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Search results for: DIFFRACTION OF BEAMS
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Interplay of hydrogen bonding and aryl-perfluoroaryl interactions in construction of supramolecular aggregates
PublicationThe stacking between aryl and perfluoroaryl units is an important class of the aromatic – aromatic interactions that has attracted rapidly growing interest in recent years. Continuing interest of our group in this subject it had been prepared three new complexes of pentafluorobenzoic acid with benzyl alcohol, 4-methylbenzyl alcohol and 4-tert-butylbenzyl alcohol and in the next step investigated their self-assembly modes by...
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Crystal structure and low-energy Einstein mode in ErV2Al20 intermetallic cage compound
PublicationSingle crystals of a new ternary aluminide ErV2Al20 were grown using a self-flux method. The crystal structure was determined by powder X-ray diffraction measurements and Rietveld refinement, and physical properties were studied by means of electrical resistivity, magnetic susceptibility and specific heat measurements. These measurements reveal that ErV2Al20 is a Curie-Weiss paramagnet down to 1.95 K with an effective magnetic...
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Granulometric analysis to etimate influence of anionic surfactrant on activated sludge structure
PublicationThe work concerns the evaluation of the possibility of using laser diffraction analyzer to determine changes in the distribution of sludge floc size in the presence of anionic surfactant. As a model of surfactant linear alkylbenzyne sulphonate (LAS) was used. The granulometric analysis showed that the pure activated sludge was composed of particles with a size of 0,001 to 2 mm. The largest and fastest changes in the distribution...
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Structure and optical parameters of Eu doped tellurium oxide thin films prepared by reactive magnetron sputtering method
PublicationIn this work the structural properties and photoluminescence of tellurium dioxide thin films doped by europium were described. Thin films were deposited by magnetron sputtering method and simultaneously heated at 200 °C. Presence of Eu ions and their valence states was confirmed by X-ray photoemission spectroscopy measurements. The structure of the films as well as the influence of europium dopant on crystalline structure of the...
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Influence of drying mode and feed per tooth rate on the fine dust creation in pine and beech sawing on a mini sash gang saw
PublicationThe experimental results of the study focused on the effect of drying processes of modified air drying and warm air steam mixture drying of pine and beech wood on the size of sawdust particles created in cutting using PRW-15M sash gang saw, are presented in the paper. Particle size analysis of dry sawdust was performed using two methods—sieving method and laser diffraction analysis. The results showed that the drying process did...
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Cluster-spin-glass behavior in new ternary RE2PtGe3 compounds (RE = Tb, Dy, Ho)
PublicationTwo new ternary germanides Tb2Pt1.2Ge2.8, Dy2Pt1.15Ge2.85 and one already known germanium Ho2Pt1.1Ge2.9.were synthesized using an arc melting technique. The obtained samples were investigated by powder X-ray diffraction, which indicated that all of them crystallized in a hexagonal structure with P6/mmm (no. 191) space group. This structure is a disordered variant of the AlB2 aristotype that favors the formation of a spin-glass-like...
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Phosphinoborenium cations stabilized by N-heterocyclic carbenes: synthesis, structure, and reactivity
PublicationPhosphinoborenium cations stabilized by N-heterocyclic carbenes (NHCs) were synthesized via the reaction of bromo(phosphino)boranes with NHCs. Their structures were investigated by heteronuclear magnetic resonance spectroscopy, X-ray diffraction, and density functional theory calculations. They possess a planar trigonal boron center directly bonded with the pyramidal phosphanyl group (PR2) and can be treated as cationic phosphinoboranes....
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Innovative management of IT projects with the use of the agent-based approach on the basis of intelligent agents
PublicationProject management is one of the major challenges for the modern economy. Dynamic changes in the structures of organizations which form the core of the economy imply changes in both management processes and structures. One element of these changes is a new approach to the manufacturing of modern and rapidly changing products (due to changing market requirements). As part of these changes, traditional organizational structures are...
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Role of bead sequence in underwater welding
PublicationThis paper presents examinations of the role of the bead sequence in underwater welding. Two specimens of wet welded layers made by covered electrodes with the use of normalized S355G10+N steel were welded by a reasonable bead sequence. For each specimen, metallographic macro- and micro-scopic tests were done. Then, Vickers HV10 hardness measurements were conducted for each pad weld in the welded layer. The results show that welding...
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Buckling of thin-walled columns accounting for initial geometrical imperfections
PublicationThe paper is devoted to the effect of some geometrical imperfections on the critical buckling load of axially compressed thin-walled I-columns. The analytical formulas for the critical torsional and flexural buckling loads accounting for the initial curvature of the column axis or the twist angle respectively are derived. The classical assumptions of theory of thin-walled beams with non-deformable cross-sections are adopted. The...
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High-quality Experiment Dedicated to microGravity Exploration, Heat Flow and Oscillation Measurement from Gdańsk
PublicationIn this paper we propose HEDGEHOG (High-quality Experiment Dedicated to microGravity Exploration, Heat flow and Oscillation measurement from Gdańsk) REXUS experiment to investigate vibrational and heat flow phenomena during the whole (ascent, microgravity phase, descent and recovery) flight of a sounding rocket. First, a proposed system of cantilever beams is discussed to study dynamic behaviour of dummy payload. Dimensioning has...
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DYNAMIC ANALYSIS OF THE RAILWAY BRIDGES IN POLAND WITH REGARDS TO HIGH-SPEED TRAINS PASSAGE ADJUSTMENT
PublicationThe dynamic analysis of the railway bridge in Tczew was carried out in the article as an example of such bridges adaptation suitability to handle high-speed trains. Calculations of railway bridges are greatly complicated and labor-consuming. The bridge model and a rolling stock passage simulation were developed in the SOFISTIK software. Three types of elements were used for the correct mapping of the structure in the calculation...
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Periodic solutions of Lagrangian systems under small perturbations
PublicationIn this paper we prove the existence of mountain pass periodic solutions of a certain class of generalized Lagrangian systems under small perturbations. We show that the found periodic solutions converge to a periodic solution of the unperturbed system if the perturbation tends to 0. The proof requires to work in a rather unusual (mixed) Orlicz–Sobolev space setting, which bears several challenges.
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Spectroscopic Optical Coherence Tomography for Thin Layer and Foil Measurements
PublicationThe main goal of this research was to assess if it is possible to evaluate the thickness of thin layers (both thin films on the surface and thin layers below the surface of the tested object) and foils using optical coherence tomography (OCT) for thickness assessment under the resolution of the standard commercially available OCT measurement system. In the proposed solution, light backscattered from the evaluated thin layer has...
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Testing of low temperature behaviour of asphalt mixtures in bending creep test
PublicationThe paper presents a method of bending beam test and its importance for evaluation of asphalt mixtures behaviour at low temperatures. Two types of asphalt mixtures: asphalt concrete AC with normal paving grade bitumen and stone mastic asphalt SMA with SBS-modified bitumen were tested. Long-term oven ageing (LTOA) test was also used in the laboratory according to SHRP procedure. The Burgers model was applied and rheological parameters...
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3D Monitoring - Identification of measurement problems at larger movements of the tracked points
PublicationAuthors identified the problems associated with the determination of the controlled points coordinates by use of automated Total Station placed behind transparent barrier. Important thing in the mentioned analysis was a large change of controlled points position and not stable Total Station’s stand (because of stand’s thermal drift). This two elements, combined with measurement made through glass plate determine the need for impact...
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PRELIMINARY FIELD TESTS AND LONG-TERM MONITORING AS A METHOD OF DESIGN RISK MITIGATION: A CASE STUDY OF GDAŃSK DEEPWATER CONTAINER TERMINAL
PublicationAppropriate risk assessment plays a fundamental role in the design. . The authors propose a possible method of design risk mitigation, which follows recommendations included in Eurocode 7. The so-called “Observational Method” (OM) can produce savings in costs and programmes on engineering projects without compromising safety. The case study presented is a complex design solution that deals with the heavy foundations of a gantry...
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On instabilities and post-buckling of piezomagnetic and flexomagnetic nanostructures
PublicationWe focus on the mechanical strength of piezomagnetic beam-like nanosize sensors during post-buckling. An effective flexomagnetic property is also taken into account. The modelled sensor is selected to be a Euler-Bernoulli type beam. Long-range interactions between atoms result in a mathematical model based on the nonlocal strain gradient elasticity approach (NSGT). Due to possible large deformations within a post-buckling phenomenon,...
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Portico Farmhouses of the Vistula Delta: Architecture, Current State and Finite Element Modelling of Timber Roof Truss under Material and Cross-section Uncertainty
PublicationThe article focuses on the oldest surviving I-type portico houses located in the Vistula Delta, which were built in the 17th and 18th centuries. The study describes the houses’ origins, structure, details of roof structures and technical condition, and it also includes numerical modelling of a roof truss and its mechanical analysis. Numerical models of the roof trusses are defined and analysed by means of the finite element method....
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Research 1: Heterojunction of (P, S) co-doped g-C3N4 and 2D TiO2 for improved carbamazepine and acetaminophen photocatalytic degradation
Open Research DataThe first research article consisted on the synthesis of phosphorus and sulfur co-doped graphitic carbon nitride incorporated in 2D TiO2 structure for solar-driven degradation of emerging pollutants from the group of pharmaceuticals not susceptible to biodegradation. The hybrid photocatalysts with different loadings of (P, S)-doped g-C3N4 were characterized...
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Evaluation of affective intervention process in development of affect-aware educational video games
PublicationIn this paper initial experiences are presented on implementing specific methodology of affective intervention design (AFFINT) for development of affect-aware educational video games. In the described experiment, 10 student teams are to develop affect-aware educational video games using AFFINT to formalize the whole process. Although all projects are still in progress, first observations and conclusions may already be presented.
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Pr-doped TiO2: The effect of metal content on photocatalytic activity
PublicationThe Pr-TiO2 nanoparticles were prepared by using the sol-gel method. As-prepared samples were characterized by BET measurements, X-ray powder diffraction analysis (XRD) and UV-Vis spectra. Visible and ultraviolet light photocatalytic activity of the sample was studied by photodegradation of phenol while considering the influence of the dopant concentration. TiO2 doped with 0.25 mol% of praseodymium showed the highest photocatalytic...
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Characterization of CaTi0.9Fe0.1O3/La0.98Mg0.02NbO4 composite
PublicationA composite of CaTi0.9Fe0.1O3 and electrolyte material, i.e. magnesium doped La0.98Mg0.02NbO4 was prepared and studied. The phase content and the sample microstructure was examined by an X-ray diffraction method and scanning electron microscopy. EDS measurements were done both for composite samples and the diffusion couple. The electrical properties were studied by four terminal DC method. The Ahigh-temperature interaction between...
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Characterization of magnesium doped lanthanum orthoniobate synthesized by molten salt route
PublicationMolten salt synthesis method has been used to prepare the single phase magnesium doped lanthanum orthoniobate. The phase composition has been checked by X-ray diffraction method and the microstructure studies have been performed by scanning electron microscopy. The high temperature properties of the material have been investigated by thermogravimetry and electrochemical impedance spectroscopy. A dependence between sample total...
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New heterometallic Co/Zn, Ag/Co, and Ag/Zn imidazolates: structural characterization and catalytic activity in the oxidation of organic compounds
PublicationNanocrystalline powders of monometallic and bimetallic imidazolates of Co, Zn, and Ag were produced by a reaction carried out in water. The powders were characterized by powder X-ray diffraction and the crystal structures of new compounds Ag2ZnIm4 and Ag2CoIm4 (Im = imidazolate) were solved. Heterometallic Co/Zn imidazolates showed the standard ZIF-8 crystal structure while Ag/Zn and Ag/Co systems were isostructural with the copper...
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ALTERNATIVE, DIRECT SYNTHESIS METHOD OF THE CERAMIC SOLID SOLUTIONS BASED ON BaTiO3 THROUGH A HIGH ENERGY BALL MILLING
PublicationPolycrystalline samples BaTiO3 and the solid solutions Ba0.9Sr0.1TiO3, Ba0.9Sr0.1Ti0.9Sn0.1O3, Ba0.9Sr0.1Ti0.8Sn0.2O3 were obtained by means of a mechanochemical treatment based on the high-energy ball milling technique and next a high temperature solid state reaction method. The influence of synthesis condition on microstructural, dielectric and ferroelectric properties of obtained solid solutions were investigated. The structure...
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Synthesis, structure and physical properties of new intermetallic spin glass-like compounds RE2PdGe3 (RE = Tb and Dy)
PublicationNew intermetallic compounds Tb2Pd1.25Ge2.75 and Dy2Pd1.25Ge2.75 have been synthesized using the arc-melting method. The crystallographic structure and magnetic, electronic transport, and thermal properties are reported. The crystal structure obtained from powder x-ray diffraction analysis suggests that these compounds crystallize in the AlB2-type structure (space group P6/mmm, no. 191) with lattice parameters a = 4.228 53(5)/4.230 54...
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STRUCTURE AND MAGNETIC PROPERTIES OF Bi5Ti3FeO15 CERAMICS PREPARED BY SINTERING, MECHANICAL ACTIVATION AND EDAMM PROCESS. A COMPARATIVE STUDY
PublicationThree different methods were used to obtain Bi5Ti3FeO15 ceramics, i.e. solid-state sintering, mechanical activation (MA) with subsequent thermal treatment, and electrical discharge assisted mechanical milling (EDAMM). The structure and magnetic properties of produced Bi5Ti3FeO15 samples were characterized using X-ray diffraction and Mössbauer spectroscopy. The purest Bi5Ti3FeO15 ceramics was obtained by standard solid-state sintering...
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Double ZIF-L structures with exceptional CO2 capacity
PublicationCarbon dioxide emission is an emerging problem nowadays and new methods are designed for its control. In this article, a report on the formation of zeolitic imidazole framework with an apparent double leaf-like morphology DZIF-L is given. The special structure of the materials prevents from aggregation of the particles providing remarkable CO2 capacity. At 0.1 MPa the CO2 uptake was 2.99 ± 0.06 mmol/g. The capacity of synthesized...
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Exploring the Reactivity of Unsymmetrical Diphosphanes toward Heterocumulenes: Access to Phosphanyl and Phosphoryl Derivatives of Amides, Imines, and Iminoamides
PublicationWe present a comprehensive study on the diphosphanation of iso(thio)cyanates by unsymmetrical diphosphanes. The reactions involving unsymmetrical diphosphanes and phenyl isocyanate or phenyl thioisocyanate gave rise to phosphanyl, phosphoryl, and thiophosphoryl derivatives of amides, imines, and iminoamides. The structures of the diphosphanation products were confirmed through NMR spectroscopy, IR spectroscopy, and single-crystal...
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Additive manufacturing of Proton-Conducting Ceramics by robocasting with integrated laser postprocessing
PublicationA hybrid system combining robocasting and NIR laser postprocessing has been designed to fabricate layers of mixed proton-electron conducting Ba0.5La0.5Co1-xFexO3-δ ceramic. The proposed manufacturing technique allows for the control of the geometry and microstructure and shortens the fabrication time to a range of a few minutes. Using 5 W laser power and a scanning speed of 500 mm⋅s− 1, sintering of a round-shaped layer with an...
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π-Indenyl substituted zirconium compounds containing terminal bondedphosphanylphosphido ligands [Ind2Zr(Cl){(Me3Si)P-PR2-jP1}]. Synthesis,X-ray analysis and NMR studies
PublicationPraca prezentuję reakcję kompleksów indenylowych cyrkonu z solami litowymi difosfanów o ogólnym wzorze R2P-P(SiMe3)Li, gdzie R = tBu, Et2N, iPr2N. W wyniku tych reakcji otrzymano 3 nowe kompleksy fosfanylofosfidowe.Otrzymane nowe kompleksy zbadano przy pomocy technik rentgenowskiej analizy strukturalnej i NMR.Dichloro-bis(indenyl)zirconium(IV) reacts with lithium derivatives of diphosphanes R2P-P(SiMe3)Li (R = tBu, Et2N, iPr2N)...
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Vortex flow caused by periodic and aperiodic sound in a relaxing maxwell fluid
PublicationThis paper concerns the description of vortex flow generated by periodic and aperiodic sound in relaxing Maxwell fluid. The analysis is based on governing equation of vorticity mode, which is a result of decomposition of the hydrodynamic equations for fluid flow with relaxation and thermal conductivity into acoustical and non-acoustical parts. The equation governing vorticity mode uses only instantaneous, not averaged over sound...
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Low-coherence sensors with nanolayers for biomedical sensing
PublicationIn this paper, we describe the fiber optic low-coherence sensors using thin film. We investigated their metrological parameters. Presented sensors were made with the use of standard telecommunication single mode optical fiber (SMF28). Different materials were applied to obtain thick layers, such as boron doped diamond, silver and gold. The thickness of layers used in the experiments ranged from 100 nm to 300 nm. Measurements were...
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Local buckling of thin-walled channel member flange made of aluminum alloy
PublicationThe paper deals with local stability of the thin-walled compressed flange of channel columns and beams made of aluminum alloy. The aim of paper is to find critical stress of local buckling of the flange member taking into account the web-flange interaction in linear and nonlinear elastic range of the member material. The governing differential equation of the problem is derived with aid of the principle of stationary total potential...
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Non-destructive Diagnostics of the Floor in the Gdańsk Crane Using Ground Penetrating Radar = Diagnostyka nieniszcząca posadzki w gdańskim Żurawiu z zastosowaniem metody georadarowej
PublicationThis paper presents the results of a ground penetrating radar (GPR) survey carried out at the Crane in Gdańsk. The measurements were conducted on the floor of the southern and northern towers. The aim of the experiment is to assess the possibility of detecting anomalies beneath the floor. The surveys were carried out in a non-destructive manner, using a georadar unit with 2 GHz and 400/900 MHz antennas. This paper compares the...
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Bearing Capacity of aluminum bars with built-up cross section and glued or welded connections
PublicationThe paper is focused on numerical analysis and experimental test of aluminum bars with glued and welded connections between separate members. The connection properties were tested experimentally. The numerical analysis were conducted for the beam and shell model of the structure. The shape and magnitude of initial geometric imperfection was taken into account
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Solar light driven degradation of norfloxacin using as-synthesized Bi 3+ and Fe 2+ co-doped ZnO with the addition of HSO 5 – : Toxicities and degradation pathways investigation
PublicationIn this study, solar light responsive Bi3+ and Fe2+ doped ZnO were synthesized and used for photocatalytic degradation of norfloxacin (NOR), an emerging water pollutant. Analysis with Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), selected area electron...
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Potential Skyrmion Host Fe(IO3)3: Connecting Stereoactive Lone-Pair Electron Effects to the Dzyaloshinskii-Moriya Interaction
PublicationMagnetic skyrmions, which are topologically distinct magnetic spin textures, are gaining increased attention for their unique physical properties and potential applications in spintronic devices. Here we present a design strategy for skyrmion host candidates based on combinations of magnetic spin, asymmetric building units having stereoactive lone-pair electrons, and polar lattice symmetry. To demonstrate the viability of the proposed...
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MSRL 2.0. as a new method for research education on urban issues
PublicationThe MSRL 2.0. research is focused on the Baltic Sea Region (BSR) as a multidimensional urban phenomenon with Gdansk acting as a hub for the research teams. The idea of the MSRL 2.0. is to promote the collaboration of professionals and graduate and PhD students by bringing together the mentor(s) with a local research team sharing experiences and proposing strategic recommendations to strengthen sustainable urban development initiatives...
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Wpływ zbrojenia polimerowymi włóknami rozproszonymi na wybrane właściwości mieszanek mineralno-asfaltowych
PublicationW artykule przedstawiono wybrane wyniki badań mieszanek mineralno-asfaltowych zbrojonych polimerowymi włóknami rozproszonymi. Ocenie poddano mieszankę włókien zbrojących aramidowo-poliolifenowych pod kątem wpływu ich zastosowania na właściwości niskotemperaturowe i odporności na deformacje trwałe mieszanek mineralno-asfaltowych. Właściwości niskotemperaturowe oceniano na podstawie testu zginania próbek belkowych oraz na podstawie...
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Surface treatment of C80U steel by long CO2 laser pulses
PublicationThe paper presents the results of laser-melted C80U steel. The processed steel was placed between two permanent magnets and laser beam whose scanning velocity was 10 mm/s. CO2 laser beam was working in pulse mode. Pulses were generated at 100% of the average preset power of 700W, with 45 ms irradiation, zero interval between pulses and beginning of pulse repetition upon the achievement of the average laser power. During the operation,...
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Low energy differential elastic electron scattering from trichloromethane
PublicationExperimental differential cross sections for low energy electron scattering from trichloromethane is measured utilizing a crossed electron-molecular beam experiment via the relative flow method, for the incident electron energies in the range of E = 0.5 eV-30 eV and the scattering angles in the range of θ = 10◦ − 130◦ .
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Low frequency noise and DLTS as silicon solar cell characterization tools
PublicationPraca zawiera wyniki pomiarów DLTS próbek o powierzchni 1 mm2 krzemowych baterii słonecznych wykazujących znaczne niejednorodności wykryte za pomocą metody LBIV (Light Beam Induced Voltage). Wyniki pomiarów charakterystyk stałoprądowych oraz szumowych tych próbek zostały także przedstawione.
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Heteroleptic tri-tert-butoxysilanethiolate complexes of manganese(II) - thermal studies
PublicationThe thermal behavior of Mn(II) silanethiolate series [Mn(SR)2L(MeOH)n], where R=SSi(OBut)3, L=heterocyclic nitrogen base and n=0, 1 or 2 has been comparatively investigated using differential scanning calorimetry (DSC), thermogravimetry (TG) and TG-infrared spectoscopy (IR) techniques. The TG curves indicate the differences in the thermal decomposition due to presence of distinct N-donor ligands and labile MeOH molecules coordinated...
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The study of structure and surface morphology of lithium titanate sol-gel derived thin films
PublicationIn this paper the structure and the surface morphology of lithium titanate (LTO) thin films are presented. Nanocrystalline thin films were prepared by sol–gel method. To examine the influence of the annealing time on as-prepared films crystallization, the coatings were heated at different temperatures in the range of 500 °C–600 °C for 10, 20, 40 and 80 h. The structure of the obtained material was investigated using the X-ray diffraction...
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Synthesis, single crystal growth and properties of Sr5Pb3ZnO12
PublicationAbstract The novel Sr5Pb3ZnO12 oxide was synthesized by the solid-state reaction method. The crystal structure was studied by means of the powder x-ray diffraction Rietveld method and was found to be similar to 3 other previously known Sr5Pb3MO12 compounds (M = Co, Ni, Cu). Crystals of several hundred microns in size of the new phase were grown in molten sodium chloride and imaged using confocal optical and scanning electron microscopy....
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Nonlinear and linear impedance of bismuth vanadate ceramics and its relation to structural properties
PublicationThe nonlinear and linear electrical properties, topography, and microstructure of bismuth-vanadate ceramics, were studied. The structurewas observed with the use of X-ray diffraction (XRD), scanning electronmicroscopy (SEM), atomic force microscopy (AFM) and confocal microscopy methods. The obtained results showed that ceramic is porous. Two phase transitionswere determinedwith the use of DSC measurements. The linear and nonlinear ac...
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Interaction of SrTi0.65Fe0.35O3-δ with LaNi0.6Fe0.4O3-δ, La0.6Sr0.4Co0.2Fe0.8O3-δ and Ce0.8Gd0.2O2-δ
PublicationIron doped strontium titanates SrTi1-xFexO3-δ are perovskites of versatile properties. They can be used in solid oxide fuel cells or high temperature oxygen sensors. Their reactivity with electrolyte materials, cathode buffer layer materials, other cathode materials or current collector layers has not been fully tested. In this study we use X-ray diffraction to check SrTi0.65Fe0.35O3-δ compatibility with Ce0.8Gd0.2O2-δ (used as...
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The influence of thermal conditions on V2O5 nanostructures prepared by sol-gel method
PublicationThis work presents the result of structure investigations ofV 2O5 nanorods grown from thin films and powders prepared by sol-gel method. To examine the best temperature of nanorods crystallization, thin films deposited by spin-coating method on quartz glass or silicon substrates and bulk xerogel powders were annealed at various temperatures ranging from 100∘C to 600∘C. The structure of the samples was characterized by X-ray diffraction...