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Search results for: bio-ceramics
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Structural phase transitions in multicomponent La0.2Nd0.2Sm0.2Gd0.2RE50.2NbO4 (RE5 = Ho, Y, Tb, Eu, Pr) oxides
PublicationIn this work, the influence of compositional complexity on the structural and thermal properties of multicomponent rare-earth ortho-niobates from the La0.2Nd0.2Sm0.2Gd0.2RE50.2NbO4 (RE5 = Ho, Y, Tb, Eu, Pr) series have been investigated. Based on X-ray powder diffraction studies using synchrotron radiation, it was found that all tested materials were pure single-phase compositions and showed stability in the monoclinic I2/c crystal...
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Comparison of Cu1.3Mn1.7O4 spinels doped with Ni or Fe and synthesized via wet chemistry and solid-state reaction methods, designed as potential coating materials for metallic interconnects
PublicationThe influence of the method applied to synthesize Cu-Mn-O spinel was evaluated. The methods selected for the investigation were EDTA gel processes and solid-state reaction synthesis. From the obtained powders, sinters were prepared and assessed in terms of their properties as potential coating materials. Additionally, the influence of Ni and Fe dopants was evaluated. The results show that the EDTA gel processes method seems to...
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Enhanced acceptor concentration, proton conductivity, and hydration in multicomponent rare‐earth ortho‐niobates
PublicationThe structural properties of (La0.2Nd0.2Sm0.2Gd0.2Eu0.2)1−xCaxNbO4−δ (x = 0–0.05) series have been studied by X-ray powder diffraction at room temperature. The thermal properties were investigated using thermogravimetry, from which the concentration of proton defects was determined. Additionally, dilatometry studies were carried out, from which the thermal expansion coefficients and the phase transition temperature between low-...
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Low temperature deposition of dense MnCo 2 O 4 protective coatings for steel interconnects of solid oxide cells
PublicationIn this work manganese cobalt spinel (MnCo2O4) coatings were deposited on steel substrates by spray pyrolysis at 390 °C. This is at much lower temperatures than previously reported (typically in excess of 900 °C). It was possible to produce coatings with well controlled thickness (2-5-10 μm). The as-deposited coatings were evaluated for their microstructural changes and electrical conductivity up to 800 °C. Results confirm the...
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Electrophoretic co-deposition of Fe2O3 and Mn1,5Co1,5O4: Processing and oxidation performance of Fe-doped Mn-Co coatings for solid oxide cell interconnects
PublicationThe “in-situ” Fe-doping of the manganese cobalt spinel was achieved by electrophoretic co-deposition of Mn1,5Co1,5O4 and Fe2O3 powders followed by a two-step reactive sintering treatment. The effects on the coating properties of two different Fe-doping levels (5 and 10 wt.% respectively) and two different temperatures of the reducing treatment (900 and 1000 °C) are discussed. Samples with Fe-doped coatings demonstrated a lower...
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Electric and magnetic properties of Lanthanum Barium Cobaltite
PublicationThe cubic Ba0.5La0.5CoO3‐δ was synthesized using solid state reaction. The structural properties were determined by the simultaneous refinement of Synchrotron Powder X‐ray Diffraction and Neutron Powder Diffraction data. Iodometric titration was used to examine the oxygen stoichiometry and average cobalt oxidation state. Low‐temperature magnetic studies show soft ferromagnetic character of fully oxidized material, with θP = 198(3)...
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Electrophoretic co-deposition of Mn1.5Co1.5O4, Fe2O3 and CuO: Unravelling the effect of simultaneous addition of Cu and Fe on the microstructural, thermo-mechanical and corrosion properties of in-situ modified spinel coatings for solid oxide cell interconnects
PublicationA systematic microstructural, thermo-mechanical and electrical characterization of simultaneous Fe–Cu doped Mn–Co spinel coatings processed by electrophoretic co-deposition on Crofer 22 APU is here reported and discussed. An innovative approach for the simultaneous electrophoretic deposition of three spinel precursors is designed, conceived and optimised, with the aim of outlining time- and energy-saving spinel modification routes....
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Antimony substituted lanthanum orthoniobate proton conductor – structure and electronic properties.
PublicationX‐ray and neutron diffraction have been utilized to analyze the crystalline and electronic structure of lanthanum orthoniobate substituted by antimony. Using X‐ray absorption spectroscopy and photoelectron spectroscopy, changes in the electronic structure of the material upon substitution have been analyzed. The structural transition temperature between fergusonite and scheelite phases for 30 mol% antimony substitution was found...
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Preparation and characterisation of iron substituted Mn1.7Cu1.3-xFexO4 spinel oxides (x = 0, 0.1, 0.3, 0.5)
PublicationSpinel oxides with the general formula Mn1.7Cu1.3-xFexO4 (x= 0, 0.1, 0.3, 0.5) were prepared and evaluated in this work for their properties at high temperatures. The effect of partially substituting Cu by Fe has not been studied so far for this group of materials and is thus evaluated in this work. Mn1.7Cu1.3-xFexO4 powders were synthesised by a soft chemistry process and studied in terms of crystallographic phase analysis, electrical...
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Processing of Ce0.8Gd0.2O2-δ barrier layers for solid oxide cells: The effect of preparation method and thickness on the interdiffusion and electrochemical performance
PublicationCe0.8Gd0.2O1.9 (CGO) barrier layers are required to mitigate the chemical reactions between Sr-containing oxygen electrode materials and Zr-based oxygen ion conductors in high-temperature solid oxide cells. Barrier layers produced by different methods were studied in this work. As a reference, a cell with no barrier layer was measured. The application of the powder-processed barrier layers, considerably increases the performance....
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Head-Space SPME for the Analysis of Organophosphorus Insecticides by Novel Silica IL-Based Fibers in Real Samples
PublicationThis work demonstrates the suitability of a newly developed ionic liquid (IL)-based silica SPME fiber for the determination of seven organophosphorus insecticides in cucumber and grapefruit samples by headspace solid-phase microextraction (HS-SPME) with a gas chromatography–flame ionization detector (FID). The sol-gel method released four different sorbent coatings, which were obtained based on a silica matrix containing ILs immobilized...
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Poly(ε-Caprolactone)/Poly(Lactic Acid) Blends Compatibilized by Peroxide Initiators: Comparison of Two Strategies
PublicationPoly(ε-caprolactone) (PCL) and poly(lactic acid) (PLA) blends were compatibilized by reactive blending and by copolymers formed during reaction in the solution. The reactive blending of PCL/PLA was performed using di-(2-tert-butyl-peroxyisopropyl)benzene (BIB) or dicumyl peroxide (DCP) as radical initiator. PCL-g-PLA copolymers were prepared using 1.0 wt. % of DCP or BIB via reaction in solution, which was investigated through...
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Właściwości mechaniczne i morfologia kompozytów biopoliuretanowych wzmocnionych modyfikowanymi włóknami sizalowymi
PublicationOmówiono wyniki badań właściwości mechanicznych i morfologii kompozytów biopoliuretanowych (bio-PUR) zawierających 5-15% mas. krótkich włókien sizalu. Materiały te wytworzono z systemu poliuretanowego, w którym zdyspergowano włókno poddane wcześniej merceryzacji lub silanizacji. Charakterystykę wytrzymałościową w warunkach statycznych uzyskano z krzywych naprężenie-odkształcenie, a morfologię kompozytów oceniono na podstawie zdjęć...
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Fluctuation-Enhanced Sensing for Biological Agent Detection and Identification
PublicationPrzedstawiono wcześniejsze wyniki badań dotyczące trzech różnych sposobów wykrywania obecności substancji biologicznych za pomocą zjawisk fluktuacyjnych: 1) wirusów wnikających do komórek, 2) zapachów emitowanych przez mikroby, 3) rozkładu widma i wartości chwilowych szumów podczas rozpraszania światła używanego do wykrywania zarodników na podstawie wyznaczenia współczynnika dyfuzji opisująceo ich ruch.We survey and show our earlier...
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The SARS‐CoV ‐2 specific IgG antibodies biophotonic sensor
PublicationIn this paper, we present the design and the principle of operation of the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) specific immunoglobulin G (IgG) biophotonic sensor, which is based on the single-mode telecommunication fiber. We fabricated the sensor head at the face of the single mode fiber-28. Due to the process of bio-functionalization, our sensor has the ability to selectively detect the SARS-CoV-2 specific...
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Trends in the new generation of green solvents in extraction processes
PublicationAnalytical chemistry, like other scientific fields, has undergone a number of changes to make it more consistent with the concept of sustainable development. Among the various steps of chemical analysis, without a doubt, sample preparation is the bottleneck in regard to following a green protocol, especially in terms of solvent consumption. Therefore, many attempts have been made to improve the environmental friendliness of this...
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A new division of bacterial UvrA homologues
PublicationThe UvrA protein is a DNA-binding and damage-recognition enzyme which participates in the prokaryotic type nucleotide excision repair (NER) pathway. It has recently been noted that some bacterial genomes comprise additional uvrA genes which encode five distinct types of UvrA homologue. We investigated the sequences of over 2400 bacterial genomes and found 130 examples of bacteria containing uvrA 2 genes. The sequence analyses conducted...
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Investigating the potential of CuSCN as hole transport layer for perovskite solar cells for applications in indoor photovoltaics
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Cubane Like Structure of a Silanethiol Primary Amine Assembly a Novel, Unusual Hydrogen Bond Pattern.
PublicationMetodą rentgenowskiej analizy strukturalnej wyznaczono struktury krystaliczne i cząsteczkowe trzech soli amoniowych: (t-BuO)3SiS(-)H3N(+)Bu-t, (i-PrO)3SiS(-)H3N(+)Bu-t i (t-BuO)3SiS(-)H3N(+)(CH2)2CH(CH3)2. Wszystkie trzy związki w ciele stałym tworzą tetramery w których atomy S i N wyznaczają w przybliżeniu naroża sześcianu. Trwałość tych agregatów, oprócz sił elektrostatycznego przyciągania, zapewnia sieć wiązań wodorowych N-H
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Morphology, surface properties and photocatalytic activity of the bismuth oxyhalides semiconductors prepared by ionic liquid assisted solvothermal method
PublicationThis is the first report of the effect of the ILs cation type (imidazolium, pyridinium and pyrrolidinium) on the morphology, surface properties and photoactivity of BiOX semiconductors type obtained by solvothermal method in glycerol. The various ionic liquids (IL) cation type as a halogen source and templating agent for the synthesis of the bismuth oxyhalides nanoparticles has been systematically investigated. The role of ILs...
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Hebb–Wagner polarization method for determining the oxygen ion conductivity in barium cerate-zirconate
PublicationIn this work, the partial conductivity of oxygen ions in BaCe0.6Zr0.2Y0.2O3 was studied at different temperatures and water partial pressures. For this purpose, a modified DC Hebb–Wagner polarization method with an electrode blocking for protons and electrons was used. A new type of measuring cell as well as a suitable calculation model were proposed for the determination of partial oxygen ionic conductivity in materials with three...
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Derivatization of single-walled carbon nanotubes with redox mediator biocatalytic oxygen electrodes
PublicationSingle-walled carbon nanotubes were covalently modyfied with a redox mediator derived from 2,2'-azino-bis-(3-ethylbenzothiazole)-6-sulfonic acid.
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Convergence of rational multistep methods of Adams-Padé type
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Convergence of rational multistep methods of of Adams-Padé type
PublicationRational generalizations of multistep schemes, where the linear stiff part of a given problem is treated by an A-stable rational approximation, have been proposed by several authors, but a reasonable convergence analysis for stiff problems has not been provided so far. In this paper we directly relate this approach to exponential multistep methods, a subclass of the increasingly popular class of exponential integrators. This natural,...
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Crystal structures of eight- and ten-membered cyclic bisanisylphosphonothioyl disulfanes and comparison with their P-ferrocenyl analogues
PublicationTwo new crystal structures of eight- and ten-membered cyclic bisanisylphosphonothioyl disulfanes, namely 2,5-bis(4-methoxyphenyl)-1,6,3,4,25,55- dioxadithiadiphosphocane-2,5-dithione, C16H18O4P2S4, and 2,5-bis(4-methoxyphenyl)-1,6,3,4,25,55-dioxadithiadiphosphecane-2,5-dithione, C18H22O4P2S4, have been determined and compared to structures of the ferrocenyl analogues. The eight-membered rings have similar conformations (TBC) but...
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Structural, mechanical and thermal behavior assessments of PCL/PHB blends reactively compatibilized with organic peroxides
PublicationThe efficiency of two commercially available organic peroxides, dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB), during reactive processing of poly (ε-caprolactone)/poly (3-hydroxybutyrate) (PCL/PHB) blends was investigated. The changes in chemical structure of PCL/PHB blends, as a function of organic peroxide type (DCP/BIB) and content (in range: 0–1.0 parts by weight - pbw), were characterized by Fourier...
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4-(Cyclic-amidino)phenols. Preparation and Use in a Diamidine Synthesis
PublicationThe Pinner synthesis was applied to the prepn. of phenols 4-substituted with cyclic amidines in high yields from readily available 4-HOC6H4C(OMe):NH.HCl and aliph. diamines. An alternative attempt was made to convert 4-HOC6H4CSNH2 to 4-(1,4,5,6-tetrahydro-5-hydroxy-2-pyrimidinyl)phenol. A procedure for the prepn. of 3,6-bis(4-hydroxyphenyl)-1,2,4,5-tetrazine is reported. The syntheses of 2,4-bis[4-(4,5-dihydro-1H-imidazol-2-yl)phenoxy]pyrimidine...
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Die Sandgrube „Köplitz“ – ein interessanter geologischer Aufschluss am Nordwestrand der Schmiedeberger Stauchendmoräne
PublicationDie Kiessandgrube Köplitz ermöglicht einen Einblick in die komplizierten, durch glazidynamische Überprägung gekennzeichneten geologischen Lagerungsverhältnisse im Bereich der Schmiedeberger Stauchendmoräne. Anhand neuer Geländedokumentationen wird ein kleiner Eindruck vom komplizierten injektiven „Fließfalten-Schuppenbau“ der Stauchendmoräne vermittelt. Die steil aufgerichteten, aus tertiären (Untermiozän bis Oligozän) und quartären...
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Ekspertyza dotycząca bezzasadności zarzutów odnośnie parametrów metrologicznych analizatorów pyłu PM2,5 postawionych firmom EAS Envimet Polska Sp. z o.o. i EAS Envimet Analytical Systems GmbH przez spółkę MLU Sp. z o.o. z siedzibą w Katowicach w postępowaniu odwoławczym o sygn. akt: KIO/UZP 435/09
PublicationW ekspertyzie sporządzonej dla EAS Envimet Polska sp. z o.o. z siedzibą w Wieliczce wykazano bezzasadność zarzutów zgłoszonych przez Spółkę MLU w Katowicach w odniesieniu do urządzenia BAM1020 w postępowaniu odwoławczym toczącym się przed Prezesem Urzędu Zamówień Publicznych w związku z zaskarżeniem rozstrzygnięcia przetargu o zamówienie publiczne nr DM/5211-06-02/09/ABA na zakup automatycznego miernika pyłu zawieszonego PM2,5...
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Calibration of permeation passive samplers with silicone membranes based onphysicochemical properties of the analytes. Anal. Chem.**2003 dostępny z Internetu http://pubs3.acs.org/acs/journals/, s. A-K, 6 rys. 7 tab. bib- liogr. 17 poz. Kalibracja permeacyjnych dozymetrów pasywnych z membraną silikonową w opar- ciu o fizykochemiczne właściwości analitów.
PublicationW pracy opisano sposób kalibracji pasywnych dozymetrów permeacyjnych, wyko-rzystywanych w badaniach powietrza w oparciu o własności fizykochemiczneanalitów. Stwierdzono silną zależność pomiędzy stałą kalibracyjną (K) dozy-metrów i liczbą atomów węgla w cząsteczce analitu (w obrębie danej grupyzwiązków chemicznych) dla alkoholi, alifatycznych i aromatycznych węglowodo-rów oraz estrów. Taka zależność występuje również pomiędzy...
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Badanie bakterii redukujących siarczany na ujęciach wód podziemnych i meto- dy ich eliminacji.**2002, 146 s. + załączniki, tab. wykr. w rozdz. bib- liogr. 78 poz. maszyn. Rozprawa doktorska /21.06.2002/. P. Gdań., Wydz. Bud. Wodn. i Inż. Środow. Promotor: prof. dr hab. K. Olańczuk-Neyman.
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Monitoring of breast tissue thermo-ablation by means of impedance measurements
PublicationW pracy przedstawiono rozważania dotyczące monitorowania jakości termoablacji zmian nowotworowych w piersi przy pomocy pomiarów impedancyjnych. Pokazano prototypowe konstrukcje sond do termoablacji jak również zaprezentowano wyniki symulacji i pierwszych eksperymentów. A usefulness of a developed probe combining power delivery to ablated breast tumour and simultaneous impedance measurements is discussed in the paper. It consists...
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3D porous graphene-based structures- synthesis and applications
PublicationPorous carbon-based materials are of the great industrial and academic interest due to their high surface area, low density, good electrical conductivity, chemical inertness and low cost of fabrication. Up to now, the main approach to obtain porous carbon structures has involved the pyrolysis of carbonaceous natural or synthetic precursors. After the isolation of graphene, the interest in 3D porous graphene-based structures (called...
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Ionic liquids - greener solvents or environmental threat?
PublicationZe względu na niemierzalnie niską prężność par ciecze jonowe były uważane za 'zielone rozpuszczalniki'. Ich zastosowanie w technologiach (bio)chemicznych przynosi korzyści nie tylko ekologiczne ale również ekonomiczne. Niemniej jednak zanieczyszczenie środowiska poprzez przedostanie się cieczy jonowych do gleb i wód gruntowych wraz ze ściekami/odciekami przemysłowymi lub w wyniku przypadkowych rozlewów stanowi realne zagrożenie....
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Molecular modelling of a psychrophilic β-galactosidase
PublicationAntarktyczny szczep, gram-ujemnych bakterii, wyizolowanych z przewodu pokarmowego kryla z gatunku Thyssanoessa macrura, sklasyfikowany na podstawie analizy sekwencji nukleotydowej geny 16S rDNA jako Pseudoalteromonas sp. 22b jest producentem wewnątrzkomórkowej zimnolubnej beta-galaktozydazy. Ponieważ enzym ten wykazuje wysoką aktywność katalityczną w zakresie temperatur od 0 do 30 stC, stanowi on atrakcyjny biokatalizator, użyteczny...
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Analiza składu fazy gazowej wytwarzanej podczas fermentacji ciemnej
PublicationFermentacja ciemna umożliwia otrzymywanie bio-wodoru z substratów pochodzenia biologicznego, np. z biomasy ligno-celulozowej. Kontrola i właściwe sterowanie przebiegiem procesu fermentacji ciemnej wymaga bieżącego monitoringu składu powstającej fazy gazowej. W niniejszej pracy przedstawiono metodykę analizy składu fazy gazowej z wykorzystaniem techniki GC-TCD-FID. Zaproponowana metodyka umożliwia oznaczenie następujących gazów...
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Bezpośrednie inwestycje zagraniczne w Polsce według kryterium czynnika wytwórczego
PublicationW artykule przeanalizowana została struktura bezpośrednich inwestycji zagranicznych (BIZ) w Polsce zgodnie z kryterium czynnika wytwórczego. Okres badań obejmuje lata 1992-2002.
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I protagonisti della grande distribuzione in Europa
PublicationThe chapter outlines the main aspects of the history of some of the most important big European department stores (El Corte Ingles, Auchan, Carrefour, LeClerc, Aldi, Esselunga and the Finiper Group,
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Data governance: Organizing data for trustworthy Artificial Intelligence
PublicationThe rise of Big, Open and Linked Data (BOLD) enables Big Data Algorithmic Systems (BDAS) which are often based on machine learning, neural networks and other forms of Artificial Intelligence (AI). As such systems are increasingly requested to make decisions that are consequential to individuals, communities and society at large, their failures cannot be tolerated, and they are subject to stringent regulatory and ethical requirements....
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A review: Fabrication of porous polyurethane scaffolds
PublicationThe aim of tissue engineering is the fabrication of three-dimensional scaffolds that can be used for the reconstruction and regeneration of damaged or deformed tissues and organs. A wide variety of techniques have been developed to create either fibrous or porous scaffolds from polymers, metals, composite materials and ceramics. However, the most promising materials are biodegradable polymers due to their comprehensive mechanical...
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Impact of strontium non-stoichiometry of SrxTi0.3Fe0.7O3-δ on structural, electrical, and electrochemical properties for potential oxygen electrode of intermediate temperature solid oxide cells
PublicationThis work presents the results of a comprehensive study on the impact of the A-site non-stoichiometry of SrxTi0.3Fe0.7O3-δ (x = 0.90, 0.95, 1.00, 1.05) ceramics on their physicochemical properties. The materials were fabricated by the conventional solid-state reaction method and their structure was determined by X-ray diffractometry, X-ray photoelectron spectroscopy and electron microscopy. Their sintering and thermal expansion...
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Educational and cognitive aspects of adaptation of nonuse spaces in monumental sacral objects.
PublicationThe area of attics and towers in historic churches in Europe are yet quite inaccessible places for visitors, shrouded in the atmosphere of mysticism, hiding many secrets. Introduction of the new public function into the non-used zones of the monumental sacral objects has many aspects including educational and cognitive ones which are discussed in the following article. The article indicates items that can be found in the zone above...
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Performance Analysis of the "Intelligent" Kirchhoff- Law - Johnson-Noise Secure Key Exchange
PublicationThe Kirchhoff-law - Johnson-noise (KLJN) secure key distribution system provides a way of exchanging theoretically secure keys by measuring random voltage and current through the wire connecting two different resistors at Alice’s and Bob’s ends. Recently new advanced protocols for the KLJN method have been proposed with enhanced performance. In this paper, we analyze the KLJN system and compare with the „intelligent” KLJN (iKLJN)...
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Harmony Search for Self-configuration of Fault–Tolerant and Intelligent Grids
PublicationIn this paper, harmony search algorithms have been proposed to self-configuration of fault-tolerant grids for big data processing. Self-configuration of computer grids lies in the fact that new computer nodes are automatically configured by software agents and then integrated into the grid. A base node works due to several configuration parameters that define some aspects of data communications and energy power consumption. We...
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Microstructure and electrical properties of manganese borosilicate glasses
PublicationThe structure, optical and electrical properties of manganese borosilicate glasses of the composition xMnO–(80 − x)SiO 2 –20B 2 O 3 (x = 40, 50, and 60 mol%) were investigated. The dependence of the glass structure on its composition was discussed and related to electrical properties. A separation of two amorphous phases was observed. It was suggested that one phase is MnO-rich and the other is SiO 2 -rich. It was found that...
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Wpływ zaolejenia zewnętrznych przegród pionowych na warunki cieplno-wilgotnościowe w budynku
PublicationW artykule przedstawiono wyniki analizy wpływu zaolejenia na rozkład wilgoci w zewnętrznych przegrodach pionowych budynku mieszkalnego wykonanych jako żelbetowe, monolityczne, ocieplone od strony zewnętrznej według rozwiązań technologii BSO. Analiza ma charakter parametryczny. W artykule przedstawiono wyniki analizy wpływu zaolejenia na rozkład wilgoci w zewnętrznych przegrodach pionowych budynku mieszkalnego wykonanych...
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Stimulated by cyclodextrins high yield synthesis of azocrown analogues comprising pyrrole or imidazole residues
PublicationThe influence of cyclodextrins (CDs) on the formation of azocrown ethers comprising pyrrole, imidazole and substituted imidazole has been studied. Pyrrole, imidazole, 2-methyl-, 4-methyl- and 4-phenylimidazole were coupled with bisdiazonium salts derived from bis-1,5-(2-aminophenoxy)-3-oxapentane or bis-1,8-(2-aminophenoxy)-3,6-dioxaoctane to form macrocyclic compounds with two azo units. The syntheses were performed under standard...
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Computational fluid dynamics simulation of heat transfer from densely packed gold nanoparticles to isotropic media
PublicationThis work aims to determine and compare heat generation and propagation of densely packed gold nanoparticles (Au NPs) induced by a resonant laser beam (532 nm) according to the Mie theory. The heat flux propagation is transferred into the materials, which here are: silica glass; soda-lime-silica glass; borosilicate glass; polymethyl methacrylate (PMMA); polycarbonate (PC); and polydimetylosiloxane (PDMS). This analysis aims to...
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Problemy pomiarów mocy i energii w linii elektroenergetycznej Polska-Litwa
PublicationW referacie przedstawiono zagadnienia związane z pomiarem mocy i energii w linii dwutorowej. Rozważania oparto na linii łączącej stacje elektroenergetyczne Ełk Bis i Alytus.
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Buckling analysis of shell structures with stochastic imperfections using six parameter nonlinear shell theory
PublicationPrzedstawiono wpływ wstępnych losowych imperfekcji geometrycznych na wartość obciążenia krytycznego powłoki. W obliczeniach zastosowano autorski program MES wykorzystujący 6-cio parametrową nieliniową teorię powłok.