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Electrical properties of silicate-lead glasses containing nanostructures of iron oxides.
Dane BadawczeElectrical properties of silicate-lead glasses doped with different content of iron oxide was studied. The set of glass samples were prepared with the composition of (50 − 0.5x)SiO2–(50 − 0.5x)PbO–xFe2O3, where x = 2, 5, 10, 15, 20 and 25 (in mol%). All sampleswere prepared by the conventional melt quenching technique; the melting was conducted in...
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Linear impedance of 1SiO2–99(40Na2O-20CaO-40P2O5) glass measured with impedance spectroscopy method at low temperature region
Dane BadawczeThe linear electrical properties of 1SiO2–99(40Na2O-20CaO-40P2O5) glass was measured by impedance spectroscopy method.
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Property sustainable value versus highest and best use analyzes
PublikacjaThis article proposes the possibility of applying fuzzy logic theory to perform the tasks of determining the market value of agricultural lands. These tasks are of a multi‐criteria character, as multiple factors are taken into consideration during the land value valuation process. The market value of agricultural land plots, calculated using fuzzy logic methods, can provide a basis for further use in the processes that are directly...
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Development of iron doped strontium titanates as oxygen electrode for solid oxide fuel cells
PublikacjaProducing efficient solid oxide fuel cells (SOFC) without the use of harmful elements is one of the current challenges. Increasing the safety of people and reducing production costs is possible, among others, thanks to the use of iron doped strontium titanates as porous oxygen electrodes. In this thesis, the results of research on iron doped strontium titanates as potential oxygen electrodes for SOFC are presented. The research...
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Nonlinear impedance of vanadate glass-ceramics containing BaTiO3
Dane BadawczeThe nonlinear impedance of vanadate glasses doped with BaTiO3 was measured. Samples of the composition of x[BaO,TiO2]–(80 − x)V2O5–20Bi2O3 where x = 5, 10 and 15 in mol% were prepared by a conventional melt quenching technique. The melting was performed in alumina crucibles at the temperature of 1273 K–1373 K. The melts were poured on a preheated (573...
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Tworzenie wartości dla akcjonariuszy w świetle nadzoru korporacyjnego
PublikacjaDuży odsetek spółek publicznych w Polsce nie tworzy wartości dla akcjonariuszy. Zaprezento-wano wyniki badań dotyczących wpływu struktur własności na efektywność działania spółek pu-blicznych. Badania te nie były w stanie wyjaśnić w wystarczającym stopniu zjawiska destrukcji warto-ści. Starano się wykazać, że jedną z przyczyn tego zjawiska jest transfer wartości. Zalicza się go do głównych problemów nadzoru korporacyjnego. Szczególna...
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Characterization of various drinking waters by new potentiometric taste sensor with lipid, lipid-like polymer membranes
PublikacjaA new sensing system comprising five all-solid-state electrodes with lipid, lipid like-polymer membranes was applied for rapid qualitative and quantitative analysis of various drinking waters. The results elaborated by chemometric methods revealed sensitivity to CO2 content in drinking water, suggesting that this sensing system could be used as a taste sensor. The ability of taste sensor to perform quantitative analysis of minerals...
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Reactive Processing and Functionalization of Ground Tire Rubber
PublikacjaThe dynamic development of the automotive industry resulted in a sig- nificant increase in rubber wastes, especially end-of-life tires, which are a serious threat to the natural environment and human health. This situation has enforced the industry and academic research groups to search new and cost-effective methods for recycling waste tires. In this field of research, reactive processing and functionaliza- tion seem to be a...
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The analysis of temperature changes of the saliva traces left on the fur during laboratory rats social contacts
PublikacjaAutomatic analysis of complex rodent social be- havior, especially aggressive ones, is of important scientific interest. In this paper we analyze the properties of the data created as a result of aggressive rodent social behavior. Detec- tion of specific aggressive behaviors is based on the event of leaving traces of saliva on the fur of the attacked individual, which are clearly visible in the thermal imaging. The traces change...
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SILICA AEROGEL TOWARDS ANODES FOR LITHIUM-ION BATTERIES
PublikacjaAn increasing demand for electrochemical energy storage and conversion devices stimulates progress in research on electrode and electrolyte materials. In the field of electrodes materials, silicon is the one of the most promising anode materials for Li-ion batteries. However silicon has the drastic volume variation (around 3 times lower on extraction) during insertion and extraction of lithium ions. As an alternative, nanocomposites...
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Utilization of shale cuttings in production of lightweight aggregates
PublikacjaThe development of technologies for unconventional hydrocarbon exploration requires designing procedures to manage drilling waste that are consistent with the waste management hierarchy. In view of this, the possibility to apply shale drill cuttings as a prospective additive (replacing bentonite) to fly ash used for the production of lightweight aggregates (LWAs) was investigated. Moreover, a facile, waste-free method of LWAs production...
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Modeling and simulation of blood flow under the influence of radioactive materials having slip with MHD and nonlinear mixed convection
PublikacjaRadioactive materials are widely in industry, nuclear plants and medical treatments. Scientists and workers in these fields are mostly exposed to such materials, and adverse effects on blood and temperature profiles are observed. In this regard, objective of the current study is to model and simulate blood based nanofluid with three very important radioactive materials, named as Uranium dioxide (UO2), Thorium dioxide (ThO2) and...
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Influence of pore formers on electrical properties of CaTi0.9Fe0.1O3-δ perovskite-type ceramics
PublikacjaPorous CaTi0.9Fe0.1O3-δ (CTF) perovskites were synthesized by the standard solid state method at different sintering temperatures with carbon black (CB), corn starch (CS) and potato starch (PS) as pore-forming agents. The ceramic samples of porosity between 9% and 42% with 5 - 40 μm pore sizes, were obtained by a 6 h sintering at either 1130º C or 1200º C of precursor powder prepared at 1470º C. X-ray diffraction analysis proved...
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Ordered titanium templates functionalized by gold films for biosensing applications – Towards non-enzymatic glucose detection
PublikacjaRecently, metal nanostructures evoke much interest due to application potential in highly sensitive detectors in biochemistry and medical diagnostics. In this work we report on preparation and characteristics of thin (1–100 nm) Au films deposited onto highly ordered structured titanium templates for SERS (Surface Enhanced Raman Spectroscopy) and electrochemical sensing. The Ti templates are formed by selective removal of TiO2 nanotubes...
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Influence of selected submicron inorganic particles on mechanical and thermo-mechanical properties of unsaturated polyester/glass composites
PublikacjaIn this paper, the influence of different submicron-scaled particles (zinc oxide, titanium dioxide, or silica) on mechanical and thermo-mechanical properties of unsaturated polyester matrix composites reinforced with glass fabric was investigated. Surface morphology of obtained composites was also examined. At first inorganic particles were mechanically dispersed into unsaturated polyester resin system as per the calculated weight...
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Fuzzy reasoning system design and assessment of load-bearing endoprostheses and their fabrication processes
PublikacjaZaproponowano piec zastosowan podejscia rozumowania rozmytego do rozwiazania problemów w dziedzinie biomechanikioraz inzynierii biomateriałów. Obejmuja one: (A) oszacowanie maksymalnych naprezen kontaktowych działajacych naendoproteze, (B) zaprojektowanie procesu spiekania dla otrzymania porowatego implantu, (C) opracowanie planu utleniania wcelu otrzymania struktury nanorurkowej na stopach Ti, (D) oraz (E) zaprojektowanie osadzania...
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Linking optical and electronic properties to photoresponse of heterojunctions based on titania nanotubes and chromium, molybdenum, and tungsten oxides
PublikacjaThe development of photosensitization strategies for titanium dioxide is necessary for the enhancement of its optical and electronic properties towards its application potential in solar photoelectrochemistry. In this work, significant differences in the photosensitizing capability of the 6th group transition metal oxides applied on the surface of titania nanotubes are reported. For the first time, correlations between the experimentally...
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XPS analysis of TBBO glass
Dane BadawczeGlasses and glass-ceramics with nominal composition 73 TeO2– 4BaO– 3Bi2O3–18SrF2-2RE2O3 (where RE = Eu, Dy) have been synthesized by conventional melt-quenching technique and subsequent heat treatment at 370 °C for 24 h in air atmosphere. Various Eu3+ to Dy3+ molar ratio have been applied to investigate luminescence properties in both glass and glass-ceramic...
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Stan czystości jezior na terenie województwa Pomorskiego = Water quality of the lakes in the Pomerania Province
PublikacjaW ramach części doświadczalnej pracy przeprowadzono analizę jakości wód z wybranych jezior. Wykonano analizy nastepujących parametrów: pH, NO3-, NO2-, F-, NH4+, Cl-, HS-, SO42-, Fecal, Mn2+, PO43-, SiO2, Al3+. Dla wybranych próbek zmierzono również parametr toksyczności. W przypadku dwóch próbek jego wysokość wskazywała na to, że badana woda zawierała substancje toksyczne. Na podstawie uzyskanych wyników badane próbki wody pochodzące...
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Signatures and acoustic images of objects moving in water
PublikacjaObservation of underwater space is part of a generaltrend, which primary purpose is to protect and increasesafety in the selected area. The basic aim of the paper ispresentation of designated acoustic characteristics typicalfor objects moving on the water surface and under water,which represent some knowledge about detection of theseobjects. Create a catalog of acoustic signature and not onlyacoustic, as well as acoustic images...
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Źródła generacji rozproszonej w systemie elektroenergetycznym
PublikacjaW artykule przedstawiono podstawy elementów systemu rozproszonej generacji. Wskazano na budowę systemu elektroenergetycznego wyposażonego w sterowane odbiory, źródła rozproszone, magazyny energii i układy kontroli napięcia FACTS. Renesans tych źródeł "pozasystemowych" (ang. non-utility genera-tion - NUG) jest wynikiem głębokich przemian w sferach techno-logii, organizacji i finansowania, zarządzania i nowego spojrzenia na ochronę...
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CSR in Polish SMEs- from perception to infatuation. Examples of socially engaged firms from Pomeranian Region
PublikacjaDespite the increasing worldwide awareness of the importance of social issues in con-temporary business management, Polish small and medium-sized enterprises seem to re-main in the group of followers, certainly not leaders, of the corporate social responsibility (CSR) movement, and this despite important dissemination efforts by numerous institu-tions. The aim of this paper is to present the bumpy road to the (still incomplete)...
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Toxicity and chemical analyses of airport runoff waters in Poland
PublikacjaThe aim of this study was to assess the ecotoxicological effects of various compounds in complex airport effluents using a chemical and ecotoxicological integrated strategy. The present work deals with the determination of sum of PCBs, PAHs, pesticides, cations, anions, phenols, anionic, cationic, non-ionic detergents, formaldehyde and metals – as well as TOC and conductivity – in runoff water samples collected from 2009 to 2011...
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Wpływ sfunkcjonalizowanych nanocząstek typu rdzeń-powłoka (Fe3O4@SiO2) na zahamowanie enzymów grzybiczych w systemach in vitro
ProjektyProjekt realizowany w Katedra Technologii Leków i Biochemii zgodnie z porozumieniem UMO-2015/17/N/NZ7/01087 z dnia 2016-03-17
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Dynamic Charging of Electric Buses as a Way to Reduce Investment Risks of Urban Transport System Electrification
PublikacjaNight charging and fast charging are currently the two most common systems for charging electric buses. Despite the fact that numerous trial installations were started, neither of these two systems has obtained unqualified approval of the users. The alternative is to charge vehicles in motion - dynamic charging which combines the advantages of trolleybus transport and of electric buses. One of the advantages is the reduction of...
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Nonlinear impedance in oxide glasses containing single and mixed alkali ions
PublikacjaThe aim of the present was to find more clues on the nonlinearities in impedance of oxide glasses. The first family of researched glasses has a composition of FeO-P2O5-Na2O. Oxide glasses containing iron and alkali are well known for a very low alkali ion mobility and may be considered purely polaron conducting. These glasses show no detectable nonlinearities in the impedance spectra. The second was a family of ionic conducting...
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Insightful studies of AuCu nanostructures deposited on Ti platform: Effect of rapid thermal annealing on photoelectrochemical activity supported by synchrotron radiation studies
PublikacjaIn this work, we present the influence of annealing atmospheres during rapid thermal annealing (40◦C/s) on nanostructured Ti platforms modified by 10 nm layer of AuCu alloy obtained via magnetron sputtering. The AuCu/Ti platform annealed under hydrogen atmosphere exhibits the best photoelectrochemical activity under visible light, i.e. 27 times higher photocurrent than for pure Ti dimpled platform, and the lowest reflectance with minimum...
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Degradation of metamizole sodium
PublikacjaW ostatnich latach notuje się znaczący wzrost konsumpcji leków i suplementów diety. Wiele osób nie zdaje sobie sprawy z niebezpieczeństw jakie niesie za sobą stosowanie leków na własną rękę. Leki przeciwbólowe i przeciwgorączkowe są stosowane w olbrzymich ilościach. Dostają się one do środowiska poprzez oczyszczalnie ścieków, odchody ludzkie i zwierzęce. W celu określenia wpływu tych grup leków na środowisko przeprowadzono badania...
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Synthesis of Titanium Dioxide via Surfactant-Assisted Microwave Method for Photocatalytic and Dye-Sensitized Solar Cells Applications
PublikacjaIn this study, titania nanoparticles were obtained using the microwave-assisted technique. Moreover, different surfactants (PEG (Mn = 400), Pluronic P123 and Triton X−100) were used during the synthesis in order to determine their impact on the crystallinity and morphology of the final products. Subsequently, techniques such as XRD, SEM and TEM (performed in high contrast and high-resolution mode), diffuse reflectance spectroscopy...
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Influence of Surface Modification of Titanium and Its Alloys for Medical Implants on Their Corrosion Behavior
PublikacjaTitanium and its alloys are often used for long-term implants after their surface treatment. Such surface modification is usually performed to improve biological properties but seldom to increase corrosion resistance. This paper presents research results performed on such metallic materials modified by a variety of techniques: direct voltage anodic oxidation in the presence of fluorides, micro-arc oxidation (MAO), pulse laser treatment,...
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Degradation of xylose using a microbial fuel cell
PublikacjaIt is generally known, that many kind of microorganisms are capable of using carbohydrates as a source of carbon and energy in an environment. The biodegradation process of monosaccharides from pentoses (in this case- racemic mixture of D - and L – xylose) is an immense opportunity for an entire reduction of biological contamination to neutral compounds through MFC. The process is occurred in a single-chamber MFC, which is contained...
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High-performance anode-supported solid oxide fuel cells with co-fired Sm0.2Ce0.8O2-δ/La0.8Sr0.2Ga0.8Mg0.2O3−δ/Sm0.2Ce0.8O2-δ sandwiched electrolyte
PublikacjaIn this study, intermediate-temperature solid oxide fuel cells (IT-SOFCs) with a nine-layer structure are constructed via a simple method based on the cost-effective tape casting-screen printing-co-firing process with the structure composed of a NiO-based four-layer anode, a Sm0.2Ce0·8O2-δ(SDC)/La0·8Sr0.2Ga0.8Mg0·2O3−δ (LSGM)/SDC tri-layer electrolyte, and an La0·6Sr0·4Co0·2Fe0·8O3-δ (LSCF)-based bi-layer cathode. The resultant...
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Structural, physicochemical and anticancer study of Zn complexes with pyridyl-based thiazolyl-hydrazones
PublikacjaThiazolyl-hydrazones (THs) exhibit a wide spectrum of biological activity that can be enhanced by complexation with various metal ions. Zn(II) complexes with α-pyridine-1,3-TH ligands may represent an alternative to the standard platinum-based chemotherapeutics. In addition, they show photoluminescence properties and thus can be regarded as multifunctional materials. In this study, we synthesized and characterized three neutral...
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Music Data Processing and Mining in Large Databases for Active Media
PublikacjaThe aim of this paper was to investigate the problem of music data processing and mining in large databases. Tests were performed on a large data-base that included approximately 30000 audio files divided into 11 classes cor-responding to music genres with different cardinalities. Every audio file was de-scribed by a 173-element feature vector. To reduce the dimensionality of data the Principal Component Analysis (PCA) with variable...
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Polaron hopping conduction in manganese borosilicate glass
PublikacjaA study on a novel material - manganese borosilicate glass without alkali metals, was reported. It was found that the obtained samples containing high amount of manganese oxide (60MnO–xSiO2–(40 − x)B2O3, x = 5, 10, 15, 20 and 30 mol%) were amorphous and homogeneous. XPS measurements showed that most of manganese ions are at oxidation level of Mn2 + ions and the mean oxidation level slightly moves toward higher value, with increasing...
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A derivatisation agent selection guide
PublikacjaThe development of new tools for providing high quality information in a cost-effective and expeditious way is one of the main aims of analytical chemistry. Remarkably, the introduc- tion of the 12 principles of green chemistry paved the way forward for the development of analytical methodologies that are, ideally, inherently safe for the operator and the environ- ment, with the least possible consumption of energy and chemicals,...
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Design and Synthesis of NTU-9/C3N4 Photocatalysts: Effects of NTU-9 Content and Composite Preparation Method
PublikacjaHybrid materials based on graphitic carbon nitride (g-C3N4) and NTU-9 metal–organic frameworks (MOF) were designed and prepared via solvothermal synthesis and calcination in air. The as-prepared photocatalysts were subsequently characterized using Brunauer–Emmett–Teller (BET) analysis, UV-Vis diffuse reflectance spectroscopy (DRS), photoluminescence (PL) emission spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy...
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Properties of an innovative multi-functional finish for the improvement of indoor air quality
PublikacjaDue to lifestyle changes, people spend most of their time indoors at present; thus, Indoor Air Quality (IAQ) is a matter of utmost importance. Multi-functional and innovative finishes can help to passively improve the IAQ, benefitting the health and comfort of occupants. For this study, reference and pre-mixed commercial mortars are compared to a new multi-functional hydraulic lime mortar for indoor finishes, in which conventional...
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In Vitro Studies on Nanoporous, Nanotubular and Nanosponge-Like Titania Coatings, with the Use of Adipose-Derived Stem Cells
PublikacjaIn vitro biological research on a group of amorphous titania coatings of different nanoarchitectures (nanoporous, nanotubular, and nanosponge-like) produced on the surface of Ti6Al4V alloy samples have been carried out, aimed at assessing their ability to interact with adipose-derived mesenchymal stem cells (ADSCs) and affect their activity. The attention has been drawn to the influence of surface coating architecture and its physicochemical...
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Titania Nanofiber Scaffolds with Enhanced Biointegration Activity—Preliminary In Vitro Studies
PublikacjaThe increasing need for novel bone replacement materials has been driving numerous studies on modifying their surface to stimulate osteogenic cells expansion and to accelerate bone tissue regeneration. The goal of the presented study was to optimize the production of titania-based bioactive materials with high porosity and defined nanostructure, which supports the cell viability and growth. We have chosen to our experiments TiO2...
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Noise and Electro-Ultrasonic Spectroscopy of Conducting PolymerThick Films
PublikacjaThick conducting films based on conducting polymer are characterized by DC conductivity and noise in temperature range 10 to 300 K. Conducting polymers could be used e.g. for the top electrode (cathode) in the solid tantalum or niobium capacitors. On the conducting polymer layer the top layer of carbon/graphite and/or silver polymer based pastes is applied in the capacitor technology. Our samples structure consists of conducting...
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Linear and nonlinear impedance of alkali and iron doped silicate-lead glasses
Dane BadawczeLinear and nonlinear impedance was studied for lead-silicate glass samples doped with iron ions and alkaline oxides. The compositions of glasses were as follows: (in %mol) 50% SiO2, 25% PbO, 15% Fe2O3 and 15% one of alkaline oxides: Na2O, K2O, Li2O. All samples were prepared by the conventional melt quenching technique. The substrates were powdered...
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A Multifunctional Microwave Filter/Sensor Component Using a Split Ring Resonator Loaded Transmission Line
PublikacjaThis research is focused on the design and realiza2 tion of a microwave component with multifunctional filter/sensor 3 operation using a resonator-loaded transmission line (TL). It is 4 shown that while the structure acts as a bandstop filter, the 5 phase of the reflection coefficient from the loading resonator(s) 6 on a movable layer can be used for displacement sensing, thus 7 allowing for combining filtering with sensing in...
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Transparent nanocomposite coatings based on epoxy and layered double hydroxide: Nonisothermal cure kinetics and viscoelastic behavior assessments
PublikacjaLayered double hydroxide (LDH) has a particular place in clay family because of its flame retardant action. The nanoplatelet-like structure of LDH makes possible development of polymer composites with cationic or anionic nature structures in which macromolecules are positioned in between nanoplatelet galleries. In this work, neat epoxy and its transparent nanocomposite coatings with sodium dodecylbenzene sulfonate (SDBS)-modified...
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The Reactivity of Phosphanylphosphinidene Complexes of Transition Metals Toward Terminal Dihaloalkanes
PublikacjaThe reactivities of phosphanylphosphinidene complexes [(DippN)2W(Cl)(η2-P−PtBu2)]− (1), [(pTol3P)2Pt(η2- P=PtBu2)] (2), and [(dppe)Pt(η2-P=PtBu2)] (3) toward dihaloalkanes and methyl iodide were investigated. The reactions of the anionic tungsten complex (1) with stochiometric Br(CH2)nBr (n = 3, 4, 6) led to the formation of neutral complexes with a tBu2PP(CH2)3Br ligand or neutral dinuclear complexes with unusual tetradentate...
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The Use of Organic Coagulants in the Primary Precipitation Process at Wastewater Treatment Plants
PublikacjaMeasurements for determining the effect of chemically enhanced primary treatment (CEPT) on the efficiency of pollutant removal from wastewater were carried out using conventional inorganic coagulants PIX113 with polymer A110 (Kemipol, Police, Poland) and unconventional cationic organic coagulants Cofloc (Attana, Coalville, UK) C29510 (Kemipol, Police, Poland) and Sedifloc 575 (3F Chimica, Sandrigo, Italy). The average removal efficiency...
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First evaluation of wastewater discharge influence on marine water contamination in the vicinity of Arctowski Station (Maritime Antarctica)
PublikacjaIn Antarctica,waste is generatedmainly during scientific research programmes and related logistics. In this study, the impact ofwastewater on the western shore of Admiralty Baywas investigated during austral summer in 2017 and 2019. A range of physicochemical parameters and the presence of selected trace metals, formaldehyde and different groups of surfactants were determined in wastewater coming from Arctowski Station and in nearby coastal...
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Cu( II ) ions removal from wastewater using starch nanoparticles ( SNPs ): An Eco‐sustainable approach
PublikacjaThe complex structured starch particles were reduced to the nanoscale size range through hydrolysis utilizing low concentration acid assisted with ultrasound irradiation. The synthesized starch nanoparticles (SNPs) were characterized by TEM, FTIR, and XRD techniques. The synthesized SNPs possessed surface activated entities, as many cationic functional groups were confirmed through the FTIR spectrum. Also, these SNPs were effectively...
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Nonlinear high temperature impedance of 35P2O5-30Fe2O3-27.5Nb2O5-7.5TiO2 glass
Dane BadawczeThe nonlinear high temperature impedance of iron- phosphate glasses doped with niobium oxide was measured. Glass samples of the composition of 35P2O5-30Fe2O3-27.5Nb2O5-7.5TiO2 (in %mol) were prepared by the conventional melt quenching technique. Appropriate amounts of reagents ((NH4)2HPO4 (≥99.9%, POCH), Fe2O3 (≥99.9%, POCH), Nb2O5 (≥99.9%, PLUKA AG)...
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Electrical characterization of diamond/boron doped diamond nanostructures for use in harsh environment applications
PublikacjaThe polycrystalline boron doped diamond (BDD) shows stable electrical properties and high tolerance for harsh environments (e.g. high temperature or aggressive chemical compounds) comparing to other materials used in semiconductor devices. In this study authors have designed electronic devices fabricated from non-intentionally (NiD) films and highly boron doped diamond structures. Presented semiconductor devices consist of highly...