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ANTIOXIDANT POWER SERIES (APS) AS A TOOL FOR RATIONAL DESIGN AND ASSESSMENT OF HEALTH PROMOTING PROPERTIES OF FUNCTONAL FOODS BASED ON ANTIOXIDANT PHYTOCHEMICALS
PublicationOver past decades, plantborne antioxidants dominated so called "translational research" in the area of food, nutrition, and disease prevention. Among consumers and producers, such phytochemicals are synonyms of nutriceuticals. Popularity and commercial success of antioxidants stems from mechanistic studies suggesting the involvement of reactive oxygen species in etiology of chronic diseases. However, epidemiology failed to provide...
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GIS-based hydrodynamic modeling for urban flood mitigation in fast-growing regions: a case study of Erbil, Kurdistan Region of Iraq
PublicationFloods threaten urban infrastructure, especially in residential neighborhoods and fast-growing regions. Flood hydrodynamic modeling helps identify flood-prone locations and improve mitigation plans' resilience. Urban floods pose special issues due to changing land cover and a lack of raw data. Using a GIS-based modeling interface, input files for the hydrodynamic model were developed. The physical basin's properties were identified...
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Diagnostic Analysis of Exhaust Gas with A Quick-Changing Temperature from a Marine Diesel Engine Part II / Two Factor Analysis
PublicationThe article presents a continuation of research carried out to determine the effect of input parameters (changes in engine structure parameters) on selected output parameters (diagnostic measures), based on quickly changing exhaust gas temperature. A method of determining the simultaneous influence of two input factors (the structure parameter and the engine load) on one output factor was presented, as well as an evaluation...
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Computational analysis of substituent effects on proton affinity and gas-phase basicity of TEMPO derivatives and their hydrogen bonding interactions with water molecules
PublicationThe study investigates the molecular structure of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and its derivatives in the gas phase using B3LYP and M06-2X functional methods. Intermolecular interactions are analyzed using natural bond orbital (NBO) and atoms in molecules (AIM) techniques. NO2-substituted TEMPO displays high reactivity, less stability, and softer properties. The study reveals that the stability of TEMPO derivatives...
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The effect of aeration mode (intermittent vs. continuous) on nutrient removal and greenhouse gas emissions in the wastewater treatment plant of Corleone (Italy)
PublicationThe paper reports the results of an experimental study aimed at comparing two configurations of a full-scale wastewater treatment plant (WWTP): conventional activated sludge (CAS) and oxic-settling-anaerobic process (OSA) with intermittent aeration (IA). A comprehensive monitoring campaign was carried out to assess multiple parameters for comparing the two configurations: carbon and nutrient removal, greenhouse gas emissions, respirometric...
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Rapid and sensitive determination of acrylamide in potato crisps using reversed-phase direct immersion single drop microextraction-gas chromatography
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Development of headspace-gas chromatography-flame ionization detection procedure to determine volatile fatty acids in zoo organic waste leachate
PublicationNadrzędnym celem pracy było opracowanie metodyki oznaczania lotnych kwasów tłuszczowych z fazy nadpowierzchniowej opartej na chromatografii gazowej z detektorem płomieniowo-jonizacyjnym oraz sprawdzenie jej przydatności w analizie próbek odcieku ze składowiska odpadów ogrodu zoologicznego. Na podstawie przeprowadzonych badań określono warunki, w jakich przebiegać powinna izolacja lotnych kwasów tłuszczowych, a także określono najlepsze...
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Process Control and Investigation of Oxidation Kinetics of Postoxidative Effluents Using Gas Chromatography with Pulsed Flame Photometric Detection (GC-PFPD)
PublicationThis article presents the results of investigations on the use of headspace analysis and gas chromatography with pulsed flame photometric detection (HSA-GC-PFPD) to evaluate the effectiveness of oxidation of postoxidative effluents from the production of bitumens. Samples of effluents from the bitumen oxidation unit were used in the experiments. In addition, the kinetics of effluent oxidation was also investigated. The content...
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Technical and economical analysis of combined cycles of gas turbine -steam turbine on pipeline compressor stations. Part II - Economic analysis
PublicationW pracy przedstawiono zagadnienie nadbudowy zespołów turbosprężarkowych, znajdujących się na tłoczni gazu ziemnego, odzyskowymi blokami parowymi. W analizie tego przedsięwzięcia wzięto pod uwagę kilka wariantów konfiguracji układu parowego oraz kilka wariantów uwzględniających zmienność obciążenia turbin gazowych napędzających kompresory. Dla układu parowego dobrano wszystkie podstawowe parametry, a następnie wykonano obliczenia...
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Technical and economical analysis of combined cycles of gas turbine - steam turbine on pipeline compressor stations. Part I - Technical analysis
PublicationW pracy przedstawiono zagadnienie nadbudowy zespołów turbosprężarkowych, znajdujących się na tłoczni gazu ziemnego, odzyskowymi blokami parowymi. W analizie tego przedsięwzięcia wzięto pod uwagę kilka wariantów konfiguracji układu parowego oraz kilka wariantów uwzględniających zmienność obciążenia turbin gazowych napędzających kompresory. Dla układu parowego dobrano wszystkie podstawowe parametry, a następnie wykonano obliczenia...
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Technical and economical analysis of combined cycles of gas turbine - steam turbine on pipeline compressor stations. Part II - Economic analysis
PublicationW pracy przedstawiono zagadnienie nadbudowy zespołów turbosprężarkowych, znajdujących się na tłoczni gazu ziemnego, odzyskowymi blokami parowymi. W analizie tego przedsięwzięcia wzięto pod uwagę kilka wariantów konfiguracji układu parowego oraz kilka wariantów uwzględniających zmienność obciążenia turbin gazowych napędzających kompresory. Dla układu parowego dobrano wszystkie podstawowe parametry, a następnie wykonano obliczenia...
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Determination of PCBs in marine sediment using pressurised liquid extraction-gas chromatography-isotope dilution mass spectrometry -method validation
PublicationOpracowano procedurę oznaczania wybranych analitów z grupy PCB w próbkach osadu dennego z wykorzystaniem techniki przyspieszonej ekstrakcji za pomocą rozpuszczalnika (PLE) w połączeniu z chromatografią gazową z detektorem spektrometrii mas. Opracowana procedura analityczna została wykorzystana do analizy próbek morskiego osadu dennego, które stanowiły przedmiot badań międzylaboratoryjnych organizowanych przez Comité Consultatif...
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Scenarios as a tool supporting decisions in urban energy policy: The analysis using fuzzy logic, multi-criteria analysis and GIS tools
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Experimental Investigation Of Using Latent Thermal Energy Storage System Comprising Of Magnesium Chloride Hexahydrate (MgCl2.6H2O) With Domestic Gas Heater
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Comprehensive two dimensional gas chromatography coupled with mass spectrometry as tool for characterization of the main pollutants present in atmospheric air in Gdansk
PublicationNowadays, the technique that is commonly used to identify and quantify the chemical compounds in gas sample is gas chromatography. The separation resolution in gas chromatography can be improved by applying the modulation technique. In this paper present is the most important information regarding the pollutants present in atmospheric air. The areas in which the tests were carried out are one of the largest industrial zones in...
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THE USE OF ULTRAFAST GAS CHROMATOGRAPHY FOR CLASSIFICATION OF PLUM SPIRITS = SPOSÓB WYKORZYSTANIA ULTRASZYBKIEJ CHROMATOGRAFII GAZOWEJ DO KLASYFIKACJI OKOWIT ŚLIWKOWYCH
PublicationStan środowiska ma znaczny wpływ na jakość upraw. W konsekwencji występowanie zanieczyszczeń w powietrzu ma istotny wpływ na jakość żywności. W skutek złego stanu powietrza zewnętrznego i wewnętrznego zmieniają się m.in. walory sensoryczne i zdrowotne niektórych produktów spożywczych. Z tego powodu należy nieustannie monitorować stan środowiska za pomocą m.in. nowoczesnej aparatury analitycznej jakim jest elektroniczny nos. W...
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Artificial neural network model of hardness, porosity and cavitation erosion wear of APS deposited Al2O3 -13 wt% TiO2 coatings
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Ekspertyza naukowo-techniczna dot. parametrów fizycznych, wytrzymałościowych i hydraulicznych geokompozytów MACRIT GTV i geosiatek ARTER GTS
PublicationPrzedmiotem ekspertyzy były badania parametrów fizycznych, wytrzymałościowych i hydraulicznych wskazanych geosyntetyków przepuszczalnych. Określono następujące parametry techniczne: masa powierzchniowa, wytrzymałość na rozciąganie i wydłużenie względne, siła przy przebiciu statycznym (metodą CBR), charakterystyczna wielkość porów, wodoprzepuszczalność (prędkość przepływu wody) w kierunku prostopadłym do płaszczyzny wyrobu.
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Comparing combined gas tubrine/steam turbine and marine low speed piston engine/steam turbine systems in naval applications
PublicationPorównano układy napędowe okrętowe kombinowane turbina gazowa- turbina parowa oraz spalinowy okrętowy silnik tłokowy wolnoobrotowy - turbina parowa. Porównywano moce oraz zużycie paliwa oraz parametry pary świeżej układu turbiny parowej.
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Combined chemoresistive and in situ FTIR spectroscopy study of nanoporous NiO films for light-activated nitrogen dioxide and acetone gas sensing
PublicationThe chemoresistive sensor response of nanoporous NiO films prepared by advanced gas deposition was investigated by combined resistivity and in situ FTIR spectroscopy, with and without simultaneous light illumination, to detect NO2 and acetone gases. The sensitivity towards NO2 increased dramatically under UV irradiation employing 275 nm light. Improved sensitivity was observed at an elevated temperature of 150 °C. In situ FTIR...
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Beyond the helium buffer: 12C−2 rotational cooling in cold traps with H2 as a partner gas: interaction forces and quantum dynamics
Publicationabstract = { The scattering cross-sections and corresponding rate coefficients for rotationally inelastic collisions of $^{12}$C$_2$^-$ ($^2 \Sigma_g^+$) with H$_2$ ($^1 \Sigma_g^+$) are presented over a broad range of cold-trap temperatures. They have been calculated using quantum scattering theory that employs a new ab initio potential energy surface. The rate coefficients for the inelastic processes in the anionic partner are...
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Characterization of diatomaceous earth coated with nitrated asphaltenes as superior adsorbent for removal of VOCs from gas phase in fixed bed column
PublicationAsphaltenes isolated from bitumen possess unusual adsorption characteristics that can be further enhanced by chemical modifications to promote interactions with VOCs’. Herein, nitrated asphaltenes are used as an active layer coated on a surface of a diatomaceous earth, in order to prepare an efficient adsorbent (AsfNitro). Breakthrough experiments with benzene, pyridine, and 1-nitropropane revealed significant increase in adsorption...
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Process control of air stream deodorization from vapors of VOCs using a gas sensor matrix conducted in the biotrickling filter (BTF)
PublicationThis article presents the validity, advisability and purposefulness of using a gas sensor matrix to monitor air deodorization processes carried out in a peat-perlite-polyurethane foam-packed biotrickling filter. The aim of the conducted research was to control the effectiveness of air stream purification from vapors of hydrophobic compounds, i.e., n-hexane and cyclohexane. The effectiveness of hydrophobic n-hexane and cyclohexane...
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First deep eutectic solvent-based (DES) stationary phase for gas chromatography and future perspectives for DES application in separation techniques
PublicationThe paper presents the first application of deep eutectic solvents (DES) as stationary phases for gas chromatography. DES obtained by mixing tetrabutylammonium chloride (TBAC) as a hydrogen bond acceptor (HBA) with heptadecanoic acid being a hydrogen bond donor (HBD) in a mole ratio of HBA:HBD equal to 1:2 was characterized by its ability to separate volatile organic compounds (VOCs). The Rohrschneider – McReynolds constants determined...
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Ekspertyza naukowo-techniczna dot. parametrów fizycznych, wytrzymałościowych i hydraulicznych geokompozytów MACRIT GTV i geosiatek ARTER GTS
PublicationPrzedmiotem ekspertyzy były badania parametrów fizycznych, wytrzymałościowych i hydraulicznych wskazanych geosyntetyków przepuszczalnych. Określono następujące parametry techniczne: masa powierzchniowa, wytrzymałość na rozciąganie i wydłużenie względne, siła przy przebiciu statycznym (metodą CBR), charakterystyczna wielkość porów, wodoprzepuszczalność (prędkość przepływu wody) w kierunku prostopadłym do płaszczyzny wyrobu.
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Ekspertyza naukowo-techniczna dot. parametrów fizycznych, wytrzymałościowych i hydraulicznych geokompozytów MACRIT GTV i geosiatek ARTER GTS
PublicationPrzedmiotem ekspertyzy były badania parametrów fizycznych, wytrzymałościowych i hydraulicznych wskazanych geosyntetyków przepuszczalnych. Określono następujące parametry techniczne: masa powierzchniowa, wytrzymałość na rozciąganie i wydłużenie względne, siła przy przebiciu statycznym (metodą CBR), charakterystyczna wielkość porów, wodoprzepuszczalność (prędkość przepływu wody) w kierunku prostopadłym do płaszczyzny wyrobu.
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A rapid and sensitive method for the quantitative analysis of ibuprofen and its metabolites in equine urine samples by gas chromatography-tandem mass spectrometry
PublicationIbuprofen is widely used in human and veterinary medicine for the treatment of chronic pain as well as rheumatic and musculoskeletal disorders. However, t he anal- gesic and anti-inflammatory properties of Ibuprofen have contributed to frequent drug abuse in equestr ian s ports. A sensitive and rapid gas chromatography with tandem mass spectrometry based method with a simple liquid-liquid extraction and deriva- tization requiring...
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Complementary Use of Multi-dimensional Gas Chromatography and Proton Transfer Reaction Mass Spectrometry for Identification of Rapeseed Oil Quality Indicators
PublicationThe change of concentration of various volatiles generated during frying may be an indicator of oil quality. Chemical compounds such as aldehydes, ketones, alcohols and carboxyl acids are the products of oxidation during thermal degradation of edible oils. Shown in this work is a complementary use of GC×GC-TOFMS and PTR-MS for the detection and determination of quality indicators of rapeseed oil. The former technique was used for...
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Preconditioners with Low Memory Requirements for Higher-Order Finite-Element Method Applied to Solving Maxwell’s Equations on Multicore CPUs and GPUs
PublicationThis paper discusses two fast implementations of the conjugate gradient iterative method using a hierarchical multilevel preconditioner to solve the complex-valued, sparse systems obtained using the higher order finite-element method applied to the solution of the time-harmonic Maxwell equations. In the first implementation, denoted PCG-V, a classical V-cycle is applied and the system of equations on the lowest level is solved...
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Comprehensive determination of flavouring additives and nicotine in e-cigarette refill solutions. Part II: Gas-chromatography–mass spectrometry analysis
PublicationFlavouring compounds are an essential part of e-liquid products for cigarettes. In general, they are regarded as safe for ingestion, but they may have unrecognized risks when they are inhaled. In some cases, manufactures do not currently abide by the Tobacco Products Directive (2014/40/EU) and do not declare the detailed contents of e-liquids on their labels. To help evaluate the health impact of flavouring substances, there is...
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The CFD analysis of influence the start of fuel injection (SOI) on combustion parameters and exhaust gas composition of the marine 4-stroke engine
PublicationThe paper presents a theoretical analysis of the impact of injection timing on the parameters of the combustion process and the composition of exhaust gas from a 4-stroke engine designed to shipbuilding. The analysis was carried out based on a three-dimensional multi-zone model of the combustion process. This model has been prepared on the basis of properties of the research facility. The input data to the model were obtained through...
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A rapid dispersive liquid–liquid microextraction of antimicrobial onion organosulfur compounds in animal feed coupled to gas chromatography-mass spectrometry
PublicationA rapid analytical procedure is proposed for determining two antimicrobial onion organosulfur compounds, propyl disulfide (PDS) and propyl propane thiosulfonate (PTSO), in animal feed. The use of PTSO as a natural ingredient in animal feed is allowed due to its antimicrobial activity against pathogenic organisms. Two analytical methodologies using gas chromatography coupled to mass spectrometry (GC-MS) are compared. After the extraction...
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Burst loss probability for the combination of extended offset time based service differentiation scheme and PPS in optical burst switching network
PublicationIn the paper analytical model for calculating burst loss probabilities for the combination of two service differentiation schemes for OBS network namely: extended offset time based scheme and PPS (Preemption Priority Schemes) is revised. Moreover authors introduce analytical model for calculating burst loss probabilities for an optical path when OBS network employs both service differentiation schemes and JET signaling. The comparison...
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Study of ZrS3-based field-effect transistors toward the understanding of the mechanisms of light-enhanced gas sensing by transition metal trichalcogenides
PublicationExtending knowledge of the properties of low-dimensional van der Waals materials, including their reactivity to the ambiance, is important for developing innovative electronic and optoelectronic devices. Transition metal trichalcogenides with tunable optical band gaps and anisotropic conductivity are an emerging class among low- dimensional structures with the possibility of gate tunability and photoreactivity. These properties...
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Influence of gas turbine controller adjustment on ship propulsion system behaviour in rough sea conditions. Part 2. The simulation investigations.
PublicationPrzedstawiono model dynamiki układu napędowego okrętowego, wykorzystując metodę elementów skończonych. Układ napędowy składa się z dwóch turbin gazowych napędzających poprzez przekładnię mechaniczną zębatą pędnik o nastawnym skoku. W symulacji układu napędowego zadawano wymuszenia wartością zadaną nastaw prędkości na regulatorze oraz wymuszenia od falowania morza w zależności od stanu morza. Przedstawiono wyniki takich symulacji.
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Generation of large finite-element matrices on multiple graphics processors
PublicationThis paper presents techniques for generating very large finite-element matrices on a multicore workstation equipped with several graphics processing units (GPUs). To overcome the low memory size limitation of the GPUs, and at the same time to accelerate the generation process, we propose to generate the large sparse linear systems arising in finite-element analysis in an iterative manner on several GPUs and to use the graphics...
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Assessment of Trace Metals Leaching During Rainfall Events from Building Rooftops with Different Types of Coverage – Case Study
PublicationRunoff water is an important medium transporting various types of pollution originating from the atmosphere and washed out from roofing materials. The study presents a quality assessment of runoff from different roofs in the context of trace metal concentrations. The analysed rooftops were covered with copper, tar paper and ceramic tile. The quality of the rain water collected at the same time satisfies the demands of the first...
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Możliwości wykorzystania sieci ASG-EUPOS do walidacji okrętowych urządzeń nawigacyjnych
PublicationW artykule przedstawiono wyniki analiz możliwości wykorzystania serwisów czasu rzeczywistego sieci ASG-EUPOS do walidacji wybranych urządzeń nawigacyjnych. Rozważania teoretyczne uzupełniono pomiarami wykonanymi na jednostce pływającej, manewrującej na Zatoce Gdańskiej. Rejestrowano wskazania odbiorników pracujących w sieci ASG-EUPOS oraz odbiorników systemu GPS wykorzystujących korekty różnicowe. Zaprezentowano wyniki przeprowadzonych...
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Assessment of tensile forces in Sopot Forest Opera membrane by in situ measurements and iterative numerical strategy for inverse problem
PublicationAssessment of tensile forces in newly build Sopot Forest Opera roofing membrane is presented. The procedure is based on in situ measurements and solution of the inverse problem by an iterative procedure. The goal of the analysis is to determine whether the stress state of the membrane is consistent with the design assumptions. The paper contains the description of measurements, used instruments, applied loadings, numerical investiga-tions...
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Ekonomicna efektivnisot` tieplovich pomp = Economic effectivenes ofheat pum-ps
PublicationNowe technologie w zakresie wytwarzania energii powinny spełniać kryterium efektywności ekonomicznej i kryterium efektywności energetycznej, które oznacza zmniejszenie zużycia energii pierwotnej po zastosowaniu nowej technologii. Kryteria te są bardzo wrażliwe na zmiany parametrów eksploatacyjnych systemów energetycznych i zmiany parametrów makroekonomicznych. W publikacji opisano model matematyczny powyższych kryteriów dla...
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Influence of gas turbine controller adjustment on propulsion system behaviour in high sea conditions. Part 1. The dynamic model of propulsion system.
PublicationDo badań przyjęto układ napędowy okrętowy z turbinami gazowymi napędzającymi poprzez przekładnię mechaniczną zębatą śrubę okrętową o zmiennym skoku. Nakład napędowy statku z turbinami gazowymi napędzającymi śrubę nastawną oddziałują wymuszenia zarówno od nastaw prędkości obrotowej wału śrubowego jaki skoku śruby napędowej, ale również istnieje silna reakcja od falowania morza (stanu morza) na pracę układu napędowego. Zbudowano...
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Gas chromatography-olfactometry (GC-O), electronic noses (e-noses) and electronic tongues (e-tongues) for in vivo food flavour measurement
PublicationThe capter revies two types of artificial olfaction instrumentation, i.e. gas-chromatography-olfactometry (GC-O) and chemical sensor technologies (electronic nose and tongue), combined with multivariate data processing methods as promising approaches for rapid analysis of food. The chapter also includes examples of specific applications for the detection of food flavour and volatile components.
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An energetic analysis of a gas turbine with regenerative heating using turbine extraction at intermediate pressure - Brayton cycle advanced according to Szewalski's idea
PublicationIn this paper, a modification of a simple gas turbine into the Brayton cycle with regenerative heating, using turbine extraction at intermediate pressure, is presented. The main concept of the retrofitting is based on the transfer of heat from the turbine exhaust gases to the air entering the combustion chamber. The extracted gas transfers heat to air via the divided regenerative heat exchanger and after that is compressed and...
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Quantification of unconjugated and total ibuprofen and its metabolites in equine urine samples by gas chromatography–tandem mass spectrometry: Application to the excretion study
PublicationIbuprofen (IBU) is a widely used nonsteroidal anti-inflammatory drug (NSAID) in human and also veterinary medicine. NSAIDs are usually highly metabolized compounds in horses; they are often present in equine urine, mostly in their conjugated forms (glucuronides). Thus, hydrolysis to cleave the glucuronide linkage prior to anti-doping analysis is often necessary for improving detection. In this study, unconjugated and total IBU...
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Example of Using Particle Swarm Optimization Algorithm with Nelder–Mead Method for Flow Improvement in Axial Last Stage of Gas–Steam Turbine
PublicationThis article focuses principally on the comparison baseline and the optimized flow efficiency of the final stage of an axial turbine operating on a gas–steam mixture by applying a hybrid Nelder– Mead and the particle swarm optimization method. Optimization algorithms are combined with CFD calculations to determine the flowpaths and thermodynamic parameters. The working fluid in this study is a mixture of steam and gas produced...
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Synergistic effects of a swirl generator and MXene/ water nanofluids used in a heat exchanger pipe of a negative CO2 emission gas power plant
Publicationfocus on optimizing heat exchangers contributes to improved temperature control mechanisms, ensuring the sustainable operation of innovative power plants working towards negative CO2 emissions. In the realm of oxy-combustion within Negative CO2 Emission Power Plants (nCO2PP), the temperature of combustion products surpasses 3000 (K). Addressing this challenge, the imperative arises to reduce these elevated temperatures to a manageable...
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CO2 capture using steam ejector condenser under electro hydrodynamic actuator with non-condensable gas and cyclone separator: A numerical study
PublicationThe concept for condensation of steam and CO2 separation in a negative CO2 emission gas power plant involves the utilization of a steam ejector condenser (SEC) for direct-contact condensation of vapor with inert gas (CO2) on a spray of subcooled liquid, integrated with a separator to produce pure CO2. Due to the increasing diffusion resistance and reduced convective heat transfer between the steam and subcooled water phases...
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Electrochemical detection of bacterial endotoxin lipopolysaccharide (LPS) on gold electrode modified with DAL-PEG-DK5-PEG-OH - Antimicrobial peptide conjugate
PublicationThis work describes fabrication of gold electrodes modified with peptide conjugate DAL-PEG-DK5-PEG-OH that enables ultra-sensitive detection of lipopolysaccharide (LPS) isolated from the reference strain of Escherichia coli O26:B6. The initial step of the established procedure implies immobilization of the fully protected DAL-PEG-DK5-PEG-OH peptide on the surface of the gold electrode previously modified by cysteamine. Then side...
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Gas-phase quasi-degeneracy of zwitterionic and canonical tautomers of glycine and proline induced by the presence of the MAlF4(M = Li, Na, K) salts
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Determination of polybrominated diphenyl ethers in house dust using standard addition method and gas chromatography with electron capture and mass spectrometric detection
PublicationMonitoring of the environmental fate of polybrominated diphenyl ethers (PBDEs) involves determination of their concentration in air, airborne particles and settled dust. This requires the implementation of appropriate analytical tools like measuring instruments, reference materials and analytical procedures. In this study an analytical procedure was developed for determining PBDEs in samples with a complex matrix composition. The...