maintain high biogas productivity or to prevent a collapse...
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A rapid dispersive liquid–liquid microextraction of antimicrobial onion organosulfur compounds in animal feed coupled to gas chromatography-mass spectrometry
PublicationA rapid analytical procedure is proposed for determining two antimicrobial onion organosulfur compounds, propyl disulfide (PDS) and propyl propane thiosulfonate (PTSO), in animal feed. The use of PTSO as a natural ingredient in animal feed is allowed due to its antimicrobial activity against pathogenic organisms. Two analytical methodologies using gas chromatography coupled to mass spectrometry (GC-MS) are compared. After the extraction...
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Quantification of unconjugated and total ibuprofen and its metabolites in equine urine samples by gas chromatography–tandem mass spectrometry: Application to the excretion study
PublicationIbuprofen (IBU) is a widely used nonsteroidal anti-inflammatory drug (NSAID) in human and also veterinary medicine. NSAIDs are usually highly metabolized compounds in horses; they are often present in equine urine, mostly in their conjugated forms (glucuronides). Thus, hydrolysis to cleave the glucuronide linkage prior to anti-doping analysis is often necessary for improving detection. In this study, unconjugated and total IBU...
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Network oscillations modulate interictal epileptiform spike rate during human memory
PublicationEleven patients being evaluated with intracranial electroencephalography for medically resistant temporal lobe epilepsy participated in a visual recognition memory task. Interictal epileptiform spikes were manually marked and their rate of occurrence compared between baseline and three 2 s periods spanning a 6 s viewing period. During successful, but not unsuccessful, encoding of the images there was a significant reduction in...
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Budesonide treatment of professional athletes and anti-doping testing- case studies
PublicationAccording to the World Anti-Doping Agency (WADA) Prohibited List, glucocorticosteroids are prohibited in competition and only when administered by oral, intravenous, intramuscular or rectal routes. Up to now, in order to differentiate whether glucocorticosteroids were administered by one of the prohibited routes or not, a specific reporting limit for urinary concentrations of parent compounds and their metabolites was established...
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Golden artefacts, resin figurines, body adhesives and tomb sediments from the pre-Columbian burial site El Caño (Gran Coclé, Panamá): tracing organic contents using molecular archaeometry
PublicationThis research aimed to determine the origin of organic residues from funerary contexts in the El Ca~no settlement (Gran Cocl�e area, Panam�a, Central America) by means of multiple molecular probing techniques (GC-MS of organic solvent extracts and pyrolysis-GC-MS, THM-GC-MS and FTIR of solid samples). The samples include particles of precious resin figurines, fillings of golden objects, tomb sediments, plant exudates from extant...
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Surface characteristics of glass fibres covered with an aluminum layer after a chemical modification process using secondary ion mass spectrometry (SIMS) and atomic force microscopy (AFM)
PublicationPrzedstawiono wyniki z badań powierzchni modyfikowanych włókien szklanych (przed i po procesie chemicznej modyfikacji ich powierzchni), które są kandydatem na przyszły oryginalny bezmatrycowy materiał odniesienia lotnych analitów etenu (C2H4) metodami spektrometrii mas jonów wtórnych oraz mikroskopii sił atomowych. Badania miały na celu obserwację zmian oraz procesów, jakie zaszły na powierzchni włókien szklanych pokrytych...
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Studies on origin of Polish honeys by two-dimensional gas chromatography Ocena pochodzenia surowcowego polskich miodów przy użyciu dwuwymiarowej chromatografii gazowej
PublicationPolish acacia, linden, rapessed and buckwheat-derived honeys and a honydew were analysed for presence of hydrocarbons, alcs., ketones and esters by 2-dimensional gas chromatog. to establish the markers for the honey origin. PrOH was found characteristic for acacia honey, Me(CH2)11OH for linden honey, Me(CH2)6CHOMe for honeydew and Me(CH2)8COOEt for the rapeseed honey. Wykorzystano technikę dwuwymiarowej chromatografii gazowej sprzężonej...
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Analiza właściwości wytrzymałościowych elastomerów uretanowych napełnionych włóknem szklanym
PublicationCelem pracy było otrzymanie elastomerów uretanowych napełnionych niewielką ilością włókna szklanego o długości ok. 5 mm oraz zbadanie wpływu włókna na właściwości wytrzymałościowe otrzymanego materiału.Poliuretany syntezowano metodą dwuetapową. Na podstawie wyników badań stwierdzono, że włókno szklane o zastosowanej długości i w przyjętej ilości nie powoduje wzrostu wytrzymałości na rozciąganie oraz wydłużenia względnego przy...
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Nowe substancje psychoaktywne. Cz. I. Współczesna sytuacja narkotykowa
PublicationGwałtowny wzrost liczby substancji wprowadzanych na rynek narkotykowy został zaobserwowany już pod koniec lat dziewięćdziesiątych XX wieku. Każdego roku syntezowane są nowe substancje jako analogi już istniejących, a ich ilość systematycznie rośnie. Niejednokrotnie wprowadzenie niewielkiej zmiany w strukturze związku może spowodować znaczne zmiany ich właściwości fizykochemicznych oraz psychoaktywnych. Nowe substancje psychoaktywne...
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WYKORZYSTANIE TECHNIK OLFAKTOMETRII TERENOWEJ I GC×GC-TOFMS DO OCENY UCIĄŻLIWOŚCI ZAPACHOWEJ POWIETRZA ATMOSFERYCZNEGO NA OBSZARACH PRZYLEGŁYCH DO SKŁADOWISKA ODPADOW KOMUNALNYCH W GDAŃSKU SZADÓŁKACH
PublicationW artykule przedstawiono wyniki badań przeprowadzonych na obszarach sąsiadujących ze składowiskiem odpadów komunalnych w Gdańsku-Szadółkach. Do oceny uciążliwości zapachowej powietrza atmosferycznego wykorzystano technikę olfaktometrii terenowej. Narzędziami, których wykorzystanie umożliwia badanie właściwości zapachowych odorantów występujących w powietrzu atmosferycznym in-situ są olfaktometry terenowe, których zastosowanie umożliwia...
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Thermal analysis of bis(tetraethylammonium) tetrachloroferrate(II)
PublicationBadano dekompozycję termiczną związków bis(tetraethylammonium) tetrachloroferrate(II). Stosowano następujące metody badawcze: TG-FTIR, TG-MS i DTA. Pomiary przeprowadzono w atmosferze obojętnej w zakresie temperatur od 293 K do 1073 K. Stałe produkty dekompozycji identyfikowano metodą spektroskopii w podczerwieni, spektroskopii Mössbauera oraz metodą dyfrakcji promieniowania rentgenowskiego. Przedyskutowano wpływ stopnia utlenienia...
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Radio Link Measurement Methodology for Location Service Applications
PublicationThe aim of this paper is the methodology of measurements executed in a radio link for the realization of radiolocation services in radiocommunication networks, particularly in cellular networks. The main results of the measurements obtained in the physical layer of the universal mobile telecommunications system (UMTS) are introduced. A new method for the utilization of the multipath propagation phenomenon to improve the estimation...
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Some advances in environmental analytics and monitoring
PublicationW pracy przedstawiono wkład Katedry Chemii Analitycznej w rozwój analityki środowiskowej i monitoringu, ze szczególnym uwzględnieniem analityki pozostałości leków w próbkach wodnych ( w układzie on-line i off-line), badań nad identyfikacją produktów degradacji organicznych zanieczyszczeń, analizy toksyn w wodach za pomocą techniki HPLC-DAD-MS, wykorzystania dozymetrii pasywnej do izolacji analitów z wody oraz jednoczesnego oznaczania...
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A study on the protection of methionine and the reduction of methionine sulfoxide in methionine-containing analogues of the growth-modeling factor Gly-His-Lys
PublicationThe protection of methionine and the reduction of methionine sulfoxide in methionine-containing analogues of Gly-His-Lys are described. The peptides were synthesized by a solid-phase method using the standard Fmoc procedure. Simultaneous deprotection of the peptide side chain and liberation from the resin were achieved using an appropriate TFA cocktail. The TFA cocktail was selected to minimize oxidation of the methionine residue....
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Capillary gas chromatography using a -cyclodextrin forenantiomeric separation of methylamphetamine, its precursors andchloro intermediates after optimization of the derivatization reaction
PublicationtThe enantiomeric ratio of methylamphetamine (MAMP) is closely related to the optical activity of precur-sors and reagents used for the synthesis and this knowledge can provide useful information concerningthe origins and synthetic methods used for illicit manufacture. The information can be utilized for reg-ulation of the precursors and investigation of the manufacturing sources but this requires analyticalprocedures to determine...
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Comprehensive methodology for Staphylococcus aureus lipidomics by liquid chromatography and quadrupole time-of-flight mass spectrometry
PublicationStaphylococcus aureus is a common pathogen known to cause relatively minor infections as well as severe disorders in humans. Although there is fair amount of published data concerning various aspects of its biology, epidemiology, genetics, etc., there is still a scarce amount of data presenting reliable and thorough investigations regarding high-throughput analysis of total S. aureus lipid content. Therefore, the aim of this study...
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Unveiling the Pool of Metallophores in Native Environments and Correlation with Their Potential Producers
PublicationFor many organisms, metallophores are essential biogenic ligands that ensure metal scavenging and acquisition from their environment. Their identification is challenging in highly organic matter rich environments like peatlands due to low solubilization and metal scarcity and high matrix complexity. In contrast to common approaches based on sample modification by spiking of metal isotope tags, we have developed a two-dimensional...
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A Closed Bipolar Electrochemical Cell for the Interrogation of BDD Single Particles: Electrochemical Advanced Oxidation
PublicationA closed bipolar electrochemical cell containing two conductive boron-doped diamond (BDD) particles of size 250 – 350 m, produced by high-pressure high-temperature (HPHT) synthesis, has been used to demonstrate the applicability of single BDD particles for electrochemical oxidative degradation of the dye, methylene blue (MB). The cell is fabricated using stereolithography 3D printing and the BDD particles are located at either...
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Red Kale (Brassica oleracea L. ssp. acephala L. var. sabellica) Induces Apoptosis in Human Colorectal Cancer Cells In Vitro
PublicationThis article presents the results of studies investigating the effect of red kale (Brassica oleracea L. ssp. acephala L. var. sabellica) extract on cancer cells (HT-29). The cytotoxicity of the red kale extract was assessed using MTT and LDH assays, while qRT-PCR was employed to analyze the expression of genes associated with the p53 signaling pathway to elucidate the effect of the extract on cancer cells. Furthermore, HPLC-ESI-QTOF-MS/MS...
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Boron-doped carbon nanowalls for fast and direct detection of cytochrome C and ricin by matrix-free laser desorption/ionization mass spectrometry
PublicationDetecting proteins via surface assisted laser desorption/ionization mass spectrometry (SALDI-MS) method is still highly challenging, and only few examples of nanomaterials have been demonstrated to perform such detection so far. In this study, carbon nanowalls (CNWs), vertically aligned graphene sheet-based materials, presenting specific morphology, dimensions, and boron doping levels have shown improved performances for both qualitative...
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Determination of antifreeze substances in the airport runoff waters by solid-phase microextraction and gas chromatography–mass spectrometry method
PublicationA new method has been developed for the determination of antifreeze agents such as ethylene glycol (EG), propylene glycol (PG), and diethylene glycol (DEG) in the samples of airport runoff water. The method is based on headspace solid–phase microextraction (HS–SPME) of target analytes, which is coupled with gas chromatography–mass spectrometry (GC–MS). Until now, there was a lack of appropriate methodology for collecting reliable...
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Multi-Technique Investigation of Grave Robes from 17th and 18th Century Crypts Using Combined Spectroscopic, Spectrometric Techniques, and New-Generation Sequencing
PublicationThe textile fragments of the funeral clothes found in the 17th and 18th century crypts were subjected to spectroscopic, spectrometric, and microbial investigation. The next-generation sequencing enabled DNA identification of microorganisms at the genus and in five cases to the species level. The soft hydrofluoric acid extraction method was optimized to isolate different classes of dyes from samples that had direct contact with...
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Ultrasound-Assisted Solvent Extraction of a Porous Membrane Packed Sample for the Determination of Tobacco-Specific Nitrosamines in the Replacement Liquids for E-Cigarettes
PublicationThe content of tobacco-specific nitrosamines (TSNAs) possessing carcinogenic properties has been an important area of research since replacement liquids were introduced for e-cigarettes. A method for determining N′-nitrosonornicotine (NNN), 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK), N′-nitrosoanatabine (NAT), and N′-nitrosoanabasine (NAB) in replacement liquids for electronic cigarettes was developed using liquid chromatography–tandem...
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Organic Acids and Polyphenols Determination in Polish Wines by Ultrasound-Assisted Solvent Extraction of Porous Membrane-Packed Liquid Samples
PublicationIn the near future, Poland is going to have more and more favorable conditions for viticulture. Organic acids and polyphenols are among the most commonly analyzed compounds due to their beneficial properties for human health and their importance in the winemaking process. In this work, a new technique involving ultrasound-assisted solvent extraction of porous membrane-packed liquid samples (UASE-PMLS) was for the first time described...
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Carbon nanowalls: A new versatile graphene based interface for laser desorption/ionization-mass spectrometry detection of small compounds in real samples.
PublicationCarbon nanowalls, vertically aligned graphene nanosheets, attract attention owing to their tunable band-gap, high conductivity, high mechanical robustness, high optical absorbance and other remarkable properties. In this paper, we report for the first time, the use of hydrophobic boron-doped carbon nanowalls (CNWs) for laser desorption/ionization of small compounds and their subsequent detection by mass spectrometry (LDI-MS). The...
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Convenient identification of desulfoglucosinolates on the basis of mass spectra obtained during liquid chromatography-diode array-electrospray ionisation mass spectrometry analysis: Method verification for sprouts of different Brassicaceae species extracts
PublicationOver the past decade, glucosinolates (GLs) present in different tissues of Brassicaceae and their breakdown products, especially isothiocyanates formed after myrosinase catalyzed hydrolysis, have been regarded as not only environment friendly biopesticides for controlling soilborne pathogens, but most importantly as promising anticarcinogenic compounds. For these reasons, the identification and quantitative determination of the...
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Zastosowanie technik dwuwymiarowych w analizie frakcji lotnej i oznaczaniu związków bioaktywynych owoców jagody kamczackiej
PublicationDotychczasowe doniesienia literaturowe wskazują, że owoce strefy borealnej, do których należy popularna w Polsce aronia, są źródłem cennych składników odżywczych i prozdrowotnych. Podobnie jagoda kamczacka, należąca do tej grupy owoców, może stanowić źródło substancji istotnych dla ludzkiej diety. Jednakże aktualny stan wiedzy o składzie chemicznym owoców jagody kamczackiej ogranicza się głównie do informacji dotyczących całkowitej...
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Composition and antimicrobial activity of fatty acids detected in the hygroscopic secretion collected from the secretory setae of larvae of the biting midge Forcipomyia nigra (Diptera: Ceratopogonidae)
PublicationThe hygroscopic secretion produced by the secretory setae of terrestrial larvae of the biting midge Forcipomyia nigra (Winnertz) was analysed using gas chromatography coupled with mass spectrometry (GC-MS). The viscous secretion is stored at the top of each seta and absorbs water from moist air. GC-MS analyses (four independent tests) showed that the secretion contained 12 free fatty acids, the most abundant of which were oleic...
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Analytical methods for exhaustive characterization of Brassica plants and dietary products based on them
PublicationGlucosinolates (GLs), and particularly two classes of their degradation products - isothiocyanates (ITC) and indoles - released upon myrosinase catalyzed hydrolysis, belong to the most promising chemopreventive dietary components. Despite their wide use in plant research, studies on chemopreventive mechanisms and industrial utilization in the production of e.g. dietary supplements, the methods of reliable characterization of myrosinase-GLs...
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Ocena narzędzi wspomagających zarządzanie przedsięwzięciami informatycznymi na przykładzie IBM Rational Method Composer
PublicationRozdział przedstawia zalety i wady oprogramowania wspomagającego zarządzanie przedsięwzięciami informatycznymi. Skupia się na ocenie technologii informatycznej spopularyzowanej na rynku przez firmę IBM jako Rational Method Composer. W rozdziale zostały zaproponowane kryteria oceny z punktu widzenia menedżera zarządzającego przedsięwzięciem oraz oceny w zależności od stopnia spełnienia tego kryterium. Ponadto przeprowadzona została...
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An attempt to identify volatile and semi-volatile organic compounds present in the Odra river waters.
PublicationCelem pracy była identyfikacja związków z grup lotnych i średniolotnych związkó organicznych. W badaniach wykorzystano technikę Pt-TD-GC-MS. Komputerowa analiza widm masowych wykazała obecność wielu związków organicznych pochodxenia naturalnego i antropogenicznego. W powłokach wód pobranych w okolicy Brzegu Dolnego oznaczono stężenia związków chloroorganicznych na poziomie pojedynczych prób. Nieco wyższe spektrum związków chloroorganicznych,...
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The analysis of raw spirits – a review of methodology
PublicationAgricultural distillates (raw spirits) are alc oholic l iquids obtained thro ugh dis till ation (preceded by alcoholic ferm entation)of specific agricultural products that do not have the properties of ethyl alcohol or a spirit, but still retain th e aroma andtaste of the raw ingredients used. This review is a brief overview of agricultural distillates and of some methods commonlyused (GC-MS, GC-FID, GC-O, electronic nose) for...
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Funcionality assessment of Citrus Hysteria peel as a protective barrier using gas chromatography
PublicationThe aim of this study was to analyse the volatile fractions of fruit peel and pulp using two-dimensional gas chromatography technique coupled with mass spectrometry. The isolation of the compounds was achieved by microextraction to the stationary phase from the headspace of the sample (HS-SPME). Mass spectrometry with time-of-flight analyser (TOF-MS) was used to identify the chemical compounds. There are no reports in the literature...
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The influence of 4,4'-bis(6-hydroxyhexoxy)biphenyl moieties on properties of polyurethanes based on 4,4'-methylenebis(cyclohexyl isocyanate)
PublicationZsyntetyzowano dwie serie poliuretanów z 4,4'-bis(6-hydroksyheksyloksy)bifenylu (BH6), poliadypinianu 1,6-heksylenu i diizocyjanianu 4,4'-dicykloheksylometanu o udziałach izomeru trans, wynoszącym odpowiednio 16 i 46%. Badano wpływ udziału wagowego (u) małocząsteczkowego diolu(BH6)w odniesieniu do sumy mas komonomerów diolowych, na właściwości uzyskanych poliuretanów metodami DSC, DTA, TGA, mikroskopii polaryzacyjnej, WAXS, DMTA...