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Możliwość wykorzystania popiołów z osadów ściekowych w betonie
PublicationIlość popiołów lotnych ze spalania osadów ściekowych rośnie na całym świecie. Ich unieszkodliwianie jest poważnym problemem ekologicznym. W pracy przedstawiono ocenę możliwości wykorzystania popiołów lotnych z osadów ściekowych w betonie. Wykonano dwie serie badawcze dla dwóch współczynników (w/s) równych 0,49 oraz 0,55 z udziałem 10% i 20% popiołu lotnego (SSA), jako zamiennika cementu. Skład chemiczny wykazał, że popiół (SSA)...
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Nanosilver-loaded PMMA bone cement doped with different bioactive glasses – evaluation of cytocompatibility, antibacterial activity, and mechanical properties
PublicationNanosilver-loaded PMMA bone cement (BC-AgNp) is a novel cement developed as a replacement for conventional cements. Despite favorable properties and antibacterial activity, BC-AgNp still lacks biodegradability and bioactivity. Hence, we investigated the doping with bioactive glasses (BGs) to create a new bioactive BC characterized by time-varying porosity and gradual release of nanosilver. The BC Cemex was used as the base material...
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State of the art in the field of emission reduction of sulphur dioxide produced during coal combustion
PublicationThe need for clean coal technologies to reduce the adverse environmental impact of coal combustion products has been grounded. The article deals with information concerning present and future technologies, directed towards the struggle against air pollution by SO2, produced during coal combustion. Their classification and critical rating from economical and technological points of views (including those developed by authors) have...
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Expert systems in assessing the construction process safety taking account of the risk of disturbances
PublicationThe objective of the paper is to present the issue of safety manage-ment during the construction process. Threats in the form of disturb-ances may occur in the preparatory phase, during the execution of the construction project and also during its operational use. The arti-cle presents the concept of applying the methodology based, among others, on Learning Bayesian Networks, Artificial Neural Networks and Support Vector Machine,...
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Stability Investigation of the PCM Nanocomposites
PublicationEnsuring the stability is a key issue to be solved for the technical application of nanocomposites. In this work, fatty acid P1801 served as base phase change material (PCM)P1801, and its main ingredients are palmitic acid (58%) and stearic acid (38%). Titania (TiO2) and alumina (Al2O3) with mass concentrations of 1% and 5% were selected as nanoparticles, while polyvinylpyrrolidone (PVP) or oleic acid (OA) with mass concentrations...
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Magnetic field effects in dye-sensitized solar cells controlled by different cell architecture
PublicationThe charge recombination and exciton dissociation are generally recognized as the basic electronic processes limiting the efficiency of photovoltaic devices. In this work, we propose a detailed mechanism of photocurrent generation in dye-sensitized solar cells (DSSCs) examined by magnetic field effect (MFE) technique. Here we demonstrate that the magnitude of the MFE on photocurrent in DSSCs can be controlled by the radius and...
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Modelling long-term technological transition of Polish power system using MARKAL: Emission trade impact
PublicationThe need for technological transition of electricity production becomes a global problem. However, in coal-dominated Polish power system this need is even more crucial than anywhere, since technical lifetime of the most domestic power plants is ending. In this paper, the impact of the EU Emission Trading Scheme (EU ETS) for CO2 combined with sulfur dioxide (SO2) and nitrogen oxides (NOx) emission trading mechanism on power technology...
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KTaO3-based nanocomposites for air treatment
PublicationThe advantage is that photocatalytic methods allow removing VOCs, NOx, SO2, deodorants, and microorganisms at the same system. The new third generation of photoactive materials activated by low powered and low cost irradiation sources (such as LEDs or black fluorescent UV lamps) can be used as photocatalysts in air purification systems. A series of single semiconductors and their nanocomposites combination were prepared using hydrothermal...
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Stability investigation of the PCM nanocomposites
PublicationIn present study was showed the results of research the stability of nanoPCMs in terms of types and concentrations of surfactant used. For stearic acid has been added PVP or oleic acid in concentrations of 0%, 5% and 10%. Nanoparticles TiO2 and Al-2O3 in concentration of 1% were chosen to be researched in this test. The mixing of nanocomposites has been done in an ultrasonic scrubber in which the samples were placed for 45 mins....
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Higher harmonics of the intensity modulated Photocurrent/Photovoltage spectroscopy response - a tool for studying photoelectrochemical nonlinearities
PublicationIn this work, a higher harmonic analysis (HHA) of the intensity modulated photocurrent/photovoltage (IMPS/IMVS) spectroscopy data is proposed as a potent tool for studying nonlinear phenomena in photoelectrochemical and photovoltaic systems. Analytical solutions of kinetic equations were constructed for cases of single and double resonance accounting for various sources of higher harmonics. These sources correspond to the physical...
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Peroxymonosulfate-assisted photocatalytic degradation of artificial sweeteners in water
PublicationIn the present study, peroxymonosulfate (PMS) activation was proposed for efficient photocatalytic degradation of aspartame, acesulfame, saccharin, and cyclamate - artificial sweeteners frequently present in wastewaters and surface waters worldwide. The TiO2 nanosheets with exposed {0 0 1} facets were synthesised using the fluorine-free lyophilisation technique as a green concept for the synthesis and used for the photodegradation...
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Fabrication of Bi6Fe2Ti3O18 Ceramics by Mixed Oxide Method
PublicationIn the present study Bi6Fe2Ti3O18 (BFTO) ceramics has been fabricated by solid state reaction from the mixture of simple oxides viz. Bi2O3, TiO2 and Fe2O3. Stoichiometric mixture of the powders was thermally analyzed so parameters of the thermal treatment were determined. The EDS measurements have shown conservation of the chemical composition of the ceramic powder after calcination. Hot-pressing method was used for final densification...
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Ordered titania nanotubes layer selectively annealed by laser beam for high contrast electrochromic switching
PublicationThe phase conversion from amorphous into crystalline one in the selected area of as-anodized titania nanotubes was achieved via laser treatment. The optimized processing parameters enable fast, one-minute crystallization of titania within an area limited by a shadow mask and without any morphology damage of ordered TiO2 tubular film. The laser annealed titania nanotubes could be easily overgrown by a conducting polymer without...
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Collagen and hyaluronic acid hydrogel in water-in-oil microemulsion delivery systems
PublicationThe efficacy of microemul-sion in dermal and transdermal delivery of active ingredients. Here, we assessed the water-in-oilmicroemulsion capacity to incorporate two natural polymers, i.e. collagen and hyaluronic acid withlow and high molecular weight. Systems were extensively characterized in terms of conductivity, phaseinversion studies, droplet diameter, polydispersity index and rheological properties. The results of thisresearch...
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Experiments on compression ignition engine powered by nano-fuels
PublicationThe use of nanoparticles in fuels provides new opportunities for modification of fuel properties, which may affect the operational parameters of engines, in particular the efficiency and fuel consumption. The paper presents comparison of compression ignition engine performance fuelled with neat diesel and nano-diesel. Alumina (Al2O3) was used as nanoparticles. Surface-active substances, including Span 80 surfactant, as well as...
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Air-sparged hydrocyclone (ASH) technology for separation and environmental clean-up
PublicationPrzedstawiono zastosowanie technologii wykorzystującej napowietrzany reaktor cyklonowy w oczyszczaniu środowiska. W pierwszych opracowaniach reaktora cyklonowego wykorzystano wkłady ze stali porowatej i polietylenu jako kontaktory fazy gazowej z ciekłą. Jako wynik badań nad rozwojem technologii wkłady porowate zostały zastąpione metalowymi siatkami, co wyeliminowało problem zatykania się elementów. Przeprowadzone badania laboratoryjne...
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Magnetic photocatalysts for water treatment
PublicationThe concept of magnetic photocatalysts with separation function requires ferromagnetic material with high magnetic susceptibility to an external magnetic field to enable recycling of composite nanoparticles. Currently, much attention is devoted to functionalization of photocatalyst using MFe2O3, where M =Fe, Zn, Co, Mn. However direct contact between photocatalyst and magnetic iron oxide particles leads to photodissolution of iron...
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Hybrid electrode materials for fast performance devices
PublicationEnergy storage devices such as Electrochemical Double Layer Capacitors and other types of the electrochemical capacitors require chemically stable, non-soluble, electrochemically active electrode materials compatible with appropriate electrolytes. Factors which determine their applicability are derived from so called electrochemical window of electroltes, nature of charge accumulation and their kinetics. On the other hand technological...
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Influence of Cement Replacement with Sewage Sludge Ash (SSA) on the Heat of Hydration of Cement Mortar
PublicationThe amount of fly ash from the incineration of sewage sludge is increasing all over the world, and its utilization is becoming a serious environmental problem. In the study, a type of sewage sludge ash (SSA) collected directly from the municipal sewage treatment plant was used. Five levels of cement replacement (2.5%, 5%, 7.5%, 10% and 20%) and unchanged water-to-binder (w/b) ratio (0.55) were used. The purpose of the study was...
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New Carvone-Based Deep Eutectic Solvents for Siloxanes Capture from Biogas
PublicationDuring biogas combustion, siloxanes form deposits of SiO2 on engine components, thus shortening the lifespan of the installation. Therefore, the development of new methods for the purification of biogas is receiving increasing attention. One of the most effective methods is physical absorption with the use of appropriate solvents. According to the principles of green engineering, solvents should be biodegradable, non-toxic, and...
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Unraveling a novel microwave strategy to fabricate exposed {001}/{101} facets anatase nanocrystals: Potential for use to the elimination of environmentally toxic metronidazole waste
PublicationThis study present a novel microwave strategy to fabricate highly active anatase particles, exposing {101} and {001} facets. Microwave treatment time was shown to determine the growth of crystals in a certain direction. To the best of our knowledge, it is the first report revealing that the contact time of TiO2 crystals with fluorine ions during the microwave process affects the formed morphology, in particular exposed facets ratio....
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Protein overproduction alters exosome secretion in Chinese hamster ovary cells
PublicationDespite the abundance of available cell lines, nearly 70% of all recombinant therapeutic proteins today are produced in Chi-nese hamster ovary (CHO) cells. The impact of protein overproduction on the secretion of exosomes by CHO cells has been investigated here. Increased secretion of extracellular vesicles (EVs) by protein overexpressing CHO cells was demonstrated with protein content assay, nanoparticle tracking analysis, and...
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Nanoparticles displacement analysis using optical coherence tomography
PublicationOptical coherence tomography (OCT) is a versatile optical method for cross-sectional and 3D imaging of biological and non-biological objects. Here we are going to present the application of polarization sensitive spectroscopic OCT system (PS-SOCT) for quantitative measurements of materials containing nanoparticles. The PS-SOCT combines the polarization sensitive analysis with time-frequency analysis. In this contribution the benefits...
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X-RAY DIFFRACTION STUDY OF BISMUTH LAYER-STRUCTURED MULTIFERROIC CERAMICS
PublicationGoal of the present research was to apply a solid state reaction route to fabricate bismuth layer-structured multiferroic ceramics described with the formula Bi5FeTi3O15 and reveal the influence of processing conditions on its crystal structure and phase composition. Simple oxide powders Bi2O3, TiO2 and Fe2O3 were used to fabricate Aurivillius-type bismuth layer-structured ferroelectrics. Pressureless sintering in ambient air was...
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Burnout Investigation of Small Diameter Tubes Immersed in Nanofluids
PublicationThis paper deals with research into pool boiling critical heat flux (CHF) of water–Al2O3, water–TiO2 and water–Cu nanofluids on horizontal stainless steel tubes. The experiments were conducted under atmospheric pressure. Nanoparticles were tested at concentrations of 0.001%, 0.01%, 0.1% and 1% by weight. Ultrasonic vibration was used in order to stabilize the dispersion of the nanoparticles. Although dispersants were not used to...
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Topochemical, Single‐Crystal‐to‐Single‐Crystal [2+2] Photocycloadditions Driven by Chalcogen‐Bonding Interactions
PublicationThe face-to-face association of (E)-1,2-di(4-pyridyl)ethylene (bpen) molecules into rectangular motifs stabilized for the first time by chalcogen bonding (ChB) interactions is shown to provide photoreactive systems leading to cyclobutane formation through single-crystal-to-single-crystal [2+2] photodimerizations. The chelating chalcogen bond donors are based on original aromatic, ortho-substituted bis(selenocyanato)benzene derivatives...
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THEORETICAL POTENTIAL OF HYDROGEN PRODUCTION FROM TEXTILES WASTES IN POMERANIAN REGION BY MEANS OF DARK FERMENTATION
PublicationModel has been developed for calculating theoretical mass of hydrogen produced from textile wastes by mean of dark fermentation. As vegetable fibres wastes were chosen two mostly used — cotton and linen (flax). As the synthethic carbohydrate rich fiber was chosen viscose. In the background there were introduced: problems of dark fermentation, characteristics of textile material structure. Additionally pathways of the process...
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Potential of ASH technology for protection against chemical and biological attacks
PublicationTechnologia wykorzystująca reaktor cyklonowy dzięki dużej wydajności posiada szczególne predyspozycje do usuwania lub niszczenia składników broni chemicznej i biologicznej ze strumieni gazów o dużym natężeniu przepływu, pochodzących z systemów ogrzewania, wentylacji i klimatyzacji, bez powodowania znacznych spadków ciśnienia. Reaktor cyklonowy posiada znaczne mniejsze rozmiary, około 10% objętości tradycyjnych systemów oczyszczania...
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Reliability of flue gas desulphurisation installations - the essential condition of efficient air pollution control
PublicationW celu minimalizacji niekorzystnego wpływu SO2 i SO3 na środowisko naturalne w wielu instalacjach skrubery odsiarczające gaz spalinowy (FGD) stosowane są do usuwania tlenków siarki z gazów wylotowych. Ostre warunki pracy skruberów i dodatkowego osprzętu powodują problemy korozyjne w powszechnie stosowanych materiałach konstrukcyjnych a awarie wywierają długookresowy wpływ na środowisko. Opisano najnowsze doświadczenia związane...
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Photocatalytic Air Purification
PublicationW publikacji zostały omówione mechanizmy i wpływ różnych czynników na fotokatalityczne usuwanie zanieczyszczeń powietrza, takich jak lotne związki organiczne (VOC), NOx i SO2. Został dokonany przegląd artykułów i patentów dotyczących przygotowywania fotokatalizatorów i technik ich osadzania na nośnikach. Zaprezentowane zostały przykłady fotoreaktorów przystosowanych do pracy w fazie gazowej. Część opisanych reaktorów może być użyta...
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Effect of Maximal Apnoea Easy-Going and Struggle Phases on Subarachnoid Width and Pial Artery Pulsation in Elite Breath-Hold Divers
PublicationPurpose: The aim of the study was to assess changes in subarachnoid space width (sas-TQ), the marker of intracranial pressure (ICP), pial artery pulsation (cc-TQ) and cardiac contribution to blood pressure (BP), cerebral blood flow velocity (CBFV) and cc-TQ oscillations throughout the maximal breath hold in elite apnoea divers. Non-invasive assessment of sas-TQ and cc-TQ became possible due to recently developed method based on...
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BACTERIAL INACTIVATION VIA LASER-DRIVEN GOLD NANOPARTICLE HEATING: SIMULATION AND ANALYSIS
PublicationThis study utilizes CFD technique to simulate the inactivation of E. coli bacteria within a microfluidic chamber, employing gold nanoparticles irradiated by a laser beam. Employing a single-phase model, the presence of bacteria is considered by treating thermal properties in the governing equations as effective, combining those of water and bacteria using established correlations from scientific literature. The conversion of light...
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Direct reduction of pellets through hydrogen: Experimental and model behaviour
PublicationThis paper presents the hydrogen reduction behaviour of industrial pellets designed for the efficient hydrogen based direct reduction. The pellets were provided with very low non ferrous oxides percentage (0.52 of basicity index) and with the absence on TiO2 oxides. The pellets measured diameters in the range 1.14–1.72 cm and were characterized in terms of porosity, pores size, tortuosity and compression strength. The pellets were...
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Nanolayers in Fiber-Optic Biosensing
PublicationIn this chapter, fiber-optic sensors based on nanolayers or thin films and their ability to perform biophotonic measurements is presented. In the last decade, fiber-optic sensors have gained popularity as biosensing devices. This has been made possible because of the design and the integration of new materials in fiber-optic technology. Nanolayers and thin films made from various materials such as nanodiamond (NCD), boron-doped...
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Mechanical Behavior of Bi-Layer and Dispersion Coatings Composed of Several Nanostructures on Ti Substrate
PublicationThree coatings suitable for biomedical applications, including the dispersion coating composed of multi-wall carbon nanotubes (MWCNTs), MWCNTs/TiO2 bi-layer coating, and MWCNTs-Cu dispersion coating, were fabricated by electrophoretic deposition (EPD) on Ti Grade II substrate. Optical microscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and nanoindentation were applied to study topography, chemical, and...
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Thermal analysis of Magnetohydrodynamics (MHD) Casson fluid with suspended Iron (II, III) oxide-aluminum oxide-titanium dioxide ternary-hybrid nanostructures
PublicationThis study is carried out to enhance and analyze the thermal performance of non-Newtonian Casson fluid by immersing Ternary hybrid nanoparticles Fe3O4-Al2O3-TiO2 uniformly. To model the behaviour of such complex phenomena mathematically, a system of complex transport differential equations is developed by utilizing a non-Fourier heat transfer model for energy transport. The non-dimensional system of transport equations involving...
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Analytical Estimation of Power Losses in a Dual Active Bridge Converter Controlled with a Single-Phase Shift Switching Scheme
PublicationMicro-grid solutions around the world rely on the operation of DC/DC power conver- sion systems. The most commonly used solution for these topologies is the use of a dual active bridge (DAB) converter. Increasing the efficiency and reliability of this system contributes to the improvement in the stability of the entire microgrid. This paper discussed an analytical method of energy efficiency and power loss estimation in a single...
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Investigation of the temperature modulation parameters on semiconductor gas sensor response
PublicationIn this work we present the results of the investigation of the sensing properties of semiconductor gas sensors with a sinusoidally modulated temperature in the presence of synthetic air (SA) and three volatile air pollutants, i.e. NH3, NO2 and SO2. The measurements were performed for different average sensor heater temperatures and the amplitude of the modulation signal. In addition, the extraction of features from the sensor...
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Barium boron aluminum silicate glass system for solid state optical gas sensors
PublicationRecent increasing demand for new eco-friendly materials and for low cost fabrication process for use in optical sensors field, raise concern about alternative materials for this application. We have designed two glass-ceramics compositions from the quaternary ROAl2O3- SiO2-B2O3(R=Ba) alkali-earth aluminum silicate system, labeled B72 and B69, with high refractive index (>1.6), large values of Abbe number (94.0 and 53.0, respectively),...
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The influence of selenium addition during germination of Brassica seeds on health-promoting potential of sprouts
PublicationThe correlation among selenium uptake, the content of bioactive compounds in sprouts, and biological activities triggered in cultured human cells by sprout extracts was investigated. Seeds of Brassica crops and rye were treated with SeO2 water solution. The selenium levels in sprouts increased from 1.0-4.1 to 53.3-382 μg/g dw with no influence on plant physiology according to the indices used. Neither the composition of glucosinolates...
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Fotokatalityczne uzdatnianie wody basenowej = Photocatalytic treatment of swimming pool water
PublicationW uzdatnianiu wody obserwuje się wzrastające znaczenie alternatywnych rozwiązań technologicznych, do których należą metody zaawansowanego utleniania oraz metody fotokatalityczne z zastosowaniem promieniowania ultrafioletowego a także, coraz częściej, promieniowania w zakresie widzialnym (słonecznego). W tym odniesieniu, przedstawiono istotę fotokatalizy w nadfiolecie i w zakresie widzialnym oraz sposoby przygotowania fotokatalizatorów...
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Featuring Semitransparent p–i–n Perovskite Solar Cells for High-Efficiency Four-Terminal/Silicon Tandem Solar Cells
PublicationTwo issues need to be resolved when fabricating p–i–n semitransparent perovskite solar cells (ST-PVSCs) for four-terminal (4 T) perovskite/silicon tandem solar cells: 1) damage to the underlying absorber (MAPbI3), electron transporting layer ([6,6]-phenyl-C61-butyric acid methyl ester, PCBM), and work function (WF) modifier (polyethylenimine, PEI), resulting from the harsh sputtering conditions for the transparent electrodes (TEs)...
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Effect of ionic liquids on surface and photocatalytic properties of selected semiconducttors
PublicationThe main aim of this doctoral dissertation was to explain the role of ionic liquids in shaping the morphology of selected semiconductors, thereby enhancing the photocatalytic activity. In order to achieve this goal, the following research steps were taken: (i) developing synthesis methods of selected semiconductors, with particular emphasis on the electrochemical oxidation method; (ii) understanding the influence of the selected...
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Advanced operating methods
PublicationSelected operating methods of resistive gas sensors were presented. The methods utilize flicker noise (1/f noise), which gives additional information about ambient gas when compared with the recorded changes of DC resistance only. Methods of flicker noise measurements were outlined. Recently developed prototype gas sensors comprising golden nanoparticle functionalized with organic ligands can generate intense flicker noise induced...
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Influence of operation temperature instability on gas sensor performance
PublicationGas sensors based on the semiconducting metal-oxides, such as SnO2, have been found to be very useful for detecting a wide range of gases. The reversible interactions of the gas with the surface of the sensing layer made of semiconducting metal-oxides are responsible for changes of sensor resistance which is usually used as a measure of sensor response. Semiconductor gas sensors are commercially available and applied in numerous...
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Impact of dyes isomerization effect on the charge transfer phenomenon occurring on the dye/nanosemiconductor interface
PublicationThe present work aimed to find the answer how does the isomerization of the Ru based dyes affect the overall photon-to-current efficiency of the DSSCs and to explain the charge transfer phenomenon occurring on the dye/ nanosemiconductor interface. Therefore, electronic and optical properties of three bipyridine derivatives anchored on the TiO2 electrode were investigated by computational simulations based on quantum chemistry codes...
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Sympathetic Activation Does Not Affect the Cardiac and Respiratory Contribution to the Relationship between Blood Pressure and Pial Artery Pulsation Oscillations in Healthy Subjects
PublicationUsing a novel method called near-infrared transillumination backscattering sounding (NIR-T/BSS) that allows for the non-invasive measurement of pial artery pulsation (cc-TQ) and subarachnoid width (sas-TQ) in humans, we assessed the influence of sympathetic activation on the cardiac and respiratory contribution to blood pressure (BP) cc-TQ oscillations in healthy subjects. The pial artery and subarachnoid width response to handgrip...
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Silver-modified titania with enhanced photocatalytic and antimicrobial properties under UV and visible light irradiation
PublicationCommercial titania photocatalysts were modified with 2 wt% of silver by photodeposition. The properties of the samples were characterized by DRS, XPS, XRD, FE-SEM and STEM. The modified samples exhibited activity under visible light and enhanced activity under UV irradiation for 2-propanol and acetic acid oxidation, respectively. The time-resolved microwave conductivity (TRMC) analysis indicated that enhanced activity (2.5–8-fold...
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The potential of imogolite nanotubes as (co-)photocatalysts: a linear-scaling density functional theory study
PublicationWe report a linear-scaling density functional theory (DFT) study of the structure, wall-polarization absolute band-alignment and optical absorption of several, recently synthesized, open-ended imogolite (Imo) nanotubes (NTs), namely single-walled (SW) aluminosilicate (AlSi), SW aluminogermanate (AlGe), SW methylated aluminosilicate (AlSi-Me), and double-walled (DW) AlGe NTs. Simulations with three different semi-local and dispersion-corrected...
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Effects of electrophoretic deposition times and nanotubular oxide surfaces on properties of the nanohydroxyapatite/nanocopper coating on the Ti13Zr13Nb alloy
PublicationLoad-bearing implants are developed with a particular emphasis placed on an application of ceramic hydroxyapatite coatings in order, to enhance the bioactivity of titanium implants and to shorten the healing time. Therefore, thin, fully crystalline coatings that are, highly adhesive, hydrophilic and demonstrating antibacterial properties are ly looked for. The aim of this research was to develop and characterize the properties...