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Opracowanie ekspertyzy dotyczącej przyczyn pękania łopatek wirnika SP turbiny PG1 typu 13UP55
PublikacjaZakres badań i analiz dotyczył ustalenia przyczyn pękania elementów łopatek wirnika SPA5 turbiny TG1 typu 13UP55 obejmował: 1. wykonanie badań składu chemicznego stali, z której wykonano łopatki dostarczone przez Zleceniodawcę dwoma metodami, 2. badania mikroobszarów zniszczenia łopatek na mikroskopie elektronowym skaningowym z mikroanalizatorem EDS, 3. badania metalograficzne makroskopowe i mikroskopowe fragmentów...
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CZYNNIKI DECYDUJĄCE O PRZYDATNOŚCI KOMPUTEROWEGO MODELU PRZEPŁYWÓW W SIECI WODOCIĄGOWEJ
PublikacjaW pracy poddano analizie wielozadaniowy proces tworzenia komputerowego modelu przepływów. W efekcie zidentyfikowano szereg czynników ograniczających obszar stosowania modelu w praktyce inżynierskiej. W zakresie pozyskiwania danych strukturalnych i operacyjnych wskazano potencjalne źródła błędów, które przyczyniają się do zmniejszenia dokładności odwzorowania stanu rzeczywistego. Specjalną rangę nadano specyfikacji czynników związanych...
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Activation of Metabotropic Glutamate Receptor (mGlu2) and Muscarinic Receptors (M1, M4, and M5), Alone or in Combination, and Its Impact on the Acquisition and Retention of Learning in the Morris Water Maze, NMDA Expression and cGMP Synthesis
PublikacjaThe Morris water maze (MWM) is regarded as one of the most popular tests for detecting spatial memory in rodents. Long-term potentiation and cGMP synthesis seem to be among the crucial factors involved in this type of learning. Muscarinic (M1, M4, and M5 receptors) and metabotropic glutamate (mGlu) receptors are important targets in the search for antipsychotic drugs with the potency to treat cognitive disabilities associated with...
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INFLUENCE OF SURFACE CURVATURE ON SESSILE DROPLET CONTACT ANGLE OF NANOFLUIDS
PublikacjaThis paper deals with change in contact angle of droplets of three nanofluids, i.e. water-Al2O3, water-TiO2 and water-Cu. Nanoparticles were tested at the concentration of 0.01%, 0.1%, and 1% by weight. Although dispersants were not used to stabilize the suspension, the solutions tested exhibited satisfactory stability. Ultrasonic vibration was used in order to stabilise the dispersion of the nanoparticles. Experimental measurements...
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Novel tetrahedral cobalt(II) silanethiolates: structures and magnetism
PublikacjaThree heteroleptic complexes of Co(II) tri-tert-butoxysilanethiolates have been synthesized with piperidine [Co{SSi(OtBu)3}2(ppd)2] 1, piperazine [Co{SSi(OtBu)3}2(NH3)]2(μ-ppz)·2CH3CN 2, and N-ethylimidazole [Co{SSi(OtBu)3}2(etim)2] 3. The complexes have been characterized by a single-crystal X-ray, revealing their tetrahedral geometry on Co(II) coordinated by two nitrogen and two sulfur atoms. Complexes 1 and 3 are mononuclear,...
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PARP inhibition potentiates the cytotoxic activity of C-1305, a selective inhibitor of topoisomerase II, in human BRCA1-positive breast cancer cells
PublikacjaTwo cellular proteins encoded by the breast and ovarian cancer type 1 susceptibility (BRCA1 and BRCA2) tumor suppressor genes are essential for DNA integrity and the maintenance of genomic stability.Approximately 5-10% of breast and ovarian cancers result from inherited alterations or mutations in these genes.Remarkably, BRCA1/BRCA2-deficient cells are hypersensitive to selective inhibition of poly(ADPribose) polymerase 1 (PARP-1),...
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Amberlyst-15 catalysed synthesis of novel indole derivatives under ultrasound irradiation: Their evaluation as serotonin 5‑HT2C receptor agonists
PublikacjaA series of indole based novel Schiff bases was designed as potential agonists of 5‑HT2C receptor that was supported by docking studies in silico. These compounds were synthesized via Amberlyst-15 catalysed condensation of an appropriate pyrazole based primary amine with the corresponding indole-3-aldehyde under ultrasound irradiation at ambient temperature. A number of target Schiff bases were obtained...
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Mono- and polynuclear Co(II) silanethiolates with aliphatic diamines
PublikacjaFour Co(II) complexes, [Co{SSi(OtBu)3}2(dmpda)] 1, [Co{SSi(OtBu)3}2(bda)2]n2 [Co{SSi(OtBu)3}2(pda)2]n3 and [Co{SSi(OtBu)3}2(hda)2]n4 [dmpda = 3-(dimethylamino)-1-propylamine; bda = 1.4-butanediamine; pda = 1.5-pentanediamine; had = 1.6-hexanediamine] have been synthesized and characterized using X-ray diffraction. Complex 1 is mononuclear and contains Co(II) coordinated by dmpda molecule in chelating mode, whereas compounds 3 and...
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Ruthenium(II) and Iridium(III) Complexes as Tested Materials for New Anticancer Agents
PublikacjaThe oncological use of cisplatin is hindered by its severe side eects and a very important resistance problem. To overcome these problems, scientists have attempted to design new generation transition-metal anticancer complexes. In this study, we present new complexes, ruthenium(II) [(6-p-cymene)RuCl(py2CO)]PF6 (1), iridium(III) [(5-Cp)IrCl(py2CO)]PF6 (2), and NH4[IrCl4(py2CO)]H2O (3), based on di-2-pyridylketone (py2CO). The prepared...
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Badania stabilności biologicznej wody w wybranych systemach wodociągowych
PublikacjaW pracy przedstawiono wyniki badań mikrobiologicznych wody powierzchniowej i wód podziemnych z rejonu Trójmiasta, które zasilają systemy dystrybucji charakteryzujące się nikim stosunkiem powierzchni kontaktu do objętości przesyłanej wody (≈0,65) w aspekcie ich stabilności biologicznej. Dokonano oceny skuteczności zastosowanych procesów uzdatniania w usuwaniu ogólnej liczby bakterii (OLB), a w badaniach laboratoryjnych określono...
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Nitrogen mass balance and mathematical model of a Structured- Bed Reactor (SBRRIA)
PublikacjaAn up-flow structured-bed reactor subjected to recirculation and intermittent aeration (SBRRIA) was operated under varying influent conditions. The influent COD/N ratio was adjusted by maintaining a stable organic loading rate (average of 1.07 kgCOD m-3 d-1) and changing the nitrogen loading rate from 0.1 to 0.4 kg N m-3. Therefore, three different COD/N ratios were tested: 9.7±1 (Scenario 1); 7.6±1 (Scenario 2) and 2.9±1 (Scenario...
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A comprehensive review of open data platforms, prevalent technologies, and functionalities
PublikacjaOpen data can play a crucial role in different sectors of the world,such as government, science, research, technology, culture, andfinance. There are several necessary measures that every organiza-tion needs to consider before opening data. There are three majorsteps to opening the data: (1) Preparation stage, and (2) launchingthe open data initiative (3) In this case, the feedback mechanismstudy such as expand and sustain stage,...
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Zjawisko interakcji idącego człowieka i drgającego podłoża konstrukcji inży-nierskiej. W: Projektowanie, budowa i estetyka kładek dla pieszych. Ed. K.Flaga, W. Średniawa. Kraków: P. Krak. Wydz. Inż. Ląd. Kated. Bud. Mostów i Tuneli**2003 s. 51-70, 11 fot. 4 rys. 21 wykr. bibliogr. 12 poz. Cykl seminariów: Projektowanie, Budowa i Estetyka Kładek dla Pieszych. Kra-ków, 8 października, 5 listopada, 3 grudnia 2003 r.
PublikacjaPrzedstawiono podstawy mechaniki chodu, wyniki badań eksperymentalnych i propozycję matematycznego opisu zjawiska dostosowania kroku człowieka do drgań konstrukcji. W części eksperymentalnej przedstawiono stanowisko badawcze wyposażone w bieżnię stacjonarną umieszczoną naplatformie pomiarowej podłączo-nej do siłownika wywołującego drgania o zadanej częstotliwości i amplitudzie. Porównano wyniki symulacji numerycznej z pomiarami...
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Revised structure of the repeating unit of the O-specific polysaccharide from Azospirillum lipoferum strain SpBr17
PublikacjaO-polisacharyd otrzymany poprzez delikatną kwasową hydrolizę lipopolisacharydu wyizolowanego z Azospirillum lipoferum SpBr17 był badany metodami spektroskopii NMR jak również metodą analizy metylacyjnej połączonej z elektroforezą SDS-PAGE. Stwierdzono, że nie jest on liniowym homopolimerem złożonym wyłącznie z (1->3) [alfa]-glikozydowo połączonych cząsteczek L-ramnopiranozy (jak proponowano wcześniej) lecz sekwencją kolejnych bloków...
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Electrochemical sensor for measurement of volatile organic compounds employing square wave perturbation voltage
PublikacjaThe paper presents the results of investigation on a prototype sensor for measurement of benzaldehyde in air. Sensitivity and limit of quantification of the sensor were determined for different internal electrolyte using the square wave voltammetry (SWV) as a detection technique. The working and counter electrodes were made of platinum. Ionic liquids 1-hexyl, 3-methylimidazolium chloride,1-hexyl, 3-methylimidazolium bis (trifluoromethanesulfonyl)...
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CO2 EMISSION TO THE ATMOSPHERE FROM CARBONATE WATERS: THE STUDY CASE OF THE LUBLIN UPLAND AND ROZTOCZE REGIONS
PublikacjaThe concentration of carbon dioxide dissolved in water (CO2(aq)) was measured in consecutive phases of the hydrological cycle. Its potentially possible degassing from groundwaters to the atmosphere was also assessed. The research was conducted in the area of occurrence of carbonate rocks of the Lublin Upland and Roztocze (SE Poland). The results of the measurements of CO2(aq) concentration varied as follows (min-max/mean): precipitation...
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Fungal co-culture improves the biodegradation of hydrophobic VOCs gas mixtures in conventional biofilters and biotrickling filters
PublikacjaThe present study systematically evaluated the potential of Candida subhashii, Fusarium solani and their consortium for the abatement of n-hexane, trichloroethylene (TCE), toluene and α-pinene in biofilters (BFs) and biotrickling filters (BTFs). Three 3.2 L BFs packed with polyurethane foam and operated at a gas residence time of 77 s with an air mixture of hydrophobic volatile organic compounds (VOCs) were inoculated with C. subhashii,...
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Aluminum-TiO2 NPs Composites as Non-precious Catalysts for Efficient Electrochemical Generation of Hydrogen
PublikacjaIn this paper, we demonstrated, for the first time, aluminum titania nanoparticle (Al-TiO2 NP) composites with variable amounts of TiO2 NPs as nonprecious active catalysts for the electrochemical generation of H2. These materials were synthesized by mixing desired amounts of hydrogen titanate nanotubes (TNTs), fabricated here by a cost-effective approach at moderate hydrothermal conditions, with aluminum powder (purity 99.7%; size...
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Preparation of 1-[Ω-(1,4,5,6-Tetrahydropyrimidin-2-yl)alkyl]thymines
PublikacjaOne-stage prepn. of the hydrochloride salts of 1-[ω-(1,4,5,6-tetrahydropyrimidin-2-yl)alkyl]-thymines, e.g. I, from 1-(ω-cyanoalkyl)thymines and a 1:1-mixt. of 1,3-diaminopropane and ethanol satd. with hydrogen sulfide is described. 1-(2-Cyanoethyl)-thymine gave a facile reversal of the Michael reaction to thymine under the conditions used. The reaction of 1,3-bis(3-cyanobenzyl)thymine with the above reagent produced 1,3-bis[3-(1,4,5,6-tetrahydropyrimidin-2-yl)benzyl]thymine.
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Usługi ośrodków podregionalnych w Polsce
PublikacjaOśrodki podregionalne definiowane są jako miasta, w których skoncentrowane są takie usługi, które w Polsce mogą być w kilku miastach województwa, ale nie w każdym mieście powiatowym. Usługi zawsze miały tendencję do koncentracji, tworząc ośrodki różnych poziomów w hierarchicznej sieci osadniczej. Celem prezentowanych badań było: (1) określenie usług typowych dla poziomu podregionalnego; (2) rozpoznanie koncentracji tych usług,...
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Monitoring of organic pollutants in coastal waters of the Gulf of Gdańsk, Southern Baltic.
PublikacjaPrzedstawiono zmiany zawartości zanieczyszczeń organicznych (np. VOC, PAH, PCB, chlorofenoli) w wodach Zatoki Gdańskiej na przestrzeni 5-ciu lat. Zawartość VOX i VOC zmieniała się od kilku ngdm-3 do kilkuset ngdm-3, podczas gdy zawartość chlorofenoli fenoksykwasów była na poziomie kilku ngdm-3. W większości próbek nie wykryto PCB.
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Cobalt(II) tri-tert-butoxysialanethiolates.Synthesis, properties, crystal and molecular structures of [Co{SSi(OtBu)3}2(L)] and[Co{SSi(OtBu)3}2(L)2] type complexes with monodentate nitrogen ligands.
PublikacjaThe title heteroleptic neutral cobalt(II) tri-tert-butoxysilanethiolate complexes with monodentate nitrogen bases (L) as additional ligands have been prepared by the reactions of [Co{μ-SSi(OtBu)3}{SSi(OtBu)3}(NH3)]2 (1) with respective bases. For pyridine both types have been prepared...
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Selection of Electrode Material for Inconel 617/P92 Steel SMAW Dissimilar Welds
PublikacjaThe present work aimed to investigate the microstructure and mechanical properties of the dissimilar shielded metal arc welded (SMAW) joint of Alloy 617 and P92 steel for advanced ultrasupercritical boilers. The SMAW joint was produced using three different types of electrodes, namely, ENiCrFe-3, ENiCrMo-3, and ENiCrCoMo-1. During microstructural observation of the welded joints, no possible cracking was detected in the weldments....
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The Quantum Efficiency Roll-Off Effect in Near-Infrared Organic Electroluminescent Devices with Iridium Complexes Emitters
PublikacjaThe electroluminescence quantum efficiency roll-off in iridium(III)-based complexes, namely Ir(iqbt)2(dpm) and Ir(iqbt)3(iqbt=1 (benzo[b]thiophen-2-yl)-isoquinolinate, dpm=2,2,6,6-tetramethyl-3,5-heptanedionate) utilized as near-infrared emitters in organic light emitting diodes with remarkable external quantum efficiencies, up to circa 3%, 1.5% and 1%, are measured and analyzed. With a 5–6 weight % of emitters embedded...
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Changes in Epigenetic Patterns Related to DNA Replication in Vicia faba Root Meristem Cells under Cadmium-Induced Stress Conditions
PublikacjaExperiments on Vicia faba root meristem cells exposed to 150 µM cadmium chloride (CdCl2) were undertaken to analyse epigenetic changes, mainly with respect to DNA replication stress. Histone modifications examined by means of immunofluorescence labeling included: (1) acetylation of histone H3 on lysine 56 (H3K56Ac), involved in transcription, S phase, and response to DNA damage during DNA biosynthesis; (2) dimethylation of histone...
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Visual TreeCmp : Comprehensive Comparison of Phylogenetic Trees on the Web
Publikacja1. We present Visual TreeCmp—a package of applications for comparing phylogenetic tree sets. 2. Visual TreeCmp includes a graphical web interface allowing the visualization of compared trees and command line application extended by comparison methods recently proposed in the literature. 3. The phylogenetic tree similarity analysis in Visual TreeCmp can be performed using eighteen metrics, of which 11 are dedicated to rooted trees...
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Analysis of floor-to-column pounding of buildings founded on different soil types
PublikacjaThe aim of this study is to investigate the effect of the soil type on buildings experiencing floor-to-column pounding during earthquakes. Five buildings with 4-storeys, 6-storeys, and 7-storeys were considered. Three types of the 4-storey building with different total heights were taken into account which leads to floor-to-column pounding at 1/3, 1/2 and 2/3 of the height of the impacted column. Two pounding scenarios were considered,...
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Ontology-Aided Software Engineering
PublikacjaThis thesis is located between the fields of research on Artificial Intelligence (AI), Knowledge Representation and Reasoning (KRR), Computer-Aided Software Engineering (CASE) and Model Driven Engineering (MDE). The modern offspring of KRR - Description Logic (DL) [Baad03] is considered here as a formalization of the software engineering Methods & Tools. The bridge between the world of formal specification (governed by the mathematics)...
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Modeling of generator performance of BLDC machine using mathematica software
PublikacjaW artykule porównano trzy modele maszyny bezszczotkowej prądu stałego z magnesami trwałymi(BLDC) w przypadku pracy prądnicowej. Najprostszy model qd0 sprowadzono do dwóch osi prostopadłychzwiązanych z wirnikiem [3]. Zakłada on sinusoidalny rozkład pola w szczelinie. Model opisany wosiach naturalnych wyprowadzono w oparciu o formalizm Lagrnage'a [4] i moŜe uwzględniać dowolnyrozkład pola wzbudzonego przez magnesy trwałe. Model pośredni...
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Analysis of the reliability of any-hop star network
PublikacjaZałożono, że sieć ma wielostopniową strukturę gwiaździstą. Jako oceny niezawodności tych sieci przyjęto: 1) średnią liczbę sprawnych par węzłów, które mogą komunikować się wzajemnie; 2) średnią liczbę sprawnych par węzłów, które mogą komunikować się poprzez węzeł centralny; 3) średnią liczbę sprawnych par węzłów, które mogą komunikować się z węzłem centralnym; 4) prawdopodobieństwo zdarzenia, że sprawne węzły mogą komunikować...
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Influence of cooling rate and additives on low-temperature properties of asphalt mixtures in the TSRST
PublikacjaThe paper presents the results and analysis of low-temperature properties of asphalt mixtures according to Thermal Stress Restrained Specimen Test (TSRST) and Indirect Tensile Test methods. Different groups of bitumen were investigated: neat, SBS-modified and highly SBS-modified. Influence of cooling rates (1 C/h, 3 C/h, 5 C/h and 10 C/h) and additives (aramid fibres and crumb rubber) was identified as well. Moreover, for each...
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Lower rim substituted tert-butylcalix[4]arenes.Part 8: Calix[4]arenes with dialkoxyphosphoryl functions. Synthesis and complexing properties
PublikacjaW pracy przedstawiono syntezę i charakterystykę otrzymanych związków (1, 2), pochodnych alkoksyfosforylowych p-tert-butylokaliks[4]arenu: 5,11,17,23-tetra-tert-butylo-25,26,27,28-tetrakis(3-diizopropoksyfosforylopropoksy)kaliks[4]arenu (1) oraz 5,11,17,23-tetra-tert-butylo-25,26,27,28-tetrakis(3-methoksyetoksyfosforylopropoksy)kaliks[4]arenu (2). Zbadano właściwości jonoforowe związków 1 i 2 w membranie elektrod jonoselektywnych,...
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Application of chemometric modeling for ionic liquid-based ultrasonic-assisted dispersive liquid-liquid microextraction: Analysis of fosetyl-aluminum in fruit and vegetable samples
PublikacjaThis manuscript presents a new method for selective extraction and determination of fosetyl-aluminum in fruits and vegetable samples based on ultrasonic-assisted dispersive liquid-liquid microextraction method using ionic liquids (IL-UA-DLLME). A UV-Visible spectrophotometer was used for detection and quantification. Plants used for sample collection were grown under controlled conditions in a greenhouse. Central composite design...
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Iridium 5d -electron driven superconductivity in ThIr3
PublikacjaA polycrystalline sample of superconducting ThI r 3 was obtained by arc-melting Th and Ir metals. Powder x-ray diffraction revealed that the compound crystalizes in a rhombohedral crystal structure (R-3m, s.g. #166) with the lattice parameters: a = 5.3394 ( 1 ) Å and c = 26.4228 ( 8 ) Å . Normal and superconducting states were studied by magnetic susceptibility, electrical resistivity, and heat capacity measurements. The results...
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Adsorption behavior and corrosion inhibitive characteristics of newly synthesized cyano-benzylidene xanthenes on copper/sodium hydroxide interface: Electrochemical, X-ray photoelectron spectroscopy and theoretical studies
PublikacjaElegant process for synthesis of 3-(7H-dibenzo[c,h]xanthen-7-yl)benzaldehyde (3), as new starting material to create a set of novel xanthene analogues, 2-(3-(7H-dibenzo[c,h]xanthen-7-yl)benzylidene)malononitrile (4), 3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylic acid (5), and Ethyl-3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylate (6), was achieved starting with available materials under mild conditions. Various...
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A 27/26-approximation algorithm for the chromatic sum coloring of bipartitegraphs
PublikacjaWe consider the CHROMATIC SUM PROBLEM on bipartite graphs which appears to be much harder than the classical CHROMATIC NUMBER PROBLEM. We prove that the CHROMATIC SUM PROBLEM is NP-complete on planar bipartite graphs with Delta less than or equal to 5, but polynomial on bipartite graphs with Delta less than or equal to 3, for which we construct an O(n(2))-time algorithm. Hence, we tighten the borderline of intractability for this...
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Dylematy polityki wspierania małych i średnich przedsiębiorstw
PublikacjaAutor sformułował i opisał 7 podstawowych dylematów polityki wspierania MSP przez państwo. Pierwszą grupę stanowią dylematy wyborów pomiędzy:1. ochroną MSP a promowaniem ich rozwoju;2. protekcjonizmem wobec firm istniejących a ułatwieniami w zakładaniu firm nowych;3. wspieraniem wszystkich MSP a wspieraniem wybranych grup spośród nich.W drugiej grupie mieszczą się dylematy wyboru:4. szczebla na jakim polityka wspierania jest projektowana...
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Analysis of Positioning Error and Its Impact on High Frequency Performance Parameters of Differential Signal Coupler of Differential Signal Coupler
PublikacjaThis paper presents the analysis of the effect of differential signal coupler positioning accuracy on its high frequency performance parameters for contact-less high speed chip-to-chip data transmission on PCB application. Our considerations are continuation of the previous works on differential signal coupler concept, design methodology and analysis for high speed data transmission monitoring presented in [1, 2]. The theoretical...
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Superconductivity in the superhard boride WB4.2
PublikacjaWe show that the superhard boride WB4.2 is a superconductor with a Tc of 2.05(5) K. Temperature-dependent magnetic susceptibility, electrical resistivity, and specific heat measurements were used to characterize the superconducting transition. The Sommerfeld constant γ for WB4.2 is 2.07(3) mJ mol−1 K−2 and the ΔC/γTc=1.56, which is somewhat higher than what is expected for weakly coupled Bardeen–Cooper–Schrieffer type superconductors....
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Impact Behaviour of Glass Fribre /Epoxy Composites with Nano-Enhanced Resin after Water Exposure
PublikacjaImpact behaviour of glass fibre /epoxy composites with nano- SiO2 modified resin was studied in terms of low velocity impact after water exposure. Nanocomposites with 1%, 2%, 3% 5% 7% nano-SiO2 (Nanopox- Evonic) were investigated. Peak impact load and impact damage area as a function of nanoparticle contents were compared for dry specimens and for samples exposed to water (0.7 %wt. 1.7% water absorbed) at 1J, 2J 3J impact energies....
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Implication of the disulfide bridge in trypsin inhibitor SFTI-1 in its interaction with serine proteinases
PublikacjaFourteen monocyclic analogues of trypsin inhibitor SFTI-1 isolated from sunflower seeds were synthesized by the solid-phase method. The purpose of this work was to establish the role of a disulfide bridge present in inhibitor's side chains of Cys3 and Cys11 in association with serine proteinases. This cyclic fragment was replaced by the disulfide bridges formed by L-pencillamine (Pen), homo-L-cysteine (Hcy), N-sulfanylethylglycine...
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Recombinant !ermostable AP Exonuclease from Thermoanaerobacter tengcongensis: Cloning, Expression, Purification, Properties and PCR Application
PublikacjaApurinic/apyrimidinic (AP) sites in DNA are considered to be highly mutagenic and must be corrected to preserve genetic integrity, especially at high temperatures. !e gene encoding a homologue of AP exonuclease was cloned from the thermophilic anaerobic bacterium Thermoanaerobacter tengcongensis and transformed into Escherichia coli. The protein product showed high identity (80%) to human Ape1 nuclease, whereas to E. coli exonuclease...
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PRELIMINARY RESULTS FROM APPLICATION PHOSLOCK® TO REMOVE PHOSPHORUS COMPOUNDS FROM WASTEWATER
PublikacjaThe aim of the study is to assess the removal effectiveness of phosphorus compoundsby using lanthanum-modified bentonite. This material was produced by the Australian company Phoslock® Water Solutions Pty Ltd. According to the company, Phoslock® has substantial capacity to bound phosphate anions. The investigation was carried out in steady conditions in laboratory model with beakers. The results of the study are related to the...
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Ti3C2 MXenes-based catalysts for the process of α-pinene isomerization
PublikacjaIn this study, the catalytic performance of Ti3C2 MXene materials in the reaction of α-pinene isomerization was demonstrated. The influence of etching agents (HF, HF/H2SO4, and HF/HCl; weight ratios of mixed acids: 1 : 3, 1 : 4, and 1 : 5) on removing Al atoms from MAX phase, creation of an accordion-like structure typical...
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Approximating the maximum 2- and 3-edge-colorable subgraph problems
PublikacjaDla ustalonej wartości parametru k>=2, problem maksymalnego podgrafu krawędziowo k-kolorowalnego polega na wskazaniu k rozłącznych skojarzeń w grafie prostym, a kryterium optymalizacji jest maksymalizacja całkowitej liczby użytych krawędzi. W pracy podano algorytmy 5/6- i 4/5-przybliżone odpowiednio dla przypadków k=2 i k=3, poprawiając wyniki znane z literatury.
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Non-Diophantine Arithmetics in Mathematics, Physics and Psychology
PublikacjaFor a long time, all thought there was only one geometry — Euclidean geometry. Nevertheless, in the 19th century, many non-Euclidean geometries were discovered. It took almost two millennia to do this. This was the major mathematical discovery and advancement of the 19th century, which changed understanding of mathematics and the work of mathematicians providing innovative insights and tools for mathematical research and applications...
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Modelling of dark fermentation of glucose and sour cabbage
PublikacjaIn the article, modified Anaerobic Digestion Models 1 (ADM-1) was tested for modelling dark fermentation for hydrogen production. The model refitting was done with the Euler method. The new model was based on sets of differential equations. The model was checked for hydrogen production from sour cabbage in batch and semi-batch in 5 g VSS (volatile solid suspension)/L and at the semi-batch process from glucose at 5 and 10 g VSS/L....
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5-Thiocyanato-2′-deoxyuridine as a possible radiosensitizer: electron-induced formation of uracil-C5-thiyl radical and its dimerization
PublikacjaIn this work, we have synthesized 5-thiocyanato-2′-deoxyuridine (SCNdU) along with the C6-deuterated nucleobase 5-thiocyanatouracil (6-D-SCNU) and studied their reactions with radiation-produced electrons. ESR spectra in γ-irradiated nitrogen-saturated frozen homogeneous solutions (7.5 M LiCl in H2O or D2O) of these compounds show that electron-induced S–CN bond cleavage occurs to form a thiyl radical (dU-5-S˙ or 6-D-U-5-S˙) and...
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Proton conductivity in multi-component ABO4-type oxides
PublikacjaThis work investigates how configurational entropy in oxides could affect proton conductivity. For this purpose, three samples of different elemental compositions are synthesized. Five, six and seven elements were introduced into the A-site of ANbO4, forming La1/5 Nd1/5 Sm1/5Gd1/5 Eu1/5NbO4, La1/6Nd1/6Sm1/6Gd1/6Eu1/6Ho1/6NbO4 and La1/7Nd1/7Sm1/7Gd1/7Eu1/7Ho1/7Er1/7NbO4, respectively. The high configuration disorder changes the...
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Multi-functional monodispersed SiO2-TiO2 core-shell nanostructure and TEOS in the consolidation of archaeological lime mortars surfaces
PublikacjaArchaeological traditional lime mortars are susceptible to many environmental conditions such as the impact of water (rain, humidity, groundwater, etc.), variation of temperatures' degrees, wind and/or pollution. Accordingly, this research aims to provide newly assessed multifunctional Nano-coating for the purpose of archaeological lime mortar protection. For this, the study combined physicochemical and mechanical characterizations...