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Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar. 4. Bitumen-Polymer Blends with Participation of Coumarone-Indene Resins with Epoxy Groups
PublicationUsing light fraction of coal tar (5.75 wt % of coumarone and 44.45 wt % of indene), glycidyl methacrylate and styrene, the coumarone-indene resin with epoxy groups (CIRE) has been synthesized. Monoperoxy derivative of diglycidyl ether Bisphenol A (PO) was used as an initiator. The possible formation of CIRE has been studied on the model systems consisting of PO, glycidyl methacrylate, indene or coumarone, or styrene, or mixture...
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The Impact of Hybrid Flame Retardant Compositions on the Performance of Foamed Flexible Polyurethane/Ground Tire Rubber Composites
PublicationCurrent sustainability-oriented trends affect polyurethane (PU) materials and stimulate the incorporation of recycled or waste-based materials as fillers. Ground tire rubber (GTR) poses as an auspicious candidate due to the excellent performance of car tires. Despite the benefits related to the mechanical performance, it contributes to the increasing flammability of the resulting composites. Herein, presented work assessed the...
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ARCHITECTURE IN BRANDING AND OVERBRANDING PROCESS. HOW GLOBALIZATION INFLUENCED ARCHITECTURE QUALITY.
PublicationGlobalization is unification. In the field of architecture and in the social structure alike, the globalization leads to a blending of economies and cultures that produces uniformly branded public space as a response to universal assumptions of integration and correlation. While branding consists in creating a recognizable and outstanding image a strong contradiction exists between both of these approaches. As a result, regional...
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Characterization of two aminotransferases from Candida albicans
PublicationAminoadipate aminotransferase (AmAA) is an enzyme of α-aminoadipate pathway (AAP) for l-lysine biosynthesis. AmAA may also participated in biosynthesis or degradation of aromatic amino acids and in d-tryptophan based pigment production. The AAP is unique for fungal microorganisms. Enzymes involved in this pathway have specific structures and properties. These features can be used as potential molecular markers. Enzymes catalyzing...
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Electrochemical simulation of metabolic reduction and conjugation reactions of unsymmetrical bisacridine antitumor agents, C-2028 and C-2053
PublicationElectrochemistry (EC) coupled with analysis techniques such as liquid chromatography (LC) and mass spectrometry (MS) has been developed as a powerful tool for drug metabolism simulation. The application of EC in metabolic studies is particularly favourable due to the low matrix contribution compared to in vitro or in vivo biological models. In this paper, the EC(/LC)/MS system was applied to simulate phase I metabolism of the representative...
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Factors affecting the quality of bottled water
PublicationThe ever-increasing popularity of bottled water means that it is important to analyze not only its mineral content but also, above all,its content of possible contaminants, especially the organic ones. In this respect, bottled waters are a special case, because apartfrom organic chemical contaminants derived from the well from which they were acquired, their secondary contamination is alwayspossible, during treatment or storage...
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Effect of oxygenation time on signal of a sensor based on ionic liquids
PublicationThe paper presents an oxygen sensor based on ionic liquids and solid electrodes. The following ionic liquids have been employed: [BMIM][BF4], [HMIM][Cl], [BMIM][N(CN2)]. Minimum time of the sensor exposure to analyte, after which the signal (current intensity) was stable, has been evaluated. An impact of volumetric flow rate of analyte on the sensor exposure time and signal has been determined. A product of permeability coefficient...
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DESIGN THINKING ORIENTED METHODOLOGY IN GROUP PROJECT AS A STEP IN THE CDIO APPROACH
PublicationRecently much scientific research and industrial work is conducted in multidisciplinary teams, where cooperation between specialists from different areas of expertise is required in order to successfully address the challenging goals. Moreover, in start-up small companies the lack of supporting departments calls for additional multidisciplinary, economic and networking skills known as T-shaped personality. Recognizing these shortcomings...
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Combinatorial scheme of finding minimal number of periodic points for smooth self-maps of simply connected manifolds
PublicationLet M be a closed smooth connected and simply connected manifold of dimension m at least 3, and let r be a fixed natural number. The topological invariant D^m_r [f], defined by the authors in [Forum Math. 21 (2009), 491-509], is equal to the minimal number of r-periodic points in the smooth homotopy class of f, a given self-map of M. In this paper, we present a general combinatorial scheme of computing D^m_r [f] for arbitrary dimension...
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An approach to constructing genuinely entangled subspaces of maximal dimension
PublicationGenuinely entangled subspaces (GESs) are the class of completely entangled subspaces that contain only genuinely multiparty entangled states. They constitute a particularly useful notion in the theory of entanglement but also have found an application, for instance, in quantum error correction and cryptography. In a recent study (Demianowicz and Augusiak in Phys Rev A 98:012313, 2018), we have shown how GESs can be efficiently...
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Desensitization of glucosamine-6-phosphate synthase to inhibition by UDP-GlcNAc
PublicationGlucosamine-6-phosphate (GlcN-6-P) synthase, known also as L-Glutamine: D-fructose-6-phosphate amidotransferase, catalyzes the first committed step in the pathway leading to the ultimate formation of UDP-GlcNAc. The final product of this pathway is an activated precursor of numerous macromolecules containing amino sugars, including chitin and mannproteins in fungi, peptidoglycan and lipopolysaccharides in bacteria, and glycoproteins...
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Carbon dioxide sequestration by industrial wastes through mineral carbonation: Current status and perspectives
PublicationMineral carbonation using natural minerals or industrial wastes is a safe and promising strategy for CO2 sequestration. Application of industrial wastes for this purpose has significant ecological and environmental value, which is one of the key green technologies in the global carbon mitigation. This review summarizes the current research status of CO2 mineralization by industrial wastes. This work surveys the mechanisms and capacities...
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Cathodic Activation of Titania-Fly Ash Cenospheres for Efficient Electrochemical Hydrogen Production: A Proposed Solution to Treat Fly Ash Waste
PublicationFly ash (FA) is a waste product generated in huge amounts by coal-fired electric and steam-generating plants. As a result, the use of FA alone or in conjunction with other materials is an intriguing study topic worth exploring. Herein, we used FA waste in conjunction with titanium oxide (TiO2) to create (FA-TiO2) nanocomposites. For the first time, a cathodic polarization pre-treatment regime was applied to such nanocomposites...
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Determination of API content in a pilot-scale blending by near-infrared spectroscopy as a first step method to process line implementation
PublicationNear infrared (NIR) spectroscopy was used for estimation of powder blend homogeneity and manufacturing control of a medicinal product powder mixture containing active pharmaceutical ingredient (API). Aiming at initiating a Process Analytical Technology (PAT) activity, the first step was a stationary mode atline evaluation. In this, the content of pharmaceutical active compound in the powder mixtures intended to the direct tabletting...
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Use of the AHP Method for Preference Determination in Yacht Design
PublicationA sailing yacht is a human-centred product, the design of which revolves primarily around the wants and desires of the future owner. In most cases, these preferences are not measurable, such as a personal aesthetic feeling, or a need for comfort, speed, safety etc. The aims of this paper are to demonstrate that these preferences can be classified and represented numerically, and to show that they are correlated with the type...
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Effect of some organic solvent - water mixtures composion on precipitated calcium carbonate in carbonation process
PublicationPrecipitated calcium carbonate particles were obtained during carbonation of calcium hydroxide slurry with carbon dioxide. Aqueous solutions of isopropyl alcohol, n-butanol and glycerol were used as solvents. Concentration of organic additives in the reactive mixture was from 0 to 20 % (vol.). Precipitation process were performed in a stirred tank reactor equipped with gas distributor. Multimodal courses of particles size distribution...
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The instantaneous frequency rate spectogram
PublicationAn accelerogram of the instantaneous phase of signal components referred to as an instantaneous frequency rate spectrogram (IFRS) is presented as a joint time-frequency distribution. The distribution is directly obtained by processing the short-time Fourier transform (STFT) locally. A novel approach to amplitude demodulation based upon the reassignment method is introduced as a useful by-product. Additionally, an estimator of energy...
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Export diversification and economic development: a dynamic spatial data analysis
PublicationThis paper contributes to the empirical literature on the relationship between ‘export variety’ (export diversification) and economic development by relaxing the assumption of cross-country independence and allowing for spatial diffusion of shocks in observed and unobserved factors. Export variety is measured for a balanced panel of 114 countries (1992-2012) using very detailed information on their exports (HS 6-digit product...
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Efficient Selenenylation of Malonates Using Bis(phosphorothioyl) Diselenide
PublicationBis(O,O-diisopropoxyphosphinothioyl) diselenide reacts readily and quickly with the sodium salt of malonates to give quantitatively stable sodium 2-(O,O-diisopropyl phosphorothioselenenyl)propanedioates. No traces of the corresponding C,C-diselenenylation products were detected. A standard aqueous workup procedure affords the products, albeit in poor yield (about 45%). It was proved that the reaction is reversible due to the presence...
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Koncepcja, modelowanie i symulacja układu napędowego prototypu samochodu elektrycznego "ELV001"
PublicationAbstract: In this paper a conception, modelling and simulation tool for drive system of the prototype electric vehicle ''ELV001'' have been presented. The design and building of this vehicle have been carried out in frame of the project: ''Building a market of electric vehicle and charging infrastructure - fundamentals of energy safety''. The simulation tools are of great assistance to engineers and researchers to reduce product-development...
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Quality of bottled waters
PublicationBottled water is a product that is purchased by annually increasing numbers of people of all age groups. The quality control of mineral waters tends to concentrate on the determination of anion and cation levels, since it is these that govern the taste, smell and possible medicinal properties of the water. The constantly rising sales of mineral waters bring with them the ever increasing exploitation of their sources. The consequences...
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Principles of smoking
PublicationTreatment of a large variety of foods with wood smoke has been practiced for centuries—predominantlymeats, poultry, and fish, but also scallops, cheeses, prunes, paprika, and themalt used to produce whiskey and some sorts of beer.The process usually includes salting and partial drying; it may also be coupled with heating. The aim is to increase the shelf life of the products, prevent food poisoning, and add a desirable smoky flavor....
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E-experiments in physics. Proper business process management, collaborative development process and project management guidance – remedy for avoiding the main IT project’s failure
PublicationOnly a few of learning aids and simulations of physical phenomena allow for building interactive experiments; experiments similar to those that should be conducted in physics laboratories at schools. Group of staff from Gdansk University of Technology decided to fill this market niche by designing and constructing a set of virtual experiments – so called e-experiments. To avoid common problems that a lot of IT products brought...
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Surface texture of pine wood beams after planing in industrial conditions
PublicationMeasuring the surface features of wooden components after planing is connected with the rising demands regarding to the quality of the painted window frames. In the paper the complex surface texture analysis especially identifying of surface damages using non-contact 3D measurement techniques for precise area measurement were presented.This enabled the study of irregular surface features with sufficient fidelity and resolution....
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MARKETING STRATEGY - SPACE AS A PRODUCT.ARCHITECTURE AS A MARKETING DEVICE.
PublicationSpace has its measurable financial value. From the economic point of view place can be treated as a product that fights for appearing in tourists' and investors' consciousnesses. Space - treated as the object of demand and supply - becomes an element in a marketing game. To reach its maximal value the given space should be competitive to other spaces, from which it wants to stand out. However, in the field of architecture - and...
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Weakly convex and convex domination numbers of some products of graphs
PublicationIf $G=(V,E)$ is a simple connected graph and $a,b\in V$, then a shortest $(a-b)$ path is called a $(u-v)$-{\it geodesic}. A set $X\subseteq V$ is called {\it weakly convex} in $G$ if for every two vertices $a,b\in X$ exists $(a-b)$- geodesic whose all vertices belong to $X$. A set $X$ is {\it convex} in $G$ if for every $a,b\in X$ all vertices from every $(a-b)$-geodesic belong to $X$. The {\it weakly convex domination number}...
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Catena-Poly[{[mu]-[eta]5:[eta]5-1-[2-(dimethylamino)ethyl-[kappa]N]cyclopentadienyl}-lithium(I)-([mu]-1,1,3,3-tetra-tert-butyltriphosphane-[kappa]3P2:P1,P3)lithium(I)]
PublicationThe title compound, [Li2(C9H14N)(C16H36P3)]n, is a by-product of the reaction of [Cp(C5H4CH2CH2NMe2)ZrCl2]n with tBu2P-P(SiMe3)Li in toluene. It is a coordination polymer composed of infinite chains running along [010]. One Li(I) atom is chelated by the cyclopentadienyl ring and and the N atom of the scorpionate ligand and a P atom, whereas the other Li(I) atom is coordinated by the backside of the cyclopentadienyl ring and two...
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Self-Organization in Multi-Agent Systems Based on Examples of Modeling Economic Relationships between Agents
PublicationThe goal of the research was to observe and analyze self-organization patterns in Multi-Agent Systems (MAS) by modeling basic economic relationships between agents forming a closed loop of relations necessary for their survival. The paper describes a worked-out MAS including an example of a production cycle and used economic rules. A special focus is put on behavior rules and decision systems of an individual agent such as: product...
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WHAT DRIVES CROSS-COUNTRY DIFFERENCES IN EXPORT VARIETY? A BILATERAL PANEL APPROACH
PublicationA worldwide event like the 2020 Coronavirus outbreak can only reinforce the interest in modelling trade diversification as a key factor in countries’ vulnerability to external shocks. This paper adopts a detailed relative framework to study the determinants of product-level export variety in a large bilateral panel of developing and developed economies (16,770 country pairs in the period 1988–2014). We find that country pairs characterized...
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Bis-phosphonated carbon nanotubes: one pot synthesis and their application as efficient adsorbent of mercury
PublicationEffective, one-pot method of CNTs phosphonylation is presented. Cheap and readily available reagents are used, so the process can be easily transferred to large-scale production. The product was analyzed using spectroscopic methods (FTIR, UV-vis, XPS). Thermal properties of the bis-phosphonated nanotubes are reported for the first time. Newly obtained material was tested as an adsorbent for mercury removal from water. The sorption...
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Smart Innovation Engineering: Toward Intelligent Industries of the Future
PublicationKnowledge-based Engineering Systems are founded upon integration of knowledge into computer systems and are one of the core requirements for the future Industry 4.0. This paper presents a system called Smart Innovation Engineering (SIE) capable of facilitating product innovation process semi-automatically. It enhances decision-making processes by using the explicit knowledge of formal decision events. The SIE system carries the...
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Detection of petroleum products using optical coherence tomography
PublicationIn this work, we present a novel method developed for the analysis of the properties of thin layers for detecting petroleum products on a water surface using a commercially available optical coherence tomography (OCT) system. The spectral density analysis of the signal from a spectroscopic OCT (S-OCT) enables us to perform the precision calculation of the thin layer thickness and other properties like homogeneity, and dispersion,...
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Using Eye-tracking to get information on the skills acquisition by the radiology residents
PublicationThis paper describes the possibility of monitoring the progress of knowledge and skills acquisition by the students of radiology. It is achieved by an analysis of a visual attention distribution patterns during image-based tasks solving. The concept is to use the eye-tracking data to recognize the way how the radiographic images are read by recognized experts, radiography residents involved in the training program, and untrained...
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Use of the AHP Method for Preference Determination in Yacht Design
PublicationA sailing yacht is a human-centred product, the design of which revolves primarily around the wants and desires of the future owner. In most cases, these preferences are not measurable, such as a personal aesthetic feeling, or a need for comfort, speed, safety etc. The aims of this paper are to demonstrate that these preferences can be classified and represented numerically, and to show that they are correlated with the type of...
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Metoda diagnostyki cieplno-przepływowej turbin parowych wykorzystująca elementy algorytmów genetycznych
PublicationRozprawa doktorska poświęcona jest opisowi budowania metody diagnostyki cieplno-przepływowej z wykorzystaniem elementów algorytmów genetycznych. Do tworzenia założeń i algorytmów metody posłużono się przykładem funkcjonowania bloku elektrowni kondensacyjnej ze szczególnym uwzględnieniem układu łopatkowego turbiny parowej. Celem pracy jest zbudowanie metody diagnostyki cieplno-przepływowej. Zadaniem metody jest przeprowadzenie procesu...
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Gasification of Densified Biomass (DB) and Municipal Solid Wastes (MSW) Using HTA/SG Technology
PublicationThe necessity of economical and rational use of natural energy sources caused a rapid development of research on the possibilities of using non‐conventional energy resources. Taking the above into account, a new technological process of thermochemical conversion of biomass and communal waste, commonly known as High Temperature Air/Steam Gasification (HTA/SG) and Multi‐Staged Enthalpy Extraction Technology (HTAG‐MEET), was developed....
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Influence of Self-Similar Traffic Type on Performance of QoS Routing Algorithms
PublicationProviding a Quality of Services (QoS) into current telecommunication networks based on packet technology is a big challenge nowadays. Network operators have to support a number of new services like voice or video which generate new type of traffic. This traffic serviced with QoS in consequence requires access to appropriate network resources. Additionally, new traffic type is mixed with older one, like best-effort. Analysis of...
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Parallel frequency tracking with built-in performance evaluation
PublicationThe problem of estimation of instantaneous frequency of a nonstationary complex sinusoid (cisoid) buried in wideband noise is considered. The proposed approach employs a bank of adaptive notch filters, extended with a nontrivial performance assessment mechanism which automatically chooses the best performing filter in the bank. Additionally, a computationally attractive method of implementing the bank is proposed. The new structure...
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Productivity effects of trade in natural resources—comparison with mechanisms of technological specialisation
PublicationThis paper compares two alternative growth paths, assessing the effects on productivity of specialisation in natural resources (NR) and in technologically advanced products. The empirical analysis exploits product-level export data for 109 developing and 51 developed economies over the period 1996–2018. We document two distinct types of specialisation, based on exports either of natural resources or of technological products, and...
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Bis(ammonium) Zoledronate Dihydrate
PublicationNeutralization of 2-(1-imidazole)-1-hydroxyl-1,1`-ethylidenediphosphonic acid (zoledronic acid) by an excess of ammonia yielded bis(ammonium) zoledronate dihydrate, {C5H8N2O7P2 2−, 2(H4N+), 2(H2O)}. The product is readily soluble in water and forms monocrystals for which the X-ray structural analysis was carried out. The zoledronic anion is of double negative charge due to deprotonation of three P–OH groups and protonation of the...
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Chemical modifications of natural oils and examples of their usage for polyurethane synthesis
PublicationNatural oils have been used in the production of plastics for a long time. However, the number of studies dedicated to polyurethane research has shown an increase only recently. Usually, petrochemical components are used in polyurethane synthesis. Nowadays, there have been attemptsmade to replace polyols in polyurethanes with the modified oils and other natural raw materials. It is a promising and important scenario because the...
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Structure and thermoelectric properties of Bi–Te alloys obtained by novel method of oxide substrates reduction
PublicationA novel method of thermoelectric materials fabrication has been developed. Oxide reagents have been melted at high temperature in air, quenched, milled to powder and reduced in hydrogen to form Bi–Te alloys. Structural and thermoelectric properties of samples have been investigated depending on initial composition and temperature of reduction process. Sample 25Bi2O3–75TeO2 reduced at 340 °C for 10 h has been found to be a p-type...
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Dissociative multi-photon ionization of isolated uracil and uracil-adenine complexes
PublicationRecent multi-photon ionization (MPI) experiments on uracil revealed a fragment ion at m/z 84 that was proposed as a potential marker for ring opening in the electronically excited neutral molecule. The present MPI measurements on deuterated uracil identify the fragment as C3H4N2O+ (uracil+ less CO), a plausible dissociative ionization product from the theoretically predicted open-ring isomer. Equivalent measurements on thymine...
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Comparison of bacterial production in the water column between two Arctic fjords, Hornsund and Kongsfjorden (West Spitsbergen)
PublicationBacterial production and the accompanying environmental factors were measured in the water columns of two Arctic fjords during the cruise in July and August 2013. Water samples were collected at six stations located in the central part of Hornsund and Kongsfjorden. In Hornsund, where average water temperatures were 1.25-fold lower than in Kongsfjorden, the bacterial production was twice as high (0.116 ± 0.102 vs 0.05 ± 0.03 mg...
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Analytical solution of non-stationary heat conduction problem for two sliding layers with time-dependent friction conditions
PublicationIn this article we conduct an overview of various types of thermal contact conditions at the sliding interface. We formulate a problem of non-stationary heat conduction in two sliding layers with generalized thermal contact conditions allowing for dependence of the heat-generation coefficient and contact heat transfer coefficient on time. We then derive an analytical solution of the problem by constructing a special coordinate...
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Relative Productivity, Country Size and Export Diversification
PublicationThis paper analyses the effects of productivity and country size on the extent of trade structure diversification. Using a testable version of the Ricardian model, we show that relative export variety is an outcome of two forces: a relative productivity change (technological progress) and a relative country size change (labour force growth). The model predictions are validated empirically using product-level trade data for a sample...
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The Effect of Polyurethane Glycolysate on the Structure and Properties of Natural Rubber/Carbon Black Composites
PublicationIn this work the use of polyurethane chemical recycling product (i.e. glycolysis of polyurethane waste realized with the mass excess of polymer) as a plasticizer for natural rubber-based composites was proposed. The effect of plasticizer type (napthenic oil and polyurethane foam glycolysate) and amount (2, 4, 6 or 8 parts per 100 parts of natural rubber) on the processing properties of rubber mixtures and chemical structure, swelling,...
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Protein overproduction alters exosome secretion in Chinese hamster ovary cells
PublicationDespite the abundance of available cell lines, nearly 70% of all recombinant therapeutic proteins today are produced in Chi-nese hamster ovary (CHO) cells. The impact of protein overproduction on the secretion of exosomes by CHO cells has been investigated here. Increased secretion of extracellular vesicles (EVs) by protein overexpressing CHO cells was demonstrated with protein content assay, nanoparticle tracking analysis, and...
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ANALYSIS OF CLIMATIC ZONES IN POLAND WITH REGARD TO ASPHALT PERFORMANCE GRADING
PublicationTowards the end of the last century a new system of bitumen grading was developed and implemented as part of the American Strategic Highway Research Program (SHRP). Its aim was to better adjust the testing methods and requirements for road bitumens to the actual conditions in which those bitumens serve in road pavements. Currently in Poland, similarly as in the other EU countries, road bitumens are tested and classified with regard...
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Performance of LSP preemption methods in different MPLS networks
PublicationPreemption in Multiprotocol Label Switching (MPLS) is an optional traffic engineering technique used to create a new path of high priority when there is not enough bandwidth available. In such case the path is admitted by removing one or more previously allocated paths of lower priority. As there are usually many possible sets of low priority paths which can be selected, a preemption algorithm is being started to select the best...