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Search results for: GELLING PROPERTIES
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Influence of electropolymerization conditions on the morphological and electrical properties of PEDOT film
PublicationIn this work the effects of electropolymerization conditions on the morphological properties and conductivity of poly(3,4-ethylenedioxythiophene) (PEDOT) film have been studied. PEDOT films were electrochemically synthesized in a one step process from acetonitrile solution containing 3,4-ethylenedioxythiophene (EDOT) and lithium perchlorate. Based on atomic force microscopy, scanning electron microscopy, cyclic voltammetry and...
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Luminescence properties of Eu3+ and Tb3+ doped silica-based xerogels
PublicationPure SiO2 xerogels and SiO2 xerogels containing SrF2: Eu3+/: Tb3+ crystals were prepared using sol-gel method. Luminescent spectra showed excitation and emission peaks characteristic to Eu3+ and Tb3+ 4f - 4f transitions. ET Tb3+→Eu3+ has been observed. XRD pattern of SiO2 matrix confirmed lack of long range order. Patterns of SiO2-SrF2:Eu3+ and SiO2-SrF2:Tb3+ showed peaks corresponding to SrF2. SEM images have shown agglomerates...
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Influence of thermal effects on mechanical properties of PVDF-coated fabric
PublicationThis paper describes the method of laboratory tests necessary for identification of temperature influence on mechanical properties of polyvinylidene fluoride-coated polyester fabric often used for tensile structures. Two nonlinear model descriptions are investigated. The first one is based on the piece-wise linear relations between stress and strain and the second one on the Murnaghan model of solid behavior. This paper is proposed...
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Properties of Nasicon-based CO2 sensor with Bi8Nb2O17 reference electrode
PublicationGas sensors are useful for the carbon dioxide concentration monitoring in many applications. The major challenge is to develop a potentiometric sensor working without the necessity of a reference gas and without a need of the reference electrode encapsulation. Important issue is a selection of reference electrode material, which should provide stable reference potential. For example as reference electrode material in sensor based...
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Influence of the Processing Method on the Properties of Ti-23 at.% Mo Alloy
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Effects of mechanical alloying conditions on the properties of Mg-based nanomaterials
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Magnetic, thermodynamic, and magnetotransport properties of CeGaGe and PrGaGe single crystals
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Magnetotransport properties of the correlated topological nodal-line semimetal YbCdGe
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Electromagnetic properties of a dielectric slab with an embedded silver nanowire grating
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Differential Scanning Calorimetry for Determining the Thermodynamic Properties of Selected Honeys
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Physical properties of the uranium ternary compoundsU3Bi4M3(M=Ni,Rh)
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Magnetic structure and properties of theS=5∕2triangular antiferromagnetα−NaFeO2
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Electrochemical Activity and Electrical Properties of Optimized Polypyrrole Coatings on Iron
PublicationIn this work, electrochemical activity and electrical properties of polypyrrole (PPy) coated iron electrodes have been investigated. PPy film was electrochemically polymerized from sodium salicylate aqueous solution under conditions, which provided an increase of iron corrosion resistance. It was noticed that the pH of the solution and the applied electrode potential range during the study of the polymer properties had an influence...
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Properties and applications of thermostable proteases sourced from Deinococcus geothermalis.
PublicationThe growing interest of extremophiles results from the fact that their enzymes arestable and active under harsh environment conditions. These type of biocatalysts are attractivedue to the fact that can be used in industrial processes that were previously regarded asincompatible with biological materials. Among extremozymes the largest group constitutethermozymes. Currently it is estimated that approximately 40% of enzymes used...
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Microstructural and electrical properties of Y0.07Sr0.93-xTiO3-δ perovskite ceramics
PublicationIn order to find a relationship between electrical and microstructural properties, yttrium-doped strontiumtitanate (7 mol%) with various values of strontium nonstoichiometry was investigated and shown in this work.It has been observed that yttrium doping can affect the electrical properties of SrTiO3 to a great extent.Moreover, the microstructural and electrical properties can be influenced by strontium nonstoichiometry.The defect...
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Water and chemical properties of hydrometeors over central european mountains
PublicationAtmospheric pollutants are transferred to the groundby the contribution of various types of hydrometeors. Because ofthe different techniques of measurement, comparative analysesbetween them are often neglected. Hence, the main goal is tocompare water volume and chemistry of different types ofhydrometeors and their role in both: water balance and pollutantsdeposition. The results of water input and atmospheric depositschemistry...
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An in situ technique for the assessment of adhesive properties of a joint under load
PublicationSlow crack propagation in adhesive bonded joints has been characterised using an asymmetric wedge test. Crack position was evaluated from strain gauge measurements, both in the debonded partof the joint and in the bonded zone. Test temperature was changed during loading, giving insight into bond evolution. The technique allows accurate, and virtually continuous, determination of crack position to be made, and therefore the evaluation...
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Pyrrole azocrown ethers - synthesis, crystal structures, and fluorescence properties
PublicationZsyntezowano nowe związki makrocykliczne zawierające w makropierścieniu pierścień pirolowy, grupy azowe oraz reszty chromoforowe i fluorescencyjne. Scharakteryzowano strukturę krystaliczną dwóch spośród otrzymanych makrocykli metodą rentgenografii strukturalnej. Stwierdzono, że zaprezentowane pirolowe azokorony to związki czułe i selektywne na jony ołowiu(II) oraz, że mogą być użyte jako chemosensory zarówno w spektroskopii UV-Vis,...
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Spectroscopic and photophysical properties of ZNTPP in a room temperature ionic liquid
PublicationThe steady-state absorption and emission spectra and the time-resolved Soret- and Q-band excited fluorescence profiles of the model metalloporphyrin, ZnTPP, have been measured in a highly purified sample of the common room temperature ionic liquid, [bmim][PF(6)]. S(2)-S(0) emission resulting from Soret-band excitation behaves in a manner completely consistent with that of molecular solvents of the same polarizability. The ionic...
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Constructional properties of polycarbonate plates for EURO 2012 Gdansk stadium
PublicationPrzedstawiono wyniki badań doświadczalnych dla płyt z poliwęglanu litego, które miały zostać wykorzystane jako materiał konstrukcyjno-osłonowy stadionu piłkarskiego na mistrzostwa Euro 2012 w Gdańsku. Zidentyfikowano moduł Younga oraz Poissona, wykonano próby cykliczne oraz pełzania. Właściwości mechaniczne poliwęglanu litego oceniono jako dobre, choć obawy budzą mikrorysy pojawiające się podczas badań w strukturze materiału.
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The effect of mercerized sisal fibres on natural rubber composites' properties
PublicationW pracy omówiono wyniki badań fizyko-mechanicznych kompozytów otrzymanych z mieszanek zawierających kauczuk naturalny oraz statystycznie zdyspergowane krótkie włókno sisalowe. Włókno naturalne przed użyciem poddano merceryzacji.Otrzymane wulkanizaty poddano badaniom wytrzymałościowym w warunkach statycznych w celu określenia wpływu parametrów wulkanizacji i ilości dodanego włókna na właściwości otrzymanych produktów. Stwierdzono...
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Influence of Glycols on the Glycolysis Process and the Structure and Properties of Polyurethane Elastomers
PublicationW pracy omówiono wyniki badań elastomerów wytworzonych z glikolizatów poddanych dezaminacji. Glikolizaty otrzymywano w procesie transestryfikacji polieterouretanów glikolami: propano-1,3-diolem, pentano-1,5-diolem oraz heksano-1,6-diolem. Procesy prowadzono przy trzech stosunkach masowych pianki:glikolu.
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Asymptotic properties of quadratic stochastic operators acting on the L1 space
PublicationQuadratic stochastic operators can exhibit a wide variety of asymptotic behaviours and these have been introduced and studied recently in the ℓ1 space. It turns out that in principle most of the results can be carried over to the L1 space. However, due to topological properties of this space one has to restrict in some situations to kernel quadratic stochastic operators. In this article we study the uniform and strong asymptotic...
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Environmental consequences of emulsifying properties of biosurfactant produced by Pseudomonas sp.
PublicationBiosurfactants are natural surfactants produced by variety of microorganisms. They are very prospective product due to good biodegradability, low toxicity, good physicochemical properties and high efficiency in many applications. Moreover, they are efficient in wide range of pH, temperatures and salinity. Thus, they have potential to be used in many applications. However, their later presence in municipal and industrial wastewater...
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Mechanical Properties of a Dike Formed from a Soil-ash Composite
PublicationThe paper presents the research results on application of composite soils for dike construction. The composite soil is produced by mixing bottom ash (by-product of energetics) with dredged material (sand) taken from the mouth of The Vistula river. The optimum composite for dike core was chosen with respect to mechanical parameters: high internal friction angle, good compaction and reduced hydraulic conductivity. The test dike was...
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Problems with modelling the strength properties of sailing vessels rigging ropes
PublicationThis article presents the basic parameters of soft ropes: natural fibre ropes, soft wire ropes and synthetic fibre ropes used for running rigging. There are only several materials still used for the production of natural fibre ropes, including cotton, jute, hemp, sisal and manila hemp. The most commonly used soft wire ropes are twisted pair ropes; for smaller diameters there is a 6x19M - FC rope and for larger diameters – 6x37M...
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The significance of the properties of water for the working cycle of the kinesin molecular motor
PublicationExplicit solvent molecular dynamics simulations were performed in this study to investigate and discuss several aspects of the influence of the properties of water on the working cycle of a molecular motor from the kinesin superfamily. The main objects of attention were: the binding of the neck linker and the association of the kinesin and the tubulin. The docking of the neck linker is considered a crucial event during the working...
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Characterization of structural, thermal and mechanical properties of bismuth silicate glasses
Publicationhe influence of heating and reduction processes on the structural, thermal and mechanical properties of bismuth-silicate glasses has been investigated. Two compositions of glasses: 40Bi2O3–60SiO2 (Bi0.57Si0.43Ox) and 27Bi2O3–73SiO2 (Bi0.43Si0.57Ox) were fabricated by a typical melt quenching technique. Then the reduction in hydrogen at 380 °C for 20, 42 or 67 h was performed. It was found that a 50 μm-thick layer was formed on...
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Heat capacities and thermodynamic properties of antimony substituted lanthanum orthoniobates
PublicationThe results of heat capacity measurements for the lanthanum orthoniobate substituted with 10, 20 and 30 mol% of antimony (LaNb0.9Sb0.1O4, LaNb0.8Sb0.2O4 and LaNb0.7Sb0.3O4) are presented and discussed. Temperature dependence of low temperature heat capacity was analyzed within the Debye and Einstein models. The Debye temperature decreased, whereas the Einstein temperature increased with antimony content. The decrease of the Debye...
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Physical properties and electronic structure of La3Co and La3Ni intermetallic superconductors
PublicationLa3Co and La3Ni are reported superconductors with transition temperatures of 4.5 and 6 K, respectively. Here, we reinvestigate the physical properties of these two intermetallic compounds with magnetic susceptibility χ, specific heat Cp and electrical resistivity ρ measurements down to 1.9 K. Although bulk superconductivity is confirmed in La3Co, as observed previously, only a trace of it is found in La3Ni, indicating that the...
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Changes in rheological properties during anaerobic digestion of activated sludge
PublicationWykonane pomiary właściwości reologicznych osadwo nadmiernych poddawanych procesowi dezintegracji mechanicznej wskazują na znaczny spadek lepkości sięgający 60%. Wraz ze stopniem dezintegracji rosły również właściwości pseudoplastyczne oraz malała granica płynięcia. Podobnie istotne zmiany właściwosci reologicznych nastepowały w osadach poddawanych fermentacji metanowej.
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Photocatalytic activity and surface properties of carbon-doped titanium dioxide
PublicationTiO2 domieszkowany węglem otrzymano poprzez hydrolizę izopropanolanu tytanu(IV) i kalcynację w 350ºC w atmosferze powietrza przez 2h. Przeprowadzone badania wykazały, że fenol (0.21 mM) jest efektywnie degradowany w fazie wodnej, w obecności otrzymanego fotokatalizatora oraz światła z zakresu widzialnego (λ>400 nm). Pole powierzchni właściwej otrzymanego C-TiO2 wynosiło około 127 m2/g, fotokatalizator absorbuje światło z zakresu...
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The influence of plastic deformation on the magnetoelastic properties of the CSN12021 grade steel
PublicationWłasności magnetosprężyste materiałów są silnie modyfikowane przez zmiany struktury dyslokacyjnej, które są wynikiem procesów deformacji plastycznej. Zmiany te mogą być wykorzystane jako podstawa do opracowania metody nieniszczącej oceny stopnia deformacji materiału.Jak dotychczas zaproponowane zostały różne metody, oparte na pomiarach pętli histerezy magnetycznej czy też natężenia magnetycznego efektu Barkhausena. Artykuł porównuje...
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Thermal and mechanical properties of polyurethanes modified with L-ascorbic acid
PublicationIn this study we report the thermal and mechanical properties of polyurethanes modified with ascorbic acid (AA). Ascorbic acid was used as a modifier at concentration of 1 or 2 mass%. The antioxidative properties of AA may improve the biocompatibility of the obtained materials, which were designed for biomedical applications. In this paper we describe characterization of obtained unmodified and ascorbic acid modified polyurethanes...
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Effect of polymer fibres reinforcement on selected properties of asphalt mixtures
PublicationThe paper presents selected results of the research program concerning fibre reinforced asphalt concrete. Aramid-polyalphaolefin fibres was used in this study. Selected properties responsible for low temperature cracking and resistance to permanent deformation are presented in this paper. Low temperature cracking susceptibility was evaluated with the results obtained from bending test of rectangular beams with constant rate of...
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Five-phase squirrel-cage motor. Construction and drive properties
PublicationThis paper presents the simulation and experimental results of a five-phase squirrel-cage induction motor. The new machine has been designed to operate in a drive system with third harmonic rotor flux injection in order to improve the motor torque utilization. The motor structure, the mathematical model as well as the laboratory prototype have been described. The motor speed-torque characteristics and transients are elaborated...
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Effect of Polymerization Statistics on the Electronic Properties of Copolymers for Organic Photovoltaics
PublicationStatistical block copolymers, composed of donor (D) and acceptor (A) blocks, are a novel type of material for organic photovoltaics (OPVs) devices. In particular a new series of polymers based on PBTZT-stat-BDTT-8, recently developed by Merck, offers high solubility in different solvents, and a high power conversion efficiency (PCE) in different device architectures. Although it is known that the electronic properties of these...
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Properties and Formation of Mineralized Veins in an Organic-Rich Shale Formation
PublicationAn earlier paper defined mineral and organic matter constituents in weak interfaces in shale formations (Ptaszynska, et. al., 2016). The formation studied in the earlier work and here is the Jurassic, early-Cretaceous Vaca Muerta formation in the Neuquen basin in Argentina. In this earlier work, mineralized "veins" were noted to be prevalent and complicated, sometimes being shear weak interfaces while in other cases they were not....
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The influence of rubber recyclate morphology on the properties of rubber-asphalt composite
PublicationIn the paper wastes, mostly in the form of used tires, were analyzed. One of the methods of waste tires application use them as a modifier of asphalt. However, the properties of rubber-asphalt composites depend on the morphology of waste tiregranulate and kind of tire recycled (car/truck). In this chapter, the influence of grinding methods of waste tire on the prop¬erties of rubber-asphalt composites were studied. SEM analysis...
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Generalized adaptive comb filter with improved accuracy and robustness properties
PublicationGeneralized adaptive comb lters can be used to identify/track parameters of quasi-periodically varying systems.In a special, signal case they reduce down to adaptive comblters, applied to elimination or extraction of nonstationarymulti-harmonic signals buried in noise. We proposea new algorithm which combines, in an adaptive way, resultsyielded by several, simultaneously working generalizedadaptive comb lters. Due to its highly...
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Luminescent properties of Ln3+ doped tellurite glasses containing AlF3
PublicationThe low-phonon energy tellurite glasses TeO2-BaO-Bi2O3 and TeO2-BaO-Bi2O3-AlF3 triply doped with Eu3+, Tb3+, Tm3+ ions in two different molar ratios were synthesized using melt-quenching technique. Their structure and luminescence properties were widely investigated by X-ray Diffraction (XRD), Differential Scanning Calorimetry (DSC), Fourier Transform Infrared Spectroscopy (FTIR) and Photoluminescence Spectroscopy (PL). The luminescence...
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The influence of Be addition on the structure and thermal properties of alkali-silicate glasses
PublicationBe-Na-(Li)-Si oxide glasses containing up to 15 mol% of BeO were prepared. Their structure was characterized by X-ray powder diffraction and Raman as well as infrared spectroscopic techniques, while their chemical compositions were examined by Inductively Coupled Plasma Optical Emission Spectrometry. All materials were found to be amorphous and contain Al contaminations from minor dissolution of the alumina crucibles. The results...
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Mechanical properties of two-stage concrete modified by silica fume
PublicationAbstract. Two-stage concretes, despite the fact that they have proven themselves in various types of construction, have not been studied to the same extent as traditional heavy concretes. Therefore, the article developed the composition of frame concrete with various additives in the composition of the cement-sand mortar. A comparison of the mechanical characteristics of the developed compositions with the addition of silica fume...
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Optical properties of daylight curable resin doped with nanodiamond powder
PublicationIn this paper a new material for 3D printing was elaborated on. Since diamond has very good optical properties, an idea occurred to us to apply it in 3D printing process. A mixture of nanodiamond powder and a standard 3D printing resin was created and several printouts have been completed. They have been tested for their abilities to transmit and absorb light in a wide spectrum of wavelengths. It turned out that the nanopowder...
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Effects of V2O5 Additive on Structure and Dielectric Properties of BiNbO4 Ceramics
PublicationGoal of the present research was to investigate the influence of V2O5 additive on the structure and dielectric properties of BiNbO4 ceramics. To fabricate BiNbO4 ceramics with V2O5 added the solid state reaction route and pressureless sintering was utilized. Thus obtained ceramics was characterized in terms of its microstructure (SEM), chemical composition (EDS), phase composition and crystalline structure (X-ray phase and structural...
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Study of anticorrosion and microwave absprption properties of NiZn ferrite pigments
PublicationPurpose - The purpose of this paper is to report the electrochemical verification of anticorrosive properties of NiZn ferrites as pigments in protective coatings and evaluation of their microwave absorbing properties. Design/methodology/approach - Ferrites, represented by formula NixZn(1-x)Fe2O4, where x=0, 0.2, 0.4, 0.6, 0.8, 1.0, were synthesized using a ceramic method. The samples of ferrites were examined by X-ray diffraction...
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Crystal structure and physical properties of a novel ternary compound La15MoxGe9
PublicationWe present the synthesis, structural characterization and physical properties measurements of a new compound, La15MoxGe9 in Mn5Si3-type derived structure with interstitial Mo. The sample was synthesized by arc-melting method. La15MoxGe9 crystallizes in non-centrosymmetric hexagonal structure P63mc (#186) with lattice parameters a = b = 15.495(5) Å and c = 6.917(2) Å. The refinement on single X-ray diffraction data show that interstitial...
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Ionic liquids in the microextraction techniques: the influence of ILs structure and properties
PublicationIonic liquids (ILs) are composed entirely of ions thus they possess unique properties, including negligible volatility, a liquid state in a broad range of temperatures and ability to change them depending on the chosen type of anion and cation, which make ILs unique and useful for many applications in sample preparation techniques. A deeper understanding of the nature of ILs and the impact of their structure on their parameters...
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Metabolomic and antioxidant properties of different varieties and origins of Dragon fruit
PublicationDragon fruit has appealed much concern from consumers as a novelty fruit with potent nutritional and medicinal benefits. Dragon fruit quality warrants comprehensive evaluation, based on the contents of pigments and health- promoting natural compounds in different varieties. This study was aimed to evaluate the differences among dragon fruit varieties extracted with methanol–water (CD3OD-D2O) and methanol (CD3OD) by proton nuclear magnetic...
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Analysis of Denoising Autoencoder Properties Through Misspelling Correction Task
PublicationThe paper analyzes some properties of denoising autoencoders using the problem of misspellings correction as an exemplary task. We evaluate the capacity of the network in its classical feed-forward form. We also propose a modification to the output layer of the net, which we called multi-softmax. Experiments show that the model trained with this output layer outperforms traditional network both in learning time and accuracy. We...