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Phosphinoborenium cations stabilized by N-heterocyclic carbenes: synthesis, structure, and reactivity
PublicationPhosphinoborenium cations stabilized by N-heterocyclic carbenes (NHCs) were synthesized via the reaction of bromo(phosphino)boranes with NHCs. Their structures were investigated by heteronuclear magnetic resonance spectroscopy, X-ray diffraction, and density functional theory calculations. They possess a planar trigonal boron center directly bonded with the pyramidal phosphanyl group (PR2) and can be treated as cationic phosphinoboranes....
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Superconductivity and ferromagnetism in Pd doped Y9Co7
PublicationThe ferromagnetic superconductor Y9Co7 was chemically doped to yield the solid solution Y9Co7-xPdx for 0 < x < 0.4. The lattice parameter a does not depend on x, whereas c increases with increasing Pd content up to x ¼ 0.2, the palladium solubility limit. The transition from ferromagnetism (TC ¼ 4.25 K) to superconductivity (Tsc ¼ 2.4 K) was observed only for the parent Y9Co7 compound. For the lowest tested Pd doping level (x ¼...
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Dehydrogenation in electron-induced dissociative ionization of pyridine molecule
PublicationThe electron-impact dissociative ionization of pyridine has been investigated using mass spectrometry. Thirty-two well-resolved mass peaks have been identified in the cation mass spectra and assigned to the most likely ionic molecular fragments. The new sixteen ionic fragments' appearance energies have been determined, and sixteen others remeasured. The total cross-section for electron-impact ionization of pyridine has been measured...
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Sustainable energy consumption – Empirical evidence of a household in Poland
PublicationThere is an expected increase in the demand for electricity from households in European countries. The outcome of the growing proportion of renewable energy sources in the energy supply mix should result in improved customer awareness regarding their electricity usage. Additionally, they must assume a more proactive role in overseeing their electricity usage. Innovation and pollution management have become crucial catalysts for...
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Application of Bayesian Networks in risk diagnostics arising from the degree of urban regeneration area degradation
PublicationUrban regeneration as a complex project, generates many extremely specific threats affecting the increase of investment risk. Its unique nature causes that probability parameter, normally applied in the process of risk quantification, is extremely difficult to estimate. Due to lack of historical data urban regeneration related activities are therefore associated with uncertainty. According to the authors, a useful tool for resolving...
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Application of BN in Risk Diagnostics Arising from the Degree of Urban Regeneration Area Degradation
PublicationUrban regeneration as a complex project, generates many extremely specific threats affecting the increase of investment risk. Its unique nature causes that probability parameter, normally applied in the process of risk quantification, is extremely difficult to estimate. Due to lack of historical data urban regeneration related activities are therefore associated with uncertainty. According to the authors, a useful tool for resolving...
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The Influence of the Aircraft Operating Fluids on the Mechanical Parameters of the Airport Surface Concrete
PublicationThe authors of the article assessed the impact of operating fluids used to service aircraft on changing mechanical parameters of cement concrete intended for airport pavement. The research concerned concrete designed with the use of CEM I 42.5N LH NA low-alkali cement, broken granite aggregate, fine washed aggregate, and admixtures. The analysis included the assessment of changes in dierences in endurance parameters over various...
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Engineering method of tire rolling resistance evaluation
PublicationTire rolling resistance is one of the most difficult tire parameters to measure. The reason is that for modern tires the force of rolling resistance corresponds to 0.5–1% of tire load, thus measurements of very small forces must be performed in a heavily loaded system. This constitutes great problems, especially in road conditions. Laboratory measurements are easier to perform, as the environment may be better controlled, but roadwheel...
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Badanie aktywności online polskich konsumentów dotyczącej marek
PublicationRozwój nowych trendów w internecie, a w szczególności Web 2.0, spowodował wzrost społecznego zaangażowania internautów oraz dalszy rozwój kanałów społecznościowych i tym samym różnego typu platform interaktywnych. Internet zachęca internautów do interakcji z witrynami, a za ich pośrednictwem z innymi użytkownikami sieci. Umożliwia im tworzenie treści na temat różne tematy, w tym na przykład związany z markami produktów. Dzięki...
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Krajowa Polityka Miejska jako wyraz miastopoglądu?
PublicationPo dwóch latach pracy w październiku 2015 Krajowa Polityka Miejska została przyjęta przez rząd RP, jako krok w stronę skoordynowania działań, w odpowiedzi na wyzwania stojące przed polskimi miastami. Jest to nowe podejście, choć Polska nie jest jedynym krajem na świecie stosującym to narzędzie koordynacji zarządzania miastami. W Krajowej Polityce Miejskiej zebrano wyniki ekspertyz rządowych. Jej ustalenia mają kierunkować zarówno...
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Inflation Forecast or Forecast(s) Targeting?
PublicationThe paper refers to L.E.O. Svensson’s concept of inflation forecast targeting (IFT) and its implementation by central banks of Sweden, Norway and the Czech Republic. The study focuses on (1) inflation forecasts published by selected central banks, i.e.headline inflation and core or monetary policy-relevant (MPR) inflation, which are made on the assumption of endogenous instrument rate, (2) one-year consumer...
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Weryfikacja Poziomów Nienaruszalności Bezpieczeństwa z uwzględnieniem Zagadnień Ochrony Informacji
PublicationNiniejszy rozdział poświęcono wybranym istotnym zagadnieniom analizy bezpieczeństwa funkcjonalnego, w szczególności weryfikacji poziomów nienaruszalności bezpieczeństwa SIL funkcji bezpieczeństwa implementowanych w rozproszonych systemach sterowania i zabezpieczeń z uwzględnieniem zagadnień ochrony informacji. Zaproponowano metodę opartą na informacji ilościowej i jakościowej do weryfikacji SIL (IEC 61508, 61511) z uwzględnieniem...
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The process of fuzzy model development for the case of polish internet mortgage market
PublicationThe aim of the paper is to present the conceptual description of fuzzy model representing the Polish Internet mortgage market. The first part of the paper consists of assessment and verification of model variables which are important for the Polish Internet Mortgage Market. This process begins with the initial set of variables which was used previously for the rule based model of the same market. As numerous aspects of the market...
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Endocrine Disrupting Compounds – Problems and Challenges
PublicationIn this chapter, information about some of the estrogenic compounds and their environmental fate and biological influence can be found. Special attention is paid to the review of the analytical approaches used at the stages of detection and determination of Endocrine Disrupting Compounds (EDCs) in the environmental samples. Also, a brief characterization of both cellular and non-cellular bioassays is presented. The discovery of...
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A design framework and a digital toolset supporting the early-stage explorations of responsive kinetic building skin concepts
PublicationIn this paper we present the first phase of our research on the development of a framework for early-stage responsive kinetic building skin design. The aims of this study were: to formulate a methodological and instrumental basis for the construction of the framework, to conduct an initial pre-assessment of its features, and finally to provide the first example of how the framework could be applied in practice. Importantly, at...
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New concept of drilling auger for displacement pile installation
PublicationIn 2020, a new version of the screw displacement auger for pile installation in soil was developed and patented in Poland. It was named DPDT (Displacement Pile Drilling Tool). The general aim of its development was to reduce the soil resistances to the auger during screwing into the ground while maintaning a good load-bearing capacity for the screw displacement piles. The “DPDT-Auger” prototype was tested as a scaled-down model...
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Real-time simulator of agricultural biogas plant
PublicationThis article presents a real-time simulator of an agricultural biogas plant. The project contains biogas and biomass circuits simulation, as well as heating circuit simulation with a complete control system and visualization interface of the whole process. The software tool used to simulate the plant work is CFD (Computational Fluid Dynamics), which enables a user to create and test simulation objects based on fundamental physical...
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Search engine marketing jako istotne narzędzie komunikacji marketingowej
PublicationKomunikacja marketingowa firmy w Internecie musi uwzględniać tzw. marketing w wyszukiwarkach internetowych (SEM). O efektywnej obecności przedsiębiorstwa w Sieci można mówić, gdy łatwo znaleźć serwis internetowy uwzględniając organiczne wyniki wyszukiwania wyszukiwarek, reklamy typu pay-per-click, optymalizację kluczowych fraz, istotność linków przychodzących (zewnętrznych) oraz wartość zamieszczonych treści. Każdy element projektu...
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On EM-driven size reduction of antenna structures with explicit constraint handling
PublicationSimulation-driven miniaturization of antenna components is a challenging task mainly due to the presence of expensive constraints, evaluation of which involves full-wave electromagnetic (EM) analysis. The recommended approach is implicit constraint handling using penalty functions, which, however, requires a meticulous selection of penalty coefficients, instrumental in ensuring optimization process reliability. This paper proposes...
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Effects of Column Base Flexibility on Seismic Response of Steel Moment-Frame Buildings
PublicationSteel Moment Resisting Frames (SMRFs) are very popular lateral load resisting systems in many seismically active regions. However, their seismic response is strongly dependent on the rotational fixity of column base connections. Despite many studies (both experimental and numerical) in this particular area, available approaches for estimating column base flexibility have been validated only against laboratory test data. In the...
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Developing Prognostic Models of Organization Evolution
PublicationThe work focuses on the problem of measuring evolution of IT organizations. Changes in business influence functioning of the IT organization. IT departments or companies must ensure that the needs of their parent company/customers will be met. Therefore they must constantly evolve. Following question can be raised: is it possible to support process of changes the IT organization to run it smoother, faster, easier but with reduced...
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Exploring the Reactivity of Unsymmetrical Diphosphanes toward Heterocumulenes: Access to Phosphanyl and Phosphoryl Derivatives of Amides, Imines, and Iminoamides
PublicationWe present a comprehensive study on the diphosphanation of iso(thio)cyanates by unsymmetrical diphosphanes. The reactions involving unsymmetrical diphosphanes and phenyl isocyanate or phenyl thioisocyanate gave rise to phosphanyl, phosphoryl, and thiophosphoryl derivatives of amides, imines, and iminoamides. The structures of the diphosphanation products were confirmed through NMR spectroscopy, IR spectroscopy, and single-crystal...
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High-quality Experiment Dedicated to microGravity Exploration, Heat Flow and Oscillation Measurement from Gdańsk
PublicationIn this paper we propose HEDGEHOG (High-quality Experiment Dedicated to microGravity Exploration, Heat flow and Oscillation measurement from Gdańsk) REXUS experiment to investigate vibrational and heat flow phenomena during the whole (ascent, microgravity phase, descent and recovery) flight of a sounding rocket. First, a proposed system of cantilever beams is discussed to study dynamic behaviour of dummy payload. Dimensioning has...
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Oceny środowiskowe a rozwój zrównoważony miast
PublicationArtykuł prezentuje możliwości wzmocnienia procedury oceny oddziaływania na środowisko (OOŚ), jako narzędzia mogącego służyć odnowie struktur miejskich. Instrumenty wykorzystywane w Polsce do realizacji idei rozwoju zrównoważonego uznano za nieskuteczne, co stało się punktem wyjścia do poszukiwania możliwości ich poprawy. Szczególny nacisk położono na wykorzystanie potencjału procedury OOŚ, mającej wspierać planowanie przestrzenne....
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Determinanty wartości przedsiębiorstw w wybranych sektorach gospodarki w Polsce
PublicationPrzedmiotem rozważań jest przedstawienie wpływu m.in. takich czynników jak kapitał obcy, ryzyko, wyniki działalności operacyjnej oraz oczekiwana stopa zwrotu na wartość przedsiębiorstwa i na wartość dla jego właścicieli, ze szczególnym uwzględnieniem kapitału obcego w postaci obligacji korporacyjnych, który stał się w prowadzonych badaniach determinantą przewodnią. Badaniem objęto 184 przedsiębiorstwa, które podzielono na cztery...
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Flavones in cocoa defence against Phytophthora megakarya
PublicationCross-pollination of suitable genotypes and earlier selection of elite offspring using adequate plants-associated defence markers in plantlets leaves are decisive for development of T. cacao genotypes tolerant to black pods disease (BPD). T. cacao plantlets from manual cross-pollination of ♀SNK64 × ♂UPA143 were analyzed for their susceptibility to BPD using leaf disc test. Subsequently, leaves (healthy, wounded and wound+infected)...
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Linezolid-resistant Enterococcus faecium strains isolated from one hospital in Poland –commensals or hospital-adapted pathogens?
PublicationOne of the most pressing problems of enterococci infections is occurring resistance to linezolid, which is an antibiotic used in the treatment of infections caused by vancomycin-resistant strains (VRE). The main objective of our research was to investigate the relationship of 19 linezolid-resistant E. faecium isolates from 18 patients hospitalized at Clinical Hospital in Gdansk (Poland). One of the LZDREF was isolated in 2003...
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Analysis of metals in air particles from Gdańsk and London with EDX/EDS detectors in electron microscope
PublicationElectron microscopy with energy dispersive X-ray spectrometry (EDX/EDS) is the example of non-destructive analytical method for surface elemental analysis, with a potential detection limit of 0.1-0.5 wt.% for most elements. A spatial resolution <10 nm can be achieved using this technique, which provides a basis for the generation of quantitative and qualitative elemental data for individual particles. In order to obtain quantitative...
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New Complementary Resonator for Permittivity- and Thickness-Based Dielectric Characterization
PublicationThe design of high-performance complementary meta-resonators for microwave sensors featur-ing high sensitivity and consistent evaluation of dielectric materials is challenging. This paper presents the design and implementation of a novel complementary resonator with high sensi-tivity for dielectric substrate characterization based on permittivity and thickness. A comple-mentary crossed arrow resonator (CCAR) is proposed and integrated...
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Green chromatography
PublicationAnalysis of organic compounds in samples characterized by different composition of the matrix is very important in many areas. A vast majority of organic compound determinations are performed using gas or liquid chromatographic methods. It is thus very important that these methods have negligible environmental impact. Chromatographic techniques have the potential to be greener at all steps of the analysis, from sample collection...
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Using On-line Measurement by Electronic Nose and Computer Simulations for Real-time Control at WWTP
PublicationContinuous investigation of wastewater quality can be carried out by a device called an e-nose. One important feature of the proposed real-time control system for WWTP is that using on-line measurements by e-nose together (Figure 1) with technological sets picked on this basis by means of computer models, it is possible to change treatment process parameters, depending on the current quality of wastewater. It can be used for the...
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Mobile Security: Threats and Best Practices
PublicationCommunicating mobile security threats and best practices has become a central objective due to the ongoing discovery of new vulnerabilities of mobile devices. To cope with this overarching issue, the goal of this paper is to identify and analyze existing threats and best practices in the domain of mobile security. To this extent, we conducted a literature review based on a set of keywords. The obtained results concern recognizable...
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The work-family interface: Job demands, work engagement and turnover intentions of Polish nurses
PublicationA conflict between one's professional life and one's family life may lead to lower well-being both at work and home. Most nurses are women who have traditionally reconciled their professional life with family life. One aim of this study was to examine the relationships between the work-family conflict (WFC),the family-work conflict (FWC), and the perception of job demands (quantitative workload and interpersonal conflicts at work)....
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QUANTITATIVE EASING POLICY AND ITS IMPACT ON THE GLOBAL ECONOMY
PublicationBased on the analysis of the impact of quantitative easing policies on the global economy, there was concluded that the world’s largest central banks and widespread debt stimulation have created the model of economic growth. This model was based on the productivity growth. The lack of productivity growth in the developed world, the active integration of developing countries (first of all China and India) in the global economy have...
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New oryginal generic technologies: A Polish R&D strategic implementation programme
PublicationPolands's pharmaceutical industry is of great significance to the whole economy. According to Forbs (2 October 2012), the cost of launching a new drug varies from USD 1 to 11 bilion. There is little Chance of a Polish pharmaceutical company developing an original drug due to financial reason.Many research teams in Poland take up research projects aimed at new biologically active compounds. But such an objective has no broader perspective,...
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Pyrolysis Process of Whole Waste Tires as a Biomass Energy Recycling
PublicationThe article is devoted to the description of material recycling of whole waste tires, including a new method of pyrolysis process, resulting in the final products: technically oil fractions (rubber plasticizer of rubber compounds) or diesel fuels (light, medium and heavy), activated carbon, gas fuel and steel scrap. Operational and performance tests of the first version of the pilot plant, consisting of three contributions cooperating...
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Hydrogen effects in duplex stainless steel welded joints - electrochemical studies
PublicationIn this work results on the influence of hydrogen on passivity and corrosion resistance of 2205 duplex stainless steel (DSS) welded joints are described. The results were discussed by taking into account three different areas on the welded joint: weld metal (WM), heat-affected zone (HAZ) and parent metal. The corrosion resistance was qualified with the polarization curves registered in a synthetic sea water. The conclusion is that,...
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Stabilization of the pyrochlore phase of Mn2Sb2O7 by double substitution
PublicationPolycrystalline samples of (Ce4+Mn2+3)(Ga3+Sb5+3)O14 were synthesized by a high-temperature solid-state reaction. In contrast with the parent Mn2Sb2O7 compound that adopts a rhombohedral or monoclinic structure at T > 600 °C, the pyrochlore structure of CeMn3GaSb3O14 is retained up to at least T = 1070°C. High-resolution synchrotron x-ray diffraction measurements show no sign of a superstructure or distortion from cubic symmetry...
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Music information analysis and retrieval - a review
PublicationW referacie przedstawiono wybrane zagadnienia związane z analizą i wyszukiwaniem informacji muzycznej. Przegląd ten został oparty na literaturze związanej z dziedziną informatyki muzycznej i koncentruje się wokół problemu parametryzacji dźwięków muzycznych i sygnałów fonicznych oraz analizie przydatności wybranych metod tzw. sztucznej inteligencji (ang. computational intelligence) do akwizycji i rozpoznawania obiektów muzycznych...
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Deep-Learning-Based Precise Characterization of Microwave Transistors Using Fully-Automated Regression Surrogates
PublicationAccurate models of scattering and noise parameters of transistors are instrumental in facilitating design procedures of microwave devices such as low-noise amplifiers. Yet, data-driven modeling of transistors is a challenging endeavor due to complex relationships between transistor characteristics and its designable parameters, biasing conditions, and frequency. Artificial neural network (ANN)-based methods, including deep learning...
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Respiratory system modelling and simulation basing on the forced oscilation technique
PublicationConventional methods of testing lung functioning demand a specific respiratory action of the patient. In contrast, the forced oscillation technique (fot) provides measurements obtained with a minimal cooperation of the subject. The aim of this study is to verify the usefulness of the forced oscillation technique modelling in respiratory system diagnosing. in order to do it two models of fot measurements have been considered: the...
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Fracture susceptibility of high RAP content asphalt concrete in terms of aging
PublicationDue to the reduction of CO2 emissions during the production of asphalt mixtures and the decrease in the demand for mineral resources, the addition of reclaimed asphalt pavement (RAP) is becoming indispensable. The durability of asphalt pavements containing a high RAP content may be reduced due to a decrease in the cracking resistance of the material, especially under the influence of operational aging. The article presents the...
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Deep Features Class Activation Map for Thermal Face Detection and Tracking
PublicationRecently, capabilities of many computer vision tasks have significantly improved due to advances in Convolutional Neural Networks. In our research, we demonstrate that it can be also used for face detection from low resolution thermal images, acquired with a portable camera. The physical size of the camera used in our research allows for embedding it in a wearable device or indoor remote monitoring solution for elderly and disabled...
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Tyre rolling resistance and its influence on fuel consumption
PublicationRolling resistance of tyres is one of the major resistive forces acting on any wheeled vehicle. Unfortunately, it is also one of the forces very difficult to measure. It is estimated that in certain traffic conditions (like for example constant speed driving with slow or moderate speed) so called Rolling Resistance Impact Factor may be as high as 0.3. This means that reduction of rolling resistance by 50% would lead to 15% of energy...
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ReFlexeNN - the Wearable EMG Interface with Neural Network Based Gesture Classification
PublicationThe electromyographic activity of muscles was measured using a wireless biofeedback device. The aim of the study was to examine the possibility of creating an automatic muscle tension classifier. Several measurement series were conducted and the participant performed simple physical exercises - forcing the muscle to increase its activity accordingly to the selected scale. A small wireless device was attached to the electrodes placed...
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Light-Modulated Sunscreen Mechanism in the Retina of the Human Eye
PublicationThe functioning of the human eye in the extreme range of light intensity requires a combination of the high sensitivity of photoreceptors with their photostability. Here, we identify a regulatory mechanism based on dynamic modulation of light absorption by xanthophylls in the retina, realized by reorientation of pigment molecules induced by trans–cis photoisomerization. We explore this photochemically switchable system using chromatographic...
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COVID-19 severity forecast based on machine learning and complete blood count data
PublicationProper triage of COVID-19 patients is a key factor in eective case management, especially with limited and insucient resources. In this paper, we propose a machine-aided diagnostic system to predict how badly a patient with COVID-19 will develop disease. The prognosis of this type is based on the parameters of commonly used complete blood count tests, which makes it possible to obtain data from a wide range of patients.We chose...
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COVID-19 severity forecast based on machine learning and complete blood count data
PublicationProper triage of COVID-19 patients is a key factor in eective case management, especially with limited and insucient resources. In this paper, we propose a machine-aided diagnostic system to predict how badly a patient with COVID-19 will develop disease. The prognosis of this type is based on the parameters of commonly used complete blood count tests, which makes it possible to obtain data from a wide range of patients.We chose...
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Tire/Road Noise On Poroelastic Road Surfaces - Results Of Laboratory Measurements
PublicationTire/road noise is the most important part of traffic noise for medium and high speed driving both in the case of passenger cars and trucks. The potential to make modification of tires that significantly reduce tire/road noise in nearly over, at least for conventional tires so the only promising action is to improve road pavements. One of the innovative solutions is poroelastic road pavement (PERS) that reduces airflow related...
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The application of the Superpave method of climatic zones analysis in Poland with regard to bitumen performance grading
PublicationCurrently in Poland, similarly as in the other EU countries, road bitumens are tested and classified with regard to mainly the penetration value determined at the tempera-ture of 25C. It should be noted that this classification is not correlated with the cli-matic conditions in which the bitumens are to serve in the road pavement. Towards the end of the last century a new system of bitumen grading was developed and im-plemented...